Water-quality data-collection activities in Colorado and Ohio: Phase III-evaluation of existing data for use in assessing regional water-quality conditions and trends
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Estimation of the average annual rate of ground-water recharge to sand and gravel aquifers using elevated tritium concentrations in ground water is an alternative to traditional steady-state and water-balance recharge-rate methods. The concept of the tritium tracer method is that the average annual rate of ground-water recharge over a period of time can be calculated from the depth of the peak tritium concentration in the aquifer. Assuming that ground-water flow is vertically downward and that aquifer properties are reasonably homogeneous, and knowing the date of maximum tritium concentration in precipitation and the current depth to the tritium peak from the water table, the average recharge rate can be calculated. The method, which is a direct-measurement technique, was applied at two sites on Nantucket Island, Massachusetts. At site 1, the average annual recharge rate between 1964 and 1983 was 26.1 inches per year, or 68 percent of the average annual precipitation, and the estimated uncertainty is ?15 percent. At site 2, the multilevel water samplers were not constructed deep enough to determine the peak concentration of tritium in ground water. The tritium profile at site 2 resembles the upper part of the tritium profile at site 1 and indicates that the average recharge rate was at least 16 .7 inches per year, or at least 44 percent of the average annual precipitation. The Nantucket tritium recharge rates clearly are higher than rates determined elsewhere in southeastern Massachusetts using the tritium, water-table-fluctuation, and water-balance (Thornthwaite) methods, regardless of the method or the area. Because the recharge potential on Nantucket is so high (runoff is only 2 percent of the total water balance), the tritium recharge rates probably represent the effective upper limit for ground-water recharge in this region. The recharge-rate values used by Guswa and LeBlanc (1985) and LeBlanc (1984) in their ground-water-flow computer models of Cape Cod are 20 to 30 percent lower than this upper limit. The accuracy of the tritium method is dependent on two key factors: the accuracy of the effective-porosity data, and the sampling interval used at the site. For some sites, the need for recharge-rate data may require a determination as statistically accurate as that which can be provided by the tritium method. However, the tritium method is more costly and more time consuming than the other methods because numerous wells must be drilled and installed and because many water samples must be analyzed for tritium, to a very small level of analytical detection. For many sites, a less accurate, less expensive, and faster method of recharge-rate determination might be more satisfactory. The factor that most seriously limits the usefulness of the tritium tracer method is the current depth of the tritium peak. Water with peak concentrations of tritium entered the ground more than 20 years ago, and, according to the Nantucket data, that water now is more than 100 feet below the land surface. This suggests that the tracer method will work only in sand and gravel aquifers that are exceedingly thick by New England standards. Conversely, the results suggest that the method may work in areas where saturated thicknesses are less than 100 feet and the rate of vertical ground-water movement is relatively slow, such as in till and in silt- and clay-rich sand and gravel deposits.
