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At least 1,621 records · Page 90Linked to original sources

Aquifer characteristics, water availability, and water quality of the Quaternary aquifer, Osage County, northeastern Oklahoma, 2001-2002

Additional sources of water are needed on the Osage Reservation for future growth and development. The Quaternary aquifer along the Arkansas River in the Osage Reservation may represent a substantial water resource, but limited amounts of hydrogeologic data were available for the aquifer. The study area is about 116 square miles of the Quaternary aquifer in the Arkansas River valley and the nearby upland areas along the Osage Reservation. The study area included the Arkansas River reach downstream from Kaw Lake near Ponca City, Oklahoma to upstream from Keystone Lake near Cleveland, Oklahoma. Electrical conductivity logs were produced for 103 test holes. Water levels were determined for 49 test holes, and 105 water samples were collected for water-quality field analyses at 46 test holes. Water-quality data included field measurements of specific conductance, pH, water temperature, dissolved oxygen, and nitrate (nitrite plus nitrate as nitrogen). Sediment cores were extracted from 20 of the 103 test holes. The Quaternary aquifer consists of alluvial and terrace deposits of sand, silt, clay, and gravel. The measured thickness of the alluvium ranged from 13.7 to 49.8 feet. The measured thickness of the terrace sediments ranged from 7 to 93.8 feet. The saturated thickness of all sediments ranged from 0 to 38.2 feet with a median of 24.8 feet. The weighted-mean grain size for cores from the alluvium ranged from 3.69 to 0.64 f, (0.08- 0.64 millimeter), and ranged from 4.02 to 2.01 f (0.06-0.25 millimeter) for the cores from terrace deposits. The mean of the weighted-mean grain sizes for cores from the alluvium was 1.67 f (0.31 millimeter), and the terrace deposits was 2.73 f (0.15 millimeter). The hydraulic conductivity calculated from grain size of the alluvium ranged from 2.9 to 6,000 feet per day and of the terrace deposits ranged from 2.9 to 430 feet per day. The calculated transmissivity of the alluvium ranged from 2,000 to 26,000 feet squared per day with a median of 5,100 feet squared per day. Water in storage in the alluvium was estimated to be approximately 200,000 acre-feet. The amount of water annually recharging the aquifer was estimated to be approximately 4,800 acre-feet. Specific conductance for all water samples ranged from 161 to 6,650 microsiemens per centimeter. Median specific conductance for the alluvium was 683 microsiemens per centimeter and for the terrace deposits was 263 microsiemens per centimeter. Dissolved-solids concentrations, estimated from specific conductance, for water samples from the aquifer ranged from 88 to 3,658 milligrams per liter. Estimated median dissolved- solids concentration for the alluvium was 376 milligrams per liter and for the terrace deposits was 145 milligrams per liter. More than half of the samples from the Quaternary aquifer were estimated to contain less than 500 milligrams per liter dissolved solids. Field-screened nitrate concentrations for the sampling in December 2001-August 2002 ranged from 0 to 15 milligrams per liter. The field-screened nitrate concentrations for the second sampling in September 2002 were less than corresponding laboratory reported values.

Water-Resources Investigations Report↗

Variability of pesticide detections and concentrations in field replicate water samples collected for the National Water-Quality Assessment Program, 1992-97

