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At least 1,603 records · Page 89Linked to original sources

USGS2013

Deformational and erosional history for the Abiquiu and contiguous area, north-central New Mexico: Implications for formation of the Abiquiu embayment and a discussion of new geochronological and geochemical analysis

Geologic mapping, age determinations, and geochemistry of rocks exposed in the Abiquiu area of the Abiquiu embayment of the Rio Grande rift, north-central New Mexico, provide data to determine fault-slip and incision rates. Vertical-slip rates for faults in the area range from 16 m/m.y. to 42 m/m.y., and generally appear to decrease from the eastern edge of the Colorado Plateau to the Abiquiu embayment. Incision rates calculated for the period ca. 10 to ca. 3 Ma indicate rapid incision with rates that range from 139 m/m.y. on the eastern edge of the Colorado Plateau to 41 m/m.y. on the western part of the Abiquiu embayment. The Abiquiu area is located along the margin of the Colorado Plateau–Rio Grande rift and lies within the Abiquiu embayment, a shallow, early extensional basin of the Rio Grande rift. Cenozoic rocks include the Eocene El Rito Formation, Oligocene Ritito Conglomerate, Oligocene–Miocene Abiquiu Formation, and Miocene Chama–El Rito and Ojo Caliente Sandstone Members of the Tesuque Formation (Santa Fe Group). Volcanic rocks include the Lobato Basalt (Miocene; ca. 15–8 Ma), El Alto Basalt (Pliocene; ca. 3 Ma), and dacite of the Tschicoma Formation (Pliocene; ca. 2 Ma). Quaternary deposits consist of inset axial and side-stream deposits of the ancestral Rio Chama (Pleistocene in age), landslide and pediment alluvium and colluvium, and Holocene main and side-stream channel and floodplain deposits of the modern Rio Chama. The predominant faults are Tertiary normal high-angle faults that displace rocks basinward. A low-angle fault, referred to as the Abiquiu fault, locally separates an upper plate composed of the transitional zone of the Ojo Caliente Sandstone and Chama–El Rito Members from a lower plate consisting of the Abiquiu Formation or the Ritito Conglomerate. The upper plate is distended into blocks that range from about 0.1 km to 3.5 km long that may represent a larger sheet that has been broken up and partly eroded. Geochronology ( 40 Ar/ 39 Ar) from fifteen volcanic and intrusive rocks resolves discrete volcanic episodes in the Abiquiu area: (1) emplacement of Early and Late Miocene basaltic dikes at 20 Ma and ca. 10 Ma; (2) extensive Late Miocene–age lava flows at 9.5 Ma, 7.9 Ma, and 5.6 Ma; and (3) extensive basaltic eruptions during the early Pliocene at 2.9 Ma and 2.4 Ma. Clasts of biotite- and hornblende-rich trachyandesites and trachydacites from the base of the Abiquiu Formation are dated at ca. 27 Ma, possibly derived from the Latir volcanic field. The most-mafic magmas are interpreted to be generated from a similar lithospheric mantle during rifting, but variations in composition are correlated with partial melting at different depths, which is correlated with thinning of the crust due to extensional processes.

GSA Special Papers↗

USGS1957

Records available to September 30, 1956, on use of water in the Delaware Basin Project area

The purpose of this report is to summarize data on the use of water in the Delaware Basin Project area (fig. 2) and to list the principal data sources that are available in published form. The tables and bibliography will assist Geological Survey personnel assigned to the Delaware Basin Project in evaluating the scope and deficiencies of previous studies of the basin. Information is also given on the use of water by public supplies in the New York-New Jersey region comprising the New York City Metropolitan Area and in the remaining north-central and south-eastern parts of New Jersey. These regions may depend increasingly on water from the Delaware River basin for part of their public supplies. The Geological Survey has the responsibility for appraising and describing the water resources of the Nation as a guide to use, development, control, and conservation of these resources. Cooperative Federal-State water-resources investigations in the Delaware Basin States have been carried on the the Geological Survey for more than 50 years. In July 1956 the Survey began the "Delaware Basin Project," a hydrologic study of the Delaware River basin in order to: 1) Determine present status and trends in water availability, quality, and use, 2) assess and improve the adequacy of the Survey's basic water data program in the basin, 3) interpret and evaluate the water-resources data in terms of past and possible future water-use and land-use practices, and 4) disseminate promptly the results of this investigation for the benefit of all interested agencies and the general public. The Geological Survey is working closely with the U.S. Corps of Engineers and other cooperating Federal and State agencies in providing water data which will contribute to the present coordinated investigation aimed at developing a plan for long-range water development in the Delaware River basin. Estimates of quantities of water used are given for water withdrawn from streams and aquifers during calendar year 1955, as compiled or estimated from publications and manuscripts prepared between 1950 and 1956. All quantities are given in millions of gallons per day (mgd). The source of the water used, ground or surface, and the type of use to which is was put -- public supply, industrial supply, irrigation, or rural use -- is given. Use of water for hydroelectric power was not compiled for this report. Most tables in this report do not subdivide withdrawals into fresh and saline water; however, most supplies are fresh, except some of those withdrawn directly from the Delaware River downstream from Philadelphia, Pa. All quantities are expressed as an average rate for a full year and are lower, therefore, than rates resulting from the increased demand for water during the summer for air conditioning and supplemental irrigation. The primary emphasis of this study was to get an over-all picture of water use throughout large parts of the basin. Therefore, publications relating to a dingle city or county, other than New York City, seldom were used; revisions and refinement based on such sources of information are best made by the field personnel most familiar with locally filed publications and published data.