Meteorologic and hydrologic data from five small watersheds in the coal areas of West Virginia were used to calibrate and test the U.S. Geological Survey Precipitation-Runoff Modeling System for simulating streamflow under various climatic and land-use conditions. Three of the basins--Horsecamp Run, Gilmer Run, and Collison Creek--are primarily forested and relatively undisturbed. The remaining basins--Drawdy Creek and Brier Creek-are extensively mined, both surface and underground above stream drainage level. Low-flow measurements at numerous synoptic sites in the mined basins indicate that coal mining has substantially altered the hydrologic system of each basin. The effects of mining on streamflow that were identified are (1) reduced base flow in stream segments underlain by underground mines, (2) increased base flow in streams that are downdip and stratigraphically below the elevation of the mined coal beds, and (3) interbasin transfer of ground water through underground mines. These changes probably reflect increased permeability of surface rocks caused by subsidence fractures associated with collapsed underground mines in the basin. Such fractures would increase downward percolation of precipitation, surface and subsurface flow, and ground-water flow to deeper rocks or to underground mine workings. Model simulations of the water budgets for the unmined basins during the 1972-73 water years indicate that total annual runoff averaged 60 percent of average annual precipitation; annual evapotranspiration losses averaged 40 percent of average annual precipitation. Of the total annual runoff, approximately 91 percent was surface and subsurface runoff and 9 percent was groundwater discharge. Changes in storage in the soil zone and in the subsurface and ground-water reservoirs in the basins were negligible. In contrast, water-budget simulations for the mined basins indicate significant differences in annual recharge and in total annual runoff. Model simulations of the water budget for Drawdy Creek basin indicate that total annual runoff during 1972-73 averaged only 43 percent of average annual precipitation--the lowest of all study basins; annual evapotranspiration losses averaged 49 percent, and interbasin transfer of ground-water losses averaged about 8 percent. Of the total annual runoff, approximately 74 percent was surface and subsurface flow and 26 percent was ground-water discharge. The low total annual runoff at Drawdy Creek probably reflects increased recharge of precipitation and surface and subsurface flow losses to ground water. Most of the increase in ground-water storage is, in turn, lost to a ground-water sink--namely, interbasin transfer of ground water by gravity drainage and (or) mine pumpage from underground mines that extend to adjacent basins. Hypothetical mining situations were posed for model analysis to determine the effects of increased mining on streamflow in the mined basins. Results of model simulations indicate that streamflow characteristics, the water budget, and the seasonal distribution of streamflow would be significantly modified in response to an increase in mining in the basins. Simulations indicate that (1) total annual runoff in the basins would decrease because of increased surface- and subsurface-flow losses and increased recharge of precipitation to ground water (these losses would tend to reduce medium to high flows mainly during winter and spring when losses would be greatest), (2) extreme high flows in response to intense rainstorms would be negligibly affected, regardless of the magnitude of mining in the basins, (3) ground-water discharge also would decrease during winter and spring, but the amount and duration of low flows during summer and fall would substantially increase in response to increased ground-water storage in rocks and in underground mines, and (4) the increase in ground-water storage in the basins would be depleted, mostly by increased losses to a grou
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The surface-water resources of the United States, the focal point for this National Water Summary, are extensively developed and managed to provide water supplies, hydroelectric power, navigation, recreational opportunities, and sufficient instream flows to maintain fish and wildlife habitats and adequate water quality. Surface water represents 77 percent of the Nation's total freshwater withdrawals, 65 percent of public supplies, 74 percent of self- supplied industries, excluding thermoelectric power generation, and 60 percent of irrigation. In only 10 States does surface water provide less than half of the total withdrawals.
Comparison of flow and chemical data collected at the principal inlet and at the outlets of Lake Ellynman urban lake in the Chicago metropolitan are--shows that detention storage alters the discharge and the quality of urban runoff. Peak water discharge and variation in the concentration of constituents transported by the runoff are usually reduced. Mass-balance relations based on comparison of measured constituent loads at the inlet and the outlets show that the lake is very efficient in trapping suspended solids, suspended sediment, and sediment-associated metals. Calculated trap efficiencies for many dissolved constituents were negative. However, negative efficiencies appear to be influenced mostly by insufficient sampling in winter. Trap efficiencies for nitrogen and phosphorus are intermediate to those determined for other constituents. Solids accumulate on the lake bottom as organic-rich muds that reduce lake storage and cover potential habitat for aquatic organisms. Lake sediments, particularly fine-grained sediments, have elevated concentrations of metals associated with them. Several organic compounds, not detected in inlet- or outlet-water samples, were detected in a lake-sediment sample collected near the inlet. Concentrations of many constituents dissolved in lake water are seasonally cyclic, with annual concentration peaks occurring during the winter. Establishment and maintenance of desirable benthic invertebrate and fish populations appear to be inhibited by sediment deposition.
