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Status of Water Levels and Selected Water-Quality Conditions in the Mississippi River Valley Alluvial Aquifer in Eastern Arkansas, 2004

During the spring of 2004, water levels were measured in 684 wells completed in the Mississippi River Valley alluvial aquifer in eastern Arkansas. Ground-water levels are affected by intense ground-water withdrawals resulting in extensive potentiometric depressions. In 2004, the highest water-level altitude measured was 293 feet above National Geodetic Vertical Datum of 1929 in northeastern Clay County. The lowest water-level altitude measured was 76 feet above National Geodetic Vertical Datum of 1929 in the center of Arkansas County. A large depression in the potentiometric surface was located in Arkansas, Lonoke, and Prairie Counties during 1998 and persisted to 2002. The area enclosed in the 100-foot contour in Arkansas County in 2004 is about the same as in 2002, however, the area enclosed in the 100-foot contour in Lonoke and Prairie Counties in 2004 has receded. Two shallower cones of depressions were located in Craighead, Cross, and Poinsett Counties and St. Francis, Woodruff, Lee, and Monroe Counties west of Crowleys Ridge during 1998. The 2004 potentiometricsurface map shows that the areas enclosed by the 140-foot contour have continued to expand. A map of changes in water-level measurements between 2000 and 2004 was constructed using the difference between water-level measurements from 625 wells reported in this report and the 2000 Mississippi River Valley alluvial aquifer report. Water-level changes between 2000 and 2004 ranged from -31.1 feet to 16.3 feet, with a mean of -0.7 feet (negative changes indicating water-level declines, positive changes indicating water-level rises). The largest rise of 16.3 feet is in Arkansas County and the largest decline of -31.1 feet is in Prairie County. Long-term water-level changes were calculated for 134 wells in the alluvial aquifer for the period from 1980 to 2004. The mean annual decline in water level for the entire study area was -0.31 feet per year with a range of -1.35 feet per year to 0.84 feet per year. The analysis of long-term water-level changes (1980-2004) in the depression in Arkansas and Prairie Counties shows the effects of the elongation of this depression. Water samples were collected from 138 wells completed in the alluvial aquifer and measured onsite for specific conductance and temperature. Samples were collected at 71 wells for dissolved chloride analysis at the U.S. Geological Survey National Water Quality Laboratory. Specific conductance ranged from 205 microsiemens per centimeter at 25 degrees Celsius at a well in Lonoke County to 1,440 microsiemens per centimeter at 25 degrees Celsius at a well in Monroe County.

Scientific Investigations Report↗

Control-structure ratings on the Chicago Sanitary and Ship Canal near Lockport, Illinois

The U.S. Army Corps of Engineers and the Metropolitan Water Reclamation District of Greater Chicago regulate flows through control structures along the Lake Michigan lakefront and the Chicago Sanitary and Ship Canal (CSSC) for Lake Michigan diversion accounting, flood control, sanitary, and navigation purposes. This report documents the measurement and computation of flow through the Lockport Controlling Works (LCW) and the Lockport Powerhouse. This analysis aided in evaluation of the ratings at both structures, and the development of new ratings at the controlling works. The LCW structure consists of seven 30-feet (ft) wide sluice gates and is used to divert water from the CSSC and into the Des Plaines River. The flow regimes for the sluice gate included both free and submerged weir. Forty and 491 flow values from U.S. Geological Survey streamflow-gaging stations were used to develop equations describing free- and submerged-weir flow, respectively, through the sluice gates. The equations were developed for canal headwater elevations ranging from -7.0 to -10.5 ft Chicago City Datum (CCD), and tailwater (Des Plaines River at Lockport) to headwater (CSSC-LCW-Base) ratios ranging from 0.31 to 0.66. The Lockport Powerhouse structure consists of nine 9-ft wide by 14-ft high sluice gates and two 10-ft diameter turbines. Both tailwater and no-tailwater effect flow regimes occurred during nine measurements. Also, the canal headwater elevations ranged from -2.74 to -8.45 ft CCD, and the gates were configured six different ways during the measurements.

Illinois↗

Water-level and recoverable water in storage changes, High Plains aquifer, predevelopment to 2015 and 2013–15

The High Plains aquifer underlies 111.8 million acres (about 175,000 square miles) in parts of eight States—Colorado, Kansas, Nebraska, New Mexico, Oklahoma, South Dakota, Texas, and Wyoming. Water-level declines began in parts of the High Plains aquifer soon after the beginning of substantial irrigation with groundwater in the aquifer area (about 1950). This report presents water-level changes and change in recoverable water in storage in the High Plains aquifer from predevelopment (about 1950) to 2015 and from 2013 to 2015. The methods to calculate area-weighted, average water-level changes; change in recoverable water in storage; and total recoverable water in storage used geospatial data layers organized as rasters with a cell size of 500 meters by 500 meters, which is an area of about 62 acres. Raster datasets of water-level changes are provided for other uses. Water-level changes from predevelopment to 2015, by well, ranged from a rise of 84 feet to a decline of 234 feet. Water-level changes from 2013 to 2015, by well, ranged from a rise of 24 feet to a decline of 33 feet. The area-weighted, average water-level changes in the aquifer were an overall decline of 15.8 feet from predevelopment to 2015 and a decline of 0.6 feet from 2013 to 2015. Total recoverable water in storage in the aquifer in 2015 was about 2.91 billion acre-feet, which was a decline of about 273.2 million acre-feet since predevelopment and a decline of 10.7 million acre-feet from 2013 to 2015.

