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Guidelines and standard procedures for studies of ground-water quality; selection and installation of wells, and supporting documentation

This is the first of a two-part report to document guidelines and standard procedures of the U.S. Geological Survey for the acquisition of data in ground-water-quality studies. This report provides guidelines and procedures for the selection and installation of wells for water-quality studies/*, and the required or recommended supporting documentation of these activities. Topics include (1) documentation needed for well files, field folders, and electronic files; (2) criteria and information needed for the selection of water-supply and observation wells, including site inventory and data collection during field reconnaissance; and (3) criteria and preparation for installation of monitoring wells, including the effects of equipment and materials on the chemistry of ground-water samples, a summary of drilling and coring methods, and information concerning well completion, development, and disposition.

Water-Resources Investigations Report↗

Water-Level Changes in the High Plains Aquifer, Predevelopment to 2007, 2005-06, and 2006-07

The High Plains aquifer underlies 111.6 million acres (174,000 square miles) in parts of eight States - Colorado, Kansas, Nebraska, New Mexico, Oklahoma, South Dakota, Texas, and Wyoming. Water-level declines began in parts of the High Plains aquifer soon after the beginning of substantial irrigation with ground water in the aquifer area. This report presents water-level changes in the High Plains aquifer from the time before substantial ground-water irrigation development had occurred (about 1950 and termed 'predevelopment' in this report) to 2007, from 2005-06, and from 2006-07. The report also presents the percentage change in saturated thickness of the aquifer, from predevelopment to 2007. Measured water-level changes from predevelopment to 2007 ranged from a rise of 84 feet in Nebraska to a decline of 234 feet in Texas. The area-weighted, average water-level changes in the aquifer were a decline of 14.0 feet from predevelopment to 2007, a decline of 0.4 foot during 2005-06, and a decline of 0.6 foot during 2006-07. Total water in storage in the aquifer in 2007 was about 2.9 billion acre-feet, which was a decline of about 270 million acre-feet since predevelopment.

Scientific Investigations Report↗

Water-level changes in the High Plains aquifer, predevelopment to 2009, 2007-08, and 2008-09, and change in water in storage, predevelopment to 2009

The High Plains aquifer underlies 111.8 million acres (175,000 square miles) in parts of eight States - Colorado, Kansas, Nebraska, New Mexico, Oklahoma, South Dakota, Texas, and Wyoming. Water-level declines began in parts of the High Plains aquifer soon after the beginning of substantial irrigation with groundwater in the aquifer area. This report presents water-level changes in the High Plains aquifer from the time before substantial groundwater irrigation development had occurred (about 1950 and termed "predevelopment" in this report) to 2009, from 2007-08, and from 2008-09. The report also presents change in water in storage in the aquifer, from predevelopment to 2009. Ninety-nine percent of the water-level changes from predevelopment to 2009 ranged from a rise of 41 feet to a decline of 178 feet. The area-weighted, average water-level changes in the aquifer were a decline of 14.0 feet from predevelopment to 2009, a decline of 0.1 foot from 2007-08, and a decline of 0.3 foot from 2008-09. Total water in storage in the aquifer in 2009 was about 2.9 billion acre-feet, which was a decline of about 274 million acre-feet since predevelopment.

Colorado;Kansas;Nebraska;New Mexico;Oklahoma;South↗

Volcano hazards assessment for the Lassen region, northern California

The Lassen region of the southernmost Cascade Range is an active volcanic area. At least 70 eruptions have occurred in the past 100,000 years, including 3 in the past 1,000 years, most recently in 1915. The record of past eruptions and the present state of the underlying magmatic and hydrothermal systems make it clear that future eruptions within the Lassen Volcanic Center are very likely. Although the annual probability of an eruption is small, the consequences of some types of eruptions could be severe. Compared to those of a typical Cascade composite volcano, eruptive vents at Lassen Volcanic Center and the surrounding area are widely dispersed, extending in a zone about 50 km wide from the southern boundary of Lassen Volcanic National Park north to the Pit River. This report presents a discussion of volcanic and other geologic hazards in the Lassen area and delineates hazards zones for different types of volcanic activity. Owing to its presence in a national park with significant visitorship, its explosive behavior, and its proximity to regional infrastructure, the Lassen Volcanic Center has been designated a "high threat volcano" in the U.S. Geological Survey National Volcano Early Warning System assessment. Volcanic eruptions are typically preceded by seismic activity and ground deformation, and the Lassen area has a network of seismometers and Global Positioning System stations in place to monitor for early warning of volcanic activity.

