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At least 163 records · Page 9Linked to original sources

Characterization of tropospheric desert aerosols at solar wavelengths by multispectral radiometry from Landsat

Characteristics of tropospheric desert aerosols are derived by comparing nadir spectral reflectivities computed from the radiative transfer models with reflectivities measured from Landsat. Over the ocean, reflectivities are compared, but over land the comparison is carried out by determining the ratios of the nadir reflectivity of the surface-atmosphere system over heavy aerosol concentration to the reflectivity of the underlying surface. This remote sensing technique is found to be a sensitive approach for measuring n 2 , the imaginary part of the refractive index. The desert aerosols under study, in the Iran and Pakistan area, are essentially pure scatterers, inasmuch as an n 2 value of 0.001±0.001 was determined for each of the four Landsat spectral bands, that is, for a spectral interval from 0.5 to 1.1 μm.

Journal of Geophysical Research C: Oceans↗

Retention of an atmosphere on early Mars

The presence of valley networks and indications of high erosion rates in ancient terrains on Mars suggest that Mars was warm and wet during heavy bombardment. Various processes that could occur on early Mars were integrated into a self-consistent model to determine what circumstances might lead to warm temperatures during and at the end of heavy bombardment. Included were weathering and burial of CO 2 as carbonates, impact erosion, sputtering, and recycling of CO 2 back into the atmosphere by burial and heating. The models suggest that despite losses from the atmosphere by weathering and impact erosion, Mars could retain a 0.5 to 1 bar atmosphere at the end of heavy bombardment partly because weathering temporarily sequesters CO 2 in the ground and protects it from impact erosion while the impact rate is declining and impact erosion is becoming less effective. Because of the low output of the early Sun, surface temperatures can be above freezing only for a very efficient greenhouse, such as that suggested by Forget and Pierrehumbert [1997]. With weak greenhouse models, temperatures are below freezing throughout heavy bombardment, and such a large amount of CO 2 is left in the atmosphere at the end of heavy bombardment that it is difficult to eliminate subsequently to arrive at the present surface inventory. With strong greenhouse models, temperatures are well above freezing during heavy bombardment and drop to close to freezing at the end of heavy bombardment, at which time the atmosphere contains 0.5 to 1 bar of CO 2 . This can be largely eliminated subsequently by sputtering and low-temperature weathering. Such a model is consistent with the change in erosion rate and the declining rate of valley formation at the end of heavy bombardment. Conditions that favor warm temperatures at the end of heavy bombardment are an efficient greenhouse, low weathering rates, low impact erosion rates, and a smaller fraction of heat lost by conduction as opposed to transport of lava to the surface.

Journal of Geophysical Research E: Planets↗

Atmospheric organochlorine pollutants and air-sea exchange of hexachlorocyclohexane in the Bering and Chukchi Seas

Organochlorine pesticides have been found in Arctic fish, marine mammals, birds, and plankton for some time. The lack of local sources and remoteness of the region imply long-range transport and deposition of contaminants into the Arctic from sources to the south. While on the third Soviet-American Joint Ecological Expedition to the Bering and Chukchi Seas (August 1988), high-volume air samples were taken and analyzed for organochlorine pesticides. Hexachlorocyclohexane (HCH), hexachlorobenzene, polychlorinated camphenes, and chlordane (listed in order of abundance, highest to lowest) were quantified. The air-sea gas exchange of HCH was estimated at 18 stations during the cruise. Average alpha-HCH concentrations in concurrent atmosphere and surface water samples were 250 pg m-3 and 2.4 ng L-1, respectively, and average gamma-HCH concentrations were 68 pg m-3 in the atmosphere and 0.6 ng L-1 in surface water. Calculations based on experimentally derived Henry's law constants showed that the surface water was undersaturated with respect to the atmosphere at most stations (alpha-HCH, average 79% saturation; gamma-HCH, average 28% saturation). The flux for alpha-HCH ranged from -47 ng m-2 day-1 (sea to air) to 122 ng m-2 d-1 (air to sea) and averaged 25 ng m-2 d-1 air to sea. All fluxes of gamma-HCH were from air to sea, ranged from 17 to 54 ng m-2 d-1, and averaged 31 ng m-2 d-1.

