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At least 163 records · Page 9Linked to original sources

USGS1983

Phase relations in the system NaCl-KCl-H 2 O II: Differential thermal analysis of the halite liquidus in the NaCl-H 2 O binary above 450°c

Thermal analysis of the halite liquidus in the system NaCl-H 2 O has been conducted for NaCl mole fractions ( X NaCl ) greater than 0.25 ( i.e. , > 50 wt. % NaCl) at pressures between 0.3 and 4.1 kb and temperatures greater than 450°C. The position of the liquidus was located by differential thermal analysis (DTA) of cooling scans only, as heating scans did not produce definitive DTA peaks. The dP/dT slope of the liquidus is positive and steep at high pressures, but at high X NaCl , and pressures below 0.5 kb it appears to reverse slope and intersects the three-phase curve (liquid-halite-vapour) at a shallow angle. However, due to the complex nature of the DTA signal when P <- 0.5 kb, there is considerable doubt about exactly what event has been recorded in the experiments conducted at these low pressures. The solubility of halite can be expressed as a function of the mole-fractional-based activity of NaCl in the liquid phase ( L ) in temperature (T, °K) and pressure (P, bars) In Our liquidus data (based on 10 compositions) above 500 bars for these brines were combined with this equation to generate activity coefficients of NaCl which were fit within their experimental uncertainties to the following one parameter Margules equation In . Concentrated solutions of NaCl show negative deviations from ideality which rapidly increase in magnitude with decreasing X NaCl .

Geochimica et Cosmochimica Acta↗

USGS2005

Determination of uranyl incorporation into biogenic manganese oxides using X-ray absorption spectroscopy and scattering

Βiogenic manganese oxides are common and an important source of reactive mineral surfaces in the environment that may be potentially enhanced in bioremediation cases to improve natural attenuation. Experiments were performed in which the uranyl ion, UO 2 2+ (U(VI)), at various concentrations was present during manganese oxide biogenesis. At all concentrations, there was strong uptake of U onto the oxides. Synchrotron-based extended X-ray absorption fine structure (EXAFS) spectroscopy and X-ray diffraction (XRD) studies were carried out to determine the molecular-scale mechanism by which uranyl is incorporated into the oxide and how this incorporation affects the resulting manganese oxide structure and mineralogy. The EXAFS experiments show that at low concentrations (<0.3 mol % U, <1 μM U(VI) in solution), U(VI) is present as a strong bidentate surface complex. At high concentrations (>2 mol % U, >4 μM U(VI) in solution), the presence of U(VI) affects the stability and structure of the Mn oxide to form poorly ordered Mn oxide tunnel structures, similar to todorokite. EXAFS modeling shows that uranyl is present in these oxides predominantly in the tunnels of the Mn oxide structure in a tridentate complex. Observations by XRD corroborate these results. Structural incorporation may lead to more stable U(VI) sequestration that may be suitable for remediation uses. These observations, combined with the very high uptake capacity of the Mn oxides, imply that Mn-oxidizing bacteria may significantly influence dissolved U(VI) concentrations in impacted waters via sorption and incorporation into Mn oxide biominerals.

Environmental Science & Technology↗

USGS2005

Comparison of heat and bromide as ground-water tracers near streams

Heat and bromide were compared as tracers for examining stream/ground water exchanges along the middle reaches of the Santa Clara River, California, during a 10-hour surface water sodium bromide injection test. Three cross sections that comprise six shallow (<1 m) piezometers were installed at the upper, middle, and lower sections of a 17 km long study reach, to monitor temperatures and bromide concentrations in the shallow ground water beneath the stream. A heat and ground water transport simulation model and a closely related solute and ground water transport simulation model were matched up for comparison of simulated and observed temperatures and bromide concentrations in the streambed. Vertical, one-dimensional simulations of sediment temperature were fitted to observed temperature results, to yield apparent streambed hydraulic conductivities in each cross section. The temperature-based hydraulic conductivities were assigned to a solute and ground water transport model to predict sediment bromide concentrations, during the sodium bromide injection test. Vertical, one-dimensional simulations of bromide concentrations in the sediments yielded a good match to the observed bromide concentrations, without adjustment of any model parameters except solute dispersivities. This indicates that, for the spatial and temporal scales examined on the Santa Clara River, the use of heat and bromide as tracers provide comparable information with respect to apparent hydraulic conductivities and fluxes for sediments near streams. In other settings, caution should be used due to differences in the nature of conservative (bromide) versus nonconservative (heat) tracers, particularly when preferential flowpaths are present.

