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At least 1,549 records · Page 86Linked to original sources

Short-term trends in sulfate deposition at selected bulk precipitation stations in New York

Trends in rainfall-adjusted sulfate concentration were assessed for 5-yr subrecords of the 14.5–17 yr of monthly bulk-deposition data from five stations in New York by using the seasonal Kendall test. For the 5-yr subrecord from 1978 to 1982, the trends for the bulk deposition were similar to those for weekly wet-only deposition for adjacent stations of the National Atmospheric Deposition Program (NADP). The long-term trend at each of the bulk-precipitation sites was downward and statistically significant at P < 0.02, whereas 26% of the 69 subrecords had trends that were statistically significant only at P < 0.2. Of these statistically significant subrecord trends, 10% were positive (opposite to the long-term trend). Furthermore, the slopes of the subrecord trends tended to be much steeper than those of the whole record. These 5-yr trends, consequently, are poor indicators of the trends that occur over much longer periods in the same record.

New York↗

High-resolution tephrochronology of the Wilson Creek Formation (Mono Lake, California) and Laschamp event using 238 U- 230 Th SIMS dating of accessory mineral rims

Sediments of the Wilson Creek Formation surrounding Mono Lake preserve a high-resolution archive of glacial and pluvial responses along the eastern Sierra Nevada due to late Pleistocene climate change. An absolute chronology for the Wilson Creek stratigraphy is critical for correlating the paleoclimate record to other archives in the western U.S. and the North Atlantic region. However, multiple attempts to date the Wilson Creek stratigraphy using carbonates and tephras yield discordant results due to open-system effects and radiocarbon reservoir uncertainties as well as abundant xenocrysts. New ion microprobe 238 U- 230 Th dating of the final increments of crystallization recorded by allanite and zircon autocrysts from juvenile pyroclasts yield ages that effectively date eruption of key tephra beds and delimit the timing of basal Wilson Creek sedimentation to the interval between 26.8±2.1 and 61.7±1.9 ka. Tephra (Ash 15) erupted during the geomagnetic excursion originally designated the Mono Lake excursion yields an age of 40.8±1.9 ka, indicating that the event is instead the Laschamp excursion. The new ages support a depositional chronology from magnetostratigraphy that indicates quasi-synchronous glacial and hydrologic responses in the Sierra Nevada and Mono Basin to regional climate change, with intervals of lake filling and glacial-snowpack melting that are in phase with peaks in spring insolation.

California↗

A 3400 year paleolimnological record of prehispanic human–environment interactions in the Holmul region of the southern Maya lowlands

The timing, magnitude and drivers of late Holocene environmental change in the Holmul region of the southern Maya lowlands are examined by combining paleoenvironmental and archeological data. Environmental proxy analyses on a ~ 3350 cal yr lacustrine sediment record include pollen, charcoal, loss on ignition, magnetic suscep- tibility, and elemental geochemistry. Archeological evidence is derived from extensive settlement surveys conducted near the study site. Results indicate nearby settlement and agricultural activity taking place in an environment characterized by open forest from around 3350 to 950 cal yr BP. The fire history shows a dramatic increase in burning during the Classic period, possibly reflecting changing agricultural strategies. A distinct band of carbonate deposited from 1270 to 1040 cal yr BP suggests decreased hydrologic input associated with drier conditions. Abrupt changes in proxy data around 940 cal yr BP indicate a cessation of human disturbance and local abandonment of the area.

Peten↗

Late Pleistocene mammoth remains from Coastal Maine, USA

Remains identified as those of a woolly mammoth ( Mammuthus primigenius ) dated at 12,200 ?? 55 14C yr B.P. were recovered while excavating in a complex sequence of glaciomarine sediments in Scarborough, Maine, USA. The mammoth was found in the top meter of a fossiliferous unit of mud and sand laminites. These sediments were deposited during a marine regressive phase following the transgression that accompanied northward retreat of the margin of the Laurentide ice sheet. A Portlandia arctica valve from the underlying transgressive unit provides a minimum age of 14,820 ?? 105 14C yr B.P. for local deglaciation. The mammoth, an adult female, died in midwinter with no evidence of human involvement. Tusk growth rates and oxygen-isotope variation over the last few years of life record low seasonality. The mammoth was transported to the site as a partial carcass by the late-glacial proto-Saco River. It sank in a near-shore setting, was subjected to additional disarticulation and scattering of elements, and was finally buried in sediments reworked by the shallowing sea. ?? 2004 University of Washington. All rights reserved.