Journal of Geophysical Research↗

Properties and distribution of paired candidate stony meteorites at Meridiani Planum

The Mars Exploration Rover Opportunity investigated four rocks, informally dubbed Barberton, Santa Catarina, Santorini, and Kasos, that are possible stony meteorites. Their chemical and mineralogical composition is similar to the howardite, eucrite, and diogenite group but with additional metal, similar to mesosiderite silicate clasts. Because of their virtually identical composition and because they appear to represent a relatively rare group of meteorites, they are probably paired. The four rocks were investigated serendipitously several kilometers apart, suggesting that Opportunity is driving across a larger population of similar rock fragments, maybe a meteorite strewn field. Small amounts of ferric Fe are a result of weathering. We did not observe evidence for fusion crusts. Four iron meteorites were found across the same area. Although mesosiderites are stony irons, a genetic link to these irons is unlikely. The stony meteorites probably fell later than the irons. The current atmosphere is sufficiently dense to land such meteorites at shallow entry angles, and it would disperse fragments over several kilometers upon atmospheric breakup. Alternatively, dispersion by spallation from an impacting meteoroid may have occurred. Santa Catarina and a large accumulation of similar rocks were found at the rim of Victoria crater. It is possible that they are associated with the impactor that created Victoria crater, but our limited knowledge about their distribution cannot exclude mere coincidence.

Journal of Geophysical Research E: Planets↗

Detection and monitoring of H2O and CO2 ice clouds on Mars

We have developed an observational scheme for the detection and discrimination of Mars atmospheric H 2 O and CO 2 clouds using ground-based instruments in the near infrared. We report the results of our cloud detection and characterization study using Mars near IR images obtained during the 1990 and 1993 oppositions. We focused on specific wavelengths that have the potential, based on previous laboratory studies of H 2 O and CO 2 ices, of yielding the greatest degree of cloud detectability and compositional discriminability. We have detected and mapped absorption features at some of these wavelengths in both the northern and southern polar regions of Mars. Compositional information on the nature of these absorption features was derived from comparisons with laboratory ice spectra and with a simplified radiative transfer model of a CO 2 ice cloud overlying a bright surface. Our results indicate that both H 2 O and CO 2 ices can be detected and distinguished in the polar hood clouds. The region near 3.00 μm is most useful for the detection of water ice clouds because there is a strong H 2 O ice absorption at this wavelength but only a weak CO 2 ice band. The region near 3.33 μm is most useful for the detection of CO 2 ice clouds because there is a strong, relatively narrow CO 2 ice band at this wavelength but only broad “continuum” H 2 O ice absorption. Weaker features near 2.30 μm could arise from CO 2 ice at coarse grain sizes, or surface/dust minerals. Narrow features near 2.00 μm, which could potentially be very diagnostic of CO 2 ice clouds, suffer from contamination by Mars atmospheric CO 2 absorptions and are difficult to interpret because of the rather poor knowledge of surface elevation at high latitudes. These results indicate that future ground-based, Earth-orbital, and spacecraft studies over a more extended span of the seasonal cycle should yield substantial information on the style and timing of volatile transport on Mars, as well as a more detailed understanding of the role of CO 2 condensation in the polar heat budget.

Journal of Geophysical Research E: Planets↗

Bora event variability and the role of air-sea feedback

A two-way interacting high resolution numerical simulation of the Adriatic Sea using the Navy Coastal Ocean Model (NCOM) and Coupled Ocean/ Atmosphere Mesoscale Prediction System (COAMPS??) was conducted to improve forecast momentum and heat flux fields, and to evaluate surface flux field differences for two consecutive bora events during February 2003. (COAMPS?? is a registered trademark of the Naval Research Laboratory.) The strength, mean positions and extensions of the bora jets, and the atmospheric conditions driving them varied considerably between the two events. Bora 1 had 62% stronger heat flux and 51% larger momentum flux than bora 2. The latter displayed much greater diurnal variability characterized by inertial oscillations and the early morning strengthening of a west Adriatic barrier jet, beneath which a stronger west Adriatic ocean current developed. Elsewhere, surface ocean current differences between the two events were directly related to differences in wind stress curl generated by the position and strength of the individual bora jets. The mean heat flux bias was reduced by 72%, and heat flux RMSE reduced by 30% on average at four instrumented over-water sites in the two-way coupled simulation relative to the uncoupled control. Largest reductions in wind stress were found in the bora jets, while the biggest reductions in heat flux were found along the north and west coasts of the Adriatic. In bora 2, SST gradients impacted the wind stress curl along the north and west coasts, and in bora 1 wind stress curl was sensitive to the Istrian front position and strength. The two-way coupled simulation produced diminished surface current speeds of ???12% over the northern Adriatic during both bora compared with a one-way coupled simulation. Copyright 2007 by the American Geophysical Union.

