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Composition of the crust in the Grenville and Appalachian Provinces of North America inferred from VP/VS ratios

We use the ratios between P and S wave velocities (V P /V S ), derived from seismic refraction data, to infer the composition of the crust in the Grenville and the Appalachian Provinces of North America. The crust exhibits V P /V S increasing with depth from 1.64 to 1.84; there is a clear distinction between the Grenville Province (average V P /V S =1.81) and the Appalachian Province (average V P /V S =1.73) which persists at all depths. The boundary between these provinces is east dipping extending for 100 km east of the Champlain thrust. In the Appalachian Province the increase in V P /V S ratios with depth from 1.67 to 1.74±0.02 may reflect a normal decrease of silica content in the continental crust. In the Grenville Province beneath the Central Granulite Terrane, an anomalous V P /V S ratio of 1.82±0.02 is observed extending to a depth of 10 km; this correlates with the abundance of Ca‐plagioclase in the Marcy Anorthosite. At greater depth (15–20 km), where seismic lamination and high electrical conductivity is observed, V P /V S is 1.84±0.02 and correlates with the Tahawus Complex, a layered mafic intrusion. Within the 25‐km‐thick lower crust of the Grenville Province the V P /V S is 1.84±0.02 and P‐velocity is 7.0±0.1 km/s, which are typical for plagioclase‐bearing rocks (gabbro‐norite). The high V P /V S ratio in the Grenville Province has not been reported in crust of any other age. Since the Grenville Province contains 75% of the world's known anorthosites, high V P /V S ratio is related to high plagioclase. We suggest that the composition of the Grenville lower crust was significantly modified by the emplacement of the anorthosites in the mid‐Proterozoic.

Journal of Geophysical Research B: Solid Earth↗

Application of the LI-COR CO 2 analyzer to volcanic plumes: a case study, volcán Popocatépetl, Mexico, June 7 and 10, 1995

Volcanic CO 2 emission rate data are sparse despite their potential importance for constraining the role of magma degassing in the biogeochemical cycle of carbon and for assessing volcanic hazards. We used a LI-COR CO 2 analyzer to determine volcanic CO 2 emission rates by airborne measurements in volcanic plumes at Popocatépetl volcano on June 7 and 10, 1995. LI-COR sample paths of ∼72 m, compared with ∼1 km for the analyzer customarily used, together with fast Fourier transforms to remove instrument noise from raw data greatly improve resolution of volcanic CO 2 anomalies. Parametric models fit to background CO 2 provide a statistical tool for distinguishing volcanic from ambient CO 2 . Global Positioning System referenced flight traverses provide vastly improved data on the shape, coherence, and spatial distribution of volcanic CO 2 in plume cross sections and contrast markedly with previous results based on traverse stacking. The continuous escape of CO 2 and SO 2 from Popocatépetl was fundamentally noneruptive and represented quiescent magma degassing from the top of a magma chamber ∼5 km deep. The average CO 2 emission rate for January-June 1995 is estimated to be at least 6400 t d −1 , one of the highest determined for a quiescently degassing volcano, although correction for downwind dispersion effects on volcanic CO 2 indicates a higher rate of ∼9000 t d −1 . Analysis of random errors indicates emission rates have 95% confidence intervals of ∼±20%, with uncertainty contributed mostly by wind speed variance, although the variance of plume cross-sectional areas during traversing is poorly constrained and possibly significant.

