USGS Science⌕ Search

SEARCH · USGS Science

Results for “Groundwater”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,585 records · Page 88Linked to original sources

Chemical constituents in groundwater from multiple zones in the eastern Snake River Plain aquifer, Idaho National Laboratory, Idaho, 2009-13

From 2009 to 2013, the U.S. Geological Survey’s (USGS) Idaho National Laboratory (INL) Project office, in cooperation with the U.S. Department of Energy, collected water-quality samples from multiple water-bearing zones in the eastern Snake River Plain aquifer. Water samples were collected from 11 monitoring wells completed in about 250–750 feet of the upper part of the aquifer, and samples were analyzed for selected major ions, trace elements, nutrients, radiochemical constituents, and stable isotopes. Each well was equipped with a multilevel monitoring system containing four to seven sampling ports that were each isolated by permanent packer systems. The sampling ports were installed in aquifer zones that were highly transmissive and that represented the water chemistry of the top three to five model layers of a steady-state and transient groundwater‑flow model. The groundwater-flow model and water chemistry are being used to better define movement of wastewater constituents in the aquifer. The water-chemistry composition of all sampled zones for the five new multilevel wells is calcium plus magnesium bicarbonate. One of the zones in well USGS 131A has a slightly different chemistry from the rest of the zones and wells and the difference is attributed to more wastewater influence from the Idaho Nuclear Technology and Engineering Center. One well, USGS 135, was not influenced by wastewater disposal and consisted of mostly older water in all of its zones. Tritium concentrations in relation to basaltic flow units indicate the presence of wastewater influence in multiple basalt flow groups; however, tritium is most abundant in the South Late Matuyama flow group in the southern boundary wells. The concentrations of wastewater constituents in deep zones in wells Middle 2051, USGS 132, USGS 105, and USGS 103 support the concept of groundwater flow deepening in the southwestern corner of the INL, as indicated by the INL groundwater-flow model.

Idaho↗

Spatially distributed groundwater recharge for 2010 land cover estimated using a water-budget model for the Island of O‘ahu, Hawai‘i

Owing mainly to projected population growth, demand for freshwater on the Island of Oʻahu is expected to increase by about 26 percent between 2010 and 2030, according to the City and County of Honolulu. Estimates of groundwater recharge are needed to evaluate the availability of fresh groundwater. For this study, a water-budget model with a daily computation interval was developed and used to estimate the spatial distribution of recharge on Oʻahu for average climate conditions (1978–2007 rainfall and 2010 land cover) and for drought conditions (1998–2002 rainfall and 2010 land cover). For average climate conditions, mean annual recharge for Oʻahu is about 660 million gallons per day, or about 36 percent of precipitation (rainfall and fog interception). Recharge for average climate conditions is about 34 percent of total water inflow, which consists of precipitation, irrigation, septic leachate, water-main leakage, and seepage from reservoirs and cesspools. Recharge is high along the crest of the Koʻolau Range, reaching as much as about 180 inches per year in the north-central part of the range. Recharge is much lower outside of the mountainous areas of the island, commonly less than 5 inches per year in unirrigated areas. The island-wide estimate of groundwater recharge for average climate conditions from this study is within 1 percent of the recharge estimate used in the 2008 State of Hawaiʻi Water Resource Protection Plan, which divides the Island of Oʻahu into 23 aquifer systems for groundwater management purposes. To facilitate direct comparisons with this study, these 23 aquifer systems were consolidated into 21 aquifer systems. Recharge estimates from this study are higher for 12 of the aquifer-system areas and lower for 9. Differences in mean rainfall distribution and the inclusion of irrigation in this study are the primary reasons for discrepancies in recharge estimates between this study and the 2008 Hawaiʻi Water Resources Protection Plan. For drought conditions, mean annual recharge for Oʻahu is about 417 million gallons per day, which is about 37 percent less than recharge for average climate conditions. For individual aquifer-system areas, recharge for drought conditions is about 25 to 70 percent less than recharge for average climate conditions.

Hawai'i↗

Multilevel groundwater monitoring of hydraulic head and temperature in the eastern Snake River Plain aquifer, Idaho National Laboratory, Idaho, 2011-13