Colorado, Kansas, Nebraska, New Mexico, Oklahoma, ↗

A field study of selected U.S. Geological Survey analytical methods for measuring pesticides in filtered stream water, June - September 2012

U.S. Geological Survey monitoring programs extensively used two analytical methods, gas chromatography/mass spectrometry and liquid chromatography/mass spectrometry, to measure pesticides in filtered water samples during 1992–2012. In October 2012, the monitoring programs began using direct aqueous-injection liquid chromatography tandem mass spectrometry as a new analytical method for pesticides. The change in analytical methods, however, has the potential to inadvertently introduce bias in analysis of datasets that span the change. A field study was designed to document performance of the new method in a variety of stream-water matrices and to quantify any potential changes in measurement bias or variability that could be attributed to changes in analytical methods. The goals of the field study were to (1) summarize performance (bias and variability of pesticide recovery) of the new method in a variety of stream-water matrices; (2) compare performance of the new method in laboratory blank water (laboratory reagent spikes) to that in a variety of stream-water matrices; (3) compare performance (analytical recovery) of the new method to that of the old methods in a variety of stream-water matrices; (4) compare pesticide detections and concentrations measured by the new method to those of the old methods in a variety of stream-water matrices; (5) compare contamination measured by field blank water samples in old and new methods; (6) summarize the variability of pesticide detections and concentrations measured by the new method in field duplicate water samples; and (7) identify matrix characteristics of environmental water samples that adversely influence the performance of the new method. Stream-water samples and a variety of field quality-control samples were collected at 48 sites in the U.S. Geological Survey monitoring networks during June–September 2012. Stream sites were located across the United States and included sites in agricultural and urban land-use settings, as well as sites on major rivers. The results of the field study identified several challenges for the analysis and interpretation of data analyzed by both old and new methods, particularly when data span the change in methods and are combined for analysis of temporal trends in water quality. The main challenges identified are large (greater than 30 percent), statistically significant differences in analytical recovery, detection capability, and (or) measured concentrations for selected pesticides. These challenges are documented and discussed, but specific guidance or statistical methods to resolve these differences in methods are beyond the scope of the report. The results of the field study indicate that the implications of the change in analytical methods must be assessed individually for each pesticide and method. Understanding the possible causes of the systematic differences in concentrations between methods that remain after recovery adjustment might be necessary to determine how to account for the differences in data analysis. Because recoveries for each method are independently determined from separate reference standards and spiking solutions, the differences might be due to an error in one of the reference standards or solutions or some other basic aspect of standard procedure in the analytical process. Further investigation of the possible causes is needed, which will lead to specific decisions on how to compensate for these differences in concentrations in data analysis. In the event that further investigations do not provide insight into the causes of systematic differences in concentrations between methods, the authors recommend continuing to collect and analyze paired environmental water samples by both old and new methods. This effort should be targeted to seasons, sites, and expected concentrations to supplement those concentrations already assessed and to compare the ongoing analytical recovery of old and new methods to those observed in the summer and fall of 2012.

Scientific Investigations Report↗

An update of the distribution of selected radiochemical and chemical constituents in perched ground water, Idaho National Laboratory, Idaho, Emphasis 1999-2001

Radiochemical and chemical wastes generated at facilities at the Idaho National Laboratory (INL) were discharged since 1952 to infiltration ponds at the Reactor Technology Complex (RTC) (known as the Test Reactor Area [TRA] until 2005), and the Idaho Nuclear Technology and Engineering Center (INTEC) and buried at the Radioactive Waste Management Complex (RWMC). Disposal of wastewater to infiltration ponds and infiltration of surface water at waste burial sites resulted in formation of perched ground water in basalts and in sedimentary interbeds above the Snake River Plain aquifer. Perched ground water is an integral part of the pathway for waste-constituent migration to the aquifer. The U.S. Geological Survey (USGS), in cooperation with the U.S. Department of Energy, maintains ground-water monitoring networks at the INL to determine hydrologic trends, and to monitor the movement of radiochemical and chemical constituents in wastewater discharged from facilities to both perched ground water and the aquifer. This report presents an analysis of water-quality and water-level data collected from wells completed in perched ground water at the INL during 1999-2001, and summarizes historical disposal data and water-level-and water-quality trends. At the RTC, tritium, strontium-90, cesium-137, dissolved chromium, chloride, sodium, and sulfate were monitored in shallow and deep perched ground water. In shallow perched ground water, no tritium was detected above the reporting level. In deep perched ground water, tritium concentrations generally decreased or varied randomly during 1999-2001. During October 2001, tritium concentrations ranged from less than the reporting level to 39.4?1.4 picocuries per milliliter (pCi/mL). Reportable concentrations of tritium during July-October 2001 were smaller than the reported concentrations measured during July-December 1998. Tritium concentrations in water from wells at the RTC were likely affected by: well's distance from the radioactive-waste infiltration ponds (commonly referred to as the warm-waste ponds); water depth below the ponds; the amount of tritium discharged to radioactive-waste infiltration ponds in the past; discontinued use of radioactive-waste infiltration ponds; radioactive decay; and dilution from disposal of nonradioactive water. During 1999-2001, the strontium-90 concentrations in two wells completed in shallow perched water near the RTC exceeded the reporting level. Strontium-90 concentrations in water from wells completed in deep perched ground water at the RTC varied randomly with time. During October 2001, concentrations in water from five wells exceeded the reporting level and ranged from 2.8?0.7 picocuries per liter (pCi/L) in well USGS 63 to 83.8?2.1 pCi/L in well USGS 54. No reportable concentrations of cesium-137, chromium-51, or cobalt-60 were present in water samples from any of the shallow or deep wells at the RTC during 1999-2001. Dissolved chromium was not detected in shallow perched ground water at the RTC during 1999-2001. Concentrations of dissolved chromium during July-October 2001 in deep perched ground water near the RTC ranged from 10 micrograms per liter (?g/L) in well USGS 61 to 82 ?g/L in well USGS 55. The largest concentrations were in water from wells north and west of the radioactive-waste infiltration ponds. During July-October 2001, dissolved sodium concentrations ranged from 7 milligrams per liter (mg/L) in well USGS 78 to 20 mg/L in all wells except well USGS 68 (413 mg/L). Dissolved chloride concentrations in shallow perched ground water ranged from 10 mg/L in wells CWP 1, 3, and 4 to 53 mg/L in well TRA A 13 during 1999-2001. Dissolved chloride concentrations in deep perched ground water ranged from 5 mg/L in well USGS 78 to 91 mg/L in well USGS 73. The maximum dissolved sulfate concentration in shallow perched ground water was 419 mg/L in well CWP 1 during July 2000. Concentrations of dissolved sulfate in water from wells USGS 54, 60

