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1,663 records · Page 87Linked to original sources

Re-Os geochronology of molybdenite by LA-ICP-MS/MS

Re-Os geochronology is a powerful tool to directly date sulphide mineralisation using phases such as molybdenite, pyrite and chalcopyrite. We present a snapshot of a method in development utilizing laser ablation inductively coupled-plasma ‘triple quad’ mass spectrometry (LA-ICP-MS/MS) for Re-Os geochronology of molybdenite. While traditional LA-(MC)-ICP-MS measurements are limited by the >90% isobaric interference correction of parent radioactive 187 Re on radiogenic daughter 187 Os, the MS/MS technology minimizes this correction through careful instrument tuning and use of a (CH 4 + H 2 + He) reaction gas mixture to mass shift 187 Os away from 187 Re. We demonstrate the potential of the MS/MS technique by presenting robust Re-Os dates for three different molybdenite samples ranging in age from ~28 to 1520 Ma.

Conference Paper

Climate-driven sulfate export in alpine watersheds may stimulate methylmercury production

Climate change is increasing sulfate export and changing wetland extent in mountain regions. These changes may increase microbially mediated production of the neurotoxic substance methylmercury due to enhanced sulfate metabolism in mountain environments. Here, we assess methylmercury concentrations and formation rates across high-elevation wetlands in the Colorado Rocky Mountains. We also investigate sulfate controls on methylmercury production within subalpine peatlands by amending soils with sulfate to mimic increased stream export of sulfate from the alpine zone and measuring methylmercury formation rates for different sulfate treatments. We found that subalpine peatlands have statistically significant higher methylmercury concentrations and formation rates compared to alpine, mineral-soil wetlands. Methylmercury production in subalpine peatlands also increased significantly ( p < 0.05) following sulfate additions; the highest rates occurred in sediments with intermediate extractable sulfate concentrations (∼0.60–1.4 mg sulfate g −1 dry soil). Our study is the first to identify soil sulfate-related thresholds for methylmercury production and sulfate-limitation of methylmercury production in subalpine peatlands. These findings highlight important linkages between climate-driven mineral weathering and mercury cycling in mountain regions globally.

Colorado

A targeted approach for mapping groundwater discharge to surface water and fish thermal refuge in four Lake Ontario tributaries

The duration, magnitude, and frequency of heatwaves are predicted to increase in the coming decades, a combination that can reduce the survival of many fish species. Across the world, there is broad interest in identifying thermal refuge for heat-intolerant fish species and exploring opportunities to enhance or protect these areas. Because deeper groundwater maintains a relatively constant temperature, groundwater-influenced areas along streams can provide cool-water refuge for fish during periods of extreme heat. A targeted approach was developed for identifying existing cold-water zones and areas of substantial groundwater discharge in four high priority Lake Ontario tributaries. Our approach included: (1) predicting where groundwater discharge is most likely with a simple geospatial model and (2) using model predictions to select field sites for intensive high-resolution study, including ground-based mapping of groundwater features (springs, seeps, tributaries) as well as drone-based optical and thermal infrared surveys. Results from field sites were used to both verify model performance and map different types and aerial extents of thermal anomalies. Geospatial modelling successfully predicted regions of widespread groundwater upwelling, later verified and mapped by field and drone surveys. Comparison of model and field survey results further highlighted specific geospatial layers, such as soil/bedrock types and topographic wetness index, as being particularly useful for predicting groundwater influence on streams in the study area. In addition, a comparison of geospatial model results with a model of fish abundances along the studied streams showed significant positive correlations for many heat-intolerant fish species over a wide geographic area. The approach developed in this study can be applied to other watersheds to highlight areas of probable groundwater discharge and could be used by fishery and water resource managers to support cold-water fish habitat management decision-making and resource conservation.

New York

Paleoseismology and paleogeodesy using coral microatolls

Establishing the rupture extent and slip distribution of individual paleo-earthquakes is vital for assessing fault behavior including the persistence of rupture segmentation, recurrence patterns, and similarity of successive events, key issues in both fault mechanics and hazard assessment. Techniques with high temporal and geodetic precision as well as a wide distribution of study sites are necessary to investigate past earthquakes in such detail. Coral microatoll growth is one of the best types of geologic record for paleoseismology and paleogeodesy given these needs, as it provides long, continuous, widely distributed records of centimeter-scale vertical tectonic motion with potentially annual-level temporal precision. This chapter describes the process of interpreting microatoll growth records to obtain time series of relative sea level, tectonic vertical deformation fields, and finally slip and coupling parameters on an underlying fault interface.

