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USGS2010

Predicting performance for ecological restoration: A case study using Spartina altemiflora

The success of population-based ecological restoration relies on the growth and reproductive performance of selected donor materials, whether consisting of whole plants or seed. Accurately predicting performance requires an understanding of a variety of underlying processes, particularly gene flow and selection, which can be measured, at least in part, using surrogates such as neutral marker genetic distances and simple latitudinal effects. Here we apply a structural equation modeling approach to understanding and predicting performance in a widespread salt marsh grass, Spartina alterniflora, commonly used for ecological restoration throughout its native range in North America. We collected source materials from throughout this range, consisting of eight clones each from 23 populations, for transplantation to a common garden site in coastal Louisiana and monitored their performance. We modeled performance as a latent process described by multiple indicator variables (e.g., clone diameter, stem number) and estimated direct and indirect influences of geographic and genetic distances on performance. Genetic distances were determined by comparison of neutral molecular markers with those from a local population at the common garden site. Geographic distance metrics included dispersal distance (the minimum distance over water between donor and experimental sites) and latitude. Model results indicate direct effects of genetic distance and latitude on performance variation among the donor sites. Standardized effect strengths indicate that performance was roughly twice as sensitive to variation in genetic distance as to latitudinal variation. Dispersal distance had an indirect influence on performance through effects on genetic distance, indicating a typical pattern of genetic isolation by distance. Latitude also had an indirect effect on genetic distance through its linear relationship with dispersal distance. Three performance indicators had significant loadings on performance alone (mean clone diameter, mean number of stems, mean number of inflorescences), while the performance indicators mean stem height and mean stem width were also influenced by latitude. We suggest that dispersal distance and latitude should provide an adequate means of predicting performance in future S. alterniflora restorations and propose a maximum sampling distance of 300 km (holding latitude constant) to avoid the sampling of inappropriate ecotypes. ?? 2010 by the Ecological Society of America.

Ecological Applications↗
USGS2010

Conserving migratory land birds in the New World: Do we know enough?

Migratory bird needs must be met during four phases of the year: breeding season, fall migration, wintering, and spring migration; thus, management may be needed during all four phases. The bulk of research and management has focused on the breeding season, although several issues remain unsettled, including the spatial extent of habitat influences on fitness and the importance of habitat on the breeding grounds used after breeding. Although detailed investigations have shed light on the ecology and population dynamics of a few avian species, knowledge is sketchy for most species. Replication of comprehensive studies is needed for multiple species across a range of areas. Information deficiencies are even greater during the wintering season, when birds require sites that provide security and food resources needed for survival and developing nutrient reserves for spring migration and, possibly, reproduction. Research is needed on many species simply to identify geographic distributions, wintering sites, habitat use, and basic ecology. Studies are complicated, however, by the mobility of birds and by sexual segregation during winter. Stable-isotope methodology has offered an opportunity to identify linkages between breeding and wintering sites, which facilitates understanding the complete annual cycle of birds. The twice-annual migrations are the poorest-understood events in a bird's life. Migration has always been a risky undertaking, with such anthropogenic features as tall buildings, towers, and wind generators adding to the risk, Species such as woodland specialists migrating through eastern North America have numerous options for pausing during migration to replenish nutrients, but some species depend on limited stopover locations. Research needs for migration include identifying pathways and timetables of migration, quality and distribution of habitats, threats posed by towers and other tall structures, and any bottlenecks for migration. Issues such as human population growth, acid deposition, climate change, and exotic diseases are global concerns with uncertain consequences to migratory birds and even lesscertain remedies. Despite enormous gaps in our understanding of these birds, research, much of it occurring in the past 30 years, has provided sufficient information to make intelligent conservation efforts but needs to expand to handle future challenges. ?? 2010 by the Ecological Society of America.

