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At least 163 records · Page 9Linked to original sources

Additions of nutrients and major ions by the atmosphere and tributaries to nearshore waters of northwestern Lake Huron

Nutrient additions by the atmosphere and six tributaries to nearshore waters of northwestern Lake Huron were measured at weekly intervals from August 1975 to July 1976. The atmosphere contributed 43% of the nitrogen (N) and 10% of the phosphorus (P) that was added during the year. The 1975–76 atmospheric loading rate of total N to this area (11 kg/ha/yr) was one of the highest found to date in the United States. N was conserved more efficiently than P in the tributary drainage basins. Of the N and P that fell annually on the watersheds under study, 2 to 37% of the N and 31 to 84% of the P was carried with runoff to the lake. From a basin where ditching and clear-cutting occurred, water, P, silica (SiO 2 ), N, and sodium were lost at higher rates than from five other basins. Most of the N in bulk atmospheric samples (23%) and tributary waters (56%) was dissolved organic N, a form of N not often measured.

Michigan

Drain tiles and groundwater resources: Understanding the relations

Executive Summary Drainage for agricultural production over the past 150 years has been an integral component of human-driven change to Minnesota’s rural landscapes. Benefits of drainage Historically, poorly drained soils across much of the State would often remain saturated or flooded after spring snowmelt, preventing timely farm operations such as tilling and planting crops (Arneman, 1963). Installation of agricultural drainage, both surface ditches and subsurface drainage, accelerated transport of water off farm fields and imparted producers higher crop yields (Beauchamp, 1987; Stoner and others, 1993). Agricultural drainage offered many other benefits such as preventing crop drown out, aerating the soil profile for improved plant growth, limiting surface runoff and soil erosion, and allowing farmers better access to croplands (Fausey and others, 1987). Without agricultural drainage on much of Minnesota’s croplands, it would have been difficult to realize high enough crop yields to remain economically viable. Environmental concerns While drainage of Minnesota croplands provided the benefits mentioned above, several environmental concerns result. These include wetland loss, degradation of downstream water quality, and reduced [potential for] recharge. Early agricultural drainage efforts (pre-20th century) led to the disappearance of much of Minnesota’s natural wetlands. Increased focus on preventing or mitigating wetland loss over the last 50 years has helped curtail further losses, even as agricultural drainage proceeds. Prior to establishment of Minnesota statehood, wetlands accounted for more than 10 million acres in Minnesota, including prairie wetlands, peatlands, and forest wetlands that comprised approximately 19 percent of the total land area (Palmer, 1915; King, 1980). In 2018, only half of Minnesota’s pre-settlement wetlands remain, mostly in parts of the State that have not experienced widespread drainage, such as northern Minnesota. Water-quality monitoring has shown that agricultural drainage, in particular the practice of subsurface drainage, provides a direct flow path for nutrient (nitrogen and soluble phosphorus) losses to surface water resources. The negative consequences of agricultural drainage on surface water quality are well documented (for example, Dinnes and others, 2002; Kladivko and others, 2004; Richards and others, 2008; Rozemeijer and others, 2010; Schottler and others, 2013). Agricultural basins with a high percentage of agricultural drainage have been implicated as part of the cause of the Gulf of Mexico hypoxia zone due to excessive nitrogen export (Goolsby and Battaglin, 2001; Randall and Mulla, 2001). The connection of hydrological effects of agricultural subsurface drainage on groundwater recharge and aquifers, on the other hand, has not been well-established. Agricultural subsurface drainage intercepts infiltrating water below croplands and directly discharges the water to nearby surface waters. However, the size of the water balance shift from drained water that would have evapotranspired or run off the land to drained water that would recharge underlying aquifers has been poorly characterized (Schuh, 2008). Drain Tiles and Groundwater Given the poor accounting of subsurface drainage effects on groundwater resources, the Minnesota Ground Water Association (MGWA) deemed it imperative that we document these effects so that groundwater resources in agricultural regions with substantial drainage can be effectively managed. This white paper documents the relations of drain tiles and groundwater resources and discusses the historical significance of agricultural drainage practices, the recognized positive benefits and potential negative consequences of agricultural drainage practices, and the gaps in understanding of the connections between agricultural drainage and groundwater resources. The major messages emerged from the findings of this white paper are: Complex history. Minnesota has a long history of agricultural drainage, spanning over 150 years. Agricultural drainage, and the eventual widespread usage of subsurface drainage, can be separated into at least four distinct periods of time: (a) early drainage to get water off the land, pre-20th century; (b) the boom and bust era (1900-1945); (c) postwar resurgence of subsurface drainage and early conservation efforts (1945-1960); and, (d) emergence of the environmental movement (1960 to present). The State’s regulatory framework that both allowed for drainage and controlled its usage during these periods is complicated and has been governed by a patchwork of both State and Federal statutes. Drainage Provinces. This white paper advances the concept of tile drainage provinces to aid in the discussion of regional differences in subsurface drainage and its overall effect on groundwater resources. Built upon the concept of groundwater provinces (Minnesota Department of Natural Resources, 2001), three distinct tile drainage provinces were conceptualized: (1) the Southeastern Province; (2) the SouthCentral Province; and, (3) the Western Province. The distinct geology and the soils that developed in these regions have implications for each region’s subsurface drainage density and the potential implications for groundwater. Knowledge gaps. Several critical knowledge gaps are identified in this paper, creating opportunities for further research to improve our understanding for better managed water resources: Extent of drainage is unknown. Direct estimates of the extent of subsurface drainage do not exist in Minnesota. However, several indirect methods have been utilized to estimate subsurface drainage, from the field-scale to countylevel through the use of geographic information system (GIS) analysis and aerial photography. Based on a 2012 U.S. Geological Survey estimate of subsurface drainage extent (Nakagaki and Wieczorek, 2016), about 21% of the land area in Minnesota has some density of subsurface drainage. Effect of drainage on underlying aquifers is unknown. A basic understanding of unconfined and confined aquifers and their recharge is necessary to connect any hydrological effects from agricultural drainage to groundwater. The basic goal of subsurface drainage to efficiently drain saturated soils clearly alters the water balance in croplands. However, its overall effect on groundwater resources has been poorly characterized, and is in large part determined by the geology below drained areas and the arrangement of underlying aquifers. Water balance shifts. An improved understanding of historical water balance shifts from pre- to post-drainage periods is necessary to understand long-term implications on net groundwater recharge. Also, more direct field-scale studies and indirect modeling studies are needed to characterize water budgets for fields with subsurface drainage.