Journal of Geophysical Research B: Solid Earth↗

Grain-size-induced weakening of H2O ices I and II and associated anisotropic recrystallization

Grain-size-dependent flow mechanisms tend to be favored over dislocation creep at low differential stresses and can potentially influence the rheology of low-stress, low-strain rate environments such as those of planetary interiors. We experimentally investigated the effect of reduced grain size on the solid-state flow of water ice I, a principal component of the asthenospheres of many icy moons of the outer solar system, using techniques new to studies of this deformation regime. We fabricated fully dense ice samples of approximate grain size 2±1 μm by transforming “standard” ice I samples of 250±50 μm grain size to the higher-pressure phase ice II, deforming them in the ice II field, and then rapidly releasing the pressure deep into the ice I stability field. At T ≤200 K, slow growth and rapid nucleation of ice I combine to produce a fine grain size. Constant-strain rate deformation tests conducted on these samples show that deformation rates are less stress sensitive than for standard ice and that the fine-grained material is markedly weaker than standard ice, particularly during the transient approach to steady state deformation. Scanning electron microscope examination of the deformed fine-grained ice samples revealed an unusual microstructure dominated by platelike grains that grew normal to the compression direction, with c axes preferentially oriented parallel to compression. In samples tested at T ≥220 K the elongation of the grains is so pronounced that the samples appear finely banded, with aspect ratios of grains approaching 50:1. The anisotropic growth of these crystallographically oriented neoblasts likely contributes to progressive work hardening observed during the transient stage of deformation. We have also documented remarkably similar microstructural development and weak mechanical behavior in fine-grained ice samples partially transformed and deformed in the ice II field.

Journal of Geophysical Research B: Solid Earth↗

Continuous monitoring of surface deformation at Long Valley Caldera, California, with GPS

Continuous Global Positioning System (GPS) measurements at Long Valley Caldera, an active volcanic region in east central California, have been made on the south side of the resurgent dome since early 1993. A site on the north side of the dome was added in late 1994. Special adaptations for autonomous operation in remote regions and enhanced vertical precision were made. The data record ongoing volcanic deformation consistent with uplift and expansion of the surface above a shallow magma chamber. Measurement precisions (1 standard error) for “absolute” position coordinates, i.e., relative to a global reference frame, are 3–4 mm (north), 5–6 mm (east), and 10–12 mm (vertical) using 24 hour solutions. Corresponding velocity uncertainties for a 12 month period are about 2 mm/yr in the horizontal components and 3–4 mm/yr in the vertical component. High precision can also be achieved for relative position coordinates on short (less than 10 km) baselines using broadcast ephemerides and observing times as short as 3 hours, even when data are processed rapidly on site. Comparison of baseline length changes across the resurgent dome between the two GPS sites and corresponding two-color electronic distance measurements indicates similar extension rates within error (∼2 mm/yr) once we account for a random walk noise component in both systems that may reflect spurious monument motion. Both data sets suggest a pause in deformation for a 3.5 month period in mid-1995, when the extension rate across the dome decreased essentially to zero. Three dimensional positioning data from the two GPS stations suggest a depth (5.8±1.6 km) and location (west side of the resurgent dome) of a major inflation center, in agreement with other geodetic techniques, near the top of a magma chamber inferred from seismic data. GPS systems similar to those installed at Long Valley can provide a practical method for near real-time monitoring and hazard assessment on many active volcanoes.

Journal of Geophysical Research B: Solid Earth↗

Färoe-Iceland Ridge Experiment: 1. Crustal structure of northeastern Iceland

Results from the F&auml;roe-Iceland Ridge Experiment (FIRE) constrain the crustal thickness as 19 km under the Northern Volcanic Zone of Iceland and 35 km under older Tertiary areas of northeastern Iceland. The Moho is defined by strong P wave and S wave reflections. Synthetic seismogram modeling of the Moho reflection indicates mantle velocities of at least 8.0 km/s beneath the Tertiary areas of northeastern Iceland and at least 7.9 km/s beneath the neovolcanic zone. Crustal diving rays resolve the structure of the upper and lower crust. Surface P wave velocities are 1.1&ndash;4.0 km/s in Quaternary rocks and are rather higher, 4.4&ndash;4.7 km/s, in the Tertiary basalts that outcrop elsewhere. The highest crustal P wave velocities observed directly from diving rays are 7.1 km/s, from rays that turn at 24 km depth. Velocities of 7.35 km/s at the base of the crust are inferred from extrapolation of the lower crustal velocity gradient (0.024 s &minus;1 ). A Poisson's ratio of approximately 0.27, equivalent to an S wave to P wave travel time ratio of 1.78, is measured throughout the crust east of the neovolcanic zone. The Poisson's ratio and the steep Moho topography (in places up to 30&deg; from the horizontal) indicate that the entire crust outside the neovolcanic zone is cool (<800&deg;C). Gravity data are well matched by a velocity/density conversion of our seismic crustal model and indicate a region of low mantle density beneath the neovolcanic zone, believed to be due to elevated mantle temperatures. The crustal thickness in the neovolcanic zone is consistent with geochemical estimates of the melt generation, placing constraints on the flow within the Iceland mantle plume.

