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Spatial and temporal variations in landscape evolution: historic and longer-term sediment flux through global catchments

Sediment generation and transport through terrestrial catchments influence soil distribution, geochemical cycling of particulate and dissolved loads, and the character of the stratigraphic record of Earth history. To assess the spatiotemporal variation in landscape evolution, we compare global compilations of stream gauge–derived () and cosmogenic radionuclide (CRN)–derived (predominantly 10 Be; ) denudation of catchments (mm/yr) and sediment load of rivers (Mt/yr). Stream gauges measure suspended sediment loads of rivers during several to tens of years, whereas CRNs provide catchment-integrated denudation rates at 10 2 –10 5 -yr time scales. Stream gauge–derived and CRN-derived sediment loads in close proximity to one another (<500 km) exhibit broad similarity ( stream gauge samples; CRN samples). Nearly two-thirds of CRN-derived sediment loads exceed historic loads measured at the same locations (). Excessive longer-term sediment loads likely are a result of longer-term recurrence of large-magnitude sediment-transport events. Nearly 80% of sediment loads measured at approximately the same locations exhibit stream gauge loads that are within an order of magnitude of CRN loads, likely as a result of the buffering capacity of large flood plains. Catchments in which space for deposition exceeds sediment supply have greater buffering capacity. Superior locations in which to evaluate anthropogenic influences on landscape evolution might be buffered catchments, in which temporary storage of sediment in flood plains can provide stream gauge–based sediment loads and denudation rates that are applicable over longer periods than the durations of gauge measurements. The buffering capacity of catchments also has implications for interpreting the stratigraphic record; delayed sediment transfer might complicate the stratigraphic record of external forcings and catchment modification.

The Journal of Geology

Effectiveness of vegetation buffers surrounding playa wetlands at contaminant and sediment amelioration

Playa wetlands, the dominant hydrological feature of the semi-arid U.S. High Plains providing critical ecosystem services, are being lost and degraded due to anthropogenic alterations of the short-grass prairie landscape. The primary process contributing to the loss of playas is filling of the wetland through accumulation of soil eroded and transported by precipitation from surrounding cultivated watersheds. We evaluated effectiveness of vegetative buffers surrounding playas in removing metals, nutrients, and dissolved/suspended sediments from precipitation runoff. Storm water runoff was collected at 10-m intervals in three buffer types (native grass, fallow cropland, and Conservation Reserve Program). Buffer type differed in plant composition, but not in maximum percent removal of contaminants. Within the initial 60 m from a cultivated field, vegetation buffers of all types removed >50% of all measured contaminants, including 83% of total suspended solids (TSS) and 58% of total dissolved solids (TDS). Buffers removed an average of 70% of P and 78% of N to reduce nutrients entering the playa. Mean maximum percent removal for metals ranged from 56% of Na to 87% of Cr. Maximum removal was typically at 50 m of buffer width. Measures of TSS were correlated with all measures of metals and nutrients except for N, which was correlated with TDS. Any buffer type with >80% vegetation cover and 30–60 m in width would maximize contaminant removal from precipitation runoff while ensuring that playas would continue to function hydrologically to provide ecosystem services. Watershed management to minimize erosion and creations of vegetation buffers could be economical and effective conservation tools for playa wetlands.

Journal of Environmental Management

Formation of natural gas hydrates in marine sediments 1. Conceptual model of gas hydrate growth conditioned by host sediment properties

