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The global occurrence of natural gas hydrate

Natural gas hydrate occurs worldwide in oceanic sediment of continental and insular slopes and rises of active and passive margins, in deep-water sediment of inland lakes and seas, and in polar sediment on both continents and continental shelves. In aquatic sediment, where water depths exceed about 300 m and bottom water temperatures approach 0° C, gas hydrate is found at the seafloor to sediment depths of about 1,100 m. In polar continental regions, gas hydrate can be present in sediment at depths between about 150 and 2000 m. Thus, natural gas hydrate is restricted to the shallow geosphere where its presence affects the physical and chemical properties of near-surface sediment. An updated global inventory reports on natural gas hydrate recovered from 19 places worldwide and includes 77 places where the presence of gas hydrate has been inferred from geophysical, geochemical, and geological evidence. The potential amount of methane in natural gas hydrate is enormous, with current estimates converging around about 10 teratonnes (10 19 g) of methane carbon.

Book chapter↗

Geology of the Harper Quadrangle, Liberia

As part of a program undertaken cooperatively by the Liberian Geological Survey (LGS) and the U. S. Geological Survey (USGS), under the sponsorship of the Government of Liberia and the Agency for International Development, U. S. Department of State, Liberia was mapped by geologic and geophysical methods during the period 1965 to 1972. The resulting geologic and geophysical maps are published in ten folios, each covering one quadrangle (see index map). The first systematic mapping in the Harper quadrangle was by Baker, S. P. Srivastava, and W. E. Stewart (LGS) at a scale of 1:500,000 in the vicinity of Harper in the southeastern, and of Karloke in the northeastern part of the quadrangle in 1960-61. Brock and Chidester carried out systematic mapping of the quadrangle at a scale of 1:250,000 in the period September 1971-May 1972; the geologic map was compiled from field data gathered by project geologists and private companies as indicated in the source diagram, photogeologic maps, interpretation of airborne magnetic and radiometric surveys, field mapping, and ground-based radiometric surveys in which hand-held scintillators were used. R. W. Bromery, C. S. Wotorson, and J. C. Behrendt contributed to the interpretation of geophysical data. Total-intensity aeromagnetic and total-count gamma radiation maps (Behrendt and Wotorson, in press a, b), and unpublished data derived from those maps, including the near-surface and the regional magnetic components and aeromagnetic/radiometric correlations, were used in the interpretation.

Harper Quadrangle↗

Borehole-geophysical investigation of the University of Connecticut landfill, Storrs, Connecticut

