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Tracing mercury from land to river: Global sources, retention, and implications for sustainability

Mercury (Hg) pollution in river systems is a global sustainability challenge. Yet the transport, transformation, and retention of Hg within global rivers remain poorly quantified, particularly in regions with sparse observations such as Southeast Asia and Africa, hindering effective pollution mitigation and reinforcing geographic inequities in scientific knowledge and environmental governance. Here, we present the first global, high-resolution simulation of riverine Hg dynamics using a process-based model that traces Hg from land-based sources through river networks to the ocean. Under a realistic scenario, we estimate that ∼1900 megagrams per year (Mg/yr) of Hg enters global rivers, including 1500 Mg/yr from human-induced sources and 400 Mg/yr from soil erosion. Nearly half of this flux (∼1000 Mg/yr) is retained in reservoirs and dams, which act as major sinks. While such retention limits downstream delivery to the oceans, it also heightens in-reservoir Hg methylation risks. By bridging the gap between Hg releases and observed riverine exports, our framework offers a scalable tool for data-limited regions, promotes data access, and supports global freshwater and pollution-management strategies.

Environmental Science & Technology

Wildfire, extreme precipitation and debris flows, oh my! Channel response to compounding disturbances in a mountain stream in the Upper Colorado Basin, USA

Compounding changes in climate and human activities stand to increase sediment input to rivers in many landscapes, including via discrete perturbations such as post-fire debris flows. Because sediment supply is a dominant control on river morphology, understanding mountain river responses to sediment regime perturbations is critical to predicting and addressing downstream effects to infrastructure, water security and aquatic habitat. A growing body of literature explores the causes, likelihood, size and composition of post-fire debris flows, but the channel response to these disturbances remains poorly studied. This study used repeat field surveys, time-lapse photographs and pre- and post-disturbance remote sensing datasets to document and analyse space- and time-varying channel response to post-fire debris flows along a steep mountain stream in the Upper Colorado River Basin, USA. Specifically, we evaluated channel morphology and bed composition changes, correlations between channel changes and valley and channel attributes, and the relative importance of spring snowmelt versus summer monsoon events. Several cross-sectional channel change types were observed from lidar a month after post-fire debris-flow events, including channelized and braided incision into deposits, incision into the pre-fire channel bed, bank erosion and no change. Channel changes were most correlated with pre-fire channel width, valley width and unit stream power, and these relationships could be tested in other burned locations to evaluate their transferability. Repeat channel surveys before and after snowmelt indicate rapid recovery and channel narrowing following major sediment disturbances, although sediment deposits remained in the channel margins. Together, these results highlight the importance of field and remote sensing-based channel surveys to improve understanding of, and potential to predict, mountain channel response to compounding climate disturbances.

Earth Surface Processes and Landforms

Combining scanning electron microscopy, X-ray diffraction, and X-ray fluorescence to characterize shear zones at the Pogo gold deposit, Alaska

This study employs a multi-method analytical approach to characterize the mineralogical, geochemical, and textural properties of fault rocks from the Pogo gold mine in the Yukon-Tanana Upland, central Alaska. Specifically, we examine cataclasites, to document the structural and geochemical evolution of shear zones and their associations with gold mineralization. To investigate the shear zone, we integrate portable X-ray fluorescence (pXRF), scanning electron microscopy-based automated mineralogy (SEM-AM), X-ray diffraction (XRD), and high-resolution micro-X-ray fluorescence (micro-XRF) mapping. These methods collectively provide insights into bulk and trace element chemistry, mineralogical composition, and deformation-related textures across multiple scales. Handheld pXRF enables rapid geochemical screening, guiding SEM-AM and XRD analyses to ensure consistent mineralogical interpretation. X-ray diffraction identifies and quantifies crystalline phases, while SEM-AM produces high-resolution mineral maps, revealing mineral abundances, grain-scale textures, and gold associations. Micro-XRF mapping further refines our understanding by showing visual trace element distributions at sub-millimetre resolution. By integrating these techniques, we improve our understanding of the nature and geochemistry of Pogo shear zones, their role in gold mineralization, and support metallurgical processing strategies. This approach enhances exploration models and resource characterization for structurally complex gold deposits.