Ecological Applications↗
USGS1998

Nitrogen excess in North American ecosystems: Predisposing factors, ecosystem responses, and management strategies

Most forests in North America remain nitrogen limited, although recent studies have identified forested areas that exhibit symptoms of N excess, analogous to overfertilization of arable land. Nitrogen excess in watersheds is detrimental because of disruptions in plant/soil nutrient relations, increased soil acidification and aluminum mobility, increased emissions of nitrogenous greenhouse gases from soil, reduced methane consumption in soil, decreased water quality, toxic effects on freshwater biota, and eutrophication of coastal marine waters. Elevated nitrate ( NO 3 − ) loss to groundwater or surface waters is the primary symptom of N excess. Additional symptoms include increasing N concentrations and higher N:nutrient ratios in foliage (i.e., N:Mg, N:P), foliar accumulation of amino acids or NO 3 − , and low soil C:N ratios. Recent nitrogen-fertilization studies in New England and Europe provide preliminary evidence that some forests receiving chronic N inputs may decline in productivity and experience greater mortality. Long-term fertilization at Mount Ascutney, Vermont, suggests that declining and slow N-cycling coniferous stands may be replaced by fast-growing and fast N-cycling deciduous forests. Symptoms of N saturation are particularly severe in high-elevation, nonaggrading spruce–fir ecosystems in the Appalachian Mountains and in eastern hardwood watersheds at the Fernow Experimental Forest near Parsons, West Virginia. In the Los Angeles Air Basin, mixed conifer forests and chaparral watersheds with high smog exposure are N saturated and exhibit the highest streamwater NO 3 − concentrations for wildlands in North America. High-elevation alpine watersheds in the Colorado Front Range and a deciduous forest in Ontario, Canada, are N saturated, although N deposition is moderate (∼8 kg·ha −1 ·yr −1 ). In contrast, the Harvard Forest hardwood stand in Massachusetts has absorbed >900 kg N/ha during 8 yr of N amendment studies without significant NO 3 − leaching, illustrating that ecosystems vary widely in the capacity to retain N inputs. Overly mature forests with high N deposition, high soil N stores, and low soil C:N ratios are prone to N saturation and NO 3 − leaching. Additional characteristics favoring low N retention capacity include a short growing season (reduced plant N demand) and reduced contact time between drainage water and soil (i.e., porous coarse-textured soils, exposed bedrock or talus). Temporal patterns of hydrologic fluxes interact with biotic uptake and internal cycling patterns in determining ecosystem N retention. Soils are the largest storage pool for N inputs, although vegetation uptake is also important. Recent studies indicate that nitrification may be widespread in undisturbed ecosystems, and that microbial assimilation of NO 3 − may be a significant N retention mechanism, contrary to previous assumptions. Further studies are needed to elucidate the sites, forms, and mechanisms of N retention and incorporation into soil organic matter, and to test potential management options for mitigating N losses from forests. Implementation of intensive management practices in N-saturated ecosystems may only be feasible in high-priority areas and on a limited scale. Reduction of N emissions would be a preferable solution, although major reductions in the near future are unlikely in many areas due to economic, energy-use, policy, and demographic considerations.

Ecological Applications↗
USGS2004

Bryophytes from Simeonof Island in the Shumagin Islands, southwestern Alaska

Simeonof Island is located south of the Alaska Peninsula in the hyperoceanic sector of the middle boreal subzone. We examined the bryoflora of Simeonof Island to determine species composition in an area where no previous collections had been reported. This field study was conducted in sites selected to represent the spectrum of environmental variation within Simeonof Island. Data were analyzed using published reports to compare bryophyte distribution patterns at three levels, the Northern Hemisphere, North America, and Alaska. A total of 271 bryophytes were identified: 202 mosses and 69 liverworts. The annotated list of species for Simeonof Island expands the known range for many species and fills distribution gaps within Hultén's Western Pacific Coast district. Maps and notes on the distribution of 14 significant distribution records are presented. Compared with bryophyte distribution in the Northern Hemisphere, the bryoflora of Simeonof Island primarily includes taxa of boreal (55%), temperate (20%), arctic (10%), and cosmopolitan (8%) distribution; 6% of the moss flora are western North America endemics. A description of the bryophytes present in the vegetation and habitat types is provided as is a quantitative analysis of the most frequently occurring bryophytes in crowberry heath.

