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USGS2004

Hydrologic Effects of the 1988 Galena Fire, Black Hills Area, South Dakota

The Galena Fire burned about 16,788 acres of primarily ponderosa pine forest during July 5-8, 1988, in the Black Hills area of South Dakota. The fire burned primarily within the Grace Coolidge Creek drainage basin and almost entirely within the boundaries of Custer State Park. A U.S. Geological Survey gaging station with streamflow records dating back to 1977 was located along Grace Coolidge Creek within the burned area. About one-half of the gaging station's 26.8-square-mile drainage area was burned. The drainage basin for Bear Gulch, which is tributary to Grace Coolidge Creek, was burned particularly severely, with complete deforestation occurring in nearly the entirety of the area upstream from a gaging station that was installed in 1989. A study to evaluate effects of the Galena Fire on streamflow, geomorphology, and water quality was initiated in 1988. The geomorphologic and water-quality components of the study were completed by 1990 and are summarized in this report. A data-collection network consisting of streamflow- and precipitation-gaging stations was operated through water year 1998 for evaluation of effects on streamflow characteristics, including both annual-yield and peak-flow characteristics, which are the main focus of this report. Moderately burned areas did not experience a substantial increase in the rate of surface erosion; however, severely burned areas underwent surficial erosion nearly twice that of the unburned areas. The sediment production rate of Bear Gulch estimated 8 to 14 months after the fire was 870 ft3/acre (44 tons/acre). Substantial degradation of stream channels within the severely burned headwater areas of Bear Gulch was documented. Farther downstream, channel aggradation resulted from deposition of sediments transported from the headwater areas. The most notable water-quality effect was on concentrations of suspended sediment, which were orders of magnitude higher for Bear Gulch than for the unburned control area. Effects on several other water-quality constituents, such as organic carbon and nitrogen and phosphorus nutrient constituents, probably were influenced by the large concentrations of suspended matter that were documented in initial post-fire, storm-flow events. The first post-fire stormflow produced the highest measured concentrations of specific conductance, nitrogen, phosphorus, organic carbon, calcium, magnesium, potassium, manganese, and sulfate in the burned areas. For most constituents sampled, differences in concentrations between burned and unburned areas were no longer discernible within about 1 year following the Galena Fire. The effects of the Galena Fire on annual-yield characteristics of Grace Coolidge Creek were evaluated primarily from comparisons with long-term streamflow records for Battle Creek, which is hydrogeologically similar and is located immediately to the north. Annual yield for Grace Coolidge Creek increased by about 20 percent as a result of the fire. This estimate was based on relations between annual yield for Grace Coolidge Creek and Battle Creek for pre- and post-burn periods. Many of the post-burn data points are well beyond the range of the pre-burn data, which is a source of uncertainty for this estimate. Substantial increases in peak-flow characteristics for severely burned drainages were visually apparent from numerous post-fire field observations. Various analyses of streamflow data indicated substantial increases in peak-flow response for burned drainage areas; however, quantification of effects was particularly difficult because peak-flow response diminished quickly and returned to a generally pre-burn condition by about 1991. Field observations of vegetation and analysis of remotely sensed data indicated that establishment of grasses and forbs occurred within a similar timeframe. Comparison of pre-fire peak flows to post-1991 peak flows indicates that these grasses and forbs were equally effective in suppressing peak flows

Water-Resources Investigations Report↗

USGS1998

Depth-duration frequency of precipitation for Texas

The U.S. Geological Survey, in cooperation with the Texas Department of Transportation, conducted a study of the depth-duration frequency of precipitation for Texas. Depth-duration frequency is an estimate of the depth of precipitation for a specified duration and frequency or recurrence interval. For this report, precipitation durations of 15, 30, and 60 minutes; 1, 2, 3, 6, 12, and 24 hours; and 1, 2, 3, 5, and 7 days were investigated. The recurrence intervals for the frequencies range from 2 to 500 years. The time series of precipitation annual maxima for 173 fifteen-minute, 274 hourly, and 865 daily National Weather Service precipitation stations with at least 10 years of record in Texas provide the basis of depth-duration frequency for each identified duration. In total, about 3,030; 10,160; and 38,120 cumulative years of record are available for the 15-minute, hourly, and daily stations, respectively. L-moment statistics of the precipitation annual maxima were calculated for each duration and for each station using unbiased L-moment estimators. The statistics calculated were the mean, L-scale, L-coefficient of variation, L-skew, and L-kurtosis. The mean for each station and duration was corrected for the bias associated with fixed-interval recording of precipitation. The generalized logistic distribution was determined, using L-moment ratio diagrams, as an appropriate probability distribution for modeling the frequency of annual maxima for durations of 15 minutes to 24 hours; whereas, the generalized extreme-value distribution was determined as appropriate for durations of 1 to 7 days. The location, scale, and shape parameters of the distributions for each duration and each station were calculated from the L-moments. These parameters were contoured using spatial interpolation, based on the geostatistical method of kriging, to produce 37 maps that depict the spatial variation and magnitude of each parameter. Contour maps of the shape parameter for the generalized extreme-value distribution for durations of 1 to 7 days are not presented; the root mean square errors of preliminary maps for 1- to 7-day shape parameters were not appreciably smaller than the statewide standard deviation. Therefore, a single statewide mean shape parameter was used for 1- to 7-day durations. The depth-duration frequency for any location in Texas can be estimated using the contour maps and the equation of the corresponding distribution.

Texas↗

USGS1999

Characteristics of fractures in crystalline bedrock determined by surface and borehole geophysical surveys, eastern surplus superfund site, Meddybemps, Maine