Book chapter

Framework for mapping liquefaction hazard–Targeted design ground motions

Liquefaction-induced ground failure poses substantial challenges to geotechnical earthquake engineering design. Current approaches for designing against liquefaction hazards, as specified in most seismic provisions, focus on estimating a liquefaction factor of safety ( 𝐹⁢𝑆𝐿 ) and typically characterize earthquake loading using design parameters based on probabilistic or deterministic ground motion levels. Because 𝐹⁢𝑆𝐿 is estimated deterministically, this basis of design neglects considerable uncertainties for estimating liquefaction triggering and its consequences and results in a lack of liquefaction-specific design criteria, particularly as structural design has advanced toward risk-targeted performance objectives. This study presents a framework for developing liquefaction-targeted design criteria based on a minimum acceptable return period of liquefaction, informed by probabilistic liquefaction hazard analysis (PLHA). PLHA quantifies annualized rates of liquefaction by considering contributions from (1) the full ground-motion probability space, and (2) uncertainties in liquefaction triggering using probabilistic models. PLHA is used in this study to characterize the current, effective return periods of 𝐹⁢𝑆𝐿 ( 𝑇𝑅,𝐹⁢𝑆 ) obtained from conventional liquefaction hazard analysis (CLHA) using uniform-hazard ground motions. 𝑇𝑅,𝐹⁢𝑆 is evaluated in a parametric study of nearly 100 sites throughout the conterminous United States. The results indicate large geographic variations in acceptable liquefaction hazard levels, with implied 𝑇𝑅,𝐹⁢𝑆 ranging between approximately 1,000 to 3,000 years. To address these inconsistencies without the computational demands of full PLHA, a framework is proposed for developing a liquefaction-targeted design peak ground acceleration, 𝑃⁢𝐺⁢𝐴𝐿 , for use in liquefaction models that result in consistent liquefaction design levels across all geographic locations. The mapped 𝑃⁢𝐺⁢𝐴𝐿 is shown to be somewhat sensitive to site-specific properties, and adjustment factors are developed and presented. The proposed 𝑃⁢𝐺⁢𝐴𝐿 mapping procedure produces 𝐹⁢𝑆𝐿 estimates that are consistent with those obtained from full PLHA at a target 𝑇𝑅,𝐹⁢𝑆 , providing a promising roadmap to incorporating PLHA concepts into current liquefaction design methods.

Journal of Geotechnical and Geoenvironmental Engin

Ambient field seismology in critical zone hydrological sciences

Passive ambient noise monitoring is an emerging tool in environmental seismology, leveraging the ambient seismic field to assess temporal variations in shallow subsurface properties. This review focuses on the potential and challenges of using scattered coda waves from noise correlation functions to monitor critical zone dynamics. The sensitivity of seismic velocities to various environmental factors, including precipitation, snowmelt, atmospheric pressure, and groundwater fluctuations, underscores the method’s versatility. While coda waves excel in detecting subtle changes due to their scattered nature, ballistic waves provide higher spatial resolution, albeit with challenges in source stability. Advances in seismic sensing, including distributed acoustic sensing and low-cost geophone networks, have enabled high-resolution monitoring of hydrological processes, subsurface deformation, and seismic hazards. Integrating seismic data with hydrological models provides insights into water storage, pore pressure changes, and soil moisture dynamics. However, limitations in spatial resolution, calibration with ground truth data, and coupled effects between environmental factors remain key challenges. This review emphasizes the importance of interdisciplinary approaches in refining methodologies, enhancing sensor deployments, and addressing data gaps. Passive seismic monitoring offers opportunities to understand critical zone processes and their broader impacts on seismic hazards and environmental sustainability.

