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Emission of pesticides into the air

During and after the application of a pesticide in agriculture, a substantial fraction of the dosage may enter the atmosphere and be transported over varying distances downwind of the target. The rate and extent of the emission during application, predominantly as spray particle drift, depends primarily on the application method (equipment and technique), the formulation and environmental conditions, whereas the emission after application depends primarily on the properties of the pesticide, soils, crops and environmental conditions. The fraction of the dosage that misses the target area may be high in some cases and more experimental data on this loss term are needed for various application types and weather conditions. Such data are necessary to test spray drift models, and for further model development and verification as well. Following application, the emission of soil fumigants and soil incorporated pesticides into the air can be measured and computed with reasonable accuracy, but further model development is needed to improve the reliability of the model predictions. For soil surface applied pesticides reliable measurement methods are available, but there is not yet a reliable model. Further model development is required which must be verified by field experiments. Few data are available on pesticide volatilization from plants and more field experiments are also needed to study the fate processes on the plants. Once this information is available, a model needs to be developed to predict the volatilization of pesticides from plants, which, again, should be verified with field measurements. For regional emission estimates, a link between data on the temporal and spatial pesticide use and a geographical information system for crops and soils with their characteristics is needed.

Conference Paper↗

Isotopic analysis of N and O in nitrite and nitrate by sequential selective bacterial reduction to N2O

Nitrite is an important intermediate species in the biogeochemical cycling of nitrogen, but its role in natural aquatic systems is poorly understood. Isotopic data can be used to study the sources and transformations of NO 2 - in the environment, but methods for independent isotopic analyses of NO 2 - in the presence of other N species are still new and evolving. This study demonstrates that isotopic analyses of N and O in NO 2 - can be done by treating whole freshwater or saltwater samples with the denitrifying bacterium Stenotrophomonas nitritireducens , which selectively reduces NO 2 - to N 2 O for isotope ratio mass spectrometry. When calibrated with solutions containing NO 2 - with known isotopic compositions determined independently, reproducible δ 15 N and δ 18 O values were obtained at both natural-abundance levels (±0.2−0.5‰ for δ 15 N and ±0.4−1.0‰ for δ 18 O) and moderately enriched 15 N tracer levels (±20−50‰ for δ 15 N near 5000‰) for 5−20 nmol of NO 2 - (1−20 μmol/L in 1−5 mL aliquots). This method is highly selective for NO 2 - and was used for mixed samples containing both NO 2 - and NO 3 - with little or no measurable cross-contamination. In addition, mixed samples that were analyzed with S. nitritireducens were treated subsequently with Pseudomonas aureofaciens to reduce the NO 3 - in the absence of NO 2 - , providing isotopic analyses of NO 2 - and NO 3 - separately in the same aliquot. Sequential bacterial reduction methods like this one should be useful for a variety of isotopic studies aimed at understanding nitrogen cycling in aquatic environments. A test of these methods in an agricultural watershed in Indiana provides isotopic evidence for both nitrification and denitrification as sources of NO 2 - in a small stream.

Indiana↗

Pesticide concentrations in multiple physical and biological stream matrices are impacted by a bioenergy production facility receiving pesticide coated corn seeds

Insecticide and fungicide seed coatings have become prevalent in conventional agriculture in recent decades. From 2015 to 2021, the AltEn bioenergy plant (Mead, Nebraska, USA) generated ethanol from almost 100% unused/expired treated corn seeds. This use of these seeds for ethanol production resulted in the accumulation of large amounts of contaminated wastewater and solid residue, a portion of which was applied to surrounding farmland. To better understand the potential long-term environmental effects from the processing of treated seeds at this facility, five nearby stream sites were sampled in 2022 after the closure of the plant; these included two sites directly impacted by AltEn, one upstream, and two downstream of the impacted sites. Water and sediment were collected in March through July, and algae and fish samples were collected in July for chemical analysis. Overall, 60 pesticide compounds (parents and transformation products) were detected in one or more matrices, including 23 fungicides, 20 insecticides, 16 herbicides, and 1 bacterial growth inhibitor. Pesticide results (maximum detection frequency, maximum concentration) varied substantially by environmental compartment: water (100% multiple pesticides; 4,600 ng L −1 thiamethoxam transformation product (NOA-407475)), algae (100% multiple pesticides, 190 ng g −1 atrazine), sediment (60% dithiopyr, 2.3 ng g −1 acetochlor) and fish (20% pyraclostrobin, 2.2 ng g −1 atrazine). Pesticides associated with treated corn seeds (e.g., insecticides clothianidin, thiamethoxam; fungicides fluoxastrobin, thiabendazole) were detected at significantly higher concentrations ( p < 0.05) in stream water from sites impacted by the AltEn facility compared to non-impacted sites. Study results indicate that pesticides associated with the AltEn facility continue to be a source of contaminants to aquatic systems after the plant’s closure in 2021.

Environmental Toxicology and Chemistry↗

The Landscape Data Commons: A system for standardizing, accessing, and applying large environmental datasets for agroecosystem research and management

Understanding where, when, and why agroecosystems are changing requires quality information about ecosystems that span land tenure, ecological processes, and spatial scales. Over the past two decades, land management agencies and research groups have adopted a suite of standardized methods for monitoring rangelands, which have been implemented at over 85,000 monitoring locations globally. However, the ability to use these data to understand agroecosystem dynamics and change across scales and across land ownership has been limited because, until now, these data have not been available in a harmonized, accessible format for analyses, modeling, and decision-support tools. We present the Landscape Data Commons, a cyberinfrastructure platform that harmonizes and aggregates standardized agroecosystem data, enables linkages to models, and facilitates analysis and interpretation of data within decision-support tools. The Landscape Data Commons provides a community platform for users to contribute data and develop next-generation tools to support agroecosystem management through the 21st century.