Surface and borehole geophysical methods were used to determine fracture orientation in crystalline bedrock at the Eastern Surplus Superfund Site in Meddybemps, Maine. Fracture-orientation information is needed to address concerns about the fate of contaminants in ground water at the site. Azimuthal square-array resistivity surveys were conducted at 3 locations at the site, borehole-acoustic televiewer and borehole-video logs were collected in 10 wells, and single-hole directional radar surveys were conducted in 9 wells. Borehole-video logs were used to supplement the results of other geophysical techniques and are not described in this report. Analysis of azimuthal square-array resistivity data indicated that high-angle fracturing generally strikes northeast-southwest at the three locations. Borehole-acoustic televiewer logs detected one prominent low-angle and two prominent high-angle fracture sets. The low-angle fractures strike generally north-northeast and dip about 20 degrees west-northwest. One high-angle fracture set strikes north-northeast and dips east-southeast; the other high-angle set strikes east-northeast and dips south-southeast. Single-hole directional radar surveys identified two prominent fracture sets: a low-angle set striking north-northeast, dipping west-northwest; and a high-angle fracture set striking north-northeast, dipping east-southeast. Two additional high-angle fracture sets are defined weakly, one striking east-west, dipping north; and a second striking east-west, dipping south. Integrated results from all of the geophysical surveys indicate the presence of three primary fracture sets. A low-angle set strikes north-northeast and dips west-northwest. Two high-angle sets strike north-northeast and east-northeast and dip east-southeast and south-southeast. Statistical correction of the fracture data for orientation bias indicates that high-angle fractures are more numerous than observed in the data but are still less numerous than the low-angle fractures. The orientation and distribution of water-yielding fractures sets were determined by correlating the fracture data from this study with previously collected borehole-flowmeter data. The water-yielding fractures are generally within the three prominent fracture sets observed for the total fracture population. The low-angle water-yielding fractures primarily strike north-northeast to west-northwest and dip west-northwest to south-southwest. Most of the high-angle water-yielding fractures strike either north-northeast or east-west and dip east-southeast or south. The spacing between water-yielding fractures varies but the probable average spacing is estimated to be 30 feet for low-angle fractures; 27 feet for the east-southeast dipping, high-angle fractures; and 43 feet for the south-southeast dipping, high-angle fractures. The median estimated apparent transmissivity of individual water-yielding fractures or fracture zones was 0.3 feet squared per day and ranged from 0.01 to 382 feet squared per day. Ninety-five percent of the water-yielding fractures or fracture zones had an estimated apparent transmissivity of 19.5 feet squared per day or less. The orientation, spacing, and hydraulic properties of water-yielding fractures identified during this study can be used to help estimate recharge, flow, and discharge of ground water contaminants. High-angle fractures provide vertical pathways for ground water to enter the bedrock, interconnections between low-angle fractures, and, subsequently, pathways for water flow within the bedrock along fracture planes. Low-angle fractures may allow horizontal ground-water flow in all directions. The orientation of fracturing and the hydraulic properties of each fracture set strongly affect changes in ground-water flow under stress (pumping) conditions.

Maine↗

USGS1995

Hydrogeology and water quality at the management systems evaluation area near Piketon, Ohio

This report presents the results of a study by the U.S. Geological Survey, The Ohio State University, and the U.S. Department of Agriculture to describe the hydrology, water quality, and geochemical factors controlling water quality at the Ohio Management Systems Evaluation Area (MSEA). The Ohio MSEA is located on a 650-acre farm in the Scioto River Valley in Pike County, south-central Ohio. The farm is underlain by an incised bedrock valley filled with about 70 feet of sand and gravel outwash deposits that are covered by a veneer of silty clay alluvium and silty loam and sandy loam soils. Outwash sediment are composed predominantly of dolomite, quartz, and calcite, and have a median organic carbon concentration of 0.39 weight percent. Horizontal hydraulic conductivity of the sediment based on results of multiple-well aquifer tests ranges from 400 to 560 feet per day. Ground-water flow is from east to west-southwest at an average velocity of 1.5 to 2.5 feet per day. Ground water and surface water at the site are highly interconnected. Big Beaver Creek recharges the outwash aquifer along the eastern edge of the study area, and ground water discharges to the Scioto River at the western edge of the study area. High-stage events on the Scioto River cause frequent flow reversals in the aquifer that allow streamwater to travel a maximum observed distance of 190 feet inland. A zone of oxidizing waters (characterized by high dissolved oxygen concentration and Eh) is found in shallow ground water for several hundred feet adjacent to Big Beaver Creek and the Scioto River. This zone of oxidizing ground water is caused by the periodic inflow of surface waters to the aquifer. A ground-water budget for the study area indicates that the aquifer received 17.7 inches of recharge during water year 1992; of this amount, 72 percent originated as infiltrating precipitation, 28 percent as infiltration of surface water from Big Beaver Creek, and 0.2 percent as leakage from bedrock. Areal variation in water quality is caused by areal differences in the relative importance of these three recharge sources. The effects of bedrock leakage are evident only in the northeast corner of the study area. Here, deep outwash waters are transitional in composition between the calcium magnesium bicarbonate waters found elsewhere in the outwash aquifer and the calcium sodium chloride waters of the bedrock aquifer. Mixing calculations indicate that these deep outwash waters are composed of as much as 26 percent bedrock water. In the southern part of the MSEA, ground water is diluted by surface water from Big Beaver Creek as it recharges the aquifer through a sand and gravel streambed. At the northeast corner of the MSEA, however, Big Beaver Creek flows across a shale streambed through which no infiltration occurs. Redox reactions in the outwash aquifer control variations in aquifer chemistry with depth. From the water table to about 40 feet below land surface, oxidizing conditions are characterized by the presence of dissolved oxygen and nitrates in ground water, Eh greater than 200 millivolts, ferrihydrite coatings on sediment grains, and the absence of dissolved iron and manganese. From about 40 feet below land surface to the base of the aquifer, reducing conditions are characterized by dissolved oxygen concentrations less than 2 mg/L, Eh less than 200 millivolts, and the presence of dissolved iron and manganese. Denitrification in the reducing zone naturally remediates anthropogenic nitrate contamination of the aquifer while oxidizing pyrite in the aquifer sediment.

Ohio↗

USGS2002

Evaluation of water quality, suspended sediment, and stream morphology with an emphasis on effects of stormflow on Fountain and Monument Creek basins, Colorado Springs and vicinity, Colorado, 1981 through 2001