Delaware↗

USGS1973

Effects of coal mining on the water resources of the Tradewater River Basin, Kentucky

The effects of coal-mine drainage on the water resources of the Tradewater River basin, in the Western Coal Field region of Kentucky, were evaluated (1) by synthesis and interpretation of 16 years of daily conductance data. 465 chemical analyses covering an 18-year period, 28 years of daily discharge data, and 14 years of daily suspended-sediment data from the Tradewater River at Olney and (2) by collection, synthesis, and interpretation of chemical and physical water-quality data and water-quantity data collected over a 2-year period from mined and nonmined sites in the basin. Maximum observed values of 13 chemical and physical water-quality parameters were three to 300 times greater in the discharge from mined subbasins than in the discharge from nonmined subbasins. Potassium, chloride, and nitrate concentrations were not significantly different between mined and nonmined areas. Mean sulfate loads carried by the Tradewater River at Olney were about 75 percent greater for the period 1955-67 than for the period 1952-54. Suspended-sediment loads at Olney for the November-April storm-runoff periods generally vary in response to strip-mine coal production in the basin above Olney. Streamflow is maintained during extended dry periods in mined subbasins after streams in nonmined subbasins have ceased flowing. Some possible methods of reducing the effects of mine drainage on the streams are considered in view of a geochemical model proposed by Ivan Barnes and F. E. Clarke. Use of low-flow-augmenting reservoirs and crushed limestone in streambeds in nonmined areas seems to be the most promising method for alleviating effects of mine drainage at the present time. Other aspects of the water resources such as variability of water quantity and water quality in the basin are discussed briefly.

Water Supply Paper↗

USGS2020

A standard operating procedure for the preparation of purposely killed juvenile salmon used to test survival model assumptions

This document describes a standard operating procedure (SOP) for the preparation of purposely killed juvenile salmon, implanted with telemetry transmitters, to be released into rivers, lakes, or streams to test one of the survival model assumptions. Procedures for releases of purposely killed fish (hereinafter dead fish releases) were developed by staff from the U.S. Geological Survey’s Columbia River Research Laboratory, on the basis of laboratory experiments and practical experience with telemetry studies in the Columbia River Basin. Initially, we used extended exposure to high dose anesthetic baths to euthanize fish for dead fish releases. This approach was selected on the basis of euthanization procedures described in the literature for studies that required an effective and rapid procedure, such as stress physiology assessments. Ultimately, this technique was deemed insufficient because detection records suggested that some fish seemed to revive and continue their migration with limited effect. That is, the detection histories of dead fish were very similar to those of live fish. To overcome this challenge, we adapted our procedures to require a combination of euthanization procedures on individual fish to ensure that there was no opportunity for revival. A combination of euthanization procedures for dead fish releases was used in one study in Germany. This SOP has been used by the U.S. Geological Survey to test survival model assumptions in several field studies and has consistently performed well. In addition, limited laboratory tests were completed to ensure that no live juvenile salmon were found in holding tanks for 24 hours following the procedures described in this SOP.

Open-File Report↗

USGS2000

National Geochemical Database, U.S. Geological Survey RASS (Rock Analysis Storage System) geochemical data for Alaska

This dataset contains geochemical data for Alaska produced by the analytical laboratories of the Geologic Division of the U.S. Geological Survey (USGS). These data represent analyses of stream-sediment, heavy-mineral-concentrate (derived from stream sediment), soil, and organic material samples. Most of the data comes from mineral resource investigations conducted in the Alaska Mineral Resource Assessment Program (AMRAP). However, some of the data were produced in support of other USGS programs. The data were originally entered into the in-house Rock Analysis Storage System (RASS) database. The RASS database, which contains over 580,000 data records, was used by the Geologic Division from the early 1970's through the late 1980's to archive geochemical data. Much of the data have been previously published in paper copy USGS Open-File Reports by the submitter or the analyst but some of the data have never been published. Over the years, USGS scientists recognized several problems with the database. The two primary issues were location coordinates (either incorrect or lacking) and sample media (not precisely identified). This dataset represents a re-processing of the original RASS data to make the data accessible in digital format and more user friendly. This re-processing consisted of checking the information on sample media and location against the original sample submittal forms, the original analytical reports, and published reports. As necessary, fields were added to the original data to more fully describe the sample preparation methods used and sample medium analyzed. The actual analytical data were not checked in great detail, but obvious errors were corrected.

Alaska↗

USGS1988

Maps showing distribution of anomalies based on the use of scoresum plots for selected groupings of elements in samples of minus-60-mesh (0.25-MM) stream sediment, Walker Lake 1 degree by 2 degrees Quadrangle, California and Nevada

This report is part of a folio of maps of the Walker Lake 1 o x 2 o quadrangle, California and Nevada, prepared under the Conterminous United States Mineral Assessment Program. The folio includes geological, geochemical, and geophysical maps, as well as mineral resources assessment maps, which identify selected known or possible mineral-deposit environments in the quadrangle. The geochemical maps show the distributions of selected individual elements (Chaffee and others, 1988 a, b, c) and the distributions of selected groups of elements (Chaffee, 1988a, b, c). Discussions accompanying the individual element maps are restricted to mineral residences of the individual elements as well as to what types of mineral deposits and environments may be represented by anomalies of a particular element. Discussions accompanying the multielemental maps describe the types of mineral deposits that may be related to each element group and indicate the most favorable localities for these deposits.