From 2011 to 2013, the U.S. Geological Survey’s Idaho National Laboratory (INL) Project Office, in cooperation with the U.S. Department of Energy, collected depth-discrete measurements of fluid pressure and temperature in 11 boreholes located in the eastern Snake River Plain aquifer. Each borehole was instrumented with a multilevel monitoring system (MLMS) consisting of a series of valved measurement ports, packer bladders, casing segments, and couplers. Multilevel monitoring at the INL has been ongoing since 2006 and this report summarizes data collected from 2011 to 2013 in 11 multilevel monitoring wells. Hydraulic head (head) and groundwater temperature data were collected from 11 multilevel monitoring wells, including 177 hydraulically isolated depth intervals from 448.0 to 1,377.6 feet below land surface. One port (port 3) within borehole USGS 134 was not monitored because of a valve failure. Head and temperature profiles reveal unique patterns for vertical examination of the aquifer’s complex basalt and sediment stratigraphy, proximity to aquifer recharge and discharge, and groundwater flow. These features contribute to some of the localized variability even though the general profile shape remained consistent over the period of record. Twenty-two major head inflections were described for 9 of 11 MLMS boreholes and almost always coincided with low‑permeability sediment layers and occasionally thick layers of dense basalt. However, the presence of a sediment layer or dense basalt layer was insufficient for identifying the location of a major head change within a borehole without knowing the true areal extent and relative transmissivity of the lithologic unit. Temperature profiles for boreholes completed within the Big Lost Trough indicate linear conductive trends; whereas, temperature profiles for boreholes completed within volcanic rift zones and near the southern boundary of the Idaho National Laboratory, indicate mostly convective heat transfer. Select boreholes along the southern boundary show a temperature reversal and cooler water deeper in the aquifer resulting from the vertical movement of groundwater. Vertical head and temperature change were quantified for each of the 11 multilevel monitoring systems. Vertical head gradients defined for the major inflections in the head profiles were as high as 2.9 feet per foot. In general, fractured basalt zones displayed relatively small vertical head differences and show a high occurrence within volcanic rift zones. Poor connectivity between fractures and higher vertical gradients were generally attributed to sediment layers and layers of dense basalt, or both. Groundwater temperatures in all boreholes ranged from 10.8 to 16.3 °C. Normalized mean head values were analyzed for all 11 multilevel monitoring wells for the period of record (2007–13). The mean head values suggest a moderately positive correlation among all boreholes and generally reflect regional fluctuations in water levels in response to seasonal climatic changes. Boreholes within volcanic rift zones and near the southern boundary (USGS 103, USGS 105, USGS 108, USGS 132, USGS 135, USGS 137A) display a temporal correlation that is strongly positive. Boreholes in the Big Lost Trough display some variations in temporal correlations that may result from proximity to the mountain front to the northwest and episodic flow in the Big Lost River drainage system. For example, during June 2012, boreholes MIDDLE 2050A and MIDDLE 2051 showed head buildup within the upper zones when compared to the June 2010 profile event, which correlates to years when surface water was reported for the Big Lost River several months preceding the measurement period. With the exception of borehole USGS 134, temporal correlation between MLMS wells completed within the Big Lost Trough is generally positive. Temporal correlation for borehole USGS 134 shows the least agreement with other MLMS boreholes located within the Big Lost Trough; however, borehole USGS 134 is close to the mountain front where tributary valley subsurface inflow is suspected.

Idaho↗

Median nitrate concentrations in groundwater in the New Jersey Highlands Region estimated using regression models and land-surface characteristics

Nitrate-concentration data are used in conjunction with land-use and land-cover data to estimate median nitrate concentrations in groundwater underlying the New Jersey (NJ) Highlands Region. Sources of data on nitrate in 19,670 groundwater samples are from the U.S. Geological Survey (USGS) National Water Information System (NWIS) and the NJ Private Well Testing Act (PWTA). In a study conducted by the USGS, in cooperation with the New Jersey Department of Environmental Protection, logistic regression was used to relate measured nitrate concentrations to five explanatory variables (percent urban and agricultural land use, septic-system density, total length of streams, and number of known contaminated sites) quantified in 610-meter-square grid cells. A method for calculating the median concentrations of nitrate from a series of logistic regression models was developed. Two calibration and two validation procedures showed that the logistic-regression-based method can estimate groundwater-nitrate concentrations in the Highlands Region accurately to within 0.1 milligram per liter as nitrogen (mg/L as N). Limitations of the logistic-regression-based method include the inability to select a logistic model with exactly 0.5 probability of exceeding the threshold value and lack of an algorithm to directly calculate the median value. Quantile regression was evaluated as a suitable alternative and was slightly less accurate than the logistic-regression method in estimating median groundwater nitrate concentrations in the Highlands Region. Multiple-linear regression with log-transformed nitrate-concentration data and the same five explanatory values was less accurate than either logistic or quantile regression in estimating median nitrate concentrations. On the basis of 4,516 2000 x 2000 foot grid cells that contain wells with data stored in NWIS and the PWTA database, the estimated median nitrate concentration for the entire Highlands Region is about 1.25 mg/L as N, and estimated median concentrations range from about 1.05 to 1.78 mg/L as N among 11 smaller administratively defined areas within the Highlands Region that vary in percentages of urban land use, agricultural land use, and septic-system density. The Kaplan-Meier method of estimating summary statistics from left-censored data was applied in order to include nondetects (left-censored data) in median nitrate-concentration calculations. Median concentrations also were determined using three alternative methods of handling nondetects. Treatment of the 23 percent of samples that were nondetects had little effect on estimated median nitrate concentrations because method detection limits were mostly less than median values.

New Jersey↗

Concentration comparison of selected constituents between groundwater samples collected within the Missouri River alluvial aquifer using purge and pump and grab-sampling methods, near the city of Independence, Missouri, 2013