Large volumes of ground water are contained in alluvial and bedrock aquifers in the semiarid Denver basin of eastern Colorado. The bedrock aquifer, for example, contains 1.2 times as much water as Lake Erie of the Great Lakes, yet it supplies only about 9 percent of the ground water used in the basin. Although this seems to indicate underutilization of this valuable water supply, this is not necessarily the case, for many factors other than the volume of water in the aquifer affect the use of the aquifer. Such factors as climatic conditions, precipitation runoff, geology and water-yielding character of the aquifers, water-level conditions, volume of recharge and discharge, legal and economic constraints, and water-quality conditions can ultimately affect the decision to use ground water. Knowledge of the function and interaction of the various parts of this hydrologic system is important to the proper management and use of the ground-water resources of the region. The semiarid climatic conditions on the Colorado plains produce flash floods of short duration and large peak-flow rates. However, snowmelt runoff from the Rocky Mountains produces the largest volumes of water and is typically of longer duration with smaller peak-flow rates. The alluvial aquifer is recharged easily from both types of runoff and readily stores and transmits the water because it consists of relatively thin deposits of gravel, sand, and clay located in the valleys of principal streams. The bedrock aquifer is recharged less easily because of its greater thickness (as much as 3,000 feet) and prevalent layers of shale which retard the downward movement of water in the formations. Although the bedrock aquifer contains more than 50 times as much water in storage as the alluvial aquifer, it does not store and transmit water as readily as the alluvial aquifer. For example, about 91 percent of the water pumped from wells is obtained from the alluvial aquifer, yet water-level declines generally have not exceeded 40 feet. By contrast, only 9 percent of the water pumped from wells is obtained from the bedrock aquifer, yet water-level declines in this aquifer have exceeded 500 feet in some areas. Depth to water in the alluvial aquifer generally is less than 40 feet, while depth to water in the bedrock aquifer may exceed 1,000 feet in some areas. Cost of pumping water to the surface and cost of maintaining existing supplies in areas of rapidly declining water levels in the bedrock aquifer affect water use. Water use is also affected by the generally poorer quality water found in the alluvial aquifer and, to a lesser extent, by the greater susceptibility of the alluvial aquifer to pollution from surface sources. Because of these factors, the alluvial aquifer is used primarily as a source of irrigation supply, which is the largest water use in the area. The bedrock aquifer is used primarily as a source of domestic or municipal supply, which is the smaller of the two principal uses, even though the bedrock aquifer contains 50 times more stored ground water than the alluvial aquifer.
This report documents the results of an analysis of the surface-water data network in Kansas for its effectiveness in providing regional streamflow information. The network was analyzed using generalized least squares regression. The correlation and time-sampling error of the streamflow characteristic are considered in the generalized least squares method. Unregulated medium-, low-, and high-flow characteristics were selected to be representative of the regional information that can be obtained from streamflow-gaging-station records for use in evaluating the effectiveness of continuing the present network stations, discontinuing some stations, and (or) adding new stations. The analysis used streamflow records for all currently operated stations that were not affected by regulation and for discontinued stations for which unregulated flow characteristics, as well as physical and climatic characteristics, were available. The State was divided into three network areas, western, northeastern, and southeastern Kansas, and analysis was made for the three streamflow characteristics in each area, using three planning horizons. The analysis showed that the maximum reduction of sampling mean-square error for each cost level could be obtained by adding new stations and discontinuing some current network stations. Large reductions in sampling mean-square error for low-flow information could be achieved in all three network areas, the reduction in western Kansas being the most dramatic. The addition of new stations would be most beneficial for mean-flow information in western Kansas. The reduction of sampling mean-square error for high-flow information would benefit most from the addition of new stations in western Kansas. Southeastern Kansas showed the smallest error reduction in high-flow information. A comparison among all three network areas indicated that funding resources could be most effectively used by discontinuing more stations in northeastern and southeastern Kansas and establishing more new stations in western Kansas.