California, Nevada↗

USGS2001

Late Cenozoic regional collapse due to evaporite flow and Dissolution in the Carbondale Collapse Center, West-Central Colorado

Dissolution and flow of Pennsylvanian evaporitic rocks in west-central Colorado created the Carbondale Collapse Center, a 450 mi2 structural depression with about 4,000 ft of vertical collapse during the late Cenozoic. This paper describes evidence of collapse in the lower Roaring Fork River valley. Both the lateral extent and amount of vertical collapse is constrained by deformed upper Cenozoic volcanic rocks that have been correlated using field mapping, 40Ar/39Ar geochronology, geochemistry, and paleomagnetism. The Carbondale Collapse Center is one of at least two contiguous areas that have experienced major evaporite tectonism during the late Cenozoic. Historic sinkholes, deformed Holocene deposits, and modern high-salinity loads in the rivers and thermal springs indicate the collapse process continues today. Flow of evaporitic rocks is an important element in the collapse process, and during initial stages of collapse it was probably the primary causative mechanism. Dissolution, however, is the ultimate means by which evaporite is removed from the collapse area. As the Roaring Fork River began to rapidly down-cut through a broad volcanic plateau during the late Miocene, the underlying evaporite beds were subjected to differential overburden pressures. The evaporitic rocks flowed from beneath the upland areas where overburden pressures remained high, toward the Roaring Fork River Valley where the pressures were much lower. Along the valley the evaporitic rocks rose upward, sometimes as diapirs, forming or enhancing a valley anticline in bedrock and locally upwarping Pleistocene terraces. Wherever the evaporites encountered relatively fresh ground water, they were dissolved, forming underground voids into which overlying bedrock and surficial deposits subsided. The saline ground water eventually discharged to streams and rivers through thermal springs and by seepage into alluvial aquifers.

Mountain Geologist↗

USGS2001

Ground-water flow in the shallow aquifer system at the Naval Weapons Station Yorktown, Virginia

The Environmental Directorate of the Naval Weapons Station Yorktown, Virginia, is concerned about possible contamination of ground water at the Station. Ground water at the Station flows through a shallow system of layered aquifers and leaky confining units. The units of the shallow aquifer system are the Columbia aquifer, the Cornwallis Cave confining unit, the Cornwallis Cave aquifer, the Yorktown confining unit, and the Yorktown-Eastover aquifer. The Eastover-Calvert confining unit separates the shallow aquifer system from deeper confined aquifers beneath the Station. A three-dimensional, finite-difference, ground-water flow model was used to simulate steady-state ground-water flow of the shallow aquifer system in and around the Station. The model simulated ground-water flow from the peninsular drainage divide that runs across the Lackey Plain near the southern end of the Station north to King Creek and the York River and south to Skiffes Creek and the James River. The model was calibrated by minimizing the root mean square error between 4 7 measured and corresponding simulated water levels. The calibrated model was used to determine the ground-water budget and general directions of ground-water flow. A particle-tracking routine was used with the calibrated model to estimate groundwater flow paths, flow rates, and traveltimes from selected sites at the Station. Simulated ground-water flow velocities of the Station-area model were small beneath the interstream areas of the Lackey Plain and Croaker Flat, but increased outward toward the streams and rivers where the hydraulic gradients are larger. If contaminants from the land surface entered the water table at or near the interstream areas of the Station, where hydraulic gradients are smaller, they would migrate more slowly than if they entered closer to the streams or the shores of the rivers where gradients commonly are larger. The ground-water flow simulations indicate that some ground water leaks downward from the water table to the Yorktown confining unit and, where the confining unit is absent, to the Yorktown-Eastover aquifer. The velocities of advective-driven contaminants would decrease considerably when entering the Yorktown confining unit because the hydraulic conductivity of the confining unit is small compared to that of the aquifers. Any contaminants that moved with advective ground-water flow near the groundwater divide of the Lackey Plain would move relatively slowly because the hydraulic gradients are small there. The direction in which the contaminants would move, however, would be determined by precisely where the contaminants entered the water table. The model was not designed to accurately simulate ground-water flow paths through local karst features. Beneath Croaker Flat, ground water flows downward through the Columbia aquifer and the Yorktown confining unit into the Yorktown-Eastover aquifer. Analyses of the movement of simulated particles from two adjacent sites at Croaker Flat indicated that ground-water flow paths were similar at first but diverged and discharged to different tributaries of Indian Field Creek or to the York River. These simulations indicate that complex and possibly divergent flow paths and traveltimes are possible at the Station. Although the Station-area model is not detailed enough to simulate ground-water flow at the scales commonly used to track and remediate contaminants at specific sites, general concepts about possible contaminant migration at the Station can be inferred from the simulations.

