SEARCH · USGS Science

Results for “Atmosphere”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,603 records · Page 89Linked to original sources

USGS2022

Response in the water level of Anvil Lake, Wisconsin, to changes in meteorological and climatic changes, Wisconsin

Anvil Lake, a relatively shallow seepage lake in northern Wisconsin, USA, has experienced dramatic changes in water level since elevation records began in 1938 in response to changes in meteorological and climatic conditions (Figure 1. Robertson et al., 2018). Anvil Lake’s water level record shows a pronounced 10–15-yr cycle, with recurring highs and lows with a typical swing of over 1 m. Although experiencing large cycles in water levels, the long-term average levels were relatively stable until about 1987, when water level dropped dramatically by an additional 1 m (in 2016). Water levels then rebounded dramatically, reaching near “normal” water levels in 2020. At its lowest level, the lake had a maximum depth of 8.2 m (mean depth of 4.7 m) and an area of 128 ha. Like most long-term records, Anvil Lake’s water level record has been measured by several observers using various techniques. To verify the consistency of the various datums used throughout this period, historical photographs with the water’s edge identified were obtained, tied to NAVD 1988 using a Real Time Kinematic satellite global positioning system, and compared with the measured water levels (See Figure 1). To determine the causes of the changes in water level, a complete water budget was estimated for Anvil Lake from 1980 to 2014. Water levels in Anvil Lake were simulated (Figure 1) using a hydrodynamic model (General Lake Model, GLM), with daily lake evaporation estimated by GLM, monthly lake/groundwater exchange estimated with a groundwater model (MODFLOW), daily precipitation from the North American Land Data Assimilation System (NLDAS), and stream inflow and outflow were set as zero because the lake has no inlets or outlet. Atmospheric fluxes (precipitation minus evaporation) primarily drove the lake-level fluctuations and trends, but sub-decadal fluctuations in net groundwater exchange (groundwater inflow minus lake seepage) either enhanced or reduced the lake level response to the atmospheric drivers. The changes in water levels were shown to affect the extent of stratification and water quality in the lake (Robertson et al., 2018). During periods of lower precipitation and lower water levels, Anvil Lake was a polymictic lake, whereas during periods of higher precipitation and higher water levels the lake was a dimictic lake with stratification lasting throughout summer. During periods with higher water levels, the water quality in the lake was shown to improve slightly as a result of the nutrients being diluted in a larger volume of water. If precipitation increases in the future, as results from many General Circulation Models (GCMs) suggest (Robertson et al., 2016), and if that outweighs the effects of increased evaporation caused by increased air temperatures, water levels in Anvil Lake may be expected to fluctuate at a higher level. Higher water levels in Anvil Lake are expected to result in the lake becoming more strongly stratified and have slightly improved water quality (lower nutrient and algal concentrations and increased water clarity) (Robertson et al., 2018).

Wisconsin↗

USGS2020

He-CO2-N2 isotope and relative abundance characterization of geothermal fluids from the Ethiopian Rift

We report He-CO 2 -N 2 isotopic and relative abundances in free gases and dissolved gas phase of geothermal fluids from the Ethiopian Rift. Fluid samples were collected from ~30 geothermal localities from three key regions throughout rifted and non-rifted areas of Ethiopia. The majority of samples, including off-rift samples, indicate a strong contribution of mantle-derived He-C-N to the fluid samples. Helium ( 3 He/ 4 He) and δ15N-(N 2 ) isotope anomalies are highest (> 15.9RA and > +5.0‰, respectively) at a single locality in south Afar (Sodere), but the maximum δ13C-(CO 2 ) (-0.78‰) is found east of Lake Shalla in the Lake District of the Main Ethiopian Rift. High 3 He/ 4 He values, consistent with mantle plume contributions, are also evident in fluids from the Lake District, where fluids from the Lake Shalla site extend up to 15.5RA. CO 2 / 3 He values span over four orders of magnitude while δ13C-(CO 2 ) values cluster mostly between mantle-like values of -4 and -7‰; only samples east of Lake Shalla display more positive values. Atmospheric-derived nitrogen has likely influenced a number of measured δ15N-(N 2 ) values but following a correction for atmospheric-contamination, the majority of samples reveal positive values (up to 6.5‰) which appear to be coupled to high 3 He/ 4 He values. In regions affected by upwelling mantle plumes, such high values have been interpreted to reflect deep mantle inputs of recycled nitrogen.