California↗

USGS1956

The physical behavior and geologic control of radon in mountain streams

Radon measurement were made in several small, turbulent mountain streams in the Wasatch Mountains near Salt Lake City and Ogden, Utah, to determine the relationship between the distribution of radon and its geologic environment. In this area, the distribution of radon in streams can be sued to locate points where relatively large amounts of radon-bearing ground water enter the stream, although other evidence of spring activity may be lacking. These points of influence ground water are marked by abrupt increases (as much as two orders of magnitude within a distance of 50 feet) in the radon content of the stream waters. The excess radon in the stream water is then rapidly lost to the atmosphere through stream turbulence. The rate of radon dissipation is an exponential function, of different slopes, with respect to distance of streamflow, and depend upon the rate and volume of streamflow, and the gradient and nature of the stream channel. The higher radon concentration can be generally related to specific stratigraphic horizons in several different drainage area. Thus, lithologic units which act as the primary aquifers can be identifies. In one area, thrust faults were found to control he influx of ground water into the stream. Estimates, based on radon concentration in stream and related spring waters, can also be made of the major increments of addition of ground water to streamflow where conventional methods such as stream gaging are not practical. The radon in the waters studied was found to be almost completely unsupported by radium in solution.

Utah↗

USGS1985

Study and interpretation of the chemical characteristics of natural water

The chemical composition of natural water is derived from many different sources of solutes, including gases and aerosols from the atmosphere, weathering and erosion of rocks and soil, solution or precipitation reactions occurring below the land surface, and cultural effects resulting from human activities. Broad interrelationships among these processes and their effects can be discerned by application of principles of chemical thermodynamics. Some of the processes of solution or precipitation of minerals can be closely evaluated by means of principles of chemical equilibrium, including the law of mass action and the Nernst equation. Other processes are irreversible and require consideration of reaction mechanisms and rates. The chemical composition of the crustal rocks of the Earth and the composition of the ocean and the atmosphere are significant in evaluating sources of solutes in natural freshwater. The ways in which solutes are taken up or precipitated and the amounts present in solution are influenced by many environmental factors, especially climate, structure and position of rock strata, and biochemical effects associated with life cycles of plants and animals, both microscopic and macroscopic. Taken together and in application with the further influence of the general circulation of all water in the hydrologic cycle, the chemical principles and environmental factors form a basis for the developing science of natural-water chemistry. Fundamental data used in the determination of water quality are obtained by the chemical analysis of water samples in the laboratory or onsite sensing of chemical properties in the field. Sampling is complicated by changes in the composition of moving water and by the effects of particulate suspended material. Some constituents are unstable and require onsite determination or sample preservation. Most of the constituents determined are reported in gravimetric units, usually milligrams per liter or milliequivalents per liter. More than 60 constituents and properties are included in water analyses frequently enough to provide a basis for consideration of the sources from which each is generally derived, the most probable forms of elements and ions in solution, solubilitycontrols, expected concentration ranges, and other chemical factors. Mechanisms that control concentrations of elements commonly present in amounts less than a few tens of micrograms per liter cannot always be easily ascertained, but present information suggests that many are controlled by solubility of their hydroxides or carbonates or by sorption on solid particles. Many dissolved organic compounds can now be specifically determined. Chemical analyses may be grouped and statistically evaluated by means, medians, frequency distributions, or ion correlations to summarize large volumes of data. Graphing of analyses or of groups of analyses aids in showing chemical relationships among water, probable sources of solutes, areal water-quality regimen, temporal and spatial variation, and water-resources evaluation. Graphs may show water type based on chemical composition, relationships among ions, or groups of ions in individual waters or many waters considered simultaneously. The relationships of water quality to hydrogeologic characteristics, such as stream discharge rate or ground-water flow patterns, can be shown by mathematical equations, graphs, and maps. About 80 water analyses selected from the literature are tabulated to illustrate the relationships described, and some of these, along with many others that are not tabulated, are also used in demonstrating graphing and mapping techniques. Relationships of water composition to source rock type are illustrated by graphs of some of the tabulated analyses. Human activities may modify water composition extensively through direct effects of pollution and indirect results of water development, such as intrusion of seawater in groundwater aquifers. Water-quality standards for domestic, agricultural, and industrial use have been published by various agencies. Irrigation project requirements for water quality are particularly intricate. Fundamental knowledge of processes that control natural-water composition is required for rational management of water quality.

