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At least 1,567 records · Page 87Linked to original sources

Rodent repellent studies. IV. Preparation and properties of trinitrobenzene-aryl amine complexes

Data are presented on methods of preparation, chemical and physical characteristics, toxicity, and repellency to rodents of complexes of symmetrical trinitrobenzene with various aromatic amines. When applied in suitable carriers or incorporated in plastic films, members of this series of materials were shown to offer significant increases in time required by wild rodents to damage common packaging materials.

Journal of the American Pharmaceutical Association↗

Using persuasive messages to encourage hunters to support regulation of lead shot

Lead shot from hunting adds the toxic metal to environments worldwide. The United States banned lead shot for hunting waterfowl in 1991 and 26 states have lead shot restrictions beyond those mandated for waterfowl hunting. The Minnesota Department of Natural Resources (MDNR) was interested in studying hunter attitudes about expanded restrictions on the use of lead shot for hunting small game to understand what communication strategies might increase public support for potential restrictions on lead shot. We mailed messages about lead shot, including 1,200 control messages and 400 of each of 9 treatment messages, and surveys to 4,800 resident small game hunters. We compared attitudes and intentions related to a possible ban among control and treatment groups. Compared to the control message, all treatment messages elicited more positive attitudes and intentions to support a ban. A basic factual message, messages with references to Ducks Unlimited, and a first-person narrative message generated the strongest support for a ban. Results also demonstrated a substantial relationship between the use of lead shot and response to persuasive messages supporting a ban.

Journal of Wildlife Management↗

Phytoremediation of a petroleum-hydrocarbon contaminated shallow aquifer in Elizabeth City, North Carolina, USA

A former bulk fuel terminal in North Carolina is a groundwater phytoremediation demonstration site where 3,250 hybrid poplars, willows, and pine trees were planted from 2006 to 2008 over approximately 579,000 L of residual gasoline, diesel, and jet fuel. Since 2011, the groundwater altitude is lower in the area with trees than outside the planted area. Soil-gas analyses showed a 95 percent mass loss for total petroleum hydrocarbons (TPH) and a 99 percent mass loss for benzene, toluene, ethylbenzene, and xylenes (BTEX). BTEX and methyl tert-butyl ether concentrations have decreased in groundwater. Interpolations of free-phase, fuel product gauging data show reduced thicknesses across the site and pooling of fuel product where poplar biomass is greatest. Isolated clusters of tree mortalities have persisted in areas with high TPH and BTEX mass. Toxicity assays showed impaired water use for willows and poplars exposed to the site's fuel product, but Populus survival was higher than the willows or pines on-site, even in a noncontaminated control area. All four Populus clones survived well at the site.

North Carolina↗

Water residence time and water depth influence on nutrient conditions, eutrophication endpoints and habitat quality in backwater lakes of a large floodplain river

Many eutrophication studies focus on the external supply of critical nutrients like nitrogen and phosphorus, but hydrology and geomorphology can enhance or dampen the effects of excessive nutrient supply. We studied six backwater lakes in the Upper Mississippi River that varied in water residence time and water depth. Eutrophication in these systems is responsible for negative impacts such as cyanobacterial blooms and toxicity, and floating plant and algal mats that disrupt recreational water uses. Increasing backwater residence time was associated with more nitrate removal and a greater likelihood of nitrogen limitation, as well as greater accumulations of duckweed. Backwaters with greater depth and lower nitrogen concentration had less likelihood of filamentous algal accumulations. The median water residence time of backwaters with low duckweed (11.7 days) and no filamentous algae (16.9 days) approached the 12-day target to maintain overwintering conditions in backwaters for fisheries survival, supporting that water residence times in this range would likely improve both winter and summer water quality. Mean depth in backwaters with low duckweed and no filamentous algae was ~1.3 m, while shallower backwaters were more likely to produce duckweed and filamentous algae mats. This indicates that deeper backwaters might reduce the likelihood of eutrophication impacts. Natural resource management at the local level may not always be able to answer global and regional threats, but habitat restoration of hydrology and geomorphology can possibly alleviate or reduce large-scale threats at the local level.