Journal of Geophysical Research B: Solid Earth↗

Multispectral thermal infrared mapping of sulfur dioxide plumes: A case study from the East Rift Zone of Kilauea Volcano, Hawaii

The synoptic perspective and rapid mode of data acquisition provided by remote sensing are well suited for the study of volcanic SO 2 plumes. In this paper we describe a plume-mapping procedure that is based on image data acquired with NASA's airborne thermal infrared multispectral scanner (TIMS) and apply the procedure to TIMS data collected over the East Rift Zone of Kilauea Volcano, Hawaii, on September 30, 1988. These image data covered the Pu‘u ‘O ‘o and Kupaianaha vents and a skylight in the lava tube that was draining the Kupaianaha lava pond. Our estimate of the SO 2 emission rate from Pu‘u ‘O ‘o (17–20 kg s −1 ) is roughly twice the average of estimates derived from correlation spectrometer (COSPEC) measurements collected 10 days prior to the TIMS overflight (10 kg s −1 ). The agreement between the TIMS and COSPEC results improves when we compare SO 2 burden estimates, which are relatively independent of wind speed. We demonstrate the feasibility of mapping Pu‘u ‘O ‘o - scale SO 2 plumes from space in anticipation of the 1998 launch of the advanced spaceborne thermal emission and reflectance radiometer (ASTER).

Journal of Geophysical Research B: Solid Earth↗

Deep seismic structure and tectonics of northern Alaska: Crustal-scale duplexing with deformation extending into the upper mantle

Seismic reflection and refraction and laboratory velocity data collected along a transect of northern Alaska (including the east edge of the Koyukuk basin, the Brooks Range, and the North Slope) yield a composite picture of the crustal and upper mantle structure of this Mesozoic and Cenozoic compressional orogen. The following observations are made: (1) Northern Alaska is underlain by nested tectonic wedges, most with northward vergence (i.e., with their tips pointed north). (2) High reflectivity throughout the crust above a basal decollement, which deepens southward from about 10 km depth beneath the northern front of the Brooks Range to about 30 km depth beneath the southern Brooks Range, is interpreted as structural complexity due to the presence of these tectonic wedges, or duplexes. (3) Low reflectivity throughout the crust below the decollement is interpreted as minimal deformation, which appears to involve chiefly bending of a relatively rigid plate consisting of the parautochthonous North Slope crust and a 10- to 15-km-thick section of mantle material. (4) This plate is interpreted as a southward verging tectonic wedge, with its tip in the lower crust or at the Moho beneath the southern Brooks Range. In this interpretation the middle and upper crust, or all of the crust, is detached in the southern Brooks Range by the tectonic wedge, or indentor: as a result, crust is uplifted and deformed above the wedge, and mantle is depressed and underthrust beneath this wedge. (5) Underthrusting has juxtaposed mantle of two different origins (and seismic velocities), giving rise to a prominent sub-Moho reflector.

