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An update of hydrologic conditions and distribution of selected constituents in water, Snake River Plain aquifer and perched groundwater zones, Idaho National Laboratory, Idaho, emphasis 2006-08

Since 1952, radiochemical and chemical wastewater discharged to infiltration ponds (also called percolation ponds), evaporation ponds, and disposal wells at the Idaho National Laboratory (INL) has affected water quality in the eastern Snake River Plain aquifer and perched groundwater zones underlying the INL. The U.S. Geological Survey, in cooperation with the U.S. Department of Energy, maintains groundwater monitoring networks at the INL to determine hydrologic trends, and to delineate the movement of radiochemical and chemical wastes in the aquifer and in perched groundwater zones. This report presents an analysis of water-level and water-quality data collected from aquifer and perched groundwater wells in the USGS groundwater monitoring networks during 2006-08. Water in the Snake River Plain aquifer primarily moves through fractures and interflow zones in basalt, generally flows southwestward, and eventually discharges at springs along the Snake River. The aquifer primarily is recharged from infiltration of irrigation water, infiltration of streamflow, groundwater inflow from adjoining mountain drainage basins, and infiltration of precipitation. From March-May 2005 to March-May 2008, water levels in wells generally remained constant or rose slightly in the southwestern corner of the INL. Water levels declined in the central and northern parts of the INL. The declines ranged from about 1 to 3 feet in the central part of the INL, to as much as 9 feet in the northern part of the INL. Water levels in perched groundwater wells around the Advanced Test Reactor Complex (ATRC) also declined. Detectable concentrations of radiochemical constituents in water samples from wells in the Snake River Plain aquifer at the INL generally decreased or remained constant during 2006-08. Decreases in concentrations were attributed to decreased rates of radioactive-waste disposal, radioactive decay, changes in waste-disposal methods, and dilution from recharge and underflow. In April or October 2008, reportable concentrations of tritium in groundwater ranged from 810 ? 70 to 8,570 ? 190 picocuries per liter (pCi/L), and the tritium plume extended south-southwestward in the general direction of groundwater flow. Tritium concentrations in water from wells completed in shallow perched groundwater at the ATRC were less than the reporting levels. Tritium concentrations in deep perched groundwater exceeded the reporting level in 11 wells during at least one sampling event during 2006-08 at the ATRC. Tritium concentrations from one or more zones in each well were reportable in water samples collected at various depths in six wells equipped with multi-level WestbayTM packer sampling systems. Concentrations of strontium-90 in water from 24 of 52 aquifer wells sampled during April or October 2008 exceeded the reporting level. Concentrations ranged from 2.2 ? 0.7 to 32.7 ? 1.2 pCi/L. Strontium-90 has not been detected within the eastern Snake River Plain aquifer beneath the ATRC partly because of the exclusive use of waste-disposal ponds and lined evaporation ponds rather than using the disposal well for radioactive-wastewater disposal at ATRC. At the ATRC, the strontium-90 concentration in water from one well completed in shallow perched groundwater was less than the reporting level. During at least one sampling event during 2006-08, concentrations of strontium-90 in water from nine wells completed in deep perched groundwater at the ATRC were greater than reporting levels. Concentrations ranged from 2.1?0.7 to 70.5?1.8 pCi/L. At the Idaho Nuclear Technology and Engineering Center (INTEC), the reporting level was exceeded in water from two wells completed in deep perched groundwater. During 2006-08, concentrations of cesium-137, plutonium-238, and plutonium-239, -240 (undivided), and americium-241 were less than the reporting level in water samples from all wells and all zones in wells equipped with multi-level WestbayTM packer sampling systems

Scientific Investigations Report↗

Hydrology of Eagle Creek Basin and effects of groundwater pumping on streamflow, 1969-2009

Urban and resort development and drought conditions have placed increasing demands on the surface-water and groundwater resources of the Eagle Creek Basin, in southcentral New Mexico. The Village of Ruidoso, New Mexico, obtains 60-70 percent of its water from the Eagle Creek Basin. The village drilled four production wells on Forest Service land along North Fork Eagle Creek; three of the four wells were put into service in 1988 and remain in use. Local citizens have raised questions as to the effects of North Fork well pumping on flow in Eagle Creek. In response to these concerns, the U.S. Geological Survey, in cooperation with the Village of Ruidoso, conducted a hydrologic investigation from 2007 through 2009 of the potential effect of the North Fork well field on streamflow in North Fork Eagle Creek. Mean annual precipitation for the period of record (1942-2008) at the Ruidoso climate station is 22.21 inches per year with a range from 12.27 inches in 1970 to 34.81 inches in 1965. Base-flow analysis indicates that the 1970-80 mean annual discharge, direct runoff, and base flow were 2,260, 1,440, and 819 acre-ft/yr, respectively, and for 1989-2008 were 1,290, 871, and 417 acre-ft/yr, respectively. These results indicate that mean annual discharge, direct runoff, and base flow were less during the 1989-2008 period than during the 1970-80 period. Mean annual precipitation volume for the study area was estimated to be 12,200 acre-feet. Estimated annual evapotranspiration for the study area ranged from 8,730 to 8,890 acre-feet. Estimated annual basin yield for the study area was 3,390 acre-ft or about 28 percent of precipitation. On the basis of basin-yield computations, annual recharge was estimated to be 1,950 acre-ft, about 16 percent of precipitation. Using a chloride mass-balance method, groundwater recharge over the study area was estimated to average 490 acre-ft, about 4.0 percent of precipitation. Because the North Fork wells began pumping in 1988, 1969-80 represents the pre-groundwater-pumping period, and 1988-2009 represents the groundwater-pumping period. The 5-year moving average for precipitation at the Ruidoso climate station shows years of below-average precipitation during both time periods, but no days of zero flow were recorded for the 11-year period 1970-80 and no-flow days were recorded in 11 of 20 years for the 1988-2009 period. View report for unabridged abstract.