Alaska↗
USGS2007

Advances and opportunities in assessing contaminant sensitivity of freshwater mussel (unionidae) early life stages

Freshwater mussels (family Unionidae, also referred to as freshwater pearly mussels, unionids, or naiades) are one of North America’s most endangered faunal groups. Near unanimity exists in characterizations of the imperilment of these ecologically, economically, and culturally important bivalve mollusks. Freshwater mussels are a renewable resource supporting a shell industry in the United States valued at $40–50 million annually [1]. In addition to being a food source for aquatic and terrestrial vertebrates, this diverse fauna helps stabilize sediment [2] and provides critical nutrient and energy cycling in streams and lakes by filtering phytoplankton, bacteria, and particulate organic matter from the water column [3]. Thirty-five species of freshwater mussels are extinct [4], 70 species are listed as threatened or endangered under the U.S. Endangered Species Act (www.fws.gov/endangered/wildlife.html), and nearly 180 species are identified as critically imperiled or vulnerable (www.natureserve.org/explorer). Declines in freshwater mussels are not unique to North America [5], but because the taxon reaches its greatest richness here, impacts are especially noteworthy.

Environmental Toxicology and Chemistry↗
USGS1999

Successful aquatic animal disease emergency programmes

The authors provide examples of emergency programmes which have been successful in eradicating or controlling certain diseases of aquatic animals. The paper is divided into four parts. The first part describes the initial isolation of viral haemorrhagic septicaemia (VHS) virus in North America in the autumn of 1988 from feral adult chinook ( Oncorhynchus tshawytscha ) and coho salmon ( O.kisutch ) returning for spawning. The fish disease control policies at both State and Federal levels in the United States of America required quarantine and emergency eradication measures upon the finding of certain exotic fish pathogens, including VHS virus. The procedures for emergency plans, destruction of stocks and disinfection of facilities are described, as well as challenge experiments with the North American strains of VHS virus and the detection of the virus in marine fish species (cod [ Gadus macrocephalus ] and herring [ Clupea harengus pallasi ]) in the Pacific Ocean. The second part of the paper outlines the aquatic animal legislation in Great Britain and within the European Union, in regard to contingency plans, initial investigations, action on the suspicion of notifiable disease and action on confirmation of infection. The legal description is followed by an account of an outbreak of viral haemorrhagic septicaemia in turbot (Scophthalmus maximus) in Great Britain, including the stamping-out process at the affected farm and investigations conducted to screen other farms in the vicinity for possible infection. The third part provides a historical review of the build-up of infectious salmon anaemia (ISA) in Norway and the attempts to control the disease using legal measures in the absence of detailed knowledge of the aetiology, epizootiology, pathogenesis, etc. of the disease. The measures taken show that the spread of ISA can be controlled using restrictions on the movement of fish, disinfection procedures, etc. However, acceptance and understanding of the chosen strategy by the fish farmers is a pre-requisite to reach that goal. Finally, the paper summarises future needs for national and international legislation, including the development of standard approaches for control, the creation of appropriate infrastructures and a better understanding of the epidemiology of aquatic animal diseases.

Revue Scientifique et Technique↗
USGS2024

Sero-epidemiology of Highly Pathogenic Avian Influenza viruses among wild birds in subarctic intercontinental transition zones

Background: The geographic expansion and evolution of A/Goose/Guangdong/1/1996(H5N1) (Gs/GD) lineage H5Nx highly pathogenic avian influenza (HPAI) viruses since 1996 have raised awareness of enzootic circulation among migratory birds and the potential for intercontinental transport and spread. Recent Pacific- and Atlantic-route introductions of HPAI to North America were facilitated by avian migration through subarctic zones, specifically Alaska and Iceland. This study aimed to identify recent historical patterns of exposure to HPAI viruses among birds within and migrating through both regions and evaluate how geographic, demographic, and taxonomic differences contribute to exposure risk at two intercontinental staging locations. Methods: During 2010-2019, blood samples were obtained from captured wild migratory seabirds and waterfowl in Alaska and Iceland. All live birds were released following completion of sampling. Sampling date, species, sampling location, and age class was documented for each bird, and sex was documented when possible. Lentiviral pseudoviruses that express the influenza hemagglutinin surface glycoprotein for H5Nx HPAI and H5 low-pathogenicity avian influenza (LPAI) were constructed for use in serological assays to screen for and quantify titers of antibodies against the latter viruses. Data were analyzed to compare (a) categorical baseline ecological traits between Iceland and Alaska, and (b) ecological traits between birds identified to be seropositive and suggestive/seronegative/fully cross-reactive birds to H5Nx HPAI in Iceland and Alaska. Factors associated with seroreactivity to H5Nx HPAI and H5 LPAI were assessed. Results: The seroprevalence of HPAI among birds in both locations was 7.3% (112/1526). Findings reveal variability in seroprevalence by year, higher rates of exposure to H5 LPAI than H5Nx HPAI overall, and significantly more seropositive and suggestive exposure of birds to H5Nx HPAI in Alaska as compared to Iceland. Geographic, demographic, and taxonomic differences contribute to exposure risk between Alaska and Iceland. Most tested birds were immuno-naïve to HPAI in both locations, which indicates many migratory birds in the subarctic are susceptible to HPAI infection, demonstrating substantial risk for intercontinental transmission between Asia, Europe, and North America. Conclusions: Our findings provide further justification for increased viral and serosurveillance in Alaska and Iceland to monitor subarctic movements of migratory birds and intercontinental transmission dynamics of currently circulating and new strains of HPAI globally.