The stability of submarine gas hydrates is largely dictated by pressure and temperature, gas composition, and pore water salinity. However, the physical properties and surface chemistry of deep marine sediments may also affect the thermodynamic state, growth kinetics, spatial distributions, and growth forms of clathrates. Our conceptual model presumes that gas hydrate behaves in a way analogous to ice in a freezing soil. Hydrate growth is inhibited within fine-grained sediments by a combination of reduced pore water activity in the vicinity of hydrophilic mineral surfaces, and the excess internal energy of small crystals confined in pores. The excess energy can be thought of as a "capillary pressure" in the hydrate crystal, related to the pore size distribution and the state of stress in the sediment framework. The base of gas hydrate stability in a sequence of fine sediments is predicted by our model to occur at a lower temperature (nearer to the seabed) than would be calculated from bulk thermodynamic equilibrium. Capillary effects or a build up of salt in the system can expand the phase boundary between hydrate and free gas into a divariant field extending over a finite depth range dictated by total methane content and pore-size distribution. Hysteresis between the temperatures of crystallization and dissociation of the clathrate is also predicted. Growth forms commonly observed in hydrate samples recovered from marine sediments (nodules, and lenses in muds; cements in sands) can largely be explained by capillary effects, but kinetics of nucleation and growth are also important. The formation of concentrated gas hydrates in a partially closed system with respect to material transport, or where gas can flush through the system, may lead to water depletion in the host sediment. This "freeze-drying" may be detectable through physical changes to the sediment (low water content and overconsolidation) and/or chemical anomalies in the pore waters and metastable presence of free gas within the normal zone of hydrate stability.

Journal of Geophysical Research B: Solid Earth

Uncertainty in critical source area predictions from watershed-scale hydrologic models

Watershed-scale hydrologic models are frequently used to inform conservation and restoration efforts by identifying critical source areas (CSAs; alternatively 'hotspots'), defined as areas that export relatively greater quantities of nutrients and sediment. The CSAs can then be prioritized or ‘targeted’ for conservation and restoration to ensure efficient use of limited resources. However, CSA simulations from watershed-scale hydrologic models may be uncertain and it is critical that the extent and implications of this uncertainty be conveyed to stakeholders and decision makers. We used an ensemble of four independently developed Soil and Water Assessment Tool (SWAT) models and a SPAtially Referenced Regression On Watershed attributes (SPARROW) model to simulate CSA locations for flow, phosphorus, nitrogen, and sediment within the ~17,000-km 2 Maumee River watershed at the HUC-12 scale. We then assessed uncertainty in CSA simulations determined as the variation in CSA locations across the models. Our application of an ensemble of models - differing with respect to inputs, structure, and parameterization - facilitated an improved accounting of CSA prediction uncertainty. We found that the models agreed on the location of a subset of CSAs, and that these locations may be targeted with relative confidence. However, models more often disagreed on CSA locations. On average, only 16%–46% of HUC-12 subwatersheds simulated as a CSA by one model were also simulated as a CSA by a different model. Our work shows that simulated CSA locations are highly uncertain and may vary substantially across models. Hence, while models may be useful in informing conservation and restoration planning, their application to identify CSA locations would benefit from comprehensive uncertainty analyses to avoid inefficient use of limited resources.

Ohio

Assessing aquifer contamination risk using immunoassay: Trace analysis of atrazine in unsaturated zone sediments

The vulnerability of a shallow aquifer in south-central Kansas to contamination by atrazine (2-chloro-4-ethylamino-6-isopropylamines-triazine) was assessed by analyzing unsaturated zone soil and sediment samples from about 60 dryland and irrigated sites using an ultrasensitive immunoassay (detection level of 0.02 µg/kg) with verification by gas chromatography/mass spectrometry (GC/MS). Samples were collected at depths of 0 to 1.2 m (i.e., the root zone), 1.2 to 1.8 m, and 1.8 to 3.0 m during two time periods-prior to planting and after harvest of crops. About 75% of the samples contained detectable concentrations of parent atrazine. At the shallow sampling depth, atrazine concentrations ranged from 0.5 to approximately 12 µg/kg. Atrazine concentrations at the intermediate (1.2-1.8 m) depth generally were <1.0 µg/kg, with most of the concentrations <0.10 µg/kg, which suggests substantial degradation of parent atrazine in the root zone. Likewise, atrazine concentrations front the deepest (1.8-3.0 m) depth ranged from <0.02 to 0.33 µg/kg. The metabolite deethylatrazine (2-amino-4-chloro-6- isopropylamine-s-triazine) was detected by GC/MS only in 2 of 60 samples with concentrations of 1.4 and 1.5 µg/kg. The reconnaissance survey shows that, in spite of atrazine use ranging from 1 to 5 or more years, there does not appear to he a significant buildup of parent compound below the root zone. Therefore, the unsaturated zone does not appear to be a major storage compartment of atrazine contamination for the underlying shallow aquifer.