Journal of Geophysical Research B: Solid Earth↗

Using nonlinear forecasting to learn the magnitude and phasing of time-varying sediment suspension in the surf zone

The time-dependent response of sediment suspension to flow velocity was explored by modeling field measurements collected in the surf zone during a large storm. Linear and nonlinear models were created and tested using flow velocity as input and suspended-sediment concentration as output. A sequence of past velocities (velocity history), as well as velocity from the same instant as the suspended-sediment concentration, was used as input; this velocity history length was allowed to vary. The models also allowed for a lag between input (instantaneous velocity or end of velocity sequence) and output (suspended-sediment concentration). Predictions of concentration from instantaneous velocity or instantaneous velocity raised to a power (up to 8) using linear models were poor (correlation coefficients between predicted and observed concentrations were less than 0.10). Allowing a lag between velocity and concentration improved linear models (correlation coefficient of 0.30), with optimum lag time increasing with elevation above the seabed (from 1.5 s at 13 cm to 8.5 s at 60 cm). These lags are largely due to the time for an observed flow event to effect the bed and mix sediment upward. Using a velocity history further improved linear models (correlation coefficient of 0.43). The best linear model used 12.5 s of velocity history (approximately one wave period) to predict concentration. Nonlinear models gave better predictions than linear models, and, as with linear models, nonlinear models using a velocity history performed better than models using only instantaneous velocity as input. Including a lag time between the velocity and concentration also improved the predictions. The best model (correlation coefficient of 0.58) used 3 s (approximately a quarter wave period) of the cross-shore velocity squared, starting at 4.5 s before the observed concentration, to predict concentration. Using a velocity history increases the performance of the models by specifying a more complete description of the dynamical forcing of the flow (including accelerations and wave phase and shape) responsible for sediment suspension. Incorporating such a velocity history and a lag time into the formulation of the forcing for time-dependent models for sediment suspension in the surf zone will greatly increase our ability to predict suspended-sediment transport.

Journal of Geophysical Research C: Oceans↗

Factors affecting suspended-solids concentrations in South San Francisco Bay, California

Measurements of suspended-solids concentration (SSC) were made at two depths at three sites in South San Francisco Bay (South Bay) to determine the factors that affect SSC. Twenty-eight segments of reliable and continuous SSC time series data longer than 14 days were collected from late 1991 or 1992 through September 1993. Spectral analysis and singular spectrum analysis were used to relate these data segments to time series of several potential forcing factors, including diurnal and semidiurnal tides, the spring-neap tidal cycle, wind shear, freshwater runoff, and longitudinal density differences. SSC is greatest during summer, when a landward wind shear is applied to South Bay by the afternoon sea breeze. About one half the variance of SSC is caused by the spring-neap cycle, and SSC lags the spring-neap cycle by about 2 days. Relatively short duration of slack water limits the duration of deposition of suspended solids and consolidation of newly deposited bed sediment during the tidal cycle, so suspended solids accumulate in the water column as a spring tide is approached and slowly deposit as a neap tide is approached. Perturbations in SSC caused by wind and local runoff from winter storms during the study period were usually much smaller than SSC variations caused by the spring-neap cycle. Variations of SSC at the study sites at tidal timescales are tidally forced, and nonlinear physical processes are significant. Advective transport dominates during spring tides, when water with higher SSC due to wind wave resuspension is advected to the main channel from shallow water, but, during neap tides, advective transport is less significant. The findings of this and other studies indicate that the tidally averaged transport of suspended solids responds to seasonal variations of wind shear in South Bay.

Journal of Geophysical Research C: Oceans↗

Subtidal circulation patterns in a shallow, highly stratified estuary: Mobile Bay, Alabama