Virginia↗

USGS2004

Herbicides and their transformation products in source-water aquifers tapped by public-supply wells in Illinois, 2001-02

During 2001-02, ground-water samples were collected from 117 public-supply wells distributed throughout Illinois to evaluate the occurrence of herbicides and their transformation products in the State?s source-water aquifers. Wells were selected using a stratified-random method to ensure representation of the major types of source-water aquifers in the State. Samples were analyzed for 18 herbicides and 18 transformation products, including 3 triazine and 14 chloroacetanilide products. Herbicide compounds (field-applied parent herbicides and their transformation products) were detected in 34 percent of samples. A subset of samples was collected unfiltered to determine if analytical results for herbicides in unfiltered samples are similar to those in paired filtered samples and, thus, can be considered equally representative of herbicide concentrations in ground water supplied to the public. The study by the U.S. Geological Survey was done in cooperation with the Illinois Environmental Protection Agency. Parent herbicides were detected in only 4 percent of all samples. The six most frequently detected herbicide compounds (from 5 to 28 percent of samples) were chloroacetanilide transformation products. The frequent occurrence of transformation products and their higher concentrations relative to those of most parent herbicides confirm the importance of obtaining information on transformation products to understand the mobility and fate of herbicides in ground-water systems. No sample concentrations determined during this study exceeded current (2003) Federal or State drinking-water standards; however, standards are established for only seven parent herbicides. Factors related to the occurrence of herbicide compounds in the State?s source-water aquifers include unconsolidated and unconfined conditions, various hydrogeologic characteristics and well-construction aspects at shallow depths, and proximity to streams. Generally, the closer an aquifer (or well location) is to a recharge area and (or) the stronger the hydraulic connection between an aquifer and a recharge area, the younger the ground water and the more vulnerable the aquifer will be to contamination by herbicide compounds. The weak relation between current (2001) statewide application rates of herbicides and current (2001-02) occurrence of herbicide compounds in source-water aquifers indicates that additional factors must be considered when relating herbicide-application rates to occurrence. These factors include historical application rates and the mobility and persistence of the various herbicide compounds in ground-water systems. Frequency of detection and concentrations of herbicides compounds in the State?s source-water aquifers are indicated to be highest during the spring, when crops are planted and herbicides primarily are applied. Excess nitrate (concentrations of nitrate, as nitrogen, higher than 3 milligrams per liter) in ground water strongly indicates the co-occurrence of herbicide compounds. However, nitrate concentrations are not a reliable indicator of herbicide-compound concentrations. The inverse relation found between current use of land for corn and soybean production and current occurrence of herbicide compounds in underlying aquifers indicates that various factors, along with current agricultural land use, contribute to herbicide occurrence. These factors include, among others, land-use history, ground-water age, ground-water-flow patterns, geology, soil microbiology, and chemistry and persistence of the herbicide compounds. Detection of agriculture-specific herbicide compounds in 71 percent of samples from urban areas with no current or recent agricultural land use near the sampled wells indicates that recharge to certain high-capacity supply wells may originate at considerable distances (up to about 10 miles) from the wells. Essentially no difference was found between the analytical results for herbicides in paired unfiltered and filtered samples,

Water-Resources Investigations Report↗

USGS1981

Water resources inventory of Connecticut Part 7: upper Connecticut River basin

The 508 square miles of the upper Connecticut River basin in north-central Connecticut include the basins of four major tributaries: the Scantic, Park, and Hockanum Rivers, and the Farmington River downstream from Tariffville. Precipitation over this area averaged 44 inches per year during 1931-60. In this period, an additional 3,800 billion gallons of water per year entered the basin in the main stem of the Connecticut River at the Massachusetts state line, about 230 billion gallons per year in the Farmington River at Tariffville, and about 10 billion gallons per year in the Seantic River at the Massachusetts state line. Some water was also imported from outside the basin by water-supply systems. About half the precipitation, 22.2 inches, was lost from the basin by evapotranspiration; the remainder flowed out of the study area in the Connecticut River at Portland. Variations in streamflow at 41 long-term continuous-record gaging stations are summarized in standardized graphs and tables that can be used to estimate streamflow characteristics at other sites. For example, mean-flow and two low-flow characteristics: (1) the 7-day annual minimum flow for 2-year and (2) 10-year recurrence intervals, have been determined for many partial-record stations throughout the basin. Of the 30 principal lakes, ponds, and reservoirs, two have usable storage capacities of more than 1 billion gallons. The maximum safe draft rate (regulated flow) of the largest of these, Shenipsit Lake at Rockville, is 6.5 million gallons per day for the 2-year and 30-year recurrence intervals (median and lowest annual flow). Floods have occurred within each month of the year but in different years. The greatest known flood on the Connecticut River was in March 1936; it had a peak flow of 130,000 cubic feet per second at Hartford. Since then, major floods have been reduced by flood-control measures. The major aquifers underlying the basin are composed of unconsolidated materials (stratified drift and till) and bedrock. Stratified drift overlies till and bedrock in valleys and lowlands in the eastern and western parts and in most of the broad central valley. The stratified drift generally ranges in thickness from 10 feet in small valleys to more than 200 feet in the Connecticut River Valley. Bedrock underlies the entire basin and is composed of (1) interbedded sedimentary and igneous rocks and (2) crystalline rocks. Ground-water sources yield from several million gallons per day from large well fields to 1 gallon per minute from single wells. Yields of 100 gal/min or more are most commonly obtained from screened wells tapping stratified-drift aquifers; amounts can be calculated by use of a series of graphs in conjunction with estimates of aquifer transmissivity and thickness. Eighteen areas underlain by good aquifers are selected as the most favorable locations for large-scale development of ground water. Selection of these areas is based on estimates of aquifer characteristics and the amount of water potentially available from induced infiltration of streamflow at low-flow conditions. Small to moderate water supplies can generally be obtained from any of the aquifers. Wells in bedrock yield at least a few gallons per minute at most sites. The probability of obtaining an adequate yield for domestic supply is greater in sedimentary than in crystalline bedrock and is also greater in stratified-drift overburden than in till. Where unaffected by man's activities, the water is of the calcium magnesium bicarbonate type, is generally low to moderate in dissolved-solids concentration, and ranges from soft to hard. In general, streamflow is less mineralized than ground water, particularly when it consists largely of direct runoff. However, streams become more highly mineralized during low-flow conditions, when most flow consists of more highly mineralized water discharged from aquifers. The median dissolved-solids concentration in water from 25 stream sites was 113 mg/L (milligrams per liter) during high flow, and 148 mg/L during low flow within the study period. Iron and manganese occur naturally in objectionable concentrations in some streams draining swamps and in some waters draining from sedimentary bedrock which contains iron- and manganese-bearing minerals. Man's activities have affected the water quality of streams in much of the area, particularly in the Hockanum and Park River basins. The degradation in quality in these streams is shown by wide and erratic changes in dissolved-solids concentration, excessive amounts of trace elements, a low dissolved-oxygen content, and abnormally high temperatures. Ground water within this area is degraded principally by induced infiltration of surface water that contains chemical wastes, by leachate from wastes stored or disposed of on the ground, and by effluents discharged from septic tanks. The quantity and quality of water are satisfactory for a wide variety of uses, and, with suitable treatment, the water may be used for most purposes. The total amount of water used in 1968 was more than 100 billion gallons. About 80 percent of this was used for industrial purposes, and 90 percent of the industrial water was obtained from surface-water sources. About 85 percent of the population was supplied with water for domestic use by 15 major public and municipal systems and 25 private associations. Analyses of water from the 13 largest systems show generally good quality.