Journal of Environmental Quality

Carbon and sediment accumulation in the Everglades (USA) during the past 4000 years: rates, drivers, and sources of error

Tropical and sub-tropical wetlands are considered to be globally important sources for greenhouse gases but their capacity to store carbon is presumably limited by warm soil temperatures and high rates of decomposition. Unfortunately, these assumptions can be difficult to test across long timescales because the chronology, cumulative mass, and completeness of a sedimentary profile are often difficult to establish. We therefore made a detailed analysis of a core from the principal drainage outlet of the Everglades of South Florida, to assess these problems and determine the factors that could govern carbon accumulation in this large sub-tropical wetland. Accelerator mass spectroscopy dating provided direct evidence for both hard-water and open-system sources of dating errors, whereas cumulative mass varied depending upon the type of method used. Radiocarbon dates of gastropod shells, nevertheless, seemed to provide a reliable chronology for this core once the hard-water error was quantified and subtracted. Long-term accumulation rates were then calculated to be 12.1 g m -2 yr -1 for carbon, which is less than half the average rate reported for northern and tropical peatlands. Moreover, accumulation rates remained slow and relatively steady for both organic and inorganic strata, and the slow rate of sediment accretion ( 0.2 mm yr -1 ) tracked the correspondingly slow rise in sea level (0.35 mm yr -1 ) reported for South Florida over the past 4000 years. These results suggest that sea level and the local geologic setting may impose long-term constraints on rates of sediment and carbon accumulation in the Everglades and other wetlands.

Florida

Extreme precipitation across adjacent burned and unburned watersheds reveals impacts of low severity wildfire on debris-flow processes

In steep landscapes, wildfire-induced changes to soil and vegetation can lead to extreme and hazardous geomorphic responses, including debris flows. The wildfire-induced mechanisms that lead to heightened geomorphic responses, however, depend on many site-specific factors including regional climate, vegetation, soil texture, and soil burn severity. As climate and land use change drive changes in fire regime, there is an increasing need to understand how fire alters geomorphic responses, particularly in areas where fire has been historically infrequent. Here, we examine differences in the initiation, magnitude, and particle-size distribution of debris flows that initiated within the area burned by the 2019 Woodbury Fire in central Arizona, USA, and those that initiated in a nearby unburned area. Despite similar rainfall intensities, unburned watersheds were less likely to produce debris flows. Debris flows in unburned areas initiated from both runoff and shallow landslides, while debris flows only initiated from runoff-related processes in the burned area. The grain-size distribution making up the matrix of debris-flow deposits within the burned area generally had a lower ratio of sand to silt relative to debris flows that initiated in the unburned area, though there were no systematic differences in the coarse fraction of debris-flow sediment between burned and unburned areas. Results help expand our ability to predict postwildfire debris-flow activity in a wider range of settings, specifically the Sonoran Desert ecoregion, and provide general insight into the impact of wildfire on geomorphic processes in steep terrain.