Comptes Rendus. Géoscience

Geothermal district energy systems coupled with seasonal underground thermal energy storage: A U.S. techno-economic screening by climate and geology

In the United States, cooling-dominated commercial building loads can cause geothermal heat pump-based district energy systems to accumulate a long-term subsurface thermal imbalance, motivating the incorporation of seasonal underground thermal energy storage. We developed a transferable workflow to evaluate geothermal district systems that pair ground heat exchangers with seasonal underground thermal energy storage. Using standardized hourly loads for seven commercial buildings and a uniform cost framework, we simulated ten U.S. cities with a physics-based ground heat exchanger model, subsurface storage simulations, and economic assessment to isolate the roles of climate and hydrogeology. In cooling-dominated cities, underground thermal energy storage supplied the majority of annual cooling, cutting electricity use and summer peaks substantially while achieving levelized costs comparable to or below conventional chiller-boiler plants. In cooler climates, the storage share shrunk, required borefield size and costs rose, and levelized cost of energy increased nearly linearly with declining underground thermal energy storage fraction, indicating storage fraction as the primary economic lever. Sensitivity analysis showed capital risk dominated by borefield drilling and surface heating, ventilation, and air-conditioning and piping, with underground thermal energy storage costs secondary. This workflow provides a transparent foundation for site-specific design and screening of next-generation geothermal district energy systems.

Arizona, Illinois, Maryland, Michigan, Mississippi

Geoelectric evidence for a wide spatial footprint of active extension in central Colorado

Three-dimensional magnetotelluric (MT) imaging in central Colorado reveals a set of north-striking high-conductivity tracks at lower-crustal (50–20 km) depths, with conductive finger-like structures rising off these tracks into the middle crust (20–5 km depth). We interpret these features to represent saline aqueous fluids and partial melt that are products of active extensional tectonomagmatism. These conductors are distributed over a wider region than the narrow corridor along which Rio Grande rift structures are traditionally mapped at the surface, and they consequently demarcate regions of the lower crust where accommodation of bulk extensional strain has concentrated conductive phases. Our observations reveal limitations in existing models of Rio Grande rift activity and may reflect unrecognized spatiotemporal variations in rift system evolution globally.

Colorado

Technique for estimating magnitude and frequency of floods in Kentucky

This report presents flood magnitude and frequency relations applicable to unregulated streams in Kentucky. The relations are based on flood data at 117 gaging stations in Kentucky and 14 in adjacent states having 10 or more years of record not significantly affected by man-made changes. Equations that relate flood magnitude and frequency to contributing drainage area in 16 geographic areas may be used to estimate magnitude of future floods with recurrence intervals of as much as 100 years on gaged and ungaged streams having drainage areas of 10 to 4,300 square miles (25 .9 to 11,100 square kilometers) . Estimating equations are also presented in graphical form for the convenience of the user. Additional graphs are presented to estimate flood magnitude for selected recurrence intervals along the Cumberland, Kentucky, and Ohio Rivers.

Kentucky

A time-space model of graphite mineral systems

Increasing demand for graphite in energy storage systems warrants review of graphite ore genesis in a mineral systems framework. Orogenic graphite encompasses the metamorphic and orogenic mineral systems that produce flake graphite and hydrothermal vein (lump and chip) graphite deposits, respectively. A common feature of orogenic graphite deposits is an association with upper amphibolite- to granulite-facies metasedimentary rocks in continent-continent or continent-island arc collisional orogens. Orogenic flake graphite deposits form primarily through graphitization of organic carbon during regional metamorphism, but strain localization and partial melting of pelitic protoliths are likely important processes for graphite grade and quality enrichment. Orogenic vein graphite deposits precipitate from hydrothermal fluids, possibly derived from metamorphism or anatexis at depth. Decarbonation reactions in mixed calcareous-carbonaceous metasedimentary sequences are the most likely carbon sources for the veins. In contrast, intrusion-related graphite includes magmatic-hydrothermal and metamorphic mineral systems that form primarily in continental arc settings via the interaction of magmas with carbonaceous sedimentary packages. Magmatic-hydrothermal flake graphite deposits are hosted in plutonic and volcanic rocks, and result from the exsolution of CO 2 -CH 4 -rich fluids from melts contaminated by such packages. Contact metamorphism of carbonaceous sedimentary rocks by plutons produces some microcrystalline (amorphous) graphite deposits, including many in China. Compilation of geologic data from known graphite deposits globally suggests that pulses of carbon deposition in the Paleoproterozoic, Mesoproterozoic, and Neoproterozoic provided source carbon material. Subsequent supercontinent orogenesis at ca. 2,100 to 1,700 Ma (Columbia), ca. 1,300 to 1,000 Ma (Rodinia), and ca. 650 to 500 Ma (Gondwana) resulted in the genesis of orogenic flake and vein graphite deposits, where favorable geologic components overlapped with organic ± carbonate carbon-rich strata. Cryogenian deposition of graphite protoliths and Cryogenian – Cambrian metamorphic mineralization account for nearly 75% of all known resources globally and coincide with profound carbon isotope excursions and climate variability, implying a link with the global carbon budget. Comparatively few graphite deposits are associated with Pangea-forming orogens, attributed to less exhumation and/or denudation. High-temperature metasedimentary belts containing organic carbon-rich protoliths are most favorable for hosting orogenic flake graphite deposits, whereas sequences that also contain carbonate protoliths are favorable for orogenic graphite veins. Continent-scale orogenic belts may host both deposit types along with vanadium deposits. Use of a time-space mineral systems framework for graphite deposits can improve exploration models needed to ensure future supply of this critical mineral and provide insights into Earth’s long-term carbon cycle.