Agricultural & Environmental Letters↗

The role of reserves and anthropogenic elements for functional connectivity and resilience of ephemeral habitats

Ecological reserves provide important wildlife habitat in many landscapes, and the functional connectivity of reserves and other suitable habitat patches is crucial for the persistence and resilience of spatially structured populations. To maintain or increase connectivity at spatial scales larger than individual patches, conservation actions may focus on creating and maintaining reserves and/or influencing management on non-reserves. Using a graph-theoretic approach, we assessed the functional connectivity and spatial distribution of wetlands in the Rainwater Basin of Nebraska, USA, an intensively cultivated agricultural matrix, at four assumed, but ecologically realistic, anuran dispersal distances. We compared connectivity in the current landscape to the historical landscape and putative future landscapes, and evaluated the importance of individual and aggregated reserve and non-reserve wetlands for maintaining connectivity. Connectivity was greatest in the historical landscape, where wetlands were also the most densely distributed. The construction of irrigation reuse pits for water storage has maintained connectivity in the current landscape by replacing destroyed wetlands, but these pits likely provide suboptimal habitat. Also, because there are fewer total wetlands (i.e., wetlands and irrigation reuse pits) in the current landscape than the historical landscape, and because the distribution of current wetlands is less clustered than that of historical wetlands, larger and longer dispersing, sometimes nonnative species may be favored over smaller, shorter dispersing species of conservation concern. Because of their relatively low number, wetland reserves do not affect connectivity as greatly as non-reserve wetlands or irrigation reuse pits; however, they likely provide the highest quality anuran habitat. To improve future levels of resilience in this wetland habitat network, management could focus on continuing to improve the conservation status of non-reserve wetlands, restoring wetlands at spatial scales that promote movements of shorter dispersing species, and further scrutinizing irrigation reuse pit removal by considering effects on functional connectivity for anurans, an emblematic and threatened group of organisms. However, broader conservation plans will need to give consideration to other wetland-dependent species, incorporate invasive species management, and address additional challenges arising from global change in social-ecological systems like the Rainwater Basin.

Nebraska↗

Climatic and topographical factors affecting the vegetative carbon stock of rangelands in arid and semiarid regions of China

Rangeland systems play an important role in ecological stabilization and the terrestrial carbon cycle in arid and semiarid regions. However, little is known about the vegetative carbon dynamics and climatic and topographical factors that affect vegetative carbon stock in these rangelands. Our goal was to assess vegetative carbon stock by examining meteorological data in conjunction with NDVI (normalized difference vegetation index) time series datasets from 2001–2012. An improved CASA (Carnegie Ames Stanford Approach) model was then applied to simulate the spatiotemporal dynamic variation of vegetative carbon stock, and analyze its response to climatic and topographical factors. We estimated the vegetative carbon stock of rangeland in Gansu province, China to be 4.4× 1014 gC, increasing linearly at an annual rate of 9.8×10 11 gC. The mean vegetative carbon density of the whole rangeland was 136.5 gC m -2 . Vegetative carbon density and total carbon varied temporally and spatially and were highly associated with temperature, precipitation and solar radiation. Vegetative carbon density reached the maximal value on elevation at 2500–3500 m, a slope of >30°and easterly aspect. The effect of precipitation, temperature and solar radiation on the vegetative carbon density of five rangeland types (desert and salinized meadow, steppe, alpine meadow, shrub and tussock, and marginal grassland in the forest) depends on the acquired quantity of water and heat for rangeland plants at all spatial scales. The results of this study provide new evidence for explaining spatiotemporal heterogeneity in vegetative carbon dynamics and responses to global change for rangeland vegetative carbon stock, and offer a theoretical and practical basis for grassland agriculture management in arid and semiarid regions.

Gansu↗

Metamodeling and mapping of nitrate flux in the unsaturated zone and groundwater, Wisconsin, USA

Nitrate contamination of groundwater in agricultural areas poses a major challenge to the sustainability of water resources. Aquifer vulnerability models are useful tools that can help resource managers identify areas of concern, but quantifying nitrogen (N) inputs in such models is challenging, especially at large spatial scales. We sought to improve regional nitrate (NO 3 − ) input functions by characterizing unsaturated zone NO 3 − transport to groundwater through use of surrogate, machine-learning metamodels of a process-based N flux model. The metamodels used boosted regression trees (BRTs) to relate mappable landscape variables to parameters and outputs of a previous “vertical flux method” (VFM) applied at sampled wells in the Fox, Wolf, and Peshtigo (FWP) river basins in northeastern Wisconsin. In this context, the metamodels upscaled the VFM results throughout the region, and the VFM parameters and outputs are the metamodel response variables. The study area encompassed the domain of a detailed numerical model that provided additional predictor variables, including groundwater recharge, to the metamodels. We used a statistical learning framework to test a range of model complexities to identify suitable hyperparameters of the six BRT metamodels corresponding to each response variable of interest: NO 3 − source concentration factor (which determines the local NO 3 − input concentration); unsaturated zone travel time; NO 3 − concentration at the water table in 1980, 2000, and 2020 (three separate metamodels); and NO 3 − “extinction depth”, the eventual steady state depth of the NO 3 − front. The final metamodels were trained to 129 wells within the active numerical flow model area, and considered 58 mappable predictor variables compiled in a geographic information system (GIS). These metamodels had training and cross-validation testing R 2 values of 0.52 – 0.86 and 0.22 – 0.38, respectively, and predictions were compiled as maps of the above response variables. Testing performance was reasonable, considering that we limited the metamodel predictor variables to mappable factors as opposed to using all available VFM input variables. Relationships between metamodel predictor variables and mapped outputs were generally consistent with expectations, e.g. with greater source concentrations and NO 3 − at the groundwater table in areas of intensive crop use and well drained soils. Shorter unsaturated zone travel times in poorly drained areas likely indicated preferential flow through clay soils, and a tendency for fine grained deposits to collocate with areas of shallower water table. Numerical estimates of groundwater recharge were important in the metamodels and may have been a proxy for N input and redox conditions in the northern FWP, which had shallow predicted NO 3 − extinction depth. The metamodel results provide proof-of-concept for regional characterization of unsaturated zone NO 3 − transport processes in a statistical framework based on readily mappable GIS input variables.