Arizona

Forecasting the effects of coastal protection and restoration projects on wetland morphology in coastal Louisiana under multiple environmental uncertainty scenarios

Few landscape scale models have assessed the effects of coastal protection and restoration projects on wetland morphology while taking into account important uncertainties in environmental factors such as sea-level rise (SLR) and subsidence. In support of Louisiana's 2012 Coastal Master Plan, we developed a spatially explicit wetland morphology model and coupled it with other predictive models. The model is capable of predicting effects of protection and restoration projects on wetland area, landscape configuration, surface elevation, and soil organic carbon (SOC) storage under multiple environmental uncertainty scenarios. These uncertainty scenarios included variability in parameters such as eustatic SLR (ESLR), subsidence rate, and Mississippi River discharge. Models were run for a 2010–2060 simulation period. Model results suggest that under a “future-without-action” condition (FWOA), coastal Louisiana is at risk of losing between 2118 and 4677 km 2 of land over the next 50 years, but with protection and restoration projects proposed in the Master Plan, between 40% and 75% of that loss could be mitigated. Moreover, model results indicate that under a FWOA condition, SOC storage (to a depth of 1 m) could decrease by between 108 and 250 million metric tons, a loss of 12% to 30% of the total coastwide SOC, but with the Master Plan implemented, between 35% and 74% of the SOC loss could be offset. Long-term maintenance of project effects was best attained in areas of low SLR and subsidence, with a sediment source to support marsh accretion. Our findings suggest that despite the efficacy of restoration projects in mitigating losses in certain areas, net loss of wetlands in coastal Louisiana is likely to continue. Model results suggest certain areas may eventually be lost regardless of proposed restoration investment, and, as such, other techniques and strategies of adaptation may have to be utilized in these areas.

Louisiana

Incorporating temperature into seepage loss estimates for a large unlined irrigation canal

Quantifying seepage losses from unlined irrigation canals is necessary to improve water use and conservation. The use of heat as a tracer is widely used in quantifying seepage rates across the sediment–water interface. In this study, field observations and two-dimensional numerical models were used to simulate seepage losses during the 2018 and 2019 irrigation season in the Truckee Canal system. Nineteen transects were instrumented with temperature probes and stage recording devices for inverse modeling to derive seepage flux and volumetric losses over the 39 km length of canal. The numerical models for each transect were calibrated and validated using the two-year dataset. Soil zones and observation data were used in each numerical model to help guide calibration of vertical and lateral heat and fluid fluxes. Model simulations were used to derive multivariable regression equations that consider stage, temperature, and hydraulic gradient. The results demonstrate the value of long-term datasets that illustrate the seasonality of groundwater levels, siltation, stage, and temperature on seepage rates. Seepage rates estimated by the numerical models range from 0.16 to 4.6 m 3 /d m −1 . Total annual volumetric losses estimated for 2018 and 2019 were 1.6 × 10 -2 to 1.2 × 10 -2 km 3 , respectively. The seepage losses estimated by this study account for 32 % to 41 % of the inflow volumes. Regression models were able to reproduce seepage time-series simulated by the numerical models reasonably well. In arid environments, water diverted into irrigation canals may be influenced by seasonal variations in temperature sufficient to influence the water accounting of conveyed surface flows.

Nevada

Assessment of crop growth and soil water modules in SWAT2000 using extensive field experiment data in an irrigation district of the Yellow River Basin

SWAT, a physically-based, hydrological model simulates crop growth, soil water and groundwater movement, and transport of sediment and nutrients at both the process and watershed scales. While the different versions of SWAT have been widely used throughout the world for agricultural and water resources applications, little has been done to test the performance, variability, and transferability of the parameters in the crop growth, soil water, and groundwater modules in an integrated way with multiple sets of field experimental data at the process scale. Using an multiple years of field experimental data of winter wheat (Triticum aestivum L.) in the irrigation district of the Yellow River Basin, this paper assesses the performance of the plant-soil-groundwater modules and the variability and transferability of SWAT2000. Comparison of the simulated results by SWAT to the observations showed that SWAT performed quite unsatisfactorily in LAI predictions during the senescence stage, in yield predictions, and in soil-water estimation under dry soil-profile conditions. The unsatisfactory performance in LAI prediction might be attributed to over-simplified senescence modeling; in yield prediction to the improper computation of the harvest index; and in soil water under dry conditions to the exclusion of groundwater evaporation from the soil water balance in SWAT. In this paper, improvements in crop growth, soil water, and groundwater modules in SWAT were implemented. The saturated soil profile was coupled to the oscillating groundwater table. A variable evaporation coefficient taking into account soil water deficit index, groundwater depth, and crop root depth was used to replace the fixed coefficient in computing groundwater evaporation. The soil water balance included the groundwater evaporation. The modifications improved simulations of crop evapotranspiration and biomass as well as soil water dynamics under dry soil-profile conditions. The evaluation shows that the crop growth and soil water components of SWAT could be further refined to better simulate the hydrology of agricultural watersheds. ?? 2008 Elsevier B.V. All rights reserved.