Quaternary Research↗

Harmonic Analysis of Sedimentary Cyclic Sequences in Kansas, Midcontinent, USA

Several stratigraphic sequences in the Upper Carboniferous (Pennsylvanian) in Kansas (Midcontinent, USA) were analyzed quantitatively for periodic repetitions. The sequences were coded by lithologic type into strings of datasets. The strings then were analyzed by an adaptation of a one-dimensional Fourier transform analysis and examined for evidence of periodicity. The method was tested using different states in coding to determine the robustness of the method and data. The most persistent response is in multiples of 8-10 ft (2.5-3.0 m) and probably is dependent on the depositional thickness of the original lithologic units. Other cyclicities occurred in multiples of the basic frequency of 8-10 with persistent ones at 22 and 30 feet (6.5-9.0 m) and large ones at 80 and 160 feet (25-50 m). These levels of thickness relate well to the basic cyclothem and megacyclothem as measured on outcrop. We propose that this approach is a suitable one for analyzing cyclic events in the stratigraphic record.

Mathematical Geology↗

Brittle deformation along the Gulf of Alaska margin in response to Paleocene-Eocene triple junction migration

A spreading center was subducted diachronously along a 2200 km segment of what is now the Gulf of Alaska margin between 61 and 50 Ma, and left in its wake near-trench intrusions and high-T, low-P metamorphic rocks. Gold-quartz veins and dikes, linked to ridge subduction by geochronological and relative timing evidence, provide a record of brittle deformation during and after passage of the ridge. The gold-quartz veins are typically hosted by faults, and their regional extent indicates there was widespread deformation of the forearc above the slab window at the time of ridge subduction. Considerable variability in the strain pattern was associated with the slab window and the trailing plate. A diffuse network of dextral, sinistral, and normal faults hosted small lode-gold deposits (<50,000 oz) in south-central Alaska, whereas crustal-scale dextral faults in southeastern Alaska are spatially associated with large gold deposits (up to 800,000 oz). We interpret the gold-quartz veins as having formed above an eastward-migrating slab window, where the forearc crust responded to the diminishing influence of the forward subducting plate, the increasing influence of the trailing plate, and the thermal pulse and decreased basal friction from the slab window. In addition, extensional deformation of the forearc resulted from the diverging motions of the two oceanic plates at the margins of the slab window. Factors that complicate interpretations of fault kinematics and near-trench dike orientations include a change in plate motions at ca. 52 Ma, northward translation of the accretionary complex, oroclinal bending of the south-central Alaska margin, and subduction of transform segments. We find the pattern of syn-ridge subduction faulting in southern Alaska is remarkably similar to brittle faults near the Chile triple junction and to earthquake focal mechanisms in the Woodlark basin - the two modern sites of ridge subduction. Therefore, extensional and strike-slip deformation above slab windows may be a common occurrence.

Alaska↗

Stratigraphic and microfossil evidence for a 4500-year history of Cascadia subduction zone earthquakes and tsunamis at Yaquina River estuary, Oregon, USA

The Sallys Bend swamp and marsh area on the central Oregon coast onshore of the Cascadia subduction zone contains a sequence of buried coastal wetland soils that extends back ∼4500 yr B.P. The upper 10 of the 12 soils are represented in multiple cores. Each soil is abruptly overlain by a sandy deposit and then, in most cases, by greater than 10 cm of mud. For eight of the 10 buried soils, times of soil burial are constrained through radiocarbon ages on fine, delicate detritus from the top of the buried soil; for two of the buried soils, diatom and foraminifera data constrain paleoenvironment at the time of soil burial. We infer that each buried soil represents a Cascadia subduction zone earthquake because the soils are laterally extensive and abruptly overlain by sandy deposits and mud. Preservation of coseismically buried soils occurred from 4500 yr ago until ∼500–600 yr ago, after which preservation was compromised by cessation of gradual relative sea-level rise, which in turn precluded drowning of marsh soils during instances of coseismic subsidence. Based on grain-size and microfossil data, sandy deposits overlying buried soils accumulated immediately after a subduction zone earthquake, during tsunami incursion into Sallys Bend. The possibility that the sandy deposits were sourced directly from landslides triggered upstream in the Yaquina River basin by seismic shaking was discounted based on sedimentologic, microfossil, and depositional site characteristics of the sandy deposits, which were inconsistent with a fluvial origin. Biostratigraphic analyses of sediment above two buried soils—in the case of two earthquakes, one occurring shortly after 1541–1708 cal. yr B.P. and the other occurring shortly after 3227–3444 cal. yr B.P.—provide estimates that coseismic subsidence was a minimum of 0.4 m. The average recurrence interval of subduction zone earthquakes is 420–580 yr, based on an ∼3750–4050-yr-long record and seven to nine interearthquake intervals. The comparison of the Yaquina Bay earthquake record to similar records at other Cascadia coastal sites helps to define potential patterns of rupture for different earthquakes, although inherent uncertainty in dating precludes definitive statements about rupture length during earthquakes. We infer that in the first half of the last millennia, the northern Oregon part of the subduction zone had a different rupture history than the southern Oregon part of the subduction zone, and we also infer that at ca. 1.6 ka, two earthquakes closely spaced in time together ruptured a length of the megathrust that extends at least from southwestern Washington to southern Oregon.

