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Proterozoic sequences and their implications for Precambrian and Cambrian geologic evolution of western Kentucky: Evidence from seismic-reflection data

Analyses of two seismic-reflection lines in western Kentucky indicate the presence of two Proterozoic, unconformity-bounded sequences. One is autochthonous and of probable Late Proterozoic age; the other is allochthonous and of probable Middle Proterozoic age. Reflector patterns and apparent relationships to similar sequences elsewhere in the region suggest that the two sequences are of continental-rift origin. The two Proterozoic sequences lie beneath and adjacent to rocks of the Cambrian rift sequence in the Rough Creek Graben. The oldest sequence, the pre-Grenville sequence, was apparently folded and thrust faulted by the Grenville compressional event, implying that it is older than ???0.975 Ga (Middle Proterozoic). Two seismic-reflection pattern types are present in the western Kentucky data that may relate to the Middle Run (lithic arenite) and volcanic sequences defined farther east near the Grenville Front. The presence of imbricate, thrust-belt geometries in the pre-Grenville sequence extends the known westward limit of Grenville compressional structures into western Kentucky. The younger, post-Grenville sequence is less deformed and was apparently formed after the Grenville compressional event; several lines of evidence indicate that it is Late Proterozoic (0.7 to 0.6 Ga) in age. This probable siliciclastic and volcanic-rift sequence is represented by only thin remnants in western Kentucky and has no equivalent near the Grenville Front in southwestern Ohio and central Kentucky. Rocks of the better documented Cambrian rifting event belong to the thick, pre-Knox sequence in the Rough Creek Graben of western Kentucky and lie unconformably above these earlier sequences. A previously undocumented, northward-thickening interval within the lower part of the Cambrian pre-Knox sequence is recognized north of the Rough Creek Graben.

Kentucky↗

Surface monitoring of microseismicity at the Decatur, Illinois, CO2 sequestration demonstration site

Sequestration of CO2 into subsurface reservoirs can play an important role in limiting future emission of CO2 into the atmosphere (e.g., Benson and Cole, 2008). For geologic sequestration to become a viable option to reduce greenhouse gas emissions, large-volume injection of supercritical CO2 into deep sedimentary formations is required. These formations offer large pore volumes and good pore connectivity and are abundant (Bachu, 2003; U.S. Geological Survey Geologic Carbon Dioxide Storage Resources Assessment Team, 2013). However, hazards associated with injection of CO2 into deep formations require evaluation before widespread sequestration can be adopted safely (Zoback and Gorelick, 2012). One of these hazards is the potential to induce seismicity on pre-existing faults or fractures. If these faults or fractures are large and critically stressed, seismic events can occur with magnitudes large enough to pose a hazard to surface installations and, possibly more critical, the seal integrity of the cap rock. The Decatur, Illinois, carbon capture and storage (CCS) demonstration site is the first, and to date, only CCS project in the United States that injects a large volume of supercritical CO2 into a regionally extensive, undisturbed saline formation. The first phase of the Decatur CCS project was completed in November 2014 after injecting a million metric tons of supercritical CO2 over three years. This phase was led by the Illinois State Geological Survey (ISGS) and included seismic monitoring using deep borehole sensors, with a few sensors installed within the injection horizon. Although the deep borehole network provides a more comprehensive seismic catalog than is presented in this paper, these deep data are not publicly available. We contend that for monitoring induced microseismicity as a possible seismic hazard and to elucidate the general patterns of microseismicity, the U.S. Geological Survey (USGS) surface and shallow borehole network described below provides an adequate event detection threshold. The formation targeted for injection is the Mount Simon Sandstone, which is laterally extensive, has high porosity and permeability and has the potential to host future CCS projects due to its favorable hydrologic characteristics and proximity to industrial sources of CO2 (Birkholzer and Zhou, 2009). At Decatur, CO2, a byproduct of ethanol production at the Archer Daniels Midland (ADM) facility, is compressed to supercritical state and injected at 2.1 km depth into the 460 m thick Mount Simon Sandstone. This sandstone has varying properties, ranging from the lower, fine- to coarse-grained sandstone with high permeability and porosity, to the middle and upper Mount Simon, which consist of planar, cross-bedded layers of varied permeability and porosity (Leetaru and Freiburg, 2014). The changes in permeability and porosity within the Mount Simon Sandstone, due to depositional and diagenetic differences, create horizontal baffles, which inhibit vertical flow and restrict the injected CO2 to remain near the injection horizon (Bowen et al., 2011). The lowest portion of the Mount Simon Sandstone overlying the Precambrian rhyolite basement is the Pre-Mount Simon interval, generally < 15 m in thickness and composed of fine- to medium-grain size sandstone that is highly deformed (Leetaru and Freiburg, 2014). The basement rhyolite has a clayrich matrix and is fractured, with significant alterations within the fractures. The primary sealing cap rock is the Eau Claire Formation, a 100–150 m thick unit at a depth of roughly 1.69 km (Leetaru and Freiburg, 2014). The Maquoketa Shale Group and the New Albany Shale serve as secondary and tertiary seals at shallower depths of ∼820 and ∼650 m, respectively. The ISGS managed the Illinois Basin–Decatur Project (IBDP), a three-year project beginning in November 2011, during which carbon dioxide was injected at a rate of ∼1000 metric tons per day until November 2014 (Finley et al., 2011, 2013). ADM manages the Illinois Industrial CCS (ICCS) project, which will inject ∼3000 metric tons/day into a second injection well starting in the summer of 2015. The USGS began monitoring microseismicity with a 13- station seismic network at Decatur in July 2013 (Fig. 1). This network provides good detection capabilities and azimuthal (focal sphere) coverage for microseismicity with moment magnitudes (Mw) above about −0:5. Here, we report on 19 months of microseismicity monitoring at the Decatur CO2 sequestration site, which permits a detailed look at the evolution and character of injection-induced seismicity.