Journal of Hydrology

Combining eddy covariance and chamber methods to better constrain CO2 and CH4 fluxes across a heterogeneous restored tidal wetland

Tidal wetlands play an important role in global carbon cycling by storing carbon in sediment at millennial time scales, transporting dissolved carbon into coastal waters, and contributing significantly to global CH 4 budgets. However, these ecosystems' greenhouse gas monitoring and predictions are challenging due to spatial heterogeneity and tidal flooding. We utilized eddy covariance and chamber measurements to quantify fluxes of CO 2 and CH 4 at a restored tidal saltmarsh across spatial and temporal scales. Eddy covariance data revealed that the site was a strong net sink for CO 2 (−387 g C-CO 2 m −2 yr −1 , SD = 46) and a small net source of CH 4 (0.7 g C-CH 4 m −2 yr −1 , SD = 0.4). After partitioning net ecosystem exchange of CO 2 into gross primary production and ecosystem respiration, we found that high net uptake of CO 2 was due to low respiration emissions rather than high photosynthetic rates. We also found that respiration rates varied between land covers with increased respiration in mudflats compared to vegetated areas. Daytime soil chamber measurements revealed that the greatest CO 2 emission was from higher elevation mudflat soils (0.5 μmol m −2 s −1 , SE = 1.3) and CH 4 emission was greatest from lower elevation Spartina foliosa soils (1.6 nmol m −2 s −1 , SD = 8.2). Overall, these results highlight the importance of the relationships between wetland plant community and elevation, and inundation for CO 2 and CH 4 fluxes. Future research should include the use of high-resolution imagery, automated chambers, and a focus on quantifying carbon exported in tidal waters.

California

Nutrients and sediment in frozen-ground runoff from no-till fields receiving liquid-dairy and solid-beef manures

Nutrients and sediment in surface runoff from frozen agricultural fields were monitored within three small (16.0 ha [39.5 ac] or less), adjacent basins at a no-till farm in southwest Wisconsin during four winters from 2003 to 2004 through 2006 to 2007. Runoff depths and flow-weighted constituent concentrations were compared to determine the impacts of surface-applied liquid-dairy or solid-beef manure to frozen and/or snow-covered ground. Despite varying the manure type and the rate and timing of applications, runoff depths were not significantly different among basins within each winter period. Sediment losses were low (generally less than 22 kg ha −1 [20 lb ac −1 ] in any year) and any statistical differences in sediment concentrations among basins were not related to the presence or absence of manure or the amount of runoff. Concentrations and losses of total nitrogen and total phosphorus were significantly increased in basins that had either manure type applied less than one week preceding runoff. These increases occurred despite relatively low application rates. Lower concentrations and losses were measured in basins that had manure applied in fall and early winter and an extended period of time (months) had elapsed before the first runoff event. The highest mean, flow-weighted concentrations of total nitrogen (31.8 mg L −1 ) and total phosphorus (10.9 mg L −1 ) occurred in winter 2003 to 2004, when liquid-dairy manure was applied less than one week before runoff. On average, dissolved phosphorus accounted for over 80% of all phosphorus measured in runoff during frozen-ground periods. The data collected as part of this study add to the limited information on the quantity and quality of frozen-ground runoff at field edges, and the results highlight the importance of manure management decisions during frozen-ground periods to minimize nutrients lost in surface runoff.