Scientific Investigations Report↗

Geology, Hydrology, and Water Quality of the Little Blackwater River Watershed, Dorchester County, Maryland, 2006-09

The Little Blackwater River watershed is a low-lying tidal watershed in Dorchester County, Maryland. The potential exists for increased residential development in a mostly agricultural watershed that drains into the Blackwater National Wildlife Refuge. Groundwater and surface-water levels were collected along with water-quality samples to document hydrologic and geochemical conditions within the watershed prior to potential land-use changes. Lithologic logs were collected in the Little Blackwater River watershed and interpreted with existing geophysical logs to conceptualize the shallow groundwater-flow system. A shallow water table exists in much of the watershed as shown by sediment cores and surface geophysical surveys. Water-table wells have seasonal variations of 6 feet, with the lowest water levels occurring in September and October. Seasonally low water-table levels are lower than the stage of the Little Blackwater River, creating the potential for surface-water infiltration into the water table. Two stream gages, each equipped with stage, velocity, specific conductance, and temperature sensors, were installed at the approximate mid-point of the watershed and near the mouth of the Little Blackwater River. The gages recorded data continuously and also were equipped with telemetry. Discharge calculated at the mouth of the Little Blackwater River showed a seasonal pattern, with net positive discharge in the winter and spring months and net negative discharge (flow into the watershed from Blackwater National Wildlife Refuge and Fishing Bay) in the summer and fall months. Continuous water-quality records showed an increase in specific conductance during the summer and fall months. Discrete water-quality samples were collected during 2007--08 from 13 of 15 monitoring wells and during 2006--09 from 9 surface-water sites to characterize pre-development conditions and the seasonal variability of inorganic constituents and nutrients. The highest mean values of nitrogen are found in the deep groundwater system, with relatively low values in the water table. Surface-water-quality samples in the lower half of the basin show a significant increase in inorganic seawater constituents, especially in summer, corresponding with net negative discharge from the Little Blackwater River. Samples also were collected from nine wells and four surface-water sites for pesticides in June 2008. The herbicides atrazine, metolachlor, and simazine, and the insecticide fipronil were detected at each of the four surface-water sites, with concentrations less than 2 micrograms per liter. Concentrations of pesticides found in groundwater were typically one to two orders of magnitude lower than pesticide concentrations found in surface water of the Little Blackwater River. Seasonal hydraulic-gradient reversals between the shallow groundwater system and the Little Blackwater River, coincident with the inflow of brackish water from Fishing Bay and Blackwater National Wildlife Refuge, indicate a potential for saltwater intrusion into the water table. The likelihood of saltwater intrusion into the water table is further supported by high chloride concentrations observed in water-table wells near the Little Blackwater River.

Scientific Investigations Report↗

Relation of hydrologic processes to groundwater and surface-water levels and flow directions in a dune-beach complex at Indiana Dunes National Lakeshore and Beverly Shores, Indiana

The potential for high groundwater levels to cause wet basements (groundwater flooding) is of concern to residents of communities in northwestern Indiana. Changes in recharge from precipitation increases during 2006-9, water-level changes from restoration of nearby wetlands in the Great Marsh in 1998-2002, and changes in recharge due to the end of groundwater withdrawals for water supply since 2005 in a community at Beverly Shores, Ind., were suspected as factors in increased groundwater levels in an unconfined surficial aquifer beneath nearby parts of a dune-beach complex. Results of this study indicate that increased recharge from precipitation and snowmelt was the principal cause of raised water levels in the dune-beach complex from 2006 to 2009. Annual precipitation totals in 2006-9 ranged from 43.88 to 55.75 inches per year (in/yr) and were substantially greater than the median 1952-2009 precipitation of 36.35 in/yr. Recharge to groundwater from precipitation in 2006-9 ranged from 13.5 to 22 in/yr; it was higher than the typical 11 in/yr because of large precipitation events and precipitation amounts received during non-growing-season months. An estimated increase in net recharge from reduced groundwater use in Beverly Shores since 2005 ranged from 1.6 in/yr in 2006 to 1.9 in/yr in 2009. Surface-water levels in the wetland were as much as about 1.1 feet higher in 2007-9 (after the 1998-2002 wetland restoration) than during seasonally wet periods in 1979-89. Similar surface-water levels and ponded water were likely during winter and spring wet periods before and after wetland restoration. High water levels similar to those in 2009 were measured elsewhere in the dune-beach complex near a natural wetland during the spring months in 1991 and 1993 after receipt of near record precipitation. Recharge from similarly high precipitation amounts in 2008-9 was also a likely cause of high groundwater levels in other parts of the dune-beach complex, such as at Beverly Shores. Perennial mounding of the water table in the surficial aquifer indicates that the recharge that created the water-table mound originates within the dune-beach complex and not through flow from the adjacent hydrologic boundaries: the restored wetland, Lake Michigan, and Derby Ditch. Infiltrating precipitation causes most seasonal and episodic rises in groundwater levels beneath the dune-beach complex. Groundwater-level fluctuations lasting days to weeks in the dune-beach complex in 2008-9 were superimposed on a seasonal high water-table altitude that began with the recharge from snowmelt and rain in February 2009 and maintained through July 2009. Increases in water-table-mound altitude under the dune-beach complex recurred in 2008-9 in response to the largest rain events of 1 inch or more and to snowmelt. Smaller, shorter-term rises in water level after individual rain events persisted over hours to less than 1 week. Groundwater-level fluctuations varied over a relatively narrow range of about 2 to 3 feet, with no net fluctuations greater than 4 feet. Groundwater levels in or near low parts of the dune-beach complex were frequently within 0 to 6 feet of the land surface and indicate the potential for groundwater flooding. Groundwater-level gradients from the water-table mound to wells next to surface-water discharges increase after rainfall and snowmelt events and recede slowly as groundwater discharges from the aquifer. Evapotranspiration is responsible for part of the general pattern of decreasing water-table altitudes observed from May to August 2009. Rapid water-level rises in the restored wetland after precipitation do not likely have an effect on groundwater flooding elsewhere in the dune-beach complex. Surface-water-level fluctuations during this study generally varied over a narrower range, approximately from 1 to 1.5 feet, as compared with groundwater fluctuations, except after a very large, 10.77-inch rainfall. Time-delayed and smaller groundwater-level

Indiana↗

Hydrogeologic framework and hydrologic budget components of the Columbia Plateau Regional Aquifer System, Washington, Oregon, and Idaho

