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Monthly streamflow and ground-water conditions in the United States and southern Canada, water years, 1945-85

The Water Resources Division of the U.S. Geological Survey has been measuring streamflow since 1888 and collecting ground-water data since 1894. The monthly publication Water Resources Review (now National Water Conditions) was established in water year 1945 to provide information quickly to the public on the status of surface- and ground-water resources of the Nation. Each monthly issue contains a map depicting the status of water conditions relative to normal for that month. This report presents these maps and a synopsis of surface and ground-water conditions for the last 41 water years (194585); a water year begins October 1 and ends September 30 of the following year.

Water Supply Paper↗

Overview of drought and hydrologic conditions in the United States and southern Canada, water years 1986-90

This report describes the drought and hydrologic conditions in the United States and southern Canada during the 1986-90 water years. This drought, which spread from the Eastern United States, where it was referred to as 'the drought of the century,' through the Midwest to the West Coast, brought to mind the Dust Bowl era of the 1930's. However, generally localized floods were numerous, but only one hurricane (Hugo) was of any consequence to the United States, Puerto Rico, and the Virgin Islands during a coincident period of anomalously low hurricane activity. The drought began in early 1984 as an 'agricultural drought,' which is a precipitation deficiency that results in a lack of soil moisture that is detrimental to agricultural production. This condition did not affect streamflow until about March or April 1986. A 'hydrological drought,' which is far more serious and widespread than an agricultural drought, was apparent from the low streamflow conditions that occurred after April 1986. To illustrate the changing nature of the drought, maps and synopses of monthly hydrologic conditions for the water years 1986-90 are presented.

Water Supply Paper↗

Methods for delineating flood-prone areas in the Great Basin of Nevada and adjacent states

The Great Basin is a region of about 210,000 square miles having no surface drainage to the ocean; it includes most of Nevada and parts of Utah, California, Oregon, Idaho, and Wyoming. The area is characterized by many parallel mountain ranges and valleys trending north-south. Stream channels usually are well defined and steep within the mountains, but on reaching the alluvial fan at the canyon mouth, they may diverge into numerous distributary channels, be discontinuous near the apex of the fan, or be deeply entrenched in the alluvial deposits. Larger rivers normally have well-defined channels to or across the valley floors, but all terminate at lakes or playas. Major floods occur in most parts of the Great Basin and result from snowmelt, frontal-storm rainfall, and localized convective rainfall. Snowmelt floods typically occur during April-June. Floods resulting from frontal rain and frontal rain on snow generally occur during November-March. Floods resulting from convective-type rainfall during localized thunderstorms occur most commonly during the summer months. Methods for delineating flood-prone areas are grouped into five general categories: Detailed, historical, analytical, physiographic, and reconnaissance. The detailed and historical methods are comprehensive methods; the analytical and physiographic are intermediate; and the reconnaissance method is only approximate. Other than the reconnaissance method, each method requires determination of a T-year discharge (the peak rate of flow during a flood with long-term average recurrence interval of T years) and T-year profile and the development of a flood-boundary map. The procedure is different, however, for each method. Appraisal of the applicability of each method included consideration of its technical soundness, limitations and uncertainties, ease of use, and costs in time and money. Of the five methods, the detailed method is probably the most accurate, though most expensive. It is applicable to hydraulic and topographic conditions found in many parts of the Great Basin. The historical method is also applicable over a wide range of conditions and is less expensive than the detailed method. However, it requires more historical flood data than are usually available, and experience and judgement are needed to obtain meaningful results. The analytical method is also less expensive than the detailed method and can be used over a wide range of conditions in which the T-year discharge can be determined directly. Experience, good judgement, and thorough knowledge of hydraulic principles are required to obtain adequate results, and the method has limited application in other than rigid-channel situations. The physiographic method is applicable to rigid-boundary channels and is less accurate than the detailed method. The reconnaissance method is relatively imprecise, but it may be the most rational method to use on alluvial fans or valley floors with discontinuous channels. In general, a comprehensive method is most suitable for use with rigid-bank streams in urban areas; only an approximate method seems justified in undeveloped areas.