Wisconsin

Environmental fate and effects of the lampricide bayluscide: a review

Bayluscide is an additive to TFM that increases the effectiveness of TFM as a lampricide. A review of the literature was undertaken to determine the environmental fate and effects of Bayluscide. Niclosamide (2', 5-dichloro-4'-nitrosalicylanilide), the active ingredient of Bayluscide, degrades rapidly in natural water and sediment systems, however, the rate of degradation is very slow in autoclaved samples. This difference suggests that degradation under laboratory conditions is dependent on microbial activity and hydrolysis plays a minor role in degradation of niclosamide. The major degradation product of niclosamide has been reported to be aminoniclosamide (2',5-dichloro-4'-aminosalicylanilide), which represented more than 50% of the residues extractable from sediments. Significantly more of the chemical is adsorbed to sediments with higher organic content and at lower pH's. The mobility of niclosamide in soil can be characterized as slight to medium; the estimated leaching distance would range from 0 to > 25 cm depending on the soil type and pH. The active ingredient of Bayluscide (niclosamide) is decomposed by ultra-violet light depending on the intensity and duration of the exposure. The uptake of residues by most invertebrates exposed to super(14)C-niclosamide is fairly rapid and equilibrium is reached within 24 h. About 90% of the accumulated residues were lost within 48 h after the organisms were transferred to clean flowing water. As with invertebrates, fish rapidly accumulate and eliminate residues of niclosamide. Three distinct residues were isolated from the extracts of edible fillet tissue; parent niclosamide, the glucuronide conjugate of niclosamide, and the sulfate ester of niclosamide. Aquatic plants and agricultural crops do not appear to be adversely affected at concentrations of Bayluscide used for lamprey or snail control. Mayflies (Hexagenia sp.). tend to be susceptible to TFM, but are relatively resistant to the effects of exposure to Bayluscide. Bayluscide was originally developed as a molluscicide to eliminate snails. Therefore, it is not surprising that mollusks are extremely sensitive to Bayluscide. Oral, dermal, and ocular administration of Bayluscide to mammals resulted in no clinical signs of systemic toxicity. Tests of the chronic effects of Bayluscide indicated that it is not mutagenic or carcinogenic. Bayluscide is not persistent in the environment; it breaks down in natural water and sediment systems through hydrolysis, photolysis, and microbial degradation. Given the limited use and tight control maintained by the U.S. Fish and Wildlife Service during applications of lampricides, Bayluscide presents minimal risk to human health and safety of the environment.

Journal of Great Lakes Research

The role of shoreland development and commercial cranberry farming in a lake in Wisconsin, USA

Musky Bay in Lac Courte Oreilles, Wisconsin, USA, is currently eutrophic. This large, shallow bay of an oligotrophic lake possesses the densest aquatic plant growth and a floating algal mat. Paleoecological reconstructions encompassing the last 130 years, were based on multiproxy analyses of sediment cores from three coring sites, two within the bay and one in the lake itself. These data were compared to historical records of the construction and expansion of two commercial cranberry bogs and shoreline residential homes to identify temporal and causal relations of eutrophication. The proxies investigated included: minor and trace elements; biogenic silica; and the diatom community. Post-depositional diagenesis of organic carbon, nitrogen, and phosphorus in the upper 30 cm of the core obscured records of historical ambient nutrient concentrations in the bay obviating their usefulness for this purpose. In contrast, calcium, magnesium, and potassium concentration profiles appeared to reflect runoff of soil amendments applied to the cranberry bogs and aerial fertilizer spraying over the eastern bog adjacent to Musky Bay. The increase in aluminum content since about 1930 coincided with the historical trend in shoreland development and construction of the original commercial cranberry farm. The biogenic silica profile recorded a steady increase of nutrients to Musky Bay over the last several decades. Stratigraphic changes in the diatom community indicated that nutrient input began to increase in the 1940s and accelerated in the mid-1990s with the onset of a noxious floating algal mat. The diatom community indicates the bay has possessed a significant macrophyte community for at least the last 200 years, but increased nutrient input was manifested by a change in the composition, and an increase in the density of the epiphytic diatom community. Cranberry farming appeared to be the major source of nutrients because the diatom community changes occurred prior to the significant increase in residential housing.