Research Square↗
USGS2008

A basin-scale approach to estimating stream temperatures of tributaries to the lower Klamath River, California

Stream temperature is an important component of salmonid habitat and is often above levels suitable for fish survival in the Lower Klamath River in northern California. The objective of this study was to provide boundary conditions for models that are assessing stream temperature on the main stem for the purpose of developing strategies to manage stream conditions using Total Maximum Daily Loads. For model input, hourly stream temperatures for 36 tributaries were estimated for 1 Jan. 2001 through 31 Oct. 2004. A basin-scale approach incorporating spatially distributed energy balance data was used to estimate the stream temperatures with measured air temperature and relative humidity data and simulated solar radiation, including topographic shading and corrections for cloudiness. Regression models were developed on the basis of available stream temperature data to predict temperatures for unmeasured periods of time and for unmeasured streams. The most significant factor in matching measured minimum and maximum stream temperatures was the seasonality of the estimate. Adding minimum and maximum air temperature to the regression model improved the estimate, and air temperature data over the region are available and easily distributed spatially. The addition of simulated solar radiation and vapor saturation deficit to the regression model significantly improved predictions of maximum stream temperature but was not required to predict minimum stream temperature. The average SE in estimated maximum daily stream temperature for the individual basins was 0.9 ?? 0.6??C at the 95% confidence interval. Copyright ?? 2008 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America. All rights reserved.

Journal of Environmental Quality↗
USGS2008

Chemical and toxicologic assessment of organic contaminants in surface water using passive samplers

Passive sampling methodologies were used to conduct a chemical and toxicologic assessment of organic contaminants in the surface waters of three geographically distinct agricultural watersheds. A selection of current-use agrochemicals and persistent organic pollutants, including polycyclic aromatic hydrocarbons, polychlorinated biphenyls, and organochlorine pesticides, were targeted using the polar organic chemical integrative sampler (POCIS) and the semipermeable membrane device passive samplers. In addition to the chemical analysis, the Microtox assay for acute toxicity and the yeast estrogen screen (YES) were conducted as potential assessment tools in combination with the passive samplers. During the spring of 2004, the passive samplers were deployed for 29 to 65 d at Leary Weber Ditch, IN; Morgan Creek, MD; and DR2 Drain, WA. Chemical analysis of the sampler extracts identified the agrochemicals predominantly used in those areas, including atrazine, simazine, acetochlor, and metolachlor. Other chemicals identified included deethylatrazine and deisopropylatrazine, trifluralin, fluoranthene, pyrene, cis- and trans-nonachlor, and pentachloroanisole. Screening using Microtox resulted in no acutely toxic samples. POCIS samples screened by the YES assay failed to elicit a positive estrogenic response. Copyright ?? 2008 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America. All rights reserved.