Wisconsin↗

Hydrogeology and water quality of the upper Floridan aquifer, western Albany area, Georgia

Geologic, hydrologic, and water-quality data were collected to refine the hydrogeologic framework conceptual model of the Upper Floridan aquifer, and to qualitatively evaluate the potential of human activities to impact water quality in the Upper Floridan aquifer in the western Albany area, Georgia. Ground-water age dating was conducted by using chlorofluorocarbons (CFC) and tritium concentrations in water from the Upper Floridan aquifer to determine if recharge and possible contaminant migration to the aquifer is recent or occurred prior to the introduction of CFCs and tritium in the early 1950's into the global natural water system. Data were collected from core holes and wells installed during this study and previously existing wells in the Albany area. Hydrogeologic data collected during this study compare well to the regional hydrogeologic conceptual model developed during previous studies. However, the greater data density available from this study shows the dynamic and local variability in the hydrologic character of the Upper Floridan aquifer in more detail. The occurrence of sediment sizes from clay to gravel in the overburden, the absence of overburden because of erosion or sinkhole collapse, and large areas lacking surface drainage west of the Flint River provide potential areas for recharge and contaminant migration from the surface to the Upper Floridan aquifer throughout the study area. Ground-water ages generally range from 9 to 34 years, indicating that recharge consisting of 'modern' water (post early-1950's) is present in the aquifer. Ground-water ages and hydraulic heads in the Upper Floridan aquifer have an irregular distribution, indicating that localized areas of recharge to the aquifer are present in the study area. Generally, water in the Upper Floridan aquifer is calcium-bicarbonate rich, having low concentrations of magnesium, potassium, sodium, chloride, and sulfate. Water in the Upper Floridan aquifer is oxygenated, having dissolved-oxygen concentrations greater than 2 milligrams per liter. Nitrite-plus-nitrate as nitrogen, is present in the aquifer at concentrations ranging from less than 0.02 to 5.5 milligrams per liter. Areas of higher nitrate concentrations in the aquifer, coupled with widely distributed localized recharge to the aquifer indicates that suburban residential and agricultural land use in the western Albany area may affect water quality in the Upper Floridan aquifer. However, concentrations exceeding drinking water criteria were not detected in the study area. Generally, water in the Upper Floridan aquifer is calcium-bicarbonate rich, having low concentrations of magnesium, potassium, sodium, chloride, and sulfate. Water in the Upper Floridan aquifer is oxygenated, having dissolved-oxygen concentrations greater than 2 milligrams per liter. Nitrite-plus-nitrate as nitrogen, is present in the aquifer at concentrations ranging from less than 0.02 to 5.5 milligrams per liter. Areas of higher nitrate concentrations in the aquifer, coupled with widely distributed localized recharge to the aquifer indicates that suburban residential and agricultural land use in the western Albany area may affect water quality in the Upper Floridan aquifer. However, concentrations exceeding drinking water criteria were not detected in the study area.

Georgia↗

Influences of environmental settings on aquatic ecosystems in the Apalachicola-Chattahoochee-Flint River basin