Alaska

Preparing for today's and tomorrow's water-resources challenges in eastern Long Island, New York

Freshwater is a vital natural resource. Although New York is a water-rich State, the wise and economical use of water resources is needed to ensure that there is enough water of adequate quality for both human and ecological needs—both for today and for tomorrow. Nowhere in New York is this more evident than in Nassau and Suffolk Counties on Long Island, where the public water supply is obtained from the sole-source aquifers located directly beneath the nearly 3 million people who live there. In 2023, in eastern Long Island’s Suffolk County, groundwater was pumped from these aquifers by more than 1,100 public water-supply wells to meet the needs of about 1.5 million people.

New York

Incorporating location uncertainty improves inference with stop-level North American Breeding Bird Survey data

Ecological models should account for uncertainty to be most effective and useful. Yet, uncertainty from model covariates—unlike that from other sources, such as sampling error or process variability—is seldom explicitly incorporated. This can cause underestimates of uncertainty to cascade through model parameter estimates, predictions, and downstream uses. Burner et al. proposed a method for quantifying uncertainty in covariates and incorporating it into models using informative Bayesian priors. This method was applied to stop-level Breeding Bird Survey (BBS) analyses, where land cover uncertainty at each stop arises from substantial stop location uncertainty. A limited validation of model-estimated land cover, using stops with known locations, indicated the method’s potential effectiveness, but it was not rigorously evaluated. We conduct a robust simulation-based test, generating stop locations, extracting land cover, and simulating bird communities across 210 BBS routes in the upper Midwest. We compare 3 models: a “known” model with true land cover, a “naive” model assuming consistent 800-m stop spacing, and a “full” model using informative priors to estimate land cover. Species parameter estimates and predicted prevalence patterns across gradients in land cover from the full model approached those of the known model and were substantially closer to the true values used in simulations relative to those from the naive model. Naive model parameters were more biased relative to the other models, and credible intervals of predicted species prevalence rarely included the true simulated values. The full model also produced land cover covariate estimates closer to true simulation values relative to the mean informative priors. Our results show that, for the BBS, informative priors enable more accurate stop-level analyses despite location uncertainty. In contrast, naive models that ignore this uncertainty yield poor inferences. More broadly, we demonstrate empirically the utility of informative priors to account for covariate uncertainty in ecological models.

Michigan, Minnesota, Wisconson

Simulating present and future groundwater/surface-water interactions and stream temperatures in Beaver Creek, Kenai Peninsula, Alaska

In many places, coldwater ecosystems are facing increasing pressure from anthropogenic warming. This study examined stream temperatures and the water balance in the Beaver Creek watershed on the Kenai Peninsula in south-central Alaska—an area that is experiencing rapid warming. Low-gradient streams near the Kenai coast provide important spawning and rearing habitat for salmon but may be especially vulnerable to rising temperatures, because of long residence times, inflows from abundant riparian wetlands, and reliance on groundwater discharge that may also warm, or decrease in volume with rising evapotranspiration. In recent decades, observed maximum 7-day temperatures have consistently exceeded statistical (regression-based) projections. Here we simulate total streamflows and temperatures with a physics-based model that links the Soil Water Balance, MODFLOW 6 and SNTEMP simulation codes on a 7-day timestep. The model is based on existing data and groundwater levels, instream flows, and stream temperatures collected during 2019–23. Future climate scenarios were developed for 2023–50 from downscaled climate projections. Results indicate that groundwater discharge is about 64 percent of the total streamflow during the months of May through September. Total streamflow and groundwater discharge are expected to remain similar to current conditions through 2050. Stream temperatures are expected to rise; by midcentury, near the Beaver Creek mouth the model predicts 34 to 63 additional days per year with average weekly temperatures above 13 degrees Celsius, 14 to 81 additional days with average weekly temperatures above 15 degrees Celsius, and routine exceedances of 20 degrees Celsius during the warmest periods. Projected stream temperatures vary spatially. Areas of high groundwater inflows in the lower main stem and some tributaries may be most resilient to warming air temperatures during dry conditions. During storm events, groundwater-dominated tributaries may have the coolest stream temperatures.

