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1,669 records · Page 87Linked to original sources
USGS2024

Declining groundwater storage expected to amplify mountain streamflow reductions in a warmer world

Groundwater interactions with mountain streams are often simplified in model projections, potentially leading to inaccurate estimates of streamflow response to climate change. Here, using a high-resolution, integrated hydrological model extending 400 m into the subsurface, we find groundwater an important and stable source of historical streamflow in a mountainous watershed of the Colorado River. In a warmer climate, increased forest water use is predicted to reduce groundwater recharge resulting in groundwater storage loss. Losses are expected to be most severe during dry years and cannot recover to historical levels even during simulated wet periods. Groundwater depletion substantially reduces annual streamflow with intermittent conditions predicted when precipitation is low. Expanding results across the region suggests groundwater declines will be highest in the Colorado Headwater and Gunnison basins. Our research highlights the tight coupling of vegetation and groundwater dynamics and that excluding explicit groundwater response to warming may underestimate future reductions in mountain streamflow.

Nature Water↗
USGS2026

Competition between invasive round goby and native slimy sculpin in a coldwater laboratory setting

Slimy sculpin ( Cottus cognatus ) abundance has substantially declined in many regions of the Laurentian Great Lakes coincident with the arrival and range expansions of invasive round goby ( Neogobius melanostomus ). Previous studies have shown that round goby can outcompete native mottled sculpin ( C. bairdii ) for shelter and negatively affect native spoonhead sculpin ( C. ricei ) growth, but direct behavioral interactions of slimy sculpin and round goby have not been observed. We conducted a laboratory experiment in which a pair of slimy sculpin were placed in an aquarium that contained an artificial spawning shelter and one round goby (treatment, n = 10) or no other fish (control, n = 10) for at least 30 days at temperatures reflective of their potential offshore overlap. We measured slimy sculpin egg deposition, aggressive interactions, artificial shelter occupancy, growth, and survival. Slimy sculpin were less likely to occupy shelters and experienced increased intraspecific competition when a round goby was present. In contrast, round goby rarely chased slimy sculpin, slimy sculpin were more likely to chase round goby, and slimy sculpin growth, egg deposition, and survival were not significantly different between groups. Differences in density between treatments and the relative size of fish could confound our observations. However, the dominant slimy sculpin occupied the shelter at similar rates between experimental groups if the round goby was smaller. Our results indicate that larger round goby overlapping with slimy sculpin could affect slimy sculpin shelter and space use, but the Great Lakes environment may create more stress for slimy sculpin than we observed.

Lake Michigan, Lake Superior↗
USGS2024

Streamflow depletion caused by groundwater pumping: Fundamental research priorities for management-relevant science

Reductions in streamflow caused by groundwater pumping, known as “streamflow depletion,” link the hydrologic process of stream-aquifer interactions to human modifications of the water cycle. Isolating the impacts of groundwater pumping on streamflow is challenging because other climate and human activities concurrently impact streamflow, making it difficult to separate individual drivers of hydrologic change. In addition, there can be lags between when pumping occurs and when streamflow is affected. However, accurate quantification of streamflow depletion is critical to integrated groundwater and surface water management decision making. Here, we highlight research priorities to help advance fundamental hydrologic science and better serve the decision-making process. Key priorities include (a) linking streamflow depletion to decision-relevant outcomes such as ecosystem function and water users to align with partner needs; (b) enhancing partner trust and applicability of streamflow depletion methods through benchmarking and coupled model development; and (c) improving links between streamflow depletion quantification and decision-making processes. Catalyzing research efforts around the common goal of enhancing our streamflow depletion decision-support capabilities will require disciplinary advances within the water science community and a commitment to transdisciplinary collaboration with diverse water-connected disciplines, professions, governments, organizations, and communities.