Field replicate water samples (“field replicates”) collected for the U.S. Geological Survey National Water-Quality Assessment (NAWQA) Program during 1992 to 1997 were used to assess the variability of pesticide detections and concentrations in environmental water samples collected from the surface-and ground-water-quality networks of the NAWQA Program. Field replicates are two or more identically collected, processed, and analyzed environmental water samples that are used to assess the overall variability of field and laboratory procedures. Variability is the degree of random error in independent measurements of the same quantity and is the opposite of precision—the degree of mutual agreement. Information on variability can be used to estimate the reproducibility of individual measurements, the concentration needed to be assured of exceeding a water-quality standard, and the likelihood that two measurements of water quality are different. Variability of pesticide detections was assessed by calculating the mean percentage detection of a pesticide and the percentage of inconsistent replicate sets. Variability of pesticide concentrations was assessed by pooling estimates of the standard deviation and relative standard deviation in replicate sets. Variability of pesticide detections and concentrations was a function of concentration, and estimates of variability were developed for discrete ranges of concentration. Reliability of estimates of variability was assessed by calculating 90-percent upper confidence bounds for the percentage of inconsistent replicate sets and for the pooled estimates. The variability of detection for most pesticides is high at concentrations less than the minimum reporting level, but the variability of detection decreases dramatically at higher concentrations. In view of the highly diverse sources of water submitted as field replicates for the NAWQA Program and the generally low concentrations (concentrations in 79 percent of replicate sets were less than 0.1 microgram per liter) of pesticides in most replicates, inconsistent detections in replicate sets likely were caused by variability in the analytical method and by water-matrix interferences (or other loss processes) that result in false-negative errors. Consequently, estimates of the frequency of detection of pesticides in environmental water samples collected for the NAWQA Program probably are biased low because of false-negative errors at concentrations near the minimum reporting level. Correlation analysis indicates that for most pesticides and concentrations, pooled estimates of relative standard deviation rather than pooled estimates of standard deviation should be used to estimate variability because pooled estimates of relative standard deviation are less affected by heteroscedasticity. The 2 Variability of Pesticide Detections and Concentrations in Field Replicate Water Samples, 1992–97 median pooled relative standard deviation was calculated for all pesticides to summarize the typical variability for pesticide data collected for the NAWQA Program. The median pooled relative standard deviation was 15 percent at concentrations less than 0.01 micrograms per liter (µg/L), 13 percent at concentrations near 0.01 µg/L, 12 percent at concentrations near 0.1 µg/L, 7.9 percent at concentrations near 1 µg/L, and 2.7 percent at concentrations greater than 5 µg/L. Pooled estimates of standard deviation or relative standard deviation presented in this report are larger than estimates based on averages, medians, smooths, or regression of the individual measurements of standard deviation or relative standard deviation from field replicates. Pooled estimates, however, are the preferred method for characterizing variability because they provide unbiased estimates of the variability of the population. Assessments of variability based on standard deviation (rather than variance) underestimate the true variability of the population. Because pooled estimates of variability are larger than estimates based on other approaches, users of estimates of variability must be cognizant of the approach used to obtain the estimate and must use caution in the comparison of estimates based on different approaches.

Water-Resources Investigations Report↗

Computer-model analysis of the use of Delaware River water to supplement water from the Potomac-Raritan-Magothy aquifer system in southern New Jersey

A computer model of the Potomac-Raritan-Magothy aquifer system was used to simulate the effects of supplementing ground water with water from the Delaware River. Replacement of ground water pumpage with surface water in a 150-square-mile area near Camden, N.J., was simulated. Artificial recharge of surface water was also simulated in the same area. A series of nine simulations was made. The simulations include the period 1974 to 2000. Two projections for water use were used. Also, in some of the model simulations a line of injection wells was simulated to prevent movement of saline water into pumping centers. The simulations indicate that heads will be as much as 100 feet higher in the year 2000 near the 150-square-mile area than that if ony ground water would be used without supplement of surface water. In the model simulations, heads recover upon application of surface water, but start declining again within 2 years. The rate of head decline after suface-water application is slower than before the application.

New Jersey↗

Effects of the proposed Prosperity Reservoir on ground water and water quality in lower Center Creek basin, Missouri

Effects of the proposed Prosperity Reservoir on ground water and water quality in lower Center Creek basin depend partly on the effectiveness of Grove Creek as a hydrologic boundary between the reservoir site and the Oronogo-Duenweg mining belt. Results of two dye traces indicate that Grove Creek probably is not an effective boundary. Therefore, higher water levels near the reservoir may cause more ground water to move into the mining belt and cause a greater discharge of zinc-laden mine water into Center Creek. Ground-water-level measurements and seepage runs on Center Creek indicate a relationship between ground-water levels, mine-water discharge and seepage, and base flow in Center Creek. From March to October 1979, ground-water levels generally decreased from 5 to 20 feet at higher elevations (recharge areas) and from 1 to 3 feet near Center Creek (discharge area); total mine water discharged to the surface before entering Center Creek decreased from 5.4 to 2.2 cubic feet per second; mine-water seepage directly to Center Creek decreased from an estimated 1.9 to 1.1 cubic feet per second; and the discharge of Center Creek near Carterville decreased from 184 to 42 cubic feet per second. Fertilizer industry wastes discharged into Grove Creek resulted in significant increases of nitrogen and phosphorus in lower Center Creek.

Missouri↗

Effects of storm-water runoff on water quality of the Edwards Aquifer near Austin, Texas