The Columbia Plateau Regional Aquifer System (CPRAS) covers an area of about 44,000 square miles in a structural and topographic basin within the drainage of the Columbia River in Washington, Oregon, and Idaho. The primary aquifers are basalts of the Columbia River Basalt Group (CRBG) and overlying sediment. Eighty percent of the groundwater use in the study area is for irrigation, in support of a $6 billion per year agricultural economy. Water-resources issues in the Columbia Plateau include competing agricultural, domestic, and environmental demands. Groundwater levels were measured in 470 wells in 1984 and 2009; water levels declined in 83 percent of the wells, and declines greater than 25 feet were measured in 29 percent of the wells. Conceptually, the system is a series of productive basalt aquifers consisting of permeable interflow zones separated by less permeable flow interiors; in places, sedimentary aquifers overly the basalts. The aquifer system of the CPRAS includes seven hydrogeologic units-the overburden aquifer, three aquifer units in the permeable basalt rock, two confining units, and a basement confining unit. The overburden aquifer includes alluvial and colluvial valley-fill deposits; the three basalt units are the Saddle Mountains, Wanapum, and Grande Ronde Basalts and their intercalated sediments. The confining units are equivalent to the Saddle Mountains-Wanapum and Wanapum-Grande Ronde interbeds, referred to in this study as the Mabton and Vantage Interbeds, respectively. The basement confining unit, referred to as Older Bedrock, consists of pre-CRBG rocks that generally have much lower permeabilities than the basalts and are considered the base of the regional flow system. Based on specific-capacity data, median horizontal hydraulic conductivity (Kh) values for the overburden, basalt units, and bedrock are 161, 70, and 6 feet per day, respectively. Analysis of oxygen isotopes in water and carbon isotopes in dissolved inorganic carbon from groundwater samples indicates that groundwater in the CPRAS ranges in age from modern (<50 years) to Pleistocene (>10,000 years). The oldest groundwater resides in deep, downgradient locations indicating that groundwater movement and replenishment in parts of this regional aquifer system have operated on long timescales under past natural conditions, which is consistent with the length and depth of long flow paths in the system. The mean annual recharge from infiltration of precipitation for the 23-year period 1985-2007 was estimated to be 4.6 inches per year (14,980 cubic feet per second) using a polynomial regression equation based on annual precipitation and the results of recharge modeling done in the 1980s. A regional-scale hydrologic budget was developed using a monthly SOil WATer (SOWAT) Balance model to estimate irrigation-water demand, groundwater flux (recharge or discharge), direct runoff, and soil moisture within irrigated areas. Mean monthly irrigation throughout the study area peaks in July at 1.6 million acre-feet (MAF), of which 0.45 and 1.15 MAF are from groundwater and surface-water sources, respectively. Annual irrigation water use in the study area averaged 5.3 MAF during the period 1985-2007, with 1.4 MAF (or 26 percent) supplied from groundwater and 3.9 MAF supplied from surface water. Mean annual recharge from irrigation return flow in the study area was 4.2 MAF (1985-2007) with 2.1 MAF (50 percent) occurring within the predominately surface-water irrigated regions of the study area. Annual groundwater-use estimates were made for public supply, self-supplied domestic, industrial, and other uses for the period 1984 through 2009. Public supply groundwater use within the study area increased from 200,600 acre-feet per year (acre-ft/yr) in 1984 to 269,100 acre-ft/yr in 2009. Domestic self-supplied groundwater use increased from 54,580 acre-ft/yr in 1984 to 71,160 acre-ft/yr in 2009. Industrial groundwater use decreased from 53,390 acre-ft/yr in 1984 t

Scientific Investigations Report↗

Using observed postconstruction peak discharges to evaluate a hydrologic and hydraulic design model, Boneyard Creek, Champaign and Urbana, Illinois

Boneyard Creek&mdash;which drains an urbanized watershed in the cities of Champaign and Urbana, Illinois, including part of the University of Illinois at Urbana-Champaign (UIUC) campus&mdash;has historically been prone to flooding. Using the Stormwater Management Model (SWMM), a hydrologic and hydraulic model of Boneyard Creek was developed for the design of the projects making up the first phase of a long-term plan for flood control on Boneyard Creek, and the construction of the projects was completed in May 2003. The U.S. Geological Survey, in cooperation with the Cities of Champaign and Urbana and UIUC, installed and operated stream and rain gages in order to obtain data for evaluation of the design-model simulations. In this study, design-model simulations were evaluated by using observed postconstruction precipitation and peak-discharge data. Between May 2003 and September 2008, five high-flow events on Boneyard Creek satisfied the study criterion. The five events were simulated with the design model by using observed precipitation. The simulations were run with two different values of the parameter controlling the soil moisture at the beginning of the storms and two different ways of spatially distributing the precipitation, making a total of four simulation scenarios. The simulated and observed peak discharges and stages were compared at gaged locations along the Creek. The discharge at one of these locations was deemed to be critical for evaluating the design model. The uncertainty of the measured peak discharge was also estimated at the critical location with a method based on linear regression of the stage and discharge relation, an estimate of the uncertainty of the acoustic Doppler velocity meter measurements, and the uncertainty of the stage measurements. For four of the five events, the simulated peak discharges lie within the 95-percent confidence interval of the observed peak discharges at the critical location; the fifth was just outside the upper end of this interval. For two of the four simulation scenarios, the simulation results for one event at the critical location were numerically unstable in the vicinity of the discharge peak. For the remaining scenarios, the simulated peak discharges over the five events at the critical location differ from the observed peak discharges (simulated minus observed) by an average of 7.7 and -1.5 percent, respectively. The simulated peak discharges over the four events for which all scenarios have numerically stable results at the critical location differs from the observed peak discharges (simulated minus observed) by an average of -6.8, 4.0, -5.4, and 1.5 percent, for the four scenarios, respectively. Overall, the discharge peaks simulated for this study at the critical location are approximately balanced between overprediction and underprediction and do not indicate significant model bias or inaccuracy. Additional comparisons were made by using peak stages at the critical location and two additional sites and using peak discharges at one additional site. These comparisons showed the same pattern of differences between observed and simulated values across events but varying biases depending on streamgage and measurement type (discharge or stage). Altogether, the results from this study show no clear evidence that the design model is significantly inaccurate or biased and, therefore, no clear evidence that the modeled flood-control projects in Champaign and on the University of Illinois campus have increased flood stages or discharges downstream in Urbana.

Illinois↗

Quantifying components of the hydrologic cycle in Virginia using chemical hydrograph separation and multiple regression analysis

This study by the U.S. Geological Survey, prepared in cooperation with the Virginia Department of Environmental Quality, quantifies the components of the hydrologic cycle across the Commonwealth of Virginia. Long-term, mean fluxes were calculated for precipitation, surface runoff, infiltration, total evapotranspiration (ET), riparian ET, recharge, base flow (or groundwater discharge) and net total outflow. Fluxes of these components were first estimated on a number of real-time-gaged watersheds across Virginia. Specific conductance was used to distinguish and separate surface runoff from base flow. Specific-conductance data were collected every 15 minutes at 75 real-time gages for approximately 18 months between March 2007 and August 2008. Precipitation was estimated for 1971&ndash;2000 using PRISM climate data. Precipitation and temperature from the PRISM data were used to develop a regression-based relation to estimate total ET. The proportion of watershed precipitation that becomes surface runoff was related to physiographic province and rock type in a runoff regression equation. Component flux estimates from the watersheds were transferred to flux estimates for counties and independent cities using the ET and runoff regression equations. Only 48 of the 75 watersheds yielded sufficient data, and data from these 48 were used in the final runoff regression equation. The base-flow proportion for the 48 watersheds averaged 72 percent using specific conductance, a value that was substantially higher than the 61 percent average calculated using a graphical-separation technique (the USGS program PART). Final results for the study are presented as component flux estimates for all counties and independent cities in Virginia.