Mineralium Deposita

Estimating paleotemperature using stable isotopes of soil-formed phyllosilicates from paleosols: A review

Fossilized soils, or paleosols, contain soil-formed phyllosilicates whose stable isotopic compositions may be used to calculate paleotemperature and thus reconstruct ancient terrestrial environments. Though paleosols are common in the geologic record, the use of phyllosilicates as paleotemperature proxies is limited in the literature owing to difficulties with selecting optimal paleosols, isolation from non-clay minerals and organic materials, mixtures of phyllosilicates in natural samples, wide variations of chemical compositions for phyllosilicates, and limited to undefined equilibrium fractionation factors between phyllosilicates-water. Here, we address these challenges by examining and comparing methods used for sample selection, mineral isolation, pretreatments, mineral identification, conventional and developing methods for oxygen and hydrogen isotopic analyses, and determination of phyllosilicate-water equilibrium fractionation factors, concluding with recommendations for best approaches for paleotemperature estimation. Additionally, we discuss how to identify and avoid detrital phyllosilicates, the impacts of diagenesis, comparison of stable isotope and non-isotope paleosol paleotemperature proxies, and challenges and opportunities for broadly using paleosols as paleoclimate archives. With ongoing efforts to refine this multi-faceted paleotemperature approach, the stable isotope geochemistry of soil-formed phyllosilicates continues to be an invaluable proxy system, enhancing our understanding of terrestrial paleoenvironments and paleoclimate.

Kansas

Fingerprinting magmatic REE deposit sources with zircon petrochronology

Carbonatites and associated alkaline silicate rocks are of considerable economic interest due to their enrichments in rare earth elements. The petrogenesis and source(s) of these complexes, however, are poorly understood. Models propose either mantle plume-derived carbon-rich melts or a mantle source enriched by subduction-related metasomatism. We use zircon trace elements to fingerprint carbonatite-alkaline complex sources, focusing on the economically significant 1.4 Ga Mountain Pass intrusive suite (MPIS). Autocrystic zircon from MPIS alkaline silicate rocks are enriched in Th and U relative to Nb suggesting a subduction influenced, oxidized source region. Lower Sc/Yb, higher Ti concentrations, and the absence of Eu anomalies in autocrystic zircon suggest derivation from a less hydrous, hotter, and deeper mantle source relative to arc-related 1.8–1.6 Ga inherited zircon. These data are best explained by syn- to post-collisional Mesoproterozoic reactivation of a subduction-metasomatized mantle source. The source and tectonic setting of the MPIS contrasts with Mesoproterozoic Gifford Creek and Bayan Obo carbonatites which exhibit plume-like compositions and are associated with rifts, suggesting different sources and tectonic settings for these economically significant deposits. We demonstrate that zircon petrochronology is a robust method for distinguishing carbonatite sources and can inform more targeted exploration strategies for critical mineral resources.