Water Resource Research↗
USGS2025

Ubiquity and causes of soil water preferential flow across 17 ecoregions

Preferential flow (PF) in soil causes the rapid transport of water, nutrients, and contaminants into the subsurface, influencing groundwater recharge and streamflow. Data scarcity has hindered the quantification of PF occurrence and the identification of its drivers across diverse ecoregions. We address this gap by analyzing high-frequency, multi-depth soil moisture data across 17 ecoregions in the USA, using ∼1,500 sensors at 40 sites. We discovered that PF is widespread, with sites experiencing PF in up to 60% of rainfall events ≥2 mm. Multiple approaches consistently show that PF is more likely to occur with increased peak rainfall intensity, finer textured material, low soil moisture variability, humid climate, and higher net primary productivity. This suggests that PF patterns could shift with projected climate changes, increasing uncertainty in predictions of groundwater recharge, water quality, and streamflow generation.

conterminous United States and Puerto Rico↗
USGS2024

Diel temperature signals track seasonal shifts in localized groundwater contributions to headwater streamflow generation at network scale

Groundwater contributions to streamflow sustain aquatic ecosystem resilience; streams without significant groundwater inputs often have well-coupled air and water temperatures that degrade cold-water habitat during warm low flow periods. Widespread uncertainty in stream-groundwater connectivity across space and time has created disparate predictions of energy and nutrient fluxes across headwater networks, hindering predictions of cold-water habitat resilience under climate change scenarios. Recently, annual paired air and water temperature signals have been harnessed to indicate stream water thermal sensitivity and the dominance of deep versus shallow groundwater influence, although the utility of diel air–water temperature signal metrics for hydrologic inference has remained unexplored. Here we analyzed two consecutive years of locally paired, air–water temperature data from 47 headwater stream sites in the Catskill Mountains, New York, USA, and discovered characteristic seasonal patterns in diel temperature signal sinusoid metrics (amplitude ratio, phase lag, and mean ratio) driven by shifts in streamflow generation mechanisms and stream network position. Hydrologic interpretations of observed patterns were supported by stream heat budget model scenarios and additional analysis of paired air–water temperature data from two streams in Shenandoah National Park, Virginia, USA, with well characterized stream-groundwater connectivity. We found that within smaller tributaries, streamflow generation transitions from runoff to groundwater dominance were driven by hillslope drying during seasonal periods of lower precipitation. This was evidenced by significant correlations (p < 0.01) between daily water:air temperature signal amplitudes (non-linear decreases of ∼ 50 %) and derived base-flow index at 22 of the 28 sites, indicating enhanced local groundwater influence on streamflow promotes decoupling of diel air–water temperature signals. Additionally, ratios between daily water:air temperature signal means were lower in tributaries (∼0.68) when compared to main-stem (∼0.8) sites, increasing linearly throughout the observational period. In conceptual stream heat budget models, groundwater inflow had minimal effects on daily phase lags (∼0.2 hr), but increases in fractional groundwater discharge (0–50 %) depressed daily amplitude (∼20 % to 50 %) and mean ratios (∼15 %), supporting the sensitivity of daily metrics to interpreted changes in seasonal groundwater contributions to streamflow. During observational periods (i.e., April through October 2021 and 2022), significant differences (p < 0.01) between tributary and main-stem air–water metrics occurred when base-flow contributions were highest (∼0.93 vs. ∼ 0.68), as sites lower in the network had daily temperature metrics dominated by stream channel thermal inertia, rather than local groundwater connectivity, showing enhanced air–water diel signal coupling during warmer, drier periods. Divergent air temperature coupling across the network was interpreted as being driven by distance from local groundwater source zones, additional lateral groundwater inflows do not contribute a meaningful fraction to channel discharge lower in the network. Given the growing footprint of stream temperature observations, diel air–water temperature signals can provide distributed metrics sensitive to upstream groundwater discharge. Consequently, these metrics can support ongoing efforts by resource managers and researchers seeking to forecast the resilience of cold-water habitat to climate warming and changing precipitation regimes in mountain headwater streams.

New York, Virginia↗
USGS1976

Guidelines for collection and field analysis of ground-water samples for selected unstable constituents

The unstable nature of many chemical and physical constituents in ground water requires special collection procedures and field analysis immediately after collection. This report describes the techniques and equipment commonly used in the collection and field analysis of samples for pH, temperature, carbonate, bicarbonate, specific conductance, Eh, and dissolved oxygen.