Minnesota

Framework for a long-term strategic plan for the Capital Area Groundwater Conservation Commission

The Capital Area Groundwater Conservation Commission oversees the use of groundwater in six parishes in Louisiana. In carrying out its statutory responsibilities and authorities, the Commission recognizes the complexity of its decisions: the long-term objectives it is seeking are multifaceted; the actions it can choose from are numerous and interdependent; and the understanding of the hydrogeological, economic, and social systems affected by its actions is limited. To navigate this complexity, the Commission is developing a long-term strategic plan to guide its activities and to serve as a primary mode of communication to stakeholders and the public. The long-term strategic plan is intended to consider actions and outcomes over at least the next 50 years within the 6 parishes in the Commission’s jurisdiction and related to all the confined aquifers in the 3000 feet below the district. The primary purposes of the plan are to promote long-term sustainability of groundwater extraction, continuity of operations of the Commission, long-term planning by water users, and clear communication with the public. The plan will describe specific management actions to be taken over time by the Commission, and the conditions under which those actions are to be taken. It will include intermediate milestones the Commission intends to achieve on the way toward achieving its long-term objectives. The actions under consideration include regulation and monitoring of groundwater withdrawal, mitigation of the environmental effects of withdrawal, support of relevant scientific studies, as well as work with partner agencies to implement measures to conserve, develop, and supplement groundwater resources. The plan will have greater detail about short-term actions than mid-term and long-term actions, and the Commission anticipates updating the plan periodically to adapt to changing circumstances and knowledge. To develop its long-term strategic plan, the Commission is working with The Water Institute of the Gulf and the U.S. Geological Survey using a facilitated process based on the principles of structured decision making (Gregory et al., 2012). This document outlines the framework for the strategic plan by describing the legal, economic, and scientific context for the plan, the fundamental objectives the Commission seeks to achieve in the long term, and the strategic alternatives it is considering.

Report

Tracing the history of submarine hydrothermal inputs and the significance of hydrothermal hafnium for the seawater budget - A combined Pb-Hf-Nd isotope approach

Secular variations in the Pb isotopic composition of a mixed hydrogenous-hydrothermal ferromanganese crust from the Bauer Basin in the eastern Equatorial Pacific provide clear evidence for changes in hydrothermal contributions during the past 7 Myr. The nearby Galapagos Rise spreading center provided a strong hydrothermal flux prior to 6.5 Ma. After 6.5 Ma, the Pb became stepwise more radiogenic and more similar to Equatorial Pacific seawater, reflecting the westward shift of spreading to the presently active East Pacific Rise (EPR). A second, previously unrecognized enhanced hydrothermal period occurred between 4.4 and 2.9 Ma, which reflects either off-axis hydrothermal activity in the Bauer Basin or a late-stage pulse of hydrothermal Pb from the then active, but waning Galapagos Rise spreading center. Hafnium isotope time-series of the same mixed hydrogenous-hydrothermal crust show invariant values over the past 7 Myr. Hafnium isotope ratios, as well as Nd isotope ratios obtained for this crust, are identical to that of hydrogenous Equatorial Pacific deep water crusts and clearly indicate that hydrothermal Hf, similar to Nd, does not travel far from submarine vents. Therefore, we suggest that hydrothermal Hf fluxes do not contribute significantly to the global marine Hf budget. ?? 2004 Elsevier B.V. All rights reserved.