Mobile Bay is a wide (25-50 km), shallow (3 m), highly stratified estuary on the Gulf coast of the United States. In May 1991 a series of instruments that measure near-surface and near-bed current, temperature, salinity, and middepth pressure were deployed for a year-long study of the bay. A full set of measurements were obtained at one site in the lower bay; all but current measurements were obtained at a midbay site. These observations show that the subtidal currents in the lower bay are highly sheared, despite the shallow depth of the estuary. The sheared flow patterns are partly caused by differential forcing from wind stress and river discharge. Two wind-driven flow patterns actually exist in lower Mobile Bay. A barotropic response develops when the difference between near-surface and near-bottom salinity is less than 5 parts per thousand. For stronger salinity gradients the wind-driven currents are larger and the response resembles a baroclinic flow pattern. Currents driven by river flows are sheared and also have a nonlinear response pattern. Only near-surface currents are driven seaward by discharges below 3000 m3/s. At higher discharge rates, surface current variability uncouples from the river flow and the increased discharge rates drive near-bed current seaward. This change in the river-forced flow pattern may be associated with a hydraulic jump in the mouth of the estuary. Copyright 1996 by the American Geophysical Union.

Journal of Geophysical Research C: Oceans↗

Origin of Bermuda's clay-rich Quaternary paleosols and their paleoclimatic significance

Red clayey paleosols that are chiefly the product of aerosolic dust deposition are interbedded in the Quaternary carbonate formations of the Bermuda oceanic island system. These paleosols provide a basis for reconstructing Quaternary atmospheric circulation patterns in the northwestern Atlantic. Geochemical analyses were performed on representative paleosol samples to identify their parent dust source. Fine-grained fractions were analyzed by energy-dispersive X ray fluorescence to determine trace element (Zr, Y, La, Ti, and Nb) concentrations and to derive geochemical signatures based on immobile element ratios. These ratios were compared with geochemical signatures determined for three possible sources of airborne dust: (1) Great Plains loess, (2) Mississippi River Valley loess, and (3) Saharan dust. The Zr/Y and Zr/La ratios provided the clearest distinction between the hypothesized dust sources. The low ratios in the paleosol B horizons most closely resemble Saharan dust in the <2-μm size class fraction. Contributions from the two North American loessial source areas could not be clearly detected. Thus Bermuda paleosols have a predominantly Saharan aerosolic dust signature. Saharan dust deposition on Bermuda during successive Quaternary glacial periods is consistent with patterns of general circulation models, which indicate that during glacial maxima the northeast summer trade winds were stronger than at present and reached latitudes higher than 30°N despite lower-than-present sea surface temperatures in the North Atlantic.

Journal of Geophysical Research D: Atmospheres↗

Detection and monitoring of H2O and CO2 ice clouds on Mars

We have developed an observational scheme for the detection and discrimination of Mars atmospheric H 2 O and CO 2 clouds using ground-based instruments in the near infrared. We report the results of our cloud detection and characterization study using Mars near IR images obtained during the 1990 and 1993 oppositions. We focused on specific wavelengths that have the potential, based on previous laboratory studies of H 2 O and CO 2 ices, of yielding the greatest degree of cloud detectability and compositional discriminability. We have detected and mapped absorption features at some of these wavelengths in both the northern and southern polar regions of Mars. Compositional information on the nature of these absorption features was derived from comparisons with laboratory ice spectra and with a simplified radiative transfer model of a CO 2 ice cloud overlying a bright surface. Our results indicate that both H 2 O and CO 2 ices can be detected and distinguished in the polar hood clouds. The region near 3.00 μm is most useful for the detection of water ice clouds because there is a strong H 2 O ice absorption at this wavelength but only a weak CO 2 ice band. The region near 3.33 μm is most useful for the detection of CO 2 ice clouds because there is a strong, relatively narrow CO 2 ice band at this wavelength but only broad “continuum” H 2 O ice absorption. Weaker features near 2.30 μm could arise from CO 2 ice at coarse grain sizes, or surface/dust minerals. Narrow features near 2.00 μm, which could potentially be very diagnostic of CO 2 ice clouds, suffer from contamination by Mars atmospheric CO 2 absorptions and are difficult to interpret because of the rather poor knowledge of surface elevation at high latitudes. These results indicate that future ground-based, Earth-orbital, and spacecraft studies over a more extended span of the seasonal cycle should yield substantial information on the style and timing of volatile transport on Mars, as well as a more detailed understanding of the role of CO 2 condensation in the polar heat budget.