Water Supply Paper↗

Simulation of flood hydrographs for Georgia streams

Flood hydrographs are needed for the design of many highway drainage structures and embankments. A method for simulating these flood hydrographs at ungaged sites in Georgia is presented in this report. The O'Donnell method was used to compute unit hydrographs and lagtimes for 355 floods at 80 gaging stations. An average unit hydrograph and an average lagtime were computed for each station. These average unit hydrographs were transformed to unit hydrographs having durations of one-fourth, one-third, one-half, and three-fourths lagtime, then reduced to dimensionless terms by dividing the time by lagtime and the discharge by peak discharge. Hydrographs were simulated for these 355 floods and their widths were compared with the widths of the observed hydrographs at 50 and 75 percent of peak flow. The dimensionless hydrograph based on one-half lagtime duration provided the best fit of the observed data. Multiple regression analysis was then used to define relations between lagtime and certain physical basin characteristics; of these characteristics, drainage area and slope were found to be significant for the rural-stream equations and drainage area, slope, and impervious area were found to be significant for the Atlanta urban-stream equation. A hydrograph can be simulated from the dimensionless hydrograph, the peak discharge of a specific recurrence interval, and the lagtime obtained from regression equations for any site in Georgia having a drainage area of less than 500 square miles. For simulating hydrographs at sites having basins larger than 500 square miles, the U.S. Geological Survey computer model CONROUT can be used. This model routes streamflow from an upstream channel location to a user-defined location downstream. The product of CONROUT is a simulated discharge hydrograph for the downstream site that has a peak discharge of a specific recurrence interval.

Georgia↗

Application of the two-film model to the volatilization of acetone and t-butyl alcohol from water as a function of temperature

The two-film model is often used to describe the volatilization of organic substances from water. This model assumes uniformly mixed water and air phases separated by thin films of water and air in which mass transfer is by molecular diffusion. Mass-transfer coefficients for the films, commonly called film coefficients, are related through the Henry's law constant and the model equation to the overall mass-transfer coefficient for volatilization. The films are modeled as two resistances in series, resulting in additive resistances. The two-film model and the concept of additivity of resistances were applied to experimental data for acetone and t-butyl alcohol. Overall mass-transfer coefficients for the volatilization of acetone and t-butyl alcohol from water were measured in the laboratory in a stirred constant-temperature bath. Measurements were completed for six water temperatures, each at three water mixing conditions. Wind-speed was constant at about 0.1 meter per second for all experiments. Oxygen absorption coefficients were measured simultaneously with the measurement of the acetone and t-butyl alcohol mass-transfer coefficients. Gas-film coefficients for acetone, t-butyl alcohol, and water were determined by measuring the volatilization fluxes of the pure substances over a range of temperatures. Henry's law constants were estimated from data from the literature. The combination of high resistance in the gas film for solutes with low values of the Henry's law constants has not been studied previously. Calculation of the liquid-film coefficients for acetone and t-butyl alcohol from measured overall mass-transfer and gas-film coefficients, estimated Henry's law constants, and the two-film model equation resulted in physically unrealistic, negative liquid-film coefficients for most of the experiments at the medium and high water mixing conditions. An analysis of the two-film model equation showed that when the percentage resistance in the gas film is large and the gas-film resistance approaches the overall resistance in value, the calculated liquid-film coefficient becomes extremely sensitive to errors in the Henry's law constant. The negative coefficients were attributed to this sensitivity and to errors in the estimated Henry's law constants. Liquid-film coefficients for the absorption of oxygen were correlated with the stirrer Reynolds number and the Schmidt number. Application of this correlation with the experimental conditions and a molecular-diffusion coefficient adjustment resulted in values of the liquid-film coefficients for both acetone and t-butyl alcohol within the range expected for all three mixing conditions. Comparison of Henry's law constants calculated from these film coefficients and the experimental data with the constants calculated from literature data showed that the differences were small relative to the errors reported in the literature as typical for the measurement or estimation of Henry's law constants for hydrophilic compounds such as ketones and alcohols. Temperature dependence of the mass-transfer coefficients was expressed in two forms. The first, based on thermodynamics, assumed the coefficients varied as the exponential of the reciprocal absolute temperature. The second empirical approach assumed the coefficients varied as the exponential of the absolute temperature. Both of these forms predicted the temperature dependence of the experimental mass-transfer coefficients with little error for most of the water temperature range likely to be found in streams and rivers. Liquid-film and gas-film coefficients for acetone and t-butyl alcohol were similar in value. However, depending on water mixing conditions, overall mass-transfer coefficients for acetone were from two to four times larger than the coefficients for t-butyl alcohol. This difference in behavior of the coefficients resulted because the Henry's law constant for acetone was about three times larger than that of