The watershed boundary of the Apalachicola-Chattahoochee-Flint (ACF) River basin defines an aquatic ecosystem whose water quality is the result of complex interactions of natural and human influences on land and water resources. Topics relating to the basin's environmental setting-its physical, biological, and cultural characteristics-are summarized to provide an understanding of factors that influence water quality and the health of aquatic ecosystems. The ACF River basin lies partly in southwestern Georgia, southeastern Alabama, and northwestern Florida and covers 19,800 square miles in the Blue Ridge, the Piedmont, and the Coastal Plain Provinces. The basin includes the drainages of the Chattahoochee River and the Flint River, which meet to form the Apalachicola River. The Apalachicola River flows into the Gulf of Mexico at Apalachicola Bay. Basin hydrology and water quality are influenced by 16 mainstem reservoirs, 13 of which are on the Chattahoochee River. Ground water in the basin is contained in six aquifers-the surficial aquifer system, the Floridan aquifer system, the Claiborne aquifer, the Clayton aquifer, the Providence aquifer, and the crystalline-rock aquifer. Physiography, climate, and hydrology of the ACF River basin provide natural conditions that support a rich and abundant diversity of plants and animals. Although most of the ACF River basin has been altered by human activities, the basin's environment is noteworthy for its remaining biological diversity and the role it plays in sustaining biological productivity in Apalachicola Bay. The Bay produces 90 percent of Florida's and 13 percent of the Nation's oyster harvest; and functions as a nursery for penaeid shrimp, blue crabs, and a variety of fin fish. The diversity of the basin's aquatic fauna is noteworthy because the basin is home to (1) the largest number of fish species among Gulf Coast drainages east of the Mississippi River, (2) the largest assemblage of freshwater fish in Florida, (3) the largest number of mollusc species among western Florida drainages, and (4) the highest species density of amphibians and reptiles on the continent north of Mexico. Population of the ACF River basin in 1990 was estimated at 2.6 million. Nearly 90 percent of the total population lived in Georgia, and nearly 60 percent lived in the Metropolitan Atlanta area. The 1990 basin population is projected to increase by 15 percent to 3.0 million by the year 2000, and by 30 percent to 3.4 million by 2010. The largest increases in populations are projected for the Metropolitan Atlanta area. In 1972-76, approximately 59 percent of the basin was covered by forest, 29 percent was agricultural, 5 percent was wetland, 4 percent was urban, and 3 percent was water or barren land. Most of the original land cover of the basin has been transformed by human activity. Timber is the basin's largest cash crop and most forests consist of second-growth stands or large acreages of planted pine. The dominant agricultural land use in the Piedmont Province is pasture and confined feeding for dairy, livestock, and poultry production. Row-crop agriculture, orchards, and silviculture are most common in the Coastal Plain Province. The top five crops in order from most to least acres harvested in 1990 were peanuts, corn, soybeans, wheat, and cotton. The water in the basin is used for public and industrial supply, irrigation, power generation, navigation, and recreation. Although most public-supply withdrawals in the Blue Ridge and Piedmont Provinces are from surface-water sources, with the exception of counties near or immediately below the Fall Line, all publicly supplied water in the Coastal Plain is withdrawn from ground-water sources. Ground water supplied 18 percent of the basin's population served by public supply. Total water withdrawn in the ACF River basin in 1990 was 2,098 million gallons per day (Mgal/d), of which Georgia withdrew 82 percent and Florida and Alabama each withdrew 9 percent. Power generation is the single largest water use. Sixteen of the basin's 22 power generating plants are located along the mainstem of the Chattahoochee River. The U.S. Army Corps of Engineers maintains a navigation channel from the mouth of the Apalachicola River to Columbus, Ga., on the Chattahoochee River and to Bainbridge, Ga., on the Flint River. Water quality in the basin is influenced by the operation of 137 municipal wastewater-treatment facilities. In 1990, 354 Mgal/d of municipal wastewater was discharged within the ACF River basin. Eighty-eight percent of the wastewater was discharged into the Chattahoochee River basin, 10.6 percent into the Flint River basin, and 1.4 percent into the Apalachicola River basin. Two-thirds of the 938 stream miles in the Georgia portion of the ACF River basin having water quality that does not meet or only partially meets the designated-use criteria in the Chattahoochee River basin. The Chattahoochee River is the most heavily-used water resource both in the ACF River basin and in Georgia. Urban runoff or unknown nonpoint sources are cited as the causes of water-quality regulations in 72 percent of violations. The remaining causes primarily are combined sewer overflows in the Atlanta area, and discharges from municipal or industrial treatment facilities with inadequate treatment capabilities or operational deficiencies.

Alabama, Florida, Georgia↗

Environmental setting and its relations to water quality in the Kanawha River basin

The Kanawha River and its major tributary, the New River, drain 12,233 mi2 in West Virginia, Virginia, and North Carolina. Altitude ranges from about 550 ft to more than 4,700 ft. The Kanawha River Basin is mountainous, and includes parts of three physiographic provinces, the Blue Ridge (17 percent), Valley and Ridge (23 percent), and Appalachian Plateaus (60 percent). In the Appalachian Plateaus Province, little of the land is flat, and most of the flat land is in the flood plains and terraces of streams; this has caused most development in this part of the basin to be near streams. The Blue Ridge Province is composed of crystalline rocks, and the Valley and Ridge and Appalachian Plateaus Provinces contain both carbonate and clastic rocks. Annual precipitation ranges from about 36 in. to more than 60 in., and is orographically affected, both locally and regionally. Average annual air temperature ranges from about 43ºF to about 55ºF, and varies with altitude but not physiographic province. Precipitation is greatest in the summer and least in the winter, and has the least seasonal variation in the Blue Ridge Province. In 1990, the population of the basin was about 870,000, of whom about 25 percent lived in the Charleston, W. Va. metropolitan area. About 75 million tons of coal were mined in the Kanawha River Basin in 1998. This figure represents about 45 percent of the coal mined in West Virginia, and about seven percent of the coal mined in the United States. Dominant forest types in the basin are Northern Hardwood, Oak-Pine, and Mixed Mesophytic. Agricultural land use is more common in the Valley and Ridge and Blue Ridge Provinces than in the Appalachian Plateaus Province. Cattle are the principal agricultural products of the basin. Streams in the Blue Ridge Province and Allegheny Highlands have the most runoff in the basin, and streams in the Valley and Ridge Province and the southwestern Appalachian Plateaus have the least runoff. Streamflow is greatest in the spring and least in the autumn. About 61 percent of the basin's population use surface water from public supply for their domestic needs; about 30 percent use self-supplied ground water, and about nine percent use ground water from public supply. In 1995, total withdrawal of water in the basin was about 1,130 Mgal/d. Total consumptive use was about 118 Mgal/d. Surface water in the Blue Ridge Province is usually dilute (less than 100 mg/L dissolved solids) and well aerated. Dissolved- solids concentrations in streams of the Valley and Ridge Province at low flow are typically greater (150-180 mg/L) than those in the Blue Ridge Province. The Appalachian Plateaus Province contains streams with the most dilute (less than 30 mg/L dissolved solids) and least dilute (more than 500 mg/L dissolved solids) water in the basin. Coal mining has degraded more miles of streams in the basin than any other land use. Streams that receive coal-mine drainage may be affected by sedimentation, and typically contain high concentrations of sulfate, iron, and manganese. Other major water-quality issues include inadequate domestic sewage treatment, present and historic disposal of industrial wastes, and logging, which results in the addition of sediment, nutrients, and other constituents to the water. One hundred eighteen fish species are reported from the Kanawha River system downstream from Kanawha Falls. Of these, 15 are listed as possible, probable, or known introductions. None of these fish species is endemic to the Kanawha River Basin. The New River system has only 46 native fishes, the lowest ratio of native fishes to drainage area of any river system in the eastern United States, and the second-highest proportion of endemic fish species (eight of 46) of any river system in the eastern United States.