Minnesota, Wisconsin↗

Volume loss and mass balance for selected physicochemical constituents in Lake Pepin, upper Mississippi River, USA

Lake Pepin is a large, natural riverine lake in the upper Mississippi River downstream of the Twin Cities metropolitan area and the confluence with the Minnesota River, which are sources of suspended sediments and pollutants (nutrients and potentially toxic materials). The lake has a history of water quality problems and has been an efficient trap for suspended sediment and sediment-associated contaminants. Based on bathymetric survey data, the loss of volume in Lake Pepin between 1897 and 1986 was estimated. The mass balance of the lake for total suspended solids, chlorophyll a, total and dissolved reactive phosphorus and total nitrogen for 9 June 1987 to 4 June 1988 was also estimated. Water was sampled at the inflow, mid-reach, and outflow of the lake. Lake Pepin is very eutrophic, based on concentrations of phosphorus, nitrogen and chlorophyll a. The lake volume decreased by approximately 21% between 1897 and 1986. Longitudinally, the greatest fraction of the whole-lake volume loss occurred in the upper lake (45%). Based on mass balance calculations, the lake trapped about half of the suspended solids entering the lake, but it had a small net export of chlorophyll a. The lake was a sink for phosphorus and nitrogen; however, it had a net export of total phosphorus at times during low flows in the summer of 1987. Internal loading of dissolved reactive phosphorus was prevalent during the summer of 1987. The only substantial export of total nitrogen occurred in June 1987 during a bloom of cyanobacteria. The lake should continue to be an efficient trap for suspended sediment and associated contaminants, but its trapping efficiency will continue to decline slowly as lake volume decreases. Lake Pepin will probably continue to experience water quality problems, such as nuisance algal growths and low dissolved oxygen, especially during summer low flows.

Minnesota, Wisconsin↗

Bioassessment of contaminant transport and distribution in aquatic ecosystems by chemical analysis of burrowing mayflies (Hexagenia)

Burrowing mayfly nymphs (Ephemeroptera) inhabit and ingest fine-grained sediments and detritus that may be enriched with metals and persistent organic compounds. The burrowing nymphs can externally adsorb and internally assimilate these contaminants, providing a link for the food chain transfer of potentially toxic substances from sediments to organisms in higher trophic levels. The emergent adults are short-lived and do not feed, thus their gut contents do not contribute greatly to their total contaminant burden. These characteristics make Hexagenia spp. and certain other burrowing mayflies useful for assessing ecosystem contamination. General protocols are presented for the collection, processing and analysis of emergent mayflies to assess the spatial distribution and bioaccumulation of sediment-associated contaminants in aquatic ecosystems. Two essential components of this bioassessment approach are a network of on-site volunteers with the materials and instructions needed to correctly collect and store samples and quality assurance procedures to estimate the accuracy of chemical analyses. The utility of this approach is demonstrated with an example of its application to the Upper Mississippi River (USA). Determination of cadmium, mercury and polychlorinated biphenyl congeners in emergent Hexagenia bilineata from a 1250km reach of this river revealed (1) several source areas of contaminants and (2) distinct patterns in the bioaccumulation (and apparent sediment-associated transport) of each residue on both small and large spatial scales.