Analyses of samples collected from Barton Springs at approximately weekly Intervals and from Barton Creek and five wells in the Austin area during selected storm-runoff periods generally show that recharge during storm runoff resulted in significant temporal and area! variations in the quality of ground water in the recharge zone of the Edwards aquifer. Recharge during storm runoff resulted in significant increases of bacterial densities in the ground water. Densities of fecal coliform bacteria in samples collected from Barton Springs, the major point of ground-water discharge, ranged from less than 1 colony per 100 milliliters during dry weather in November 1981 and January and August 1982 to 6,100 colonies per 100 milliliters during a storm in May 1982. Densities of fecal streptococcal bacteria ranged from 1 colony per 100 miniliters during dry weather in December 1981 to 11,000 colonies per 100 miniliters during a storm in May 1982. Recharge during storm runoff resulted in significant decreases in the specific conductance and the concentration of total nitrate nitrogen in the ground water. Specific-conductance values of samples from Barton Springs ranged from 438 micromhos per centimeter at 25° Celsius after a storm in October 1981 to 682 micromhos after a relatively long period of deficient rainfall in September 1982. The specific-conductance values and, thus, the mineralization of the ground water in the recharge zone generally were inversely related to the quantity of recharge. Nitrate nitrogen was the most prevalent form of nitrogen in the ground water. Concentrations of total nitrate nitrogen in samples from Barton Springs ranged from 0.51 milligram per liter after a storm in October 1981 to 1.6 milligrams per liter during dry weather in February and September 1982. Although the values of these and other properties or constituents in ground water varied temporally and areally, available data indicate that the values of most of the major and minor elements in ground water in the recharge zone of the Edwards aquifer were significantly less than the primary maximum or secondary maximum contaminant levels set by the U.S. Environmental Protection Agency for public water systems. Bacteriological data for Barton Springs and selected wells indicate that the ground water in the aquifer is susceptible to bacterial pollution, especially during storm runoff. The water may require disinfection if used for drinking or culinary purposes.

Water-Resources Investigations Report↗

Water-quality conditions and an evaluation of ground- and surface-water sampling programs in the Livermore-Amador Valley, California

A program to monitor the ground- and surface water quality in the Livermore-Amador Valley has been operated since 1976. As of 1982, this monitoring network consisted of approximately 130 wells, about 100 of which were constructed specifically for this program, and 9 surface water stations. Increased demand on the groundwater for municipal and industrial water supply in the past has caused a decline in water levels and a gradual buildup of salts from natural surface-water recharge and land disposal of treated wastewater from waste treatment plants. Results of this study identify the salt buildup to be the major problem with the groundwater quality. Established water quality objectives for dissolved solids are exceeded in 52 of 130 wells. Concentrations of dissolved nitrate are also in excess of basin objectives and health standards. Water quality in both surface and groundwater is highly variable areally. Magnesium to calcium magnesium bicarbonate groundwater are found in the areas where most of the high volume municipal wells are located. Large areas of sodium bicarbonate water occur in the northern part of the valley. Except for two stations on Arroyo Las Positas which has sodium chloride water, surface water is mixed-cation bicarbonate water. (USGS)

California↗

Water quality of Lake Tuscaloosa and streamflow and water quality of selected tributaries to Lake Tuscaloosa, Alabama, 1982-86

Lake Tuscaloosa, created in 1969 by the impoundment of North River, provides the primary water supply for Tuscaloosa, Alabama , and surrounding areas. This report describes the percent contribution of major tributaries to the mean inflow to the lake; water quality; and changes in water quality in the lake and selected tributaries. During base flow, about 60% of the total flow into Lake Tuscaloosa is contributed by Binion and Carroll Creeks, which drain only 22% of the Lake Tuscaloosa basin. Binion and Carroll Creek basins are underlain primarily by sand and gravel deposits of the Coker Formation. Mean inflow to the lake was 1,150 cu ft/sec during 1983, a wet year, and 450 cu ft/sec during 1985, a relatively dry year. More than 80% of the total inflow during both years was contributed by North River and Binion, Cripple, and Carroll Creeks. About 59% was contributed by North River during those years. Except for pH, sulfate, and dissolved and total recoverable iron and manganese, the water quality of the tributaries is generally within drinking water limits and acceptable for most uses. The water quality of Lake Tuscaloosa is generally within drinking water limits and acceptable for most uses. The maximum and median concentrations of sulfate increased every year at the dam from 1979 to 1985 (7.2 to 18 mg/L and 6.2 to 14 mg/L, respectively). The dissolved solids concentrations for water at the dam have varied (1979-86) from 27 to 43 mg/L; the sulfate, 5.2 to 18 mg/L; and the dissolved iron, 10 to 250 micrograms/L--all within the recommended drinking water limits. However, concentrations of dissolved manganese and total recoverable iron and manganese at the dam commonly exceeded the recommended drinking water limits. In November 1985, after the summer warmup and increase in biological activity, the water quality at five depth profiles sites on Lake Tuscaloosa was acceptable for most uses, generally. However, a dissolved oxygen concentration of 1 mg/L or less was observed within 5 to 10 ft of the bottom for several depth profiles. At depths > 35 to 40 ft (out of a total depth of about 50 to 100 ft) the dissolved oxygen concentration was < 5 mg/L at several sites. By mid-January 1986, the temperature and dissolved oxygen depth profiles were virtually constant from top to bottom of the lake at all five sites; this indicated that lake turnover was complete. However, significant variation existed in pH depth profiles. (Author 's abstract)