Journal of Geophysical Research E: Planets↗

Erosional and depositional patterns associated with the 1993 Missouri River floods inferred from SIR-C and TOPSAR radar data

The Missouri River floods of 1993 caused significant and widespread damage to the floodplains between Kansas City and St. Louis. Immediately downstream of levee breaks, flood waters scoured the bottoms. As the floodwaters continued, they spread laterally and deposited massive amounts of sand as crevasse splays on top of agricultural fields. We explore the use of radar interferometry and backscatter data for quantitative estimation of scour and deposition for Jameson Island/Arrow Rock Bottoms and Lisbon Bottoms, two bottoms that were heavily damaged during the floods and subsequently abandoned. Shuttle imaging radar C (SIR-C) L band (24 cm) HH (horizontally transmitted and horizontally received) radar backscatter data acquired in October 1994 were used together with a distorted Born approximation canopy scattering model to determine that the abundance of natural leafy forbs controlled the magnitude of backscatter for former agricultural fields. Forb areal density was found to be inversely correlated with thickness of sand deposited during the floods, presumably because thick sands prevented roots from reaching nutrient rich, moist bottoms soils. Using the inverse relationship, a lower bound for the mass of sand added was found to be 6.3 million metric tons over the 17 km 2 study area. Digital elevation data from topographic synthetic aperture radar (TOPSAR) C band (5.6 cm) interferometric observations acquired in August 1994 were compared to a series of elevation profiles collected on the ground. Vertical errors in TOPSAR were estimated to range from 1 to 2 m, providing enough accuracy to generate an estimate of total mass (4.7 million metric tons) removed during erosion of levees and scour of the bottoms terrains. Net accretion of material to the study areas is consistent with the geologic record of major floods where sediment-laden floodwaters crested over natural levees, initially scoured into the bottoms, and then deposited sands as crevasse splays as the flows spread out and slowed by frictional dissipation. The addition of artificial levees to the Missouri River system has undoubtedly enhanced flood damage, although quantitative estimation of the degree of enhancement will require additional work.

Journal of Geophysical Research E: Planets↗

Extension across Tempe Terra, Mars, from measurements of fault scarp widths and deformed craters

Two independent methods, with no common assumptions, have been used to estimate the extension across the heavily deformed Tempe Terra province of the Tharsis region of Mars. One method uses measurements of normal fault scarp width with average scarp slope data for simple grabens and rifts on Mars to estimate the fault throw, which, combined with sparse fault dip data, can be used to estimate extension. Formal uncertainties in this method are only slightly greater than those in other methods, given that the total uncertainty is dominated by the likely uncertainty in the fault dip (assumed to be 60° ± 15°). Measurement of normal fault scarp widths along two N25°–50°W directed traverses across Tempe Terra both yield about 22 ± 16 km of extension (or ∼2% strain across the northern traverse and nearly 3% across the southern one). About three quarters of the extension has occurred during the two main phases of Tharsis-related deformation from Middle/Late Noachian to Early Hesperian and from Late Hesperian to Early Amazonian, with more extension closer to the center of Tharsis during the first phase. Extension across the region was also determined by measuring the elongation and elongation direction of all ancient Noachian impact craters without ejecta blankets, which predate most of the deformation. Results have been corrected for initial non circularity of craters, established from similar measurements of young (post deformation) impact craters, yielding a statistically significant mean strain of 1.96 ± 0.35% in a N38° ± 10°W direction across Tempe Terra (extension of ∼20 ± 4, comparable in magnitude and direction to the average result from the scarp measurement method). Both methods indicate an average extension for single normal fault scarps (and shortening across wrinkle ridges for the crater method) of ∼100 m. The agreement between the results of the two independent methods in overall extension and average single normal fault extension argues that the average scarp slope and fault dip data in the fault scarp width method accurately represent the actual extension across the observed structures. This conclusion supports existing geometric and kinematic models for structural features on Mars. A preliminary estimate of the total circumferential extension around Tharsis (at a radius of ∼2500 km) is roughly 60 ± 42 km; total hoop strain is about 0.4% distributed heterogeneously (Tempe Terra is the most highly strained region on Mars).