Connecticut↗

USGS2017

Synthesis centers as critical research infrastructure

Demand for the opportunity to participate in a synthesis-center activity has increased in the years since the US National Science Foundation (NSF)–funded National Center for Ecological Analysis and Synthesis (NCEAS) opened its doors in 1995 and as more scientists across a diversity of scientific disciplines have become aware of what synthesis centers provide. The NSF has funded four synthesis centers, and more than a dozen new synthesis centers have been established around the world, some following the NSF model and others following different models suited to their national funding environment ( http://synthesis-consortium.org ). Scientific synthesis integrates diverse data and knowledge to increase the scope and applicability of results and yield novel insights or explanations within and across disciplines (Pickett et al. 2007 , Carpenter et al. 2009 ). The demand for synthesis comes from the pressing societal need to address grand challenges related to global change and other issues that cut across multiple societal sectors and disciplines and from recognition that substantial added scientific value can be achieved through the synthesis-based analysis of existing data. Demand also comes from groups of scientists who see exciting opportunities to generate new knowledge from interdisciplinary and transdisciplinary collaboration, often capitalizing on the increasingly large volume and variety of available data (Kelling et al. 2009 , Bishop et al. 2014 , Specht et al. 2015b ). The ever-changing nature of societal challenges and the availability of data with which to address them suggest there will be an expanding need for synthesis. However, we are now entering a phase in which government support for some existing synthesis centers has ended or will be ending soon, forcing those centers to close or develop new operational models, approaches, and funding streams. We argue here that synthesis centers play such a unique role in science that continued long-term public investment to maximize benefits to science and society is justified. In particular, we argue that synthesis centers represent community infrastructure more akin to research vessels than to term-funded centers of science and technology (e.g., NSF Science and Technology Centers). Through our experience running synthesis centers and, in some cases, developing postfederal funding models, we offer our perspective on the purpose and value of synthesis centers. We present case studies of different outcomes of transition plans and argue for a fundamental shift in the conception of synthesis science and the strategic funding of these centers by government funding agencies.

BioScience↗

USGS2012

Phosphorus and groundwater: Establishing links between agricultural use and transport to streams

Phosphorus is a highly reactive element that is essential for life and forms a variety of compounds in terrestrial and aquatic ecosystems. In water, phosphorus may be present as the orthophosphate ion (PO 4 3- ) and is also present in all life forms as an essential component of cellular material. In natural ecosystems, phosphorus is derived from the erosion of rocks and is conserved for plant growth as it is returned to the soil through animal waste and the decomposition of plant and animal tissue; but in agricultural systems, a portion of the phosphorus is removed with each harvest, especially since phosphorus is concentrated in the seeds and fruit. Phosphorus is added to soil by using chemical fertilizers, manure, and composted materials. Agricultural use of chemical phosphorus fertilizer, in the United States, in 2008 was 4,247,000 tons, which is an increase of 25 percent since 1964 (http://www.ers.usda.gov/Data/FertilizerUse/). Widely grown corn, soybeans, and wheat use the greatest amount of phosphorus fertilizer among agricultural crops. Phosphorus is largely retained in soil by a process called adsorption. Soils have a limited capacity to store phosphorus, and once the capacity of soil to adsorb phosphorus is exceeded, the excess will dissolve and move more freely with water either directly to a stream or downward to an aquifer. Surface-water runoff from rainstorms or excess irrigation is the primary way that phosphorus or soil containing phosphorus is transported to streams in most watersheds. There is a growing awareness that long-term over-application of manure and chemical fertilizer contributes to phosphorus movement into the groundwater system, resulting in a significant groundwater source of phosphorus to streams and lakes, as well as potential contamination of the groundwater resources. Leaching of applied fertilizer and surface runoff of phosphorus from the soil can contribute to excess growth of algae in downstream water bodies, a condition known as eutrophication. Excessive amounts of algae in eutrophic water bodies can cause large daily changes in the amount of dissolved oxygen in the water because oxygen concentrations tend to be high during daylight hours as a result of photosynthetic activity but then decrease at night. Low concentrations of dissolved oxygen can stress or kill sensitive species living in the water. This study examined concentrations and movement of phosphorus in the soils and groundwater in five agricultural settings across the United States characterized by differences in soil geochemistry, climate, irrigation usage, and cropping systems to assess potential phosphorus movement in the soil and groundwater under common agricultural conditions. The study design included assessment of a variety of agricultural practices, especially cropping patterns and irrigation, so that the factors that contribute to phosphorus movement to groundwater, or sequestration of the phosphorus to soil could be compared and examined. This type of information could potentially be used to formulate best management practices to limit the transport of phosphorus from the agricultural fields.