Journal of Geophysical Research C: Oceans↗

Spatial and temporal multiyear sea ice distributions in the Arctic: A neural network analysis of SSM/I data, 1988-2001

Arctic multiyear sea ice concentration maps for January 1988-2001 were generated from SSM/I brightness temperatures (19H, 19V, and 37V) using modified multiple layer perceptron neural networks. Learning data for the neural networks were extracted from ice maps derived from Okean and ERS satellite imagery to capitalize on the stability of active radar multiyear ice signatures. Evaluations of three learning algorithms and several topologies indicated that networks constructed with error back propagation learning and 3-20-1 topology produced the most consistent and physically plausible results. Operational neural networks were developed specifically with January learning data, and then used to estimate daily multiyear ice concentrations from daily-averaged SSM/I brightness temperatures during January. Monthly mean maps were produced for analysis by averaging the respective daily estimates. The 14-year series of January multiyear ice distributions revealed dense and persistent cover in the central Arctic surrounded by expansive regions of highly fluctuating interannual cover. Estimates of total multiyear ice area by the neural network were intermediate to those of other passive microwave algorithms, but annual fluctuations and trends were similar among all algorithms. When compared to Radarsat estimates of multiyear ice concentration in the Beaufort and Chukchi Seas (1997-1999), average discrepancies were small (0.9-2.5%) and spatial coherency was reasonable, indicating the neural network's Okean and ERS learning data facilitated passive microwave inversion that emulated backscatter signatures. During 1988-2001, total January multiyear ice area declined at a significant linear rate of -54.3 x 10 3 km 2 /yr -1 (-1.4%/yr -1 ). The most persistent and extensive decline in multiyear ice concentration (-3.3%/yr -1 ) occurred in the southern Beaufort and Chukchi Seas. In autumn 1996, a large multiyear ice recruitment of over 106 km 2 (mostly in the Siberian Arctic) fully replenished the previous 8-year decline in total area, but it was followed by an accelerated and compensatory decline during the subsequent 4 years. Seventy-five percent of the interannual variation in January multiyear sea ice area was explained by linear regression on two atmospheric parameters: the previous inter's (JFM) Arctic Oscillation index as a proxy to melt duration and the previous year's average sea level pressure gradient across the Fram Strait as a proxy to annual ice export. Consecutive year changes (1994-2001) in January multiyear ice volume were significantly correlated with duration of the intervening melt season (R 2 = 0.73, -80.0 km 3 /d -1 ), emphasizing a large thermodynamic influence on the Arctic's mass sea ice balance during summers with anomalous melt durations.

Journal of Geophysical Research↗

A semi-mechanistic model for partitioning evapotranspiration reveals transpiration dominates the water flux in drylands

Popular evapotranspiration (ET) partitioning methods make assumptions that might not be well-suited to dryland ecosystems, such as high sensitivity of plant water-use efficiency (WUE) to vapor pressure deficit (VPD). Our objectives were to (a) create an ET partitioning model that can produce fine-scale estimates of transpiration (T) in drylands, and (b) use this approach to evaluate how climate controls T and WUE across ecosystem types and timescales along a dryland aridity gradient. We developed a novel, semi-mechanistic ET partitioning method using a Bayesian approach that constrains abiotic evaporation using process-based models, and loosely constrains time-varying WUE within an autoregressive framework. We used this method to estimate daily T and weekly WUE across seven dryland ecosystem types and found that T dominates ET across the aridity gradient. Then, we applied cross-wavelet coherence analysis to evaluate the temporal coherence between focal response variables (WUE and T/ET) and environmental variables. At yearly scales, we found that WUE at less arid, higher elevation sites was primarily limited by atmospheric moisture demand, and WUE at more arid, lower elevation sites was primarily limited by moisture supply. At sub-yearly timescales, WUE and VPD were sporadically correlated. Hence, ecosystem-scale dryland WUE is not always sensitive to changes in VPD at short timescales, despite this being a common assumption in many ET partitioning models. This new ET partitioning method can be used in dryland ecosystems to better understand how climate influences physically and biologically driven water fluxes.