Water-Resources Investigations Report↗

Simulation of effects of ground-water development on water-levels in glacial-drift aquifers in the Brooten-Belgrade area, west-central Minnesota

Ground-water flow in the confined- and unconfined-drift aquifers in the Brooten-Belgrade area of west-central Minnesota was simulated with a three-dimensional finite-difference ground-water-flow model. Model results indicate that about 96 percent of the total inflow to the modeled area is from precipitation. Discounting evapotranspiration, 63 percent of the total outflow is ground-water discharge to the East Branch Chippewa and North Fork Crow Rivers, and 34 percent is ground-water pumpage. The model was used to simulate the steady-state effects of below-normal precipitation (drought) and hypothetical increases in ground-water development. Model results indicate that reduced recharge and increased pumping during a hypothetical 3-year extended drought would lower regional water levels from 2 to 5 feet in each aquifer and as much as 20 feet in the lowermost aquifer zone; ground-water discharge to the East Branch Chippewa and North Fork Crow Rivers would be reduced by 38 percent. The addition of 10 to 20 hypothetical wells in confined aquifers, pumping 123 to 246 million gallons per year, would result in regional water-level declines of 0.1 to 0.5 feet. Simulated water-level declines in wells completed in the lower part of the system would be as much as 5.0 feet as a result of pumping 246 million gallons per year from 20 hypothetical wells. Water-level declines in overlying and underlying aquifers would range from 0.4 to 2.8 feet. Ground-water discharge to the East Branch Chippewa and North Fork Crow Rivers would be unaffected by the pumpage.

Minnesota↗

Selected water-quality characteristics and flow of ground water in the San Luis basin, including the Conejos River subbasin, Colorado and New Mexico

Chemical analyses of water from 99 wells and 19 springs in the San Luis basin in Colorado and New Mexico were evaluated to determine selected water quality characteristics as an aid in understanding the flow of groundwater in the basin. The evaluation shows that the distribution of chemical water types in the basin is consistent with chemical changes to be expected along flow paths in rocks typical of those in the basin. The San Luis basin area is underlain by a surficial (< 100-ft-thick) unconfined aquifer and, in turn, by a confining bed and a deeper confined aquifer. Previous studies have indicated that the groundwater system is recharged around the edges of the basin and that groundwater then moves toward discharge areas in the topographically closed part of the basin and along principal streams. The evaluation of water quality data showed that groundwater at the perimeter of the San Luis basin is primarily a calcium bicarbonate type, which is typical in recharge areas. Groundwater near the center of the basin is primarily a sodium bicarbonate type, which is typical of groundwater in downgradient areas. The change in principal cation from calcium to sodium indicates chemical evolution of the water along the groundwater flow path and supports previously developed concepts of groundwater movement in the basin. The exchange of calcium for sodium along the flow path also is assumed to occur in the Conejos River subbasin. Upgradient wells yield calcium bicarbonate type water, whereas downgradient wells yield sodium bicarbonate type water. However, an exception to this relation is found at McIntire Spring, which yields calcium bicarbonate type water from a downgradient location. The source of water discharging from the spring may be the confined aquifer, with hydraulic connection along the Manassa fault. The concentration of dissolved solids in water from both the unconfined and confined aquifers increases downgradient. The increase is dramatic in the closed basin, ranging from < 500 mg/L to > 30 ,000 mg/L. In this area, the normal increase in concentration by dissolution of minerals along the flow path is exceeded by the increase due to evapotranspiration from the shallow water table. (Lantz-PTT)

Water-Resources Investigations Report↗

Ground-water hydrology and the effects of vertical leakage and leachate migration on ground-water quality near the Shelby County landfill, Memphis, Tennessee

An investigation of potential leakage of leachate from the Shelby County landfill near Memphis, West Tennessee, was conducted during 1986-87. The migration of leachate from the landfill to the shallow alluvial aquifer system and the potential leakage to the deeper confined Memphis aquifer of Tertiary age were investigated. A network of observation wells was drilled to determine water levels and aquifer properties in the shallow and deep aquifers as well as in the confining layer. Water samples were collected to define potential leachate occurrence. A depression in the water table within the shallow alluvial aquifer was defined from the water-level data. Drawdowns within the cone of depression are as much as 14 feet lower than the adjoining Wolf River. Recharge from the river and leachate from the landfill moves toward the depression. The presence of leachate within the shallow aquifer was confirmed from determinations of dissolved solids and dissolved chloride concentrations and comparisons with areas away from the aflected zone. Leakage from the water-table aquifer to the Memphis aquifer was confirmed from chemical analyses and hydraulic-head data. Dissolved-solids concentrations in water samples from the upper Memphis aquifer near the landfill are higher than in samples from the Memphis aquifer in unaffected areas. Tritium activities in water samples from the upper Memphis aquifer were as high as 34 pico-Curies per liter indicating recent recharge to the Memphis aquifer. The presence of synthetic organic compounds and elevated concentrations of dissolved solids, chloride, and trace metals indicate the leachate has aflected water quality in the alluvial aquifer. Vertical migration of ground water could transmit leachate down to the Memphis aquifer. Although water-quality data indicate that water is leaking from the alluvial aquifer to the Memphis aquifer, most of the data do not indicate the occurrence of leachate in the Memphis aquifer. Chemical data from one well in the Memphis aquifer near the landfill indicates a slightly elevated dissolved-chloride concentration, but the data are limited.