Illinois↗

Correlation of uppermost Precambrian and lower Cambrian strata from southern to east-central Nevada

Study of exposed uppermost Precambrian and Lower Cambrian strata in southern and east-central Nevada and intervening areas indicates that the Johnnie Formation of southern Nevada and the McCoy Creek Group (restricted) are correlative. In detail, the uppermost units of both sequences, the Rainstorm Member of the Johnnie Formation and the Osceola Argillite (and the equivalent unit G) of the McCoy Creek Group, arc lithologically similar and also considered correlative. Both are characterized by pale-red or purplish-medium-gray siltstone with abundant bedding-surface markings, and both contain scarce to abundant amounts of evenly or lenlicularly laminated limestone or silty limestone. Both units are lithologically unique in their respective areas of occurrence, and both are known to be widely distributed. Several thousand feet of dominantly detrital rocks occur above the Johnnie Formation in southern Nevada and the McCoy Creek Group in east-central Nevada. These detrital rocks consist of quartzite and siltstone in southern Nevada (the Stirling Quartzite, Wood Canyon Formation, and Zabriskie Quartzite) and dominantly quartzite (the Prospect Mountain Quartzite) in cast-central Nevada. Study in areas between southern and east-central Nevada indicates that the Stirling, Wood Canyon, and Zabriskie Formations change facies to the north and become lithologically similar to one another. The Prospect Mountain Quartzite of east-central Nevada is believed to be the final result of the facies change. It is equivalent to the combined Stirling, Wood Canyon, and Zabriskie of southern Nevada.

California, Nevada↗

Evolution of the Precambrian lithosphere: Seismological and geochemical constraints

Several recent models of crustal evolution are based on the belief that the thickness of the continental crust is proportional to its age, with ancient crust being the thickest. A worldwide review of seismic structure contradicts this belief and falsifies these models, at least for the Archean. Proterozoic crust has a thickness of 40–55 km and a substantial high‐velocity (>7 km/s) layer at its base, while Archean crust is only 27–40 km thick (except at the site of younger rifts and collisional boundaries) and lacks the basal high‐velocity layer. Seismology also provides evidence that the lithosphere is thickest beneath Archean cratons, while diamond ages show that this lithospheric keel must have already existed in the Archean. Geochemical data also indicate significant differences between Archean and Proterozoic lithosphere. Major and trace element studies of sediments show a change in upper crustal composition between the Archean and Proterozoic. Archean rocks are depleted in Si and K and enriched in Na, Ca, and Mg. There is also a marked change in the Eu/Eu * ratio. Mantle xenoliths and continental flood basalts show that the mantle lithosphere beneath Archean crust is ultradepleted in FeO compared to that beneath post‐Archean crust. The secular change in the crust‐forming process is attributed to a decline in mantle temperature, leading to a change in the composition of the lithospheric mantle. The higher temperature of the Archean mantle led to the eruption of komatiitic lavas, producing a refractory lithospheric mantle which is ultradepleted in FeO and volatiles. The resultant lithospheric keel is intrinsically less dense than the surrounding mantle and thus not susceptible to delamination. It was sufficiently thick and cool for diamonds to form during the Archean. In contrast, Proterozoic crust developed above fertile mantle. The eruption of continental flood basalts and underplating of basaltic sills is attributed to subsequent heating and partial melting of the lithospheric mantle. Consequently, Proterozoic crust is thickened and has a high‐velocity basal layer.