Journal of Environmental Quality↗
USGS2008

Agriculture-related trends in groundwater quality of the glacial deposits aquifer, central Wisconsin

Measuring and understanding trends in groundwater quality is necessary for determining whether changes in land-management practices have an effect on groundwater quality. This paper describes an approach that was used to measure and understand trends using data from two groundwater studies conducted in central Wisconsin as part of the USGS NAWQA program. One of the key components of this approach, determining the age of sampled groundwater, gave a temporal component to the snapshots of water quality that were obtained through synoptic-sampling efforts. This approach can be used at other locations where groundwater quality data are collected, groundwater age can be determined, and associated temporal data are available. Results of these studies indicate measured concentrations of nitrate and atrazine plus deethylatrazine were correlated to historical patterns of fertilizer and atrazine use. Concentrations of nitrate in groundwater have increased over time; concentrations of atrazine plus deethylatrazine increased and then decreased. Concentrations of nitrate also were correlated to screen depth below the water level and concentrations of dissolved O2; concentrations of atrazine plus deethylatrazine were correlated to dissolved O2 and annual precipitation. To measure trends in concentrations of atrazine plus deethylatrazine, the data, collected over a near-decadal period, were adjusted to account for changes in laboratory-reporting levels and analytical recoveries. Only after accounting for these changes was it apparent that the median concentrations of atrazine plus deethylatrazine decreased over the near-decadal interval between sampling efforts. Copyright ?? 2008 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America. All rights reserved.

Conference Paper↗
USGS2008

Decadal-scale changes of pesticides in ground water of the United States, 1993-2003

Pesticide data for ground water sampled across the United States between 1993-1995 and 2001-2003 by the U.S. Geological Survey National Water-Quality Assessment Program were evaluated for trends in detection frequency and concentration. The data analysis evaluated samples collected from a total of 362 wells located in 12 local well networks characterizing shallow ground water in agricultural areas and six local well networks characterizing the drinking water resource in areas of variable land use. Each well network was sampled once during 1993-1995 and once during 2001-2003. The networks provide an overview of conditions across a wide range of hydrogeologic settings and in major agricultural areas that vary in dominant crop type and pesticide use. Of about 80 pesticide compounds analyzed, only six compounds were detected in ground water from at least 10 wells during both sampling events. These compounds were the triazine herbicides atrazine, simazine, and prometon; the acetanilide herbicide metolachlor; the urea herbicide tebuthiuron; and an atrazine degradate, deethylatrazine (DEA). Observed concentrations of these compounds generally were <0.12 ??g L-1. At individual wells, changes in concentrations typically were <0.02 ??g L-1. Data analysis incorporated adjustments for changes in laboratory recovery as assessed through laboratory spikes. In wells yielding detectable concentrations of atrazine, DEA, and prometon, concentrations were significantly lower (?? = 0.1) in 2001-2003 than in 1993-1995, whereas detection frequency of these compounds did not change significantly. Trends in atrazine concentrations at shallow wells in agricultural areas were found to be consistent overall with recent atrazine use data. Copyright ?? 2008 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America. All rights reserved.

Conference Paper↗
USGS2008

Decadal-scale changes of nitrate in ground water of the United States, 1988-2004

This study evaluated decadal-scale changes of nitrate concentrations in groundwater samples collected by the USGS National Water-Quality Assessment Program from 495 wells in 24 well networks across the USA in predominantly agricultural areas. Each well network was sampled once during 1988-1995 and resampled once during 2000-2004. Statistical tests of decadal-scale changes of nitrate concentrations in water from all 495 wells combined indicate there is a significant increase in nitrate concentrations in the data set as a whole. Eight out of the 24 well networks, or about 33%, had significant changes of nitrate concentrations. Of the eight well networks with significant decadal-scale changes of nitrate, all except one, the Willamette Valley of Oregon, had increasing nitrate concentrations. Median nitrate concentrations of three of those eight well networks increased above the USEPA maximum contaminant level of 10 mg L-1. Nitrate in water from wells with reduced conditions had significantly smaller decadal-scale changes in nitrate concentrations than oxidized and mixed waters. A subset of wells had data on ground water recharge date; nitrate concentrations increased in response to the increase of N fertilizer use since about 1950. Determining ground water recharge dates is an important component of a ground water trends investigation because recharge dates provide a link between changes in ground water quality and changes in land-use practices. Copyright ?? 2008 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America. All rights reserved.