Earth and Planetary Science Letters

Hydrated silicate minerals on Mars observed by the Mars Reconnaissance Orbiter CRISM instrument

Phyllosilicates, a class of hydrous mineral first definitively identified on Mars by the OMEGA (Observatoire pour la Mineralogie, L’Eau, les Glaces et l’Activitié) instrument 1 , 2 , preserve a record of the interaction of water with rocks on Mars. Global mapping showed that phyllosilicates are widespread but are apparently restricted to ancient terrains and a relatively narrow range of mineralogy (Fe/Mg and Al smectite clays). This was interpreted to indicate that phyllosilicate formation occurred during the Noachian (the earliest geological era of Mars), and that the conditions necessary for phyllosilicate formation (moderate to high pH and high water activity 3 ) were specific to surface environments during the earliest era of Mars’s history 4 . Here we report results from the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) 4 of phyllosilicate-rich regions. We expand the diversity of phyllosilicate mineralogy with the identification of kaolinite, chlorite and illite or muscovite, and a new class of hydrated silicate (hydrated silica). We observe diverse Fe/Mg-OH phyllosilicates and find that smectites such as nontronite and saponite are the most common, but chlorites are also present in some locations. Stratigraphic relationships in the Nili Fossae region show olivine-rich materials overlying phyllosilicate-bearing units, indicating the cessation of aqueous alteration before emplacement of the olivine-bearing unit. Hundreds of detections of Fe/Mg phyllosilicate in rims, ejecta and central peaks of craters in the southern highland Noachian cratered terrain indicate excavation of altered crust from depth. We also find phyllosilicate in sedimentary deposits clearly laid by water. These results point to a rich diversity of Noachian environments conducive to habitability.

Nature

Evaluating the potential role of bioactive chemicals on the distribution of invasive Asian carp upstream and downstream from river mile 278 in the Illinois waterway

Two non-native carp species have invaded the Illinois Waterway and are a threat to Great Lakes ecosystems. Poor water quality in the upper Illinois Waterway, may be a factor contributing to the stalling of the carp population front near river mile 278. In 2015, the U.S. Geological Survey collected 4 sets of water samples from two sites upstream and 4 sites downstream from river mile 278, and one tributary. Each sample was analyzed for up to 649 unique parameters of which 287 were detected including 96 pesticides, 62 pharmaceuticals, 39 wastewater indicator compounds, 29 metals, 19 volatile organic compounds (VOCs), six disinfection by-products (DBPs), five hormones, and five carboxylic acids. Potential for bioactivity was estimated by comparing chemical concentrations to aquatic life or human health criteria and to in-vitro bioactivity screening results in the U.S EPA ToxCast™ database. The resulting hazard quotients and exposure-activity ratios (EARs) are toxicity indexes, that can be used to rank potential bioactivity of individual chemicals and chemical mixtures. This analysis indicates that several bioactive chemicals (BCs) including: carbendazim, 2,4-D, metolachlor, terbuthylazine, and acetochlor (pesticides); 1,4-dioxane (VOC); metformin, diphenhydramine, sulfamethoxazole, tramadol, fexofenadine, and the anti-depressants (pharmaceuticals); bisphenol A, 4-nonylphenol, galaxolide, 4-tert-octylphenol (wastewater indicator chemical); lead and boron (metals); and estrone (hormone) all occur in the upper Illinois Waterway at concentrations that produce elevated EARs values and may be adversely affecting carp reproduction and health. The clear differences in water quality upstream and downstream from river mile 278 with higher contaminant concentrations and potential bioactivity upstream could represent a barrier to carp range expansion.

Illinois

Component flow processes at four streams in the Catskill Mountains, New York, analysed using episodic concentration/discharge relationship

Plots of solute concentration against discharge have been used to relate stream hydrochemical variations to processes of flow generation, using data collected at four streams in the Catskill Mountains, New York, during the Episodic Response Project of the US Environmental Protection Agency. Results suggest that a two-component system of shallow and deep saturated subsurface flow, in which the two components respond simultaneously during hydrologic events, may be applicable to the study basins. Using a large natural sea-salt sodium input as a tracer for precipitation, it is argued that an additional distinction can be made between pre-event and event water travelling along the shallow subsurface flow path. Pre-event water is thought to be displaced by infiltrating event water, which becomes dominant on the falling limb of the hydrograph. Where, as appears to be the case for sulfate, a solute equilibrates rapidly within the soil, the pre-event-event water distinction is unimportant. However, for some solutes there are clear and consistent compositional differences between water from the two sources, evident as a hysteresis loop in concentration-discharge plots. Nitrate and acidity, in particular, appear to be elevated in event water following percolation through the organic horizon. Consequently, the most acidic, high nitrate conditions during an episode generally occur after peak discharge. A simple conceptual model of episode runoff generation is presented on the basis of these results.Plots of solute concentration against discharge have been used to relate stream hydrochemical variations to processes of flow generation, using data collected at four streams in the Catskill Mountains, New York, during the Episodic Response Project of the US Environmental Protection Agency. Results suggest that a two-component system of shallow and deep saturated subsurface flow, in which the two components respond simultaneously during hydrologic events, may be applicable to the study basins. Using a large natural sea-salt sodium input as a tracer for precipitation, it is argued that an additional distinction can be made between pre-event and event water travelling along the shallow subsurface flow path. Pre-event water is thought to be displaced by infiltrating event water, which becomes dominant on the falling limb of the hydrograph. Where, as appears to be the case for sulfate, a solute equilibrates rapidly within the soil, the pre-event - event water distinction is unimportant. However, for some solutes there are clear and consistent compositional differences between water from the two sources, evident as a hysteresis loop in concentration-discharge plots. Nitrate and acidity, in particular, appear to be elevated in event water following percolation through the organic horizon. Consequently, the most acidic, high nitrate conditions during an episode generally occur after peak discharge. A simple conceptual model of episode runoff generation is presented on the basis of these results.