Scientific Investigations Report↗

Assessment of the presence of sewage in the Mill River under low-flow conditions, Springfield, Massachusetts, 2010–11

The U.S. Geological Survey, in cooperation with the Pioneer Valley Planning Commission, the U.S. Environmental Protection Agency, and the Massachusetts Department of Environmental Protection Senator William X. Wall Experiment Station, assessed the presence of 14 commonly used human-health pharmaceutical compounds, fecal indicator bacteria, and other man-made compounds indicative of the presence of human sewage in the lower reach of the Mill River near its confluence with the Connecticut River in Springfield, Massachusetts. The study was part of the Tri-State Connecticut River Targeted Watershed Initiative and involved the collection and analysis of raw river water at three sites along the reach, extending from Watershops Pond to the mouth, over the course of a low-flow period, July through November 2010. Previous studies in the region indicated that nonpoint or undocumented sources of wastewater contributed a variety of organic contaminants and potentially harmful bacteria to rivers under both high- and low-flow conditions. Additional samples, including a raw sewage sample collected near a Mill River combined sewer overflow during a non-overflow period, were collected in March 2011. The study was designed to determine if city sewage or other domestic sources of wastewater were entering the river within this reach during low-flow conditions. No definitive evidence of sewage was measured in Mill River water samples collected during the study period. Fecal indicator bacteria, including Escherichia coli ( E. coli ) and enterococci bacteria, were detected in all Mill River water samples. In the DNA analysis of enterococci cultures from the Mill River, samples generally tested negative for the Enterococcus faecium ( esp ) human-specific genetic marker, whereas the raw sewage sample tested positive. Samples also generally tested negative in the human-specific rDNA marker assay for the anaerobic bacterium Bacteroidetes . Samples tested negative in 2010 for two Bacteroidetes human-specific genetic markers, HF134 and HF183, except samples from near the mouth of the Mill River, which tested positive. Samples collected in March 2011 from all three measurement sites tested positive for both markers. The results of bacterial analyses suggest that the fecal bacteria in summer and fall months are most likely of animal origin rather than human. Despite the urban setting, long history of development, and many potential sources of man-made contamination in the Mill River, none of the 12 water samples collected during the study contained targeted pharmaceutical compounds at concentrations greater than the analytical reporting levels. Other man-made compounds, like fluorescent whitening agents, were measured and detected in samples at low concentrations 4 out of 5 times the samples were collected; however, the other lines of evidence do not support a sewer source but rather other nonpoint sources upstream in the watershed. The results of this study do not support the hypothesis that aging sewer lines or combined sewer overflow infrastructure leak into the Mill River as tested during the low-flow conditions during sampling for this study. None of the results from Mill River samples offer conclusive evidence of the presence of sewage. Some low-level detections of pharmaceutical compounds, other man-made chemicals, and bacteria suggest an upstream, nonpoint source. A single raw sewage sample was collected, diluted, and examined for comparison with Mill River water samples and to ensure that the analytical methods could detect typical wastewater constituents. High levels of bacteria were measured, and low levels of three anthropogenic pharmaceutical compounds were detected, confirming the effectiveness of the sub-part-per-million method. The concentration of fluorescent whitening agent-1 in the sewage sample was 90,000 times greater than the median concentration in the Mill River samples.

Massachusetts↗

Development of a screening tool to examine lake and reservoir susceptibility to eutrophication in selected watersheds of the eastern and southeastern United States

This report describes a new screening tool to examine lake and reservoir susceptibility to eutrophication in selected watersheds of the eastern and southeastern United States using estimated nutrient loading and flushing rates with measures of waterbody morphometry. To that end, the report documents the compiled data and methods (R-script) used to categorize waterbodies by Carlson’s Trophic State Index. Assessments were completed for 232 lakes and reservoirs having a surface area greater than or equal to 0.1 square kilometer in watersheds that drain to the Atlantic and eastern Gulf of Mexico coasts of the United States and in watersheds within the Tennessee River Basin. Waterbodies were categorized by type—natural lakes, headwater reservoirs, and downstream reservoirs—and were assessed independently. Recursive partitioning and the model-based boosting routine were used to create four-node regression trees to group waterbodies into five endpoints from low-to-high measures of Secchi depth, and concentrations of chlorophyll a and microcystin according to shared nutrient loading, flushing rate, and morphometric characteristics. Trophic state designations were assigned based on the average value within each of the five endpoints. An application (procedure) is provided using the tool to examine the susceptibility of a given waterbody of interest to eutrophication. Results of this study can aid water-resource managers in prioritizing lake and reservoir protection and restoration efforts based on the susceptibility of these waterbodies to eutrophication relative to nutrient loading, flushing rate, and morphometric characteristics.