Upper Mississippi River↗

Guidelines for evaluation and treatment of lead poisoning of wild raptors

Lead poisoning is a threat to birds, particularly scavenging birds of prey. With the availability of portable lead-testing kits, an increasing number of field researchers are testing wild-caught birds, in situ , for lead poisoning. We describe guidelines for evaluation of lead toxicity in wild raptors by outlining field testing of blood-lead concentrations, presenting criteria for removing a lead-poisoned bird from the wild for treatment, and suggesting strategies for effective treatment of lead intoxicated raptors. Field testing of birds is most commonly accomplished via portable electrochemical analysis of blood; visual observation of condition alone may provide insufficient evidence upon which to make a decision about lead poisoning. Our intended audience is not only the avian research community, but also rehabilitation facilities that may receive apparently uninjured birds. Best practices suggest that birds whose blood-lead levels are <40 μg/dL be released back to the wild as soon as possible after capture. The decision to release or treat birds with blood-lead levels between 40 μg/dL and 60 μg/dL should be made based on the presence of clinical signs of poisoning and relevant biological characteristics (e.g., breeding status). Finally, birds with blood-lead levels >60 μg/dL are potentially lethally poisoned and best served if removed from the wild for appropriate treatment at a licensed rehabilitation facility and later released. We present guidelines for decision-making when treating lead poisoning of wild raptors. Future work based on experimental studies will clarify the role of lead poisoning for specific species and be important to refine these guidelines to improve effectiveness.

Wildlife Society Bulletin↗

Regulation of subcellular localization of the Aryl Hydrocarbon Receptor (AhR)

The aryl hydrocarbon receptor (AhR) is a ligand-activated transcription factor that mediates the toxicity of dioxin and other xenobiotics. In the absence of exogenous ligand, AhR is cytosolic. We investigated how AhR is retained in the cytosol and how dioxin induces AhR to move to the nucleus. Disruption of nuclear export of AhR by the nuclear export inhibitor leptomycin B (LMB) or by mutation of the AhR nuclear export signal resulted in nuclear accumulation of AhR in the absence of exogenous ligand. Mutation of the AhR nuclear localization signal resulted in defects in nuclear import of AhR in both the presence and the absence of exogenous ligand. Dioxin treatment caused a more rapid accumulation of AhR in the nucleus than LMB treatment. In the presence of both dioxin and LMB, nuclear accumulation of AhR was more rapid than in the presence of dioxin alone. Our results show that AhR shuttles between the nucleus and the cytosol in the absence of exogenous ligand. Binding of ligand induces an increase in the rate of nuclear import of AhR but does not eliminate nuclear export of AhR.

Archives of Biochemistry and Biophysics↗

Fish thymocyte viability, apoptosis and necrosis: In-vitro effects of organochlorine contaminants

The thymus is believed to be a central component of haematopoiesis and immune function in teleosts. Hence, chemically-elicited adverse effects to the thymus may result in immunomodulation and organ dysfunction. The objective of this research was to assess the levels of active (apoptotic) and passive (necrotic) cell death in untreated and organochlorine treated fish thymocytes. Lake trout ( Salvelinus namaycush ) thymocytes were challenged with Aroclor 1254 (concentration range 1·5–10·5 μg ml −1 ) and alpha, beta, gamma, delta isomers of hexachlorocyclohexane (concentration range 10–100 μ M ). The resulting maintenance or loss of viability was assessed by cytofluorometry (expression of phosphatidylserine and exclusion of propidium iodide) and confirmed with fluorescence microscopy. The results indicate that 20–60% of thymocytes in healthy fish undergo apoptosis, whereas thymocytes treated for 6–24 h with organochlorines exhibit increased levels of apoptotic cell death. This study demonstrates that given sufficient concentration, contact time and cellular receptors, organochlorines such as Aroclor 1254 and hexachloro-cyclohexanes may induce direct or indirect toxicity, altered functionality, or cell death to an organ important for fish immunocompetence.