Water Supply Paper↗

Ground-water conditions in Las Vegas Valley, Clark County, Nevada; part 1 Hydrogeologic Framework

This report describes the lithology, thickness, and extent of valley-fill deposits in Las Vegas Valley, Nev. This information will be used to develop a hydraulic model of the valley's ground-water system. Las Vegas Valley is a structural basin formed by bedrock that ranges in age from Precambrian through Miocene. Gravity data indicate that the deeper parts of the basin are filled with 3,000-5,000 feet of clastic sedimentary deposits that range in age from Miocene through Holocene. These deposits constitute the valley-fill aquifer and yield most of the water pumped in the valley. The upper 1,000 feet of this valley fill consist of coarse-grained deposits (sand and gravel), fine-grained deposits (silt and clay), and heterogeneous deposits that comprise either thinly interbedded coarse- and fine-grained deposits or mixtures of the two. Coarse-grained deposits, in places more than 1,000 feet thick, underlie the south and west sides of the valley and interfinger with fine-grained and heterogeneous deposits toward the center of the valley. Intervals of fairly thin heterogeneous deposits underlie parts of the valley, but they are not laterally persistent. The distribution of coarse-grained and fine-grained deposits in three depth zones of the valley fill (0-200 feet, 200-700 feet, and 700-1,000 feet) suggests that: (1) the Spring Mountains and McCullough Range were the major sources of clastic material for the valley fill; (2) Frenchman Mountain and the Las Vegas Range were emplaced later than the Spring Mountains; (3) the east side of the Spring Mountains, which was originally closer to the center of the valley, has receded westward because of erosion; and (4) shallow, fine-grained deposits (0-200 feet deep) are more susceptible to subsidence than deeper ones. The bedrock basin that underlies Las Vegas Valley consists of a deeply buried part that underlies most of the valley and a shallow bedrock surface on the west side of the valley. The deep part of the basin is bounded on the east by normal faults at the base of Frenchman Mountain, on the west by a possible normal fault that coincides with a zone of fault scarps, on the north by vertical or strike-slip displacement along the Las Vegas shear zone, and on the northwest by a bedrock high that underlies the area between Tule Springs and Corn Creek Springs. The shallow bedrock surface (as much as 1,000 feet deep) underlies the west side of the valley from La Madre Mountain to the McCullough Range. Some of the fault scarps in the valley fill coincide with possible bedrock faults, which suggests a tectonic origin for some of the faulting of valley-fill deposits; however, the area of fault scarps on the west side of the valley also coincides with a rapid lateral change from incompressible bedrock to more compressible valley-fill deposits. Thus, both differential compaction and tectonic movement may be responsible for faulting of valley-fill deposits.