Virginia↗

Hydrologic conditions, groundwater quality, and analysis of sink hole formation in the Albany area of Dougherty County, Georgia, 2009

The U.S. Geological Survey, in cooperation with the Albany Water, Gas, and Light Commission has conducted water resources investigations and monitored groundwater conditions and availability in the Albany, Georgia, area since 1977. This report presents an overview of hydrologic conditions, water quality, and groundwater studies in the Albany area of Dougherty County, Georgia, during 2009. Historical data also are presented for comparison with 2009 data. During 2009, groundwater-level data were collected in 29 wells in the Albany area to monitor water-level trends in the surficial, Upper Floridan, Claiborne, Clayton, and Providence aquifers. Groundwater-level data from 21 of the 29 wells indicated an increasing trend during 2008&ndash;09. Five wells show no trend due to lack of data and three wells have decreasing trends. Period-of-record water levels (period of record ranged between 1957&ndash;2009 and 2003&ndash;2009) declined slightly in 10 wells and increased slightly in 4 wells tapping the Upper Floridan aquifer; declined in 1 well and increased in 2 wells tapping the Claiborne aquifer; declined in 4 wells and increased in 2 wells tapping the Clayton aquifer; and increased in 1 well tapping the Providence aquifer. Analyses of groundwater samples collected during 2009 from 12 wells in the Upper Floridan aquifer in the vicinity of a well field located southwest of Albany indicate that overall concentrations of nitrate plus nitrite as nitrogen increased slightly from 2008 in 8 wells. A maximum concentration of 12.9 milligrams per liter was found in a groundwater sample from a well located upgradient from the well field. The distinct difference in chemical constituents of water samples collected from the Flint River and samples collected from wells located in the well-field area southwest of Albany indicates that little water exchange occurs between the Upper Floridan aquifer and Flint River where the river flows adjacent to, but downgradient of, the well field. Water-quality data collected during 2008 from two municipal wells located in northern Albany and downgradient from a hazardous waste site indicate low-level concentrations of pesticides in one of the wells; however, no pesticides were detected in samples collected during 2009. Detailed geologic cross sections were used to create a three-dimensional, hydrogeologic diagram of the well field southwest of Albany in order to examine the occurrence of subsurface features conducive to sinkhole formation. Monitored groundwater-level data were used to assess the possible relations between sinkhole formation, precipitation, and water levels in the Upper Floridan aquifer. Although the water levels in well 12L382 oscillated above and below the top of the aquifer on a regular basis between 2007 and 2009, sinkhole development did not appear to correlate directly with either well-field pumping or water levels in the Upper Floridan aquifer. Specifically, two sinkholes formed in each of the years 2003 and 2005 when water levels were almost 20 feet above the top of the aquifer during most of the year. Water-level and sinkhole-formation data continue to be collected to allow further study and analysis.

Georgia↗

Relations between precipitation, groundwater withdrawals, and changes in hydrologic conditions at selected monitoring sites in Volusia County, Florida, 1995--2010

A study to examine the influences of climatic and anthropogenic stressors on groundwater levels, lake stages, and surface-water discharge at selected sites in northern Volusia County, Florida, was conducted in 2009 by the U.S. Geological Survey. Water-level data collected at 20 monitoring sites (17 groundwater and 3 lake sites) in the vicinity of a wetland area were analyzed with multiple linear regression to examine the relative influences of precipitation and groundwater withdrawals on changes in groundwater levels and lake stage. Analyses were conducted across varying periods of record between 1995 and 2010 and included the effects of groundwater withdrawals aggregated from municipal water-supply wells located within 12 miles of the project sites. Surface-water discharge data at the U.S. Geological Survey Tiger Bay canal site were analyzed for changes in flow between 1978 and 2001. As expected, water-level changes in monitoring wells located closer to areas of concentrated groundwater withdrawals were more highly correlated with withdrawals than were water-level changes measured in wells further removed from municipal well fields. Similarly, water-level changes in wells tapping the Upper Floridan aquifer, the source of municipal supply, were more highly correlated with groundwater withdrawals than were water-level changes in wells tapping the shallower surficial aquifer system. Water-level changes predicted by the regression models over precipitation-averaged periods of record were underestimated for observations having large positive monthly changes (generally greater than 1.0 foot). Such observations are associated with high precipitation and were identified as points in the regression analyses that produced large standardized residuals and/or observations of high influence. Thus, regression models produced by multiple linear regression analyses may have better predictive capability in wetland environments when applied to periods of average or below average precipitation conditions than during wetter than average conditions. For precipitation-averaged hydrologic conditions, water-level changes in the surficial aquifer system were statistically correlated solely with precipitation or were more highly correlated with precipitation than with groundwater withdrawals. Changes in Upper Floridan aquifer water levels and in water-surface stage (stage) at Indian and Scoggin Lakes tended to be highly correlated with both precipitation and withdrawals. The greater influence of withdrawals on stage changes, relative to changes in nearby surficial aquifer system water levels, indicates that these karstic lakes may be better connected hydraulically with the underlying Upper Floridan aquifer than is the surficial aquifer system at the other monitoring sites. At most sites, and for both aquifers, the 2-month moving average of precipitation or groundwater withdrawals included as an explanatory variable in the regression models indicates that water-level changes are not only influenced by stressor conditions across the current month, but also by those of the previous month. The relations between changes in water levels, precipitation, and groundwater withdrawals varied seasonally and in response to a period of drought. Water-level changes tended to be most highly correlated with withdrawals during the spring, when relatively large increases contributed to water-level declines, and during the fall when reduced withdrawal rates contributed to water-level recovery. Water-level changes tended to be most highly (or solely) correlated with precipitation in the winter, when withdrawals are minimal, and in the summer when precipitation is greatest. Water-level changes measured during the drought of October 2005 to June 2008 tended to be more highly correlated with groundwater withdrawals at Upper Floridan aquifer sites than at surficial aquifer system sites, results that were similar to those for precipitation-averaged conditions. Also, changes in stage at Indian and Scoggin Lakes were highly correlated with precipitation and groundwater withdrawals during the drought. Groundwater-withdrawal rates during the drought were, on average, greater than those for precipitation-averaged conditions. Accounting only for withdrawals aggregated from pumping wells located within varying radial distances of less than 12 miles of each site produced essentially the same relation between water-level changes and groundwater withdrawals as that determined for withdrawals aggregated within 12 miles of the site. Similarly, increases in withdrawals aggregated over distances of 1 to 12 miles of the sites had little effect on adjusted R-squared values. Analyses of streamflow measurements collected between 1978 and 2001 at the U.S. Geological Survey Tiger Bay canal site indicate that significant changes occurred during base-flow conditions during that period. Hypothesis and trend testing, together with analyses of flow duration, the number of zero-flow days, and double-mass curves indicate that, after 1988, when a municipal well field began production, base flow was statistically lower than the period before 1988. This decrease in base flow could not be explained by variations in precipitation between these two periods.