Journal of Geophysical Research E: Planets↗

Sedimentary history and mass flow structures of Chryse and Acidalia Planitiae, Mars

Geologic mapping and crater counting in Chryse and Acidalia Planitiae (GAP) reveal five major sedimentary deposits of Hesperian to Early Amazonian age, including (1) a mass flow deposited during the Early Hesperian near Deuteronilus Mensae (northeast of the map region) that may have resulted from the carving of Kasei Valles, >3000 km southwest of the exposed part of the deposit; (2) knobby plains material consisting of channel (likely; from Simud and Tiu Valles and possibly Ares and Shalbatana Valles) and mass-wasting deposits in central and eastern CAP; (3) material largely from Maja and Ares Valles emplaced in at least western and southern CAP (outcrops in southern Chryse Planitia developed thermokarst); (4) a thin mass flow covering much of southern Chryse Planitia that emanated from Simud and Tiu Valles; and (5) a thick, extensive (perhaps >3500 km across) mass flow deposit in central and northern CAP derived from accumulation and backflow of the preceding thin mass flow or perhaps melting of polar deposits. Other possible deposits may not be recognizable owing to burial by younger materials or a lack of morphologic signature. Various associated landforms appear to be consistent with the mass flow interpretations, including lobate and linear scarps along deposit edges, fractures related to desiccation of thick sediments, troughs, and ridges near the edges of the deposit indicative of secondary mass movement and deformation, pitted domes and fissure-fed flows possibly formed by sedimentary (mud) eruptions, and longitudinal channel grooves perhaps formed by roller vortices. No convincing evidence for paleoshorelines or stagnant ice sheets is found in CAP. These findings suggest that mass flow and hyperconcentrated flooding may have been the predominant processes of outflow-channel dissection in CAP. Elsewhere in the northern plains, similar landforms are prevalent. The mass flow interpretation does not require either multiple episodes of extraordinarily high water-discharge rates achieved by freeing huge volumes of water from the crust, repetitive recycling of immense volumes of water into highland aquifers at the heads of Chryse channels, or profound climate change. Mars Pathfinder will most likely land on and inspect the surface of the thin mass flow that originated from the canyons of Simud and Tiu Valles.

Journal of Geophysical Research E: Planets↗

Selection of the Mars Pathfinder landing site

The Mars Pathfinder spacecraft will land on a depositional fan near the mouth of the catastrophic outflow channel, Ares Vallis (19.5°N, 32.8°W). This site offers the prospect of analyzing a variety of rock types from the ancient cratered highlands, intermediate-age ridged plains, and reworked channel deposits. Analyses of these rocks by Pathfinder instruments will enable first-order scientific questions to be addressed, such as differentiation of the crust, the development of weathering products, and the nature of the early environment, as well as their subsequent evolution on Mars. Constraints imposed by (1) spacecraft and rover designs (which are robust), (2) entry, descent, and landing, (3) scientific potential at various sites, and (4) safety were important considerations in site selection. Engineering constraints require a 70 km by 200 km smooth, flat (low slopes) area located between 10° and 20°N that is below 0 km elevation, with average radar reflectivity, little dust, and moderate rock abundance. Three regions on Mars are between 10° and 20°N and below 0 km elevation: Chryse, Amazonis, and Isidis-Elysium. Science considerations favor sites at the mouths of outflow channels (grab bag sites offer an assay of rock types on Mars), highland sites (early crustal differentiation and climate), and sites covered with dark (unoxidized) material. Sites are considered safe if they are clearly below 0 km elevation, appear acceptably free of hazards in high-resolution (<50 m/pixel) Viking orbiter images and have acceptable reflectivity and roughness at radar wavelengths, thermal inertia, rock abundance, red to violet ratio, and albedo. Recent 3.5-cm wavelength radar observations were used to verify elevation, reflectivity, and roughness within the landing ellipses. Three sites meet all of these criteria: Ares Vallis, Tritonis Lacus, and Isidis. Although Isidis appears to be safer than Tritonis and Ares, the greater scientific potential at Ares Vallis resulted in its selection. Comparisons of the Grand Coulee (channel) and the depositional Ephrata Fan of the Channeled Scabland in eastern Washington, with Ares Vallis and its depositional fan also suggest the Ares Vallis landing site is safe and scientifically interesting.