Journal of Paleolimnology

Satellite assessment of winter cover crop and conservation tillage outcomes to support adaptive management in working landscapes

The use of winter cover crops and conservation tillage are agricultural practices promoted to reduce nutrient and sediment loss from cropland, improve soil health, increase infiltration, and support farm nutrient cycling and ecosystem services. However, environmental performance of these practices is variable in the working farm landscape. The Lower Chesapeake Bay research project within the USDA Long-Term Agroecosystem Research (LTAR) network has collaboratively developed satellite remote sensing algorithms to measure the performance and phenology of winter cover crops (aboveground biomass, nitrogen content, fractional cover, and emergence and termination dates) using no-cost Harmonized Landsat and Sentinel-2 multispectral satellite imagery. This research supports annual operational assessment of >28,000 fields per year in four states. Results document the impacts of agronomic management on conservation outcomes, support adaptive management of incentive payment structures, and can reduce the workload for conservation district staff by remotely verifying cover crop management. Additionally, super-spectral satellite applications have been developed to accurately map crop residue cover by measuring lignocellulose absorption in shortwave infrared wavelengths, producing a 7-year time series of tillage intensity maps for the Delmarva Peninsula. These remote sensing products can be used in decision support and modeling to estimate changes in nutrient, sediment, and carbon cycling resulting from conservation practice implementation in the working farm landscape. This manuscript provides an overview of remote sensing research findings and applications associated with the USDA LTAR and Conservation Effects Assessment Projects (CEAP), documenting a variety of previously published outcomes with update and expansion of techniques using additional unpublished data and analyses as appropriate.

Maryland

Effects of upland disturbance and instream restoration on hydrodynamics and ammonium uptake in headwater streams

Delivery of water, sediments, nutrients, and organic matter to stream ecosystems is strongly influenced by the catchment of the stream and can be altered greatly by upland soil and vegetation disturbance. At the Fort Benning Military Installation (near Columbus, Georgia), spatial variability in intensity of military training results in a wide range of intensities of upland disturbance in stream catchments. A set of 8 streams in catchments spanning this upland disturbance gradient was selected for investigation of the impact of disturbance intensity on hydrodynamics and nutrient uptake. The size of transient storage zones and rates of NH4+ uptake in all study streams were among the lowest reported in the literature. Upland disturbance did not appear to influence stream hydrodynamics strongly, but it caused significant decreases in instream nutrient uptake. In October 2003, coarse woody debris (CWD) was added to 1/2 of the study streams (spanning the disturbance gradient) in an attempt to increase hydrodynamic and structural complexity, with the goals of enhancing biotic habitat and increasing nutrient uptake rates. CWD additions had positive short-term (within 1 mo) effects on hydrodynamic complexity (water velocity decreased and transient storage zone cross-sectional area, relative size of the transient storage zone, fraction of the median travel time attributable to transient storage over a standardized length of 200 m, and the hydraulic retention factor increased) and nutrient uptake (NH4+ uptake rates increased). Our results suggest that water quality in streams with intense upland disturbances can be improved by enhancing instream biotic nutrient uptake capacity through measures such as restoring stream CWD. ?? 2007 by The North American Benthological Society.