California↗

Hydrology of the Black Hills area, South Dakota

The Black Hills Hydrology Study was initiated in 1990 to assess the quantity, quality, and distribution of surface water and ground water in the Black Hills area of South Dakota. This report summarizes the hydrology of the Black Hills area and the results of this long-term study. The Black Hills area of South Dakota and Wyoming is an important recharge area for several regional, bedrock aquifer systems and various local aquifers; thus, the study focused on describing the hydrologic significance of selected bedrock aquifers. The major aquifers in the Black Hills area are the Deadwood, Madison, Minnelusa, Minnekahta, and Inyan Kara aquifers. The highest priority was placed on the Madison and Minnelusa aquifers, which are used extensively and heavily influence the surface-water resources of the area. Within this report, the hydrogeologic framework of the area, including climate, geology, ground water, and surface water, is discussed. Hydrologic processes and characteristics for ground water and surface water are presented. For ground water, water-level trends and comparisons and water-quality characteristics are presented. For surface water, streamflow characteristics, responses to precipitation, annual yields and yield efficiencies, and water-quality characteristics are presented. Hydrologic budgets are presented for ground water, surface water, and the combined ground-water/surface-water system. A summary of study findings regarding the complex flow systems within the Madison and Minnelusa aquifers also is presented.

South Dakota↗

Magnitude and frequency of floods in small drainage basins in Idaho

A method is presented in this report for determining magnitude and frequency of floods on streams with drainage areas between 0.5 and 200 square miles. The method relates basin characteristics, including drainage area, percentage of forest cover, percentage of water area, latitude, and longitude, with peak flow characteristics. Regression equations for each of eight regions are presented for determination of QIQ/ the peak discharge, which, on the average, will be exceeded once in 10 years. Peak flows, Q25 and Q 50 , can then be estimated from Q25/Q10 and Q-50/Q-10 ratios developed for each region. Nomographs are included which solve the equations for basins between 1 and 50 square miles. The regional regression equations were developed using multiple regression techniques. Annual peaks for 303 sites were analyzed in the study. These included all records on unregulated streams with drainage areas less than about 500 square miles with 10 years or more of record or which could readily be extended to 10 years on the basis of nearby streams. The log-Pearson Type III method as modified and a digital computer were employed to estimate magnitude and frequency of floods for each of the 303 gaged sites. A large number of physical and climatic basin characteristics were determined for each of the gaged sites. The multiple regression method was then applied to determine the equations relating the floodflows and the most significant basin characteristics. For convenience of the users, several equations were simplified and some complex characteristics were deleted at the sacrifice of some increase in the standard error. Standard errors of estimate and many other statistical data were computed in the analysis process and are available in the Boise district office files. The analysis showed that QIQ was the best defined and most practical index flood for determination of the Q25 and 0,50 flood estimates. Regression equations are not developed because of poor definition for areas which total about 20,000 square miles, most of which are in southern Idaho. These areas are described in the report to prevent use of regression equations where they do not apply. They include urbanized areas, streams affected by regulation or diversion by works of man, unforested areas, streams with gaining or losing reaches, streams draining alluvial valleys and the Snake Plain, intense thunderstorm areas, and scattered areas where records indicate recurring floods which depart from the regional equations. Maximum flows of record and basin locations are summarized in tables and maps. The analysis indicates deficiencies in data exist. To improve knowledge regarding flood characteristics in poorly defined areas, the following data-collection programs are recommended. Gages should be operated on a few selected small streams for an extended period to define floods at long recurrence intervals. Crest-stage gages should be operated in representative basins in urbanized areas, newly developed irrigated areas and grasslands, and in unforested areas. Unusual floods should continue to be measured at miscellaneous sites on regulated streams and in intense thunderstorm-prone areas. The relationship between channel geometry and floodflow characteristics should be investigated as an alternative or supplement to operation of gaging stations. Documentation of historic flood data from newspapers and other sources would improve the basic flood-data base.