This report documents water quality and suspended sediment with an emphasis on evaluating the effects of stormflow on Fountain Creek Basin in the vicinity of Colorado Springs, Colorado. Water-quality data collected at 11 sites between 1981 and 2001 were used to evaluate the effects of stormflow on water quality. Suspended-sediment data collected at seven sites from 1998 through 2001 were used to evaluate effects of stormflow on suspended-sediment concentrations, discharges, and yields. Data were separated into three flow regimes: base flow, normal flow, and stormflow. A comparison of stormwater-quality concentrations measured between 1981 and 2001 to Colorado acute instream standards indicated that, except for isolated occurrences, stormwater quality met acute instream standards. At several sites, 5-day biochemical oxygen demand, fecal coliform, and selected nutrient concentrations tended to be highest during stormflow and lowest during base flow. Dissimilar to the other nutrients, dissolved nitrite plus nitrate concentrations generally were highest during base flow and lowest during stormflow. Most dissolved trace-element concentrations associated with stormflow decreased or showed little change compared to base flow. However, median concentrations of total copper, iron, lead, nickel, manganese, and zinc for stormflow samples generally were much larger than nonstorm samples. The substantially larger concentrations of total copper, iron, lead, nickel, manganese, and zinc measured at site 5800 during stormflow as compared to other sites indicates a relatively large source of these metals in the reach between sites 5530 and 5800. Semi-volatile organic compounds in samples collected during stormflow were detected relatively infrequently at the four sites monitored; however, analysis of pesticide data collected during stormflow showed a relatively frequent detection of pesticides at low levels. Nitrogen, phosphorus, and particulate trace-element loads substantially increased during stormflow. Suspended-sediment concentrations, discharges, and yields associated with stormflow were significantly greater than during normal flow. Depending on the site and year, suspended-sediment concentrations associated with storm-flow generally were 3 to10 times greater than concentrations measured during normal flow, and suspended-sediment discharges were usually more than 10 times greater during stormflow. The April through October cumulative suspended-sediment discharges and streamflows were largest in 1999 at all sites. Although large spatial variations in suspended-sediment yields occurred during normal flows, the suspended-sediment yields associated with stormflow generally were more than 10 times greater than the suspended-sediment yields that occurred during normal flow. The smallest suspended-sediment yields generally were less than 1 ton per day per square mile during stormflow. The largest suspended-sediment yields occurred at sites located in the Cottonwood Creek Basin and were greater than 10 tons per day per square mile.

Colorado↗

USGS2002

Evaluation of water quality, suspended sediment, and stream morphology with an emphasis on effects of stormwater on Fountain and Monument Creek basins, Colorado Springs and vicinity, Colorado, 1981-2001

Water-Resources Investigations Report↗

USGS2003

Occurrence and temporal variability of methyl tert -butyl ether (MTBE) and other volatile organic compounds in select sources of drinking water : results of the focused survey

The large-scale use of the gasoline oxygenate methyl tert -butyl ether (MTBE), and its high solubility, low soil adsorption, and low biodegradability, has resulted in its detection in ground water and surface water in many places throughout the United States. Studies by numerous researchers, as well as many State and local environmental agencies, have discovered high levels of MTBE in soils and ground water at leaking underground gasoline-storage-tank sites and frequent occurrence of low to intermediate levels of MTBE in reservoirs used for both public water supply and recreational boating. In response to these findings, the American Water Works Association Research Foundation sponsored an investigation of MTBE and other volatile organic compounds (VOCs) in the Nation's sources of drinking water. The goal of the investigation was to provide additional information on the frequency of occurrence, concentration, and temporal variability of MTBE and other VOCs in source water used by community water systems (CWSs). The investigation was completed in two stages: (1) reviews of available literature and (2) the collection of new data. Two surveys were associated with the collection of new data. The first, termed the Random Survey, employed a statistically stratified design for sampling source water from 954 randomly selected CWSs. The second, which is the focus of this report, is termed the Focused Survey, which included samples collected from 134 CWS source waters, including ground water, reservoirs, lakes, rivers, and streams, that were suspected or known to contain MTBE. The general intent of the Focused Survey was to compare results with the Random Survey and provide an improved understanding of the occurrence, concentration, temporal variability, and anthropogenic factors associated with frequently detected VOCs. Each sample collected was analyzed for 66 VOCs, including MTBE and three other ether gasoline oxygenates (hereafter termed gasoline oxygenates). As part of the Focused Survey, 451 source-water samples and 744 field quality-control (QC) samples were collected from 78 ground-water, 39 reservoir and (or) lake, and 17 river and (or) stream source waters at fixed intervals for a period of 1 year. Using a common assessment level of 0.2 μg/L (micrograms per liter) (2.0 μg/L for methyl ethyl ketone), 37 of the 66 VOCs analyzed were detected in both surveys. However, VOCs, especially MTBE and other gasoline oxygenates, were detected more frequently in the Focused Survey than in the Random Survey. MTBE was detected in 55.5 percent of the CWSs sampled in the Focused Survey and in 8.7 percent of those sampled in the Random Survey. Little difference in occurrence, however, was observed for trihalomethanes (THMs), which were detected in 16.4 and 14.8 percent of Focused Survey and Random Survey CWSs, respectively. This may indicate a pervasive occurrence of THMs in several source-water types, regardless of CWS size or geographic location. Using data at or above the method detection limit to assess temporal variability and anthropogenic factors associated with frequent detection of select VOCs, concentrations in the Focused Survey in ground-water, reservoir, and river source waters were typically less than 1 μg/L. Also, at a 95-percent confidence interval, no statistically significant differences were observed in comparing concentrations in the first and second ground-water sample. A weak seasonal pattern was observed in samples collected from reservoirs and lakes where gasoline oxygenates and other gasoline compounds were detected more frequently during spring and summer, presumedly a result of increased use of motorized watercraft during these seasons. In contrast, seasonal patterns were not observed in samples collected from rivers and streams. The lack of seasonal differences in river and stream source waters sampled may indicate a common and continuous source of contamination. The most frequently detected VOC (MTBE) and the two most frequently occurring subgroups of VOCs (gasoline oxygenates and THMs) detected in CWS source waters were further characterized to evaluate some anthropogenic factors that may better explain their frequent occurrence. Gasoline oxygenates were detected in 73.9 percent of all CWSs sampled. The concentration of gasoline oxygenates was slightly correlated with watercraft use on reservoirs inside MTBE high-use areas (r2=0.3783) but not outside of these areas (r2=0.0242). In general, the concentration of gasoline oxygenates increased as watercraft use increased. THMs were detected in 47.8 percent of the CWSs supplied by surface water. The frequent occurrence of THMs in reservoir source waters was determined to be an artifact of disinfection and the recycling of chlorinated water to these reservoirs. All CWSs with frequent occurrence of THMs served by a reservoir indicated that chlorine was added to waters for various reasons and that the chlorinated water was then released back to, or upstream of, the reservoir or lake that was sampled.