New Mexico↗

Hematite spherules at Meridiani: results from MI, Mini-TES, and Pancam

We report on observations of hematite‐bearing spherules at Meridiani Planum made using the Microscopic Imager (MI), Mini‐Thermal Emission Spectrometer (Mini‐TES), and Panoramic Camera (Pancam) instruments on the Mars Exploration Rover Opportunity. Spherules were observed on soil surfaces and in outcrop rocks, both on undisturbed surfaces and in abraded surfaces ground using the Rock Abrasion Tool (RAT). Spherule size and shape change little along the 850 m eastward traverse from Eagle Crater to Endurance Crater, but spherules decrease and then slightly increase in size along the 6 km traverse from Endurance south to Victoria Crater. Local populations range from submillimeters to several millimeters in diameter. An additional small diameter (100 μ m) size population is possible. An increase in irregular shapes is found near Victoria Crater. This, combined with the size decrease south of Endurance, suggests either a changing depositional environment, or variation in the duration and timing of diagenetic events. The dominant smaller size population observed early in the mission in aeolian areas and ripple crests is observed as the primary size population in abraded outcrop farther south. This suggests that successively younger beds are exposed at the surface along the southward traverse. Stratigraphically higher units removed by erosion could be recorded by the present surface lag deposit. Coordinated systematic observations are used to determine optical and infrared hematite indices of the surface soils in Pancam and Mini‐TES. In spite of the systematic variation seen in MI, both Pancam and Mini‐TES indices are highly variable based on the local surface, and neither show systematic trends south of Endurance. The lack of a 390 cm −1 feature in Mini‐TES spectra suggests concentric or radial interior structure within the spherules at scales too fine for MI to observe. Mini‐TES does not detect any silicate component in the spherules. A bound water component in soils or in exchange with the atmosphere is observed. These spherules have been previously interpreted as concretions formed within what were once water‐saturated, diagenetically altered “dirty evaporate” sandstone sediments. Our observations support this interpretation; however, no single terrestrial analog provides a model that can account for all attributes of the spherules on Mars.

Journal of Geophysical Research↗

Spatial and temporal variability of pCO2, carbon fluxes and saturation state on the West Florida Shelf

The West Florida Shelf (WFS) is a source of uncertainty for the Gulf of Mexico carbon budget. Data from the synthesis of approximately 135,000 pCO2 values from over 96 cruises from the WFS show that the shelf waters fluctuate between being a weak source to a weak sink of carbon with the atmosphere. Overall, the shelf acts as a weak source of CO2 at 0.32 ± 1.5 mol m-2 yr-1. Subregions, however, reveal slightly different trends, where surface waters associated with 40 m – 200 m isobaths in the northern and southern WFS are generally weak sinks all year, except for summer when they act as sources of CO2. Conversely, nearshore waters (< 40 m) are a source of CO2 are a source all year round, particularly the southern shallow waters. The pCO2 of seawater has been increasing at a rate of approximately 5.26 µatm yr-1 as compared to atmospheric pCO2 which has increased at a rate of about 1.7 µatm yr-1 from 1996 to 2016. The pCO2 and CO2 flux on the shelf from 1996 - 2016 have increased about 49 µatm, and 1.08 mol m-2, respectively. The WFS is emitting 9.23 Tg C yr-1, with the southern nearshore region emitting the most at 9.01 Tg C yr-1 and the northern region acting as a sink of -1.96 Tg C yr-1.