Hydrological Processes

Combined use of remote sensing and continuous monitoring to analyse the variability of suspended-sediment concentrations in San Francisco Bay, California

Analysis of suspended-sediment concentration data in San Francisco Bay is complicated by spatial and temporal variability. In situ optical backscatterance sensors provide continuous suspended-sediment concentration data, but inaccessibility, vandalism, and cost limit the number of potential monitoring stations. Satellite imagery reveals the spatial distribution of surficial-suspended sediment concentrations in the Bay; however, temporal resolution is poor. Analysis of the in situ sensor data in conjunction with the satellite reflectance data shows the effects of physical processes on both the spatial and temporal distribution of suspended sediment in San Francisco Bay. Plumes can be created by large freshwater flows. Zones of high suspended-sediment concentrations in shallow subembayments are associated with wind-wave resuspension and the spring-neap cycle. Filaments of clear and turbid water are caused by different transport processes in deep channels, as opposed to adjacent shallow water.

Estuarine, Coastal and Shelf Science

Sediment resuspension and transport patterns on a fringing reef flat, Molokai, Hawaii

Corals are known to flourish in various turbid environments around the world. The quantitative distinction between clear and turbid water in coral habitats is not well defined nor are the amount of sediment in suspension and rates of sedimentation used to evaluate the condition of reef environments well established. This study of sediment resuspension, transport, and resulting deposition on a fringing reef flat off Molokai, Hawaii, uses a year of time-series data from a small, instrumented tripod. It shows the importance of trade winds and ocean wave heights in controlling the movement of sediment. Sediment is typically resuspended daily and the dominant controls on the magnitude of events (10-25 mg/l) are the trade-wind-generated waves and currents and tidal elevation on the reef flat. The net flux of sediment on this reef is primarily along the reef flat in the direction of the prevailing trade winds (to the west), with a secondary direction of slightly offshore, towards a zone of low coral abundance. These results have application to reef studies and reef management in other areas in several ways. First, the observed resuspension and turbidity results from fine-grained terrigenous sediment that appears to be trapped and recycled on the reef flat. Thus corals are subjected to light attenuation by the same particles repeatedly, however small the amount. Secondly, the measurements show high temporal variability (from daily to seasonal scales) of sediment resuspension, indicating that single measurements are inadequate to accurately describe conditions on a reef flat. ?? Springer-Verlag 2004.

Coral Reefs

Using multiple geochemical tracers to characterize the hydrogeology of the submarine spring off Crescent Beach, Florida

A spectacular submarine spring is located about 4 km east of Crescent Beach, FL, in the Atlantic Ocean. The single vent feature of Crescent Beach Spring provides a unique opportunity to examine onshore–offshore hydrogeologic processes, as well as point source submarine ground water discharge. The Floridan aquifer system in northeastern Florida consists of Tertiary interspersed limestone and dolomite strata. Impermeable beds confine the water-bearing zones under artesian pressure. Miocene and younger confining strata have been eroded away at the vent feature, enabling direct hydrologic communication of Eocene ground water with coastal bottom waters. The spring water had a salinity of 6.02, which was immediately diluted by ambient seawater during advection/mixing. The concentration of major solutes in spring water and onshore well waters confirm a generalized easterly flow direction of artesian ground water. Nutrient concentrations were generally low in the reducing vent samples, and the majority of the total nitrogen species existed as NH 3 . The submarine ground water tracers, Rn-222 (1174 dpm l −1 , dpm), methane (232 nM) and barium (294.5 nM) were all highly enriched in the spring water relative to ambient seawater. The concentrations of the reverse redox elements U, V and Mo were expectedly low in the submarine waters. The strontium isotope ratio of the vent water ( 87 Sr/ 86 Sr=0.70798) suggests that the spring water contain an integrated signature indicative of Floridan aquifer system ground water. Additional Sr isotopic ratios from a series of surficial and Lower Floridan well samples suggest dynamic ground water mixing, and do not provide clear evidence for a single hydrogeologic water source at the spring vent. In this karst-dominated aquifer, such energetic mixing at the vent feature is expected, and would be facilitated by conduit and fractured flow. Radium isotope activities were utilized to estimate flow-path trajectories and to provide information on potential travel times between an onshore well and the spring. Using either 223 Ra and 224 Ra or 228 Ra, and qualifying this approach with several key assumptions, estimates of water mass travel times from an upper Floridan well in Crescent Beach to the submarine vent feature (distance=4050 m) are in the order of ∼0.01–0.1 m min −1 .