Tennessee↗

Method for predicting water demand for crop uses in New Jersey in 1990, 2000, 2010, and 2020, and for estimating water use for livestock and selected sectors of the food-processing industry in New Jersey in 1987

A method was developed to predict water demand for crop uses in New Jersey. A separate method was developed to estimate water use for livestock and selected sectors of the food-processing industry in 1987. Predictions of water demand for field- grown crops in New Jersey were made for 1990, 2000, 2010, and 2020 under three climatological scenarios: (1) wet year, (2) average year, and (3) drought year. These estimates ranged from 4.10 times 10 to the 9th power to 16.82 times 10 to the 9th power gal (gallons). Irrigation amounts calculated for the three climatological scenarios by using a daily water-balance model were multiplied by predicted numbers of irrigated acreage. Irrigated acreage was predicted from historical crop-irrigation data and from predictions of harvested acreage produced by using a statistical model relating population to harvested acreage. Predictions of water demand for cranberries and container-grown nursery crops also were made for 1990, 2000, 2010, and 2020. Predictions of water demand under the three climatological scenarios were made for container- grown nursery crops, but not for cranberries, because water demand for cranberries varies little in response to climatological factors. Water demand for cranberries was predicted to remain constant at 4.43 times 10 to the 9th power gal through the year 2020. Predictions of water demand for container-grown nursery crops ranged from 1.89 times 10 to the 9th power to 3.63 times 10 to the 9th power gal. Water-use for livestock in 1987 was estimated to be 0.78 times 10 to the 9th power gal, and water use for selected sectors of the food-processing industry was estimated to be 3.75 times 10 to the 9th power gal.

Water-Resources Investigations Report↗

Geologic setting and water quality of selected basins in the active coal-mining areas of Ohio, 1989-91, with a summary of water quality for 1985-91

This report presents streamwater- and ground-water-quality data collected to characterize the baseline water quality for 21 drainage basins in the coal-mining region of eastern Ohio. The study area is mostly within the unglaciated part of eastern Ohio along the western edge of the Appalachian Plateaus Physiographic Province. The data collected from 1989-91 and presented in this report represent the third and final phase of a 7-year study to assess baseline water quality in Ohio's coal region during 1985-1991. During 1989-91, 246 samples from 41 streamwater sites were collected periodically from a long-term site network. Ranges and medians of measurements made at the long-term streamwater sites were following: specific conductance, 270 to 5,170 and 792 microsiemens per centimeter at 25 degrees Celsius; pH, 2.7 to 9.1 and 7.8; alkalinity, 1 to 391 and 116 mg/L (milligrams per liter). Ranges and medians of laboratory analyses of the same samples were the following: dissolved sulfate, 13 to 2,100 and 200 mg/L; dissolved aluminum, <10 to 17,000 and 300 ? /L (micrograms per liter); dissolved iron, <10 to 53,000 and 60 ? /L; and dissolved manganese, <10 to 17,000 and 295 ? /L. The ranges for concentrations of total recoverable aluminum, iron, and manganese were similar to the ranges of concentrations found for dissolved constituents. Medians of total recoverable aluminum and iron were about 10 times greater than the medians of dissolved aluminum and iron. During 1989-91, once-only sample collections were done at 45 streamwater sites in nine basins chosen for synoptic sampling. At several sites in the Middle Hocking River basin and Leading Creek basin, water had low pH and high concentrations of dissolved aluminum, iron and manganese. These water-quality characteristics are commonly associated with ace mine drainage. Throughout the entire 7-year study (1985-91), medians for most constituents at the long-term streamwater-sampling sites were fairly consistent, despite the geographic diversity of the study area. Waters from several long-term sites, including several sites in Moxahala Creek and Middle Hocking River basins, had low pH and high concentrations of several constituents, including dissolved sulfate, iron, aluminum, and manganese; this combinations characteristics is indicitive of acid drainage from surface-mining operations. At many of the streamwater sites where concentration of these constituents were high, pH values in the neutral or alkaline range were indicative of stream buffering by carbonate rock or restoration of mined lands in the drainage system. The basins with sites in this category include Yellow and Cross Creeks and Wheeling Creek basins. Water quality at other sites showed little or no effects from surface mining. Ground-water samples collected during the last phase of the study (1989-91) were mostly from unconsolidated aquifers. The waters were generally hard to very hard and calcium bicarbonate in type. During the entire 7-year study period, medians of pH in ground-water samples varied little, and most values were in the alkaline range. Except for a few sites where concentrations of dissolved sulfate exceeded 250 mg/L and concentrations of total recoverable and dissolved iron and manganese exceeded 1,000 ? /L, the quality of ground water at the wells sampled in the study area showed little effect from coal mining.