Idaho↗

Magnitude and frequency of floods from selected drainage basins in South Dakota

The 2-, 5-, 10-, 25-, 50-, and 100-year floods are determined for gaged sites on 120 selected, small drainage basins in South Dakota. These estimates are from the frequency curves defined from the streamflow records. Short-term records for 66 sites were extended on the basis of long-term climatic records and a rainfall-runoff model. These frequency curves may provide the best estimates of floods at these gaged sites. Analyses of flood-frequency information from these gaged sites have been the basis for techniques (published previously) used in estimating flood magnitude and frequency at ungaged sites in South Dakota. This report supplements flood-frequency information published earlier. It presents: Annual peak discharges colected during a 25-year period at 124 crest-stage partial-record stations; maximum observed and unit discharges determined for 124 crest-stage and 120 continuous-record gaging stations; updated flood-frequency curves for 120 crest-stage gages; a documentation of analytical procedures used; and a summary of the small-streams flood-peak data collection program in the State from 1955 to 1981. Maximum flood peaks determined at 244 partial- and continuous-record gaging stations and at 52 miscellaneous sites are compared with regional flood relationships.

South Dakota↗

Analysis of three tests of the unconfined aquifer in southern Nassau County, Long Island, New York

Drawdown and recovery data from three 2-day aquifer tests (OF) the unconfined (water-table) aquifer in southern Nassau County, N.Y., during the fall of 1979, were analyzed. Several simple analytical solutions, a typecurve-matching procedure, and a Galerkin finite-element radial-flow model were used to determine hydraulic conductivity, ratio of horizontal to vertical hydraulic conductivity, and specific yield. Results of the curve-matching procedure covered a broad range of values that could be narrowed through consideration of data from other sources such as published reports, drillers ' logs, or values determined by analytical solutions. Analysis by the radial-flow model was preferred because it allows for vertical variability in aquifer properties and solves the system for all observation points simultaneously, whereas the other techniques treat the aquifer as homogeneous and must treat each observation well separately. All methods produced fairly consistent results. The ranges of aquifer values at the three sites were: horizontal hydraulic conductivity, 140 to 380 feet per day; transmissivity 11,200 to 17,100 feet squared per day; ratio of horizontal to vertical hydraulic conductivity 2.4:1 to 7:1, and specific yield , 0.13 to 0.23. (USGS)

Water-Resources Investigations Report↗

The computer model Hydrotherm, a three-dimensional finite-difference model to simulate ground-water flow and heat transport in the temperature range of 0 to 1,200 degrees C

Quantitative modeling of the deep parts of magmatic- hydrothermal systems has been limited by the lack of publicly available, documented computer models for multiphase, high-temperature flow. This report documents HYDROTHERM, a finite-difference model for three-dimensional, multiphase flow of pure water and heat over a temperature range of 0 to 1,200 degrees Celsius and a pressure range of 0.5 *0 10,000 bars.HYDROTHEP*M is an extension of multiphase geothermal models developed by the U.S. Geological Survey in the 1970's. It solves numerical approximations to mass- and energy-balance equations that are posed in terms of pressure and enthalpy. Major assumptions are that the rock matrix can be treated as a porous medium; that water and rock are in thermal equilibrium; and that capillary pressure is negligible.

Water-Resources Investigations Report↗

Filtration of water-sediment samples for the determination of organic compounds

This report describes the equipment and procedures used for on-site filtration of surface-water and ground-water samples for determination of organic compounds. Glass-fiber filters and a positive displacement pumping system are suitable for processing most samples for organic analyses. An optional system that uses disposable in-line membrane filters is suitable for a specific gas chromatography/mass spectrometry, selected-ion monitoring analytical method for determination of organonitrogen herbicides. General procedures to minimize contamination of the samples include preparing a clean workspace at the site, selecting appropriate sample-collection materials, and cleaning of the equipment with detergent, tap water, and methanol.