The U.S. Geological Survey, in cooperation with the City of Independence, Missouri, Water Department, has historically collected water-quality samples using the purge and pump method (hereafter referred to as pump method) to identify potential contamination in groundwater supply wells within the Independence well field. If grab sample results are comparable to the pump method, grab samplers may reduce time, labor, and overall cost. This study was designed to compare constituent concentrations between samples collected within the Independence well field using the pump method and the grab method. Relative percent differences between environmental grab and duplicate grab samples were greater than 10 percent for 80 percent of the constituents. Duplicate grab samples were collected by tethering two grab samplers together, because the amount of water collected by each grab sampler is close to the amount necessary for analysis. The screened interval lengths of monitoring wells within the Independence well field is not conducive to collecting multiple grab samples by tethering samplers. The inability to collect required duplicate quality assurance samples may limit the use of grab samplers. Concentrations between pump and grab samples were similar for analyzed nutrient species, the variability between methods was less than the variability between historical duplicate samples, and there were no significant differences determined. Major ion relative percent differences were less than 10 percent and root mean square error differences between methods and between historical duplicate samples were less than 1 milligram per liter with the exception of sulfate. Statistically significant differences were determined between pump and grab samples for sodium and fluoride. There is a strong association between major ion pump and grab samples based on bivariate plots and simple linear regressions. Variability between pump and grab samples of analyzed nutrients and major ions may have minimal effect on the ability to monitor temporal changes and potential groundwater contamination threats. Relative percent differences between methods were greater than 10 percent for most analyzed trace elements. Barium, cobalt, manganese, and boron had concentrations that were significantly different between sampling methods. Barium, molybdenum, boron, and uranium method concentrations indicate a close association between pump and grab samples based on bivariate plots and simple linear regressions. Grab sample concentrations were generally larger than pump concentrations for these elements and may be because of using a larger pore sized filter for grab samples. Analysis of zinc blank samples suggests zinc contamination in filtered grab samples. Variations of analyzed trace elements between pump and grab samples could reduce the ability to monitor temporal changes and potential groundwater contamination threats. The degree of precision necessary for monitoring potential groundwater threats and application objectives need to be considered when determining acceptable variation amounts.

Missouri↗

Groundwater-level change and evaluation of simulated water levels for irrigated areas in Lahontan Valley, Churchill County, west-central Nevada, 1992 to 2012

The acquisition and transfer of water rights to wetland areas of Lahontan Valley, Nevada, has caused concern over the potential effects on shallow aquifer water levels. In 1992, water levels in Lahontan Valley were measured to construct a water-table map of the shallow aquifer prior to the effects of water-right transfers mandated by the Fallon Paiute-Shoshone Tribal Settlement Act of 1990 (Public Law 101-618, 104 Stat. 3289). From 1992 to 2012, approximately 11,810 water-righted acres, or 34,356 acre-feet of water, were acquired and transferred to wetland areas of Lahontan Valley. This report documents changes in water levels measured during the period of water-right transfers and presents an evaluation of five groundwater-flow model scenarios that simulated water-level changes in Lahontan Valley in response to water-right transfers and a reduction in irrigation season length by 50 percent. Water levels measured in 98 wells from 2012 to 2013 were used to construct a water-table map. Water levels in 73 of the 98 wells were compared with water levels measured in 1992 and used to construct a water-level change map. Water-level changes in the 73 wells ranged from -16.2 to 4.1 feet over the 20-year period. Rises in water levels in Lahontan Valley may correspond to annual changes in available irrigation water, increased canal flows after the exceptionally dry and shortened irrigation season of 1992, and the increased conveyance of water rights transferred to Stillwater National Wildlife Refuge. Water-level declines generally occurred near the boundary of irrigated areas and may be associated with groundwater pumping, water-right transfers, and inactive surface-water storage reservoirs. The largest water-level declines were in the area near Carson Lake. Groundwater-level response to water-right transfers was evaluated by comparing simulated and observed water-level changes for periods representing water-right transfers and a shortened irrigation season in areas near Fallon and Stillwater, Nevada. In the Stillwater modeled area, water rights associated with nearly 50 percent of the irrigated land were transferred from 1992 to 1998, represented by the model scenario reduction in groundwater recharge by 50 percent. The scenario resulted in a simulated average decline of 0.6 foot; average observed water-level change for the modeled area was estimated to be 0.0 foot, or no change. In the Fallon modeled area, transfers of water rights associated with 180 acres of land occurred from 1994 to 2008. The transfer is most similar to the scenario for removal of 320 acres of irrigated land. The model scenario resulted in simulated water-level declines of 0.1; water levels measured from 1994 to 2012 indicate no significant trends in water levels, or approximately zero change in water levels, for the Fallon modeled area. The model scenarios included the simulation of a irrigation season shortened by 50 percent, which was determined to have occurred in the 1992 irrigation season in both modeled areas. The shortening of the irrigation season in the Fallon modeled area resulted in simulated water-level declines of 1.1 feet; observed declines were estimated to be 1.3 feet. The Stillwater model simulations resulted in a simulated decline of 1.4 feet, and observed water levels declined an estimated 2.3 feet for the area. The estimated difference between simulated and observed water levels are 0.2 and 0.9 foot for the Fallon and Stillwater modeled areas, respectively. Observed water-level changes were generally within one standard deviation of changes from model simulations, based on the selected periods of comparison. Simulated and observed water-level changes agree well, generally within 1 foot; however, the model scenarios were only approximately similar to the observed conditions, and periods of comparison were generally shorter for the observed periods and included additional cumulative effects of water-right transfers. Climate variability was not considered in the model scenarios.

Nevada↗

An update of the Death Valley regional groundwater flow system transient model, Nevada and California

Since the original publication of the Death Valley regional groundwater flow system (DVRFS) numerical model in 2004, more information on the regional groundwater flow system in the form of new data and interpretations has been compiled. Cooperators such as the Bureau of Land Management, National Park Service, U.S. Fish and Wildlife Service, the Department of Energy, and Nye County, Nevada, recognized a need to update the existing regional numerical model to maintain its viability as a groundwater management tool for regional stakeholders. The existing DVRFS numerical flow model was converted to MODFLOW-2005, updated with the latest available data, and recalibrated. Five main data sets were revised: (1) recharge from precipitation varying in time and space, (2) pumping data, (3) water-level observations, (4) an updated regional potentiometric map, and (5) a revision to the digital hydrogeologic framework model. The resulting DVRFS version 2.0 (v. 2.0) numerical flow model simulates groundwater flow conditions for the Death Valley region from 1913 to 2003 to correspond to the time frame for the most recently published (2008) water-use data. The DVRFS v 2.0 model was calibrated by using the Tikhonov regularization functionality in the parameter estimation and predictive uncertainty software PEST. In order to assess the accuracy of the numerical flow model in simulating regional flow, the fit of simulated to target values (consisting of hydraulic heads and flows, including evapotranspiration and spring discharge, flow across the model boundary, and interbasin flow; the regional water budget; values of parameter estimates; and sensitivities) was evaluated. This evaluation showed that DVRFS v. 2.0 simulates conditions similar to DVRFS v. 1.0. Comparisons of the target values with simulated values also indicate that they match reasonably well and in some cases (boundary flows and discharge) significantly better than in DVRFS v. 1.0.