Scientific Investigations Report↗

Hydrogeologic framework and conceptual model of the Red River alluvial aquifer east of Lake Texoma, southeastern Oklahoma, 1980–2022

The 1973 Oklahoma Groundwater Law (Oklahoma Statutes §82-1020.5) requires that the Oklahoma Water Resources Board conduct hydrologic investigations of the State’s groundwater basins to support a determination of the maximum annual yield for each groundwater basin. At present (2025), the Oklahoma Water Resources Board has not established a maximum annual yield for the Red River alluvial aquifer east of Lake Texoma. To support the evaluation and determination of a maximum annual yield, a hydrogeologic framework and conceptual groundwater-flow model were developed to assess groundwater availability in the Red River alluvial aquifer east of Lake Texoma. The scope of this hydrologic investigation is the alluvium and terrace containing the Red River alluvial aquifer in Oklahoma between Lake Texoma, the Texas State line, and the Arkansas State line, an extent referred to in this report as “the eastern part of the Red River alluvial aquifer.” Parts of the alluvium and terrace extent in Arkansas and Texas are included in some analyses to address hydrologic influences from outside the aquifer’s boundaries in Oklahoma. The eastern part of the Red River alluvial aquifer in southeastern Oklahoma consists of approximately 401,280 acres of Quaternary alluvium and terrace deposits associated with the Red River and its major tributaries. Mean annual recharge to the aquifer for the 1980–2022 study period was estimated to be 8.62 inches per year, or 17.98 percent of the mean annual precipitation over the same period (47.94 inches). This mean annual recharge rate is equivalent to an inflow of approximately 288,250 acre-feet per year for the eastern part of the Red River alluvial aquifer. Recharge estimated using the Soil-Water-Balance code accounts for 98.7 percent of the conceptual-model inflows to the eastern part of the Red River alluvial aquifer. Saturated-zone evapotranspiration accounts for 11.9 percent and net streambed seepage accounts for 87.4 percent of the outflows in the conceptual model.

Arkansas, Oklahoma, Texas↗

Long-term trends of selected pesticides in the Little Arkansas River, south-central Kansas, 1995–2023

The eastern part of the High Plains Aquifer, herein called the Equus beds aquifer, is currently a primary source of water (2026) for the city of Wichita, Kansas. The Equus Beds Aquifer Storage and Recovery Project was developed in the early 1990s to meet future water demands by using the Little Arkansas River as an artificial aquifer recharge water source during above-base-flow conditions in the river. Little Arkansas River water is diverted at an intake structure, treated following National Primary Drinking Water Regulations as a guideline, and delivered to the aquifer through recharge basins or injection wells for later use. The U.S. Geological Survey, in cooperation with the city of Wichita, completed the study described in this report to quantify and characterize Little Arkansas River water-quality data. Data in this report can be used to evaluate changing conditions in aquifer recharge source water, provide science-based information for decision making, and help meet regulatory monitoring requirements. Continuous streamflow, specific conductance, turbidity, and discrete atrazine data were collected from two Little Arkansas River study sites and discrete glyphosate and aminomethylphosphonic acid was collected from one of the two Little Arkansas River study sites from 1995 to 2023 to evaluate water-quality conditions and assess pesticide trends. Pesticide trends in the herbicides atrazine and glyphosate and the herbicide-associated compound aminomethylphosphonic acid (a glyphosate degradate) were evaluated using the R package seawaveQ. Pesticides modeled with the seawaveQ R package had increasing and decreasing trends during the study period, depending on the individual pesticide and if there were strong seasonal patterns; larger estimated concentrations occurring in late spring and early summer. Modeled atrazine concentrations exceeded the Federal maximum contaminant level of 3 micrograms per liter about 8 percent of the time at both study sites. Atrazine had a nonsignificant increasing trend (98 percent) at the Highway 50 site and a nonsignificant decreasing trend (31 percent) at the downstream Sedgwick site during the study period. Glyphosate and aminomethylphosphonic acid trends were not evident at the Sedgwick site during the study period.

Kansas↗

Seepage investigation of the Rio Grande from below Leasburg Dam, Leasburg, New Mexico, to above American Dam, El Paso, Texas, 2015

Seepage investigations have been conducted annually by the U.S. Geological Survey from 1988 to 1998 and from 2004 to the present (2015) along a 64-mile reach of the Rio Grande from below Leasburg Dam, Leasburg, New Mexico, to above American Dam, El Paso, Texas, as part of the Mesilla Basin monitoring program. Results of the investigation conducted in 2015 are presented in this report. The 2015 seepage investigation was conducted on February 10, 2015, during the low-flow conditions of the non-irrigation season. During the 2015 investigation, discharge was measured at 23 sites along the main-stem Rio Grande and 19 inflow sites within the study reach. Because of extended drought conditions affecting the basin, many sites along the Rio Grande (17 main-stem and 10 inflow) were observed to be dry in February 2015. Net seepage gain or loss was computed for each subreach (the interval between two adjacent measurement locations along the river) by subtracting the discharge measured at the upstream location from the discharge measured at the closest downstream location along the river and then subtracting any inflow to the river within the subreach. An estimated gain or loss was determined to be meaningful when it exceeded the cumulative measurement uncertainty associated with the net seepage computation. The cumulative seepage loss in the 64-mile study reach in 2015 was 17.3 plus or minus 2.6 cubic feet per second. Gaining and losing reaches identified in this investigation generally correspond to seepage patterns observed in previous investigations conducted during dry years, with the gaining reaches occurring primarily at the southern (downstream) end of the basin.