Water-Resources Investigations Report↗

A three-dimensional method-of-characteristics solute-transport model (MOC3D)

This report presents a model, MOC3D, that simulates three-dimensional solute transport in flowing ground water. The model computes changes in concentration of a single dissolved chemical constituent over time that are caused by advective transport, hydrodynamic dispersion (including both mechanical dispersion and diffusion), mixing (or dilution) from fluid sources, and mathematically simple chemical reactions (including linear sorption, which is represented by a retardation factor, and decay). The transport model is integrated with MODFLOW, a three-dimensional ground-water flow model that uses implicit finite-difference methods to solve the transient flow equation. MOC3D uses the method of characteristics to solve the transport equation on the basis of the hydraulic gradients computed with MODFLOW for a given time step. This implementation of the method of characteristics uses particle tracking to represent advective transport and explicit finite-difference methods to calculate the effects of other processes. However, the explicit procedure has several stability criteria that may limit the size of time increments for solving the transport equation; these are automatically determined by the program. For improved efficiency, the user can apply MOC3D to a subgrid of the primary MODFLOW grid that is used to solve the flow equation. However, the transport subgrid must have uniform grid spacing along rows and columns. The report includes a description of the theoretical basis of the model, a detailed description of input requirements and output options, and the results of model testing and evaluation. The model was evaluated for several problems for which exact analytical solutions are available and by benchmarking against other numerical codes for selected complex problems for which no exact solutions are available. These test results indicate that the model is very accurate for a wide range of conditions and yields minimal numerical dispersion for advection-dominated problems. Mass-balance errors are generally less than 10 percent, and tend to decrease and stabilize with time.

Water-Resources Investigations Report↗

Ecological effects on streams from forest fertilization: Literature review and conceptual framework for future study in the western Cascades

Fertilization of forests with urea-nitrogen has been studied numerous times for its effects on water quality. Stream nitrogen concentrations following fertilization are typically elevated during winter, including peaks in the tens-of-thousands of parts per billion range, with summer concentrations often returning to background or near-background levels. Despite these increases, water-quality criteria for nitrogen have rarely been exceeded. However, such criteria are targeted at fish toxicity or human health and are not relevant to concentrations that could cause ecological disturbances. Studies of the responses of stream biota to fertilization have been rare and have targeted either immediate, toxicity-based responses or used methods insensitive to ongoing ecological processes. This report reviews water-quality studies following forest fertilizations, emphasizing Cascade streams in the Pacific Northwest and documented biological responses in those streams. A conceptual model predicting potential ecological response to fertilization, which includes effects on algal growth and primary production, is presented. In this model, applied fertilizer nitrogen reaching streams is mostly exported during winter. However, some nitrogen retained in soils or stream and riparian areas may become available to aquatic biota during spring and summer. Biological responses may be minimal in small streams nearest to application because of light limitation, but may be elevated downstream where light is sufficient to allow algal growth. Ultimately, algal response could be greatest in downstream reaches, although ambient nutrient concentrations remain low due to uptake and benthic nutrient recycling. Ground-water flow paths and hyporheic processing could be critical in determining the fate of applied nitrogen. A framework is provided for testing this response in the Little River watershed, a tributary to the North Umpqua River, Oregon, at basic and intensive levels of investigation.

Oregon↗

Uncertainty in the Great Lakes water balance

This report describes the Great Lakes hydrologic system and methods used to quantify individual components of the water balance. Potential sources of uncertainty are identified and, where appropriate, alternate or additional data, models, and estimation methods suitable for reducing uncertainties are discussed. Finally, approximate uncertainties of all components are identified, compared, and assessed within the context of net basin supply. Results indicate that average uncertainties in monthly estimates of individual water-balance components may range from 1.5 percent to 45 percent. These uncertainties may cause uncertainties in monthly net basin supply estimates of approximately 2,600 ft 3 /s to 33,500 ft 3 /s for individual Great Lakes.

Great Lake Basin↗

Simulation and particle-tracking analysis of ground-water flow near the Savannah River site, Georgia and South Carolina, 2002, and for selected ground-water management scenarios, 2002 and 2020