Conference Paper

Effect of land cover type on 3D deformation recovery from synthetically deformed high-resolution satellite optical imagery

The limits of detection for earthquake surface deformation in the spatial domain have improved with advances in remote sensing imagery data availability, resolution, and analysis. Sub-pixel correlation and digital elevation model (DEM) differencing from sub-meter, earthquake-spanning satellite optical imagery has enhanced surface rupture mapping and deformation measurements. However, knowledge of measurement accuracy and uncertainty is limited. To address this, we construct orthophotos and digital elevation models (DEMs) from repeat high resolution (∼0.5 m) satellite optical imagery along two sections of the Garlock fault, California with clear fault geomorphology and differing land cover. We deform later sets of DEMs and images with synthetic earthquakes containing both diffuse and discrete horizontal and vertical displacements. Sub-pixel image correlation and DEM differencing demonstrate how vegetation degrades recovered displacement accuracy. In barren land cover, horizontal displacements are detectable to an expected ∼1/10th-pixel size. With shrubs, trees, and grass, detectable displacements increase to >1/2-pixel size, and filtering results by correlation score and using elevation values as input rather than image values improves accuracy. Vertical displacement detection thresholds remain lower in vegetation, at >1-pixel size. Higher slope angles degrade displacement recovery, worsened by vegetation. Diminishing seasonal separation improves accuracy over vegetated regions, though not to the level achieved in barren environments. These results will inform research and operational efforts on the utility of high resolution satellite optical imagery for detecting deformation in varied land cover. Furthermore, they reveal where alternative measurements, such as from LiDAR or radar interferometry, are required to mitigate the effects of vegetation and capture fine-scale crustal deformation.

California

Tracing mercury from land to river: Global sources, retention, and implications for sustainability

Mercury (Hg) pollution in river systems is a global sustainability challenge. Yet the transport, transformation, and retention of Hg within global rivers remain poorly quantified, particularly in regions with sparse observations such as Southeast Asia and Africa, hindering effective pollution mitigation and reinforcing geographic inequities in scientific knowledge and environmental governance. Here, we present the first global, high-resolution simulation of riverine Hg dynamics using a process-based model that traces Hg from land-based sources through river networks to the ocean. Under a realistic scenario, we estimate that ~1,900 megagrams per year (Mg/yr) of Hg enters global rivers, including 1,500 Mg/yr from human-induced sources and 400 Mg/yr from soil erosion. Nearly half of this flux (~1,000 Mg/yr) is retained in reservoirs and dams, which act as major sinks. While such retention limits downstream delivery to the oceans, it also heightens in-reservoir Hg methylation risks. By bridging the gap between Hg releases and observed riverine exports, our framework offers a scalable tool for data-limited regions, promotes data access, and supports global freshwater and pollution-management strategies.

EarthArXiv

Season and antecedent conditions impact concentration-discharge relationships for dissolved organic carbon and alkalinity in southeast Alaskan watershed

Fluvial export of dissolved carbon plays an important role in watershed-scale biogeochemistry. Predicted changes in climate are expected to impact watershed hydrologic regimes, and in turn, the sources and export of dissolved carbon from watersheds. Here, we utilize high resolution measurements of discharge and dissolved carbon concentration to examine how concentration-discharge (CQ) relationships vary seasonally and during high flow events over the main runoff season (May–October) in a temperate forested watershed in Southeast Alaska. Concentration-discharge relationships for dissolved organic carbon (DOC) and alkalinity demonstrated strong seasonal patterns, with more linear relationships in May and June versus other months. Changing power law model slopes ( b values; the exponent in a power law regression between runoff and carbon yields) indicated potentially shifting watershed sources (biogenic vs. geologic) and contrasting dominant flowpaths (shallow vs. deeper groundwater) for DOC and alkalinity over the sampling period. During the largest storm event of the study, DOC and alkalinity b values shifted from an overall pattern of transport (mean b = 1.58 values >1.0 indicate transport limitation) and source limitation (mean b = 0.48, values <1.0 indicate source limitation) to chemostatic (DOC, b = 0.99; alkalinity, b = 1.019). In June through August, patterns in hysteresis index suggest that CQ relationships were altered when storms followed in close succession to each other. Together, these findings indicate that seasonal and antecedent flow conditions play a role in dissolved carbon export from forested watersheds. Understanding these dynamics, particularly during winter months, will become increasingly important as changes to hydroclimate impact riverine carbon export.