Water-Resources Investigations Report↗

USGS1991

Hydrology and the hypothetical effects of reducing nutrient applications on water quality in the Bald Eagle Creek Headwaters, southeastern Pennsylvania prior to implementation of agricultural best-management practices

The report characterizes a 0.43-square-mile agricultural watershed in York County, underlain by albite-chlorite and oligoclase-mica schist in the Lower Susquehanna River basin, that is being studied as part of the U.S. Environmental Protection Agency's Chesapeake Bay Program. The water quality of Bald Eagle Creek was studied from October 1985 through September 1987 prior to the implementation of Best-Management Practices to reduce nutrient and sediment discharge into Muddy Creek, a tributary to the Chesapeake Bay. About 88 percent of the watershed is cropland and pasture, and nearly 33 percent of the cropland is used for corn. The animal population is entirely dairy cattle. About 85,640 pounds of nitrogen (460 pounds per acre) and 21,800 pounds of phosphorus (117 pounds per acre) were applied to fields; 52 percent of the nitrogen and 69 percent of the phosphorus was from commercial fertilizer. Prior to fertilization, nitrate nitrogen in the soil ranged from 36 to 136 pounds per acre and phosphorus ranged from 0.89 to 5.7 pounds per acre in the top 4 feet of soil. Precipitation was about 18 percent below normal and streamflow about 35 percent below normal during the 2-year study. Eighty-four percent of the 20.44 inches of runoff was base flow. Median concentrations of total nitrogen and dissolved phosphorous in base flow were 0.05 and 0.04 milligrams per liter as phosphorus, respectively. Concentrations of dissolved nitrate in base flow increased following wet periods after crops were harvested and manure was applied. During the growing season, concentrations decreased similarly to those observed in carbonate-rock areas as nutrient uptake and evapotranspiration by corn increased. About 4,550 pounds of suspended sediment, 5,250 pounds of nitrogen, and 66.6 pounds of phosphorus discharged in base flow during the 2-year period. The suspended sediment load was about 232,000 pounds in stormflow from 26 storms that contributed 51 percent of the total stormflow. The nitrogen load was about 651 pounds and the phosphorus load was about 74 pounds in stormflow from 16 storms that contributed 28 percent of the total stormflow. It is estimated that concentrations of total nitrogen and phosphorus in base flow need to be reduced by 12 and 48 percent, respectively, to detect changes during the nutrient-management phase. Likewise, loads to total nitrogen and phosphorus in base flow need to be reduced by 62 and 57 percent.

Pennsylvania↗

USGS1985

Cost effectiveness of stream-gaging program in Michigan

This report documents the results of a study of the cost effectiveness of the stream-gaging program in Michigan. Data uses and funding sources were identified for the 129 continuous gaging stations being operated in Michigan as of 1984. One gaging station was identified as having insufficient reason to continue its operation. Several stations were identified for reactivation, should funds become available, because of insufficiencies in the data network. Alternative methods of developing streamflow information based on routing and regression analyses were investigated for 10 stations. However, no station records were reproduced with sufficient accuracy to replace conventional gaging practices. A cost-effectiveness analysis of the data-collection procedure for the ice-free season was conducted using a Kalman-filter analysis. To define missing-record characteristics, cross-correlation coefficients and coefficients of variation were computed at stations on the basis of daily mean discharge. Discharge-measurement data were used to describe the gage/discharge rating stability at each station. The results of the cost-effectiveness analysis for a 9-month ice-free season show that the current policy of visiting most stations on a fixed servicing schedule once every 6 weeks results in an average standard error of 12.1 percent for the current $718,100 budget. By adopting a flexible servicing schedule, the average standard error could be reduced to 11.1 percent. Alternatively, the budget could be reduced to $700,200 while maintaining the current level of accuracy. A minimum budget of $680,200 is needed to operate the 129-gaging-station program; a budget less than this would not permit proper service and maintenance of stations. At the minimum budget, the average standard error would be 14.4 percent. A budget of $789,900 (the maximum analyzed) would result in a decrease in the average standard error to 9.07 percent. Owing to continual changes in the composition of the network and the changes in the uncertainties of streamflow accuracy at individual stations, the cost-effectiveness analysis will need to be updated regularly if it is to be used as a management tool. Cost of these updates need to be considered in decisions concerning the feasibility of flexible servicing schedules.

Michigan↗

USGS1989

Cost-effectiveness of the streamflow-gaging program in Minnesota

A three-step analysis of the cost-effectiveness of the streamflow-gaging program in Minnesota is documented in this report. In the first step of the analysis, the data uses and funding sources were identified for the 96 continuous-record streamflow-gaging stations operated in 1985. Nineteen sources of funding and 42 uses were identified for the data collected in this program. Two stations were identified as producing data no longer sufficiently needed to warrant continuing their operation. Three other stations were identified as having uses specific to short-term studies. One station was destroyed in 1985. It is recommended that the remaining 90 station be maintained in the program for the foreseeable future. In the second step, multiple-linear-regression analysis was investigated as a possible method for providing the data collected at 23 stations. The multiple-linear-regression method was not sufficiently accurate to provide the needed data, and it is recommended that the 23 stations remain in the program. It also is recommended that flow-routing methods be investigated to see if they could provide the needed data for stations on the Red Lake River, the upper Minnesota River, and on the Mississippi River in the Minneapolis-St Paul metropolitan area. In the third step, the cost-effectiveness of collecting data from 77 of the remaining 90 stations was determined for the open-water period, April 1 through October 30. Data for 13 stations are provided to the U.S. Geological Survey or are collected at fixed intervals and were, therefore, not used in the analysis. The average standard error per station for estimation of the streamflow records is about 24 percent for the statewide network, about 11 percent for the stations operated by the St. Paul field office, about 22 percent for the stations operated by the Grand Rapids field office, and about 37 percent for the stations operated by the Montevideo field office. The current policy for collecting data from the 77 stations during the open-water period cost $198,000 in 1985. The estimated average standard error per station for the statewide network could be reduced from 24.4 percent to 20.6 percent at the $198,000 budget, if the minimum number of discharge measurements at each station were reduced from five to three during the open-water period and the remaining budget were used to make additional discharge measurements at stations with large standard errors. It is recommended that, before this data-collection plan is implemented, the effects of the plan on the cost of collecting data be evaluated for (1) possible increased lost record because of the data collection plan, and (2) the possible need for additional trips to visit noncontinuous-record stations. It also is recommended that the data-accuracy needs of the funding agencies be considered before the plan is implemented.