A borehole-geophysical investigation was conducted to help characterize the hydrogeology of the fractured-rock aquifer and the distribution of unconsolidated glacial deposits near the former landfill and chemical waste-disposal pits at the University of Connecticut in Storrs, Connecticut. Eight bedrock boreholes near the landfill and three abandoned domestic wells located nearby were logged using conventional and advanced borehole-geophysical methods from June to October 1999. The conventional geophysical-logging methods included caliper, gamma, fluid temperature, fluid resistivity, and electromagnetic induction. The advanced methods included deviation, optical and acoustic imaging of the borehole wall, heat-pulse flowmeter, and directional radar reflection. Twenty-one shallow piezometers (less than 50-feet deep) were logged with gamma and electromagnetic induction tools to delineate unconsolidated glacial deposits. Five additional shallow bedrock wells were logged with conventional video camera, caliper, electromagnetic induction, and fluid resistivity and temperature tools. The rock type, foliation, and fracturing of the site were characterized from high-resolution optical-televiewer (OTV) images of rocks penetrated by the boreholes. The rocks are interpreted as fine- to medium-grained quartz-feldsparbiotite-garnet gneiss and schist with local intrusions of quartz diorite and pegmatite and minor concentrations of sulfide mineralization similar to rocks described as the Bigelow Brook Formation on regional geologic maps. Layers containing high concentrations of sulfide minerals appear as high electrical conductivity zones on electromagneticinduction and borehole-radar logs. Foliation in the rocks generally strikes to the northeast-southwest and dips to the west, consistent with local outcrop observations. The orientation of foliation and small-scale gneissic layering in the rocks, however, varies locally and with depth in some of the boreholes. In two of the boreholes, the foliation strikes predominantly to the northwest and dips to the northeast. Although small-scale faults and lithologic discontinuities were observed in the OTV data, no large-scale faults were observed that appear on regional geologic maps. Fractures were located and characterized through the use of conventional geophysical, OTV, acoustic-televiewer (ATV), and borehole-radar logs. The orientation of fractures varies considerably across the site; some fractures are parallel to the foliation, whereas others cross-cut the foliation. Many of the transmissive fractures in the bedrock boreholes strike about N170°E and N320°E with dips of less than 45°. Other transmissive fractures strike about N60°E with dips of more than 60°. Most of the transmissive fractures in the domestic wells strike about N60°E and N22°E with dips of more than 45°. The strike of N60°E is parallel to the trend of a thrust fault that appears on regional geologic maps. Vertical flow in the boreholes was measured with the heat-pulse flowmeter under ambient and (or) pumping conditions. Results of ATV, OTV, and conventional logs were used to locate specific zones for flowmeter testing. Ambient downflow was measured in three boreholes, ambient upflow was measured in two other boreholes, and both ambient downflow and upflow were measured in a sixth borehole. The other five bedrock boreholes and domestic wells did not have measurable vertical flow. The highest rate of ambient flow was measured in the background borehole in which upflow and downflow converged and exited the borehole at a fracture zone near a depth of 62 feet. Ambient flow of about 340 gallons per day was measured. In the other five wells, ambient flow of about 20 to 35 gallons per day was measured. Under low-rate pumping (0.25 to 1 gallon per minute), one to six inflow zones were identified in each well. Usually the fractures that are active under ambient conditions contribute to the well under pumping conditions. To prevent ambient vertical flow and the potential for cross-contamination, temporary borehole liners were installed in five of the boreholes. Specific-capacity and open-hole transmissivity values were determined in eight boreholes completed in bedrock. The specific capacity estimated for these boreholes ranges from 0.14 to 1.6 gallons per minute per foot. The values for open-hole transmissivity range over two orders of magnitude and when proportioned to individual fracture transmissivity, range from 23 to 340 feet squared per day. Two boreholes had been drilled to intersect electrically conductive zones identified by previous surface-geophysical investigations. The borehole-geophysical results indicate that the boreholes penetrate electrically conductive structures consistent with the anomalies interpreted from the surface-geophysical data. Borehole MW121R was located to intersect a dipping electrically conductive anomaly at about 60 feet, interpreted from the two-dimensional direct currentresistivity survey conducted on the western side of the landfill. The electromagnetic-conductivity log in the borehole contains a high electrical conductivity anomaly at a depth of 69 feet. The magnitude of this anomaly is nearly 10,000 millisiemens per meter and is coincident with a layer containing sulfide mineralization, rather than fractures. The other borehole, MW105R, was located to intersect another anomaly south of the landfill. This anomaly was interpreted as a north-south striking, westward dipping feature. In the borehole, two south-striking, westward dipping fractures were identified in the ATV, OTV, and radar logs. The specific conductance of the fluid measured near these fractures was as high as 1,250 microsiemens per centimeter. Water-quality samples collected in October 1999 from an isolated zone from 71.5 to 76.5 feet indicated high specific conductance (810 microsiemens per centimeter), high concentrations of iron and cadmium, negative oxidation-reduction potential, and chlorobenzene. Collectively, these parameters indicate that the high specific conductance in the borehole logs for MW105R was caused by landfill leachate. Therefore, the anomaly identified by boreholeand surface-geophysical surveys is interpreted as a conductive lithologic feature and a permeable fracture zone that contains landfill leachate.

Connecticut↗

Potential application of radiogenic isotopes and geophysical methods to understand the hydrothermal dystem of the Upper Geyser Basin, Yellowstone National Park

Numerous geochemical and geophysical studies have been conducted at Yellowstone National Park to better understand the hydrogeologic processes supporting the thermal features of the Park. This report provides the first 87Sr/86Sr and 234U/238U data for thermal water from the Upper Geyser Basin (UGB) intended to evaluate whether heavy radiogenic isotopes might provide insight to sources of groundwater supply and how they interact over time and space. In addition, this report summarizes previous geophysical studies made at Yellowstone National Park and provides suggestions for applying non-invasive ground and airborne studies to better understand groundwater flow in the subsurface of the UGB. Multiple samples from Old Faithful, Aurum, Grand, Oblong, and Daisy geysers characterized previously for major-ion concentrations and isotopes of water (δ2H, δ18O, and 3H) were analyzed for Sr and U isotopes. Concentrations of dissolved Sr and U are low (4.3–128 ng g-1 Sr and 0.026–0.0008 ng g-1 U); consequently only 87Sr/86Sr data are reported for most samples. Values of 87Sr/86Sr for most geysers remained uniform between April and September 2007, but show large increases in all five geysers between late October 2007 and early April, 2008. By late summer of 2008, 87Sr/86Sr values returned to values similar to those observed a year earlier. Similar patterns are not present in major-ion data measured on the same samples. Furthermore, large geochemical differences documented between geysers are not observed in 87Sr/86Sr data, although smaller differences between sites may be present. Sr-isotope data are consistent with a stratified hydrologic system where water erupted in spring and summer of 2007 and summer of 2008 equilibrated with local intracaldera rhyolite flows at shallower depths. Water erupted between October 2007 and April 2008 includes greater amounts of groundwater that circulated deep enough to acquire a radiogenic 87Sr/86Sr, most likely from Archean basement rocks. Details of how the shallow and deep components interact and mechanisms causing these interactions remain unknown, but the data demonstrate the usefulness of obtaining Sr-isotope data from future sample campaigns. Geophysical methods that would be useful for characterization of the UGB subsurface properties and geothermal system include electromagnetic (EM), gravity, and ambient seismic. A suite of ground-based EM methods could be used in a synergistic combination together with airborne EM surveys to provide data for a range of spatial scales and resolutions. Existing thermal data for the shallow subsurface could be used to relate ground and airborne EM survey data to locations of geothermal fluids near the surface. Gravity surveys would be useful for mapping subsurface density anomalies and possibly monitoring changes in degree of saturation with groundwater. Ambient seismic surveys would be useful for estimating the thickness of unconsolidated deposits that contain the shallow groundwater system. A study that combines radiogenic isotope tracers with geophysical methods has the potential to better characterize the geothermal workings in the UGB. Insights gained could lead to a better understanding of the geothermal system and how Park infrastructure may cause perturbations. Measurements of radiogenic isotopes from multiple geysers and pools in localized areas within the UGB that are coupled with data from geophysical surveys would help refine conceptual models of mixing between deep- and shallow-derived subsurface fluids.