North Carolina, Virginia, West Virginia↗

Instream water use in the United States: water laws and methods for determining flow requirements

Water use generally is divided into two primary classes - offstream use and instream use. In offstream use, sometimes called out-of-stream or diversionary use, water is withdrawn (diverted) from a stream or aquifer and transported to the place of use. Examples are irrigated agriculture, municipal water supply, and industrial use. Each of these offstream uses, which decreases the volume of water available downstream from the point of diversion, is discussed in previous articles in this volume. Instream use, which generally does not diminish the flow downstream from its point of use, and its importance are described in this article. One of the earliest instream uses of water in the United States was to turn the water wheels that powered much of the Nation's industry in the 18th and 19th centuries. Although a small volume of water might have been diverted to a mill near streamside, that water usually was returned to the stream near the point of diversion and, thus, the flow was not diminished downstream from the mill. Over time, the generation of hydroelectric power replaced mill wheels as a means of converting water flow into energy. Since the 1920's, the generation of hydroelectric power increasingly has become a major instream use of water. By 1985, more than 3 billion acre-feet of water (3,050,000 million gallons per day) was used annually for hydropower generation (Solley and others, 1988, p. 45)-enough water to cover the State of Colorado to a depth of 51 feet. Navigation is another instream use with a long history. The Lewis and Clark expedition journals and many of Mark Twain's novels illustrate the extent to which the Nation originally depended on adequate streamfiows for basic transportation. Navigation in the 1980's is still considered to be an instream use; however, it often is based upon a stream system that has been modified greatly through channelization, diking, and construction of dams and locks. The present (1987) inland water navigation system in the conterminous United States consists of about 12,000 miles of maintained waterways, over which about 500 million tons of cargo is carried each year (U.S. Army Corps of Engineers, 1988, p. 16). Although not so widely practiced in recent years, streams have been used to dispose of raw waste products from homes, communities, and factories. This use has been discouraged by law and public policy because of public health concerns and the damage it causes to the environment. Beginning in the mid-1960's, other instream uses gained new prominence in the water-resources arena-the assertion of a legal right to a free-flowing stream for biological, recreational, and esthetic purposes. These uses themselves, however, are not new. Riverine habitat always has produced fish, and the beauty of flowing water always has evoked a strong sense of esthetic appreciation. What is new is the emerging legitimacy and awareness of these noneconomic uses under State and Federal laws and regulations. In the past, environmental uses of flowing water were ignored, for the most part, under a long-standing legal tradition that favored offstream uses and certain instream uses that had a strong economic basis. The history of instream-flow policy debate really concerns those recently recognized types of interim uses. Although the more transitional water uses have been protected by law, the recognition of other in stream uses has resulted in substantial changes in State water laws. Although methods for determining the volume of water needed for most traditional water uses are relatively straight-forward and well-established, methods for determining water requirements for the in stream uses have been developed only recently and are continuing to evolve. Water laws that have favored the more traditional water uses, the inherent nature of conflict between instream and offstream water uses, and the special kinds of technological and philosophical problems posed by the "newer" types of instream uses are described below. Water laws that have been passed to accommodate the more recently recognized instream uses are summarized.

Report↗

Feasibility of using acoustic velocity meters for estimating highly organic suspended-solids concentrations in streams

A field experiment was conducted at the Levee 4 canal site below control structure G-88 in the Everglades agricultural area in northwestern Broward County, Florida, to study the relation of acoustic attenuation to suspended-solids concentrations. Acoustic velocity meter and temperature data were obtained with concurrent water samples analyzed for suspended-solids concentrations. Two separate acoustic velocity meter frequencies were used, 200 and 500 kilohertz, to determine the sensitivity of acoustic attenuation to frequency for the measured suspended-solids concentration range. Suspended-solids concentrations for water samples collected at the Levee 4 canal site from July 1993 to September 1994 ranged from 22 to 1,058 milligrams per liter, and organic content ranged from about 30 to 93 percent. Regression analyses showed that attenuation data from the acoustic velocity meter (automatic gain control) and temperature data alone do not provide enough information to adequately describe the concentrations of suspended solids. However, if velocity is also included as one of the independent variables in the regression model, a satisfactory correlation can be obtained. Thus, it is feasible to use acoustic velocity meter instrumentation to estimate suspended-solids concentrations in streams, even when suspended solids are primarily composed of organic material. Using the most comprehensive data set available for the study (500 kiloherz data), the best fit regression model produces a standard error of 69.7 milligrams per liter, with actual errors ranging from 2 to 128 milligrams per liter. Both acoustic velocity meter transmission frequencies of 200 and 500 hilohertz produced similar results, suggesting that transducers of either frequency could be used to collect attenuation data at the study site. Results indicate that calibration will be required for each acoustic velocity meter system to the unique suspended-solids regime existing at each site. More robust solutions may be defined in streams with suspended solids having lower percentages of organic composition.