Water Supply Paper↗

USGS2010

Kinetically influenced terms for solute transport affected by heterogeneous and homogeneous classical reactions

Simulation of transport affected by heterogeneous or homogeneous reversible reactions requires a choice between local equilibrium-based and kinetics-based models. The error associated with the use of equilibrium-based models is equivalent to the error of neglecting certain mathematical terms in the governing kinetics-based transport equations. Identification and evaluation of these kinetically influenced terms can therefore aid in the development of criteria for applicability of local equilibrium- based transport models. This paper extends a four-step derivation procedure, previously presented for cases of transport affected by surface reactions, to transport problems involving homogeneous reactions (solution phase complex formation or oxidation-reduction) and/or precipitation-dissolution reactions. Derivations for these classes of reactions are used to illustrate the manner in which mathematical differences between reaction classes are reflected in the mathematical derivation procedures required to identify kinetically influenced terms. Simulation results for a case of transport affected by a single solution phase complexation reaction and for a case of transport affected by a precipitation-dissolution reaction are used to demonstrate the nature of departures from equilibrium-controlled transport as well as the use of kinetically influenced terms in determining criteria for the applicability of the local equilibrium assumption. A final derivation for a multireaction problem demonstrates the application of the generalized procedure to a case of transport affected by reactions of several classes.

Water Resources Research↗

USGS1984

Proton and metal ion binding to natural organic polyelectrolytes—II. Preliminary investigation with a peat and a humic acid

We summarize here experimental studies of proton and metal ion binding to a peat and a humic acid. Data analysis is based on a unified physico-chemical model for reaction of simple ions with polyelectrolytes employing a modified Henderson-Hasselbalch equation. Peat exhibited an apparent intrinsic acid dissociation constant of 10 −4.05 , and an apparent intrinsic metal ion binding constant of: 400 for cadmium ion; 600 for zinc ion; 4000 for copper ion; 20000 for lead ion. A humic acid was found to have an apparent intrinsic proton binding constant of 10 −2.6 . Copper ion binding to this humic acid sample occurred at two types of sites. The first site exhibited reaction characteristics which were independent of solution pH and required the interaction of two ligands on the humic acid matrix to simultaneously complex with each copper ion. The second complex species is assumed to be a simple monodentate copper ion-carboxylate species with a stability constant of 18.

Organic Geochemistry↗

USGS1979

Derivation of linearized constitutive equations for plane-strain of an elastic-plastic (strain hardening) material

The purpose of this report is to derive several of the basic equations for a paper on folding and folding of idealized rock (Johnson, 1979). That paper is based on constitutive equations for an ideal, strain-hardening material defined by Hill (1950, p. 30) and generalized to include Coulomb behavior and dilatancy by Rudnicki and Rice (1975). The most attractive feature of the theory is that folding and faulting, which are intimately related in nature, are different responses of the same material to different boundary conditions. In the paper by Johnson (1979) it is shown that single layers of sedimentary rocks are unlikely to fold, rather they will fault, because of low contrasts in elasticity and strength properties of sedimentary rocks such as layers of dolomite, limestone, sandstone, or siltstone in media of shale. Further, multi-layers of these same rocks will fault rather than fold if contacts are bonded, but they will fold readily if contacts between layers are frictionless, or have low yield strengths, for example due to high pore-water pressure. These conclusions are based on solutions of the equations presented in the following pages, using experimental stress-strain curves for various rock types.