A study was conducted to evaluate the effects of potential development of the Dakota aquifer on the layered-aquifer system above Permian rocks in a 5,000-square-mile area of southwestern Kansas. This aquifer system, which consists of five layers, includes the Cheyenne aquifer, the Kiowa confining unit, the Dakota aquifer, the Niobrara-Graneros confining unit, and the High Plains aquifer. Water supplies from the sandstone aquifers thus far have been developed mainly in parts of Hodgeman and Ford Counties. Management restrictions placed on further development of the High Plains aquifer could lead to additional development of the sandstone aquifers in the study area. The upper sandstone aquifer, the Dakota aquifer, consists of sandstone and shale of the Lower Cretaceous Dakota Sandstone and is as much as 400 feet thick. Transmissivity of the Dakota aquifer, determined from analyses of pumping tests, ranges from 100-7,100 feet squared per day. The Dakota aquifer is confined where it is overlain by the shales and limestones of the Upper Cretaceous Niobrara-Graneros confining unit, but locally it is unconfined. The lower sandstone aquifer, the Cheyenne aquifer, consists of the sandstone and shales of the Lower Cretaceous Cheyenne Sandstone in the eastern half of the study area plus undifferentiated Middle and Upper Jurassic rocks (sandstone, siltstone, shale, and limestone) in the western half of the study area. Maximum thickness of the Cheyenne aquifer is more than 300 feet, and maximum transmissivity is estimated at 3,000 feet squared per day. Estimated water use in the study area was about 8,800,000 acre-feet from the High Plains aquifer and about 160,000 acre-feet from the Dakota aquifer during 1975-82. The Cheyenne aquifer is not developed in the study area, and no water use from it is reported. The chemical characteristics of water in the sandstone aquifers are highly variable in the study area. Water in the Dakota aquifer is a calcium bicarbonate type water, similar to water in the High Plains aquifer, in the subcrop area. However, in areas distant from the subcrop, water in the Dakota aquifer is a sodium bicarbonate type water with dissolved-solids concentrations in excess of 500 milligrams per liter. In some parts of the study area, water from the Dakota presents high to very high salinity and sodium hazards to crops and soil when it is used for irrigation. The Cheyenne aquifer locally contains mineralized water, as indicated by the response of resistivity curves on geophysical logs. Hydrographs of wells completed in the Dakota aquifer indicate that the Dakota and High Plains aquifers are hydraulically connected in and near subcrop areas. Locally, the Dakota aquifer has converted from confined to unconfined conditions as a result of declining water levels due to pumpage from the Dakota aquifer and as the result of depletion of the High Plains aquifer in subcrop areas. Gradual declines in the potentiometric surface of the Dakota aquifer have occurred since the onset of pumpage in the 1960's; however, water levels in some wells have risen during the late 1970's. A digital computer model of three-dimensional groundwater flow was developed to simulate hydrologic conditions of a five-layer hydrologic system for 1975-82 conditions. The major components of the simulated 1975-82 water budget were well discharge from the High Plains aquifer and loss of ground water from storage in the High Plains aquifer. Although downward leakage from the High Plains aquifer in the study area represented only 18,000 acre-feet of the 1,365,000 acre-feet discharged from the High Plains aquifer during 1982, it was a major source of inflow to the Dakota aquifer. Changes in storage in the Dakota aquifer in the study area during 1982 were about 5,000 acre-feet. A baseline projection was made using 1982 simulated hydraulic heads from the calibrated model and 1982 rates of pumpage from both the High Plains and the Dakota aquifer
A deterministic precipitation-runoff model, the Precipitation-Runoff Modeling System, was applied in two small basins located in the Warrior coal field, Alabama. Each basin has distinct geologic, hydrologic, and land-use characteristics. Bear Creek basin (15.03 square miles) is undisturbed, is underlain almost entirely by consolidated coal-bearing rocks of Pennsylvanian age (Pottsville Formation), and is drained by an intermittent stream. Turkey Creek basin (6.08 square miles) contains a surface coal mine and is underlain by both the Pottsville Formation and unconsolidated clay, sand, and gravel deposits of Cretaceous age (Coker Formation). Aquifers in the Coker Formation sustain flow through extended rainless periods. Preliminary daily and storm calibrations were developed for each basin. Initial parameter and variable values were determined according to techniques recommended in the user's manual for the modeling system and through field reconnaissance. Parameters with meaningful sensitivity were identified and adjusted to match hydrograph shapes and to compute realistic water year budgets. When the developed calibrations were applied to data exclusive of the calibration period as a verification exercise, results were comparable to those for the calibration period. The model calibrations included preliminary parameter values for the various categories of geology and land use in each basin. The parameter values for areas underlain by the Pottsville Formation in the Bear Creek basin were transferred directly to similar areas in the Turkey Creek basin, and these parameter values were held constant throughout the model calibration. Parameter values for all geologic and land-use categories addressed in the two calibrations can probably be used in ungaged basins where similar conditions exist. The parameter transfer worked well, as a good calibration was obtained for Turkey Creek basin.