Florida↗

Flood hydrology and dam-breach hydraulic analyses of five reservoirs in Colorado

The U.S. Department of Agriculture Forest Service has identified hazard concerns for areas downstream from five Colorado dams on Forest Service land. In 2009, the U.S. Geological Survey, in cooperation with the Forest Service, initiated a flood hydrology analysis to estimate the areal extent of potential downstream flood inundation and hazard to downstream life, property, and infrastructure if dam breach occurs. Readily available information was used for dam-breach assessments of five small Colorado reservoirs (Balman Reservoir, Crystal Lake, Manitou Park Lake, McGinnis Lake, and Million Reservoir) that are impounded by an earthen dam, and no new data were collected for hydraulic modeling. For each reservoir, two dam-breach scenarios were modeled: (1) the dam is overtopped but does not fail (break), and (2) the dam is overtopped and dam-break occurs. The dam-breach scenarios were modeled in response to the 100-year recurrence, 500-year recurrence, and the probable maximum precipitation, 24-hour duration rainstorms to predict downstream flooding. For each dam-breach and storm scenario, a flood inundation map was constructed to estimate the extent of flooding in areas of concern downstream from each dam. Simulation results of the dam-break scenarios were used to determine the hazard classification of the dam structure (high, significant, or low), which is primarily based on the potential for loss of life and property damage resulting from the predicted downstream flooding.

Colorado↗

Simulation of groundwater flow and hydrologic effects of groundwater withdrawals from the Kirkwood-Cohansey aquifer system in the Pinelands of southern New Jersey

The Kirkwood-Cohansey aquifer system is an important source of present and future water supply in southern New Jersey. Because this unconfined aquifer system also supports sensitive wetland and aquatic habitats within the New Jersey Pinelands (Pinelands), water managers and policy makers need up-to-date information, data, and projections that show the effects of potential increases in groundwater withdrawals on these habitats. Finite-difference groundwater flow models (MODFLOW) were constructed for three drainage basins (McDonalds Branch Basin, 14.3 square kilometers (km 2 ); Morses Mill Stream Basin, 21.63 km 2 ; and Albertson Brook Basin, 52.27 km 2 ) to estimate the effects of potential increases in groundwater withdrawals on water levels and the base-flow portion of streamflow, in wetland and aquatic habitats. Three models were constructed for each drainage basin: a transient model consisting of twenty-four 1-month stress periods (October 2004 through September 2006); a transient model to simulate the 5- to 10-day aquifer tests that were performed as part of the study; and a high-resolution, steady-state model used to assess long-term effects of increased groundwater withdrawals on water levels in wetlands and on base flow. All models were constructed with the same eight-layer structure. The smallest horizontal cell dimensions among the three model areas were 150 meters (m) for the 24-month transient models, 10 m for the steady-state models, and 3 m for the transient aquifer-test models. Boundary flows of particular interest to this study and represented separately are those for wetlands, streams, and evapotranspiration. The final variables calibrated from both transient models were then used in steady-state models to assess the long-term effects of increased groundwater withdrawals on water levels in wetlands and on base flow. Results of aquifer tests conducted in the three study areas illustrate the effects of withdrawals on water levels in wetlands and on base flow. Pumping stresses at aquifer-test sites resulted in measurable drawdown in each observation well installed for the tests. The magnitude of drawdown in shallow wetland observation wells at the end of pumping ranged from 5.5 to 16.7 centimeters (cm). The stresses induced by the respective tests reduced the flow of the smallest stream (McDonalds Branch) by 75 percent and slightly reduced flow in a side channel of Morses Mill Stream, but did not measurably affect the flow of Morses Mill Stream or Albertson Brook. Results of aquifer-test simulations were used to refine the estimates of hydraulic properties used in the models and to confirm the ability of the model to replicate observed hydrologic responses to pumping. Steady-state sensitivity simulation results for a variety of single well locations and depths were used to define overall “best-case” (smallest effect on wetland water levels and base flow) and “worst-case” (greatest effect on wetland water levels and base flow) groundwater withdrawal configurations. “Best-case” configurations are those for which the extent of the wetland areas within a 1-kilometer (km) radius of the withdrawal well is minimized, the well is located at least 100 m and as far from wetland boundaries as possible, and the withdrawal is from a deep well (50–90 m deep). “Worst-case” configurations are those for which the extent of wetlands within a 1-km radius of the withdrawal well is maximized, the well is located 100 m or less from a wetland boundary, and the withdrawal is from a relatively shallow well (30–67 m deep). “Best-” and “worst-case” simulations were applied by locating hypothetical wells across the study areas and assigning groundwater withdrawals so that the sum of the withdrawals for the basin is equal to 5, 10, 15, and 30 percent of overall recharge. The results were compared to the results of simulations of no groundwater withdrawals. Results for withdrawals of 5 percent of recharge show that the area of wetland water-level decline that exceeded 15 cm was as much as 1.5 percent of the total wetland area for the “best-case” simulations and as much as 9.7 percent of the total wetland area for the “worst-case” simulations. For the same withdrawals, base-flow reduction was as much as 5.1 percent for the “best-case” simulations and as much as 8.6 percent for the “worst-case” simulations. Results for withdrawals of 30 percent of recharge show that the area of wetland water-level decline that exceeded 15 cm was as much as 70 percent of the total wetland area for the “best-case” simulations and as much as 84 percent of the total wetland area for the “worst-case” simulations. For the same withdrawals, base-flow reduction was as much as 30 percent for the “best-case” simulations and as much as 51 percent for the “worst-case” simulations. Results for withdrawals of 10 and 15 percent of recharge show decreased water levels and base flow that are intermediate between those simulated for 5 and 30 percent of recharge. Several approaches for applying the results of this study to other parts of the Pinelands were explored. An analytical-modeling technique based on the Thiem equation and image-well theory was developed to estimate local drawdown distributions resulting from withdrawals in other areas within the Pinelands. Results of example applications of this technique were compared with those of the numerical simulations used in this study and were shown to be useful. Differences among the three basins in the simulated percentage of basin wetlands affected by drawdown were found to be related to the proximity of wetlands to streams, the proximity of wetlands to pumped wells, and the vertical conductance of the aquifer system. These factors formed the basis for an index of wetland vulnerability to drawdown. An empirically-derived model based on the Gompertz function and the wetland vulnerability index was developed, tested, and shown to be an effective means to evaluate potential drawdown in wetlands at a basin scale throughout the Pinelands. Base-flow reduction can be estimated from generalized results of the numerical models, estimates of evapotranspiration reduction, or available regional groundwater flow models. These approaches could be used to evaluate alternative water-supply strategies and, in conjunction with ecological-modeling results, to determine maximum basin withdrawal rates within the limits of acceptable ecological change.

New Jersey↗

Bankfull-channel geometry and discharge curves for the Rocky Mountains Hydrologic Region in Wyoming

Regional curves relate bankfull-channel geometry and bankfull discharge to drainage area in regions with similar runoff characteristics and are used to estimate the bankfull discharge and bankfull-channel geometry when the drainage area of a stream is known. One-variable, ordinary least-squares regressions relating bankfull discharge, cross-sectional area, bankfull width, and bankfull mean depth to drainage area were developed from data collected at 35 streamgages in or near Wyoming. Watersheds draining to these streamgages are within the Rocky Mountains Hydrologic Region of Wyoming and neighboring states.