Open-File Report↗

USGS2018

Thiamine deficiency in fishes: Causes, consequences, and potential solutions

Thiamine deficiency complex (TDC) is a disorder resulting from the inability to acquire or retain thiamine (vitamin B 1 ) and has been documented in organisms in aquatic ecosystems ranging from the Baltic Sea to the Laurentian Great Lakes. The biological mechanisms leading to TDC emergence may vary among systems, but in fishes, one common outcome is high mortality among early life stages. Here, we review the causes and consequences of thiamine deficiency in fishes and identify potential solutions. First, we examine the biochemical and physiological roles of thiamine in vertebrates and find that thiamine deficiency consistently results in impaired neurological function across diverse taxa. Next, we review natural producers of thiamine, which include bacteria, fungi, and plants, and suggest that thiamine is not currently limiting for most animal species inhabiting natural aquatic environments. A survey of historic occurrences of thiamine deficiency identifies consumption of a thiamine-degrading enzyme, thiaminase, as the primary explanation for low levels of thiamine in individuals and subsequent onset of TDC. Lastly, we review conservation and management strategies for TDC mitigation ranging from evolutionary rescue to managing for a diverse forage base. As recent evidence suggests occurrences of thiamine deficiency may be increasing in frequency, increased awareness and a better mechanistic understanding of the underlying causes associated with thiamine deficiency may help prevent further population declines.

Reviews in Fish Biology and Fisheries↗

USGS2022

Modeling geomagnetic induction in submarine cables

Submarine cables have become a vital component of modern infrastructure, but past submarine cable natural hazard studies have mostly focused on potential cable damage from landslides and tsunamis. A handful of studies examine the possibility of space weather effects in submarine cables. The main purpose of this study is to develop a computational model, using Python , of geomagnetic induction on submarine cables. The model is used to estimate the induced voltage in the submarine cables in response to geomagnetic disturbances. It also utilizes newly acquired knowledge from magnetotelluric studies and associated investigations of geomagnetically induced currents in power systems. We describe the Python-based software, its working principle, inputs/outputs based on synthetic geomagnetic field data, and compare its operational capabilities against analytical solutions. We present the results for different model inputs, and find: 1) the seawater layer acts as a shield in the induction process: the greater the ocean depth, the smaller the seafloor geoelectric field; and 2) the model is sensitive to the Ocean-Earth layered conductivity structure.

Frontiers in Physics↗

USGS2005

Evaluation of simplified stream-aquifer depletion models for water rights administration

We assess the predictive accuracy of Glover's (1974) stream-aquifer analytical solutions, which are commonly used in administering water rights, and evaluate the impact of the assumed idealizations on administrative and management decisions. To achieve these objectives, we evaluate the predictive capabilities of the Glover stream-aquifer depletion model against the MODFLOW numerical standard, which, unlike the analytical model, can handle increasing hydrogeologic complexity. We rank-order and quantify the relative importance of the various assumptions on which the analytical model is based, the three most important being: (1) streambed clogging as quantified by streambed-aquifer hydraulic conductivity contrast; (2) degree of stream partial penetration; and (3) aquifer heterogeneity. These three factors relate directly to the multidimensional nature of the aquifer flow conditions. From these considerations, future efforts to reduce the uncertainty in stream depletion-related administrative decisions should primarily address these three factors in characterizing the stream-aquifer process. We also investigate the impact of progressively coarser model grid size on numerically estimating stream leakage and conclude that grid size effects are relatively minor. Therefore, when modeling is required, coarser model grids could be used thus minimizing the input data requirements.

Groundwater↗

USGS1987

Development of sinkholes resulting from man's activities in the Eastern United States