Journal of Geophysical Research B: Solid Earth↗

Stratiform chromitite at Campo Formoso, Bahia, Brazil

Serpentinized ultramafic rocks of pre-Minas age (Precambrian) crop out in an elongate belt 1 km wide and 15 km long on the west side of the Serra de Jacobina near Campo Formoso, Brazil. The original stratiform ultramafic body has been so metamorphosed, faulted, and eroded that only narrow dismembered segments occur along the thrust-faulted west side of the Serra de Jacobina. The most economically important segment is that near Campo Formoso where chromitite layers can be followed for about 8 km near the base of the intrusion. Three to five chromitite layers of minable thicknesses have been mapped, the thickest being 1.4 to 1.8 m. The aggregate thickness of chromitite is about 5 m and the average grade is about 43.5 percent Cr 2 0 3 . The Cr:Fe ratio ranges from 1.6:1 in weathered friable chromite to 3:1 in massive unweathered chromitite; in cleaned chromite concentrates the ratio is as much as 3.3:1. Estimates of indicated chromite ore reserves range from 16 to 20 million metric tons, of which only an estimated 6 million tons can profitably be mined. Factors preventing full exploitation of the chromite include (1) the local presence of as much as 7 m of overlying colluvium, (2) the extremely faulted character of the chromitite layers, (3) the presence of an overlying quartzite thrust plate very near the line of chromitite outcrops, and (4) the steep dips of the chromitite layers, 15° to 40° along the Pedrinhas-Limoeiro trends and 50° to 65° along the Cascabulhos trend.

Bahia↗

Petrogenesis of garnet two-mica granites in the Ruby Mountains, Nevada

Garnet-two-mica granites of Jurassic (160 ± 3 m.y.) and Cretaceous (83 ± 1.3 m.y.) ages intrude amphibolite facies metasedimentary rocks of Precambrian age and lower Paleozoic sedimentary rocks in the northern part of the Ruby Mountains, Nevada. High initial 87 Sr/ 86 Sr and high values of δ 18 O for minerals suggest a dominantly sedimentary source for the magmas. Total rare-earth contents are low and less fractionated (Ce N /Yb N = 10) than granitic rocks of similar composition in the Sierra Nevada and show a negative Eu anomaly (Eu/Eu* = 0.57). These data are consistent with melting in the stability field of plagioclase with little contribution to the melt from refractory minerals such as zircon, sphene, and apatite. Minor euhedral garnets are manganese-rich and magnesium-poor (al 60 sp 34 py 3.6 gr 2.8 ) compared to garnet (al 79 sp 6 py 13 gr 2 ) in the intruded metamorphic rocks and show an increase in manganese and a decrease in calcium in the outer few microns. Fractionation of magnesium-iron between garnet and biotite, and of sodium-potassium between K-feldspar and plagioclase in the granites suggest submagmatic equilibration temperatures, in the range of 365° to 505°C, whereas oxygen isotope equilibration temperatures for two granites are higher at 480° and 570°C. The compositions of the granites plot near minimum melting compositions in the water-saturated quartz-albite-orthoclase system. Comparison of muscovite plus quartz stability, the water-saturated granite solidus, and experimental garnet-melt equilibria suggests pressures of crystallization no lower than about 3.5 kbar. This pressure is compatible with that estimated from garnet-plagioclase-sillimanite-quartz equilibria for the intruded metasedimentary rocks.