Florida

Evaluating behavior of oxygen, nitrate, and sulfate during recharge and quantifying reduction rates in a contaminated aquifer

This study evaluates the biogeochemical changes that occur when recharge water comes in contact with a reduced aquifer. It specifically addresses (1) which reactions occur in situ, (2) the order in which these reactions will occur if terminal electron acceptors (TEAs) are introduced simultaneously, (3) the rates of these reactions, and (4) the roles of the aqueous and solid-phase portions of the aquifer. Recharge events of waters containing various combinations of O 2 , NO 3 , and SO 4 were simulated at a shallow sandy aquifer contaminated with waste fuels and chlorinated solvents using modified push−pull tests to quantify rates. In situ rate constants for aerobic respiration (14.4 day - 1 ), denitrification (5.04−7.44 day - 1 ), and sulfate reduction (4.32−6.48 day - 1 ) were estimated. Results show that when introduced together, NO 3 and SO 4 can be consumed simultaneously at similar rates. To distinguish the role of aqueous phase from that of the solid phase of the aquifer, groundwater was extracted, amended with NO 3 and SO 4 , and monitored over time. Results indicate that neither NO 3 nor SO 4 was reduced during the course of the aqueous-phase study, suggesting that NO 3 and SO 4 can behave conservatively in highly reduced water. It is clear that sediments and their associated microbial communities are important in driving redox reactions.

Environmental Science & Technology

Large-scale flow experiments for managing river systems

Experimental manipulations of streamflow have been used globally in recent decades to mitigate the impacts of dam operations on river systems. Rivers are challenging subjects for experimentation, because they are open systems that cannot be isolated from their social context. We identify principles to address the challenges of conducting effective large-scale flow experiments. Flow experiments have both scientific and social value when they help to resolve specific questions about the ecological action of flow with a clear nexus to water policies and decisions. Water managers must integrate new information into operating policies for large-scale experiments to be effective. Modeling and monitoring can be integrated with experiments to analyze long-term ecological responses. Experimental design should include spatially extensive observations and well-defined, repeated treatments. Large-scale flow manipulations are only a part of dam operations that affect river systems. Scientists can ensure that experimental manipulations continue to be a valuable approach for the scientifically based management of river systems.

BioScience

Paleocene-Eocene dinoflagellate biostratigraphy in the central Delaware coastal plain

Dinoflagellate cyst palynology and lithostratigraphy from three continuously cored boreholes (Blackbird, Smyrna, and Woodland Beach), supplemented by calcareous nannofossil biostratigraphic data, were used to refine the age and correlation of three Paleocene-Eocene formations in northern Delaware: the Vincentown, Manasquan, and Shark River. Lithologic logs reveal significant facies changes in the upper Paleocene Vincentown Formation over a short distance (*9 km) southeastward, transitioning from very permeable glauconite-quartz-shell-rich sands that form the regionally important Rancocas/Aquia aquifer to much less permeable muddy sands and sandy muds. These lithologic changes represent a shift from nearshore, clear, warm-water, carbonate-rich sand shoals to mud-dominated deeper-water, offshore shelfal environments. Dinocyst assemblages including Areoligera gippingensis, Cribroperidinium giuseppei, and Stenodinium meckelfeldensis confirm the Paleogene ages and track these paleoceanographic changes from shallow coastal settings updip to neritic or outer marine settings downdip. The Vincentown Formation is unconformably overlain by the lower Eocene Manasquan Formation, which consists predominantly of silt and clay with relatively consistent lithology across the study area, representing general neritic or open marine conditions. Lithology, dinoflagellate cyst assemblages, and calcareous nannofossil data indicate that the Marlboro Clay and its record of the onset of the Paleocene-Eocene Thermal Maximum (PETM) global warming event is absent from the Paleocene-Eocene transition at these sites, with an unconformity marking the boundary between the Vincentown and Manasquan formations. The youngest unit examined, the Eocene Shark River Formation, unconformably overlies the Manasquan Formation and consists of interbedded clayey silts and sands, with dinoflagellate assemblages suggesting a return to coastal or inner neritic settings. Calcareous nannofossil zones recognized from the Woodland Beach core corroborate the depositional ages determined using dinoflagellates throughout the sequence, confirming the chronostratigraphic framework for these important coastal plain units.