Water-quality records from two nationwide sampling networks are now of sufficient length to permit nationally consistent analysis of long-term water-quality trends at more than 300 locations on major U.S. rivers. Observed trends in 24 water-quality measures for the period 1974--81 provide evidence of both improvement and deterioration in stream quality during a time of major changes in atmospheric and terrestrial influences on surface waters. Particularly noteworthy are widespread decreases in lead and fecal bacteria concentrations and widespread increases in nitrate, arsenic, and cadmium concentrations. Changes in municipal waste treatment, leaded-gasoline consumption, highway-salt use, and nitrogen-fertilizer application, and regionally variable trends in coal production and combustion during the period, appear to be reflected in water-quality changes. There is evidence that atmospheric deposition of a variety of substances has played a surprisingly large role in water-quality changes.
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Streamflow on Long Island is derived principally from shallow ground water that flows above the deeper regional flow system. The movement of shallow ground water was studied during 1975-82 at Connetquot Brook, an undisturbed stream in Connetquot River State Park, in south-central Long Island, New York. The investigation encompassed (1) field studies of streamflow, ground-water levels, and age of water as indicated by tritium and dissolved-oxygen concentrations and (2) numerical simulation of the shallow flow system to evaluate the hydraulic factors that govern the direction of shallow ground-water flow near and beneath the stream. Analysis of water-level data indicates that ground water flows essentially horizontally throughout the drainage basin except near and beneath the stream, where it moves vertically upward toward the stream discharge boundary. Water levels in wells driven directly into the streambed and into the streambank at three sites were 1 to 2 feet higher than stream stage in the first 5 feet of penetration. Increases in head, which were detected to depths of 30 feet beneath the streambed, indicate upward movement of water above that depth. Hydraulic conductivity of the streambed sediments was calculated from head gradients in the streambed and from measured stream seepage; values were between 11 and 15 feet per day. Water samples from selected wells were analyzed for dissolved-oxygen and tritium concentrations to determine the relative age of the water in an attempt to locate the bottom boundary of the shallow flow system. Dissolved oxygen showed no pattern, but tritium concentrations about 1,000 feet from the stream were lower than those near the stream. The tritium concentrations indicate that the lower flow boundary was between 45 and 100 feet below the water table. A two-dimensional cross-sectional flow model of the shallow flow system was developed. The near-stream model response compared well with field data when the streambed discharge boundary was simulated as a uniform leaky bed. A systematic sensitivity analysis was done to determine which factors have the greatest influence on hydraulic head in the system. Ten dimensional parameters that describe the important aspects of the flow system were combined into a series of dimensionless parameters to simplify analysis. Results indicate that (1) streambed factors (width and hydraulic conductivity) are most influential upon heads near the stream, (2) factors representing thickness of the shallow flow system influence heads distant from the stream but have a negligible effect near the stream, and (3) factors that represent the quantity of water entering the system (recharge) influence the heads throughout the area. Field measurements of hydraulic head indicate that the thickness of the shallow flow system below the stream channel is about 30 feet. However, results of the sensitivity analysis indicate that the shallow system's thickness has a negligible effect on head distribution beneath the stream.