Water Supply Paper↗

Ground-water conditions in Las Vegas Valley, Clark County, Nevada: Part 2, hydrogeology and simulation of ground-water flow

In sedimentary deposits beneath arid Las Vegas Valley, ground-water levels have declined as much as 280 feet since 1912 in deeper aquifers due to pumping associated with urban development. Accompanying land subsidence has been as great as 5 feet. Predictive simulations show that by maintaining pumpage and recharge at 1980 levels and using municipal wells only during periods of peak water demand, rates of water-level decline and land subsidence will be reduced.

Nevada↗

Leachate migration from an in-situ oil-shale retort near Rock Springs, Wyoming

Hydrogeologic factors influencing leachate movement from an in-situ oil-shale retort near Rock Springs, Wyoming, were investigated through models of ground-water flow and solute transport. Leachate, indicated by the conservative ion thiocyanate, has been observed ? mile downgradient from the retort. The contaminated aquifer is part of the Green River Formation and consists of thin, permeable layers of tuff and sandstone interbedded with oil shale. Most solute migration has occurred in an 8-foot sandstone at the top of the aquifer. Ground-water flow in the study area is complexly three dimensional and is characterized by large vertical variations in hydraulic head. The solute-transport model was used to predict the concentration of thiocyanate at a point where ground water discharges to the land surface. Leachate with peak concentrations of thiocyanate--45 milligrams per liter or approximately one-half the initial concentration of retort water--was estimated to reach the discharge area during January 1985. This report describes many of th3 advantages, as well as the problems, of site-specific studies. Data such as the distribution of thin, permeable beds or fractures might introduce an unmanageable degree of complexity to basin-wide studies but can be incorporated readily into site-specific models. Solute migration in the study area occurs primarily in thin, permeable beds rather than in oil-shale strata. Because of this behavior, leachate traveled far greater distances than might otherwise have been expected. The detail possible in site-specific models permits more accurate prediction of solute transport than is possible with basin-wide models. A major problem in site-specific studies is identifying model boundaries that permit the accurate estimation of aquifer properties. If the quantity of water flowing through a study area cannot be determined prior to modeling, the hydraulic conductivity and ground-water velocity will be poorly estimated.

Water Supply Paper↗

The geochemical evolution of aqueous sodium in the Black Creek Aquifer, Horry and Georgetown counties, South Carolina

The Black Creek aquifer contains dilute seawater near the North Carolina State line, probably the result of incomplete flushing of ancient seawater. Data do not indicate that the dilute seawater has migrated toward areas of fresh ground-water withdrawals. The concentration of chloride in ground-water samples ranges from 5 to 720 milligrams per liter and that of sodium from 160 to 690 milligrams per liter. Ion-exchange reactions (sodium for calcium and fluoride for hydroxyl) occur with the calcium carbonate dissolution reaction which produces calcium, bicarbonate, and hydroxyl ions. The reaction sequence and stoichiometry result in an aqueous solution in which the sum of bicarbonate and chloride equivalents per liter is equal to the equivalents per liter of sodium. Calcium ions are exchanged for sodium ions derived from sodium-rich clays upgradient of the dilute seawater. The cation-exchange reaction equilibrates at a sodium concentration of 280 milligrams per liter. Amounts of sodium greater than 280 milligrams per liter are contributed from dilute seawater. The cation-exchange reaction approaches an equilibrium which represents a mass-action limit in terms of the ratio of sodium to calcium in solution versus the ratio of exchangeable sodium to calcium on clay surfaces. Where the limit of calcium carbonate solubility is approached and dissolution ceases, some precipitation of calcite probably takes place. The dissolution of calcite exposes fossil shark teeth which release fluoride ions to the ground water through anion exchange with aqueous hydroxyl ions.