Fact Sheet↗

USGS2010

Hydrogeomorphic segments and hydraulic microhabitats of the Niobrara River, Nebraska— With special emphasis on the Niobrara National Scenic River

The Niobrara River is an ecologically and economically important resource in Nebraska. The Nebraska Department of Natural Resources’ recent designation of the hydraulically connected surface- and groundwater resources of the Niobrara River Basin as “fully appropriated” has emphasized the importance of understanding linkages between the physical and ecological dynamics of the Niobrara River so it can be sustainably managed. In cooperation with the Nebraska Game and Parks Commission, the U.S. Geological Survey investigated the hydrogeomorphic and hydraulic attributes of the Niobrara River in northern Nebraska. This report presents the results of an analysis of hydrogeomorphic segments and hydraulic microhabitats of the Niobrara River and its valley for the approximately 330-mile reach from Dunlap Diversion Dam to its confluence with the Missouri River. Two spatial scales were used to examine and quantify the hydrogeomorphic segments and hydraulic microhabitats of the Niobrara River: a basin scale and a reach scale. At the basin scale, digital spatial data and hydrologic data were analyzed to (1) test for differences between 36 previously determined longitudinal hydrogeomorphic segments; (2) quantitatively describe the hydrogeomorphic characteristics of the river and its valley; and (3) evaluate differences in hydraulic microhabitat over a range of flow regimes among three fluvial geomorphic provinces. The statistical analysis of hydrogeomorphic segments resulted in reclassification rates of 3 to 28 percent of the segments for the four descriptive geomorphic elements. The reassignment of classes by discriminant analysis resulted in a reduction from 36 to 25 total hydrogeomorphic segments because several adjoining segments shared the same ultimate class assignments. Virtually all of the segment mergers were in the Canyons and Restricted Bottoms (CRB) fluvial geomorphic province. The most frequent classes among hydrogeomorphic segments, and the dominant classes per unit length of river, are: a width-restricted valley confinement condition, sinuous-planview pattern, irregular channel width, and an alternate bar configuration. The Niobrara River in the study area flows through a diversity of fluvial geomorphic settings in its traverse across northern Nebraska. In the Meandering Bottoms (MB) fluvial geomorphic province, river discharge magnitudes are low, and the valley exerts little control on the channel-planview pattern. Within the CRB province, the river flows over a diversity of geologic formations, and the valley and river narrow and expand in approximate synchronicity. In the Braided Bottoms (BB) fluvial geomorphic province, the river primarily flows over Cretaceous Pierre Shale, the valley and channel are persistently wide, and the channel slope is generally uniform. The existence of vegetated islands and consequent multithread channel environments, indicated by a higher braided index, mostly coincided with reaches having gentler slopes and less unit stream power. Longitudinal hydrology curves indicate that the flow of the Niobrara River likely is dominated by groundwater as far downstream as Norden. Unit stream power values in the study area vary between 0 and almost 2 pounds per foot per second. Within the MB province, unit stream power steadily increases as the Niobrara gains discharge from groundwater inflow, and the channel slope steepens. The combination of steep slopes, a constrained channel width, and persistent flow within the CRB province results in unit stream power values that are between three and five times greater than those in less confined segments with comparable or greater discharges. With the exception of hydrogeomorphic segment 3, which is affected by Spencer Dam, unit stream power values in the BB province are generally uniform. Channel sinuosity values in the study area varied generally between 1 and 2.5, but with locally higher values measured in the MB province and at the entrenched bedrock meanders of hydrogeomorphic segment 18 in the CRB province. The differences in channel morphology and hydraulic geometries between fluvial geomorphic provinces are evident in the types, relative abundance, and response of hydraulic microhabitats to changing discharges. The four gaging stations chosen for hydraulic microhabitat analysis are distributed among three different fluvial geomorphic provinces. In the MB province, the smaller channel and lower discharges resulted in the dominance of shallow and intermediate-depth hydraulic environments with the vast majority of hydraulic microhabitat restricted to shallow categories even during upper-decile discharges. In the CRB province, intermediate depth hydraulic conditions, particularly intermediate-swift, dominate over all ranges of discharge. Hydraulic microhabitat conditions were most diverse in the BB province, with most hydraulic microhabitat categories present over the entire range of discharges analyzed. The calculated differences in hydraulic microhabitat distributions, abundance, and adjustments between streamflow-gaging stations were the result of differences in physical structure of the channel and subsequent channel hydraulic geometry. At the reach scale, field measurements made in water years 2008 and 2009 in four study reaches within the Scenic Reach were used to (1) characterize the elevation and geomorphic processes associated with fluvial landforms, (2) build hydraulic geometry relations, (3) examine flow hydraulics over a range of discharges, and (4) examine the types and responses of hydraulic microhabitats to a range of flow magnitudes. Four landform groups were identified and named in order of increasing elevation: low flood plains, intermediate flood plains, low terraces, and high terraces. The terraces were poorly characterized because the surveys did not extend across the full width of the alluvial valley bottom. The two lowest fluvial landforms are likely active in the modern hydroclimatic regime. Sediment samples obtained in the study reaches indicate that the primary bed material in the active channel ranged in size from coarse silt to coarse sand. Grain-size distributions from samples also indicate that the bed of the Niobrara River among the study reaches coarsens and has increasing grainsize variability in the downstream direction. Values of at-a-station hydraulic geometry exponents indicate that the Niobrara River in the study reaches adjusts its geometry to changing discharges primarily through increases in flow depth and velocity. Relations at one cross section indicated that, at least locally, changes in width were also an important channel adjustment mechanism. Hydraulic behavior over the range of flows measured was not consistent among all study reaches, but two general modes of hydraulic behavior were observed in the reaches with substantial coverage of the bed by fine sediment. At the Sunny Brook and Muleshoe study reaches, average boundary-shear stress remained approximately constant, and hydraulic resistance decreased, for discharges below 900 cubic feet per second (ft 3 /s). Above 900 ft 3 /s, average boundary shear stress and hydraulic resistance both increased. The Rock Barn study reach did not exhibit the same two-mode hydraulic behavior observed at the Sunny Brook and Muleshoe reaches. The coincident increase in boundary shear stress above 900 ft 3 /s observed at the Sunny Brook and Muleshoe study reaches represents a potential hydraulic threshold above which bedload transport rates were likely to increase markedly. No consistent bed-adjustment pattern (scour or fill) was identified in the study reaches over the range of flows or over the measurement season. Analysis of hydraulic microhabitats over the range of discharges measured at the study reaches indicates that some percentage of most habitat niche categories was available for at least one discharge condition, but the majority of hydraulic habitat available was within the intermediate-swift and deepswift habitat niche categories. Deep-swift conditions dominated nearly all study reaches under all measured discharge conditions. Slight differences in habitat distributions were observed between the study reaches with substantial coverage of the bed by fine sediment—Sunny Brook, Muleshoe, and Rock Barn—and the bedrock-dominated reach, Crooked Creek. Although the four study reaches occupy three different hydrogeomorphic segments, the types, relative abundance, and response of hydraulic microhabitat niche distributions to changing discharge conditions generally were similar among all reaches.