Delaware

Channel morphology and bed-sediment characteristics before and after riparian vegetation clearing in the Cottonwood Ranch, Platte River, Nebraska, water years 2001-2004

Riparian areas along a reach of Platte River passing through Nebraska Public Power District's Cottonwood Ranch Property were modified during 2002 to 2004 to enhance in-channel habitats for endangered and threatened avian species. A component of this alteration involved the removal of riparian vegetation from riverbanks and islands to provide roosting habitat for the endangered whooping crane and to provide nesting and foraging habitat for the endangered least tern and threatened piping plover. It was hypothesized that the removal of riparian vegetation could have the effect of stimulating channel widening in this reach by increasing the potential of these surfaces to erode under natural fluvial action. It also was hypothesized that as a direct or indirect consequence of the alterations, a local increase in sediment supply also might occur, potentially resulting in geomorphic change downstream and possibly initiating negative third-party effects. The cumulative effects of the management activities on the channel morphology and sediment transport in this reach were monitored during water years 2001-2004 by measuring transect elevation profiles and bed-sediment-size gradations upstream, within, and downstream from the managed area before and after the development activities. An analysis of variance (ANOVA) was performed to determine if the geomorphic variables measured before and after the development activities were significantly different. Although statistically significant differences were detected in some of the variables, increases in mean bed elevation did not occur in a greater percentage of the monitoring sections measured downstream compared to upstream from the management activities. This result suggests that the management activities did not have a substantial effect on the downstream river channel morphology and sediment transport. However, it is important to place these short-term and site-specific results in the context that river flows following the management activities were at historical low rates, and therefore the potential to affect and the opportunity to detect possible geomorphic change within and downstream from the managed reach were limited.

Scientific Investigations Report

Quality of water in the White River and Lake Tapps, Pierce County, Washington, May-December 2010

The White River and Lake Tapps are part of a hydropower system completed in 1911–12. The system begins with a diversion dam on the White River that routes a portion of White River water into the southeastern end of Lake Tapps, which functioned as a storage reservoir for power generation. The stored water passed through the hydroelectric facilities at the northwestern end of the lake and returned to the White River through the powerhouse tailrace. Power generation ceased in January 2004, which altered the hydrology of the system by reducing volumes of water diverted out of the river, stored, and released through the powerhouse. This study conducted from May to December 2010 created a set of baseline data collected under a new flow regime for selected reaches of the White River, the White River Canal (Inflow), Lake Tapps Diversion (Tailrace) at the powerhouse, and Lake Tapps. Three sites, one on the White River at Headworks, one on the White River at R Street, and one on the Tailrace, were equipped for continuous recording of water-quality data, and three sites (Headworks, White River Canal Inflow, and Tailrace) were sampled for discrete water-quality data. Nine lake sites were measured for physical and water-quality properties and samples were collected for analyses of nutrients, suspended solids, and fecal-coliform bacteria concentrations. Samples from the lake also were analyzed for concentrations of chlorophyll a and organic chemicals. Discrete samples indicated that water from the White River, White River Canal Inflow, and Tailrace sites generally was turbid, warm, chemically dilute, and well-oxygenated. Exceptions occurred at the sites when flow to the White River Canal was suspended or when little or no flow was released from the lake into the Tailrace. The quality of physical properties and concentrations in water measured continuously at the three sites generally was good and met the freshwater criteria designated by Washington State Department of Ecology for recreational and aquatic-life uses, with several exceptions. The 7-day average of daily maximum temperatures (7–DADMax) was greater than the freshwater aquatic life criterion of 16 degrees Celsius (°C) for core summer salmonid habitat on 6 days at the Headworks site and 37 days at the R-Street site during the study. The 7-DADMax temperatures were greater than the 13°C criterion for spawning, rearing, and incubation on 6 days at the Headworks site and 20 days at the R-Street site. The freshwater aquatic life criterion for dissolved oxygen of 9.5 milligrams per liter (mg/L) for core summer salmonid habitat was not met at the Headworks and R-Street sites for periods during July and August 2010. Exceptions also occurred at the Headworks site for measurements of pH, which were greater than the aquatic life upper limit of 8.5 pH units during July 2010. Aquatic life pH criteria were not met at the Tailrace site during June, July, and August 2010, when pH was greater than 8.5 pH units, and during August 2010 when pH decreased to less than 6.5 pH units. Lake Tapps water near the surface was relatively clear, warm, and well oxygenated. The clearest water of the nine lake sites was at the Deep site with a median Secchi disk transparency measurement of 6.05 m (meters), which represents a two- to six-fold increase over historical measurements of transparency at this location. Median water temperatures were 18.2–18.9°C and maximums were from 22.9–25.0°C. Median dissolved oxygen concentrations were greater than 8.42 mg/L and minimums generally were not lower than 7.4 mg/L. By early July 2010, weak thermal stratification developed at most lake sites into at least a warm surface layer overlying a small thermocline. A well-defined hypolimnion developed below the thermocline only at the Deep site. With the development of thermal stratification, hypolimnion water became anoxic at several sites (Deep, Tapps Island, Snag Island, and Lake Outlet). By late September 2010, an anoxic layer about 15 m thick had formed in the hypolimnion of the Deep site. Mixing during autumn overturn in late November re-oxygenated the water column of all the sites with about 10–12 mg/L of dissolved oxygen. On the basis of pH and specific conductance measurements, Lake Tapps water is pH neutral and chemically dilute. Median pH values for water in the epilimnion and the hypolimnion ranged from 6.84 to 7.64 pH units and maximums did not exceed 7.8 pH units at any site. Median specific conductance was typically less than 70 microsiemens per centimeter at 25°C for the epilimnion and the hypolimnion. Concentrations of nutrients and chlorophyll a in Lake Tapps were low. At most of the sites and in most of the samples from the epilimnion, total phosphorus concentrations were less than the Washington State Department of Ecology phosphorus criterion of 0.01 mg/L for maintaining oligotrophic conditions. Median concentrations of total nitrogen (unfiltered water) ranged from about 0.14 mg/L (Deep, Tapps Island, and Dike 2B sites) to about 0.18 mg/L (Allan Yorke and Lake Inlet sites). Chlorophyll a concentrations were low with median concentrations of 2.16 micrograms per liter (mg/L) or less. The majority of chlorophyll a concentrations were well below the Oregon Department of Environmental Quality action level of 10 mg/L. Using the Carlson Trophic-Status Index and average measures of transparency, chlorophyll a , and total phosphorus data from this study, Lake Tapps generally fits within the oligotrophic classification, but with a few exceptions. At Allan Yorke, Lake Inlet, and Southeast Arm sites, the chlorophyll a and total phosphorus indexes of nearly 40 approach the upper limit of oligotrophic conditions. In addition, average concentrations of total phosphorus at Lake Inlet and Southeast Arm are at Nürnberg's (1996) threshold concentration of 0.01 mg/L, which suggests a slight tendency towards mesotrophic conditions at these two sites during summer July–September. On the basis of epilimnetic nitrogen to phosphorus concentration ratios of greater than 17, Lake Tapps primary production is phosphorus limited at all but two study sites. At the Lake Inlet and Southeast Arm sites, ratios of 15 and 16, respectively, for the summer period suggest either nitrogen or phosphorus (or both) may limit algal growth. Water samples collected at the Allan Yorke, Snag Island, and Lake Outlet study sites were screened for the presence of more than 250 organic chemicals. A total of 14 compounds were detected in trace amounts (or determined to be present) at one or more of the 3 sites. The Allan Yorke site had 9 detections, the Snag Island site had 10 detections, and the Lake Outlet site had 5 detections of compounds mostly belonging to the group of wastewater indicator chemicals. Compounds detected (or with verified presence) at all three sites included the herbicide 2,4-D, the insecticide and mosquito repellant DEET, the herbicide fluridone used for Eurasian watermilfoil eradication, and the herbicide prometon. The largest concentrations of these compounds were in samples from the Allan Yorke site; the lowest concentrations were from the Lake Outlet site.