Oregon↗

Fossil tabulate corals reveal outcrops of Paleozoic sandstones in the Atlantic Coastal Plain Province, Southeastern USA

The geologic history of the Southeastern United States of America is missing nearly 350-million-years of rocks, sediments, and fossils. This gap defines the Fall Line nonconformity where Upper Ordovician consolidated rocks are directly overlain by Upper Cretaceous unconsolidated sediments of the Atlantic Coastal Plain Province. Here we begin to fill in the missing geologic record by reporting the discovery of fossils of lower-to-middle Paleozoic tabulate corals (Syringophyllidae) in angular, quartz-rich, ferruginous sandstones that crop out in the Carolina Sandhills Physiographic Province that forms the updip margin of the Atlantic Coastal Plain Province near the Fall Line. These fossils of extinct tabulate corals are the first evidence that Paleozoic (Upper Ordovician–Lower Silurian) sandstones crop out amidst the mostly Mesozoic-to-Cenozoic deposits of the Atlantic Coastal Plain Province of the United States of America. This discovery of Paleozoic fossils and strata in a region in which they were previously entirely unknown offers a more complete insight into the geologic history of the Southern Appalachian Mountains Region, Carolina Sandhills and updip margin of the Atlantic Coastal Plain Province and extends the previously identified range of Syringophyllidae in North America.