Wyoming↗

Geophysical analysis of the Salmon Peak Formation near Amistad Reservoir Dam, Val Verde County, Texas, and Coahuila, Mexico, March 2006, to aid in piezometer placement

Since 1992, numerous sinkholes have developed northwest of the Amistad Reservoir dam on the Rio Grande. Increases in the discharge of springs south of the dam, on the western side of the Rio Grande, in Coahuila, Mexico, have been documented. In 1995 the Mexico Section of the International Boundary and Water Commission (IBWC) completed a study of the western embankment (Coahuila, Mexico) of the dam that included surface geophysics, borehole geophysics, and installation of piezometers to learn more about subsurface conditions. As part of a 5-year safety inspection in 2005, technical advisors recommended that one line of similarly constructed piezometers be installed on the eastern embankment (Val Verde County, Texas) of the dam for comparison of water levels (potentiometric head) on both the western and eastern embankments of Amistad Reservoir dam. To provide technical assistance for the horizontal and vertical placement of piezometers on the eastern embankment of Amistad Reservoir dam, the U.S. Geological Survey, in cooperation with the U.S. Section of the IBWC, conducted a study along both the western and eastern embankments of Amistad Reservoir dam. The study involved an integrated approach using surface and borehole geophysical methods. In the western embankment investigation, geological and geophysical characteristics that indicate relatively large water-yielding properties of the Salmon Peak Formation were identified. The direct-current (DC) resistivity method was selected as the surface geophysical reconnaissance technique to correlate relatively large water-yielding properties of the Salmon Peak Formation, identified from analysis of borehole geophysical logs, with variations in subsurface resistivity. The dipole-dipole array and the reciprocal Schlumberger array were selected as the most applicable DC resistivity arrays. Two resistivity units were identified in both the dipole-dipole array data and the reciprocal Schlumberger array data along DC resistivity profiles on both embankments. Resistivity unit 1 generally is of relatively low resistivity, ranging from 45 to 150 ohm-meters compared with resistivity unit 2, which ranges from 120 to 345 ohm-meters (depending on the DC array type). The presence of mapped sinkholes in the reservoir north of the western embankment study area and the zone of increased water content (as indicated by zones of low neutron log count rates in nearby piezometers) leads to the conclusion that resistivity unit 1 is a preferential flow path where surface water from Amistad Reservoir is forced into the ground-water system (because of increased head from the reservoir). In the eastern embankment investigation, trends in the spatial distribution of sinkholes and the occurrence of weathered zones were identified from geologic descriptions of cores. The correlation of surface geophysical DC resistivity, historical lithologic data, and general trend of documented sinkholes along the eastern end of the eastern embankment profile were used to justify further exploration (drilling of piezometers) in the eastern expression of resistivity unit 1. The spatial location of the piezometers and the screened intervals were selected to best match the locations of the screened intervals of the western embankment piezometers. Six piezometers were installed on the eastern embankment and logged using borehole geophysical techniques. Surface DC resistivity sections superimposed on the resistivity logs for two piezometers indicate three discernible resistivity units that correlate with resistivity units 2, 1, and 2, respectively, identified in the western embankment study area. Resistivity units 1 and 2 in the DC resistivity profiles generally correspond with low and high resistivity zones, respectively, on the normal and lateral resistivity logs collected in the nearby piezometers at the time of installation.