Nevada↗

Generation of potassium-poor magmas in the northern Sierra Nevada and the Svecofennian of Finland

Comparison of the evolution of magmas in the Precambrian of southwestern Finland with that in the Paleozoic and Mesozoic of the northern Sierra Nevada brings out features that may clarify the origin of potassium-poor silicic magmas. In the northern Sierra Nevada, Paleozoic sodarhyolitic effusive rocks and associated trondhjemite represent silicic differentiates of andesitic magmas formed near a Benioff zone. These potassium-poor magmas were formed early, before thickening of the crust, and were followed by basaltic and rhyolitic magmas with normal potassium content. In southwestern Finland, where 70 percent of the area is covered by silicic and intermediate plutonic rocks, the early synkinematic intrusive masses are trondhjemitic and the later ones are granitic with eutectic ratios of quartz, plagioclase, and potassium feldspar. The latest granites are exceptionally rich in potassium feldspar. The oldest rocks, cordierite-garnet-sillimanite gneisses and interbedded metavolcanic rocks, are folded on gently plunging axes that steepen diapirically around large late-kinematic plutonic masses. Trondhjemite occurs as thin sheetlike masses parallel to the folded bedding and could not have traveled far without losing its initial heat. Therefore it seems that the trondhjemitic magma was formed at shallow depths. By analogy with the shallow depth of early magma generation in the northern Sierra Nevada, it is suggested that the trondhjemitic magmas in Finland formed at mantle depths near a Benioff zone or at the base of the early thin crust at pressures where phlogopite or biotite was stable. Later, after thickening of the crust above, potassium from the biotite was released, making the late kinematic magmas rich in potassium. A plate-tectonic model of an island-arc environment explains the coeval age of the Svecofennian and "Karelian" foldbelts and the increase of potassium with decreasing age in the extrusive and intrusive magmas.

northern Sierra Nevada, Svecofennian block↗

Reservoir analysis of the Denver earthquakes: A case of induced seismicity

Injection of fluid wastes into the fractured Precambrian crystalline bedrock beneath the Rocky Mountain Arsenal near Denver triggered earthquakes in the 1960's. An analysis, based on the assumption that fluid flow in the fractured reservoir can be approximated by flow in a porous medium, is presented. The configuration and hydrologic properties of the reservoir are determined from two lines of evidence: (1) locations of earthquake hypocenters determined by seismic arrays installed at the Arsenal and (2) observed long-term decline in fluid levels in the injection well. Together these two sets of data indicate that a long, narrow reservoir, aligned in the direction N 60°W, exists. The reservoir is 3.35 km in width, extends 30.5 km to the northwest and infinitely to the southeast, and spans a depth interval from 3.7 to 7.0 km below land surface. It has a transmissivity of 1.08×10-5 m2/s and a storage coefficient of 1.0×10-5. Computed pressure buildup along the length of the reservoir is compared with the spatial distribution of earthquake epicenters. The comparison shows that earthquakes are confined to that part of the reservoir where the pressure buildup exceeds 32 bars. This critical value is interpreted as the pressure buildup above which earthquakes occur. The migration of earthquake epicenters away from the injection well, a phenomenon noted by previous investigators, can be accounted for by the outward propagation of the critical pressure buildup. The analysis is extended to examining the effects of rapid flow in fractures opened by high injection pressure. The results show that the effect is confined to a small region within 1 km of the injection well. The existence of a critical pressure buildup above which earthquakes occur is completely consistent with the theory on the role of fluid pressure in fault movement as presented by Hubbert and Rubey.

Colorado↗

Thermal thickness and evolution of Precambrian lithosphere: A global study

The thermal thickness of Precambrian lithosphere is modeled and compared with estimates from seismic tomography and xenolith data. We use the steady state thermal conductivity equation with the same geothermal constraints for all of the Precambrian cratons (except Antarctica) to calculate the temperature distribution in the stable continental lithosphere. The modeling is based on the global compilation of heat flow data by Pollack et al. [1993] and more recent data. The depth distribution of heat‐producing elements is estimated using regional models for ∼300 blocks with sizes varying from 1°×1° to about 5°×5° in latitude and longitude and is constrained by laboratory, seismic and petrologic data and, where applicable, empirical heat flow/heat production relationships. Maps of the lateral temperature distribution at depths 50, 100, and 150 km are presented for all continents except Antarctica. The thermal thickness of the lithosphere is calculated assuming a conductive layer overlying the mantle with an adiabat of 1300°C. The Archean and early Proterozoic lithosphere is found to have two typical thicknesses, 200–220 km and 300–350 km. In general, thin (∼220 km) roots are found for Archean and early Proterozoic cratons in the Southern Hemisphere (South Africa, Western Australia, South America, and India) and thicker (>300 km) roots are found in the Northern Hemisphere (Baltic Shield, Siberian Platform, West Africa, and possibly the Canadian Shield). We find that the thickness of continental lithosphere generally decreases with age from >200 km beneath Archean cratons to intermediate values of 200±50 km in early Proterozoic lithosphere, to about 140±50 km in middle and late Proterozoic cratons. Using known crustal thickness, our calculated geotherms, and assuming that isostatic balance is achieved at the base of the lithosphere, we find that Archean and early Proterozoic mantle lithosphere is 1.5% less dense (chemically depleted) than the underlying asthenosphere, while middle and late Proterozoic subcrustal lithosphere should be depleted by ∼0.6–0.7%. Our results suggest three contrasting stages of lithosphere formation at the following ages: >2.5 Ga, 2.5–1.8 Ga, and <1.8 Ga. Ages of komatiites, greenstone belts, and giant dike swarms broadly define similar stages and apparently reflect secular changes in mantle temperature and, possibly, convection patterns.