South Carolina↗

Stable isotope systematics of sulfate minerals

Stable isotope studies of sulfate minerals are especially useful for unraveling the geochemical history of geological systems. All sulfate minerals can yield sulfur and oxygen isotope data. Hydrous sulfate minerals, such as gypsum, also yield oxygen and hydrogen isotope data for the water of hydration, and more complex sulfate minerals, such as alunite and jarosite also yield oxygen and hydrogen isotope data from hydroxyl sites. Applications of stable isotope data can be divided into two broad categories: geothermometry and tracer studies. The equilibrium partitioning of stable isotopes between two substances, such as the isotopes of sulfur between barite and pyrite, is a function of temperature. Studies can also use stable isotopes as a tracer to fingerprint various sources of hydrogen, oxygen, and sulfur, and to identify physical and chemical processes such as evaporation of water, mixing of waters, and reduction of sulfate to sulfide. Studies of sulfate minerals range from low-temperature surficial processes associated with the evaporation of seawater to form evaporite deposits to high-temperature magmatic-hydrothermal processes associated with the formation of base-and precious-metal deposits. Studies have been conducted on scales from submicroscopic chemical processes associated with the weathering of pyrite to global processes affecting the sulfur budget of the oceans. Sulfate isotope studies provide important information to investigations of energy and mineral resources, environmental geochemistry, paleoclimates, oceanography (past and present), sedimentary, igneous, and metamorphic processes, Earth systems, geomicrobiology, and hydrology. One of the most important aspects of understanding and interpreting the stable isotope characteristics of sulfate minerals is the complex interplay between equilibrium and kinetic chemical and isotopic processes. With few exceptions, sulfate minerals are precipitated from water or have extensively interacted with water at some time in their history. Because of this nearly ubiquitous association with water, the kinetics of isotopic exchange reactions among dissolved species and solids are fundamental in dictating the isotopic composition of sulfate minerals. In general, the heavier isotope of sulfur is enriched in the higher oxidation state, such that under equilibrium conditions, sulfate minerals (e.g. barite, anhydrite) are expected to be enriched in the heavy isotope relative to disulfide minerals (e.g. pyrite, marcasite), which in turn are expected to be enriched relative to monosulfide minerals (e.g. pyrrhotite, sphalerite, galena) ( Sakai 1968 , Bachinski 1969 ). The kinetics of isotopic exchange among minerals with sulfur at the same oxidation state, such as sphalerite, and galena, are such that equilibrium is commonly observed. In contrast, isotopic equilibrium for exchange reactions between minerals of different oxidation states depends on factors such as the pH, time and temperature of reaction, the direction of reaction, fluid composition, and the presence or absence of catalysts ( Ohmoto and Lasaga 1982 ). The kinetics of oxygen isotope exchange between dissolved sulfate and water are extremely sluggish. Extrapolation of the high-temperature (100 to 300°C) isotopic exchange kinetic data of Chiba and Sakai (1985) to ambient temperatures suggests that it would take several billions of years for dissolved sulfate and seawater to reach oxygen isotopic equilibrium. In contrast, the residence time of sulfate in the oceans is only 7.9 million years ( Holland 1978 ). However, at higher temperatures (>200°C), oxygen isotopic exchange is sufficiently rapid to permit application of sulfate isotope geothermometry to geothermal systems and hydrothermal mineral deposits. In general, equilibrium prevails at low pH and high temperatures, whereas kinetic factors preclude equilibrium at low temperatures even at low pH. Thus, the sluggish kinetics of sulfur and oxygen isotope exchange reaction at low temperatures impair the use of these isotopes to understand the conditions of formation of sulfate minerals in these environments. However, because of these slow kinetics, the oxygen and sulfur isotopic compositions of sulfate minerals may preserve a record of the sources and processes that initially produced the dissolved sulfate, because the isotope ratios may not re-equilibrate during fluid transport and mineral precipitation. The first part of this chapter is designed to provide the reader with a basic understanding of the principles that form the foundations of stable isotope geochemistry. Next, an overview of analytical methods used to determine the stable isotope composition of sulfate minerals is presented. This overview is followed by a discussion of geochemical processes that determine the stable isotope characteristics of sulfate minerals and related compounds. The chapter then concludes with an examination of the stable isotope systematics of sulfate minerals in a variety of geochemical environments.

Reviews in Mineralogy and Geochemistry↗

Geologic map of the Mare Australe area of Mars

The south polar region of Mars is among the most geologically diverse on the planet. The areas is within the heavily cratered hemisphere of Mars bu t is distinguished by a variety of younger, regionally extensive deposits and a n a ssemblage of unique erosional forms. The spectrum of units varies from the oldest to the youngest on the planet. The oldest unit, typif ying t h e cratered hemisphere, is the material of ancient large craters, most of which have undergone advanced degradation. These ancient crater materials are overlain by a variety of regional deposits, including extensive intercrater debris blankets, r i dged volcanic flows, and massive eolian deposits that eroded to form complex cliff-rimmed pits. In the central zone of the polar region, south of roughly 75 ˚ S., these depositional units are, in turn, unconformably overlain by a t remendous sedimentary complex 1,500-2,000 km in diameter, consisting of 40 or more regularly spaced horizontal starta . Each stratum retains apparently uniform thickness (several tons of meters) over hundreds of kilometers; erosional unconformities between starta have not as yet been identified. Resting on the uppermost surface of this layered terrain is the perm anent residual polar ice cap. This complex stratigraphic record may ultimately hold the keys t o the initial atmospheric evolution, climatological fluctuations, and the history, budget, and mobility of wate r on the planet.