Scientific Investigations Report↗

Switching predominance of organic versus inorganic carbon exports from an intermediate-size subarctic watershed

Hydrologic exports of dissolved inorganic and organic carbon (DIC, DOC) reflect permafrost conditions in arctic and subarctic river basins. DIC yields in particular, increase with decreased permafrost extent. We investigated the influence of permafrost extent on DIC and DOC yield in a tributary of the Yukon River, where the upper watershed has continuous permafrost and the lower watershed has discontinuous permafrost. Our results indicate that DIC versus DOC predominance switches with interannual changes in water availability and flow routing in intermediate-size watersheds having mixed permafrost coverage. Large water yield and small concentrations from mountainous headwaters and small water yield and high concentrations from lowlands produced similar upstream and downstream carbon yields. However, DOC export exceeded DIC export during high-flow 2011 while DIC predominated during low-flow 2010. The majority of exported carbon derived from near-surface organic sources when landscapes were wet or frozen and from mineralized subsurface sources when infiltration increased.

Alaska↗

Heat-flow data and their relation to observed geothermal phenomena near Klamath Falls, Oregon

Two holes were drilled to depths of about 180 m in the Lower Klamath Lake basin south of Klamath Falls, Oregon, to obtain heat flow data and to provide estimates of the thermal conductivity of the valley fill. Twenty-nine thermal conductivity determinations on eight cores give a mean conductivity of 1.82 mcal/cm s °C (0.75 W/m °K). Curvature in the upper 50 m of both terriperature profiles indicates a decrease in surface temperature of about 1.8°C, presumably resulting frorn reclamation of what was marshland in the early part of this century. A surprisingly low heat flow of 0.3 HFU (1 HFU = 10 −6 cal/cm 2 s = 41.8 mW/m 2 ) was measured at site LS near the center of the basin. At site OC-1, 7 km east of LS and 2 km from the Klamath Hills geothermal zone, the heat flow was 1.44 HFU, also a low value in this setting. Temperature profiles in 15 unused water wells in the area had linear gradients ranging from 47° to 170°C/km. The corresponding lower limits of heat flow (conductivities measured at the two heat flow sites being used) range from 0.8 to 3.1 HFU. These variations in heat flow evidently are caused by temperature variations in a convecting system within the near-surface volcanic rocks and do not provide firm constraints on the nature of heat sources at depth.

Journal of Geophysical Research↗

Hydroacoustic, seismic, and bathymetric observations of the 2014 submarine eruption at Ahyi Seamount, Mariana Arc

Ahyi seamount, a shallow submarine volcano in the Northern Mariana Islands, began erupting on April 23, 2014. Hydroacoustic eruption signals were observed on the regional Mariana seismic network and on distant hydrophones, and NOAA scuba divers working in the area soon after the eruption began heard and felt underwater explosion sounds. The NOAA crew observed yellow orange bubble mats along the shore of neighboring Farallon de Pájaros island, but no other surface manifestations of the eruption were reported by the crew or observed in satellite data. Here, we detail the eruption chronology and its morphologic impacts through analysis of seismic and hydroacoustic recordings and repeat bathymetric mapping. Throughout the 2-week-long eruption, Ahyi produced several thousand short, impulsive hydroacoustic signals that we interpret as underwater explosions as well as tremor near the beginning and end of the sequence. The initial tremor, which occurred for 2 hours, is interpreted as small phreatomagmatic explosions. This tremor was followed by a 90 min pause before the characteristic impulsive signals began. Occasional tremor (lasting up to a few minutes) during the last 1.5 days of the eruption is interpreted as more sustained eruptive activity. Bathymetric changes show that a new crater, about 150 m deep, formed near the former summit and a large landslide chute formed on the southeastern flank. Comparing to other geophysically-detected submarine eruptions, we find that the signals from the 2014 Ahyi eruption were more similar to those from other shallow or at surface submarine eruptions than those at deep (>500 m) eruptions.

Geochemistry, Geophysics, Geosystems↗

Hexavalent and total chromium at low reporting concentrations in source-water aquifers and surface waters used for public supply in Illinois, 2013