Journal of Environmental Quality↗
USGS2008

Regional nitrate and pesticide trends in ground water in the eastern San Joaquin Valley, California

Protection of ground water for present and future use requires monitoring and understanding of the mechanisms controlling long-term quality of ground water. In this study, spatial and temporal trends in concentrations of nitrate and pesticides in ground water in the eastern San Joaquin Valley, California, were evaluated to determine the long-term effects of agricultural and urban development on regional ground-water quality. Trends in concentrations of nitrate, the nematocide 1,2-dibromo-3-chloropropane, and the herbicide simazine during the last two decades are generally consistent with known nitrogen fertilizer and pesticide use and with the position of the well networks in the regional ground-water flow system. Concentrations of nitrate and pesticides are higher in the shallow part of the aquifer system where domestic wells are typically screened, whereas concentrations are lower in the deep part of the aquifer system where public-supply wells are typically screened. Attenuation processes do not seem to significantly affect concentrations. Historical data indicate that concentrations of nitrate have increased since the 1950s in the shallow and deep parts of the aquifer system. Concentrations of nitrate and detection of pesticides in the deep part of the aquifer system will likely increase as the proportion of highly affected water contributed to these wells increases with time. Because of the time of travel between the water table and the deep part of the aquifer system, current concentrations in public-supply wells likely reflect the effects of 40- to 50-yr-old management practices. Copyright ?? 2008 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America. All rights reserved.

Conference Paper↗
USGS2008

Fate and transport of pesticides in the ground water systems of southwest Georgia, 1993-2005

Modern agricultural practices in the United States have resulted in nearly unrivaled efficiency and productivity. Unfortunately, there is also the potential for release of these compounds to the environment and consequent adverse affects on wildlife and human populations. Since 1993, the National Water-Quality Assessment (NAWQA) program of the U.S. Geological Survey has evaluated water quality in agricultural areas to address these concerns. The objective of this study is to evaluate trends in pesticide concentrations from 1993-2005 in the surficial and Upper Floridan aquifers of southwest Georgia using pesticide and pesticide degradate data collected for the NAWQA program. There were six compounds - five herbicides and one degradate - that were detected in more than 20% of samples: atrazine, deethylatrazine (DEA), metolachlor, alachlor, floumeturon, and tebuthiuron. Of the 128 wells sampled during the study, only eight wells had pesticide concentrations that either increased (7) or decreased (1) on a decadal time scale. Most of the significant trends were increasing concentrations of pesticides in older water; median pesticide concentrations did not differ between the surficial and Upper Floridan aquifers from 1993 and 2005. Deethylatrazine, in the Upper Floridan aquifer, was the only compound that had a significant change (increase) in concentration during the study. The limited number of wells with increases in pesticide concentrations suggest that ground-water sources of these compounds are not increasing in concentration over the time scale represented in this study. Copyright ?? 2008 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America. All rights reserved.

Conference Paper↗
USGS2008

Land management impacts on dairy-derived dissolved organic carbon in ground water

Dairy operations have the potential to elevate dissolved organic carbon (DOC) levels in ground water, where it may interact with organic and inorganic contaminants, fuel denitrification, and may present problems for drinking water treatment. Total and percent bioavailable DOC and total and carbon-specific trihalomethane (THM) formation potential (TTHMFP and STHMFP, respectively) were determined for shallow ground water samples from beneath a dairy farm in the San Joaquin Valley, California. Sixteen wells influenced by specific land management areas were sampled over 3 yr. Measured DOC concentrations were significantly elevated over the background as measured at an upgradient monitoring well, ranging from 13 to 55 mg L-1 in wells downgradient from wastewater ponds, 8 to 30 mg L-1 in corral wells, 5 to 12 mg L-1 in tile drains, and 4 to 15 mg L-1 in wells associated with manured fields. These DOC concentrations were at the upper range or greatly exceeded concentrations in most surface water bodies used as drinking water sources in California. DOC concentrations in individual wells varied by up to a factor of two over the duration of this study, indicating a dynamic system of sources and degradation. DOC bioavailability over 21 d ranged from 3 to 10%, comparable to surface water systems and demonstrating the potential for dairy-derived DOC to influence dissolved oxygen concentrations (nearly all wells were hypoxic to anoxic) and denitrification. TTHMFP measurements across all management units ranged from 141 to 1731 ??g L-1, well in excess of the maximum contaminant level of 80 ??g L-1 established by the Environmental Protection Agency. STHMFP measurements demonstrated over twofold variation (???4 to ???8 mmol total THM/mol DOC) across the management areas, indicating the dependence of reactivity on DOC composition. The results indicate that land management strongly controls the quantity and quality of DOC to reach shallow ground water and hence should be considered when managing ground water resources and in any efforts to mitigate contamination of ground water with carbon-based contaminants, such as pesticides and pharmaceuticals. Copyright ?? 2008 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America. All rights reserved.