Ethiopian Rift↗

USGS2011

Land cover change, biogeochemical modelling of carbon stocks, and climate change in West Africa

The carbon in ecosystems exists in dynamic soil and vegetation pools which vary in amounts and cycle with the global atmosphere at varying rates. These stocks and fluxes play important roles in global carbon regulation and in the maintenance of goods and services. Changes in land cover or ecosystems result in increased or decreased fluxes to the atmosphere and play a major role in climate regulation. Carbon in soil is closely coupled to soil nitrogen and the continued mining of soil for crops or fuel without replenishment of nutrients results in decreased productivity and impacts food security. The assessment of these processes across large areas, although difficult, is aided by the integration of simulation modelling (biogeochemical and ecosystem) and remote sensing. We acquired satellite imagery for four periods from the 1960s to 2000s, trained environmental scientists from 14 countries on image analysis and interpretation, and now report systematic analyses of land cover changes in select countries of West Africa and quantify potential impacts of climate change and management at specific sites. Statistical changes and maps of land cover are documented for most countries. Senegal, for example, illustrates a 57 percent loss in dense forests between 1975 and 2000 with an even greater loss rate in the preceding 10 years. Bare soil increased 16.6 percent, often related to unproductive “badland” formation. Settlements increased 45.6 percent, and reforestation replaced bare sandy areas for sand dune stabilization. In some countries (Senegal and Ghana), the impact of these conversions and changes in land management and future projections has been incorporated into biogeochemical models to quantify carbon changes and project future carbon and crop scenarios. We present current assessments of carbon fluxes and the availability of data for these West African countries.

Conference Paper↗

USGS2007

Optimization of an ecosystem model through the assimilation of eddy flux observations using a smoothed ensemble Kalman filter

The parameters of ecosystem models are conventionally optimized through nonsequential inversion methods, which treat observations as a whole and lack the flexibility to investigate possible temporal evolution of the model parameters. This research developed a smoothed ensemble Kalman filter (SEnKF) to assess to what extent the parameters and state variables of an ecosystem model can be simultaneously optimized through the assimilation of eddy flux observations. The performance of the SEnKF was demonstrated in one case study: the assimilation of measurements of carbon exchange between a mixed forest and the atmosphere at Niwot Ridge Forest (Colorado, USA) from 2000 to 2004 into a carbon flux partition model. Our analyses demonstrated that some model parameters, such as light use efficiency and respiration coefficients, were highly constrained by eddy flux data at daily to seasonal time scales. Light use efficiency was strongly seasonal. Model predictions based on parameters modified by the SEnKF were much improved, compared to predictions made without progressive data assimilation. The SEnKF reduced the variance of state variables that is caused by uncertainties of parameters and driving variables. The analysis of net ecosystem exchange of carbon between the forest and the atmosphere was improved.

Conference Paper↗

USGS2004

Global environmental databases from CEOS agencies

The Committee on Earth Observation Satellites (CEOS) is an international organization charged with coordinating international civil spaceborne missions designed to observe and study planet Earth. Comprising 44 space agencies and other national and international organizations, CEOS is recognized as the major international forum for the coordination of Earth observation satellite programs and for the interaction of these programs with users of satellite data worldwide. CEOS was created in 1984 in response to a recommendation from the Economic Summit of Industrialized Nations Working Group on Growth, Technology, and Employment’s Panel of Experts on Satellite Remote Sensing. This group recognized the multidisciplinary nature of satellite Earth observation and the value of coordination across all proposed missions. The CEOS members collect, maintain, apply, and make available data from space missions that encompass the atmospheric, terrestrial, and oceanographic fields. Collectively, these members possess petabytes of Earth observation data critical to understanding the Earth environment. Uses include monitoring oil slicks, evaluating human-induced changes to the atmosphere, determining mineral exploration areas, assessing the environmental effects of volcanic eruptions, measuring the growth of urban areas, determining where landscapes have changed because of urban growth trends, improving the efficiency of fishing as a world food stock, monitoring pest infestation, managing crop production, predicting climate and weather, and numerous other applications vital to industry, national infrastructures, and the world as a whole. The vast amount of satellite obtained, environmental data the CEOS members possess represents a fertile resource for researchers worldwide to exploit.