Minnesota↗

USGS1997

Preliminary conceptual models of the occurrence, fate, and transport of chlorinated solvents in karst regions of Tennessee

Published and unpublished reports and data from 22 contaminated sites in Tennessee were reviewed to develop preliminary conceptual models of the behavior of chlorinated solvents in karst aquifers. Chlorinated solvents are widely used in many industrial operations. High density and volatility, low viscosity, and solubilities that are low in absolute terms but high relative to drinkingwater standards make chlorinated solvents mobile and persistent contaminants that are difficult to find or remove when released into the groundwater system. The major obstacle to the downward migration of chlorinated solvents in the subsurface is the capillary pressure of small openings. In karst aquifers, chemical dissolution has enlarged joints, bedding planes, and other openings that transmit water. Because the resulting karst conduits are commonly too large to develop significant capillary pressures, chlorinated solvents can migrate to considerable depth in karst aquifers as dense nonaqueous-phase liquids (DNAPL's). Once chlorinated DNAPL accumulates in a karst aquifer, it becomes a source for dissolved-phase contamination of ground water. A relatively small amount of chlorinated DNAPL has the potential to contaminate ground water over a significant area for decades or longer. Conceptual models are needed to assist regulators and site managers in characterizing chlorinated-solvent contamination in karst settings and in evaluating clean-up alternatives. Five preliminary conceptual models were developed, emphasizing accumulation sites for chlorinated DNAPL in karst aquifers. The models were developed for the karst regions of Tennessee, but are intended to be transferable to similar karst settings elsewhere. The five models of DNAPL accumulation in karst settings are (1) trapping in regolith, (2) pooling at the top of bedrock, (3) pooling in bedrock diffuse-flow zones, (4) pooling in karst conduits, and (5) pooling in isolation from active ground-water flow. More than one conceptual model of DNAPL accumulation may be applicable to a given site, depending on details of the contaminant release and geologic setting. Trapping in regolith is most likely to occur where the regolith is thick and relatively impermeable with few large cracks, fissures, or macropores. Accumulation at the top of rock is favored by flat-lying strata with few fractures or karst features near the bedrock surface. Fractures or karst features near the bedrock surface encourage migration of chlorinated DNAPL into karst conduits or diffuse-flow zones in bedrock. DNAPL can migrate through one bedrock flow regime into an underlying flow regime with different characteristics or into openings that are isolated from significant ground-water flow. As a general rule, the difficulty of finding and removing DNAPL increases with depth, lateral distance from the source, and complexity of the ground-water flow system. The prospects for mitigation are generally best for DNAPL accumulation in the regolith or at the bedrock surface. However, many such accumulations are likely to be difficult to find or remove. Accumulations in bedrock diffuse-flow zones or in fractures isolated from flow may be possible to find and partially mitigate, but will likely leave significant amounts of contaminant in small fractures or as solute diffused into primary pores.

Tennessee↗

USGS1996

Water-quality assessment of the Rio Grande Valley, Colorado, New Mexico, and Texas: Shallow ground-water quality of a land-use area in the San Luis Valley, south-central Colorado, 1993

This report describes the quality of shallow ground water in an agricultural area in the San Luis Valley, Colorado, and discusses how natural and human factors affect the quality of shallow ground water. Thirty-five wells were installed, and water samples were collected from these wells and analyzed for selected dissolved common constituents, nutrients, trace elements, radionuclides, and synthetic organic compounds. The San Luis Valley is a high intermontane valley that is partially drained by the Rio Grande. The San Luis Valley land-use study area was limited to a part of the valley where the depth to water is generally less than 25 feet. The area where the 35 monitor wells were installed was further limited to the part of the study area where center-pivot overhead sprinklers are used to irrigate crops. Precipitation, runoff from adjacent mountainous areas, and ground-water inflow from the adjacent mountainous areas are the main sources of water to the aquifers in the San Luis Valley. Discharge of water from the shallow, unconfined aquifer in the valley is mainly from evapotranspiration. The dominant land use in the San Luis Valley is agriculture, although nonirrigated land and residential land are interspersed with agricultural land. Alfalfa, native hay, barley, wheat, potatoes, and other vegetables are the main crops. Dissolved-solids concentrations in shallow ground water sampled ranged from 75 to 1,960 milligrams per liter. The largest median concentration of cations was for calcium, and the largest median concentration of anions was for bicarbonate in shallow ground water in the San Luis Valley. Calcium concentrations ranged from 7.5 to 300 milligrams per liter, and bicarbonate concentrations ranged from 28 to 451 milligrams per liter. Nitrite plus nitrate concentrations ranged from less than 0.1 to 58 milligrams per liter as N; water from 11 wells had nitrite plus nitrate concentrations greater than 10 milligrams per liter as N. With the exception of the following trace elements--aluminum, barium, iron, manganese, molybdenum, and uranium--the concentrations of trace elements were less than 10 micrograms per liter in 90 percent of the samples. All trace-element concentrations measured were below the maximum contaminant levels set by the U.S. Environmental Protection Agency. Five samples exceeded the proposed maximum contaminant level of 0.02 milligram per liter for uranium. All samples collected exceeded the proposed maximum contaminant level for radon-222. The volatile organic compound methyltertbutylether was detected in one sample at a concentration of 0.6 microgram per liter. Of the pesticides analyzed for, one or more were detected in water from 5 of the 35 wells sampled. Metribuzin was the most commonly detected pesticide and was detected in water from three wells at concentrations ranging from an estimated 0.005 to 0.017 microgram per liter. Metolachlor (detected in one sample at a concentration of 0.072 microgram per liter), prometon (detected in one sample at a concentration of 0.01 microgram per liter), and p,p'-DDE (detected in one sample at an estimated concentration of 0.002 microgram per liter) were the other pesticides detected. The U.S. Environmental Protection Agency lifetime health advisory for metolachlor, metribuzin, and prometon is 100 micrograms per liter, which is much larger than the concentrations measured in the shallow ground water sampled for this study. The elevated nitrite plus nitrate concentrations in shallow ground water are indicative of leaching of fertilizers from the land surface. This conclusion is consistent with conclusions made in other investigations of the San Luis Valley.