Journal of Geophysical Research B: Solid Earth↗

Summary appraisals of the nation's ground-water resources – Souris-Red-Rainy region

A broad-perspective analysis of the ground-water resources and present and possible future water development and management in the Souris-Red-Rainy Region is presented. The region includes the basins of the Souris River within Montana and North Dakota; the Red River of the North in South Dakota, North Dakota, and Minnesota; and the Rainy River within Minnesota. The region includes 59,645 square miles, mostly in North Dakota and Minnesota. The terrain is relatively flat, but ranges in altitude from 2,541 to 750 feet. Annual average precipitation ranges from 14 inches in the west to 28 inches in the east and about 75 percent of it is rain. The mean annual snowfall ranges from 32 inches in the west to 64 inches in the east. Temperatures range from -55&deg; to 118&deg; F (-48.3&deg; to 47.8&deg; C). Irrigation is needed at least part of the time to assure crop production, particularly in the western part of the region. Sand and gravel deposits in the drift form the most important freshwater aquifers. Other aquifers are found in at least parts of the region in the Precambrian, Paleozoic, Cretaceous, and Tertiary rocks. The potentiometric surface in the bedrock aquifers generally decreases in altitude toward the Red River of the North, indicating that the general direction of ground-water movement is toward the river. Ground water with less than 3,000 milligrams per liter dissolved solids is available throughout the region. Ground water with less than 1,000 milligrams per liter occurs in most of the region east of the Red River of the North and in most of the shallow aquifers west of the river. The total volume of water available from storage having less than 3,000 milligrams per liter dissolved solids is estimated to be 5x10 8 acre-feet. In addition to the fresh and slightly saline water, the region has abundant highly mineralized water that can be considered as a resource. Yields of wells in individual bedrock aquifers are generally less than 100 gallons per minute but locally yields may be as much as 500 gallons per minute and more. Yields in drift aquifers are frequently less than 100 gallons per minute but range from 5 to 1,000 gallons per minute. In a few places outwash yields more than 1,000 gallons per minute. Ground water is the sole or a primary source of water supply in much of the region, including supplies for irrigation, domestic and livestock, municipal, and industrial needs. Reportedly, the potential irrigation development is 1,550,000 acres, as compared with 50,200 acres in 1975. Both ground- and surface-water supplies would be required to meet these demands. Rural domestic and livestock water supplies are derived almost entirely from ground-water sources. Smaller communities and towns generally rely on ground water, and the cities and industries use ground water, surface water, or both. The municipalities using surface water generally depend upon reservoir storage. Water quality rather than quantity is the greater water-supply problem for many communities in the region. Increased demands on both ground-water and surface-water supplies likely will be made in the future. Storage of surface water in the ground-water reservoirs during times of surplus for withdrawal during times of scarcity would aid in meeting these demands. The surplus (flood) water is of better chemical quality than underlying ground water in parts of the western half of the region. Freshwater could be stored in saline- or freshwater aquifers, and pumped out later, as needed. Thus, the ground-water reservoirs have a definite present and potential role in water management. To understand the hydrologic system for management purposes there is a need to determine more adequately the geologic and hydrologic characteristics of existing aquifers and the location of new aquifers. Also, as pumping and other stresses on any part of the hydrologic system affect other parts of the system, monitoring programs ideally should be started and maintained to detect changes and determine effects of the stresses. Many alternatives are available for managing water in the region. Some of these are operational and others are undergoing research. Adequate hydrologic information is needed to aid in solving problems of water supply, use, and pollution.