Nebraska↗

USGS2014

Brine contamination to aquatic resources from oil and gas development in the Williston Basin, United States

The Williston Basin, which includes parts of Montana, North Dakota, and South Dakota in the United States and the provinces of Manitoba and Saskatchewan in Canada, has been a leading domestic oil and gas producing region for more than one-half a century. Currently, there are renewed efforts to develop oil and gas resources from deep geologic formations, spurred by advances in recovery technologies and economic incentives associated with the price of oil. Domestic oil and gas production has many economic benefits and provides a means for the United States to fulfill a part of domestic energy demands; however, environmental hazards can be associated with this type of energy production in the Williston Basin, particularly to aquatic resources (surface water and shallow groundwater) by extremely saline water, or brine, which is produced with oil and gas. The primary source of concern is the migration of brine from buried reserve pits that were used to store produced water during recovery operations; however, there also are considerable risks of brine release from pipeline failures, poor infrastructure construction, and flow-back water from hydraulic fracturing associated with modern oilfield operations. During 2008, a multidisciplinary (biology, geology, water) team of U.S. Geological Survey researchers was assembled to investigate potential energy production effects in the Williston Basin. Researchers from the U.S. Geological Survey participated in field tours and met with representatives from county, State, tribal, and Federal agencies to identify information needs and focus research objectives. Common questions from agency personnel, especially those from the U.S. Fish and Wildlife Service, were “are the brine plumes (plumes of brine-contaminated groundwater) from abandoned oil wells affecting wetlands on Waterfowl Production Areas and National Wildlife Refuges?” and “are newer wells related to Bakken and Three Forks development different than the older, abandoned wells (in terms of potential for affecting aquatic resources)?” Of special concern were the wetland habitats of the ecologically important Prairie Pothole Region, which overlays a part of the Williston Basin and is recognized for the production of a majority of North America’s migratory waterfowl. On the basis of the concerns raised by on-the-ground land managers, as well as findings from previous research, a comprehensive study was developed with the following goals: summarize existing information pertaining to oil and gas production and aquatic resources in the Williston Basin; assess brine plume migration from new and previously studied sites in the Prairie Pothole Region; perform a regional, spatial evaluation of oil and gas production activities and aquatic resources; assess the potential for brine contamination to wetlands and streams; and hold a decision analysis workshop with key stakeholders to discuss issues pertaining to oil and gas production and environmental effects and to identify information gaps and research needs. This report represents an initial, multidisciplinary evaluation of measured and potential environmental effects associated with oil and gas production in the Williston Basin and Prairie Pothole Region. Throughout this report there are reviews of current knowledge, and discussions relating to data gaps and research needs. On the basis of the information presented, future research needs include: regional geophysical and water-quality assessments to establish baselines for current conditions and estimate the extent of previous brine contamination, investigations into the direct effects of brine to biotic communities, and evaluations to identify the most effective techniques to mitigate brine contamination.