Colorado↗

USGS1997

Water-quality assessment of the Rio Grande Valley, Colorado, New Mexico, and Texas -- Shallow ground-water quality and land use in the Albuquerque area, central New Mexico, 1993

This report describes the quality of shallow ground water and the relations between land use and the quality of that shallow ground water in an urban area in and adjacent to Albuquerque, New Mexico. Water samples were collected from 24 shallow wells. Samples were analyzed for selected common constituents, nutrients, trace elements, radionuclides, volatile organic compounds, and pesticides. The study area, which is in the Albuquerque Basin in central New Mexico, was limited to the Rio Grande flood plain; depth to water in this area generally is less than 25 feet. The amount and composition of recharge to the shallow ground-water system are important factors that affect shallow ground-water composition in this area. Important sources of recharge that affect shallow ground-water quality in the area include infiltration of surface water, which is used in agricultural land-use areas to irrigate crops, and infiltration of septic-system effluent in residential areas. Agricultural land use represents about 28 percent of the area, and residential land use represents about 35 percent of the total study area. In most of the study area, agricultural land use is interspersed with residential land use and neither is the dominant land use in the area. Land use in the study area historically has been changing from agricultural to urban. The composition of shallow ground water in the study area varies considerably. The dissolved solids concentration in shallow ground water in the study area ranges from 272 to 1,650 milligrams per liter, although the relative percentages of selected cations and anions do not vary substantially. Calcium generally is the dominant cation and bicarbonate generally is the dominant anion. Concentrations of nutrients generally were less than 1 milligram per liter. The concentration of many trace elements in shallow ground water was below or slightly above 1 microgram per liter and there was little variation in the concentrations. Barium, iron, manganese, molybdenum, and uranium were the only trace elements analyzed for that had median concentrations greater than 5 micrograms per liter. Volatile organic compounds were detected in 5 of 24 samples. Cis-1,2-dichloroethene and 1,1-dichloroethane were the most commonly detected volatile organic compounds (detected in two samples each). Pesticides were detected in 8 of 24 samples. Prometon was the most commonly detected pesticide (detected in 5 of 24 samples). Concentrations of volatile organic compounds and pesticides detected were much smaller than any U.S. Environmental Protection Agency standards that have been established. Infiltration of surface water and the evaporation or transpiration of this water, which partially is the result of past and present agricultural land use, seem to affect the concentrations of common constituents in shallow ground water in the study area. The small excess chloride in shallow ground water relative to surface water that has been affected by evaporation or transpiration could be due to mixing of shallow ground water with small amounts of precipitation/bulk deposition or septic-system effluent. Infiltration of septic-system effluent (residential land use) has affected the shallow ground-water composition in parts of the study area on the basis of the small dissolved oxygen concentrations, large dissolved organic carbon concentrations, and excess chloride. Despite the loading of nitrogen to the shallow ground-water system as the result of infiltration of septic-system effluent, the small nitrogen concentrations in shallow ground water probably are due to the small dissolved oxygen concentrations and relatively large dissolved organic carbon concentrations. The small concentrations and lack of variation of most trace elements indicate that land use has not substantially affected the concentration

New Mexico↗

USGS1998

Water-quality assessment of part of the upper Mississippi River basin, Minnesota and Wisconsin— Ground-water quality in an urban part of the Twin Cities Metropolitan area, Minnesota, 1996

In the spring of 1996, the Upper Mississippi River Basin Study Unit of the National Water-Quality Assessment Program drilled 30 shallow monitoring wells in a study area characterized by urban residential and commercial land uses. The monitoring wells were installed in sandy river-terrace deposits adjacent to the Mississippi River in Anoka and Hennepin Counties, Minnesota, in areas where urban development primarily occurred during the past 30 years. Analyses of sediments collected during well drilling indicated that at most well sites the aquifer materials had relatively high hydraulic conductivities (ranging from 0.01 to 238 feet per day), and relatively low organic carbon contents (0.10 to 41 grams per kilogram), indicating a high susceptibility to leaching of fertilizers and organic substances used on the land surface. Sediment pH values, which can affect leaching of pesticides, were generally alkaline, ranging from 5.1 to 9.6. Ground-water levels ranged from 2.39 to 23.14 feet below land surface, and indicated that shallow ground water flows primarily toward the Mississippi River. Dissolved-oxygen concentrations in water samples from the wells were generally less than 3 milligrams per liter (mg/L) and specific conductances were generally greater than 600 microsiemens per centimeter. Calcium, magnesium, sodium, bicarbonate, chloride, and sulfate were the primary dissolved constituents in the water samples. Sodium and chloride concentrations were generally greater than commonly reported in the region, probably due to leaching of sodium chloride applied to roads during the winter. Most tracemetal concentrations in ground-water samples were less than 10 micrograms per liter (μg/L), but concentrations of iron and manganese commonly exceeded Secondary Maximum Contaminant Levels set by the U.S. Environmental Protection Agency of 300 and 50 μg/L, respectively. Mineral saturation indices indicated that calcite, dolomite, and gypsum were slightly undersaturated in most water samples, and that quartz, and many oxides and hydroxides of iron and manganese were oversaturated in all of the water samples. Concentrations of nitrate nitrogen, the primary nutrient of concern in ground water, ranged from less than 0.05 to 16 mg/L, with a median concentration of 1.4 mg/L. Dissolved phosphorus concentrations ranged from less than 0.01 to 1.5 mg/L in the water samples, with a median concentration of 0.02 mg/L. Water from one well was oversaturated with respect to hydroxyapatite, a phosphatic mineral used as a fertilizer. Pesticide compounds were detected in water samples from 16 wells, but concentrations of those compounds were less than 1.0 μg/L. Prometon, an herbicide commonly used for right-of-way weed control, was detected in water samples from 10 of the wells. Atrazine, and its metabolite deethylatrazine, were detectable in water samples from 6 and 8 wells, respectively. Atrazine is commonly applied to land planted with corn and is detectable in rainfall and air samples in concentrations of less than 1 ng/L in the urban land use study area. Other detected pesticide compounds, which are used in agriculture, right-of-way weed control, or lawn care included: tebuthiuron, EPTC, p , p '-DDE, metolachlor, simazine, bentazon, and bromacil. Volatile organic compounds were detected in water samples from 26 wells, but the concentrations of most of those compounds were less than 1 μg/L. Carbon disulfide, which may be produced by bacteria in soils, was the most commonly detected volatile organic compound in water samples from the wells. Other detected volatile organic compounds included: methyl chloride, acetone, dichlorofluoromethane, tetrahydrofuran, trichlorofluoromethane, methyl iodide, 1,1-dichloroethane, chloroform, toluene, trichloroethane, trichloroethene, cis -1,2-dichloroethene, methylene chloride, bromodichloromethane, benzene, methylisobutylketone, ethyl ether, and tetrachloroethene. Tritium concentrations, analyzed in water samples from 15 of the 30 wells, indicated that shallow ground water has been recharged since the mid-1950's, and that shallow ground water should be affected by urban development that has taken place over the past 40 years. Land uses in the urban land use study area affected the concentrations of some water-quality constituents. Concentrations of nitrate and chloride, and frequencies of detection of pesticides and of volatile organic compounds, were greater in water samples from the surficial sand and gravel aquifer underlying the urban land use study area than in water samples from similar aquifers from part of the Upper Mississippi River Basin National Water-Quality Assessment study unit. Land uses within 500-meter radii of each well were quantified by digitizing overlays of aerial photographs that were verified and updated in the field. Concentrations of magnesium and sulfate were greater in ground water beneath areas of denser residential development, which may be a natural artifact of better drainage and a deeper water table in those areas. Frequencies of detection of some pesticides and volatile organic compounds were greater in water from wells with greater proportions of industrial and transportation land uses. Ground water in areas with less dense residential development, mostly the more recently-developed areas, tended to have greater concentrations of agricultural herbicides and some nutrients probably a relict of previous agricultural land use.