Rio Grande↗

Coeur d'Alene Lake, Idaho: Insights gained From limnological studies of 1991-92 and 2004-06

More than 100 years of mining and processing of metal-rich ores in northern Idaho’s Coeur d’Alene River basin have resulted in widespread metal contamination of the basin’s soil, sediment, water, and biota, including Coeur d’Alene Lake. Previous studies reported that about 85 percent of the bottom of Coeur d’Alene Lake is substantially enriched in antimony, arsenic, cadmium, copper, lead, mercury, silver, and zinc. Nutrients in the lake also are a major concern because they can change the lake’s trophic status—or level of biological productivity—which could result in secondary releases of metals from contaminated lakebed sediments. This report presents insights into the limnological functioning of Coeur d’Alene Lake based on information gathered during two large-scale limnological studies conducted during calendar years 1991–92 and water years 2004–06. Both limnological studies reported that longitudinal gradients exist from north to south for decreasing water column transparency, loss of dissolved oxygen, and increasing total phosphorus concentrations. Gradients also exist for total lead, total zinc, and hypolimnetic dissolved oxygen concentrations, ranging from high concentrations in the central part of the lake to lower concentrations at the northern and southern ends of the lake. In the southern end of the lake, seasonal anoxia serves as a mechanism to release dissolved constituents such as phosphorus, nitrogen, iron, and manganese from lakebed sediments and from detrital material within the water column. Nonparametric statistical hypothesis tests at a significance level of α=0.05 were used to compare analyte concentrations among stations, between lake zones, and between study periods. The highest dissolved oxygen concentrations were measured in winter in association with minimum water temperatures, and the lowest concentrations were measured in the Coeur d’Alene Lake hypolimnion during late summer or autumn as prolonged thermal stratification restricted mixing of the oxygenated upper water column and the hypolimnion, where oxygen was consumed. Large differences in median concentrations of dissolved inorganic nitrogen were measured between the euphotic zone and hypolimnion in the deep areas of the lake. These differences in nitrogen concentrations were attributable to several limnological processes, including seasonal inflow plume routing, isolation from wind-driven circulation and associated hypolimnetic enrichment, phytoplanktonic assimilation during summer months, and benthic flux. Increased chlorophyll- a and total phosphorus concentrations were measured throughout the lake in the 2004–06 study compared with results from the 1991–92 study. No significant change in hypolimnetic dissolved inorganic nitrogen concentration throughout the lake was noted even though total nitrogen loads into the lake decreased between study periods. Total zinc and total lead decreased throughout the lake from the 1991-92 study to the 2004-06 study except in the southern part of the lake, where concentrations were typically low. Median detected nitrogen-to-phosphorus ratios decreased from the 1991–92 study to the 2004–06 study. Whereas the lake was clearly phosphorus-limited in 1991–92, in 2004–06 the lake may have been much closer to the boundary value of 7.2 that separates nitrogen from phosphorus limitation. However, due to changes in analytical reporting limits in the period between the two studies, the data are insufficiently certain to draw reliable conclusions with regard to limiting nutrients. For both studies, the trophic state of the lake was classified as oligotrophic (less productive) or mesotrophic (moderately productive), depending on the constituent used for classification. Internal circulation from wind-generated waves and changes in the lake’s thermocline are important processes for distribution of water-quality constituents throughout Coeur d’Alene Lake. Surficial distribution of trace metals throughout most of the lake, including bays, is relatively uniform. Even south of the Coeur d’Alene River mouth, lakebed sediments are contaminated with trace metals. Inflow plume routing of the two primary inflow sources, the Coeur d’Alene and St. Joe Rivers, also significantly affects the fate and transport of contaminants. Most riverine inflows appear to move through the lake as overflow during summer, interflow during spring and autumn, and underflow during winter. Benthic flux is another key transport process for contaminants in Coeur d’Alene Lake. The results of in situ benthic flux chamber experiments indicated movement of dissolved metals, nutrients, and dissolved organic carbon out of the lakebed sediments. However, the lake is an overall sink for these constituents when they are associated with particulate material.

Idaho↗

Constituent concentrations, loads, and yields to Beaver Lake, Arkansas, water years 1999-2008

Beaver Lake is a large, deep-storage reservoir used as a drinking-water supply and considered a primary watershed of concern in the State of Arkansas. As such, information is needed to assess water quality, especially nutrient enrichment, nutrient-algal relations, turbidity, and sediment issues within the reservoir system. Water-quality samples were collected at three main inflows to Beaver Lake: the White River near Fayetteville, Richland Creek at Goshen, and War Eagle Creek near Hindsville. Water-quality samples collected over the period represented different flow conditions (from low to high). Constituent concentrations, flow-weighted concentrations, loads, and yields from White River, Richland Creek, and War Eagle Creek to Beaver Lake for water years 1999-2008 were documented for this report. Constituents include total ammonia plus organic nitrogen, dissolved nitrite plus nitrate nitrogen, dissolved orthophosphorus (soluble reactive phosphorus), total phosphorus, total nitrogen, dissolved organic carbon, total organic carbon, and suspended sediment. Linear regression models developed by computer program S-LOADEST were used to estimate loads for each constituent for the 10-year period at each station. Constituent yields and flow-weighted concentrations for each of the three stations were calculated for the study. Constituent concentrations and loads and yields varied with time and varied among the three tributaries contributing to Beaver Lake. These differences can result from differences in precipitation, land use, contributions of nutrients from point sources, and variations in basin size. Load and yield estimates varied yearly during the study period, water years 1999-2008, with the least nutrient and sediment load and yields generally occurring in water year 2006, and the greatest occurring in water year 2008, during a year with record amounts of precipitation. Flow-weighted concentrations of most constituents were greatest at War Eagle Creek near Hindsville than White River near Fayetteville and Richland Creek at Goshen. Loads and yields of most constituents were greater at the War Eagle Creek and White River stations than at the Richland Creek Station.