Development of induced sinkholes in carbonate terranes in the Eastern United States has resulted in costly damage and water pollution. Previously, detailed investigations of sinkholes were limited to Alabama and Missouri, with the most comprehensive being in Alabama. An investigation of the remainder of the area was made in 1981 to regionalize previous findings. More than 850 sites of sinkhole development have been identified in 19 States. It is estimated that more than 6,500 sinkholes or related features have formed at these sites. Most have occurred since 1950. Based on information available, States most impacted are Alabama, Florida, Georgia, Missouri, Pennsylvania, and Tennessee. The total cost of damage and associated protective measures resulting from induced sinkholes is unknown. Costs reported for a limited number of sites were about $170 million--expended almost entirely after 1970. About $140 million were expended at five dams in four States and to repair or protect highways in two States. Sinkholes are of two types, natural and induced {accelerated or caused by man}. The sudden development of both types results from the collapse of the roof of a cavity or cavern in rock, or from the downward migration of unconsolidated deposits into solutionally enlarged openings in the top of bedrock. The occurrence of sinkholes resulting from bedrock roof collapses, in comparison with the occurrence of sinkholes resulting from downward migration of unconsolidated deposits, is rare. Induced sinkholes are of two types: those resulting from a decline in water level due to ground-water withdrawals and those resulting from construction. Sinkholes resulting from water-level declines are caused by loss of buoyant support, increase in velocity of water movement, water-level fluctuations, and induced recharge. Most induced sinkholes resulting from construction are caused by the diversion or impoundment of surface drainage over unconsolidated deposits resting on openings in the top of bedrock. Collapse mechanisms include loading, saturation, and piping. Assessment of existing or potential sinkhole problems at a site requires recognition of features associated with sinkhole development and knowledge of triggering mechanisms that cause sinkholes. Natural sinkhole development is generally not predictable. Induced sinkhole development is predictable in some instances, but is predictable only in the sense that it will occur in a particular area. The most predictable development results from dewatering by wells, quarries, and mines. Alternatives that allow avoiding or minimizing sinkhole hazards are most numerous when a problem or potential problem is recognized during site evaluation. The number of alternatives declines after the beginning of site development. Where sinkhole development is predictable, zoning of land use can minimize hazards.

Circular↗

USGS2025

Estimation of the accessible and useful resource base for electric-grade enhanced geothermal systems (EGS) resources of the Great Basin, USA

Scientists with the U.S. Geological Survey (USGS) recently completed a provisional assessment of the electric-grade geothermal resources associated with the low-permeability geologic formations of the Great Basin, USA, where resources are assumed to be accessible using enhanced geothermal systems (EGS) technologies (i.e., the engineering of sufficient permeability to facilitate efficient heat extraction). This assessment required estimation of the accessible resource base (electric-grade heat [>90ºC] at depths where drilling and stimulation are deemed achievable using current technology) and useful resource (heat that can be extracted from the accessible region). Electric-grade heat can be estimated from existing temperature models. The accessible resource base can be estimated as the electric-grade heat that exists at depths shallower than 6 km based on the limitations of current drilling and stimulation technologies, along with evidence for sustained natural fracture conductivity at depth. The useful part of the accessible heat can be estimated as the product of three efficiencies and factors: the heat extraction efficiency, the viable geology factor, and the reservoir spacing efficiency. The accessible and useful parts of the resource can be estimated in units of heat, or in units of electric power using an electrical conversion efficiency, which is a function of resource temperature. We also estimate the ranges for each of the efficiencies and describe the motivations behind the choice of best estimates used for the recent assessment. An analytic solution is provided for the useful resource above any depth (in units of electric power), where efficiency estimation assumes nearly steady heat extraction rates that cool reservoirs to 90ºC over 30 years of power generation.

Great Basin↗

USGS2011

Developing an institutional framework to incorporate ecosystem services into decision making-Proceedings of a workshop