Minnesota↗

USGS1996

Hydrogeology and simulation of ground-water flow at the South Well Field, Columbus, Ohio

The City of Columbus, Ohio, operates four radial collector wells in southern Franklin County. The 'South Well Field' is completed in permeable outwash and ice-contact deposits, upon which flow the Scioto River and Big Walnut Creek. The wells are designed to yield approximately 42 million gallons per day; part of that yield results from induced infiltration of surface water from the Scioto River and Big Walnut Creek. The well field supplied up to 30 percent of the water supply of southern Columbus and its suburbs in 1991. This report describes the hydrogeology of southern Franklin County and a tran sient three-dimensional, numerical ground-water- flow model of the South Well Field. The primary source of ground water in the study area is the glacial drift aquifer. The glacial drift is composed of sand, gravel, and clay depos ited during the Illinoian and Wisconsinan glaciations. In general, thick deposits of till containing lenses of sand and gravel dominate the drift in the area west of the Scioto River. The thickest and most productive parts of the glacial drift aquifer are in the buried valleys in the central and eastern parts of the study area underlying the Scioto River and Big Walnut Creek. Horizontal hydraulic conductivity of the glacial drift aquifer differs spa tially and ranges from 30 to 375 feet per day. The specific yield ranges from 0.12 to 0.30. The secondary source of ground water within the study area is the underlying carbonate bedrock aquifer, which consists of Silurian and Devonian limestones, dolomites, and shales. The horizontal hydraulic conductivity of the carbonate bedrock aquifer ranges from 10 to 15 feet per day. The storage coefficient is about 0.0002. The ground-water-flow system in the South Well Field area is recharged by precipitation, regional ground-water flow, and induced stream infiltration. Yearly recharge rates varied spatially and ranged from 4.0 to 12.0 inches. The three-dimensional, ground-water-flow model was constructed by use of the U.S. Geological Survey three-dimensional finite-difference ground-water-flow code. Recharge, boundary flux, and river leakage are the principal sources of water to the flow system. The study area is bounded on the north and south by streamlines, with flow entering the area from the east and west. Areal recharge is contributed throughout the study area, although a comparatively high percentage of precipitation reaches the water table in the area east of the Scioto River where little surface drain age exists. Ground-water flow is downward in the uplands of the Scioto River, and upward near the river in the glacial drift and carbonate bedrock aquifers. The numerical model contains 53 rows, 45 columns, and 3 layers. The uppermost two layers represent the glacial drift. The bottom layer represents the carbonate bedrock. The horizontal model grid is variably spaced to account for differences in available data and to simulate heads accurately in specific areas of interest. The length and width of grid cells range from 200 to 2,000 feet; the finer spacings are designed to increase detail in the areas near the collector wells. The model uses 7,155 active nodes. Measurements of water levels from October 1979 were used to represent steady-state conditions before municipal pumping at the well field began. Measurements made during March 1986 were used to represent steady-state conditions after commencement of pumping at the well field. Water levels measured during March 1986 - June 1991 were used for calibration targets in the transient simulations. The transient model was discretized into eight stress periods of 93 to 487 days on the basis of recharge, well-field pumpage, and available water-level data. Transient model calibration was based on seven sets of hydraulic-head measure ments made during March 1986 - June 1991. This time period includes large-scale increases in well- field production associated with a drought in the summer of 1988, an

Water-Resources Investigations Report↗

USGS2002

Base (100-year) flood elevations for selected sites in Livingston County, Missouri

The primary criteria for community participation in the National Flood Insurance Program is the adoption and enforcement of floodplain management requirements that minimize the potential for flood damages to existing and proposed development in flood-hazard areas. This report provides base flood elevations (BFE) for a 100-year recurrence-interval flood for use in the management and regulation of 18 flood-hazard areas designated by the Federal Emergency Management Agency as approximate Zone A areas in Livingston County, Missouri. The one-dimensional surface-water flow models HEC-RAS and Water-Surface PROfile (WSPRO) were used to compute base (100-year) flood elevations for 18 Zone A sites. The HEC-RAS model was used at BFE sites 1 to 6, 9, 10, and 15 to 18. The WSPRO model was used at BFE sites 7, 8, and 11 to 14. The 18 sites are all located in Livingston County, Missouri, at U.S., State, or County road crossings, and the base flood elevation was determined at the upstream side of each crossing. The base (100-year) flood elevations for BFE 1, 2, and 3 on Shoal Creek at Dawn and Shoal Creek Drainage Ditch near Dawn are 701.0, 701.0, and 696.5 feet, respectively. The base (100-year) flood elevations for BFE 4 and 5 on Indian Branch near Sampsel and a tributary to Indian Branch near Sampsel are 711.7 and 755.4 feet, respectively. Site BFE 6 is located on Honey Creek near Farmersville and the base (100-year) flood elevation for this site is 730.8 feet. One site (BFE 7) is located on No Creek near Farmersville. The base (100-year) flood elevation for this site is 731.3 feet. Site BFE 8 is located on Crooked Creek near Chillicothe and the base (100-year) elevation is 716.4 feet. One site (BFE 9) is located on a tributary to Coon Creek at Chillicothe. The base (100-year) flood elevation for this site is 734.9 feet. Two sites (BFE 10 and 11) are located on Blackwell Branch at Chillicothe. The base (100-year) flood elevation for BFE 10 is 738.9 feet and for BFE 11 is 701.7 feet. The base (100-year) flood elevation for BFE 12 on Medicine Creek near Chula is 721.7 feet. Sites BFE 13 and 15 are on Muddy Creek and for BFE 14 is on Little Muddy Creek near Chula. The base (100-year) flood elevations for BFE 13 and 15 are 733.0 and 717.9 feet, respectively and for BFE 14 is 734.6 feet. Downstream from BFE 12 is site BFE 16 on Medicine Creek near Wheeling. The base (100-year) flood elevation for site BFE 16 is 686.1 feet. One site (BFE 17) is located on Campbell Creek near Bedford. The base (100-year) flood elevation at this site is 691.8 feet. Site BFE 18 is located on Towstring Creek near Hale. The base (100-year) flood elevation for site BFE 18 is 667.4 feet.