Ground-water flow under 2002 hydrologic conditions was evaluated in an eight-county area in Georgia and South Carolina near the Savannah River Site (SRS), by updating boundary conditions and pumping rates in an existing U.S. Geological Survey (USGS) ground-water model. The original ground-water model, developed to simulate hydrologic conditions during 1987-92, used the quasi-three-dimensional approach by dividing the Floridan, Dublin, and Midville aquifer systems into seven aquifers. The hydrogeologic system was modeled using six active layers (A2-A7) that were separated by confining units with an overlying source-sink layer to simulate the unconfined Upper Three Runs aquifer (layer A1). Potentiometric- surface maps depicting September 2002 for major aquifers were used to update, evaluate, and modify boundary conditions used by the earlier ground-water flow model. The model was updated using the USGS finite-difference code MODFLOW-2000 for mean-annual conditions during 1987-92 and 2002. The specified heads in the source-sink layer A1 were lowered to reflect observed water-level declines during the 1998-2002 drought. These declines resulted in a decrease of 12.1 million gallons per day (Mgal/d) in simulated recharge or vertical inflow to the uppermost confined aquifer (Gordon, layer A2). Although ground-water pumpage in the study area has increased by 32 Mgal/d since 1995, most of this increase (17.5 Mgal/d) was from the unconfined Upper Three Runs aquifer (source-sink layer A1) with the remaining 14.5 Mgal/d assigned to the active layers within the model (A2-A7). The simulated water budget for 2002 shows a decrease from the 1987-92 model from 1,040 Mgal/d to 1,035 Mgal/d. The decreased ground-water inflows and increased ground-water withdrawal rates reduced the simulated ground-water outflow to river cells in the active layers of the model by 43 Mgal/d. The calibration statistics for all layers of the 2002 simulation resulted in a decrease in the root mean square (RMS) of the residuals from 10.6 to 8.0 feet (ft). The residuals indicate 83.3 percent of the values for the 2002 simulation met the calibration error criteria established in the original model, whereas 88.8 percent was within the specified range for the 1987-92 simulation. Simulated ground-water outflow to the Savannah River and its tributaries during water year 2002 was 560 cubic feet per second (ft3/s), or 86 percent of the observed gain in mean-annual streamflow between streamflow gaging stations at the Millhaven, Ga., and Augusta, Ga. At Upper Three Runs Creek, simulated ground-water discharge during 2002 was 110 ft3/s, or 83 percent of the observed streamflow at two streamflow gaging stations near the SRS. These results indicate that the constructed model calibrated to 1987-92 conditions and modified for 2002 dry conditions is still representative of the hydrologic system. The USGS particle-tracking code MODPATH was used to generate advective water-particle pathlines and their associated time-of-travel based on MODFLOW simulations for 1987-92, 2002, and each of four hypothetical ground-water management scenarios. The four hypothetical ground-water management scenarios represent hydrologic conditions for (1) reported pumping for 2002 and boundary conditions for an average year; (2) reported pumping for 2002 with SRS pumping discontinued and boundary conditions for an average year; (3) projected 2020 pumping and boundary conditions for an average year; and (4) projected 2020 pumping and boundary conditions for a dry year. The MODPATH code was used in forward-tracking mode to evaluate flowpaths from areas on the SRS and in backtracking mode to evaluate further areas of previously documented trans-river flow on the Georgia side of the Savannah River. Trans-river flow is a condition in which the local head gradients might allow migration of contaminants from the SRS into the underlying aquifers and beneath the Savannah River into Georgia. More...

Georgia, South Carolina↗

Historical Changes in Precipitation and Streamflow in the U.S. Great Lakes Basin, 1915-2004

The total amount of water in the Great Lakes Basin is important in the long-term allocation of water to human use and to riparian and aquatic ecosystems. The water available during low-flow periods is particularly important because the short-term demands for the water can exceed the supply. Precipitation increased over the last 90 years in the U.S. Great Lakes Basin. Total annual precipitation increased by 4.5 inches from 1915 to 2004 (based on the average of 34 U.S. Historical Climatology Network stations), 3.5 inches from 1935 to 2004 (average of 34 stations), and 4.2 inches from 1955 to 2004 (average of 37 stations). Variability in precipitation from year to year was large, but there were numerous years with relatively low precipitation in the 1930s and 1960s and many years with relatively high precipitation after about 1970. Annual runoff increased over the last 50 years in the U.S. Great Lakes Basin. Mean annual runoff increased by 2.6 inches, based on the average of 43 U.S. Geological Survey streamflow-gaging stations from 1955 to 2004 on streams that were relatively free of human influences. Variability in runoff from year to year was large, but on average runoff was relatively low from 1955 to about 1970 and relatively high from about 1970 to 1995. Runoff increased at all stations in the basin except in and near the Upper Peninsula of Michigan, where relatively small runoff decreases occurred. Changes in annual runoff for the 16 stations with data from 1935 to 2004 were similar to the changes from 1955 to 2004. The mean annual 7-day low runoff (the lowest annual average of 7 consecutive days of runoff) increased from 1955 to 2004 by 0.048 cubic feet per second per square mile based on the average of 27 stations. Runoff in the U.S. Great Lakes Basin from 1955 to 2004 increased for all months except April. November through January and July precipitation and runoff increased by similar amounts. There were differences between precipitation and runoff changes for February, March, and April, which were likely due to lower ratios of snowfall to rain and earlier snowmelt runoff in recent years. Increases in precipitation were larger than increases in runoff for May, June, August, September, and October. Some of this difference could be due to the different locations of the precipitation and streamflow stations in the basin. Part of the difference may be explained by changes in evapotranspiration. Some of the few highly urbanized and highly regulated stations analyzed in this report had larger increases in annual 7-day low-runoff from 1955 to 2004 than any of the stations in the U.S. Great Lakes Basin that are on streams relatively free of human influences. This demonstrates the human influence over time on very low streamflows. Changes-even over periods as long as 90 years-can be part of longer cycles. Previous studies of Great Lakes Basin precipitation and St. Lawrence River streamflow, using data from the mid-1800s to the late-1900s, showed low precipitation and streamflow in the late 1800s and early 1900s relative to earlier and later periods.