The routine and effective incorporation of ecosystem services information into resource management decisions requires a careful consideration of the value of goods and services provided by natural systems. A multidisciplinary workshop was held in October 2008 on "Developing an Institutional Framework to Incorporate Ecosystem Services into Decision Making." This report summarizes that workshop, which focused on examining the relationship between an institutional framework and consideration of ecosystem services in resource management decision making. This workshop was the third in a series of three preconference workshops associated with ACES 2008 (A Conference on Ecosystem Services): Using Science for Decision Making in Dynamic Systems. These workshops were designed to explore the ACES 2008 theme on decision making and how the concept of ecosystem services can more effectively be incorporated into conservation, restoration, resource management, and development decisions. Preconference workshop 1, "Developing a Vision: Incorporating Ecosystem Services into Decision Making," was held April 15, 2008, in Cambridge, MA. In this workshop, participants addressed what would have to happen to make ecosystem services more routinely and effectively used in conservation, restoration, resource management, and development decisions, and identified some key challenges to developing the analytical framework (Hogan and others, 2009). Preconference workshop 2, "Developing an Analytical Framework: Incorporating Ecosystem Services into Decision Making," was held July 28, 2008, in Naples, FL, and focused on the analytical process and identification of research priorities for ecosystem services, their production and use, their spatial and temporal characteristics, their relationship with natural systems, and their interdependencies (Hogan and others, 2010). The summary presented here synthesizes the discussion at workshop 3 and considers how institutional structures and policy instruments can be used to achieve the vision developed in workshop 1, while recognizing the analytical capabilities and limitations identified in workshop 2. Our purpose was to identify how to use ecosystem service information more effectively and broadly in resource management and development decisions. We recognized the need to facilitate an integrated understanding of (1) the natural capital that produces ecosystem services; (2) the geospatial and temporal aspects of ecosystem service production, values, and use; (3) the value of ecosystem services (monetary and nonmonetary); and (4) institutional instruments, processes, and structures (property rights, laws, governance structures, and courts, for example). Interdisciplinary collaboration and understanding is beneficial and needs to engage stakeholders. The appropriate use of institutional structures, including markets, to integrate ecosystem services into decision making depends on the players and characteristics of the specific situation (such as stakeholders, the ecosystem, resources, and the political environment). Incorporating ecosystem service values into decisions requires consideration of place-based social, cultural, economic, and landscape characteristics and institutions. Thus, a single, prescribed solution will not work-various institutional strategies must be used in different situations. Market-based approaches require appropriate regulations, monitoring, and enforcement, depending on the situation and place. Further, market approaches will need to be coupled with nonmarket approaches into an integrated institutional framework.

Open-File Report↗

USGS1990

A finite-element model for simulation of two-dimensional steady-state ground-water flow in confined aquifers

A computer program based on the Galerkin finite-element method was developed to simulate two-dimensional steady-state ground-water flow in either isotropic or anisotropic confined aquifers. The program may also be used for unconfined aquifers of constant saturated thickness. Constant head, constant flux, and head-dependent flux boundary conditions can be specified in order to approximate a variety of natural conditions, such as a river or lake boundary, and pumping well. The computer program was developed for the preliminary simulation of ground-water flow in the Edwards-Trinity Regional aquifer system as part of the Regional Aquifer-Systems Analysis Program. Results of the program compare well to analytical solutions and simulations .from published finite-difference models. A concise discussion of the Galerkin method is presented along with a description of the program. Provided in the Supplemental Data section are a listing of the computer program, definitions of selected program variables, and several examples of data input and output used in verifying the accuracy of the program.

Open-File Report↗

USGS1990

Geohydrology and simulation of ground-water flow in the carbonate rocks of the Valley Creek basin, eastern Chester County, Pennsylvania