On the basis of their recent review of the human health effects of hexavalent chromium [Cr(VI)] in public drinking water, the U.S. Environmental Protection Agency is considering the need for Federal regulation of Cr(VI). Presently, only total chromium is regulated, at a Maximum Contaminant Level (MCL) of 100 micrograms per liter (µg/L). The occurrence of Cr(VI) in groundwater and surface waters generally is attributed to industrial sources, but can be of natural origin. California’s recently established MCL for Cr(VI) of 10 µg/L illustrates the drinking-water concerns associated with Cr(VI). To improve understanding of the possible impact of a Cr(VI)-specific standard that approximates the California level on the management of Illinois’ public drinking water, the U.S. Geological Survey, in cooperation with the Illinois Environmental Protection Agency, assessed the occurrence and distribution of Cr(VI) in the State’s public-water supplies. During 2013, untreated water samples were collected to be analyzed for Cr(VI) and total chromium [Cr(T)] at 119 water-supply wells and 32 surface-water intakes; also, 32 treated surface-water samples were collected near the point of treatment and 32 near the furthest point of distribution. Public-supply sample sites were selected by a stratified random method. Samples typically were analyzed within 24 hours of collection at reporting limits of 0.02 µg/L for Cr(VI) and 0.1 µg/L for Cr(T). The occurrence of Cr(VI) was compared with selected geophysical, physical, and sampling factors that might more fully explain its distribution and magnitude of concentrations. The maximum concentration of Cr(VI) in groundwater was 2.1 µg/L. Maximum concentrations in untreated and treated surface water were 0.29 µg/L and 2.4 µg/L, respectively. All sample concentrations were below the California MCL; only 35 percent were below that State’s non-enforceable public health goal of 0.02 of µg/L. Cr(VI) was undetected in 43 percent of untreated groundwater samples, with a median of 0.06 µg/L when detected. All but two (94 percent) of untreated surface-water samples had detections. In untreated surface water, the median concentration was 0.09 µg/L, whereas in treated (tap and distributed) water the median was 0.20 µg/L. Surface waters treated with lime for softening typically had the greatest Cr(VI) concentrations (maximum, 2.4 µg/L; median, 1.2 µg/L). The maximum concentration of Cr(T) in groundwater was 1.8 µg/L. Maximum concentrations in untreated and treated surface water were 1.8 µg/L and 2.5 µg/L, respectively. All sample concentrations were below the Federal MCL. Total chromium was detected in 65 percent of untreated groundwater samples, with a median of 0.40 µg/L, when detected. All but one (97 percent) of untreated surface-water samples had detections. In untreated surface water, the median concentration was 0.40 µg/L, whereas in treated (tap and distributed) water the median was 0.30 µg/L. As with Cr(VI), surface waters treated with lime typically had the greatest Cr(T) concentrations. Examination of factors that might account for or be associated with the occurrence of Cr(VI) in public-supply source waters found few clearly evident factors. Associations in frequencies of occurrence and range of concentrations indicate that surface waters and groundwaters of shallow, unconsolidated, unconfined aquifers, particularly alluvial aquifers, are possibly most commonly affected by anthropogenic sources of Cr(VI). Groundwaters of deep (greater than 500 feet) bedrock aquifers, particularly the Cambrian-Ordovician aquifer system, are possibly most commonly affected by geologic sources of Cr(VI). Additional study, with supporting geologic and geochemical data that were not collected in this study, would be necessary to verify these associations. There was a weak positive relation (ρ = 0.23) between concentrations of Cr(VI) and Cr(T) in untreated water samples, with a much stronger positive relation (ρ = 0.86 and ρ = 0.90, respectively) in samples collected soon after treatment and near the endpoint of distribution. The stronger relation and greater similarity between Cr(VI) and Cr(T) concentrations in treated water samples indicate that Cr(VI) represents a greater proportion of the measured concentrations of Cr(T) in treated waters than in untreated waters. The analysis of spikes and other quality-assurance samples indicate uncertainties associated with obtaining or confirming consistently accurate analytical results for Cr(VI) at near the applied reporting limit of 0.02 µg/L.

Illinois↗

Role of heat and detachment in continental extension as viewed from the eastern basin and range province in Arizona