Alaska

Flood-inundation maps for the Cuyahoga River at Jaite, Ohio, 2024

Digital flood-inundation maps for a nearly 6-mile reach of the Cuyahoga River at Jaite, Ohio, were created by the U.S. Geological Survey (USGS) in cooperation with the Northeast Ohio Regional Sewer District Board of Trustees. The maps depict estimates of the extent and depth of flooding corresponding to selected water levels (stages) at USGS streamgage 04206425 on the Cuyahoga River at Jaite, Ohio. Water-surface profiles were computed for the stream reach by using a one-dimensional steady-state step-backwater model. The hydraulic model was calibrated to the current USGS streamgage data and then used to compute 15 water-surface profiles for flood stages at 1-foot intervals referenced to the streamgage datum and ranging from 6 to 20 feet, which correspond to below “action stage” to “major flood stage” as reported by the National Weather Service. The simulated water-surface profiles were then used with a geographic information system digital elevation model derived from light detection and ranging data to delineate the areas flooded at each stage. These maps, along with current stage data from the USGS streamgage and forecasted high-flow stages from the National Weather Service, can provide emergency management personnel and residents with information that is critical for flood response activities such as evacuations and road closures, as well as for postflood recovery efforts.

Ohio

State shifts in the deep Critical Zone drive landscape evolution in volcanic terrains

Understanding the near-surface environment where atmospheric and solid earth processes interact, often termed the “Critical Zone,” is important for assessing resources and building resilient societies. Here, we examine a volcanic landscape in the Oregon Cascade Range, an understudied Critical Zone setting that is host to major regional water resources, pervasive silicate weathering, and significant geohazards. We leverage a bedrock age chronosequence to show that the volcanic Critical Zone undergoes a structural shift, from depth extents of >1 km to meters, over timescales of ~1 My. We map an active groundwater volume comparable to major continental lakes, stored at the Cascade Range crest. This state shift makes volcanic landscape evolution a unique probe of deep coupling between Earth systems.

PNAS

Groundwater tracing used to delineate recharge areas and map karst groundwater pathways for subterranean streams at Oregon Caves National Monument and Preserve

Oregon Caves National Monument and Preserve in southwestern Oregon is a 4,554-​acre area managed by the National Park Service that is home to several cave systems, including Oregon Caves, which is the longest cave in Oregon, with 3.03 miles of mapped passages. Because of the interconnected nature of karst hydrologic systems, it is critical to understand the areas that can influence water quality and quantity in karst environments. Toward this goal, dye tracing was conducted by the U.S. Geological Survey from 2021 to 2024 to better understand the pathways that karst groundwater follows at Oregon Caves National Monument and Preserve and to delineate recharge areas for two caves, Oregon Caves and Cave Next Door. During the project, eight dye injections were conducted, delineating a 0.51-​square-​mile recharge area for Oregon Caves and a 0.69-​square-​mile recharge area for Cave Next Door. Additionally, the study helped to identify three resurgences associated with Oregon Caves that were previously unknown and showed that the recharge areas for the two caves were distinct from one another. The dye traces also illuminated some unique recharge characteristics of the karst at Oregon Caves, including a high variance in karst groundwater velocities, retention within the karst aquifers, and a significant diffuse-​flow component.

Oregon

Field observations and logs from the Rose Hip trench exposure across a north-facing scarp within the Seattle Fault Zone, southern Bainbridge Island, Washington

The Seattle Fault Zone is an approximately 70-km-long, east-west-trending zone of south-dipping blind reverse faults within the Puget lowland region in Washington. Because of the proximity, the Seattle Fault Zone poses a significant earthquake hazard to the Puget sound and Seattle metropolitan regions. We present preliminary mapping and trench-site information from a paleoseismic investigation across a newly identified active fault scarp located within the hanging wall of the Seattle Fault Zone on southern Bainbridge Island, Washington. The trench exposed monoclinally folded Miocene bedrock, fractured and faulted glacial-related deposits, and laminated lacustrine deposits capped by slope-derived colluvium. The observations from this investigation record late Pleistocene to Holocene north-vergent folding and faulting along this new fault scarp.

Washington

Preconditioned Conjugate-Gradient 2 (PCG2), a computer program for solving ground-water flow equations

This report documents PCG2: a numerical code to be used with the U.S. Geological Survey modular three-dimensional, finite-difference, ground-water flow model. PCG2 uses the preconditioned conjugate-gradient method to solve the equations produced by the model for hydraulic head. Linear or nonlinear flow conditions may be simulated. PCG2 includes two reconditioning options: modified incomplete Cholesky preconditioning, which is efficient on scalar computers; and polynomial preconditioning, which requires less computer storage and, with modifications that depend on the computer used, is most efficient on vector computers. Convergence of the solver is determined using both head-change and residual criteria. Nonlinear problems are solved using Picard iterations. This documentation provides a description of the preconditioned conjugate gradient method and the two preconditioners, detailed instructions for linking PCG2 to the modular model, sample data inputs, a brief description of PCG2, and a FORTRAN listing.