California, Nevada↗

Extraction and development of inset models in support of groundwater age calculations for glacial aquifers

The U.S. Geological Survey developed a regional model of Lake Michigan Basin (LMB). This report describes the construction of five MODFLOW inset models extracted from the LMB regional model and their application using the particle-tracking code MODPATH to simulate the groundwater age distribution of discharge to wells pumping from glacial deposits. The five study areas of the inset model correspond to 8-digit hydrologic unit code (HUC8) basins. Two of the basins are tributary to Lake Michigan from the east, two are tributary to the lake from the west, and one is just west of the western boundary of the Lake Michigan topographic basin. The inset models inherited many of the inputs to the parent LMB model, including the hydrostratigraphy and layering scheme, the hydraulic conductivity assigned to bedrock layers, recharge distribution, and water use in the form of pumping rates from glacial and bedrock wells. The construction of the inset models entailed modifying some inputs, most notably the grid spacing (reduced from cells 5,000 feet on a side in the parent LMB model to 500 feet on a side in the inset models). The refined grid spacing allowed for more precise location of pumped wells and more detailed simulation of groundwater/surface-water interactions. The glacial hydraulic conductivity values, the top bedrock surface elevation, and the surface-water network input to the inset models also were modified. The inset models are solved using the MODFLOW–NWT code, which allows for more robust handling of conditions in unconfined aquifers than previous versions of MODFLOW. Comparison of the MODFLOW inset models reveals that they incorporate a range of hydrogeologic conditions relative to the glacial part of the flow system, demonstrated by visualization and analysis of model inputs and outputs and reflected in the range of ages generated by MODPATH for existing and hypothetical glacial wells. Certain inputs and outputs are judged to be candidate predictors that, if treated statistically, may be capable of explaining much of the variance in the simulated age metrics. One example of a predictor that model results indicate strongly affects simulated age is the depth of the well open interval below the simulated water table. The strength of this example variable as an overall predictor of groundwater age and its relation to other predictors can be statistically tested through the metamodeling process. In this way the inset models are designed to serve as a training area for metamodels that estimate groundwater age in glacial wells, which in turn will contribute to ongoing studies, under the direction of the U.S. Geological Survey National Water Quality Assessment, of contaminant susceptibility of shallow groundwater across the glacial aquifer system.

Illinois, Indiana, Michigan, Wisconsin↗

Preliminary groundwater salinity mapping near selected oil fields using historical water-sample data, central and southern California

The distribution of groundwater salinity was mapped for 31 oil fields and adjacent aquifers and summarized by 8 subregions across major oil-producing areas of central and southern California. The objectives of this study were to describe the distribution of groundwater near oil fields having total dissolved solids less than 10,000 milligrams per liter (mg/L) based on available data and to document where data gaps exist. Salinity was represented by the measured or calculated concentration of total dissolved solids (TDS) in samples of produced water obtained from petroleum wells and groundwater obtained from water wells. The water chemistry data were used to estimate the minimum depths of TDS greater than 3,000 mg/L and greater than 10,000 mg/L in areas near selected oil fields using historical water-chemistry data coupled with available well-location and construction information. The 10,000 mg/L threshold, representing the highest level of TDS concentration of water that could be considered as a potential source of drinking water, was present in all but 4 (Jasmin, Kern Bluff, Kern Front, and Mount Poso) of the 31 individual oil fields. Among petroleum wells, the median TDS concentration of produced water ranged from 500 mg/L for the Jasmin field to 32,636 mg/L for the Elk Hills field. Among water wells, median TDS concentrations, either reported or calculated from specific conductance, ranged from 151 mg/L for wells within 2 miles of the Ten Section field to 9,750 mg/L for wells within 2 miles of the combined North and South Belridge fields. In general, TDS across the eight geographic subregions increased with depth, but the relation of TDS with depth varied regionally. The most pronounced increases in TDS with depth were across the West Kern Valley Floor and West Kern Valley Margin subregions on the west side of the San Joaquin Valley, and in the vicinity of the Wilmington field in the Los Angeles Basin subregion; in these areas, relatively high TDS concentrations greater than 10,000 mg/L were present within the upper few hundred to several thousand feet of land surface. Total dissolved solids concentrations increased more gradually with depth in the Middle Kern Valley Floor subregion, in the South Kern Valley Margin subregion, in the vicinity of the Montebello and Santa Fe Springs fields in the Los Angeles Basin subregion, and in the Central Coast Basin subregion. The Kern Sierran Foothills and East Kern Valley Floor subregions, on the east side of the San Joaquin Valley, had the most gradual increases in TDS with depth. Fields in the East Kern Valley Floor subregion generally had groundwater and produced water with TDS less than 10,000 mg/L that extended to a large depth compared to most other subregions. Overall, the west side of the San Joaquin Valley in Kern County and the Wilmington field in Los Angeles County generally have the highest TDS values and the shallowest depths to high TDS. High TDS at relatively shallow depths on the west side of the San Joaquin Valley may be because of a combination of natural conditions and anthropogenic factors. In the vicinity of the Wilmington field in the Los Angeles Basin subregion, high TDS at relatively shallow depths is attributable at least in part to seawater intrusion. Fields on the east side of the San Joaquin Valley in Kern County have the lowest TDS and greatest depths to TDS greater than 10,000 mg/L because of their geologic setting adjacent to Sierra Nevada recharge areas. Reconnaissance salinity mapping was limited by several factors. The primary limitation was the lack of well-construction data for a significant number of water wells. Bottom perforation, well depth, or hole depth were not available for 35 percent of wells used for salinity mapping. A second limitation was variability in data quality. Total dissolved solids and specific conductance data were compiled from different data sources with varying degrees of documentation that ranged from comprehensive to very little or none. As a result, it was not always possible to assess the quality of the provided data with respect to either conditions at each well during sampling or the methodology used for sample collection and analysis. A third limitation was the lack of wells, either petroleum or water, and associated TDS data over large vertical intervals for some fields. As a result, the distribution of salinity and the depths at which TDS concentration exceeds the 3,000 and 10,000 mg/L thresholds could not always be precisely determined. This analysis highlights key gaps that need to be filled with additional analysis of other sources of information, such as borehole geophysical logs and new water sample or geophysical data collection.