Water-Resources Investigations Report↗

Water-quality assessment of the South Platte River basin, Colorado, Nebraska, and Wyoming: Analysis of available nutrient, suspended-sediment, and pesticide data, water years 1980-92

Nutrient, suspended-sediment, and pesticide data from surface- and ground-water sites in the South Platte River Basin for water years 1980-92 were compiled, screened, and interpreted. This activity is part of the U.S. Geological Survey's National Water Quality Assessment (NAWQA) program. The analysis of existing water-quality data provides a perspective on recent water-quality conditions in the South Platte River Basin, evaluations of the strengths and weaknesses of available data, and implications for water-quality issues and future study priorities and design. Most data analyzed were collected by the U.S. Geological Survey. Additionally, data from three local agencies were used in the analysis. A total of 3,484 samples from 54 surface-water sites and 107 wells were used in the analysis. The areal distribution of nutrient samples collected from surface-water and ground-water sites were sufficient in number and areal distribution to describe current water- quality conditions throughout the basin, but data were not sufficient to analyze factors and processes affecting water quality. However, suspended- sediment and pesticide data were sparse in their distribution with respect to time, space, and flow regime, and were sufficient only to provide a preliminary description of conditions in the basin.

Colorado, Nebraska, Wyoming↗

Water resources and potential effects of ground-water development in Maggie, Marys, and Susie Creek basins, Elko and Eureka counties, Nevada

The basins of Maggie, Marys, and Susie Creeks in northeastern Nevada are along the Carline trend, an area of large, low-grade gold deposits. Pumping of ground water, mostly for pit dewatering at one of the mines, will reach maximum rates of about 70,000 acre-ft/yr (acre-feet per year) around the year 2000. This pumping is expected to affect ground-water levels, streamflow, and possibly the flow of Carlin spring, which is the water supply for the town of Carlin, Nev. Ground water in the upper Maggie Creek Basin moves from recharge areas in mountain ranges toward the basin axis and discharges as evapotranspiration and as inflow to the stream channel. Ground water in the lower Maggie, Marys, and Susie Creek Basins moves southward from recharge areas in mountain ranges and along the channel of lower Maggie Creek to the discharge area along the Humboldt River. Ground-water underflow between basins is through permeable bedrock of Schroeder Mountain from the upper Maggie Creek Basin to the lower Maggie Creek Basin and through permeable volcanic rocks from lower Maggie Creek to Carlin spring in the Marys Creek Basin. The only source of water to the combined area of the three basins is an estimated 420,000 acre-ft/yr of precipitation. Water leaves as runoff (38,000 acre-ft/yr) and evapotranspiration of soil moisture and ground water (380,000 acre-ft/yr). A small part of annual precipitation (about 25,000 acre-ft/yr) infiltrates the soil zone and becomes ground-water recharge. This ground water eventually is discharged as evapotranspiration (11,000 acre-ft/yr) and as inflow to the Humboldt River channel and nearby springflow (7,000 acre-ft/yr). Total discharge is estimated to be 18,000 acre-ft/yr.

Water-Resources Investigations Report↗

Relations of surface-water quality to streamflow in the Atlantic Coastal, lower Delaware River, and Delaware Bay basins, New Jersey, water years 1976-93