Scientific Investigations Report↗

Trends in the quality of water in New Jersey streams, water years 1998-2007

Trends were determined in flow-adjusted values of selected water-quality characteristics measured year-round during water years 1998-2007 (October 1, 1997, through September 30, 2007) at 70 stations on New Jersey streams. Water-quality characteristics included in the analysis are dissolved oxygen, pH, total dissolved solids, total phosphorus, total organic nitrogen plus ammonia, and dissolved nitrate plus nitrite. In addition, trend tests also were conducted on measurements of dissolved oxygen made only during the growing season, April to September. Nearly all the water-quality data analyzed were collected by the New Jersey Department of Environmental Protection and the U.S. Geological Survey as part of the New Jersey Department of Environmental Protection Ambient Surface-Water Quality Monitoring Network. Monotonic trends in flow-adjusted values of water quality were determined by use of procedures in the ESTREND computer program. A 0.05 level of significance was selected to indicate a trend. Results of tests were not reported if there were an insufficient number of measurements or insufficient number of detected concentrations, or if the results of the tests were affected by a change in data-collection methods. Trends in values of dissolved oxygen, pH, and total dissolved solids were identified using the Seasonal Kendall test. Trends or no trends in year-round concentrations of dissolved oxygen were determined for 66 stations; decreases at 4 stations and increases at 0 stations were identified. Trends or no trends in growing-season concentrations of dissolved oxygen were determined for 65 stations; decreases at 4 stations and increases at 4 stations were identified. Tests of pH values determined trends or no trends at 26 stations; decreases at 2 stations and increases at 3 stations were identified. Trends or no trends in total dissolved solids were reported for all 70 stations; decreases at 0 stations and increases at 24 stations were identified. Trends in total phosphorus, total organic nitrogen plus ammonia, and dissolved nitrate plus nitrite were identified by use of Tobit regression. Two sets of trend tests were conducted-one set with all measurements and a second set with all measurements except the most extreme outlier if one could be identified. The result of the test with all measurements is reported if the results of the two tests are equivalent. The result of the test without the outlier is reported if the results of the two tests are not equivalent. Trends or no trends in total phosphorus were determined for 69 stations. Decreases at 12 stations and increases at 5 stations were identified. Of the five stations on the Delaware River included in this study, decreases in concentration were identified at four. Trends or no trends in total organic nitrogen plus ammonia were determined for 69 stations. Decreases and increases in concentrations were identified at six and nine stations, respectively. Trends or no trends in dissolved nitrate plus nitrite were determined for 66 stations. Decreases and increases in concentration were identified at 4 and 19 stations, respectively.