Washington

Caffeine and pharmaceuticals as indicators of waste water contamination in wells

The presence of caffeine or human Pharmaceuticals in ground water with elevated nitrate concentrations can provide a clear, unambiguous indication that domestic waste water is a source of some of the nitrate. Water from domestic, public supply, and monitoring wells in three communities near Reno, Nevada, was sampled to test if caffeine or Pharmaceuticals are common, persistent, and mobile enough in the environment that they can be detected in nitrate-contaminated ground water and, thus, can be useful indicators of recharge from domestic waste water. Results of this study indicate that these compounds can be used as indicators of recharge from domestic waste water, although their usefulness is limited because caffeine is apparently nonconservative and the presence of prescription Pharmaceuticals is unpredictable. The absence of caffeine or Pharmaceuticals in ground water with elevated nitrate concentrations does not demonstrate that the aquifer is free of waste water contamination. Caffeine was detected in ground water samples at concentrations up to 0.23 μg/L. The human Pharmaceuticals chlorpropamide, phensuximide, and carbamazepine also were detected in some samples.

Groundwater

Determination of the relative uptake of ground vs. surface water by Populus deltoides during phytoremediation

The use of plants to remediate polluted groundwater is becoming an attractive alternative to more expensive traditional techniques. In order to adequately assess the effectiveness of the phytoremediation treatment, a clear understanding of water-use habits by the selected plant species is essential. We examined the relative uptake of surface water (i.e., precipitation) vs. groundwater by mature Populus deltoides by applying irrigation water at a rate equivalent to a 5-cm rain event. We used stable isotopes of hydrogen (D) and oxygen (18O) to identify groundwater and surface water (irrigation water) in the xylem sap water. Pretreatment isotopic ratios of both deuterium and 18O, ranked from heaviest to lightest, were irrigation water > groundwater > xylem sap. The discrepancy in preirrigation isotopic signatures between groundwater and xylem sap suggests that in the absence of a surface source of water (i.e., between rain events) there is an unknown amount of water being extracted from sources other than groundwater (i.e., soil surface water). We examined changes in volumetric soil water content (%), total hourly sapflux rates, and trichloroethene (TCE) concentrations. Following the irrigation treatment, volumetric soil water increased by 86% and sapflux increased by as much as 61%. Isotopic signatures of the xylem sap became substantially heavier following irrigation, suggesting that the applied irrigation water was quickly taken up by the plants. TCE concentrations in the xylem sap were diluted by an average of 21% following irrigation; however, dilution was low relative to the increase in sapflux. Our results show that water use by Populus deltoides is variable. Hence, studies addressing phytoremediation effectiveness must account for the relative proportion of surface vs. groundwater uptake.