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Low-level radioactive solid waste has been buried in trenches at a site near Beatty, Nev., since 1962. In 1976, as part of a national program, the U.S. Geological Survey began a study of the geohydrology of the waste-burial site to provide a basis for estimating the potential for radionuclide migration in the unsaturated zone beneath the waste-burial trenches. Data collected include meteorological information for calibration of a long-term water-budget analysis, soil-moisture profiles, soil-water potentials, and hydraulic properties of representative unsaturated sediment samples to a depth of about 10 meters (m). The waste-burial facility is in the northern Amargosa Desert about 170 kilometers (km) northwest of Las Vegas, Nevo The region is arid; mean annual precipitation at Lathrop Wells, 30 km south of the site, is only 7.4 centimeters (cm). The mean daily maximum temperature at Lathrop Wells in July, the hottest month, is 37 ° C. The site is underlain by poorly stratified deposits of gravelly or silty sand and sandy gravel, and thick beds of clayey sediments. The total thickness of valley-fill deposits beneath the site is about 175 m; the unsaturated zone is about 85 m thick. Volumetric soil moisture to depths of 4 m ranges from 4 to 10 percent but commonly is in the range of 6 to 8 percent. Soil-water potential, measured to depths of 3 to 10 m, ranged from -10 to -70 bars. Unsaturated hydraulic conductivity computed from laboratory analyses of representative samples ranges from 10 -13 to 10 -14 centimeters per day (cm/d). Evaporation studies over a 2-year (yr) period were used to calibrate a numerical procedure for analyzing long-term precipitation data and estimating annual water budgets during the 15-yr period 1962-76. This analysis (1) demonstrated that a potential exists for deep percolation (greater than 2 m), despite high annual evaporation demands, and (2) provided predictions of the time of year and the antecedent conditions that enhance the probability of deep percolation. Soil-moisture profiles obtained monthly over an 18-month (mo) period demonstrate that deep percolation does occur. Soil-moisture conditions antecedent to an observed deep-percolation event, and the time of year when the percolation occurred, support the interpretations based on long-term meteorological records. Calculation of downward moisture movement through the waste-trench backfill material, on the basis of simplified assumptions, suggests that moisture could have penetrated as much as 6 m below land surface from 1963, when the oldest trenches were closed, to 1980, but that the moisture requirement for such penetration far exceeded the amount of moisture actually available. Steady-state downward movement of moisture at depths greater than 10 m and beneath the waste-burial trenches would be on the order of 4 cm per 1,000 yr, assuming a steady flux rate of 1x10 -5 cm/d.
Five principal creeks, First Creek, Second Creek, Wood Creek, Third Creek, and Incline Creek, having a cumulative drainage of 17.8 square miles, furnished a yearly average of about 15,000 acre-feet of runoff, mainly snowmelt, to Lake Tahoe during the 1970-73 water years. Annual runoff from the individual streams ranged from 460 to 7,070 acre-feet, and discharges ranged from 0.2 to 110 cubic feet per second. During the 4 years, the five streams delivered to Lake Tahoe 31,000 tons of sediment, which averaged about 75 percent gravel and sand, 15 percent silt, and 10 percent clay. Annual cumulative sediment load for the five creeks ranged from 1,500 to 11,000 tons; individual streams furnished 20 to 5,200 tons annually. Measured sediment transport at the stream mouths ranged from 1 to 13,200 milligrams per liter and from 0.001 to 1,420 tons per day; sediment concentrations up to 63,200 milligrams per liter were measured at upstream tributary sites. Estimated annual sediment yields of principal drainage basins ranged from 3 to 930 tons per square mile from undeveloped areas and from 26 to 5,000 tons per square mile from developed areas; yields for developed areas appeared to average about 10 times those of undeveloped areas, and roadways apparently were the major source. Erosion disequilibrium caused by prestudy flash floods on two of the creeks continues to manifest itself through high natural sediment yields. The Second Creek flood of 1967 yielded about 75,000 tons of sediment in one afternoon. Fluvial nutrient transport seems quantitatively related to magnitudes of sediment and water transport. Movement rates of organic nitrogen and particulate phosphorus were greater than rates of other nutrient species moving to the lake.