Open-File Report↗

Environmental controls of suppressed fall crop productivity in an agrivoltaic solar array

Globally, agrivoltaics (AV) research has revealed how microclimates created by photovoltaic (PV) panels can be leveraged to promote reciprocal benefits for agricultural land use and PV energy generation. Yet, in regions of the United States where emissions reduction laws are likely to lead to greater PV development on croplands, empirical evaluation of such co-location remain under explored. Furthermore, the most common approach to AV in the United States is one that maximizes energy generation and secondarily accommodates for agricultural management, and the controls of crop production in facilities that employ such an approach are underrepresented in the AV literature. Here, we assessed the agronomic and physiological response of two vegetable crops (radish and radicchio) with different carbon allocation patterns (belowground and aboveground, respectively) in an energy focused AV facility during a fall growing season, in New York, United States. We found that a reduction in total irradiance (−24%) within the AV array decreased total biomass in both crop types (46% and 49%), with significant alterations to root-shoot ratios in radish. Reductions in total biomass were not a result of physiological acclimation, indicating that AV crops had similar photosynthetic capacity as control crops; however, the environmental constraints imposed by energy focused AV design (i.e. reduced irradiance) limited C uptake overall. Our findings highlight the need for novel management approaches (e.g. earlier planting of AV fall crops) to help overcome yield penalties incurred by energy focused AV designs.

New York↗

Effects of Surface-Water Diversion and Ground-Water Withdrawal on Streamflow and Habitat, Punaluu Stream, Oahu, Hawaii

The surface- and ground-water resources of the Punaluu area of northeast Oahu, Hawaii, have been and continue to be important for cultural, domestic, agricultural, recreational, and aesthetic purposes. Punaluu Stream flows perennially because rain falls frequently in the area and ground water discharges to the stream. Flow in Punaluu Stream is reduced by the direct diversion of water for off-stream uses and possibly from the withdrawal of ground water near the stream. Punaluu Ditch diverts water from Punaluu Stream near an altitude of 210 feet. During the recent period 1995-2004, discharge in Punaluu Stream that was equaled or exceeded 50 percent of the time (median or Q50 discharge) and discharge that was equaled or exceeded 95 percent of the time (Q95 discharge) measured immediately upstream from the Punaluu Ditch diversion intake, respectively, were 18 and 13 cubic feet per second, whereas the Q50 and Q95 discharges measured immediately downstream from the diversion intake, respectively, were 7.0 and 1.3 cubic feet per second. Thus, near an altitude of 210 feet, diversion of surface water by the Punaluu Ditch caused the Q50 discharge in Punaluu Stream to be reduced to 39 percent of the natural Q50 discharge, and the Q95 discharge was reduced to 10 percent of the natural value. The relative effects of the Punaluu Ditch diversion on flow in Punaluu Stream decreased in a downstream direction, mainly because of the compensating effects of tributary inflows and ditch return flows. At an altitude of 10 feet, the Q50 discharge in Punaluu Stream was 82 percent of the natural Q50 discharge, and the Q95 discharge was 69 percent of the natural value. Changes in streamflow affect the quantity and quality of physical habitat used by native stream fauna. The Physical Habitat Simulation System (PHABSIM) approach was used to evaluate the effects of different diversion scenarios on physical habitat for selected native species in Punaluu Stream. Habitat-suitability criteria developed for streams in northeast Maui, Hawaii, were used to determine the effects of incremental changes in streamflow on physical habitat, in terms of weighted usable area (WUA) in Punaluu Stream. The effects of different diversion conditions on WUA for Neritina granosa and Awaous guamensis were evaluated by determining the average number of days per year for which WUA values are less than a specified reference value (during periods when discharge is less than or equal to the median natural discharge). For recent diverted conditions (1995-2004), the average number of days per year that WUA values are less than 50 or 75 percent of the WUA value at median natural discharge generally (1) decreases in a downstream direction, reflecting the effects of tributary inflows and ditch return flows, (2) is less than the corresponding number of days for constant diversion rates greater than about 4-5 cubic feet per second at a stream altitude of 10 feet, and (3) is greater than the corresponding number of days for a constant diversion rate of 10 cubic feet per second at stream altitudes of 40, 100, and 140 feet. The number of days that WUA values are less than 75 percent of the WUA value at median natural discharge generally increases substantially for constant diversion rates exceeding about 4-5 cubic feet per second. At stream altitudes of 10, 40, 100, and 200 feet and for constant diversion rates of up to 4 cubic feet per second, WUA values are less than 75 percent of the WUA value at median natural discharge for fewer than 13 days per year. At stream altitudes above 40 feet and for a constant diversion rate of 10 cubic feet per second, WUA values are less than 75 percent of the WUA value at median natural discharge for 131 to 183 days per year. Stream temperature is a factor that potentially could affect the abundance and distribution of native aquatic species. Measured stream temperatures immediately upstream and downstream from the diversion intake did not indicat

Scientific Investigations Report↗

Water quality and nutrient loading in the Klamath River between Keno, Oregon and Seiad Valley, CA from 1996-1998