Journal of Geophysical Research Planets↗

The imager for Mars Pathfinder experiment

The imager for Mars Pathfinder (IMP), a stereoscopic, multispectral camera, is described in terms of its capabilities for studying the Martian environment. The camera's two eyes, separated by 15.0 cm, provide the camera with range‐finding ability. Each eye illuminates half of a single CCD detector with a field of view of 14.4×14.0° and has 12 selectable filters. The ƒ/18 optics have a large depth of field, and no focussing mechanism is required; a mechanical shutter is avoided by using the frame transfer capability of the 512×512 CCD. The resolving power of the camera, 0.98 mrad/pixel, is approximately the same as the Viking Lander cameras; however, the signal‐to‐noise ratio for IMP greatly exceeds Viking, approaching 350. This feature along with the stable calibration of the filters between 440 and 1000 nm distinguishes IMP from Viking. Specially designed targets are positioned on the Lander; they provide information on the magnetic properties of wind‐blown dust, measure the wind vectors, and provide radiometric standard reflectors for calibration. Also, eight low‐transmission filters are included for imaging the Sun directly at multiple wavelengths, giving IMP the ability to measure dust opacity and potentially the water vapor content. Several experiments beyond the requisite color panorama are described in detail: contour mapping of the local terrain, multispectral imaging of the surrounding rock and soil to study local mineralogy, viewing of three wind socks, measuring atmospheric opacity and water vapor content, and estimating the magnetic properties of wind‐blown dust. This paper is intended to serve as a guide to understanding the scientific integrity of the IMP data that will be returned from Mars starting on July 4, 1997.

Journal of Geophysical Research E: Planets↗

Variation of the 3-μm absorption feature on Mars: observations over eastern Valles Marineris by the mariner 6 infrared spectrometer

A new approach for calibration of the shortest wavelength channel (1.8 to 6.0 &mu;m) of the Mariner 6 infrared spectrometer was derived. This calibration provides a new description of the instrument response function from 1.8 to 3.7 &mu;m and accounts for the thermal contribution to the signal at longer wavelengths. This allows the two segments from 1.8 to 6 &mu;m to be merged into a single spectrum. The broad water of hydration absorption spans these two segments and is examined in these merged spectra using a method of band integration. Unlike previous analyses which rely on ratios at two wavelengths, the integration method can assess the band strength independently from the albedo in the near infrared. Spectra taken over the eastern end of the Valles Marineris are examined for variations of the band-integrated value, and three distinct clusters are found. Within the estimated uncertainty, two clusters (both low and high albedo) have approximately the same integrated band depth. The third cluster (medium albedo) has an integrated band depth about 10% higher. This difference cannot be systematically attributed to either surface or atmospheric parameters and suggests variation in the amount of water either chemically or physically bound in surface materials. Approximately one-half of the high integrated band depth cluster is associated with chaotic terrain at the source of outflow channels, the other half occurs over lower inertia plains adjacent to chasmata. This suggests both surface physical properties and mineralogy as well as water in exchange with the atmosphere contribute to the 3-&mu;m bound water absorption.

Journal of Geophysical Research E: Planets↗