International Journal of Phytoremediation

Health and condition of endangered juvenile Lost River and shortnose suckers relative to water quality and fish assemblages in Upper Klamath Lake, Oregon, and Clear Lake Reservoir, California

Executive Summary Most mortality of endangered Lost River ( Deltistes luxatus ) and shortnose ( Chasmistes brevirostris ) suckers in Upper Klamath Lake, Oregon, appears to occur within the first year of life. However, juvenile suckers in Clear Lake Reservoir, California, appear to survive longer and may even recruit to the spawning populations. Our goal in this study was to develop productive lines of inquiry into the causes of mortality of juvenile suckers, especially in Upper Klamath Lake, through comparison of sucker health and environmental conditions in both lakes. The health of juvenile suckers was associated with physical, biological, and chemical characteristics in each lake from July to September 2013 and 2014. Water-quality dynamics differed substantially between lakes. Diel fluctuations were greater for dissolved-oxygen concentrations and pH in Upper Klamath Lake than in Clear Lake Reservoir, but diel temperature fluctuations were greater in Clear Lake Reservoir. Minimum dissolved-oxygen concentrations were as low as 1.0 milligram per liter (mg/L) in Upper Klamath Lake, but were no lower than 5.7 mg/L in Clear Lake Reservoir. Unionized ammonia (NH 3 ) concentrations were near or less than the minimum reporting limit of 0.002 mg/L NH 3 in Clear Lake Reservoir and generally were less than the concentration known to cause cellular changes to the gills or mortality of suckers in Upper Klamath Lake. Concentrations of microcystins were less than the detection limit (&le;0.10 microgram per liter [&mu;g/L]) in both dissolved (<63 micrometers [&mu;m]) and particulate (&ge;63 &mu;m) fractions of water samples collected from Clear Lake Reservoir in both years. In Upper Klamath Lake, concentrations of microcystins were relatively low in the 2013 particulate fractions and dissolved fractions of samples in both years, but as high as 44.30 &mu;g/L, more than 44 times the World Health Organization recommended levels for drinking water (1 &mu;g/L), in the 2014 particulate fraction. However, there was little histological evidence and no chemical evidence that these concentrations in water were harmful to suckers that we captured. The species and age compositions of juvenile sucker populations differed between lakes. A total of 98 percent of all juvenile suckers captured in Upper Klamath Lake were age-0. In contrast, as many as six age classes of suckers were represented in Clear Lake Reservoir, indicating much better juvenile survival than in Upper Klamath Lake. Based on genetic species identification, 98 percent of juvenile suckers collected from Clear Lake Reservoir were shortnose or Klamath largescale suckers ( Catostomus snyderi ). In contrast, there was a high degree of apparent genetic hybridization in juvenile suckers collected from Upper Klamath Lake, and both Lost River and non-Lost River juvenile suckers were nearly equally represented in samples. Neither gross nor histological examination revealed a high prevalence of abnormalities in suckers that might indicate a mechanism for juvenile mortality in Upper Klamath Lake. Therefore, high mortality primarily may have occurred outside our study period (for example, in spring or over winter), or was owing to a factor that could not be detected with our methods (for example, predation). Alternatively, abnormalities in a small percentage of passively captured suckers in Upper Klamath Lake may indicate health-related issues that were more prevalent in populations than in our samples. Some apparent symptoms of stress or exposure to irritants, such as peribiliary cuffing in hepatocytes and mild inflammation and necrosis in gill tissues, were present in suckers from both lakes and do not appear to be clues to the cause of differential mortality between lakes. Seasonal trends in energy storage as glycogen and triglycerides were similar between lakes, indicating prey availability was not a factor in differential mortality. Differences in sucker health and condition between lakes were considered the most promising clues to the causes of differential juvenile sucker morality between lakes. A low prevalence of petechial hemorrhaging of the skin (16 percent) and deformed opercula (8 percent) in Upper Klamath Lake suckers may indicate exposure to a toxin other than microcystin. Suckers grew slower in their first year of life, but had similar or greater triglyceride and glycogen levels in Upper Klamath Lake compared to Clear Lake Reservoir. These findings do not suggest a lack of prey quantity but may indicate lower prey quality in Upper Klamath Lake.

California, Oregon