Colorado;Montana;Wyoming↗

Hydrologic and water-quality conditions in the lower Apalachicola-Chattahoochee-Flint and parts of the Aucilla-Suwannee-Ochlockonee River basins in Georgia and adjacent parts of Florida and Alabama during drought conditions, July 2011

As part of the U.S. Department of the Interior sustainable water strategy, WaterSMART, the U.S. Geological Survey documented hydrologic and water-quality conditions in the lower Apalachicola-Chattahoochee-Flint and western and central Aucilla-Suwannee-Ochlockonee River basins in Alabama, Florida, and Georgia during low-flow conditions in July 2011. Moderate-drought conditions prevailed in this area during early 2011 and worsened to exceptional by June, with cumulative rainfall departures from the 1981-2010 climate normals registering deficits ranging from 17 to 27 inches. As a result, groundwater levels and stream discharges measured below median daily levels throughout most of 2011. Water-quality field properties including temperature, dissolved oxygen, specific conductance, and pH were measured at selected surface-water sites. Record-low groundwater levels measured in 12 of 43 surficial aquifer wells and 128 of 312 Upper Floridan aquifer wells during July 2011 underscored the severity of drought conditions in the study area. Most wells recorded groundwater levels below the median daily statistic, and 7 surficial aquifer wells were dry. Groundwater-level measurements taken in July 2011 were used to determine the potentiometric surface of the Upper Floridan aquifer. Groundwater generally flows to the south and toward streams except in reaches where streams discharge to the aquifer. The degree of connection between the Upper Floridan aquifer and streams decreases east of the Flint River where thick overburden hydraulically separates the aquifer from stream interaction. Hydraulic separation of the Upper Floridan aquifer from streams located east of the Flint River is shown by stream-stage altitudes that differ from groundwater levels measured in close proximity to streams. Most streams located in the study area during 2011 exhibited below normal flows (streamflows less than the 25th percentile), substantiating the severity of drought conditions that year. Streamflow and springflow measured at 202 sites along 2,122 stream miles during July 20-24, 2011, identified about 286 miles of losing streams, about 1,230 miles of gaining streams, and about 606 miles of streams with no flow. Water-quality field properties measured at 123 stream and 5 spring sites during July 2011 yielded water temperatures ranging from 20.6 to 31.6 degrees Celsius, dissolved oxygen ranging from 0.47 to 9.98 milligrams per liter, specific conductance ranging from 13 to 834 microsiemens per centimeter at 25 degrees Celsius, and pH ranging from 3.6 to 8.03.

Alabama, Florida, Georgia↗

Geophysical and hydrologic analysis of an earthen dam site in southern Westchester County, New York

Ninety percent of the drinking water for New York City passes through the Hillview Reservoir facility in the City of Yonkers, Westchester County, New York. In the past, several seeps located downslope from the reservoir have flowed out from the side of the steepest slope at the southern end of the earthen embankment. One seep that has been flowing continuously was discovered during an inspection of the embankment in 1999. Efforts were made in 2001 to locate the potential sources of the continuous flowing seep. In 2005, the U.S. Geological Survey, in cooperation with the New York City Department of Environmental Protection, began a cooperative study to investigate the relevant hydrogeologic framework to characterize the local groundwater-flow system and to determine possible sources of the seeps. The two agencies used hydrologic and surface geophysical techniques to assess the earthen embankment of the Hillview Reservoir. Between April 1, 2005 and March 1, 2008, water levels were measured manually each month at 46 wells surrounding the reservoir, and flow was measured monthly at three of the five seeps on the embankment. Water levels were measured hourly in the East Basin of the reservoir, at 24 of 46 wells, and discharge was measured hourly at two of the five seeps. Slug tests were performed at 16 wells to determine the hydraulic conductivity of the geologic material surrounding the screened zone. Estimated hydraulic conductivities for 25 wells on the southern embankment ranged from 0.0063 to 1.2 feet per day and averaged 0.17 foot per day. The two-dimensional resistivity surveys indicate a subsurface mound of electrically conductive material (low-resistivity zone) beneath the terrace area (top of dam) surrounding the reservoir with a distinct elevation increase closer to the crest. Two-dimensional shear wave velocity surveys indicate a similar structure of the high shear wave velocity materials (high-velocity zone), increasing in elevation toward the crest and decreasing toward the reservoir and toward the northern part of the study area. Water-quality samples collected from 12 wells, downtake chamber 1 of the reservoir, and two seeps detected the presence of arsenic, toluene, and two trihalomethanes. Water-quality samples collected at the two seeps detected fluoride, indicating a connection with reservoir water. Shallow wells on the southern embankment exhibited the largest seasonal water-level fluctuations ranging between 6 feet and 12 feet. The embankment is constructed from reworked low-permeability glacial deposits at the site. Water-level responses in observation wells within the embankment indicate that there is a shallow (approximately the upper 45 feet of the embankment) and a deep water-bearing unit within the embankment with a large downward vertical gradient between the shallow and deep water-bearing units. Precipitation strongly affected water levels in shallow wells, whereas the basin appears to be the main control on water levels in the deep wells. Seeps on the embankment slope appear to be caused by above-average precipitation that increases water levels in the shallow water-bearing unit, but does not easily recharge the deep water-bearing unit. Based on the data that have been analyzed, source water to the seeps appears to be primarily groundwater and, to a lesser extent, water from the East Basin of the reservoir.

New York↗

Hydrogeologic framework, hydrology, and water quality in the Pearce Creek Dredge Material Containment Area and vicinity, Cecil County, Maryland, 2010-11

In 2009, to support an evaluation of the feasibility of reopening the Pearce Creek Dredge Material Containment Area (DMCA) in Cecil County, Maryland, for dredge-spoil disposal, the U.S. Geological Survey (USGS) began to implement a comprehensive study designed to improve the understanding of the hydrogeologic framework, hydrology, and water quality of shallow aquifers underlying the DMCA and adjacent communities, to determine whether or not the DMCA affected groundwater quality, and to assess whether or not groundwater samples contained chemical constituents at levels greater than maximum allowable or recommended levels established by the U.S. Environmental Protection Agency Safe Drinking Water Act. The study, conducted in 2010-11 by USGS in cooperation with the U.S. Army Corps of Engineers, included installation of observation wells in areas where data gaps led earlier studies to be inconclusive. The data from new wells and existing monitoring locations were interpreted and show the DMCA influences the groundwater flow and quality. Groundwater flow in the two primary aquifers used for local supplies-the Magothy aquifer and upper Patapsco aquifer (shallow water-bearing zone)-is radially outward from the DMCA toward discharge areas, including West View Shores, the Elk River, and Pearce Creek Lake. In addition to horizontal flow outward from the DMCA, vertical gradients primarily are downward in most of the study area, and upward near the Elk River on the north side of the DMCA property, and the western part of West View Shores. Integrating groundwater geochemistry data in the analysis, the influence of the DMCA is not only a source of elevated concentrations of dissolved solids but also a geochemical driver of redox processes that enhances the mobilization and transport of redox-sensitive metals and nutrients. Groundwater affected by the DMCA is in the Magothy aquifer and upper Patapsco aquifer (shallow water-bearing zone). Based on minimal data, the water quality in the upper Patapsco aquifer deep water-bearing zone does not seem to have been impacted by the DMCA.