South Carolina↗

National water summary 1986: Hydrologic events and ground-water quality

Ground water is one of the most important natural resources of the United States and degradation of its quality could have a major effect on the welfare of the Nation. Currently (1985), ground water is the source of drinking water for 53 percent of the Nation's population and for more than 97 percent of its rural population. It is the source of about 40 percent of the Nation's public water supply, 33 percent of water for irrigation, and 17 percent of freshwater for selfsupplied industries. Ground water also is the source of about 40 percent of the average annual streamflow in the United States, although during long periods of little or no precipitation, ground-water discharges provide nearly all of the base streamflow. This hydraulic connection between aquifers and streams implies that if a persistent pollutant gets into an aquifer, it eventually could discharge into a stream. Information presented in the 1986 National Water Summary clearly shows that the United States has very large amounts of potable ground water available for use. Although naturally occurring constituents, such as nitrate, and human-induced substances, such as synthetic organic chemicals, frequently are detected in ground water, their concentrations usually do not exceed existing Federal or State standards or guidelines for maximum concentrations in drinking water. Troublesome contamination of ground water falls into two basic categories related to the source or sources of the contamination. Locally, high concentrations of a variety of toxic metals, organic chemicals, and petroleum products have been detected in ground water associated with point sources such as wastedisposal sites, storage-tank leaks, and hazardous chemical spills. These types of local problems commonly occur in densely populated urban areas and industrialized areas. Larger, multicounty areas also have been identified where contamination frequently is found in shallow wells. These areas generally are associated with broad-scale, or nonpoint, sources of contamination such as agricultural activities or highdensity domestic waste disposal (septic systems) in urban centers. At present, only a very small percentage of the total volume of potable ground water in the United States is contaminated from both point and nonpoint sources; however, available data, especially data about the occurrence of synthetic organic and toxic substances, generally are inadequate to determine the full extent of ground-water contamination in the Nation's aquifers or to define trends in groundwater quality. Most information about the occurrence of these substances has come from the study of individual sites or areas where contamination had already been detected or suspected. Management and protection of ground water present a major challenge to the Nation. Current and projected costs of detection and cleanup of existing ground-water contamination are staggering and, even so, complete removal of pollutants from ground water in the vicinity of some waste sites might not be technically feasible. At all levels of government, the task of protecting the resource for its most beneficial uses is difficult and controversial. Despite increasing awareness that some of the Nation's ground water is contaminated with a variety of toxic metals, synthetic organic chemicals, radionuclides, pesticides, and other contaminants that might present a long-term risk to human health, public policy towards ground-water protection is still in the formative stages. Despite increasing efforts devoted to ground-water protection by State and Federal regulatory and resource-management agencies, the extent of ground-water contamination is likely to appear to increase over the next few years because more agencies will be searching for evidence of contamination, and they will be using increasingly sensitive analytical procedures. Increased technology and expanded monitoring activities probably will detect the effects of past contamination and land uses on water quality. The significant time lag between a waterquality change in one part of an aquifer system and the effects of that change at a downgradient site, such as a well, results from the generally slow movement of ground water. This lag between cause and observed effect needs to be considered in evaluating the effectiveness of current and future ground-water policies and remedial measures. Conclusive answers to questions about the location, extent, and severity of ground-water contamination, and about trends in ground-water quality, must await further collection and analysis of data from the Nation's aquifers. Generalizations, however, can be made, and the 1986 National Water Summary, which describes the natural quality of ground-water resources in each State and the major contamination problems that have been identified as of 1986, provides a national perspective of the ground-water-quality situation. The 1986 National Water Summary follows the format of previous volumes. It contains three parts, and the contents of each of these parts are highlighted below.

Water Supply Paper↗

Sand waves, bars, and wind-blown sands of the Rio Orinoco, Venezuela and Colombia