A water quality study was performed in the mainstem Klamath River from Keno, Oregon to Seiad Valley, California during 1996 through 1998. Four sites within the study area were continuously monitored using multiparameter recorders. Water quality sampling was also performed at these four locations in 1996 and 1997. Additional water quality sampling sites were added in 1998 for a total of 8 locations between Keno and Seiad. Temperature ranged from near zero &deg;C to >25 &deg;C with cooler temperatures in early spring and fall, and maximum temperatures occurring in july and August of each year. Dissolved oxygen concentration ranged from near zero mg/L to >13 mg/L with highest DO occurring in early spring and fall and lowest DO occurring in mid-summer. Air temperature was generally highly correlated with water temperature with r values ranging from 0.8 to 0.9 during the study period from 1996-1998. Water temperature in the study area exceeded chronic (>16&deg;C) and acute (>22&deg;C) criteria for salmonids during the summer months. Although chronic DO &laquo;7 mg/L) criteria were exceeded throughout most of the study area during the summer, in the free-flowing river below Iron Gate Dam the acute DO &laquo;5.5 mg/L) criteria were not exceeded. Nonpoint source pollution in the form of agricultural return flows, industrial, or sewage effluent entering the stream may have resulted in higher ammonia and total organic nitrogen concentrations at the upstream locations in the Klamath River study area (Keno and J.C. Boyle Powerplant). Nitrification of ammonia and organic nitrogen seemed to result in higher concentrations of nitrate in the downstream Klamath River (Iron Gate Dam). Total phosphorus concentration stayed relatively stable through the reservoirs in the study area, but decreased in the downstream direction between Iron Gate Dam and Seiad. Ortho-phosphorus concentrations increased longitudinally through the reservoirs, then decreased in the downstream direction between Iron Gate Dam and Seiad. An increase in ortho-phosphorus concentration can indicate internal cycling occurring in the reservoirs as well as photosynthesis. On an annual basis total phosphorus loading increased longitudinally from up- to downstream between Keno and Seiad. The increase was statistically significant (p =.03) indicating that the reservoirs in series in the Klamath River study area do not function as a nutrient sink. However, during the summer there was no statistically significant difference in total P loading when Keno, Iron Gate and Seia~ locations were compared, therefore, the reservoirs may act as a nutrient sink seasonally. The Klamath River study locations were generally nitrogen limited, although at Keno, a regUlar change from N limitation to P limitation occurred during the fall of all three years of the study. When the Klamath River annual nutrient loading values are compared to other rivers in the vicinity, the Carson, Truckee, and Long Tom Rivers also appear to be nutrient enriched. The Carson and South Yamhill Rivers seem to be N limited systems and the Wood, Long Tom, Snake and Truckee Rivers seem to be P limited systems. Implementing management strategies for reservoir operations to improve water quality and reduce nutrient concentration or loading in the Klamath River study area to benefit anadromous fisheries may be difficult and expensive. However, improving the thermal regime in spring to benefit YOY salmonids may be possible as is short-term relief in late summer for oversummering species. Decreases in nutrient concentration or loading accomplished through best management practices in the water shed may allow general protection of water resources in the Klamath Basin for future needs.

California, Oregon↗

Variability of discharge, nutrients, and Escherichia coli from tile drains in a small agricultural stream, a synoptic study in the School Branch watershed, Hendricks County, Indiana

The U.S. Geological Survey, in cooperation with the Indiana Department of Environmental Management, sampled a 1-mile stream reach of School Branch in Hendricks County, Indiana. Sampling consisted of 24 tile drain sites and surface-water sites both upstream and downstream from the tile drains. This study intended to (1) assess the variability of discharge, nutrients, and Escherichia coli ( E. coli ) among tiles within a stream reach in variable conditions; (2) define how the tiles affect the stream hydrology and water quality; and (3) determine potential management implications. Samples were collected on three dates—round 1 on June 12, 2018, after fertilizer was applied; round 2 on September 11, 2018, in fall harvest conditions; and round 3 on April 16, 2019, before fertilizer was applied—to encompass differing precipitation events, multiple seasons, and field conditions. Sites were sampled for water-quality parameters, dissolved and total nutrients (ammonia, nitrate plus nitrite, total nitrogen, orthophosphate, and total phosphorus), E. coli , and instantaneous discharge. Instantaneous nutrient loads were calculated from tiles and at the upstream and downstream surface-water sites. Nutrient concentrations and instantaneous loads varied depending on the tile and the sampling date. Tiles contributed between 26.5 and 66.0 percent of increased discharge between the surface-water sites. Tiles contributed between 34.7 and 87.4 percent and between 19.7 and 65.9 percent of the increased total nitrogen and phosphorus loads, respectively, for the downstream site relative to the upstream site. Most of the total nitrogen and total phosphorus from the tiles was in the dissolved forms (nitrate plus nitrite and orthophosphate). Surface-water samples had a nitrate plus nitrite to total nitrogen ratio of 71 to 93 percent, with an average of 82 percent; tile samples ranged from 44 to nearly 100 percent, with an average of 91 percent dissolved nitrogen. Surface-water samples had an orthophosphate to total phosphorus ratio of 30 to 65 percent, with an average of 53 percent; tile samples ranged from 32 to nearly 100 percent, with an average of 85 percent dissolved phosphorus. E. coli was detected in all but 5.79 percent of tile and surface-water samples. The E. coli results indicated the possibility of human or animal fecal contamination by way of septic systems leaking or directly linked to the tiles draining into the study area. Consequently, five microbial source tracking samples were collected from the upstream and downstream surface-water sites between August 3, 2021, and May 18, 2022. Human, canine, ruminant, and avian sources of fecal contamination were evaluated. The microbial source tracking samples indicated that human-specific sources are likely consistently contributing to elevated fecal contamination. Differences in discharge, nutrient concentrations, nutrient loads, and E. coli concentrations show that many factors affect how tiles alter the hydrology and water quality of receiving waters. The timing and severity of precipitation events, season, and the antecedent conditions of the field or watershed before sampling can affect the results. Tiles with the largest discharge rate had the most potential effect on the water quality and quantity of the stream. Targeting high-flowing tiles may affect efforts to improve overall water quality.