Journal of Environmental Quality↗
USGS2008

National, holistic, watershed-scale approach to understand the sources, transport, and fate of agricultural chemicals

This paper is an introduction to the following series of papers that report on in-depth investigations that have been conducted at five agricultural study areas across the United States in order to gain insights into how environmental processes and agricultural practices interact to determine the transport and fate of agricultural chemicals in the environment. These are the first study areas in an ongoing national study. The study areas were selected, based on the combination of cropping patterns and hydrologic setting, as representative of nationally important agricultural settings to form a basis for extrapolation to unstudied areas. The holistic, watershed-scale study design that involves multiple environmental compartments and that employs both field observations and simulation modeling is presented. This paper introduces the overall study design and presents an overview of the hydrology of the five study areas. Copyright ?? 2008 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America. All rights reserved.

Journal of Environmental Quality↗
USGS2009

Removal of organic wastewater contaminants in septic systems using advanced treatment technologies

The detection of pharmaceuticals and other organic wastewater contaminants (OWCs) in ground water and surface-water bodies has raised concerns about the possible ecological impacts of these compounds on nontarget organisms. On-site wastewater treatment systems represent a potentially significant route of entry for organic contaminants to the environment. In this study, effluent samples were collected and analyzed from conventional septic systems and from systems using advanced treatment technologies. Six of 13 target compounds were detected in effluent from at least one septic system. Caffeine, paraxanthine, and acetaminophen were the most frequently detected compounds, and estrogenic activity was detected in 14 of 15 systems. The OWC concentrations were significantly lower in effluent after sand filtration (p < 0.01) or aerobic treatment (p < 0.05) as compared with effluent that had not undergone advanced treatment. In general, concentrations in conventional systems were comparable to those measured in previous studies of municipal wastewater treatment plant (WWTP) influent, and concentrations in systems after advanced treatment were comparable to previously measured concentrations in WWTP effluent. These data indicate that septic systems using advanced treatment can reduce OWCs in treated effluent to similar concentrations as municipal WWTPs. Copyright ?? 2009 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America. All rights reserved.

Journal of Environmental Quality↗
USGS2008

Environmental occurrence and shallow ground water detection of the antibiotic monensin from dairy farms

Pharmaceuticals used in animal feeding operations have been detected in various environmental settings. There is a growing concern about the impact on terrestrial and aquatic organisms and the development of antibiotic-resistant strains of microorganisms. Pharmaceutical use in milking cows is relatively limited compared with other livestock operations, except for the ionophore monensin, which is given to lactating cows as a feed. By weight, monensin can be the most significant antibiotic used in a dairy farm. This study investigates the potential of monensin to move from dairy operations into the surrounding ground water. Using two dairy farms in California as study sites, we twice collected samples along the environmental pathway-from flush lanes, lagoon waters, and shallow ground water beneath the dairies and beneath its associated manured fields. Monensin concentrations were determined using solid-phase extraction and liquid chromatography-tandem mass spectrometry with positive electrospray ionization. Monensin was detected in all of the flush lane and lagoon water samples. Theoretical maximum concentration estimated from the actual dosing rate and the theoretical excretion rate assuming no attenuation was one order of magnitude greater than observed concentrations, suggesting significant attenuation in the manure collection and storage system. Monensin was also detected, at levels ranging from 0.04 to 0.39 microg L(-1), in some of the ground water samples underneath the production area of the dairy but not from the adjacent manured fields. Concentrations in ground water immediately downgradient of the lagoons were one to two orders of magnitude lower than the concentrations detected in lagoons, suggesting attenuation in the subsurface. The data suggest the possibility of monensin transport into shallow (2-5 m) alluvial ground water from dairy management units, including manure storage lagoons and freestalls occupied by heifers, lactating cows, and dry cows.

Journal of Environmental Quality↗