Minnesota, Montana, North Dakota, South Dakota↗

Summary appraisals of the Nation's ground-water resources; Souris-Red-Rainy region

A broad-perspective analysis of the ground-water resources and present and possible future water development and management in the Souris-Red-Rainy Region is presented. The region includes the basins of the Souris River within Montana and North Dakota; the Red River of the North in South Dakota, North Dakota, and Minnesota; and the Rainy River within Minnesota. The region includes 59,645 square miles, mostly in North Dakota and Minnesota. The terrain is relatively flat, but ranges in altitude from 2,541 to 750 feet. Annual average precipitation ranges from 14 inches in the west to 28 inches in the east and about 75 percent of it is rain. The mean annual snow fall ranges from 32 inches in the west to 64 inches in the east. Temperatures range from -55&deg; to 118&deg;F (-48.3&deg; to 47.8&deg;C). Irrigation is needed at least part of the time to assure crop production, particularly in the western part of the region. Sand and gravel deposits in the drift form the most important fresh-water aquifers. Other aquifers are found in at least parts of the region in the Precambrian, Paleozoic, Cretaceous, and Tertiary rocks. The potentiometric surface in the bedrock generally decreases in altitude toward the Red River of the North, indicating that the general direction of ground-water movement is toward the river. Ground-water with less than 3,000 milligrams per liter dissolved solids is available throughout the region. Ground water with less than 1,000 milligrams per liter occurs in most of the region east of the Red River of the North and in most of the shallow aquifers west of the river. The total volume of water available from storage having less than 3,000 milligrams per liter dissolved solids is estimated to be 5 x 10 8 acre-feet. In addition to the fresh and slightly saline water, the region has abundant highly mineralized water that can be considered as a resource. Yields of wells in individual bedrock aquifers are generally less than 100 gallons per minute but locally yields may be as much as 500 gallons per minute and more. Yields in drift aquifers are frequently less than 100 gallons per minute but range from 5 to 1,000 gallons per minute. In a few places outwash yields more than 1,000 gallons per minute. Ground water is the sole or a primary source of water supply in much of the region, including supplies for irrigation, domestic and livestock, municipal, and industrial needs. Reportedly, the potential irrigation development is 1,550,000 acres, as compared with 50,200 acres in 1975. Both ground- and surface-water supplies would be required to meet these demands. Rural domestic and livestock water supplies are derived almost entirely from ground-water sources. Smaller communities and towns generally rely on ground water, and the cities and industries use ground water, surface water, or both. The municipalities using surface water generally depend upon reservoir storage. Water quality rather than quantity is the greater water-supply problem for many communities in the region. Increased demands on both ground-water and surface-water supplies likely will be made in the future. Storage of surface water in the ground-water reservoirs during times of surplus for withdrawal during times of scarcity would aid in meeting these demands. The surplus (flood) water is of better chemical quality than underlying ground water in parts of the western half of the region. Fresh water could be stored in saline- or fresh-water aquifers, and pumped out later, as needed. Thus, the ground-water reservoirs have a definite present and potential role in water management. To understand the hydrologic system for management purposes there is a need to determine more adequately the geologic and hydrologic characteristics of existing aquifers and the location of new aquifers. Also, as pumping and other stresses on any part of the hydrologic system affect other parts of the system, monitoring programs ideally should be started and maintained to detect changes and determine effects of the stresses. Many alternatives are available for managing water in the region. Some of these are operational and others are undergoing research. Adequate hydrologic information is needed to aid in solving problems of water supply, use and pollution.

Minnesota, Montana, North Dakota, South Dakota↗

The nature of the crust in the Yukon-Koyukuk province as inferred from the chemical and isotopic composition of five Late Cretaceous to Early Tertiary volcanic fields in western Alaska