Conference Paper↗

USGS2023

Central Beaufort Sea Wave and Hydrodynamic Modeling Study; Report 2: Modeled waves, hydrodynamics, and sediment transport within Foggy Island Bay

Renewed interest in nearshore oil exploration and production in the shallow waters of the Central Beaufort Sea Shelf has created a need to advance our understanding of the past, current, and future atmospheric and oceanographic conditions that affect existing and planned infrastructure and nearshore ecosystems. At the time of writing this report, Hilcorp Alaska LLC has received BOEM approval for an oil and gas Development and Production Plan (DPP) that includes the construction of the Liberty Drilling Island (LDI) in Foggy Island Bay, situated within Stefansson Sound circa 30 km east of Prudhoe Bay (Figure 1.1). The aim of this study is to investigate how longer periods of open water (defined as < 15% ice cover), decreased sea ice cover, and changes in ocean and atmospheric conditions might affect wave and storm surge conditions, sediment transport patterns, and coastal erosion rates within Foggy Island Bay as well as the modeled influence of the offshore artificial island on sediment transport patterns.

Alaska↗

USGS2023

Central Beaufort Sea Wave and Hydrodynamic Modeling Study--Report 1: Field measurements and model development

Renewed interest in nearshore oil exploration and production in the shallow waters of the Central Beaufort Sea Shelf has created a need to advance our understanding of the past, current, and future atmospheric and oceanographic conditions that affect existing and planned infrastructure and nearshore ecosystems. At the time of writing this report, Hilcorp Alaska, LLC, has received BOEM approval for an oil and gas Development and Production Plan (DPP) that includes the construction of the Liberty Drilling Island (LDI) in Foggy Island Bay, situated within Stefansson Sound circa 30 km east of Prudhoe Bay (Figure 1.1). The aim of this study is to investigate how longer periods of open water (defined as < 15% ice cover), decreased sea ice cover, and changes in ocean and atmospheric conditions might affect wave and storm surge conditions, sediment transport patterns, and coastal erosion rates within Foggy Island Bay as well as the modeled influence of the offshore artificial island on sediment transport patterns.

Foggy Island Bay↗

USGS2003

Climate-change scenarios

Three procedures were used to develop a set of plausible scenarios of anthropogenic climate change by the year 2100 that could be posed to the sectors selected for assessment (Fig. 2.2). First, a workshop of climatologists with expertise in western North American climates was convened from September 10-12, 1998 at the National Center for Ecological Analysis and Synthesis in Santa Barbara, CA to discuss and propose a set of scenarios for the Rocky Mountain/Great Basin (RMGB) region. Secondly, the 20 th -century climate record was analyzed to determine what trends might have occurred during the period. Since CO2 and other greenhouse gases increased during the century, it was reasonable to examine whether the changes projected for the 21st century had begun to appear during the 20th, at least qualitatively though not quantitatively. Third, on the assumption of a two-fold increase in atmospheric CO 2 by 2100, climate-change scenarios for the 21 st century were projected with two, state-of-the-art computer models that simulate the complex interactions between earth, atmosphere, and ocean to produce the earth’s climate system. Each of the last two procedures has its strengths and weaknesses, and each can function to some degree as a check on the other. The historical analysis has the advantage of using empirical measurements of actual climate change taken over an extensive network of measuring stations. These make it possible to subdivide a large region like the RMGB into subreqions to assess the uniformity of climate and climate change over the region. And the historical measurements can to some degree serve as a check on the GCM simulations when the two are compared over the same time period.

Great Basin, Rocky Mountains↗

USGS1987

Variation of wet deposition chemistry in Sequoia National Park, California

Sequoia National Park has monitored wet deposition chemistry in conjunction with the National Atmospheric Deposition Program and National Trends Network (NADP/NTN), on a weekly basis since July, 1980. Annual deposition of H, NO 3 and SO 4 (0.045, 3.6, and 3.9 kg ha −1 a −1 , respectively) is relatively low compared to that measured in the eastern United States, or in the urban Los Angeles and San Francisco areas. Weekly ion concentrations are highly variable. Maximum concentrations of 324,162, and 156 μeq ol −1 of H, NO 3 and SO 4 have been recorded for one low volume summer storm (1.4 mm). Summer concentrations of NO 3 and SO 4 average two and five times higher, respectively, than concentrations reported for remote areas in the world. There is considerable variability in the ionic concentration of low volume samples, and much less variability in moderate and high volume samples.