Journal of the North American Benthological Societ

Hydraulic anisotropy characterization of pneumatic-fractured sediments using azimuthal self potential gradient

The pneumatic fracturing technique is used to enhance the permeability and porosity of tight unconsolidated soils (e.g. clays), thereby improving the effectiveness of remediation treatments. Azimuthal self potential gradient (ASPG) surveys were performed on a compacted, unconsolidated clay block in order to evaluate their potential to delineate contaminant migration pathways in a mechanically-induced fracture network. Azimuthal resistivity (ARS) measurements were also made for comparative purposes. Following similar procedures to those used in the field, compressed kaolinite sediments were pneumatically fractured and the resulting fracture geometry characterized from strike analysis of visible fractures combined with strike data from optical borehole televiewer (BHTV) imaging. We subsequently injected a simulated treatment (electrolyte/dye) into the fractures. Both ASPG and ARS data exhibit anisotropic geoelectric signatures resulting from the fracturing. Self potentials observed during injection of electrolyte are consistent with electrokinetic theory and previous laboratory results on a fracture block model. Visual (polar plot) analysis and linear regression of cross plots show ASPG lobes are correlated with azimuths of high fracture strike density, evidence that the ASPG anisotropy is a proxy measure of hydraulic anisotropy created by the pneumatic fracturing. However, ARS data are uncorrelated with fracture strike maxima and resistivity anisotropy is probably dominated by enhanced surface conduction along azimuths of weak 'starter paths' formed from pulverization of the clay and increases in interfacial surface area. We find the magnitude of electrokinetic SP scales with the applied N2 gas pressure gradient (??PN2) for any particular hydraulically-active fracture set and that the positive lobe of the ASPG anomaly indicates the flow direction within the fracture network. These findings demonstrate the use of ASPG in characterizing the effectiveness of (1) pneumatic fracturing and (2) defining likely flow directions of remedial treatments in unconsolidated sediments and rock. ?? 2008 Elsevier B.V. All rights reserved.

Journal of Contaminant Hydrology

Sediment and nutrient delivery from thermokarst features in the foothills of the North Slope, Alaska: Potential impacts on headwater stream ecosystems

Permafrost is a defining characteristic of the Arctic environment. However, climate warming is thawing permafrost in many areas leading to failures in soil structure called thermokarst. An extensive survey of a 600 km2 area in and around the Toolik Lake Natural Research Area (TLNRA) revealed at least 34 thermokarst features, two thirds of which were new since ???1980 when a high resolution aerial survey of the area was done. Most of these thermokarst features were associated with headwater streams or lakes. We have measured significantly increased sediment and nutrient loading from thermokarst features to streams in two well-studied locations near the TLNRA. One small thermokarst gully that formed in 2003 on the Toolik River in a 0.9 km2 subcatchment delivered more sediment to the river than is normally delivered in 18 years from 132 km2 in the adjacent upper Kuparuk River basin (a long-term monitoring reference site). Ammonium, nitrate, and phosphate concentrations downstream from a thermokarst feature on Imnavait Creek increased significantly compared to upstream reference concentrations and the increased concentrations persisted over the period of sampling (1999-2005). The downstream concentrations were similar to those we have used in a long-term experimental manipulation of the Kuparuk River and that have significantly altered the structure and function of that river. A subsampling of other thermokarst features from the extensive regional survey showed that concentrations of ammonium, nitrate, and phosphate were always higher downstream of the thermokarst features. Our previous research has shown that even minor increases in nutrient loading stimulate primary and secondary production. However, increased sediment loading could interfere with benthic communities and change the responses to increased nutrient delivery. Although the terrestrial area impacted by thermokarsts is limited, the aquatic habitat altered by these failures can be extensive. If warming in the Arctic foothills accelerates thermokarst formation, there may be substantial and wide-spread impacts on arctic stream ecosystems that are currently poorly understood. Copyright 2008 by the American Geophysical Union.

Journal of Geophysical Research G: Biogeosciences