The Bill Williams River area of west-central Arizona includes not only the Rawhide-Buckskin metamorphic core complex, which is part of the lower Colorado River highly extended terrane (HET), but also the boundary between the extended terranes of the Basin and Range Province and the less deformed Arizona Transition Zone/Colorado Plateau. This provides important constraints on models that address the mechanisms for the mid- to late Tertiary deformation. Three phases of extension are present. The oldest is the extension associated with core-complex tectonism, which characteristically shows a lower plate composed of lineated mylonitic gneiss overlain by a detachment fault that is regionally nearly horizontal but undulates at the local scale. The fault in turn is overlain by an upper plate that includes Precambrian basement rocks, recrystallized Paleozoic sedimentary rocks, Mesozoic(?) metasedimentary and metavolcanic rocks of greenschist facies, and unaltered to hydrothermally altered syntectonic sedimentary and volcanic rocks of Miocene age. The upper plate is cut by closely spaced faults of modest structural relief that strike northwest and strongly rotate intervening blocks to face southwest. Most of these faults do not penetrate below the detachment fault. Fault spacing increases, and rotation decreases, to the northeast, away from the trace of the detachment. The second phase consists of “classic” Basin-Range high-angle normal faults that strike about north and have wide spacing, high structural relief, and modest rotation of blocks. These faults have no consistent direction of displacement and so produced horst and graben that form the ranges and basins visible today. This phase is locally superposed on Phase I, and also extends in more subdued form into the Transition Zone/Colorado Plateau. The third phase consists of tectonic quiescence and is present everywhere except parts of the Transition Zone that are still active seismically. The first phase occurred in the early and middle Miocene and was accompanied by deposition of syntectonic fluviolacustrine rocks (Suite I); the second (middle to late Miocene) was marked by interior-basin deposits (Suite II); the third (latest Miocene through Quaternary) is characterized by deposits related to through-flowing drainage. The phases grade into each other and thus are likely to be genetically related. Tectonic models must take into account not only the geographic distribution of deformation at any one time but also the time-dependent succession of deformation at any one place. A model proposed in this paper attempts to do this. The model is thermotectonic. A heating event in the lower crust, (basaltic intrusion, asthenospheric upwelling) combined with stretching, causes a sharp thermal front to rise within the crust. Embedded within the front is an “isotherm” that marks the brittle-ductile transition. As the front rises, it leaves behind a trail of shear zones, each marking a locus of preferred failure defined by mechanical or physical properties, or combinations thereof. The highest shear zone, now preserved in fossil form as the “detachment”, occurs where the front impinges on the meteoric groundwater, a few km below the topographic surface. The water steepens the thermal gradient at the front, which it stabilizes. A convective hydrothermal circulation system is established, causing alteration and mineralization above the ductile-brittle transition, as well as pore overpressure that results in hydrofracturing (producing monolithologic breccias) and the sliding of gravity-glide sheets. During these events, extension is taking place by brittle failure in the upper plate and ductile deformation below the detachment. Simultaneously, the hottest areas (core complexes) are updomed, promoting drainage reversals and the sliding of breccias and glide sheets. All this occurred only in the hottest areas or “blisters”, now marked by the core complexes. Distal areas showed less or no deformation at the surface. With time and the waning of the thermal event, the thermal front, and thus the brittle-ductile transition, smoothed out and sank, again leaving a trail of shear zones. Phase 1 deformation ceased and was replaced by Phase 2 deformation that occurred over a much wider area. Eventually, the front sank so deep that surface deformation ceased. This illustrates how the style of deformation at the surface may be a measure of the depth to the brittle-ductile transition. According to the thermotectonic model, extensional strain does not need to be constant along the detachment, in contrast to models involving simple shear through crustal-scale normal faults. On the contrary, one would expect strain to vary geographically as a function of maximum temperature attained, because of the well known relation between temperature and lithospheric strength. The thermotectonic model is also in good accord with geophysical characteristics of the Basin and Range Province, which suggests that extension was accompanied by intrusion of basalt into the lower crust, with consequent heating and anatexis. Many studies in the U.S. and elsewhere support the model by showing that continental extension commonly is accompanied by near-surface temperatures corresponding to the brittle-ductile transition, by steep thermal gradients, and by hydrothemal convective systems. A possible driving mechanism from the thermotectonic processes described by the model is the rise of asthenospheric domes or welts, which thin the lithosphere by subcrustal transfer while heating and stretching it. An asthenospheric welt that migrates northeastward while dying out might explain the encroachment of relatively subdued extension onto the Colorado Plateau, as well as the juxtaposition of compressive stress on the plateau with extensional stress in the adjacent Transition Zone and Basin and Range Province.

Arizona↗

Possible Extent and Depth of Salt Contamination in Ground Water Using Geophysical Techniques, Red River Aluminum Site, Stamps, Arkansas, April 2003

A surface-geophysical investigation of the Red River Aluminum site at Stamps, Arkansas, was conducted in cooperation with the Arkansas Department of Environmental Quality to determine the possible extent and depth of saltwater contamination. Water-level measurements indicate the distance to water level below land surface ranges from about 1.2 to 3.9 feet (0.37 to 1.19 meters) in shallow monitor wells and about 10.5 to 17.1 feet (3.20 to 5.21 meters) in deeper monitoring wells. The two-dimensional, direct-current resistivity method identified resistivities less than 5 ohm-meters which indicated possible areas of salt contamination occurring in near-surface or deep subsurface ground water along four resistivity lines within the site. One line located east of the site yielded data that demonstrated no effect of salt contamination. Sections from two of the five data sets were modeled. The input model grids were created on the basis of the known geology and the results and interpretations of borehole geophysical data. The clay-rich Cook Mountain Formation is modeled as 25 ohm-meters and extends from 21 meters (68.9 feet) below land surface to the bottom of the model (about 52 meters (170.6 feet)). The models were used to refine interpretation of the resistivity data and to determine extent of saltwater contamination and depth to the Cook Mountain Formation. Data from the resistivity lines indicate both near-surface and subsurface saltwater contamination. The near-surface contamination appears as low resistivity (less than 5 ohm-meters) on four of the five resistivity lines, extending up to 775 meters (2,542.8 feet) horizontally in a line that traverses the entire site south to north. Model resistivity data indicate that the total depth of saltwater contamination is about 18 meters (59 feet) below land surface. Data from four resistivity lines identified areas containing low resistivity anomalies interpreted as possible salt contamination. A fifth line located just east of the site showed no saltwater contamination.