Late Cretaceous and early Tertiary volcanic and plutonic rocks in western Alaska comprise a vast magmatic province extending from the Alaska Range north to the Arctic Circle, south to Bristol Bay, and west to the Bering Sea Shelf. The chemical and isotopic composition of five of these Late Cretaceous to early Tertiary volcanic fields in the north central part of this province were studied to determine if Paleozoic or older continental crust underlies the Yukon-Koyukuk province. Three of the fields, the Blackburn Hills, Yukon River, and Kanuti, occur within the Yukon-Koyukuk province and two, the Sischu and Nowitna, overlie bordering Precambrian and Paleozoic metamorphic terranes to the southeast. High initial 87 Sr/ 86 Sr of 0.7075–0.7079 and moderate initial 143 Nd/ 144 Nd of 0.51244–0.51247 of rhyolite, dacite, and high-silica andesite of the Sischu volcanic field indicate that the magmas have interacted with the underlying Paleozoic or older continental crust. The relatively limited variation of isotopic (initial 87 Sr/ 86 Sr = 0.7044–0.7051; initial 143 Nd/ 144 Nd = 0.51256–0.51257) and elemental compositions of andesites from the Nowitna field can be accounted for by assimilation of small amounts of Paleozoic or older continental crust during crystal fractionation of andesite parent magmas at crustal levels. The Blackburn Hills field, which consists of medium-K basalt, andesite, and rhyolite intruded by a small granitic pluton, has a large range in initial 87 Sr/ 86 Sr and initial 143 Nd/ 144 Nd that plot in the field for 60 Ma mantle, from near mid-ocean ridge basalts to near “bulk-earth” compositions (initial 87 Sr/ 86 Sr = 0.7033–0.7052; initial 143 Nd/ 144 Nd = 0.51253–0.51290). Andesites and basalts from the Blackburn Hills are divided into two group on the basis of rare earth element (REE) and isotopic composition. Isotopic variation in the more primitive group 1 is best explained by assimilation of the lower crust of the Jurassic to Early Cretaceous Koyukuk terrane by mantle-derived basalts during crystal fractionation, though part of the isotopic variation may be due to metasomatism of an oceanic island basalt type mantle source by fluids derived from subducted sediments. Group 2 andesites from the Blackburn Hills have lower heavy REE abundances and more enriched isotopic compositions. These group 2 andesites and dacites from the Kanuti field, which have ( 87 Sr/ 86 Sr) i = 0.7043–0.7048 and ( 143 Nd/ 144 Nd) i = 0.51248–0.51267, appear to have formed by partial melting of the lower crust of the Koyukuk terrane. The Yukon River field consists of basalt, andesite, dacite, and rhyolite having ( 87 Sr/ 86 Sr) i = 0.7037–0.7051 and ( 143 Nd/ 144 Nd) i = 0.51266–0.51280; its isotopic composition does not require the presence of Paleozoic or older continental crust under the volcanic field and may have formed by interaction between mantle-derived melts and the oceanic Angayucham/Tozitna or island arc Koyukuk terrane. Most of the intrusive rocks and rhyolite domes from the Blackburn Hills volcanic field have ( 87 Sr/ 86 Sr) i = 0.7038–0.7041 and dacites from the Kanuti volcanic field have ( 87 Sr/ 86 Sr) i = 0.7043–0.7048. Thus little or no old continental crust was involved in the genesis of the Late Cretaceous and early Tertiary rocks and therefore probably does not extend beneath this part of the Yukon-Koyukuk province. However, the ultimate source of the small volumes of enriched shoshonitic andesite ( 87 Sr/ 86 Sr = 0.7075, 143 Nd/ 144 Nd = 0.5125) erupted at 118 Ma in the Yukon-Koyukuk province may be continental lithosphere, which may have been thrust under this part of the Yukon-Koyukuk province during arc-continent collision in the Early Cretaceous.