Indiana↗

Bird productivity and nest predation in agricultural grasslands

Effective conservation strategies for grassland birds in agricultural landscapes require understanding how nesting success varies among different grassland habitats. A key component to this is identifying nest predators and how these predators vary by habitat. We quantified nesting activity of obligate grassland birds in three habitats [remnant prairie, cool-season grass Conservation Reserve Program (CRP) fields, and pastures) in southwest Wisconsin, 2002-2004. We determined nest predators using video cameras and examined predator activity using track stations. Bobolink ( Dolichonyx oryzivorus ) and Henslow's Sparrow ( Ammodramus henslowii ) nested primarily in CRP fields, and Grasshopper Sparrow (A. savannarum) in remnant prairies. Eastern Meadowlark ( Sturnella magna ) nested evenly across all three habitats. Daily nest survival rate for Eastern Meadowlark varied by nesting stage alone. Daily nest survival rate for Grasshopper Sparrow varied by nest vegetation and distance to the nearest woody edge; nest survival was higher near woody edges. In CRP fields, most predators were grassland-associated, primarily thirteen-lined ground squirrels ( Ictidomys tridecemlineatus ). In pastures, one-third of the nest predators were grassland-associated (primarily thirteen-lined ground squirrels) and 56% were associated with woody habitats (primarily raccoons, Procyon lotor). Raccoon activity was greatest around pastures and lowest around prairies; regardless of habitat, raccoon activity along woody edges was twice that along non-woody edges. Thirteen-lined ground squirrel activity was greater along prairie edges than pastures and was greater along nonwoody edges compared to woody edges. In CRP fields, raccoon activity was greater along edges compared to the interiors; for ground squirrels these relationships were reversed. Using video camera technology to identify nest predators was indispensable in furthering our understanding of the grassland system. The challenge is to use that knowledge to develop management actions for both birds and predators.

Studies in Avian Biology↗

Age and quality of ground water and sources of nitrogen in the surficial aquifers in Pumpkin Creek Valley, western Nebraska, 2000

Ground water is the source of drinking water for the residents of Pumpkin Creek Valley, western Nebraska. In this largely agricultural area, shallow aquifers potentially are susceptible to nitrate contamination. During the last 10 years, ground-water levels in the North Platte Natural Resources District have declined and contamination has become a major problem for the district. In 2000, the U.S. Geological Survey and the North Platte Natural Resources District began a cooperative study to determine the age and quality of the ground water and the sources of nitrogen in the aquifers in Pumpkin Creek Valley. Water samples were collected from 8 surface-water sites, 2 springs, and 88 ground-water sites during May, July, and August 2000. These samples were analyzed for physical properties, nutrients or nitrate, and hydrogen and oxygen isotopes. In addition, a subset of samples was analyzed for any combination of chlorofluorocarbons, tritium, tritium/helium, sulfur-hexafluoride, carbon-14, and nitrogen-15. The apparent age of ground water in the alluvial aquifer typically varied from about 1980 to modern, whereas ground water in the fractured Brule Formation had a median value in the 1970s. The Brule Formation typically contained ground water that ranged from the 1940s to the 1990s, but low-yield wells had apparent ages of 5,000 to 10,000 years before present. Data for oxygen-18 and deuterium indicated that lake-water samples showed the greatest effects from evaporation. Ground-water data showed no substantial evaporative effects and some ground water became isotopically heavier as the water moved downgradient. In addition, the physical and chemical ground-water data indicate that Pumpkin Creek is a gaining stream because little, if any, of its water is lost to the ground-water system. The water-quality type changed from a sodium calcium bicarbonate type near Pumpkin Creek's headwaters to a calcium sodium bicarbonate type near its mouth. Nitrate concentrations were largest in the alluvial system (median = 5 mg/L) and smallest in the surface-water system (median = 1 mg/L). Most nitrate concentrations exceeding the U.S. Environmental Protection Agency maximum contaminant level for drinking water of 10 mg/L as nitrogen were adjacent to irrigated fields and in areas where alluvial sediments are less than 50 ft thick. Sources of nitrogen in the ground water of the study area included naturally occurring nitrogen, commercial fertilizer, and animal waste. Based on nitrate concentration and delta nitrogen-15, the nitrogen in 65 percent of the water samples appears to have originated from a mixture of commercial fertilizers and animal waste. Some of the smallest nitrate concentrations in the ground-water samples contained some of the largest delta nitrogen-15 values (greater than 10 per mil), which suggests animal waste as the likely source. Commercial fertilizers were the likely source of most of the nitrogen in water samples with nitrate concentrations that exceeded 10 mg/L. The source of the nitrogen in water samples with nitrate concentrations exceeding 10 mg/L, but with delta nitrogen-15 values close to 10 per mil, could not be determined.

Nebraska↗