Water-Resources Investigations Report↗

Mapping bedrock surface contours using the horizontal-to-vertical spectral ratio (HVSR) method near the middle quarter srea, Woodbury, Connecticut

The bedrock surface contours in Woodbury, Connecticut, were determined downgradient of a commercial zone known as the Middle Quarter area (MQA) using the novel, noninvasive horizontal-to-vertical (H/V) spectral ratio (HVSR) passive seismic geophysical method. Boreholes and monitoring wells had been drilled in this area to characterize the shallow subsurface to within 20 feet (ft) of the land surface, but little was known about the deep subsurface, including sediment thicknesses and depths to bedrock (Starn and Brown, 2007; Brown and others, 2009). Improved information on the altitude of the bedrock surface and its spatial variation was needed for assessment and remediation of chlorinated solvents that have contaminated the overlying glacial aquifer that supplies water to wells in the area.

Connecticut↗

Consequences of abrading bed load on vertical and lateral bedrock erosion in a curved experimental channel

In this study, we conducted multiple physical experiments to estimate the efficacy and spatial pattern of erosion by abrading sediment moving through a simple U‐shaped channel bend with erodible bed and banks. The experiments showed that in the bend, lateral abrasion followed a monotonically increasing linear relationship with sediment feed rate. However, vertical incision had a more complex relation with the sediment feed rate, with an initial increase in abrasion as the feed rate increased followed by a decrease in abrasion of the bed as cover effects became dominant at higher feed rates. Bank erosion was large in places where the width and the lateral slope of the point bar were relatively large. On the other hand, in places where the width of the point bar was smaller, the bedrock bed was eroded primarily along the boundary of the point bar, resulting in a bedrock bench near the outer bank.

Shimanto River↗

On the state of lithospheric stress in the absence of applied tectonic forces

Numerous published analyses of the nontectonic state of stress are based on Hooke's law and the boundary condition of zero horizontal deformation. This approach has been used to determine the gravitational stress state as well as the effects of processes such as erosion and temperature changes on the state of lithospheric stress. The major disadvantage of these analyses involves the assumption of lateral constraint which seems unrealistic in view of the observational fact that the crust can deform horizontally in response to applied loads. If the same problems are addressed by assuming that the remote stress state is constant, instead of the condition of zero horizontal deformation, then the resulting stress states are entirely different and in good accord with observations. In the absence of applied tectonic forces the only likely gravitational stress states are those for which all three principal stresses are nearly equal. To the contrary, the gravitational stress states developed on the basis of the lateral constraint assumption can be ruled out. The processes of erosion and sedimentation have slight tendencies to increase and decrease, respectively, the state of deviatoric stress. In particular, for initial stress states in the range of slightly extensional to compressional, erosion has the effect of enhancing the ratio of average horizontal to vertical stress, which may explain, at least in part, the common observation of high near-surface horizontal stresses. Temperature changes have only minor effects on the stress state, as averaged over the thickness of the lithosphere.

Journal of Geophysical Research Solid Earth↗

Worldwide distribution of subaquatic gas hydrates

Sediments containing natural gas hydrates occur worldwide on continental and insular slopes and rises of active and passive margins, on continental shelves of polar regions, and in deep-water (> 300 m) environments of inland lakes and seas. The potential amount of methane in natural gas hydrates is enormous, with current estimates at about 1019 g of methane carbon. Subaquatic gas hydrates have been recovered in 14 different areas of the world, and geophysical and geochemical evidence for them has been found in 33 other areas. The worldwide distribution of natural gas hydrates is updated here; their global importance to the chemical and physical properties of near-surface subaquatic sediments is affirmed. ?? 1993 Springer-Verlag.

Geo-Marine Letters↗

Climatic effects of 30 years of landscape change over the Greater Phoenix, Arizona, region: 1. Surface energy budget changes