California↗

USGS1988

Short-term trends in sulfate deposition at selected bulk precipitation stations in New York

Trends in rainfall-adjusted sulfate concentration were assessed for 5-yr subrecords of the 14.5–17 yr of monthly bulk-deposition data from five stations in New York by using the seasonal Kendall test. For the 5-yr subrecord from 1978 to 1982, the trends for the bulk deposition were similar to those for weekly wet-only deposition for adjacent stations of the National Atmospheric Deposition Program (NADP). The long-term trend at each of the bulk-precipitation sites was downward and statistically significant at P < 0.02, whereas 26% of the 69 subrecords had trends that were statistically significant only at P < 0.2. Of these statistically significant subrecord trends, 10% were positive (opposite to the long-term trend). Furthermore, the slopes of the subrecord trends tended to be much steeper than those of the whole record. These 5-yr trends, consequently, are poor indicators of the trends that occur over much longer periods in the same record.

New York↗

USGS1992

Variation of rock-forming metals in sub-annual increments of modern Greenland snow

Modern snowpack from central south Greenland was sampled in sub-seasonal increments and analysed for a suite of major, minor and trace rock-forming metals (K, Rb, Cs, Ca, Sr, Ba). There is a sharp seasonal concentration maximum for all six metals that comes in summer, later than mid-June. Metal concentrations in all other parts of the year's snowpack are up to 10 or more times smaller. The concentration maximum is preceded by low values in autumn-winter, very low values in early-mid-spring, and moderate-to-high values in late spring-early summer; this pattern is seen consistently in three-separate time stratigraphic intervals representing the same seasonal periods, spanning the time interval 1981–1984. The absolute concentration values of the snow strata representing the low-concentration portion of the year, autumn-winter-spring, may vary substantially from year to year, by a factor of two, or more. The finding that all rock-forming metals are at a sharp concentration maximum in late summer contrasts with the interpretations of several other studies in high-latitude northern regions. Those studies have reported a broad maximum of continental dust-associated metals in late winter and spring. However, samples of the other studies have mostly come from regions farther to the north, and the analyses have emphasized industrial pollutant metals rather than the matched rock-forming suite of the present study. The metals measured were chosen to give information about the origin and identity of the rock and soil dusts, and sea salts, present as impurities in the snow. Metal ratios indicate that the dusts in the snowpacks are of continental origin and from ferromagnesian rocks. Source rock types for dusts in central south Greenland snow contrast with the felsic rock dusts of the Sierra Nevada, CA, annual snowpacks, and with the very felsic rock dusts in large south central Alaskan mountain glaciers. Samples in which masses of sea salt are much larger than those of rock dusts may be identified by small changes in metal ratios caused by moderate increases of K and Ca from marine sources, nearly unaccompanied by the minor and trace metals Rb, Cs and Ba, that are very rare in the oceans. A sampling frequency, such as that of the present study, that divides a year's accumulation into 8–10 subsamples is sufficient to reveal details of the time pattern of variation in proportions and concentrations of metals that give information about atmospheric deposition of important types of earth materials.

Atmospheric Environment - Part A General Topics↗

USGS1995

A possible deficiency in estimates of wet deposition obtained from data generated by the NADP/NTN network

A conventional precipitation scavenging model is used to evaluate the effect of the performance of a wet-deposition collector on the reported deposition amounts. Three National Atmospheric Deposition Program/National Trends Network sites in semi arid western Colorado were chosen to evaluate chloride and sulfate wet deposition. Observations of the performance of a wet-deposition collector have demonstrated a delay in opening and cycling during a precipitation event. A significant fraction of wet deposition may be excluded when small amounts of initial precipitation are not sampled and a potentially large fraction of annual wet deposition may be excluded if a majority of precipitation events are small. The actual amount missed depends on the precipitation intensity, variability of intensity with time, raindrop or snowflake size and the individual performance characteristics of the collector. Detailed performance data are needed for individual wet-deposition collectors before accurate estimates of wet deposition can be expected.