Relations of water quality to streamflow were determined for 18 water-quality constituents at 28 surface-water-quality stations within the drainage area of the Atlantic Coastal, lower Delaware River, and Delaware Bay Basins for water years 1976-93. Surface-water-quality and streamflow data were evaluated for trends (through time) in constituent concentrations during high and low flows, and relations between constituent concentration and streamflow, and between constituent load and streamflow, were determined. Median concentrations were calculated for the entire period of study (water years 1976-93) and for the last 5 years of the period of study (water years 1989-93) to determine whether any large variation in concentration exists between the two periods. Medians also were used to determine the seasonal Kendall\'s tau statistic, which was then used to evaluate trends in concentrations during high and low flows. Trends in constituent concentrations during high and low flows were evaluated to determine whether the distribution of the observations changes through time for intermittent (nonpoint storm runoff) and constant (point sources and ground water) sources, respectively. High- and low-flow trends in concentrations were determined for some constituents at 26 of the 28 water-quality stations. Seasonal effects on the relations of concentration to streamflow are evident for 10 constituents at 14 or more stations. Dissolved oxygen shows seasonal dependency at all stations. Negative slopes of relations of concentration to streamflow, which indicate a decrease in concentration at high flows, predominate over positive slopes because of dilution of instream concentrations from storm runoff. The slopes of the regression lines of load to streamflow were determined in order to show the relative contributions to the instream load from constant (point sources and ground water) and intermittent sources (storm runoff). Greater slope values indicate larger contributions from storm runoff to instream load, which most likely indicate an increased relative importance of nonpoint sources. Load-to-streamflow relations along a stream reach that tend to increase in a downstream direction indicate the increased relative importance of contributions from storm runoff. Likewise, load-to-streamflow relations along a stream reach that tend to decrease in a downstream direction indicate the increased relative importance of point sources and ground-water discharge. The magnitudes of the load slopes for five constituents increase in the downstream direction along the Great Egg Harbor River, indicating an increased relative importance of storm runoff for these constituents along the river. The magnitudes of the load slopes for 11 constituents decrease in the downstream direction along the Assunpink Creek and for 5 constituents along the Maurice River, indicating a decreased relative importance of storm runoff for these constituents along the rivers.

New Jersey↗

Relations of surface-water quality to streamflow in the Raritan River basin, New Jersey, water years 1976-93

Relations of water quality to streamflow were determined for 18 water-quality constituents at 21 surface-water stations within the drainage area of the Raritan River Basin for water years 1976-93. Surface-water-quality and streamflow data were evaluated for trends (through time) in constituent concentrations during high and low flows, and relations between constituent concentration and streamflow, and between constituent load and streamflow, were determined. Median concentrations were calculated for the entire period of study (water years 1976-93) and for the last 5 years of the period of study (water years 1989-93) to determine whether any large variation in concentration exists between the two periods. Medians also were used to determine the seasonal Kendall’s tau statistic, which was then used to evaluate trends in concentrations during high and low flows. Trends in constituent concentrations during high and low flows were evaluated to determine whether the distribution of the observations changes through time for intermittent (nonpoint storm runoff) or constant (point sources and ground water) sources, respectively. Highand low-flow trends in concentrations were determined for some constituents at 13 of the 21 water-quality stations; 8 stations have insufficient data to determine trends. Seasonal effects on the relations of concentration to streamflow are evident for 16 of the 18 constituents. Negative slopes of relations of concentration to streamflow, which indicate a decrease in concentration at high flows, predominate over positive slopes because of the dilution of instream concentrations by storm runoff. The slopes of the regression lines of load to streamflow were determined in order to show the relative contributions to the instream load from constant (point sources and ground water) and intermittent sources (storm runoff). Greater slope values indicate larger contributions from storm runoff to instream load, which most likely indicate an increased relative importance of nonpoint sources. The slopes of load-to-streamflow relations along a stream reach that tend to increase in a downstream direction indicate the increased relative importance of contributions from storm runoff. The slopes of load-to-streamflow relations increase in the downstream direction for alkalinity at North Branch Raritan and Millstone Rivers, for some or all of the nutrient species at South Branch and North Branch Raritan Rivers, for hardness at South Branch Raritan River, for dissolved solids at North Branch Raritan River, for dissolved sodium at Lamington River, and for suspended sediment and dissolved oxygen at Millstone River. Likewise, the slopes of load-tostreamflow relations along a stream reach that tend to decrease in a downstream direction indicate the increased relative importance of point sources and ground-water discharge. The slopes of load-to-streamflow relations decrease in the downstream direction for dissolved solids at Raritan and Millstone Rivers; for dissolved sodium, dissolved chloride, total ammonia plus organic nitrogen, and total ammonia at South Branch Raritan, Raritan, and Millstone Rivers; for dissolved oxygen at North Branch Raritan and Lamington Rivers; for total nitrite at Lamington, Raritan, and Millstone Rivers; for total boron at South Branch Raritan and Millstone Rivers; for total organic carbon at North Branch Raritan River; for suspended sediment and total nitrogen at Raritan River; and for hardness, total phosphorus, and total lead at Millstone River.