Alaska

Tracing mercury from land to river: Global sources, retention, and implications for sustainability

Mercury (Hg) pollution in river systems is a global sustainability challenge. Yet the transport, transformation, and retention of Hg within global rivers remain poorly quantified, particularly in regions with sparse observations such as Southeast Asia and Africa, hindering effective pollution mitigation and reinforcing geographic inequities in scientific knowledge and environmental governance. Here, we present the first global, high-resolution simulation of riverine Hg dynamics using a process-based model that traces Hg from land-based sources through river networks to the ocean. Under a realistic scenario, we estimate that ∼1900 megagrams per year (Mg/yr) of Hg enters global rivers, including 1500 Mg/yr from human-induced sources and 400 Mg/yr from soil erosion. Nearly half of this flux (∼1000 Mg/yr) is retained in reservoirs and dams, which act as major sinks. While such retention limits downstream delivery to the oceans, it also heightens in-reservoir Hg methylation risks. By bridging the gap between Hg releases and observed riverine exports, our framework offers a scalable tool for data-limited regions, promotes data access, and supports global freshwater and pollution-management strategies.

Environmental Science & Technology

Physicochemical properties and bioreactivity of sub-10 µm geogenic particles: Comparison of volcanic ash and desert dust

Exposure to ambient particulate matter (PM) with an aerodynamic diameter of <10 μm (PM 10 ) is a well-established health hazard. There is increasing evidence that geogenic (Earth-derived) particles can induce adverse biological effects upon inhalation, though there is high variability in particle bioreactivity that is associated with particle source and physicochemical properties. In this study, we investigated physicochemical properties and biological reactivity of volcanic ash from the April 2021 eruption of La Soufrière volcano, St. Vincent, and two desert dust samples: a standardized test dust from Arizona and an aeolian Gobi Desert dust sampled in China. We determined particle size, morphology, mineralogy, surface texture and chemistry in sub-10 μm material to investigate associations between particle physicochemical properties and observed bioreactivity. We assessed cellular responses (cytotoxic and pro-inflammatory effects) to acute particle exposures (24 hr) in monocultures at the air-liquid interface using two types of cells of the human airways: BEAS-2B bronchial epithelial cells and A549 alveolar type II epithelial cells. In acellular assays, we also assessed particle oxidative potential and the presence of microorganisms. The results showed that volcanic ash and desert dust exhibit intrinsically different particle morphology, surface textures and chemistry, and variable mineralogical content. We found that Gobi Desert dust is more bioreactive than freshly erupted volcanic ash and Arizona test dust, which is possibly linked to the presence of microorganisms (bacteria) and/or nanoscale elongated silicate minerals (potentially clay such as illite or vermiculite) on particle surfaces.

GeoHealth

Beyond optimality: Dryland ecosystems infrequently use water efficiently for carbon gain

Optimality theory assumes plants maximize carbon gain per unit water lost and is often implemented to scale leaf-level carbon gain and water use to regional and global scales. Optimality theory is often mathematically represented by assuming plant water-use efficiency (WUE) scales with VPD k , where k = ½ represents expected optimal behavior. It is unclear, however, if this relationship holds in arid and semi-arid ecosystems that are strongly impacted by soil and atmospheric moisture status. We used data from seven flux tower sites along an aridity gradient in New Mexico to answer: how does the relationship between WUE and VPD compare to expectations based on optimality theory? To address this question, we integrated the Dynamic Evapotranspiration Partitioning Approach for Rapid Timescales with a stochastic antecedent model to estimate ecosystem-level WUE (GPP/T) and the net sensitivity of WUE to VPD, or k Dynamic , which we compare to the theoretical optimal sensitivity of k = ½. Our results show that optimality theory is not always appropriate, and k Dynamic often deviates from ½, especially at some of the more arid sites or during periods of low soil moisture. At less arid, higher elevation sites, k Dynamic is most consistent with optimality theory at moderate VPD levels, but not at high VPD. In general, the sensitivity of WUE to VPD is highly variable such that k Dynamic exhibits notable daily and seasonal variability, suggesting highly dynamic stomatal behavior. These results emphasize that representing plant water-use strategies as dynamic in time and space is critical to improving large-scale estimates of plant water use.

New Mexico