Journal of Geophysical Research Solid Earth↗

Phanerozoic continental growth and gold metallogeny of Asia

The Asian continent formed during the past 800 m.y. during late Neoproterozoic through Jurassic closure of the Tethyan ocean basins, followed by late Mesozoic circum-Pacific and Cenozoic Himalayan orogenies. The oldest gold deposits in Asia reflect accretionary events along the margins of the Siberia, Kazakhstan, North China, Tarim–Karakum, South China, and Indochina Precambrian blocks while they were isolated within the Paleotethys and surrounding Panthalassa Oceans. Orogenic gold deposits are associated with large-scale, terrane-bounding fault systems and broad areas of deformation that existed along many of the active margins of the Precambrian blocks. Deposits typically formed during regional transpressional to transtensional events immediately after to as much as 100 m.y. subsequent to the onset of accretion or collision. Major orogenic gold provinces associated with this growth of the Asian continental mass include: (1) the ca. 750 Ma Yenisei Ridge, ca. 500 Ma East Sayan, and ca. 450–350 Ma Patom provinces along the southern margins of the Siberia craton; (2) the 450 Ma Charsk belt of north-central Kazakhstan; (3) the 310–280 Ma Kalba belt of NE Kazakhstan, extending into adjacent NW Xinjiang, along the Siberia–Kazakhstan suture; (4) the ca. 300–280 Ma deposits within the Central Asian southern and middle Tien Shan (e.g., Kumtor, Zarmitan, Muruntau), marking the closure of the Turkestan Ocean between Kazakhstan and the Tarim–Karakum block; (5) the ca. 190–125 Ma Transbaikal deposits along the site of Permian to Late Jurassic diachronous closure of the Mongol–Okhotsk Ocean between Siberia and Mongolia/North China; (6) the probable Late Silurian–Early Devonian Jiagnan belt formed along the margin of Gondwana at the site of collision between the Yangtze and Cathaysia blocks; (7) Triassic deposits of the Paleozoic Qilian Shan and West Qinling orogens along the SW margin of the North China block developed during collision of South China; and (8) Jurassic(?) ores on the margins of the Subumusu block in Myanmar and Malaysia. Circum-Pacific tectonism led to major orogenic gold province formation along the length of the eastern side of Asia between ca. 135 and 120 Ma, although such deposits are slightly older in South Korea and slightly younger in the Amur region of the Russian Southeast. Deformation related to collision of the Kolyma–Omolon microcontinent with the Pacific margin of the Siberia craton led to formation of 136–125 Ma ores of the Yana–Kolyma belt (Natalka, Sarylakh) and 125–119 Ma ores of the South Verkhoyansk synclinorium (Nezhdaninskoe). Giant ca. 125 Ma gold provinces developed in the Late Archean uplifted basement of the decratonized North China block, within its NE edge and into adjacent North Korea, in the Jiaodong Peninsula, and in the Qinling Mountains. The oldest gold-bearing magmatic–hydrothermal deposits of Asia include the ca. 485 Ma Duobaoshan porphyry within a part of the Tuva–Mongol arc, ca. 355 Ma low-sulfidation epithermal deposits (Kubaka) of the Omolon terrane accreted to eastern Russia, and porphyries (Bozshakol, Taldy Bulak) within Ordovican to Early Devonian oceanic arcs formed off the Kazakhstan microcontinent. The Late Devonian to Carboniferous was marked by widespread gold-rich porphyry development along the margins of the closing Ob–Zaisan, Junggar–Balkhash, and Turkestan basins (Amalyk, Oyu Tolgoi); most were formed in continental arcs, although the giant Oyu Tolgoi porphyry was part of a near-shore oceanic arc. Permian subduction-related deformation along the east side of the Indochina block led to ca. 300 Ma gold-bearing skarn and disseminated gold ore formation in the Truong Son fold belt of Laos, and along the west side to ca. 250 Ma gold-bearing skarns and epithermal deposits in the Loei fold belt of Laos and Thailand. In the Mesozoic Transbaikal region, extension along the basin margins subsequent to Mongol–Okhotsk closure was associated with ca. 150–125 Ma formation of important auriferous epithermal (Balei), skarn (Bystray), and porphyry (Kultuminskoe) deposits. In northeastern Russia, Early Cretaceous Pacific margin subduction and Late Cretaceous extension were associated with epithermal gold-deposit formation in the Uda–Murgal (Julietta) and Okhotsk–Chukotka (Dukat, Kupol) volcanic belts, respectively. In southeastern Russia, latest Cretaceous to Oligocene extension correlates with other low-sulfidation epithermal ores that formed in the East Sikhote–Alin volcanic belt. Other extensional events, likely related to changing plate dynamics along the Pacific margin of Asia, relate to epithermal–skarn–porphyry districts that formed at ca. 125–85 Ma in northeastmost China and ca. 105–90 Ma in the Coast Volcanic belt of SE China. The onset of strike slip along a part of the southeastern Pacific margin appears to correlate with the giant 148–135 Ma gold-rich porphyry–skarn province of the lower and middle Yangtze River. It is still controversial as to whether true Carlin-like gold deposits exist in Asia. Those deposits that most closely resemble the Nevada (USA) ores are those in the Permo-Triassic Youjiang basin of SW China and NE Vietnam, and are probably Late Triassic in age, although this is not certain. Other Carlin-like deposits have been suggested to exist in the Sepon basin of Laos and in the Mongol–Okhotsk region (Kuranakh) of Transbaikal.

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