Fish and Shellfish Immunology↗

Quantitative approaches to characterizing natural chemical weathering rates

Silicate minerals, constituting more than 90% of the rocks exposed at the earth’s surface, are commonly formed under temperature and pressure conditions that make them inherently unstable in surficial environments. Undoubtedly, the most significant aspect of chemical weathering resulting from this instability is the formation of soils which makes life possible on the surface of the earth. Many soil macronutrients in this “critical zone” are directly related to the rate at which primary minerals weather (Huntington, 1995; Chadwick et al., 2003). Chemical weathering also creates economically significant ore deposits, such as those for Al and U (Samma, 1986; Misra, 2000), as well as potentially releasing high concentrations of toxic trace elements such as Se and As (Frankenberger and Benson, 1994). Silicate weathering is a significant buffer to acidification caused by atmospheric deposition (Driscoll et al., 1989) and from land use practices (Farley and Werritty, 1989). Atmospheric CO 2 levels have been primarily controlled by the balance between silicate weathering and the rate of volcanic inputs from the Earth’s interior, a relationship which may explain long-term climate stability (Ruddiman, 1997)

Book chapter↗

Solute transport processes

Soils and aquifers are major compartments of the subsurface environment, which together control the terrestrial hydrological cycle. This subsurface is important for water resources and also as repository for municipal, industrial, and government waste. Aquifers are typically recharged by natural rainfall entering the soil profile and leaching into deeper soil layers. Due to intensive agricultural or industrial activities the leachate leaving the soil profile and entering the aquifer may contain concentrations of toxic substances such as agrochemicals, heavy metals, and polycyclic aromatic hydrocarbons. At contaminated industrial sites light and dense non-aqueous phase liquids (LNAPLs, DNAPLs) may be transported as a separate phase to the underlying aquifer systems. Once any of these chemicals have entered the aquifer they can be transported over large horizontal distances thus contaminating large parts of the aquifer and threateningwater supplywells. Remediation of highly contaminated aquifer systems is commonly a long-term and expensive proposition. As safe and effective use of the subsurface environment is a major challenge facing our society, there is a great need to improve our understanding of the shallow subsurface and the groundwater systems. This particularly includes the understanding of transport processes, which are responsible for the fate of contaminants.

Book chapter↗

Cyanide hazards to plants and animals from gold mining and related water issues

Highly toxic sodium cyanide (NaCN) is used by the international mining community to extract gold and other precious metals through milling of high-grade ores and heap leaching of low-grade ores (Korte et al. 2000). The process to concentrate gold using cyanide was developed in Scotland in 1887 and was used almost immediately in the Witwatersrand gold fields of the Republic of South Africa. Heap leaching with cyanide was proposed by the U.S. Bureau of Mines in 1969 as a means of extracting gold from low-grade ores. The gold industry adopted the technique in the 1970s, soon making heap leaching the dominant technology in gold extraction (Da Rosa and Lyon 1997). The heap leach and milling processes, which involve dewatering of gold-bearing ores, spraying of dilute cyanide solutions on extremely large heaps of ores containing low concentrations of gold, or the milling of ores with the use of cyanide and subsequent recovery of the gold-cyanide complex, have created a number of serious environmental problems affecting wildlife and water management. In this account, we review the history of cyanide use in gold mining with emphasis on heap leach gold mining, cyanide hazards to plants and animals, water management issues associated with gold mining, and proposed mitigation and research needs.

Archives of Environmental Contamination and Toxico↗

National standards and guidelines for pesticides in water, sediment, and aquatic organisms

The effects of pesticides 1 on water quality commonly are assessed by comparing measured concentrations of individual pesticide compounds in the environment with concentrations that have been determined to have potential adverse effects on humans, aquatic organisms, or other beneficial uses of water. Direct evaluation of the adverse effects of every pesticide present in a given hydrologic system is beyond the scope and budget of most water-quality studies. Many studies rely on standards or guidelines set by federal or state agencies or other institutions to indicate what concentrations may have adverse effects on human health, aquatic organisms, or wildlife. Such standards and guidelines generally are based on laboratory or field studies that document the effects of individual pesticides on specific aspects of water quality. Single-species toxicity tests (using a single species of a test organism) under various laboratory conditions are the most common type of study, whereas artificial ecosystem studies (using multiple species of a test organism) and field studies are relatively uncommon. Such studies rarely consider the effects of exposure to more than one chemical at a time. Technical information from such studies has been used by the U.S. Environmental Protection Agency (USEPA) 2 in issuing national standards, such as drinking-water regulations (for example, see USEPA 1991a) and guidelines, such as ambient water-quality criteria for the protection of human health and aquatic organisms (for example, see USEPA 1980a) to meet its statutory requirements under the Safe Drinking Water Act (SDWA) and the Clean Water Act (CWA). The Food and Drug Administration (FDA) also has used its authority under the Federal Food, Drug, and Cosmetic Act (FFDCA) to set action levels (enforceable regulatory limits) for unavoidable residues of pesticides in foods (FDA 1990).