California↗

Chemical and isotopic characteristics of methane in groundwater of Ohio, 2016

In 2016, the U.S. Geological Survey, in cooperation with the Ohio Water Development Authority, investigated the hydrogeologic setting, chemical and isotopic characteristics, and origin of methane in groundwater of Ohio. Understanding the occurrence and distribution of methane in groundwater is important in terms of public safety because methane in water wells can pose a risk of explosion. In addition, documenting the chemical and isotopic characteristics of methane in groundwater can make an important contribution to future stray gas investigations. Water samples were collected from 15 domestic water wells known to produce methane, which were in 12 counties in diverse parts of Ohio. The wells were 75–345 feet deep and tapped a range of aquifer types, including glacial deposits and bedrock of Upper Ordovician, Upper Devonian, Lower Mississippian, and Pennsylvanian ages. Although the hydrogeologic settings were varied, there was a broad similarity among the well sites in that the bedrock was predominantly shale and the glacial deposits were predominantly clay. The wells were sampled for dissolved inorganic constituents; dissolved organic carbon; methane and other dissolved gases; stable isotopes (carbon, hydrogen, and oxygen) of methane, water, and dissolved inorganic carbon; and carbon-14 of methane. Gas composition and stable isotopes of methane were used to differentiate thermogenic and microbial methane. The degree of fractionation of hydrogen and carbon isotopes was used to evaluate the pathway of microbial methanogenesis (carbon dioxide [CO 2 ] reduction or acetate fermentation) and the effects of secondary processes such as oxidation, mixing, and migration. The concentration of carbon-14 of methane was used to evaluate the relative age of the carbon source. The quality of water from the 15 wells differed greatly; water types ranged from CaMgHCO 3 to NaCl, and total dissolved solids concentrations ranged from 318 to 2,940 milligrams per liter (mg/L). Methane concentrations ranged from 1.2 to 120 mg/L. Of the 15 samples, 12 had methane concentrations greater than 28 mg/L, the level that can pose a risk of explosion. Of the 15 samples, 12 had chemical and isotopic characteristics or "signatures" consistent with microbial methane formed by CO 2 reduction. CO 2 reduction is commonly associated with microbial degradation of organic matter in anaerobic aquifers and with the formation of microbial shale gas and coalbed methane along margins of sedimentary basins. Two of 15 samples were interpreted as having a component of thermogenic methane based on the δ 13 C of methane (−50.96 and −47.74 parts per thousand [per mil]) and gas dryness (28 and 5). One of 15 samples (from the shallowest well) had chemical and isotopic characteristics consistent with methane oxidation by sulfate reduction based on light δ 13 C of dissolved inorganic carbon (−31.6 per mil) and evidence of sulfate reduction in terms of the odor and appearance of the water. For the 12 samples interpreted as microbial methane formed by CO 2 reduction, the δ 13 C of methane varied from −75 to −56 per mil. Multiple samples from the same aquifer demonstrated a general trend of increasing δ 13 C of methane with depth. Samples with lighter δ 13 C of methane (−75 to −62 per mil) were from shallower wells (or wells with shallow open intervals), and the isotopic signature of the water was consistent with modern or postglacial groundwater recharge. Three samples with heavier δ 13 C of methane (−61 to −56 per mil) were from deeper wells or more confined aquifers where the isotopic signature of water was consistent with older (glacial) recharge. In addition, δ 13 C of dissolved inorganic carbon was enriched (+12 to +18.9 per mil), and carbon-14 of methane was consistent with carbon associated with Paleozoic bedrock or older glacial deposits. These observations are generally consistent with increased Rayleigh-type fractionation at greater depths; however, other interpretations are possible. Isotopic signatures can be ambiguous, especially in areas with complex geologic histories that include multiple episodes of migration, mixing, and (or) oxidation. Many of the wells were in proximity to multiple potential natural and anthropogenic pathways of methane migration; however, it is not possible to determine if the methane in any of the wells is related to human activities based on the chemical and isotopic data collected for this study.