New Jersey↗

A review of current capabilities and science gaps in water supply data, modeling, and trends for water availability assessments in the Upper Colorado River Basin

The Colorado River is a critical water resource in the southwestern United States, supplying drinking water for 40 million people in the region and water for irrigation of 2.2 million hectares of land. Extended drought in the Upper Colorado River Basin (UCOL) and the prospect of a warmer climate in the future pose water availability challenges for those charged with managing the river. Limited water availability in the future also may negatively affect aquatic ecosystems and wildlife that depend upon them. Water availability components of special importance in the UCOL include streamflow, salinity in groundwater and surface water, groundwater levels and storage, and the role of snow in the UCOL water cycle. This manuscript provides a review of current “state of the science” for these UCOL water availability components with a focus on identifying gaps in data, modeling, and trends in the basin. Trends provide context for evaluations of current conditions and motivation for further investigation and modeling, models allow for investigation of processes and projections of future water availability, and data support both efforts. Information summarized in this manuscript will be valuable in planning integrated assessments of water availability in the UCOL.

Arizona, Colorado, New Mexico, Utah, Wyoming↗

Occurrence and geochemistry of radium in water from principal drinking-water aquifer systems of the United States

A total of 1270 raw-water samples (before treatment) were collected from 15 principal and other major aquifer systems (PAs) used for drinking water in 45 states in all major physiographic provinces of the USA and analyzed for concentrations of the Ra isotopes 224Ra, 226Ra and 228Ra establishing the framework for evaluating Ra occurrence. The US Environmental Protection Agency Maximum Contaminant Level (MCL) of 0.185Bq/L (5pCi/L) for combined Ra ( 226Ra plus 228Ra) for drinking water was exceeded in 4.02% (39 of 971) of samples for which both 226Ra and 228Ra were determined, or in 3.15% (40 of 1266) of the samples in which at least one isotope concentration ( 226Ra or 228Ra) was determined. The maximum concentration of combined Ra was 0.755Bq/L (20.4pCi/L) in water from the North Atlantic Coastal Plain quartzose sand aquifer system. All the exceedences of the MCL for combined Ra occurred in water samples from the following 7PAs (in order of decreasing relative frequency of occurrence): the Midcontinent and Ozark Plateau Cambro-Ordovician dolomites and sandstones, the North Atlantic Coastal Plain, the Floridan, the crystalline rocks (granitic, metamorphic) of New England, the Mesozoic basins of the Appalachian Piedmont, the Gulf Coastal Plain, and the glacial sands and gravels (highest concentrations in New England).The concentration of Ra was consistently controlled by geochemical properties of the aquifer systems, with the highest concentrations most likely to be present where, as a consequence of the geochemical environment, adsorption of the Ra was slightly decreased. The result is a slight relative increase in Ra mobility, especially notable in aquifers with poor sorptive capacity (Fe-oxide-poor quartzose sands and carbonates), even if Ra is not abundant in the aquifer solids. The most common occurrence of elevated Ra throughout the USA occurred in anoxic water (low dissolved-O 2) with high concentrations of Fe or Mn, and in places, high concentrations of the competing ions Ca, Mg, Ba and Sr, and occasionally of dissolved solids, K, SO 4 and HCO 3. The other water type to frequently contain elevated concentrations of the Ra radioisotopes was acidic (low pH), and had in places, high concentrations of NO 3 and other acid anions, and on occasion, of the competing divalent cations, Mn and Al. One or the other of these broad water types was commonly present in each of the PAs in which elevated concentrations of combined Ra occurred. Concentrations of 226Ra or 228Ra or combined Ra correlated significantly with those of the above listed water-quality constituents (on the basis of the non-parametric Spearman correlation technique) and loaded on principal components describing the above water types from the entire data set and for samples from the PAs with the highest combined Ra concentrations.Concentrations of 224Ra and 226Ra were significantly correlated to those of 228Ra (Spearman's rank correlation coefficient, +0.236 and +0.326, respectively). Activity ratios of 224Ra/ 228Ra in the water samples were mostly near 1 when concentrations of both isotopes were greater than or equal to 0.037Bq/L (1pCi/L), the level above which analytical results were most reliable. Co-occurrence among these highest concentrations of the Ra radionuclides was most likely in those PAs where chemical conditions are most conducive to Ra mobility (e.g. acidic North Atlantic Coastal Plain). The concentrations of 224Ra were occasionally greater than 0.037Bq/L and the ratios of 224Ra/ 228Ra were generally highest in the PAs composed of alluvial sands and Cretaceous/Tertiary sandstones from the western USA, likely because concentrations of 224Ra are enhanced in solution relative to those of 228Ra by alpha recoil from the aquifer matrix. Rapid adsorption of the two Ra isotopes (controlled by the alkaline and oxic aquifer geochemistry) combined with preferential faster recoil of 224Ra generates a 224Ra/ 228Ra ratio much greater than

Applied Geochemistry↗