Scientific Investigations Report↗

Groundwater and surface-water interaction and potential for underground water storage in the Buena Vista-Salida Basin, Chaffee County, Colorado, 2011

By 2030, the population of the Arkansas Headwaters Region, which includes all of Chaffee and Lake Counties and parts of Custer, Fremont, and Park Counties, Colorado, is forecast to increase about 73 percent. As the region’s population increases, it is anticipated that groundwater will be used to meet much of the increased demand. In September 2009, the U.S. Geological Survey, in cooperation with the Upper Arkansas Water Conservancy District and with support from the Colorado Water Conservation Board; Chaffee, Custer, and Fremont Counties; Buena Vista, Cañon City, Poncha Springs, and Salida; and Round Mountain Water and Sanitation District, began a 3-year study of groundwater and surface-water conditions in the Buena Vista-Salida Basin. This report presents results from the study of the Buena Vista-Salida Basin including synoptic gain-loss measurements and water budgets of Cottonwood, Chalk, and Browns Creeks, changes in groundwater storage, estimates of specific yield, transmissivity and hydraulic conductivity from aquifer tests and slug tests, an evaluation of areas with potential for underground water storage, and estimates of stream-accretion response-time factors for hypothetical recharge and selected streams in the basin. The four synoptic measurements of flow of Cottonwood, Chalk, and Browns Creeks, suggest quantifiable groundwater gains and losses in selected segments in all three perennial streams. The synoptic measurements of flow of Cottonwood and Browns Creeks suggest a seasonal variability, where positive later-irrigation season values in these creeks suggest groundwater discharge, possibly as infiltrated irrigation water. The overall sum of gains and losses on Chalk Creek does not indicate a seasonal variability but indicates a gaining stream in April and August/September. Gains and losses in the measured upper segments of Chalk Creek likely are affected by the Chalk Cliffs Rearing Unit (fish hatchery). Monthly water budgets were estimated for selected segments of five perennial streams (Cottonwood, North Cottonwood, Chalk, and Browns Creeks, and South Arkansas River) in the Buena Vista-Salida Basin for calendar year 2011. Differences between reported diversions and estimated crop irrigation requirements were used to estimate groundwater recharge in the areas irrigated by water supplied from the diversions. The amount of groundwater recharge in all the basins varied monthly; however, the greatest amount of recharge was during June and July for Cottonwood, North Cottonwood, and Chalk Creeks and South Arkansas River. The greatest amount of recharge in 2011 in Browns Creek occurred in July and August. The large seasonal fluctuations of groundwater near irrigated areas in the Buena Vista-Salida Basin indicate that the increased groundwater storage resulting from infiltration of surface-water diversions has dissipated by the following spring. Areas within the Buena Vista-Salida Basin with the potential for underground storage were identified using geographic information system data, including topographic, geologic, and hydrologic data, excluding the mountainous areas that border the Buena Vista-Salida Basin and igneous and metamorphic rock outcrop areas. The areas that met the selection criteria for underground water storage are located on terrace deposits near the Arkansas River and adjacent to its major tributaries. The selected areas also contain much of the irrigated land within the basin; consequently, irrigation ditches and canals could provide a means of conveying water to potential recharge sites.

Colorado↗

The discovery and character of Pleistocene calcrete uranium deposits in the Southern High Plains of west Texas, United States

This report describes the discovery and geology of two near-surface uranium deposits within calcareous lacustrine strata of Pleistocene age in west Texas, United States. Calcrete uranium deposits have not been previously reported in the United States. The west Texas uranium deposits share characteristics with some calcrete uranium deposits in Western Australia—uranium-vanadium minerals hosted by nonpedogenic calcretes deposited in saline lacustrine environments. In the mid-1970s, Kerr-McGee Corporation conducted a regional uranium exploration program in the Southern High Plains province of the United States, which led to the discovery of two shallow uranium deposits (that were not publicly reported). With extensive drilling, Kerr-McGee delineated one deposit of about 2.1 million metric tons of ore with an average grade of 0.037 percent U 3 O 8 and another deposit of about 0.93 million metric tons of ore averaging 0.047 percent U 3 O 8 . The west-Texas calcrete uranium-vanadium deposits occur in calcareous, fine-grained sediments interpreted to be deposited in saline lakes formed during dry interglacial periods of the Pleistocene. The lakes were associated with drainages upstream of a large Pleistocene lake. Age determinations of tephra in strata adjacent to one deposit indicate the host strata is middle Pleistocene in age. Examination of the uranium-vanadium mineralization by scanning-electron microscopy indicated at least two generations of uranium-vanadium deposition in the lacustrine strata identified as carnotite and a strontium-uranium-vanadium mineral. Preliminary uranium-series results indicate a two-component system in the host calcrete, with early lacustrine carbonate that was deposited (or recrystallized) about 190 kilo-annum, followed much later by carnotite-rich crusts and strontium-uranium-vanadium mineralization in the Holocene (about 5 kilo-annum). Differences in initial 234 U/ 238 U activity ratios indicate two separate, distinct fluid sources.