Open-File Report↗
USGS2026

A methods framework for evaluating measurement consistency across spectrometers for multispectral uncrewed aerial system vegetation mapping applications

The U.S. Geological Survey collects remote sensing data to support national scientific assessments of natural resources, hazards, and landscape change. Spectrometers and spectroradiometers are essential for gathering point-based spectral measurements used in applications such as uncrewed aerial systems (UAS) multispectral image calibration, validation, and analysis. Evaluating how different instruments perform in laboratory and field environments helps determine whether they provide consistent, interoperable measurements. Such verification can expand access to spectral ground data during UAS operations by allowing scientists to use alternative instruments when budgets, logistics, or field conditions limit options. We propose and test a methodological framework for evaluating spectrometers for measurement consistency during UAS multispectral vegetation mapping applications. There are three central evaluation components to the framework: laboratory, field, and relative to UAS multispectral imagery. By evaluating the instruments in both relatively controlled and uncontrolled environments, we thoroughly examine measurement consistency and when/why measurements may differ. We opportunistically selected two instruments for a case study in a coastal marsh setting: a compact laboratory spectrometer we modified for field use and a field-ready spectroradiometer. The instruments produced consistent measurements in both environments. We found differences between the field spectra and UAS spectra that likely reflect the perspectives of ground vs. aerial data and indicate that further radiometric calibration may be needed.

Massachusetts↗
USGS2026

Comparative crop yield forecasting using satellite-derived biophysical and agro-climatic predictors in Sub-Saharan Africa

Timely and accurate crop yield forecasting is central to food security early warning systems, particularly in climate-vulnerable regions. While operational forecasting frameworks commonly rely on precipitation and vegetation indices such as NDVI, their ability to provide actionable lead time remains limited. Here, we evaluate the added value of satellite-derived biophysical Essential Climate Variables (ECVs): Leaf Area Index (LAI) and Fraction of Photosynthetically Active Radiation (FAPAR), for forecasting millet yield in Burkina Faso (BF) and maize yield in South Africa (ZA) and Malawi (MW). Using Random Forest models, we quantify forecast skill across the growing season at both national and sub-national scales. Results show that LAI and FAPAR provide effective forecast lead times of approximately 4 months in BF, 2 months in ZA, and up to 6 months in MW relative to harvest. At peak performance, Mean Absolute Percentage Error (MAPE) reaches 19.8% (LAI) and 23.8% (FAPAR) in BF, 12.0% and 9.8% in ZA, and 21.8% and 20.8% in MW, respectively. Across countries, biophysical parameters often outperform NDVI and precipitation, particularly in arid and semi-arid regions. At the sub-national level, LAI and FAPAR enable classification of administrative units into high and moderate-skill forecast units, revealing strong spatial heterogeneity linked to crop dominance. However, forecast skill declines where the target crop is not the dominant type, highlighting an important limitation for operational deployment. Overall, the findings suggest that satellite-derived biophysical parameters can provide earlier and more spatially resolved yield signals than commonly used predictors, with potential to improve the timeliness and effectiveness of food security early warning systems.

Remote Sensing Applications: Society and Environme↗
USGS2025

Wet meadow regeneration through restoration of biophysical feedbacks

Wet meadows are globally significant ecosystems that provide critical hydrological, ecological, and biogeochemical functions, yet their extent has declined dramatically due to land use changes and hydrologic alteration. These sedge-dominated wetlands exist at the drier end of the wetland gradient, maintained by shallow groundwater and periodic inundation. This paper is a global synthesis of the ecological, geomorphic, and hydrological dynamics of wet meadows, with an emphasis on alluvial systems, to inform effective restoration strategies. We compare wet meadows to other wetlands, classify them into palustrine, lacustrine, and alluvial types, then focus on alluvial wet meadows and discuss how their formation and persistence depend on ground and surface water interactions, sediment deposition and flow obstructions, all mediated by biological processes. In particular, we highlight the role of hydric graminoids in resisting erosion and maintaining soil cohesion, how beaver promote meadow persistence, and the significance of wet meadows as carbon sinks. We also present stratigraphic evidence demonstrating that incision, often triggered by anthropogenic activity or changing climate, is the primary mechanism of alluvial wet meadow degradation, resulting in water table decline and shifts in vegetation composition. Restoration requires reversing these incisional processes through techniques that elevate water tables, disperse flow and retain sediment—methods traditionally associated with either soil conservation or stream restoration. These include nature-based solutions that create obstructions such as beaver dams and their analogues, rock and wood-based obstructions and incision trench or gully filling and grading. Given their multifunctional value—including but not limited to flood attenuation, biodiversity support, and carbon sequestration—wet meadows warrant a focused restoration framework. This review advocates for a valley-floor scale restoration paradigm that integrates hydrological reconnection, sediment retention, and biological reinforcement to ensure long-term resilience of these systems in the face of changing climate and land use pressures.