Water-Resources Investigations Report

Potential climate and human water-use effects on water-quality trends in a semiarid, western U.S. watershed: Fountain Creek, Colorado, USA

Nutrients, total dissolved solids (TDS), and trace elements affect the suitability of water for human and natural needs. Here, trends in such water-quality constituents are analyzed for 1999–2022 for eight nested monitoring sites in the 24,000 km 2 Fountain Creek watershed in Colorado, USA, by using the weighted regressions on time, discharge, and season (WRTDS) methodology. Fountain Creek shares characteristics with other western U.S. watersheds: (1) an expanding but more water-efficient population, (2) a heavy reliance on imported water, (3) a semiarid climate trending towards warmer and drier conditions, and (4) shifts of water from agricultural to municipal uses. The WRTDS analysis found both upward and downward trends in the concentrations of nutrients that reflected possible shifts in effluent management, instream uptake, and water conservation by a watershed population that grew by about 40%. Selenium, other trace elements, and TDS can pose water-quality challenges downstream and their concentrations were found to have a downwards trend. Those trends could be driven by either a warming and drying of the local climate or decreased agricultural irrigation, as both would reduce recharge and subsequent mobilization from natural geologic sources via groundwater discharge. The patterns illustrate how changes in climate and water use may have affected water quality in Fountain Creek and demonstrate the patterns to look for in other western watersheds.

Colorado

Special issue “The 2024 M7.6 Noto Peninsula earthquake and seismic swarm”

The 2024 Mw7.5 (M JMA 7.6) Noto Peninsula earthquake struck the Noto Peninsula, central Japan on January 1, 2024, causing widespread damage. This Mw7.5 mainshock, together with the prolonged seismic swarm that persisted in the northeastern Noto Peninsula since the end of 2020, of which the largest event was the 2023 M JMA 6.5 earthquake, constitutes one of the most significant seismic sequences in Japan in recent decades. The sequence provides a rare opportunity to investigate the complex interplay among swarm activity, fluid migration, fault geometry and distribution, and the preparatory conditions required for a large inland crustal earthquake. Motivated by this scientific context, this special issue brings together studies examining the sequence from diverse disciplinary perspectives, incorporating seismic, geodetic, and tsunami-related observations and modelling.

Noto Peninsula

Cnidarian–algal partnerships structure bacterial communities during strobilation in Cassiopea xamachana

Cnidarian–algal (Symbiodiniaceae) symbioses rely on complex interactions among the cnidarian host, algal symbionts, and associated bacterial communities. In the upside-down jellyfish Cassiopea xamachana , the polyp-to-medusa transition (strobilation) requires the establishment of symbiosis with Symbiodiniaceae algal partners, yet bacterial community dynamics during this developmental process remain unknown. Here, we experimentally induced symbiosis in aposymbiotic polyps using four algal treatments: xenic Symbiodinium microadriaticum (native symbiont), xenic Breviolum minutum , antibiotic-treated B. minutum , and a photosynthetically impaired B. minutum mutant. We combined 16S rRNA gene sequencing with measurements of photosynthetic efficiency, asexual budding, and algal surface N-glycan profiles to characterize holobiont assembly during symbiosis onset and strobilation. Algal treatment structured bacterial communities in both algal cultures and polyp tissues. Our analyses identified a set of amplicon sequence variants that consistently distinguished strobilating polyps from non-strobilating aposymbiotic and mutant polyps, in addition to potential bacterial biomarkers associated with successful metamorphosis. Strobilation was associated with the enrichment of bacterial communities putatively involved in sulfur and nitrogen cycling, whereas non-strobilating aposymbiotic and mutant polyps were characterized by opportunistic bacteria and increased community variability. Together, these results reveal coordinated changes in algal physiology, surface glycan profiles, and bacterial community structure associated with successful strobilation in C. xamachana and support a model in which tripartite host–alga–bacteria interactions influence cnidarian life stage transitions.