Ohio↗

Groundwater and surface-water resources near Red Fleet Reservoir, Uintah County, Utah

Red Fleet Reservoir in Uintah County, Utah, is an approximately 26,000 acre-foot (acre-ft) on-channel reservoir in the Big Brush Creek drainage on the south slopes of the Uinta Mountains. It is operated primarily for irrigation needs while providing a supplemental drinking-water supply to the Vernal, Utah area. Red Fleet Reservoir, which was operated by the Bureau of Reclamation and the Uintah Water Conservancy District through 2015, began storing water in May 1980. The reservoir is on southward dipping Mesozoic lithologies ranging from Jurassic to Cretaceous in age. The Nugget and Frontier Sandstone aquifers are the targeted units in this investigation, which is to characterize groundwater conditions that exist in each sandstone aquifer and how they interact with Red Fleet Reservoir. Groundwater levels were measured in six wells and one spring in the Nugget Sandstone and the Frontier Sandstone aquifers. Water levels in the Nugget Sandstone aquifer were 35–70 feet above the maximum stage of Red Fleet Reservoir on the west and east banks. Water levels in the Frontier Sandstone aquifer were 15–30 feet below the observed stage of Red Fleet Reservoir on the west bank during the study period. A water budget was calculated for Red Fleet Reservoir between May 1980 and December 2015. During this period, 1,050,000 acre-ft of water from Big Brush Creek discharged into the reservoir, while 993,000 acre-ft of water was released downstream of Red Fleet Dam. Total evaporation from May 1980 through December 2015 was about 52,000 acre-ft, while total precipitation over the same period was about 12,000 acre-ft. From May 1980 through December 2015, the total pumped volume of water from the Tyzack Pump Station, at the base of Red Fleet Dam, was about 42,000 acre-ft. Total groundwater discharge to Red Fleet Reservoir from 1980 through 2015 was about 40,000 acre-ft. Water was sampled from four wells and from the inflow arm of Red Fleet Reservoir, and analyzed for major-ion chemistry, select trace metals, nutrients, and environmental tracers. Water sampled from the Nugget Sandstone aquifer yielded good-quality water with dissolved-solids concentrations of less than 200 milligram per liter, and no trace elements above the Environmental Protection Agency drinking-water standards. Water sampled from the Frontier Sandstone aquifer yielded poor-quality water with dissolved-solids concentrations of about 2,150 milligrams per liter with trace elements approaching drinking-water standards for arsenic. Dissolved noble gases used to identify recharge elevations and temperatures for groundwater indicate that water in the Nugget Sandstone aquifer likely recharged at a high altitude and low temperature, and not locally because of interaction with Red Fleet Reservoir. The Frontier Sandstone aquifer is likely recharged at low elevation and at temperatures similar to those observed at Red Fleet Reservoir.

Utah↗

Effects of a crude-oil recovery remediation system operated 1999–2003 on groundwater plumes and unsaturated-zone vapor concentrations at a crude-oil spill site near Bemidji, Minnesota

A crude-oil spill occurred in 1979 when a pipeline burst near Bemidji, Minnesota. More than 70 percent of the 1.7 million liters of spilled crude oil was removed shortly thereafter. In response to a requirement by the State regulatory agency to remove the remaining crude to a sheen in all wells, in 1998, the pipeline company installed a dual-pump recovery system at the site. This additional remediation from 1999 to 2003 resulted in removal of about 115,000 liters of crude oil, representing between 36 and 41 percent of the volume of oil (281,000–317,000 liters) estimated to be present in 1998. Effects of the 1999–2003 remediation on groundwater plumes and unsaturated-zone vapor concentrations were evaluated by the U.S. Geological Survey using several methods including measurements of oil thicknesses in wells; field water-quality properties of dissolved oxygen, specific conductance, temperature, and pH in groundwater; and vapor concentrations of methane, carbon dioxide, nitrogen, and oxygen in the unsaturated zone. Although the recovery system decreased oil thicknesses near the remediation wells, average oil thicknesses measured in all wells at the site were not reduced substantially. Dissolved oxygen and specific conductance measurements indicate that a secondary plume was created during the remediation, caused by the disposal of pumped water from the remediation wells in an upgradient infiltration gallery. This plume expanded rapidly immediately after the start of the remediation in 1999, resulting in expansion of the anoxic zone of groundwater upgradient and beneath the existing natural attenuation plume. Beginning in 2000–1, for example, specific conductance concentrations noticeably increased in many wells at the north oil pool from about 400 to more than 700 microsiemens per centimeter. The rapid expansion of the anoxic and elevated specific conductance plume indicates that the remediation contributed substantial amounts of biodegradable dissolved organic carbon to groundwater through the infiltration gallery. The trends in vapor data collected before, during, and after the remediation generally support the research hypothesis that crude-oil removal would have an insignificant effect on vapor concentrations in the unsaturated zone. Although there were some small changes in the concentration of methane, carbon dioxide, nitrogen, and oxygen in the unsaturated zone, these changes were not coincident with the beginning or cessation of the remediation and are therefore thought to be the result of other factors affecting biodegradation rates. A decrease in methane concentrations in one representative well, for example, is thought to be the result of reduced rates of biodegradation and methane production from the increasingly more weathered crude oil. Oil-phase recovery at this site was determined to be challenging and resulted in considerable volumes of mobile and entrapped oil remaining in the subsurface despite remediation efforts.