West Florida shelf↗

Controls on methane released through ebullition in peatlands affected by permafrost degradation

Permafrost thaw in peat plateaus leads to the flooding of surface soils and the formation of collapse scar bogs, which have the potential to be large emitters of methane (CH 4 ) from surface peat as well as deeper, previously frozen, permafrost carbon (C). We used a network of bubble traps, permanently installed 20&thinsp;cm and 60&thinsp;cm beneath the moss surface, to examine controls on ebullition from three collapse bogs in interior Alaska. Overall, ebullition was dominated by episodic events that were associated with changes in atmospheric pressure, and ebullition was mainly a surface process regulated by both seasonal ice dynamics and plant phenology. The majority (>90%) of ebullition occurred in surface peat layers, with little bubble production in deeper peat. During periods of peak plant biomass, bubbles contained acetate-derived CH 4 dominated (>90%) by modern C fixed from the atmosphere following permafrost thaw. Post-senescence, the contribution of CH 4 derived from thawing permafrost C was more variable and accounted for up to 22% (on average 7%), in the most recently thawed site. Thus, the formation of thermokarst features resulting from permafrost thaw in peatlands stimulates ebullition and CH 4 release both by creating flooded surface conditions conducive to CH 4 production and bubbling as well as by exposing thawing permafrost C to mineralization.

Alaska↗

Sources of global warming of the upper ocean on decadal period scales

Recent studies find global climate variability in the upper ocean and lower atmosphere during the twentieth century dominated by quasi-biennial, interannual, quasi-decadal and interdecadal signals. The quasi-decadal signal in upper ocean temperature undergoes global warming/cooling of ???0.1??C, similar to that occuring with the interannual signal (i.e., El Nin??o-Southern Oscillation), both signals dominated by global warming/cooling in the tropics. From the National Centers for Environmental Prediction troposphere reanalysis and Scripps Institution of Oceanography upper ocean temperature reanalysis we examine the quasi-decadal global tropical diabetic heat storage (DHS) budget from 1975 to 2000. We find the anomalous DHS warming tendency of 0.3-0.9 W m-2 driven principally by a downward global tropical latent-plus-sensible heat flux anomaly into the ocean, overwhelming the tendency by weaker upward shortwave-minus-longwave heat flux anomaly to drive an anomalous DHS cooling tendency. During the peak quasi-decadal warming the estimated dissipation of DHS anomaly of 0.2-0.5 W m-2 into the deep ocean and a similar loss to the overlying atmosphere through air-sea heat flux anomaly are balanced by a decrease in the net poleward Ekman heat advection out of the tropics of 0.4-0.7 W m-2. This scenario is nearly the opposite of that accounting for global tropical warming during the El Nin??o. These diagnostics confirm that even though the global quasi-decadal signal is phase-locked to the 11-year signal in the Sun's surface radiative forcing of ???0.1 W m-2, the anomalous global tropical DHS tendency cannot be driven by it directly.

Journal of Geophysical Research C: Oceans↗

Ventifacts at the Pathfinder landing site

About half of the rocks at the Mars Pathfinder Ares Vallis landing site appear to be ventifacts, rocks abraded by windborne particles. Comparable resolution images taken by the Imager for Mars Pathfinder (IMP) camera and the Viking landers show that ventifacts are more abundant at the Pathfinder site. The ventifacts occur in several forms, including rocks with faceted edges, finger‐like projections, elongated pits, flutes, grooves, and possible rills. The trends of elongated pits, flutes, grooves, and rills cluster at ∼280–330° clockwise from north and generally dip 10–30° away from their trend direction. These orientations are indicative of southeast to northwest winds and differ from the trend of wind tails at the landing site, the direction of local wind streaks, and predictions of the Global Circulation Model, all of which indicate northeast to southwest winds. The disparity between these data sets strongly suggests that local circulation patterns have changed since the abrasion of the ventifacted rocks. The greater number of ventifacts at the Pathfinder site compared to either of the Viking sites is most easily explained as being due to a larger supply of abrading particles, composed of either sand‐sized grains or indurated dust aggregates, and higher surface roughness, which should increase the momentum of saltating grains. The Pathfinder ventifacts may have formed shortly after the deposition of outflow channel sediments nearly 2 Gry ago, when a large local supply of abrading particles should have been abundant and atmospheric conditions may have been more conducive to rock abrasion from saltating grains. Based on how ventifacts form on Earth, the several ventifact forms seen at the Pathfinder site and their presence on some rocks but not on others are probably due to local airflow conditions, original rock shape, exposure duration, rock movement, and to a lesser extent, rock lithology. The abundance of ventifacts at the Pathfinder site, together with other evidence of weathering, indicates that unaltered rock surfaces are rare on Mars.