Atmospheric Environment↗

USGS2007

Feasibility of a simple laboratory approach for determining temperature influence on SPMD–air partition coefficients of selected compounds

Semipermeable membrane devices (SPMDs) are a widely used passive sampling methodology for both waterborne and airborne hydrophobic organic contaminants. The exchange kinetics and partition coefficients of an analyte in a SPMD are mediated by its physicochemical properties and certain environmental conditions. Controlled laboratory experiments are used for determining the SPMD–air ( K sa 's) partition coefficients and the exchange kinetics of organic vapors. This study focused on determining a simple approach for measuring equilibrium K sa 's for naphthalene (Naph), o -chlorophenol ( o -CPh) and p -dichlorobenzene ( p -DCB) over a wide range of temperatures. SPMDs were exposed to test chemical vapors in small, gas-tight chambers at four different temperatures (−16, −4, 22 and 40 °C). The exposure times ranged from 6 h to 28 d depending on test temperature. K sa 's or non-equilibrium concentrations in SPMDs were determined for all compounds, temperatures and exposure periods with the exception of Naph, which could not be quantified in SPMDs until 4 weeks at the −16 °C temperature. To perform this study the assumption of constant and saturated atmospheric concentrations in test chambers was made. It could influence the results, which suggest that flow through experimental system and performance reference compounds should be used for SPMD calibration.

Atmospheric Environment↗

USGS2011

Short-term nitrogen additions can shift a coastal wetland from a sink to a source of N 2 O

Coastal salt marshes sequester carbon at high rates relative to other ecosystems and emit relatively little methane particularly compared to freshwater wetlands. However, fluxes of all major greenhouse gases (N 2 O, CH 4 , and CO 2 ) need to be quantified for accurate assessment of the climatic roles of these ecosystems. Anthropogenic nitrogen inputs (via run-off, atmospheric deposition, and wastewater) impact coastal marshes. To test the hypothesis that a pulse of nitrogen loading may increase greenhouse gas emissions from salt marsh sediments, we compared N 2 O, CH 4 and respiratory CO 2 fluxes from nitrate-enriched plots in a Spartina patens marsh (receiving single additions of NaNO 3 equivalent to 1.4 g N m −2 ) to those from control plots (receiving only artificial seawater solutions) in three short-term experiments (July 2009, April 2010, and June 2010). In July 2009, we also compared N 2 O and CH 4 fluxes in both opaque and transparent chambers to test the influence of light on gas flux measurements. Background fluxes of N 2 O in July 2009 averaged −33 μmol N 2 O m −2 day −1 . However, within 1 h of nutrient additions, N 2 O fluxes were significantly greater in plots receiving nitrate additions relative to controls in July 2009. Respiratory rates and CH 4 fluxes were not significantly affected. N 2 O fluxes were significantly higher in dark than in transparent chambers, averaging 108 and 42 μmol N 2 O m −2 day −1 respectively. After 2 days, when nutrient concentrations returned to background levels, none of the greenhouse gas fluxes differed from controls. In April 2010, N 2 O and CH 4 fluxes were not significantly affected by nitrate, possibly due to higher nitrogen demands by growing S. patens plants, but in June 2010 trends of higher N 2 O fluxes were again found among nitrate-enriched plots, indicating that responses to nutrient pulses may be strongest during the summer. In terms of carbon equivalents, the highest average N 2 O and CH 4 fluxes observed, exceeded half the magnitude of typical daily net carbon sequestration rates by salt marshes. Thus, anthropogenic additions of nitrate to coasts can substantially alter N 2 O fluxes from marshes, although substantial temporal variation in these fluxes was observed. To better assess the climatic roles of salt marshes, greenhouse gas emissions need to be studied in the context of chronic nitrogen loads that impact many coastal ecosystems.

Atmospheric Environment↗

USGS2020

An overview of bioaerosol load and health impacts associated with dust storms: A focus on the Middle East

Dust storms are an important environmental problem worldwide. The main sources of dust storms include the Sahara, the Middle East, and central and northeastern Asia. Dust storms originating from these regions can be dispersed across oceans and in some cases globally. They occur throughout the year and vary in frequency and intensity. The biological agents (e.g., fungi, bacteria and viruses) and the mineral and chemical compositions of dust may have adverse effects on human health and quality of life. Desert dusts may cause respiratory diseases, cardiovascular diseases, cardiopulmonary diseases, mental health issues, injuries and death from transport accidents caused by poor visibility. This paper presents dust storm human health research conducted in the Middle East in both indoor and outdoor environments. Results illustrate that particle concentration and bioaerosol types in the atmosphere are affected by climate change and meteorological factors. Recent data trends indicate that annual dust aerosol concentrations have increased worldwide. According to studies conducted in the Middle East, the incidence of respiratory and cardiovascular mortality and hospital visits have increased dramatically following dust storm exposures but very few have demonstrated a regional causation. National and international collaborative efforts are needed to advance our understanding of the global implications of dust storms and what may be the most effective means of mitigation.