Minnesota↗

Time-domain electromagnetic soundings and passive-seismic measurements for delineation of saline groundwater in the Genesee Valley-fill aquifer system, western New York, 2016–17

The U.S. Geological Survey, in cooperation with the New York State Department of Environmental Conservation, used noninvasive surface geophysics in the investigation of the distribution of saline groundwater in the valley-fill aquifer system of the Genesee River Valley near the former Retsof salt mine in western New York. In 1994, the Retsof salt mine, the largest of its kind in the western hemisphere, underwent a catastrophic roof collapse that resulted in groundwater inflow from the valley-fill aquifer system and bedrock fracture zones into the mine through two bedrock-rubble chimneys and the subsequent dissolution and filling of the mine with saturated brine. Since the early 2000s, except for a period of remedial pumping in 2006 to 2013, high-salinity water has migrated upward through the rubble chimneys into the basal part the aquifer system. The extent of saline-water migration within the aquifer system had not been evaluated since the end of remedial pumping when all the monitoring wells were grouted shut and abandoned. Installation of a monitoring-well network would be expensive and difficult given the thickness and heterogeneous character of valley fill. An investigation of the current extent of saline water in the aquifer system was warranted because the basal part of the aquifer is shallow to the north and it is used for water supply. In fall 2016 and fall 2017, the U.S. Geological Survey collected time-domain electromagnetic soundings at 105 sites along 13 cross-valley transects north and south of the mine-collapse area, east of Piffard, and on the Fowlerville Moraine. The time-domain electromagnetic soundings were colocated with passive-seismic measurements to estimate the bedrock-surface elevation through use of a regression equation developed from measurements at well sites with reported bedrock depths in the study area. An integrated analysis of the time-domain electromagnetic soundings with the depth-to-bedrock estimates, well logs, and past chloride-monitoring data suggests the presence of a zone of high electrical conductivity associated with saline water in the confined lower part of the valley-fill aquifer system. This high-salinity zone delineated in the lower confined aquifer extends from the mine-collapse area northward for more than 2.5 miles (4.0 kilometers). The chloride concentration in groundwater within this high-conductivity zone may be about 20,000 milligrams per liter. Saline water flowing upward through the bedrock-rubble chimneys and mixing with northward groundwater flow in the lower confined aquifer likely is a major source of chlorides for this high-conductivity zone. The northern extent of the zone is unclear because of the presence of highly saline water zones that were delineated by time-domain electromagnetic soundings in the lower confined aquifer and uppermost bedrock and are probably associated with historic salt-solution wells in Piffard or possibly sourced from natural brine pools.

New York↗

Assessment of well yield, dominant fractures, and groundwater recharge in Wake County, North Carolina

A cooperative study led by the U.S. Geological Survey and Wake County Environmental Services was initiated to characterize the fractured-rock aquifer system and assess the sustainability of groundwater resources in and around Wake County. This report contributes to the development of a comprehensive groundwater budget for the study area, thereby helping to enable resource managers to make sound and sustainable water-supply and water-use decisions. Construction information was used to analyze the well depth, casing depth, and reported well yield of more than 7,500 inventoried wells. The median well depth and casing depth were 265 feet (ft) below land surface (bls) and 68 ft bls, respectively, and the median well yield was 10 gallons per minute. Generally, well yield increased with depth to around 200 ft bls and then began to decrease with depth within the fractured-rock aquifer. Borehole geophysical logging methods were used to characterize the fractured-rock aquifer by mapping the orientation of geologic structures within the subsurface. Structure measurements were made on resulting log data and mapped to observed general spatial trends within the regional groundwater system and more distinct hydrogeologic units. Many of the fractures observed within the borehole logs are steeply dipping across Wake County, although open fractures with shallow dip angles were also observed in most rock classes. Regional geologic structural trends were observed in proximity to the Jonesboro Fault. Potential groundwater recharge in the study area was estimated using a Soil-Water-Balance (SWB) model, as well as using base flow hydrograph separation. The SWB model calculated net infiltration below the root zone for 1981 through 2019 for a 5,402-square-mile area that extends to the counties surrounding Wake County. The mean annual net infiltration rate for the 39-year period was about 8.6 inches per year for the study area. The mean annual net infiltration results from the SWB model were comparable to annual base flow estimates using the PART hydrograph-separation method at six U.S. Geological Survey streamgages within the study area. Mean annual base flow for all six drainage basins was near 7.5 inches per year and estimates ranged from 2.9 to 8.9 inches. Comparisons of mean annual potential recharge from the SWB model and base flow estimates were generally within 2 inches, except during high flows for most of the drainage basins in the study area.

North Carolina↗

Distribution of ancient carbon in groundwater and soil gas from degradation of petroleum near the Red Hill Bulk Fuel Storage Facility, O‘ahu, Hawai‘i

The groundwater below the Red Hill Bulk Fuel Storage Facility (the facility) in Oʻahu, Hawaiʻi, contains fuel compounds from past spills. This study used carbon-14 analyses to distinguish fuel-derived carbon from background carbon, along with other biodegradation indicators, to address two goals: (1) determine the extent and migration direction of groundwater affected by residual fuel below the facility and (2) determine if residual fuel locations in the subsurface could be identified by analyzing soil gas at the surface above the facility. Groundwater from 19 wells was sampled between September 2022 and April 2023. Nonvolatile dissolved organic carbon (NVDOC) from a well presumed to be unaffected by past spills contained 38 percent ancient carbon indicating a natural source of ancient carbon in the subsurface. The NVDOC concentrations and ancient carbon percentages indicate fuel biodegradation products are likely present on the north and south of Red Hill with the greatest effects at well RHMW02 near the 2014 spill site. The NVDOC concentrations are almost three times higher than diesel range organic (DRO) concentrations in groundwater from the same sites. Major ion data indicate that iron reduction is an important biodegradation process. Soil probe samples and soil carbon traps were used to determine the carbon-14 content of soil carbon dioxide. Ancient carbon from fuel biodegradation was not detected at any soil probe or carbon trap site in contrast to a 2017 study which reported ancient carbon detections. A reanalysis of the 2017 results using a range of local values for background carbon-14 indicates that ancient carbon from fuel biodegradation was probably only detected in lower tunnel exhaust system samples and not in any soil carbon trap samples. Measurements of carbon dioxide efflux with a dynamic closed chamber were highly variable. The soil gas results indicate that soil gas measurements at land surface were not useful for detecting residual fuel at the facility.