Texas↗

Mapping the altitude of the top of the Dockum Group and paleochannel analysis using surface geophysical methods on and near Cannon Air Force Base in Curry County, New Mexico, 2020

The hydrogeology on and near Cannon Air Force Base (AFB) in eastern New Mexico was assessed to gain a better understanding of preferential groundwater flow paths through paleochannels. In and near the study area, paleochannels incised the top surface of the Dockum Group (Chinle Formation) and were subsequently filled in with electrically resistive coarse-grained sediments of the overlying Ogallala Formation, resulting in a preferential groundwater flow path in the form of a paleochannel network. A better understanding of the spatial characteristics of this preferential groundwater flow path is needed to support ongoing efforts to remediate groundwater contamination at Cannon AFB. Therefore, the U.S. Geological Survey, in cooperation with the U.S. Air Force Civil Engineer Center, used surface geophysical resistivity methods and data compiled from previous studies to better understand the spatial distribution and characteristics of the paleochannel network incised into the top of the Dockum Group. Previous studies have shown these paleochannels incised into the top of the Dockum Group with increasing resolution, but limited borehole data on and near Cannon AFB continued to make accurately mapping the top of Dockum Group challenging. For this study, surface geophysical resistivity measurements in the form of time-domain electromagnetic soundings made by the U.S. Geological Survey were used in conjunction with data previously published by Architecture, Engineering, Construction, Operations, and Management and borehole data compiled from the New Mexico Water Rights Reporting System database to prepare an updated map of the top of the Dockum Group that includes the location and characteristics of paleochannels incised into the top of the Dockum Group (Chinle Formation). A total of 149 borehole picks (determinations of the tops and bases of geologic units and their hydrogeologic-unit equivalents) were obtained from previous studies, along with 72 additional borehole picks from the New Mexico Water Rights Reporting System database and 43 picks from newly collected time-domain electromagnetic soundings. The data were gridded and contoured using Oasis Montaj v. 9.8.1. The updated map of the top of Dockum Group has many areas of uncertainty greater than 20 feet, because there are not enough data for the gridding process to reliably determine a value. However, this interpretation of the altitude of the top of the Dockum Group represents a substantial improvement in data resolution compared to previous studies. Two methodologies were used to evaluate paleochannels incised in the top of the Dockum Group across the study area: (1) trend-removal grid analysis and (2) analysis with Esri’s ArcMap Hydrology toolset. These two paleochannel analysis techniques show groundwater flow direction as well as areas having the deepest saturated thickness. Hydrologically, these techniques show where aquifer storage is highest (in the deepest parts of the paleochannel network), as well as the spatial distribution of preferential groundwater flow paths (the paleochannels). The analyses indicate a large paleochannel trending to the southeast, with smaller channels feeding in from the west. Areas where groundwater management could be more beneficial are indicated by locations where these flow lines intersect the deeper parts of the paleochannel.

New Mexico↗

Factors Affecting Water Quality in Domestic Wells in the Upper Floridan Aquifer, Southeastern United States, 1998-2005

The Floridan aquifer system is a highly productive carbonate aquifer that provides drinking water to about 10 million people in Florida, Georgia, and South Carolina. Approximately 1.6 million people rely on domestic wells (privately owned household wells) for drinking water. Withdrawals of water from the Floridan aquifer system have increased by more than 500 percent from 630 million gallons per day (2.38 cubic meters per day) in 1950 to 4,020 million gallons per day (15.2 cubic meters per day) in 2000, largely due to increases in population, tourism, and agriculture production. Water samples were collected from 148 domestic wells in the Upper Floridan aquifer in Florida, Georgia, South Carolina, and Alabama during 1998-2005 as part of the U.S. Geological Survey (USGS) National Water-Quality Assessment Program. The wells were located in different hydrogeologic settings based on confinement of the Upper Floridan aquifer. Five networks of wells were sampled con-sisting of 28 to 30 wells each: two networks were in unconfined areas, two networks were in semiconfined areas, and one network was in the confined area. Physical properties and concentrations of major ions, trace elements, nutrients, radon, and organic compounds (volatile organic compounds and pesticides) were measured in water samples. Concentrations were compared to water-quality benchmarks for human health, either U.S. Environmental Protection Agency (USEPA) Maximum Contaminant Levels (MCLs) for public water supplies or USGS Health-Based Screening Levels (HBSLs). The MCL for fluoride of 4 milligrams per liter (mg/L) was exceeded for two samples (about 1 percent of samples). A proposed MCL for radon of 300 picocuries per liter was exceeded in about 40 percent of samples. Nitrate concentrations in the Upper Floridan aquifer ranged from less than the laboratory reporting level of 0.06 to 8 mg/L, with a median nitrate concentration less than 0.06 mg/L (as nitrogen). Nitrate concentrations did not exceed the MCL of 10 mg/L. Statistical comparisons indicated that median nitrate concentrations were significantly different by degree of confinement where the highest median nitrate concentration was 1.46 mg/L for 58 samples from unconfined areas, and by network, where the highest median nitrate concentration was 2.43 mg/L in 28 samples from unconfined areas in southwestern Georgia. Nitrate concentrations in unconfined areas were positively correlated to: (1) the percentage of agricultural land use around the well, (2) the amount of nitrogen fertilizer applied, and (3) the dissolved oxygen concentrations in groundwater. Volatile organic compounds (VOCs) were detected in about 63 percent of all samples. Chloroform, carbon disulfide, and 1,2-dichloropropane were the most frequently detected VOCs. Chloroform, a byproduct of water chlorination, was most frequently detected in unconfined urban areas. Carbon disulfide, a solvent, was most frequently detected in confined areas in southeastern Georgia. Pesticides were detected in about 21 percent of all samples, but were detected in about 69 percent of the 28 samples from unconfined areas in southwestern Georgia. The herbicides atrazine, deethylatrazine, and metolachlor were the most frequently detected pesticides.