Journal of Geophysical Research E: Planets↗

Source limitation of carbon gas emissions in high-elevation mountain streams and lakes

Inland waters are an important component of the global carbon cycle through transport, storage, and direct emissions of CO 2 and CH 4 to the atmosphere. Despite predictions of high physical gas exchange rates due to turbulent flows and ubiquitous supersaturation of CO 2 —and perhaps also CH 4 —patterns of gas emissions are essentially undocumented for high mountain ecosystems. Much like other headwater networks around the globe, we found that high-elevation streams in Rocky Mountain National Park, USA, were supersaturated with CO 2 during the growing season and were net sources to the atmosphere. CO 2 concentrations in lakes, on the other hand, tended to be less than atmospheric equilibrium during the open water season. CO 2 and CH 4 emissions from the aquatic conduit were relatively small compared to many parts of the globe. Irrespective of the physical template for high gas exchange (high k ), we found evidence of CO 2 source limitation to mountain streams during the growing season, which limits overall CO 2 emissions. Our results suggest a reduced importance of aquatic ecosystems for carbon cycling in high-elevation landscapes having limited soil development and high CO 2 consumption via mineral weathering.

Journal of Geophysical Research G: Biogeosciences↗

Physical properties of the Mars Exploration Rover landing sites as inferred from Mini-TES-derived thermal inertia

The Miniature Thermal Emission Spectrometer (Mini‐TES) on board the two Mars Exploration Rovers provides the first opportunity to observe thermal properties from the Martian surface, relate these properties to orbital data, and perform soil conductivity experiments under Martian conditions. The thermal inertias of soils, bedforms, and rock at each landing site were derived to quantify the physical properties of these features and understand geologic processes occurring at these localities. The thermal inertia for the Gusev plains rock target Bonneville Beacon (∼1200 J m −2 K −1 s −1/2 ) is consistent with a dense, basaltic rock, but the rocks at the Columbia Hills have a lower thermal inertia (∼620 J m −2 K −1 s −1/2 ), suggesting that they have a volcaniclasic origin. Bedforms on the floors of craters at both landing sites have thermal inertias of 200 J m −2 K −1 s −1/2 , consistent with a particle diameter of ∼160 μm. This diameter is comparable to the most easily moved grain size in the current atmosphere on Mars, suggesting that these bedforms may have formed under current atmospheric conditions. Along the Meridiani plains, the thermal inertia is lower than that derived from TES and Thermal Emission Imaging System (THEMIS) orbital data. This discrepancy is not well understood. Mini‐TES–derived thermal inertias at Gusev along a ∼2.5 km traverse follow trends in thermal inertia measured from orbit with TES and THEMIS. However, along the traverse, there are variability and mixing of particle sizes that are not resolved in the orbital thermal inertia data due to meter‐scale processes that are not identifiable at larger scales.

Journal of Geophysical Research E: Planets↗

High-resolution topomapping of candidate MER landing sites with Mars Orbiter Camera narrow-angle images