Frontiers in Environmental Science↗
USGS2025

Determination of per- and polyfluoroalkyl substances in water by direct injection of matrix-modified centrifuge supernatant and liquid chromatography/tandem mass spectrometry with isotope dilution

A direct-injection liquid chromatography/tandem mass spectrometry method was developed to determine 34 per- and polyfluoroalkyl substances (PFAS), including selected branched isomers, in centrifuge supernatant of matrix-modified (amended with approximately 50 percent methanol) water samples. The method has been validated in reagent water, surface water, groundwater, and wastewater effluent. Other water types (for example, drinking water, untreated wastewater, and landfill leachate) have been analyzed by the method but not systematically validated. Recovery of isotope-dilution standards, added to each sample, may be used to assess method performance in nonvalidated matrices on a sample-by-sample basis. Using this method, PFAS concentrations were determined in the range of 2–2,000 nanograms per liter in water samples. This range can be extended by diluting concentrated samples. At circumneutral pH, most compounds are present in the environment in their ionized form, and data are reported as such (for example, perfluorooctanoic acid is referred to as “perfluorooctanoate” [PFOA], perfluorooctane sulfonic acid is referred to as “perfluorooctane sulfonate” [PFOS]). Sample preparation procedures were designed without the use of filtration and with minimum sample handling steps to mitigate procedural losses of target compounds due to sorption to surfaces. Further, isotope-dilution quantification allowed for the correction of bias that may result from procedural losses, matrix-induced signal suppression or enhancement, and other factors. Validation experiments to characterize bias and variability, method detection level, and holding time were done in four distinct water matrices—reagent water, surface water, treated wastewater effluent, and groundwater—at multiple concentration levels. Mean PFAS recoveries met data quality objectives of bias and variability studies in all four validation matrices except for two compounds with low and variable recovery in the reagent water matrix only. Isotope-dilution standards, treated as surrogate compounds, were analyzed in more than 1,500 customer-submitted environmental samples with aggregate recovery of 102.5±6.5 percent (mean±standard deviation). Maximum holding times for all target compounds in the four validation matrices were 28 days for refrigerated samples and 90 days for frozen samples.

Techniques and Methods↗
USGS2026

Global pegmatite-hosted lithium, cesium, and rubidium resources: A dataset for grade and tonnage modeling

Quantitative mineral resource assessments of potential undiscovered deposits can inform future mineral supply scenarios, but their accuracy is conditional on building robust grade and tonnage models of known deposits. This study presents an up-to-date global compilation and analysis of recently discovered and original, in-situ pegmatite-hosted Li, Cs, and Rb resources prior to historic production. Our analysis yields a median tonnage of 21.2 million tons (Mt) and grade of 1.12% Li 2 O, respectively, for global Li pegmatite deposits ( n = 73). The grades and tonnages of Li pegmatite resources vary depending on the age of the bedrock host domain, pegmatite crystallization age, and primary ore mineralogy. Lithium pegmatite resources hosted in Archean to transitional Archean-Paleoproterozoic domains have the largest median tonnage (29.8 Mt; n = 38), and those hosted in Paleoproterozoic to Mesoproterozoic domains have smaller median tonnages (6.5 Mt; n = 16). Cesium deposits where pollucite is the primary ore mineral have a bimodal grade distribution, with modes of 2.40 and 0.035 wt% Cs 2 O for high- and low-grade deposits, respectively, while Rb deposits are more unimodal with a median grade of 0.247 wt% Rb 2 O. Pegmatite-hosted Cs and Rb resources have median tonnages of 7.6 and 6.3 Mt, respectively. Covariation between ore mineralogy and the degree of crustal enrichment in pegmatite-hosted deposits is diagnostic of petrogenetic differences, including melt source characteristics, magma evolution, or variable degrees of volatile solubility. The Li pegmatite compilation is suitable for fitting robust numerical models to support quantitative assessments. More well-defined Rb and Cs pegmatite resources are required for quantitative assessments, but these data provide useful information about original in-place resources for framing supply discussions.