Montana, North Dakota↗

USGS1988

Maps showing distribution of anomalies based on the use of R-mode factor analysis for selected groupings of elements in samples of minus-60-mesh (0.25-MM) stream sediment and nonmagnetic heavy-mineral concentrate, Walker Lake 1 degree by 2 degrees Quadrangle, California and Nevada

California, Nevada↗

USGS1999

Geochemical investigations and interim recommendations for priority abandoned mine sites on U.S.D.A. Forest Service lands, Mineral Creek watershed, San Juan County, Colorado

Field observations, sampling of mine dumps and mine drainage waters, and laboratory studies of dump materials have been made at mining areas deemed to be on public lands administered by the USDA Forest Service in the Mineral Creek watershed. Results of chemical analyses of dump materials, leachates of those materials, and of surface waters draining mines or dumps provide indications of where acid is generated or consumed, and what metals are mobilized below mines or dumps. Information on 25 sites is reviewed and reclamation priorities are ranked into four classes (high, medium, low priority, or no work required). The western side of the upper Animas watershed (the Mineral Creek watershed) has a history of mining and prospecting for about 130 years. The intensity of miningrelated disturbance is higher than in most parts of the San Juan Mountains region, but actually is much less than the eastern half of the watershed (US BLM lands) and none of the mines moved millions of tons of rock and ore as in some of the eastern mines. The majority of the roughly one thousand mining sites on the USFS lands are very small (less than 100 tons or 70 cubic yards of dump material), are more than 2 miles from a major stream, or are so inaccessible as to prohibit reclamation. Twenty five sites have been considered by others to have significant size and potential for significant environmental degradation. These most significant mining areas were evaluated by multiple criteria, including tendency to generate acid or liberate toxic metals, observed acidic pH or dead vegetation (?kill zones?) below dumps or adits, potential mobility of metals, and likelihood of transport into streams of the watershed. In the author?s opinion, no single measurable parameter, such as metal concentration, is reliable for ranking significance or feasibility of reclamation. Rather, subjective estimates are required to evaluate combinations of, or interactions among, several parameters. The most subjective estimate in ranking feasibility of reclamation is the amount of natural and mine-related contamination at each mining area. Mitigation of natural contributions at mines or unmined areas is beyond the scope of these Abandoned Mine Lands (AML) investigations, but must be considered when planning reclamation. Available information for the 25 problem sites is adequate for ranking, but at some sites additional information on groundwater conditions is needed for a more reliable ranking and evaluation of reclamation methods.

Colorado↗

USGS1970

Study and interpretation of the chemical characteristics of natural water

The chemical composition of natural water is derived from many different sources of solutes, including gases and aerosols from the atmosphere, weathering and erosion of rocks and soil, solution or precipitation reactions occurring below the land surface, and cultural effects resulting from activities of man. Some of the processes of solution or precipitation of minerals can be closely evaluated by means of principles of chemical equilibrium including the law of mass action and the Nernst equation. Other processes are irreversible and require consideration of reaction mechanisms and rates. The chemical composition of the crustal rocks of the earth and the composition of the ocean and the atmosphere are significant in evaluating sources of solutes in natural fresh water. The ways in which solutes are taken up or precipitated and the amounts present in solution are influenced by many environmental factors, especially climate, structure and position: of rock strata, and biochemical effects associated with life cycles of plants and animals, both microscopic and macroscopic. Taken all together and in application with the further influence of the general circulation of all water in the hydrologic cycle, the chemical principles and environmental factors form a basis for the developing science of natural-water chemistry. Fundamental data used in the determination of water quality are obtained by the chemical analysis of water samples in the laboratory or onsite sensing of chemical properties in the field. Sampling is complicated by changes in composition of moving water and the effects of particulate suspended material. Most of the constituents determined are reported in gravimetric units, usually milligrams per liter or milliequivalents per liter. More than 60 constituents and properties are included in water analyses frequently enough to provide a basis for consideration of the sources from which each is generally derived, most probable forms of elements and ions in solution, solubility controls, expected concentration ranges and other chemical factors. Concentrations of elements that are commonly present in amounts less than a few tens of micrograms per liter cannot always be easily explained, but present information suggests many are controlled by solubility of hydroxide or carbonate or by sorption on solid particles. Chemical analyses may be grouped and statistically evaluated by averages, frequency distributions, or ion correlations to summarize large volumes of data. Graphing of analyses or of groups of analyses aids in showing chemical relationships among waters, probable sources of solutes, areal water-quality regimen, and water-resources evaluation. Graphs may show water type based on chemical composition, relationships among ions, or groups of ions in individual waters or many waters considered simultaneously. The relationships of water quality to hydrologic parameters, such as stream discharge rate or ground-water flow patterns, can be shown by mathematical equations, graphs, and maps. About 75 water analyses selected from the literature are tabulated to illustrate the relationships described, and some of these, along with many others that are not tabulated, are also utilized in demonstrating graphing and mapping techniques. Relationships of water composition to source rock type are illustrated by graphs of some of the tabulated analyses. Activities of man may modify water composition extensively through direct effects of pollution and indirect results of water development, such as intrusion of sea water in ground-water aquifiers. Water-quality standards for domestic, agricultural, and industrial use have been published by various agencies. Irrigation project requirements for water quality are particularly intricate. Fundamental knowledge of processes that control natural water composition is required for rational management of water quality.

Water Supply Paper↗

USGS1959

Study and interpretation of the chemical characteristics of natural water

Water Supply Paper↗