Maryl↗

Hydrology of the middle San Pedro area, southeastern Arizona

In the middle San Pedro Watershed in southeastern Arizona, groundwater is the primary source of water supply for municipal, domestic, industrial, and agricultural use. The watershed comprises two smaller subareas, the Benson subarea and the Narrows-Redington subarea. Early 21st century projections for heavy population growth in the watershed have not yet become a reality, but increased groundwater withdrawals could have undesired consequences - such as decreased base flow to the San Pedro River, and groundwater-level declines - that would lead to the need to deepen existing wells. This report describes the hydrology, hydrochemistry, water quality, and development of a groundwater budget for the middle San Pedro Watershed, focusing primarily on the elements of groundwater movement that could be most useful for the development of a groundwater model Precipitation data from Tombstone, Arizona, and base flow at the stream-gaging station on the San Pedro River at Charleston both show relatively dry periods during the 1960s through the mid-1980s and in the mid-1990s to 2009, and wetter periods from the mid-1980s through the mid-1990s. Water levels in four out of five wells near the mountain fronts show cyclical patterns of recharge, with rates of recharge greatest in the early 1980s through the mid-1990s. Three wells near the San Pedro River recorded their lowest levels during the 1950s to the mid-1960s. The water-level record from one well, completed in the confined part of the coarse-grained lower basin fill, showed a decline of approximately 21 meters. Annual flow of the San Pedro River, measured at the Charleston and Redington gages, has decreased since the 1940s. The median annual streamflow and base flow at the gaging station on the river near Tombstone has decreased by 50 percent between the periods 1968–1986 and 1997–2009. Estimates of streamflow infiltration along the San Pedro River during 1914–2009 have decreased 44 percent, with the largest decreases in the months June–October in the Benson subarea. In the Narrows-Redington subarea, streamflow infiltration has decreased about 65 percent during 1914–2009. The average annual outflow (27.6 hm 3 /year [cubic hectometers per year]) from the Benson subarea aquifer for water years 2001 through 2009 exceeded the inflows (20.0 hm 3 / yr) by 7.60 hm 3 /yr. In the Narrows-Redington subarea for the same period, the average annual outflow (15.7 hm 3 /yr) from the aquifer system exceeded the inflows (13.8 hm 3 /yr) by nearly 2 hm 3 /yr. The largest withdrawals of groundwater in both subareas are for irrigation; these withdrawals peaked in 1973 and have been steadily decreasing since then. Recharge from streamflow infiltration exceeded recharge from the mountain-front and from ephemeral channels in the Benson subarea. In the Narrows-Redington subarea, however, recharge from mountain-front and ephemeral channel recharge exceeded recharge from streamflow infiltration. Evapotranspiration by phreatophytes accounts for the largest outflow of groundwater for both subareas—78 percent of the outflow in the Narrows-Redington subarea and 62 percent of the outflow in the Benson subarea. Precipitation, surface-water, and groundwater chemistry and isotope data indicated the relative age and residence time of groundwater, the amount of interaction between geologic sources and groundwater, and how recharge elevation and season were related to the presence of modern water. The bedrock aquifer receives modern recharge (

Arizona↗

An update of hydrologic conditions and distribution of selected constituents in water, eastern Snake River Plain aquifer and perched groundwater zones, Idaho National Laboratory, Idaho, emphasis 2009–11