Ore Geology Reviews↗
USGS2026

Tracking baseflow supply dynamics using SWOT data from small groundwater-dominated lakes

In situ surface-water monitoring strategies are biased towards larger perennial streams and lakes and are generally not designed to track mechanisms of baseflow supply contributed by the dynamic storage of aquifers. Additionally, small (< 1 km 2 ) groundwater-influenced lakes and wetlands globally have little in situ monitoring infrastructure. We explored the utility of remotely sensed Surface Water Ocean Topography Satellite (SWOT) data, collected from 2023 onward, to characterise the seasonal and multi-year water-level trends of groundwater flow-through kettle lakes distributed across the permeable sediments of eastern Massachusetts, USA. This analysis indicated that water levels for kettle lakes with areas down to approximately 0.05 km 2 are resolvable in the study area. Our examination of 17 kettle lakes found that SWOT water-surface elevation data closely tracked groundwater levels in adjacent monitoring wells where available, including the timing of seasonal patterns (highest levels generally in late spring), although there was some variation between years and there was a substantial lag in the timing of high water levels for a lake located downgradient from a 30-m-thick vadose zone. Furthermore, SWOT-observed water-level increases in kettle lakes tracked with baseflow increases in two adjacent groundwater-dominated streams, as would be expected from increased hydraulic gradients. Unlike spectral remote sensing, SWOT data are generally not affected by cloud cover, resulting in a potential for groundwater-dominated lakes to be sentinels of dynamic storage patterns, including identification of baseflow drought lags, which are currently ill-defined hydrological processes. SWOT monitoring of groundwater-influenced surface waters shows potential for augmenting existing monitoring wells and streamgages as continuous monitors of groundwater levels and baseflow supply in permeable terrain.

Massachusetts↗
USGS1999

Effects of snowmobile use on snowpack chemistry in Yellowstone National Park, 1998

Snowmobile use in Yellowstone National Park has increased substantially in the past three decades. In areas of greatest snowmobile use, elevated levels of by-products of gasoline combustion such as ammonium and benzene have been detected in snowpack samples. Annual snowpacks and snow-covered roadways trap deposition from local and regional atmospheric emissions. Snowpack samples representing most of the winter precipitation were collected at about the time of maximum annual snow accumulation at a variety of locations in the park to observe effects of a range of snowmobile traffic levels. Concentrations of organic and inorganic compounds in snow samples from pairs of sites located directly in and off snow-packed roadways used by snowmobiles were compared to concentrations in samples collected at nearby off-road sites. Concentrations of ammonium were 2 to 5 times higher for the in-road snow compared to off-road snow for each pair of sites. Thus, concentrations decreased rapidly with distance from roadways. In addition, concentrations of ammonium, nitrate, sulfate, benzene, and toluene in snow were positively correlated with snowmobile use.

Wyoming↗
USGS2025

World minerals outlook—Cobalt, gallium, helium, lithium, magnesium, palladium, platinum, and titanium through 2029

Given the rapid expansion in the demand for mineral commodities that underpin worldwide economic growth and technological advancement, information regarding expected country-level mine production and production capacity is becoming increasingly important to industry stakeholders, end users, and policymakers. Production capacity can limit future supply, depending on how rapidly that capacity is able to expand. Current capacity can be evaluated on the basis of past production. Decreases to future capacity can be taken into account from announcements of planned shutdowns of mines or processing facilities, which are frequently publicized well in advance of such closures. Likewise, capacity expansions, which usually involve multiple stages—such as permitting, financing, and construction (all of which take time)—can also be estimated. As such, it is possible to evaluate midterm future capacity based on estimates of today’s capacities along with consideration of future investment plans. This World Minerals Outlook provides estimated capacities for cobalt, gallium, helium, lithium, magnesium, palladium, platinum, and titanium for 2025 through 2029. The results of this analysis indicate that two mineral commodities important to the manufacture of lithium-ion batteries—cobalt and lithium—are expected to have large capacity growth in the next few years, likely owing to expectations for increased demand for these batteries. For gallium, helium, palladium, and platinum, capacity is expected to remain stable or exhibit moderate growth. Still, these expected capacity levels are higher than current production, allowing for future production growth. The production capacity outlook is opaque for magnesium and titanium metal, which have a significant fraction of current production in nonmarket economies, such as China and Russia. Ultimately, though, where free market conditions prevail, full utilization of capacity potential for those commodities is likely to depend on supply deficits and prices that are above production costs.