Scientific Investigations Report↗

A conceptual site model of contaminant transport pathways from the Bremerton Naval Complex to Sinclair Inlet, Washington, 2011–21

Historical activities on the Bremerton Naval Complex (BNC) in Puget Sound, Washington, have resulted in Sinclair Inlet sediments with elevated concentrations of contaminants, including organic contaminants such as polychlorinated biphenyls and trace elements including mercury. Six U.S. Geological Survey–U.S. Navy datasets have been collected since the last major assessment, in 2013, of soil and groundwater contaminant transport pathways and mercury loading estimates from the BNC to Sinclair Inlet. These include: mercury isotope analysis to support sourcing of mercury in Sinclair Inlet; mercury sampling within the dry dock systems; nearshore thermal surveys to identify potential groundwater discharge locations to Sinclair Inlet; time-series monitoring in nearshore wells to understand the inland extent and dynamics of the tidal mixing zone; tidal studies of mercury in nearshore monitoring wells in an area of contaminated fill material called Site 1; and a spatial survey of trace elements and other parameters in nearshore monitoring wells, pore water, seeps, surface water, and sediment along unwalled shorelines in the western part of the BNC. The results were incorporated into an updated Conceptual Site Model and used to update contaminant load estimates from the terrestrial BNC to Sinclair Inlet. The results from these studies provide data to the U.S. Navy to support prioritization of on-going remediation actions to manage contamination on the BNC that reduce potential impacts to Sinclair Inlet sediment, surface water, and fish and shellfish tissue. Mercury isotope analysis of surface sediments and particulate material indicated that a similar industrial mercury profile is present throughout Puget Sound, including terrestrial and marine BNC samples and in other Sinclair Inlet sediments and persists across regions with low and elevated mercury concentrations. Two sources of mercury at the BNC are Sites 1 and 2 subsurface soils/fill material, with total mercury concentrations in particulates collected from the bottom of monitoring wells drilled in these materials ranging from 18,000 to 44,000 nanograms per gram (as compared to the Washington State Marine Sediment Cleanup Screening Level of 590 nanograms per gram). Contaminants are transported from the terrestrial BNC to Sinclair Inlet via three primary pathways, (1) stormwater outfalls, (2) dry dock discharges, and (3) direct discharge along unwalled shorelines. Previous loading estimates (based on filtered total mercury) ranked stormwater outfalls, particularly outfall PSNS015 in Site 2 soils, as the largest soil and groundwater contaminant transport pathway from the terrestrial BNC to Sinclair Inlet. Updated loading estimates in this report suggest that the dry dock systems may be a larger pathway of mercury from the terrestrial BNC to Sinclair Inlet than previously thought, within the same order of magnitude as the PSNS015 storm-drain system. Trace-element loads via direct shoreline discharge are difficult to estimate due to the large and dynamic tidal mixing zone of groundwater and seawater in the nearshore along unwalled shorelines. However, current best estimated ranges suggest that direct shoreline discharge is one of the three main pathways and may contribute smaller mercury loads than the stormwater and the dry dock systems. Along unwalled shorelines, direct groundwater discharge of terrestrial contaminants may be less important than recirculating seawater in the nearshore mixing zone that can extract contaminants from nearshore subsurface material. Total estimated mercury loads from the terrestrial BNC to Sinclair Inlet range from approximately 40 to 200 grams of filtered total mercury per year and a minimum of 70–350 grams of particulate total mercury per year, for a minimum total of 110–525 grams of whole (filtered plus particulate) total mercury per year. Data gaps are identified that, if filled, would further refine the Conceptual Site Model and contaminant loading estimates from the terrestrial BNC to Sinclair Inlet.

Washington↗

Water-quality characteristics of Montana streams in a statewide monitoring network, 1999-2003

A statewide monitoring network of 38 sites was operated during 1999-2003 in cooperation with the Montana Department of Environmental Quality to provide a broad geographic base of water-quality information on Montana streams. The purpose of this report is to summarize and describe the water-quality characteristics for those sites. Samples were collected at U.S. Geological Survey streamflow-gaging stations in the Missouri, Yellowstone, and Columbia River basins for stream properties, nutrients, suspended sediment, major ions, and selected trace elements. Mean annual streamflows were below normal during the period, which likely influenced water quality. Continuous water-temperature monitors were operated at 26 sites. The median of daily mean water temperatures for the June-August summer period ranged from 12.5 degC at Kootenai River below Libby Dam to 23.0 degC at Poplar River near Poplar and Tongue River at Miles City. In general, sites in the Missouri River basin commonly had the highest water temperatures. Median daily mean summer water temperatures at four sites (Jefferson River near Three Forks, Missouri River at Toston, Judith River near Winifred, and Poplar River near Poplar) classified as supporting or marginally supporting cold-water biota exceeded the general guideline of 19.4 degC for cold-water biota. Median daily mean temperatures at sites in the network classified as supporting warm-water biota did not exceed the guideline of 26.7 degC for warm-water biota, although several sites exceeded the warm-water guideline on several days during the summer. More...

Scientific Investigations Report↗