Middle East↗

USGS2021

Biological and chemical recovery of acidified Catskill Mountain streams in response to the Clean Air Act Amendments of 1990

Decades of acidic deposition have adversely affected aquatic and terrestrial ecosystems in acid-sensitive watersheds in parts of the eastern United States. The national Acid Rain Program (Title IV of the 1990 Clean Air Act Amendments - CAAA) helped reduce emissions of sulfur dioxide (SO 2 ) and nitrogen oxides (NO x ) and resulted in sharp decreases in the acidity of atmospheric deposition. The decrease in acidic deposition produced a steady decline in the acidity of streams in many poorly buffered waters across the western Adirondacks and parts of the Catskill Mountains of New York. Until recently, however, there has been little evidence of biological recovery in most acid-sensitive streams in both regions. Long-term deposition and stream-chemistry records and fish-community data from quantitative surveys done during 1991–93 and again during 2012–19 at 13 sites in the upper Neversink River and its tributaries were evaluated to determine if chemical and biological recovery were evident in this Catskill Mountain watershed and if they could be linked to regional declines in acidic deposition. Between 1991 and 2019, large decreases in sulfate and nitrate deposition in the basin mirrored declines in total nationwide SO 2 and NO x emissions. There were corresponding decreases in sulfate and nitrate concentrations in deposition at a National Trends Network station at Frost Valley (NY68) and coincident declines in sulfate concentrations at four long-term monitoring sites in the Neversink River watershed. Mean acid neutralizing capacity and pH increased and inorganic aluminum (Al i ) concentrations from routine summertime samples decreased significantly at most moderately to severely acidified sites between the two study periods. Richness, density, and biomass of fish communities increased at most sites, while the density and biomass of brook trout Salvelinus fontinalis populations increased at fewer sites that were undergoing chemical recovery. Although recovery is far from complete, trends in deposition chemistry, water quality, and fish assemblages in streams of the upper Neversink watershed indicate that the 1990 CAAA is having positive impacts on aquatic ecosystems in the Catskill Mountain region, New York.

New York↗

USGS2009

In situ measurements of contributions to the global electrical circuit by a thunderstorm in southeastern Brazil

The global electrical circuit, which maintains a potential of about 280??kV between the earth and the ionosphere, is thought to be driven mainly by thunderstorms and lightning. However, very few in situ measurements of electrical current above thunderstorms have been successfully obtained. In this paper, we present dc to very low frequency electric fields and atmospheric conductivity measured in the stratosphere (30-35??km altitude) above an active thunderstorm in southeastern Brazil. From these measurements, we estimate the mean quasi-static conduction current during the storm period to be 2.5 ?? 1.25??A. Additionally, we examine the transient conduction currents following a large positive cloud-to-ground (+ CG) lightning flash and typical - CG flashes. We find that the majority of the total current is attributed to the quasi-static thundercloud charge, rather than lightning, which supports the classical Wilson model for the global electrical circuit.

Atmospheric Research↗

USGS2001

Use of stable sulfur isotopes to identify sources of sulfate in Rocky Mountain snowpacks

Stable sulfur isotope ratios and major ions in bulk snowpack samples were monitored at a network of 52 high-elevation sites along and near the Continental Divide from 1993 to 1999. This information was collected to better define atmospheric deposition to remote areas of the Rocky Mountains and to help identify the major source regions of sulfate in winter deposition. Average annual ??34S values at individual sites ranged from + 4.0 to + 8.2??? and standard deviations ranged from 0.4 to 1.6???. The chemical composition of all samples was extremely dilute and slightly acidic; average sulfate concentrations ranged from 2.4 to 12.2 ??eql-1 and pH ranged from 4.82 to 5.70. The range of ??34S values measured in this study indicated that snowpack sulfur in the Rocky Mountains is primarily derived from anthropogenic sources. A nearly linear relation between ??34S and latitude was observed for sites in New Mexico, Colorado, and southern Wyoming, which indicates that snowpack sulfate in the southern part of the network was derived from two isotopically distinct source regions. Because the major point sources of SO2 in the region are coal-fired powerplants, this pattern may reflect variations in the isotopic composition of coals burned by the plants. The geographic pattern in ??34S for sites farther to the north in Wyoming and Montana was much less distinct, perhaps rflecting the paucity of major point sources of SO2 in the northern part of the network.

Atmospheric Environment↗