Scientific Investigations Report↗
USGS2026

Variable pH habitats could help prepare stone crabs for coastal acidification

Coastal acidification is being exacerbated by terrestrial organic inputs, especially after high precipitation events. Florida’s rainy season coincides with stone crab ( Menippe mercenaria) reproduction, and pH extremes could limit future harvests by reducing reproductive output. Populations that experience pH variability can serve as “natural laboratories” for estimating the tolerance of a species to coastal acidification. Here, we conducted a series of experiments to determine if ovigerous stone crabs conditioned in more variable pH habitats (seagrass) would result in faster embryonic development, greater hatching success, and higher larval survival relative to crabs conditioned in habitats with lower pH variability (sandy habitats). After field conditioning, crabs were transported to the laboratory and randomly acclimated to either a control pH (pH = ~ 7.90) or a reduced pH condition (pH = ~ 7.60) until larval release. The rate of embryo development was slower in the laboratory reduced pH treatment, however, there were no observable field condition effects on embryo development rate. Crabs conditioned in the more pH variable seagrass habitat did have greater hatching success and higher larval survival than crabs in less pH variable sandy habitats; however, larval survival was low across all treatments. These results suggest that the pH variability experienced in seagrass habitats during brooding may serve as a mechanism for stone crabs to acclimatize to extremes in seawater pH.

Marine Biology↗
USGS2025

Factors influencing landslide occurrence in low-relief formerly glaciated landscapes: Landslide inventory and susceptibility analysis in Minnesota, USA

In landscapes recently impacted by continental glaciation, landslides may occur where topographic relief has been generated by the drainage of glacial lakes and ensuing post-glacial fluvial network development into unconsolidated glacially derived sediments and exhumed bedrock. To investigate linkages among environmental variables, post-glacial landscape development, and landslides, we created a landslide inventory of nearly 10,000 landslides in five regions of the formerly glaciated low-relief state of Minnesota, USA. Multivariate logistic regression indicates the importance of slope angle, lithology, and the development of stream valleys to landslide distribution. Areas underlain by fine-grained glaciolacustrine and nearshore deposits that are incised by streams are particularly prone to shallow (<1-2 m depth) landslides. Landslides also occur in a wide range of glacial and fluvial deposits, and as rockfall in layered Paleozoic sedimentary rocks in central and southern Minnesota and Precambrian igneous and sedimentary rocks in northeastern Minnesota. Although no more than 1-2% of the studied regions are susceptible to landslides, they can pose risk to life and safety, damage infrastructure, and impact water quality. The combination of recently generated low-relief steep slopes, extensive unconsolidated sediments, and layered sedimentary bedrock make this formerly glaciated landscape more susceptible to landslides than current national-scale models indicate.

Minnesota↗
USGS2025

Re-Os geochronology of molybdenite by LA-ICP-MS/MS

Re-Os geochronology is a powerful tool to directly date sulphide mineralisation using phases such as molybdenite, pyrite and chalcopyrite. We present a snapshot of a method in development utilizing laser ablation inductively coupled-plasma ‘triple quad’ mass spectrometry (LA-ICP-MS/MS) for Re-Os geochronology of molybdenite. While traditional LA-(MC)-ICP-MS measurements are limited by the >90% isobaric interference correction of parent radioactive 187 Re on radiogenic daughter 187 Os, the MS/MS technology minimizes this correction through careful instrument tuning and use of a (CH 4 + H 2 + He) reaction gas mixture to mass shift 187 Os away from 187 Re. We demonstrate the potential of the MS/MS technique by presenting robust Re-Os dates for three different molybdenite samples ranging in age from ~28 to 1520 Ma.

Conference Paper↗
USGS2025

Climate-driven sulfate export in alpine watersheds may stimulate methylmercury production

Climate change is increasing sulfate export and changing wetland extent in mountain regions. These changes may increase microbially mediated production of the neurotoxic substance methylmercury due to enhanced sulfate metabolism in mountain environments. Here, we assess methylmercury concentrations and formation rates across high-elevation wetlands in the Colorado Rocky Mountains. We also investigate sulfate controls on methylmercury production within subalpine peatlands by amending soils with sulfate to mimic increased stream export of sulfate from the alpine zone and measuring methylmercury formation rates for different sulfate treatments. We found that subalpine peatlands have statistically significant higher methylmercury concentrations and formation rates compared to alpine, mineral-soil wetlands. Methylmercury production in subalpine peatlands also increased significantly ( p < 0.05) following sulfate additions; the highest rates occurred in sediments with intermediate extractable sulfate concentrations (∼0.60–1.4 mg sulfate g −1 dry soil). Our study is the first to identify soil sulfate-related thresholds for methylmercury production and sulfate-limitation of methylmercury production in subalpine peatlands. These findings highlight important linkages between climate-driven mineral weathering and mercury cycling in mountain regions globally.

Colorado↗