Scientific Investigations Report↗

Estimated sediment thickness, quality, and toxicity to benthic organisms in selected impoundments in Massachusetts

The U.S. Geological Survey and the Massachusetts Department of Fish and Game, Division of Ecological Restoration, collaborated to collect baseline information on the quantity and quality of sediment impounded behind selected dams in Massachusetts, including sediment thickness and the occurrence of contaminants potentially toxic to benthic organisms. The thicknesses of impounded sediments were measured, and cores of sediment were collected from 32 impoundments in 2004 and 2005. Cores were chemically analyzed, and concentrations of 32 inorganic elements and 108 organic compounds were quantified. Sediment thicknesses varied considerably among the 32 impoundments, with an average thickness of 3.7 feet. Estimated volumes also varied greatly, ranging from 100,000 cubic feet to 81 million cubic feet. Concentrations of toxic contaminants as well as the number of contaminants detected above analytical quantification levels (also known as laboratory reporting levels) varied greatly among sampling locations. Based on measured contaminant concentrations and comparison to published screening thresholds, bottom sediments were predicted to be toxic to bottom-dwelling (benthic) organisms in slightly under 30 percent of the impoundments sampled. Statistically significant relations were found between several of the contaminants and individual indicators of urban land use and industrial activity in the upstream drainage areas of the impoundments. However, models developed to estimate contaminant concentrations at unsampled sites from upstream landscape characteristics had low predictive power, consistent with the long and complex land-use history that is typical of many drainage areas in Massachusetts.

Massachusetts↗

Numerical model of the groundwater-flow system near the southeastern part of Puget Sound, Washington

Groundwater flow in the active model area (AMA) was simulated using a groundwater-flow model. A steady-state model version of the model simulates equilibrium conditions, and a transient model version simulates monthly variability. The model corresponds to the physical and temporal dimensions of the conceptual model and groundwater budget. The steady-state model version represents average conditions for an 11-year period (January 1, 2005–December 31, 2015), and the transient model represents monthly hydrologic variability within that period. The 13-layer model was constructed using MODFLOW-NWT with a uniformly spaced grid consisting of 416 rows, 433 columns, and cells with a horizontal dimension of 500 feet (ft) on a side. The model was calibrated to measured values of water levels in wells and lakes and estimated base flow for selected streamflow measurement stations, commonly referred to as streamgages. Model calibration was accomplished using a combination of manual and automatic methods, including the Model-Independent Parameter Estimation (PEST) program that adjusted model input parameters with the aim of minimizing the difference between estimated and model-simulated values of hydraulic head and base flow. Model boundary conditions consist of all simulated groundwater inflow to and outflow from the AMA. For example, a stream reach that simulates a gain from or loss to groundwater is a boundary condition that allows water to exit or enter, respectively, the groundwater system. Other boundary conditions include springs, seeps, precipitation recharge, groundwater exchange with lakes and Puget Sound, and groundwater pumping. A comparison of the estimated groundwater budget to that simulated by the steady-state model version indicates that the relative percentages of total inflow or total outflow for six major categories of boundary conditions are similar for the two budgets. The model was used to simulate three suites of scenarios of potential drought and water-use changes. Scenario 1 suite consisted of the steady-state model version that was run with 0, 15, 20, and 25 percent reduction of precipitation recharge to assess the corresponding reductions in base flow with decreasing recharge. The last simulation for the scenario 1 suite consisted of the transient model version simulating 3 years of consecutive seasonal drought, defined by the months of May through September, to assess the corresponding base-flow reductions. Scenario 2 suite consisted of the steady-state model version with all simulated groundwater use removed, compared with a simulation that includes current groundwater use to evaluate changes to potentiometric surfaces and base flows. Scenario 3 suite consisted of a transient model version of the model that simulated pumping increases for four different categories of water-supply wells (compared to no pumping increases) to evaluate resulting reductions in base flow. Although, these scenarios provide examples of model applications and useful insights, many other scenarios could be simulated. A description of how to download the model is described in the body of this report. Uncertainty is associated with most model inputs. Groundwater levels, lake levels, and land-surface altitudes are relatively certain; other model inputs are far less certain, including precipitation recharge, base flow, hydraulic properties, water use, and the three-dimensional structure of subsurface hydrogeologic units. Models are useful not because of high levels of accuracy of all model inputs, but because they combine the best information and estimates available, thereby providing the best predictions available related to physical processes. The model described in this report simulates groundwater flow on a regional scale, which has inherent limitations for simulating hydrologic scenarios at local scales. Model structures and inputs were generalized to be consistent with this regional scale. For example, the actual groundwater system has much greater heterogeneity of hydraulic conductivity than is possible within the model’s degrees of freedom. Variations in hydraulic gradients over distances less than 500 ft cannot be simulated. The distances between model features, such as a pumping well and a stream, must be placed at 500-ft intervals and are co-located if both features are within the same model cell.

Washington↗