Book chapter↗

Preliminary assessment of the effects of selenium in agricultural drainage on fish in the San Joaquin Valley

Concentrations of total selenium were measured in whole-body samples of seven fishes from the Sacramento and San Joaquin River systems and the San Francisco Bay complex. Concentrations of selenium (up to 11 µ g/g dry weight in whole-body composite samples) were highest in fish from canals and sloughs in the Grassland Water District (Grasslands) that received large inflows of subsurface agricultural drainage water. Slightly lower selenium concentrations occurred in fish from the San Joaquin River immediately downstream from tributaries draining the Grasslands. Although circumstantial evidence suggests that selenium-sensitive species such as bluegills and largemouth bass are being excluded from the Grasslands, conclusive evidence of selenium toxicity is still lacking. In response to earlier reports of high concentrations of selenium in several species collected from the Grasslands, the California Department of Health Services has urged people to limit consumption of fish from this region.

Book chapter↗

Anticoagulant rodenticides and wildlife: Introduction

Rodents have interacted with people since the beginning of systematic food storage by humans in the early Neolithic era. Such interactions have had adverse outcomes such as threats to human health, spoiling and consumption of food sources, damage to human infrastructure and detrimental effects on indigenous island wildlife (through inadvertent anthropogenic assisted introductions). These socio/economic and environmental impacts illustrate the clear need to control populations of commensal rodents. Different methods have been applied historically but the main means of control in the last decades is through the application of rodenticides, mainly anticoagulant rodenticides (ARs) that inhibit blood clotting. The so-called First Generation Anticoagulant Rodenticides (FGARs) proved highly effective but rodents increasingly developed resistance. This led to a demand for more effective alternative compounds and paved the way to the development of Second Generation Anticoagulant Rodenticides (SGARs). These were more acutely toxic and persistent, making them more effective but also increasing the risks of exposure of non-target species and secondary poisoning of predatory species. SGARs often fail the environmental thresholds of different regulatory frameworks because of these negative side-effects, but their use is still permitted because of the overwhelming societal needs for rodent control and the lack of effective alternatives. This book provides a state-of-the-art overview of the scientific advancements in assessment of environmental exposure, effects and risks of currently used ARs. This is discussed in relation to the societal needs for rodent control, including risk mitigation and development of alternatives.