During March 1982, a reconnaissance study was carried out along a reach of the Rio Orinoco between Puerto Ayacucho and Ciudad Bolivar. This was the low-flow season. Samples of bed material and suspended sediments were collected, sonic records of the bed were obtained at several locations, and the exposed bars and sand waves were studied at four locations. Sounding records were obtained at two of these locations during June and November when flow covered the bars, and additional studies were made on the ground at some of these same sites during March 1983. The bed of the river is mostly sand with small quantities, about 5 percent by weight on average, of gravel. Suspended- sediment concentrations were low, ranging between 20 milligrams per liter above Rio Apure to almost 40 milligrams per liter below its confluence with the Rio Orinoco. The annual sediment load is estimated to be 240x10 6 megagrams per year. During the dry season, 35 percent or more of the bed is exposed in the form of large bars composed of many sand waves. Trade winds blow upriver and there is substantial upriver transport of river sediments by the wind. If the bars contain very coarse sands and fine gravel, deflation forms a lag deposit that armors the bar surface and prevents further erosion. Theoretical calculations show that the lower limit for the fraction of the bed that needs to be covered with nonmoving particles to prevent further erosion and the smallest size of the armor particles depend only on wind speed. Calculations of bed-material transport were made for a typical wide and narrow section of the river; the annual load, excluding the wash load, is about 30 x 10 6 megagrams per year. A new definition for wash load is proposed; it is material that can be suspended as soon as its motion is initiated. For the Rio Orinoco, this is material finer than 0.1 millimeters.

Water Supply Paper↗

Evapotranspiration and microclimate at a low-level radioactive-waste disposal site in northwestern Illinois

From July 1982 through June 1984, a study was made of the evapotranspiration and microclimate at a low-level radioactive-waste disposal site near Sheffield, Bureau County, Illinois. Vegetation at the site consists of mixed pasture grasses, primarily awnless brome (Bromus inermis) and red clover (Trifoleum pratense). Three methods were used to estimate evapotranspiration: (1) an energy budget with the Bowen ratio, (2) an aerodynamic profile, and (3) a soil-based water budget. For the aerodynamic-profile method, sensible-heat flux was estimated by a profile equation and evapotranspiration was then calculated as the residual in the energy-balance equation. Estimates by the energy-budget and aerodynamic-profile methods were computed from hourly data and then summed by days and months. Yearly estimates (for March through November) by these methods were in close agreement: 648 and 626 millimeters, respectively. Daily estimates reach a maximum of about 6 millimeters. The water-budget method produced only monthly estimates based on weekly or biweekly soil-moisture content measurements. The yearly evapotranspiration estimated by this method (which actually included only the months of April through October) was 655 millimeters. The March-through-November average for the three methods of 657 millimeters was equivalent to 70 percent of total precipitation. Continuous measurements were made of incoming and reflected shortwave radiation, incoming and emitted longwave radiation, net radiation, soil-heat flux, soil temperature, horizontal windspeed, and wet- and dry-bulb air temperature. Windspeed and air temperature were measured at heights of 0.5 and 2.0 meters (and also at 1.0 meter after September 1983). Soilmoisture content of the soil zone was measured with a gamma-attenuation gage. Annual precipitation (938 millimeters) and average temperature (10.8 degrees Celsius) at the Sheffield site were virtually identical to long-term averages from nearby National Weather Service stations. Solar radiation averaged 65 percent of that normally expected under clear skies. Net radiation averaged 70.1 watts per square meter and was highest in July and negative during some winter months. Wind direction varied but was predominately south-southeasterly. Wind speed at the 2-meter height averaged 3.5 meters per second and was slightly higher in winter months than the rest of the year. The amount of water stored within the soil zone was greatest in early spring and least in late summer. Seasonal and diurnal trends of evapotranspiration rates mirrored those of net radiation; July was usually the month with the highest evapotranspiration rate. The ratio of sensible- to latentheat fluxes (commonly called the Bowen ratio) for the 2-year study period was 0.38, as averaged from the three methods. Monthly Bowen ratios fluctuated somewhat but averaged about 0.35 for late spring through summer. In fall, the ratio declined to zero or to slightly negative values. When the ratio was negative, the latent-heat flux was slightly greater than the net radiation because of additional energy supplied by' the cooling soil and air. Evapotranspiration calculated by the three methods averaged 75 percent of potential evapotranspiration, as estimated by the Penman equation. There was no apparent seasonal trend in the relation between actual and potential evapotranspiration rates.