We analyzed narrow‐angle Mars Orbiter Camera (MOC‐NA) images to produce high‐resolution digital elevation models (DEMs) in order to provide topographic and slope information needed to assess the safety of candidate landing sites for the Mars Exploration Rovers (MER) and to assess the accuracy of our results by a variety of tests. The mapping techniques developed also support geoscientific studies and can be used with all present and planned Mars‐orbiting scanner cameras. Photogrammetric analysis of MOC stereopairs yields DEMs with 3‐pixel (typically 10 m) horizontal resolution, vertical precision consistent with ∼0.22 pixel matching errors (typically a few meters), and slope errors of 1–3°. These DEMs are controlled to the Mars Orbiter Laser Altimeter (MOLA) global data set and consistent with it at the limits of resolution. Photoclinometry yields DEMs with single‐pixel (typically ∼3 m) horizontal resolution and submeter vertical precision. Where the surface albedo is uniform, the dominant error is 10–20% relative uncertainty in the amplitude of topography and slopes after “calibrating” photoclinometry against a stereo DEM to account for the influence of atmospheric haze. We mapped portions of seven candidate MER sites and the Mars Pathfinder site. Safety of the final four sites (Elysium, Gusev, Isidis, and Meridiani) was assessed by mission engineers by simulating landings on our DEMs of “hazard units” mapped in the sites, with results weighted by the probability of landing on those units; summary slope statistics show that most hazard units are smooth, with only small areas of etched terrain in Gusev crater posing a slope hazard.

Journal of Geophysical Research E: Planets↗

Magnesium and calcium sulfate stabilities and the water budget of Mars

Magnesium sulfate probably plays a dominant role in the water cycle of Mars away from the polar ice caps through hydration and dehydration reactions. This prominence is due to its abundance, its occurrence in numerous hydration states, and its ability to hydrate and dehydrate rapidly. New experimental studies on the metastable reaction between hexahydrite (MgSO4??6H2O) and starkeyite (MgSO4-4H2O) as a function of temperature and relative humidity, supplemented by recent investigations of the stable reaction between epsomite (MgSO4??7H2O) and hexahydrite and by phase equilibrium calculations, suggest that the most important magnesium sulfate phases involved in the Martian water cycle are MgSO4??11 H2O, epsomite, starkeyite, and possibly kieserite (MgSO4??H2O). Hexahydrite is not predicted to be stable on the surface of Mars. During diurnal variations in temperature and relative humidity, 1 kg of MgSO4 can release or remove from the atmosphere 1.5 kg of H2O by cycling between kieserite and MgSO4??11 H2O. Despite subequal abundances of calcium sulfate, calcium sulfates are not likely to be important in the water cycle of the planet because of sluggish rates of hydration and dehydration and a more limited range of H2O concentrations per kilogram of CaSO4 (0.00 to 0.26 kg kg-1). Modern or recent erosion on Mars attributed to liquid water may be due to the dehydration Of MgSO4??11 H2O because of the inferred abundance and likelihood of occurrence of this phase and its limited stability relative to known variations in temperature and relative humidity.

Journal of Geophysical Research E: Planets↗

Controls on mangrove forest‐atmosphere carbon dioxide exchanges in western Everglades National Park

We report on net ecosystem production (NEP) and key environmental controls on net ecosystem exchange (NEE) of carbon dioxide (CO 2 ) between a mangrove forest and the atmosphere in the coastal Florida Everglades. An eddy covariance system deployed above the canopy was used to determine NEE during January 2004 through August 2005. Maximum daytime NEE ranged from −20 to −25 μ mol (CO 2 ) m −2 s −1 between March and May. Respiration (R d ) was highly variable (2.81 ± 2.41 μ mol (CO 2 ) m −2 s −1 ), reaching peak values during the summer wet season. During the winter dry season, forest CO 2 assimilation increased with the proportion of diffuse solar irradiance in response to greater radiative transfer in the forest canopy. Surface water salinity and tidal activity were also important controls on NEE. Daily light use efficiency was reduced at high (>34 parts per thousand (ppt)) compared to low (<17 ppt) salinity by 46%. Tidal inundation lowered daytime R d by ∼0.9 μ mol (CO 2 ) m −2 s −1 and nighttime R d by ∼0.5 μ mol (CO 2 ) m −2 s −1 . The forest was a sink for atmospheric CO 2 , with an annual NEP of 1170 ± 127 g C m −2 during 2004. This unusually high NEP was attributed to year‐round productivity and low ecosystem respiration which reached a maximum of only 3 g C m −2 d −1 . Tidal export of dissolved inorganic carbon derived from belowground respiration likely lowered the estimates of mangrove forest respiration. These results suggest that carbon balance in mangrove coastal systems will change in response to variable salinity and inundation patterns, possibly resulting from secular sea level rise and climate change.

Florida↗