This paper is part 1 of a two-part study that evaluates the climatic effects of recent landscape change for one of the nation's most rapidly expanding metropolitan complexes, the Greater Phoenix, Arizona, region. The region's landscape evolution over an approximate 30-year period since the early 1970s is documented on the basis of analyses of Landsat images and land use/land cover (LULC) data sets derived from aerial photography (1973) and Landsat (1992 and 2001). High-resolution, Regional Atmospheric Modeling System (RAMS), simulations (2-km grid spacing) are used in conjunction with consistently defined land cover data sets and associated biophysical parameters for the circa 1973, circa 1992, and circa 2001 time periods to quantify the impacts of intensive land use changes on the July surface temperatures and the surface radiation and energy budgets for the Greater Phoenix region. The main findings are as follows: since the early 1970s the region's landscape has been altered by a significant increase in urban/suburban land area, primarily at the expense of decreasing plots of irrigated agriculture and secondarily by the conversion of seminatural shrubland. Mean regional temperatures for the circa 2001 landscape were 0.12??C warmer than the circa 1973 landscape, with maximum temperature differences, located over regions of greatest urbanization, in excess of 1??C. The significant reduction in irrigated agriculture, for the circa 2001 relative to the circa 1973 landscape, resulted in dew point temperature decreases in excess of 1??C. The effect of distinct land use conversion themes (e.g., conversion from irrigated agriculture to urban land) was also examined to evaluate how the most important conversion themes have each contributed to the region's changing climate. The two urbanization themes studied (from an initial landscape of irrigated agriculture and seminatural shrubland) have the greatest positive effect on near-surface temperature, increasing maximum daily temperatures by 1??C. Overall, sensible heat flux differences between the circa 2001 and circa 1973 landscapes result in a 1 W m -2 increase in domain-wide sensible heating, and a similar order of magnitude decrease in latent heating, highlighting the importance of surface repartitioning in establishing near-surface temperature trends. In part 2 of this study, we address the role of the surface budget changes on the mesoscale dynamics/thermodynamics, in context of the large-scale environment. Copyright 2009 by the American Geophysical Union.

Journal of Geophysical Research D: Atmospheres↗

Geophysical characterization of the American River levees, Sacramento, California, with electromagnetics, capacitively coupled resistivity, and DC resistivity

A geophysical characterization of a portion of American River levees in Sacramento, California was conducted in May, 2007. Targets of interest included the distribution and thickness of sand lenses that underlie the levees and the depth to a clay unit that underlies the sand. The concern is that the erosion of these sand lenses can lead to levee failure in highly populated areas of Sacramento. DC resistivity (Geometric’s OhmMapper and Advanced Geosciences, Inc.’s SuperSting R8 systems) and electromagnetic surveys (Geophex’s GEM-2) were conducted over a 6 mile length of the levee on roads and bicycle and horse trails. 2-D inversions were conducted on all the geophysical data. The OhmMapper and SuperSting surveys produced consistent inversion results that delineated potential sand and clay units. GEM-2 apparent resistivity data were consistent with the DC inversion results. However, the GEM-2 data could not be inverted due to low electromagnetic response levels, high ambient electromagnetic noise, and large system drifts. While this would not be as large a problem in conductive terrains, it is a problem for a small induction number electromagnetic profiling system such as the GEM-2 in a resistive terrain (the sand lenses). An integrated interpretation of the geophysical data acquired in this investigation is presented in this report that includes delineation of those areas consisting of predominantly sand and those areas consisting predominantly of clay. In general, along most of this part of the American River levee system, sand lenses are located closest to the river and clay deposits are located further away from the river. The interpreted thicknesses of the detected sand deposits are variable and range from 10 ft up to 60 ft. Thus, despite issues with the GEM-2 inversion, this geophysical investigation successfully delineated sand lenses and clay deposits along the American River levee system and the approximate depths to underlying clay zones. The results of this geophysical investigation should help the USACE to maintain the current levee system while also assisting the designers and planners of levee enhancements with the knowledge of what is to be expected from the near-surface geology and where zones of concern may be located.

California↗

Geophysical studies of the Syncline Ridge area, Nevada Test Site, Nye County, Nevada

A wide variety of geophysical methods were employed to study a proposed nuclear waste site at Syncline Ridge on the Nevada Test Site, Nev. The proposed site was believed to be a relatively undisturbed synclinal structure containing a thick argillite unit of Misslsslppian age, the Eleana Formation unit J, which would be the emplacement medium. Data acquisition for the geophysical studies was constrained because of rugged topography in a block of Tipplpah Limestone overlying the central part of the proposed site. This study employed gravity, magnetic, seismic refraction and reflection, and four distinct electrical methods to try and define the structural integrity and shape of the proposed repository medium. Detailed and regional gravity work revealed complex structure at the site. Magnetics helped only in identifying small areas of Tertiary volcanic rocks because of low magnetization of the rocks. Seismic refraction assisted in identifying near surface faulting and bedrock structure. Difficulty was experienced in obtaining good quality reflection data. This implied significant structural complexity but also revealed the principal features that were supported by other data. Electrical methods were used for fault identification and for mapping of a thick argillaceous unit of the Eleana Formation in which nuclear waste was to be emplaced. The geophysical studies indicate that major faults along the axis of Syncline Ridge and on both margins have large vertical offsets displacing units so as not only to make mining difficult, but also providing potential paths for waste migration to underlying carbonate aquifers. The Eleana Formation appeared heterogeneous, which was inferred to be due to structural complexity. Only a small region in the northwest part of the study area was found to contain a thick and relatively undisturbed volume of host rock.

Open-File Report↗