Since 1952, wastewater discharged to infiltration ponds (also called percolation ponds) and disposal wells at the Idaho National Laboratory (INL) has affected water quality in the eastern Snake River Plain (ESRP) aquifer and perched groundwater zones underlying the INL. The U.S. Geological Survey (USGS), in cooperation with the U.S. Department of Energy, maintains groundwater monitoring networks at the INL to determine hydrologic trends, and to delineate the movement of radiochemical and chemical wastes in the aquifer and in perched groundwater zones. This report presents an analysis of water-level and water-quality data collected from aquifer, multilevel monitoring system (MLMS), and perched groundwater wells in the USGS groundwater monitoring networks during 2009–11. Water in the ESRP aquifer primarily moves through fractures and interflow zones in basalt, generally flows southwestward, and eventually discharges at springs along the Snake River. The aquifer primarily is recharged from infiltration of irrigation water, infiltration of streamflow, groundwater inflow from adjoining mountain drainage basins, and infiltration of precipitation. From March–May 2009 to March–May 2011, water levels in wells generally declined in the northern part of the INL. Water levels generally rose in the central and eastern parts of the INL. Detectable concentrations of radiochemical constituents in water samples from aquifer wells or MLMS equipped wells in the ESRP aquifer at the INL generally decreased or remained constant during 2009–11. Decreases in concentrations were attributed to radioactive decay, changes in waste-disposal methods, and dilution from recharge and underflow. In 2011, concentrations of tritium in groundwater from 50 of 127 aquifer wells were greater than or equal to the reporting level and ranged from 200±60 to 7,000±260 picocuries per liter. Tritium concentrations from one or more discrete zones from four wells equipped with MLMS were greater than or equal to reporting levels in water samples collected at various depths. Tritium concentrations in water from wells completed in shallow perched groundwater at the Advanced Test Reactor Complex (ATR Complex) were less than the reporting levels. Tritium concentrations in deep perched groundwater at the ATR Complex equaled or exceeded the reporting level in 12 wells during at least one sampling event during 2009–11 at the ATR Complex. Concentrations of strontium-90 in water from 20 of 76 aquifer wells sampled during April or October 2011 exceeded the reporting level. Strontium-90 was not detected within the ESRP aquifer beneath the ATR Complex. During at least one sampling event during 2009–11, concentrations of strontium-90 in water from 10 wells completed in deep perched groundwater at the ATR Complex equaled or exceeded the reporting levels. During 2009–11, concentrations of plutonium-238, and plutonium-239, -240 (undivided), and americium-241 were less than the reporting level in water samples from all aquifer wells and in all wells equipped with MLMS. Concentrations of cesium-137 were equal to or slightly above the reporting level in 8 aquifer wells and from 2 wells equipped with MLMS. The concentration of chromium in water from one well south of the ATR Complex was 97 micrograms per liter (μg/L) in April 2011, just less than the maximum contaminant level (MCL) of 100 μg/L. Concentrations of chromium in water samples from 69 other wells sampled ranged from 0.8 μg/L to 25 μg/L. During 2009–11, dissolved chromium was detected in water from 15 wells completed in perched groundwater at the ATR Complex. In 2011, concentrations of sodium in water from most wells in the southern part of the INL were greater than the background concentration of 10 milligrams per liter (mg/L); the highest concentrations were at or near the Idaho Nuclear Engineering and Technology Center (INTEC). After the newpercolation ponds were put into service in 2002 southwest of the INTEC, concentrations of sodium in water samples from the Rifle Range well rose steadily until 2008, when the concentrations generally began decreasing. The increases and decreases were attributed to disposal variability in the new percolation ponds. Concentrations of sodium in most wells equipped with MLMS generally were consistent with depth. During 2011, dissolved sodium concentrations in water from 17 wells completed in deep perched groundwater at the ATR Complex ranged from 6 to 146 mg/L. In 2011, concentrations of chloride in most water samples from aquifer wells south of the INTEC and at the Central Facilities Area exceeded the background concentrations of 15 mg/L, but were less than the secondary MCL of 250 mg/L. Chloride concentrations in water from wells south of the INTEC have generally increased because of increased chloride disposal to the old percolation ponds since 1984 when discharge of wastewater to the INTEC disposal well was discontinued. After the new percolation ponds were put into service in 2002 southwest of the INTEC, concentrations of chloride in water samples from one well rose steadily until 2008 then began decreasing. Chloride concentrations in water from all but one well completed in the ESRP aquifer at or near the ATR Complex were less than background and ranged between 10 and 14 mg/L during 2011, similar to concentrations detected during the 2006–08 reporting period. During 2011, chloride concentrations in water from two aquifer wells at the Radioactive Waste Management Complex (RWMC) were slightly greater than concentrations detected during the 2006–08 reporting period. The vertical distribution of chloride concentrations in wells equipped with MLMS were generally consistent within zones during 2009–11 and ranged from about 8 to 20 mg/L. During April 2011, dissolved chloride concentrations in shallow perched groundwater at the ATR Complex ranged from 7 to 13 mg/L in water from three wells. Dissolved chloride concentrations in deep perched groundwater at the ATR Complex during 2011 ranged from 4 to 54 mg/L. In 2011, sulfate concentrations in water samples from 11 aquifer wells in the south-central part of the INL equaled or exceeded the background concentration of sulfate and ranged from 40 to 167 mg/L. The greater-than-background concentrations in water from these wells probably resulted from sulfate disposal at the ATR Complex infiltration ponds or the old INTEC percolation ponds. In 2011, sulfate concentrations in water samples from two wells near the RWMC were greater than background levels and could have resulted from well construction techniques and (or) waste disposal at the RWMC. The vertical distribution of sulfate concentrations in three wells near the southern boundary of the INL was generally consistent with depth, and ranged between 19 and 25 mg/L. The maximum dissolved sulfate concentration in shallow perched groundwater near the ATR Complex was 400 mg/L in well CWP 1 in April 2011. During 2009–11, the maximum concentration of dissolved sulfate in deep perched groundwater at the ATR Complex was 1,550 mg/L in a well located west of the chemical-waste pond. In 2011, concentrations of nitrate in water from most wells at and near the INTEC exceeded the regional background concentrations of 1 mg/L and ranged from 1.6 to 5.95 mg/L. Concentrations of nitrate in wells south of INTEC and farther away from the influence of disposal areas and the Big Lost River show a general decrease in nitrate concentrations through time. During 2009–11, water samples from 30 wells were collected and analyzed for volatile organic compounds (VOCs). Six VOCs were detected. At least one and up to five VOCs were detected in water samples from 10 wells. The primary VOCs detected include carbon tetrachloride, chloroform, tetrachloroethylene, 1,1,1-trichloroethane, and trichloroethylene. In 2011, concentrations for all VOCs were less than their respective MCL for drinking water, except carbon tetrachloride in water from two wells. During 2009–11, variability and bias were evaluated from 56 replicate and 16 blank quality-assurance samples. Results from replicate analyses were investigated to evaluate sample variability. Constituents with acceptable reproducibility were stable isotope ratios, major ions, nutrients, and VOCs. All radiochemical constituents and trace metals had acceptable reproducibility except for gross beta-particle radioactivity, aluminum, antimony, and cobalt. Bias from sample contamination was evaluated from equipment, field, container, and source-solution blanks. No detectable constituent concentrations were reported for equipment blanks of the thief samplers and sampling pipes or for the source-solution and field blanks. Equipment blanks of bailers had detectable concentrations of strontium-90, sodium, chloride, and sulfate, and the container blank had a detectable concentration of dichloromethane.

Idaho↗

Effects of hydrologic modifications on salinity and formation of hypoxia in the Mississippi River-Gulf Outlet and adjacent waterways, southeastern Louisiana, 2008 to 2012

The Mississippi River-Gulf Outlet (MRGO) was constructed between 1958 and 1968 to provide a safer and shorter route between the Gulf of Mexico and the Port of New Orleans for ocean-going vessels. In 2006, the U.S. Congress directed the U.S. Army Corps of Engineers (USACE) to develop and implement a plan to deauthorize a portion of the MRGO ship channel from its confluence with the Gulf Intracoastal Waterway to the Gulf of Mexico. In 2009, in accordance with plans submitted to Congress, the USACE built a rock barrier across the MRGO near Hopedale, Louisiana. Following Hurricane Katrina, Congress also authorized the USACE to implement the Hurricane Storm Damage Risk Reduction System (HSDRRS) by building structures in the MRGO and adjacent surface waters, to reduce vulnerability of this area to storm surge. The HSDRRS includes the Gulf Intracoastal Waterway-Lake Borgne Surge Barrier and Gate Complex near mile 58 of the deauthorized portion of the MRGO and the Seabrook Gate Complex on the Inner Harbor Navigation Canal (IHNC). By blocking or limiting tidal exchange in the MRGO, these barriers could affect water quality in the MRGO and nearby waters including Lake Pontchartrain, the IHNC, and Lake Borgne. In 2008, the U.S. Geological Survey, in cooperation with the USACE, began a study to document the effects of the construction activities on salinity and dissolved oxygen in these surface waters. Data were collected from August 2008 through October 2012. Completion of the rock barrier in the vicinity of mile 35 in July 2009 reduced hydrologic circulation and separated the MRGO into two distinct salinity regimes, with substantially fresher conditions prevailing upstream from the rock barrier. The rock barrier also contributed to a zone of hypoxia (dissolved oxygen less than 2 milligrams per liter) that formed along the channel bottom during the warmer summer months in each year of this monitoring; the zone was much more developed downstream from the rock barrier. The most extensive hypoxic zone was measured in October 2009 when it extended at least 34 miles in the MRGO, from mile 20 to mile 54. Construction of the surge barrier and flood gates did not affect salinity or dissolved oxygen in any comparable manner. The factors that contributed the most to hypoxia in the MRGO were the reductions in tidal water movement there after completion of the rock barrier combined with the channel depth in the MRGO, in places 10 to 30 feet deeper than surrounding surface water bodies. These factors helped to stratify salinity by reducing vertical mixing in the water column.

Louisiana↗