Book chapter↗

Applications of imaging spectroscopy data: A case study at Summitville, Colorado

From 1985 through 1992, the Summitville open-pit mine produced gold from lowgrade ore using cyanide heap-leach techniques, a method to extract gold whereby the ore pile is sprayed with water containing cyanide, which dissolves the minute gold grains. Environmental problems due to mining activity at Summitville include significant increases in acidic and metal-rich drainage from the site, leakage of cyanide-bearing solutions from the heap-leach pad into an underdrain system, and several surface leaks of cyanide-bearing solutions into the Wightman Fork of the Alamosa River. In general, drainage from the Summitville mine moves downslope into the Wightman Fork, a small tributary of the Alamosa River, which in turn flows east into the Terrace Reservoir before entering the agricultural lands of the San Luis Valley. The increase in the trace-metal burden of the Alamosa River watershed due to the mining activities at Summitville is of concern to farmers and fisherman, as well as Federal and State of Colorado agencies having responsibility for land stewardship. The environment of the Summitville area is a result of 1) its geologic evolution, that culminated in the formation of precious-metal mineral deposits; and 2) previous metal mining activity. Mining accentuates, accelerates, and pertubates natural geochemical processes. The development of underground workings, open pits, mill tailings, and spoil heaps and the extractive processing of ore enhances the likelihood of releasing chemicals and elements to the surrounding areas and at increased rates relative to unmined areas. Both mined and unmined mineralized areas can produce acid drainage from the formation and movement of highly acidic water rich in heavy metals. This acidic water forms principally through the chemical reaction of oxygenated surface water and shallow subsurface water with rocks that contain sulfide minerals, producing sulphuric acid. Heavy metals can be leached by the acid solution that comes in contact with mineralized rocks, a process that may be enhanced by bacterial action. The resulting fluids may be highly toxic and, when mixed with groundwater, surface water, and soil, may have harmful effects on humans, animals, and plants. Thus, understanding the geologic and hydrologic history of this area is a critical piece of the environmental puzzle in the Summitville area. The Summitville mine operators had ceased active mining and begun environmental remediation, including treatment of the heap-leach pile and installation of a water-treatment facility, when it declared bankruptcy in December 1992 and abandoned the mine site. The U.S. Environmental Protection Agency (EPA) immediately took over the Summitville site under EPA Superfund Emergency Response authority. Summitville has focused public attention on the environmental effects of modern mineral-resource development. Soon after the mine was abandoned, Federal, State, and local agencies, along with Alamosa River water users and private companies, began extensive studies at the mine site and surrounding areas. These studies included analysis of water, soil, livestock and vegetation. The role of the U.S. Geological Survey (USGS) was to provide geologic, hydrologic and agricultural information about the mine and surrounding area and to describe and evaluate the environmental condition of the Summitville mine and the downstream effects of the mine on the San Luis Valley (King 1995).

Colorado↗

The use of tumors in wild populations of fish to assess ecosystem health

Evidence has linked toxicants in aquatic systems with cancer in fish and population level effects on species. Thus some types of tumors may be useful monitors of ecosystem health, at least as affected by genotoxins and promoters. However, tumors caused by purely genetic mechanisms or by virus would not be good indicators. Only neoplasms which have chemicals as a portion of their etiology (either as initiators or promoters) would be useful in assessing ecosystem health. Lesions which may fit these criteria include liver neoplasms (both biliary and hepatic) and skin lesions in a variety of primarily benthic fishes, and neural lesions in various drum species and in butterfly fish species. Two studies purporting to demonstrate a lack of tumors in fish from polluted areas have been reexamined and found either to have insufficient data on vulnerable species or to actually support a tumor-pollution linkage. Thus certain lesions in vulnerable species or species groups may serve as a mechanism to assess one facet of ecosystem health.

Journal of Aquatic Ecosystem Health↗

Effects of cover materials on leaching of constituents from dolomitic lead mine tailings

Five raised-bed test plots were used to study the effects of cover materials on the leaching of constituents from dolomitic Pb mine tailings over a 2-yr period. The cover materials studied were a fertilizer and seed mixture, anaerobically digested sewage sludge, loam and sod, and fallen leaves from silver maples ( Acer Saccharinum ); one plot was not covered. Fresh leachates and receiving pool waters were analyzed for ten metals, Si, P, inorganic anions, filterable organic carbon (FOC), and alkalinity. The mixture of fertilizer and seed decreased leaching of Pb and Zn during the first year. The leaf cover increased leaching of Pb during both years; this effect decreased as the leaves weathered. Sludge caused some increase in Pb leaching during the first year, and increased Cd leaching during both years. Concentrations of most leachate constituents decreased, and pH increased in the receiving pools. Concentrations of Pb remained higher in the receiving pool for the leaf-covered plot than in the other pools. Increases in leaching of Pb and Cd with a sludge cover were moderate, and the ability of the material to support plant growth on the tailings suggested that it may be a good medium for inducing growth of vegetative cover on the dolomitic tailings. Other organic materials may cause pronounced increase in the concentration of toxic trace metals in leachate from the tailings.

Missouri↗