ISME Communications

Groundwater quality near the Placerita Oil Field, California, 2018

Groundwater-quality data and potential fluid-migration pathways near the Placerita Oil Field in Los Angeles County, California, were examined by the U.S. Geological Survey to determine if oil-field fluids (water and gas from oil-producing and non-producing zones) have mixed with groundwater resources. Six of the 13 new groundwater samples collected for this study contained petroleum hydrocarbons, thermogenic gas, inorganic chemical signatures, and (or) isotopic values consistent with potential mixing with fluids from hydrocarbon-bearing formations. For historical groundwater samples, benzene was the most detected petroleum hydrocarbon. The historical groundwater samples with a benzene concentration greater than 0.5 micrograms per liter were from environmental monitoring wells at industrial or commercial facilities unrelated to oil and gas development that, in many cases, have identified soil or groundwater contamination and were not typically analyzed for other constituents that could provide additional lines of evidence for potential mixing with oil-field fluids. Methane was not detected in any of the 12 historical samples with a reported measurement. Reviewing historical data revealed factors that could potentially adversely affect groundwater quality in the study area. These factors include modified hydraulic gradients caused by large volumes of water extracted from the main production area and reinjected downgradient into nonproducing zones, well-barrier failures in wells constructed in the northern part of the oil field before the 1970s, well-barrier failures in produced-water disposal wells downgradient from the main production area, and naturally occurring hydrocarbons at shallow intervals. The groundwater samples most geochemically similar to samples from hydrocarbon-bearing formations were in areas where hydrocarbons are naturally occurring at shallow intervals and where oil development is at shallow depths. Additional data for hydraulic heads, water quality, and formation temperatures at multiple depths in areas with large injection volumes and well-integrity issues are needed to evaluate whether those factors have contributed to mixing between fluids from oil-producing or injection formations and groundwater resources.

California

Reservoir thermal energy storage pre-assessment for the United States

Storing thermal energy underground for later use in electricity production or direct-use heating/cooling is a promising, viable, and economical green energy option. Reservoir thermal energy storage (RTES) is one such option, which stores energy in underutilized permeable strata with low ambient groundwater flow rates and more geochemically evolved (e.g. brackish/saline) waters relative to overlying principal aquifer systems. The U.S. Geological Survey has begun assessing RTES potential nationally by focusing on five generalized geologic regions (Basin and Range, Coastal Plain, Illinois Basin, Michigan Basin, Pacific Northwest) across the United States. Hydrogeologic reservoir models are developed for the following eight metropolitan area cities within those regions to evaluate RTES performance across different climates and subsurface conditions: Albuquerque, New Mexico; Charleston, South Carolina; Chicago and Decatur, Illinois; Lansing, Michigan; Memphis, Tennessee; Phoenix, Arizona; and Portland, Oregon. Evaluated metrics include estimated required well spacing, thermal storage capacity, and thermal recovery efficiency through time. Also considered for each reservoir are potential complicating factors, including reservoir depth, thermally driven free convection, and groundwater salinity. This work focuses on direct-use cooling because the need for cooling modern office buildings greatly exceeds that for heating in most parts of the country (Falta and others, 2016); however, the evaluated metrics are also relevant to heating and electricity applications. Results indicate that favorable RTES conditions exist in each region, with the Coastal Plain and Basin and Range being especially favorable for thermal storage capacity, while the Pacific Northwest and Michigan Basin excel at energy recovery for the evaluated cooling application. The results underscore the utility of developing maps of thermal storage capacity, subsurface temperature models, and volumetric estimates of thermal storage capacity to serve as key RTES resource classification standards. Overall, this pre-assessment provides a basic understanding of RTES potential in several cities and geologic regions throughout the country and will aid ongoing thermal energy storage assessment efforts.

Arizona, Illinois, Michigan, New Mexico, Oregon, S

Simulating human behavior under earthquake early warning

Earthquakes are a rapid-onset hazard where advance planning and learning plays a key role in mitigating injuries and death to individuals. Recent advances in earthquake detection have resulted in the development of earthquake early warning (EEW) systems. These systems can provide advance warning to predetermined geographic regions that an earthquake is in progress, which may result in individuals receiving warning seconds before significant shaking is felt at their location. This additional time could allow individuals to take more effective protective actions during the immediate disaster. To demonstrate this, we created an agent-based simulation of a basic apartment that allowed us to randomly and repeatedly simulate an individual receiving and responding to an EEW message. The results of our preliminary simulation show that, in our study environment, earthquake early warning alerts have the potential to allow for sufficient time for individuals to take protective actions.

Washington

Reconfigured-Channel Monitoring and Assessment Program

A U.S. Geological Survey program to monitor and assess channel reconfiguration activity is described. A data base available on the world wide web will enable land-management agencies and other interested parties to evaluate the long-term success of various channel reconfiguration projects. A demonstration project on the Lake Fork of the Gunnison River, Colorado, illustrates the program objectives and approach.

Colorado