Hawaii↗

Groundwater flow model for the Des Moines River alluvial aquifer near Des Moines, Iowa

Des Moines Water Works (DMWW) is a regional municipal water utility that provides residential and commercial water resources to about 600,000 customers in Des Moines, Iowa, and surrounding municipalities in central Iowa. DMWW has identified a need for increased water supply and is exploring the potential for expanding groundwater production capabilities in the Des Moines River alluvial aquifer, where it operates two radial collector wells (RCWs). The U.S. Geological Survey, in cooperation with DMWW, completed a study of the Des Moines River alluvial aquifer and interactions of the RCWs with the aquifer; no previously published model has included the existing well locations, which is the focus of this model. A conceptual and numerical groundwater flow model have been developed to characterize the Des Moines River alluvial aquifer under existing conditions, to simulate water levels observed in the RCWs, and to provide publicly accessible hydrologic data and research that advance understanding of the regional hydrologic system and can potentially be used in the future to evaluate groundwater production scenarios. Model performance was assessed by comparing observed and simulated groundwater levels that included water level elevations, water level changes, water level inequality observations, surface water streamflow, and change in surface water volume from upstream to downstream. Water table elevation in the aquifer layers is on average slightly overestimated with average absolute value error less than 1.5 meters at both RCWs and less than 2.5 meters for all observation wells in the alluvial aquifer layers. The model also accurately simulated water tables greater than the RCW design minimum (a water level threshold at which RCW pumping is reduced) in all timesteps for which water level observation data existed. Water table elevation error was higher in other model layers that were not the focus of the study, and the model did not accurately match streamflow targets.

Iowa↗

Hydrogeologic framework and conceptual groundwater-flow model of the panhandle and northwest parts of the High Plains (Ogallala) aquifer in Oklahoma, 1998–2022

This study was conducted by the U.S. Geological Survey, in cooperation with the Oklahoma Water Resources Board, to update the hydrogeologic framework and conceptual flow model for the panhandle and northwest parts of the High Plains (Ogallala) aquifer in Oklahoma, which together compose the Ogallala aquifer focus area. The study included the construction of a potentiometric surface, and available geologic and hydrologic data were used to evaluate saturated thickness of the aquifer. The water budget for the updated conceptual groundwater-​flow model was based on estimated inflows and outflows for the 1998–2022 study period. Saturated thickness of the Ogallala aquifer averaged 127 and 116 feet for the panhandle and northwest parts, respectively. Groundwater withdrawals from the Ogallala aquifer for 1998–2022 averaged 422,054 and 39,645 acre-feet per year (acre-ft/yr) for the panhandle and northwest parts, respectively. Recharge, the primary inflow, was estimated at 0.63 inch per year for the 1998–2022 study period, with the panhandle part of the Ogallala aquifer receiving 175,068 acre-ft/yr and the northwest part of the Ogallala aquifer receiving 49,376 acre-ft/yr. Additional inflows included irrigation return flows, estimated at 8,111 and 642 acre-ft/yr for the panhandle and northwest parts, respectively, of the Ogallala aquifer. Net lateral groundwater flows, considered to be aquifer outflows, were estimated to account for 31,908 acre-ft/yr for the Ogallala aquifer focus area. Streambed seepage, which was an outflow of 5,535 acre-ft/yr, was only present in the northwest part of the Ogallala aquifer. Vertical leakage and saturated-zone evapotranspiration were considered negligible outflows. These findings provide a revised conceptual groundwater-flow model water budget for the Ogallala aquifer focus area in Oklahoma.

Colorado, Kansas, Oklahoma, Texas↗

Application of a coupled vegetation competition and groundwater simulation model to study effects of sea level rise and storm surges on coastal vegetation

Global climate change poses challenges to areas such as low-lying coastal zones, where sea level rise (SLR) and storm-surge overwash events can have long-term effects on vegetation and on soil and groundwater salinities, posing risks of habitat loss critical to native species. An early warning system is urgently needed to predict and prepare for the consequences of these climate-related impacts on both the short-term dynamics of salinity in the soil and groundwater and the long-term effects on vegetation. For this purpose, the U.S. Geological Survey’s spatially explicit model of vegetation community dynamics along coastal salinity gradients (MANHAM) is integrated into the USGS groundwater model (SUTRA) to create a coupled hydrology–salinity–vegetation model, MANTRA. In MANTRA, the uptake of water by plants is modeled as a fluid mass sink term. Groundwater salinity, water saturation and vegetation biomass determine the water available for plant transpiration. Formulations and assumptions used in the coupled model are presented. MANTRA is calibrated with salinity data and vegetation pattern for a coastal area of Florida Everglades vulnerable to storm surges. A possible regime shift at that site is investigated by simulating the vegetation responses to climate variability and disturbances, including SLR and storm surges based on empirical information.

Journal of Marine Science and Engineering↗