Sixty-eight percent of the 22.6-square-mile Valley Creek basin is underlain by Cambrian and Ordovician limestone and dolomite. Ground water flows through a network of interconnected secondary openings; primary porosity is virtually nonexistent. Some of these openings have been enlarged by solution. Secondary porosity and permeability exhibit great spatial variability, and the yield and specific capacity of wells are highly variable. The number of water-bearing zones decreases with depth. Fifty percent of water-bearing zones are encountered within 100 feet of the land surface, and 81 percent are within 200 feet. Most ground-water flow in the Valley Creek basin is local and discharges to nearby streams. Ground-water discharge comprised an average of 76 percent of the flow of Valley Creek during 1983--87, including both natural ground- water discharge and quarry pumpage discharged to Valley Creek. Discharge from the Cedar Hollow quarry comprised 21 to 26 percent of the base flow of Valley Creek; the average was 23 percent. The average natural base flow of Valley Creek would be 8 percent lower if the quarry were not operating. Regional ground-water flow is to the northeast to the Schuylkill River. On the western side of the Valley Creek basin, the ground-water divide is 1/2 mile west of the surface-water divide. An estimated 0.75 million gallons per day of ground water flows from the adjacent West Valley Creek basn eastward into the Valley Creek basin. A ground-water divide is not present on the eastern side of the basin; the water table slopes gently eastward toward the Schuylkill River. On the northeaster side, an estimated 1.76 million gallons per day of ground water flows northeastward out of the basin to the Schuylkill River beneath the surface-water divide. On the southeaster side, an estimated 0.85 million gallons per day of ground water flows beneath the surface-water divide into the basin. Annual water budgets and an average water budget were calculated for 1983-87 for the 20.8-square-mile area bove the streamflow-gaging station. Annual precipitation for 1983-87 ranged from 40.61 to 56.55 inches and averaged 47.25 inches; annual streamflow ranged from 15.55 to 28.57 inches and averaged 22.31 inches; annual evapotranspiration ranged from 18.21 to 24.83 inches and averaged 22.90 inches; and annual recharge ranged from 15.89 to 26.84 inches and averaged 21.04 inches. The Valley Creek basin was modeled as a two-dimensional water-table aquifer. Recharge to, ground-water flow through, and discharge from the rocks of Chester valley were simulated. In order to include the natural hydrologic boundaries of the ground-water-flwo system, the 66.4-square-mile area between the Brandywine Creek and the Schuylkill River was modeled. The model was calibrated under stead-state conditions using avareage recharge and evapotranspiration rates. Aquifer hydraulic conductivity was estimated from specific-capacity and quifer-test data. The average (1983-87) annual water budget for hte Valley Creek basin was simualted. The effect of increased ground-water development on base flow and underflow was simulated by locating a hypothetical well field produceing 4 million gallons per day in different parts of the basin. Pumpage from a well field near surface-water divides would induce as much as an additional 1.41 inches per year of underflow from an adjacent surface-water basin. Pumpage from a well field near the center of the basin would affect base flow more than underflow. Increased seepage of ground water into quarries as a result of their expansion was simulated as increased withdrawal by pumping. A 100-percent increase in the pumping rate of the Cedar Hollow quarry, from 3.93 to 7.86 million gallons per day, owuld reduce the natural base flow of Valley Creek by 18 percent. However, the quarry pumpage would be discharged to Valley Creek, thereby increasing the base flow at the gaging station by

Pennsylvania↗

USGS1992

Sampling design for spatially distributed hydrogeologic and environmental processes

A methodology for the design of sampling networks over space is proposed. The methodology is based on spatial random field representations of nonhomogeneous natural processes, and on optimal spatial estimation techniques. One of the most important results of random field theory for physical sciences is its rationalization of correlations in spatial variability of natural processes. This correlation is extremely important both for interpreting spatially distributed observations and for predictive performance. The extent of site sampling and the types of data to be collected will depend on the relationship of subsurface variability to predictive uncertainty. While hypothesis formulation and initial identification of spatial variability characteristics are based on scientific understanding (such as knowledge of the physics of the underlying phenomena, geological interpretations, intuition and experience), the support offered by field data is statistically modelled. This model is not limited by the geometric nature of sampling and covers a wide range in subsurface uncertainties. A factorization scheme of the sampling error variance is derived, which possesses certain atttactive properties allowing significant savings in computations. By means of this scheme, a practical sampling design procedure providing suitable indices of the sampling error variance is established. These indices can be used by way of multiobjective decision criteria to obtain the best sampling strategy. Neither the actual implementation of the in-situ sampling nor the solution of the large spatial estimation systems of equations are necessary. The required values of the accuracy parameters involved in the network design are derived using reference charts (readily available for various combinations of data configurations and spatial variability parameters) and certain simple yet accurate analytical formulas. Insight is gained by applying the proposed sampling procedure to realistic examples related to sampling problems in two dimensions.

Advances in Water Resources↗

USGS1990

Application of a hollow-fiber, tangential-flow device for sampling suspended bacteria and particles from natural waters

The design and application of a hollow-fiber tangential-flow filtration device has been used to concentrate bacteria and suspended particles from large volume surface water and groundwater samples (i.e., hundreds of liters). Filtrate tlux rates (4–8 L min −1 ) are equal to or faster than those of other devices that are based on continuous flow centrifugation and plate and frame filtration. Particle recovery efficiencies for inorganic particles (approximately 90%) were similar to other dewatering devices, but microbial cell recoveries (30–90%) were greatly improved by this technique relative to other currently available methods. Although requirements for operation and maintenance of the device are minimal, its size, as with other dewatering devices, limits its applicability at remote sample sites. Nevertheless, it has proven useful for sample collection in studies involving microbial transport and analysis of particle-associated trace inorganic solutes.

Journal of Environmental Quality↗