Water Supply Paper↗

A well system to recover usable water from a freshwater-saltwater aquifer in Puerto Rico

Aquifers in coastal areas of Puerto Rico commonly contain limited quantities of freshwater that occur as a thin layer at the surface of the water table. Many wells have been abandoned because well screens were inadvertently placed in saltwater parts of the aquifer. A scavenger/production well couple that can be installed in an abandoned well, screened in both freshwater and saltwater parts of the aquifer, provides an effective method for extracting freshwater from the well. Withdrawal of a sufficient quantity of water having low chloride concentrations, by use of a well couple, depends on the upward movement of saltwater within the aquifer when the well is pumped. Upward movement of saltwater depends on the relative concentrations of chloride in the borehole and on the distribution of horizontal and vertical hydraulic conductivity of the aquifer. For any well screened in an aquifer that contains both freshwater and saltwater, a family of curves can be constructed to represent all combinations of pumping rates and corresponding chloride loads when the scavenger well and the production well are being pumped simultaneously. The curves permit estimates of optimal withdrawals of freshwater based on the desired pumping rates and the levels of chloride concentration required for each well.

Water Supply Paper↗

Effects of highway runoff on streamflow and water quality in the Sevenmile Creek basin, a rural area in the Piedmont Province of North Carolina, July 1981 to July 1982

An evaluation of water-quality data from streams that receive stormwater runoff from a segment of Interstate Highway 85 in North Carolina indicated increased levels of many constituents compared to levels in nearby undeveloped basins. Additional data collected from a network of dry and wet atmospheric deposition collectors, lysimeter samples, soil surveys, wind measurements, and road sweepings helped define the general sources and migration of chemical substances near the highway. The eight study basins, located in a rural area in the Piedmont of North Carolina, had a combined area of 17.5 square miles and drained a 4.8-mile-long segment of the interstate. The average traffic flow along this section was 25,000 vehicles per day. During storm runoff, streamflow in basins traversed by the highway rose and fell more rapidly than that in the undeveloped basins. This more rapid response is due to the impervious, paved area of the basins and the manmade drainage systems designed to rapidly move water off the highway. Alkalinity, specific conductance, and concentrations of calcium, sodium, and chloride were greater at the highway stations than in the undeveloped basins as a result of highway salting for control of ice. Specific conductance and concentrations of dissolved and total nitrogen peaked at the beginning of each storm event. The data indicated that, for the study basins, highway runoff had little or no effect on suspended sediment, water temperature, dissolved oxygen, and pH. However, the pH at all stations decreased during stormflow because the rainfall drained off by the streams had pH values less than 5.7. High metals concentrations were found in the soils within 100 feet of the highway and in the soil water infiltrating the soil zone. Chromium, copper, nickel, and zinc concentrations in the streams near the highway generally were above the maximum levels recommended by the U.S. Environmental Protection Agency (EPA) for the protection of aquatic life. Lead and cadmium concentrations frequently exceeded the maximum levels recommended by the EPA for drinking water. The highway is a source of contaminants to surrounding areas. Particulate and metal loads in dustfall and chemical-constituent concentrations in soils decrease exponentially with distance from the highway. The highest concentrations of contaminants were found on the downwind side. Increased concentrations of metals (cadmium, chromium, iron, lead, nickel, and zinc) in rainfall were observed in samples collected near the highway and in samples collected approximately one-half mile away. Material loading due to dustfall was greater than loading due to rainfall. Loading due to saltated particles, those heavier particles bounced along the highway surface, was higher than loading due to dustfall. Saltation loads were greatest during the winter months because of highway deicing and sanding, which supplied an estimated two-thirds of the saltated materials. The remaining one-third of the saltated load came primarily from the deposition of particles from vehicles. Some of the greatest constituent concentrations were measured in the soil water sampled from the lysimeters located adjacent to the highway.

North Carolina↗