Missouri↗

USGS1997

Changes in flow in the Beaver-North Canadian River basin upstream from Canton Lake, western Oklahoma

This report presents the results of an evaluation of hydrologic data for the Beaver-North Canadian River basin upstream from Canton Lake in western Oklahoma. It examines the climatic and hydrologic data for evidence of trends. The hydrologic data examined includes total annual flow, base flow, and annual peak discharges. This study was conducted to determine if there is evidence of trends present in hydrologic and climatic data. All available streamflow-gaging station data, with at least 10 or more years of record, were examined for trends. In addition, the data were divided into an 'early' period (ending in 1971), representing conditions before ground-water levels had declined appreciably, and a 'recent' period (1978-1994), reflecting the condition of declining ground-water levels, including the effects of storage reservoirs. Tests for trend, moving averages, and comparisons of median and average flows for an early period (ending in 1971) with those for the recent period (1978-1994) show that the total annual volume of flow and the magnitudes of instantaneous annual peak discharges measured at most gaging stations in the Beaver- North Canadian River basin have decreased in recent years. Precipitation records for the panhandle, however, show no corresponding changes. The changes in flow are most pronounced in the headwaters upstream from Woodward, but also are evident at Woodward and near Seiling, which represents the inflow to Canton Lake. The average annual discharge decreased between the early period and the recent period by the following amounts: near Guymon, 18,000 acre-feet; at Beaver, 68,000 acre-feet; at Woodward, 72,000 acre-feet; and near Seiling, 63,000 acre-feet. These decreases, expressed as a percentage of the average flows for the early period, were 91 percent near Guymon, 82 percent at Beaver, 49 percent at Woodward, and 37 percent near Seiling. The medians of the annual peak discharges decreased from the early period to the recent period by the following amounts: near Guymon, 98 percent; at Beaver, 86 percent; at Woodward, 80 percent; and near Seiling, 53 percent. The Guymon gage is not affected by reservoirs; the other three mainstem gaging stations are influenced by reservoirs, but the decreases in annual peak discharges are greater than can be explained by storage in those reservoirs. Base flows have undergone substantial change, but unlike the annual volumes the base flows show some increases and some decreases. Flow duration analyses show a shift in the distribution of annual flows. Less contribution is coming from large floods that formerly added substantially to the yearly average flows. Near Seiling, for example, the magnitudes of the large flows that occur less than about 20 percent of the time were greatly reduced in the recent period. A primary mechanism producing these decreased streamflows appears to be the depletion of ground water in the High Plains aquifer that underlies more than 90 percent of the basin. Changes in farming and conservation practices and in water use also may be having an effect.

Oklahoma↗

USGS2004

Changes in ground-water quality near two granular-iron permeable reactive barriers in a sand and gravel aquifer, Cape Cod, Massachusetts, 1997-2000

Two experimental permeable reactive barriers (PRBs) of granular zero-valent iron were emplaced in the path of a tetrachloroethene plume (the Chemical Spill-10 plume) at the Massachusetts Military Reservation, Cape Cod, Massachusetts, in June 1998. The goal of the field experiment was to achieve emplacement of a granular-iron PRB deeper than attempted before. The PRBs were expected to create a reducing environment and degrade the tetrachloroethene by reductive dechlorination. The goal of the work presented in this report was to observe temporary and sustained changes to the ground-water chemistry downgradient from the PRBs. A hydraulic-fracturing method involving injection of the granular iron with a guar-biopolymer and enzyme slurry was used to install the parallel 30- to 33-foot-wide wall-shaped barriers at a depth of 82 to 113 feet below land surface. An acetic acid and enzyme mixture was subsequently injected in wells near the barriers to degrade the guar biopolymer. Prior to the emplacement, tetrachloroethene concentrations in the Chemical Spill-10 plume at the study area were as high as 250 micrograms per liter. Other water properties in the plume generally were similar to the properties of uncontaminated ground water in the area, which typically has dissolved oxygen concentrations of 250 to 375 micromoles per liter, pH of 5.5 to 6.0, and specific conductance of 60 to 90 microsiemens per centimeter. Water-quality samples were collected periodically from monitoring wells near the PRBs to determine how the emplacement of the granular-iron walls altered the ground-water quality. In addition, an automated well-sampling device measured temperature, specific conductance, pH, and dissolved oxygen every 1–4 days for 16 months in a well downgradient from the two parallel PRBs. Temporary increases (lasting about 5 to 6 months) in specific conductance were observed downgradient from the PRBs as a result of the sodium chloride, potassium carbonate, and other salts included in the slurry and the acetic acid and enzyme mixture that was subsequently injected to degrade the guar biopolymer. Temporary increases in the concentrations of major cations (sodium, potassium, magnesium, and calcium) were observed downgradient from the PRBs, as were temporary but substantial increases in the dissolved and total organic carbon concentrations. Methane was detected, sulfate concentrations decreased temporarily, and concentrations of dissolved inorganic carbon increased in samples from wells downgradient from the PRBs. A sustained (longer than 12 months) reducing environment, in which dissolved oxygen concentrations decreased to zero, the pH increased to about 6.8, and dissolved iron concentrations increased substantially, developed as a result of the oxidation (corrosion) of the granular iron; this zone persisted at least 65 feet downgradient from the PRBs. The pH and dissolved iron concentrations increased with distance from the granular-iron walls. Concentrations of arsenic, cobalt, manganese, and phosphorus increased, and nitrate concentrations were reduced to below the detection limit downgradient from the walls. A sustained decrease of tetrachloroethene concentrations was not observed; however, reductive dechlorination products were observed at wells downgradient from the PRBs during several rounds of sampling. The emplacement of zero-valent iron in the aquifer to remove tetrachloroethene from the ground water caused changes in the water chemistry that persisted farther downgradient from the PRBs than has been observed at other sites because of the low chemical reactivity of the quartz-dominated aquifer sediments and the low ambient dissolved chemical concentrations in the ground water. The small transverse dispersion in the aquifer and the probable long-term persistence of the iron indicate that the chemically altered zone probably will extend a substantial distance downgradient from the PRBs for a substantial period of time (years); further investigation would be needed to determine this distance.

Massachusetts↗