IMAP↗

Geologic map of MTM -45252 and-45257 quadrangles, Reull Vallis region of Mars

Mars Transverse Mercator (MTM) quadrangles -45252 and -45257 (latitude 42.5&deg; S. to 47.5&deg;S., longitude 250&deg; W. to 260&deg; W.) cover a portion of the highlands of Promethei Terra east of Hellas basin. The map area consists of heavily cratered ancient highland materials having moderate to high relief, isolated knobs and massifs of rugged mountainous material, and extensive tracts of smooth and channeled plains. Part of the ~1,500-km-long Reull Vallis outflow system is within the map area. The area also contains surficial deposits, such as the prominent large debris aprons that commonly surround highland massifs. Regional slopes are to the west, toward the Hellas basin, as indicated by topographic maps of Mars. Approximately 60 percent of the surface of Mars is covered by rugged, heavily cratered terrains believed to represent the effects of heavy bombardment in the inner solar system about 4.0 billion years ago. Much of this terrain, including that within the map area, records a long history of modification by tectonism, fluvial processes, mass wasting, and eolian activity. The presence of fluvial features to the east of Hellas basin, including Reull Vallis and other smaller channels, has significant implications for past environmental conditions. The degraded terrains surrounding Hellas basin provide constraints on the role and timing of volatile-driven activity in the evolution of the highlands. Current photogeologic mapping at 1:500,000 scale (see also Mest and Crown, 2002) from analysis of Viking Orbiter images complements previous geomorphic studies of Reull Vallis and other highland outflow systems, drainage networks, and highland debris aprons, as well as regional geologic mapping studies and geologic mapping of Hellas basin as a whole at 1:5,000,000 scale. Viking Orbiter image coverage of the map area generally ranges from 160 to 220 m/pixel; the central part of the map area is covered by higher resolution images of about 47 m/pixel. Crater size-frequency distributions have been compiled to constrain the relative ages of geologic units and determine the timing and duration of inferred geologic processes.

IMAP↗

Precipitation and Runoff Simulations of the Carson Range and Pine Nut Mountains, and Updated Estimates of Ground-Water Inflow and the Ground-Water Budgets for Basin-Fill Aquifers of Carson Valley, Douglas County, Nevada, and Alpine County, California

Recent estimates of ground-water inflow to the basin-fill aquifers of Carson Valley, Nevada, and California, from the adjacent Carson Range and Pine Nut Mountains ranged from 22,000 to 40,000 acre-feet per year using water-yield and chloride-balance methods. In this study, watershed models were developed for watersheds with perennial streams and for watersheds with ephemeral streams in the Carson Range and Pine Nut Mountains to provide an independent estimate of ground-water inflow. This report documents the development and calibration of the watershed models, presents model results, compares the results with recent estimates of ground-water inflow to the basin-fill aquifers of Carson Valley, and presents updated estimates of the ground-water budget for basin-fill aquifers of Carson Valley. The model used for the study was the Precipitation-Runoff Modeling System, a physically based, distributed-parameter model designed to simulate precipitation and snowmelt runoff as well as snowpack accumulation and snowmelt processes. Geographic Information System software was used to manage spatial data, characterize model drainages, and to develop Hydrologic Response Units. Models were developed for * Two watersheds with gaged perennial streams in the Carson Range and two watersheds with gaged perennial streams in the Pine Nut Mountains using measured daily mean runoff, * Ten watersheds with ungaged perennial streams using estimated daily mean runoff, * Ten watershed with ungaged ephemeral streams in the Carson Range, and * A large area of ephemeral runoff near the Pine Nut Mountains. Models developed for the gaged watersheds were used as index models to guide the calibration of models for ungaged watersheds. Model calibration was constrained by daily mean runoff for 4 gaged watersheds and for 10 ungaged watersheds in the Carson Range estimated in a previous study. The models were further constrained by annual precipitation volumes estimated in a previous study to provide estimates of ground-water inflow using similar water input. The calibration periods were water years 1990-2002 for watersheds in the Carson Range, and water years 1981-97 for watersheds in the Pine Nut Mountains. Daily mean values for water years 1990-2002 were then simulated using the calibrated watershed models in the Pine Nut Mountains. The daily mean values of precipitation, runoff, evapotranspiration, and ground-water inflow simulated from the watershed models were summed to provide annual mean rates and volumes for each year of the simulations, and mean annual rates and volumes computed for water years 1990-2002. Mean annual bias for the period of record for models of Daggett Creek and Fredericksburg Canyon watersheds, two gaged perennial watersheds in the Carson Range, was within 4 percent and relative errors were about 6 and 12 percent, respectively. Model fit was not as satisfactory for two gaged perennial watersheds, Pine Nut and Buckeye Creeks, in the Pine Nut Mountains. The Pine Nut Creek watershed model had a large negative mean annual bias and a relative error of -11 percent, underestimated runoff for all years but the wet years in the latter part of the record, but adequately simulated the bulk of the spring runoff most of the years. The Buckeye Creek watershed model overestimated mean annual runoff with a relative error of about -5 percent when water year 1994 was removed from the analysis because it had a poor record. The bias and error of the calibrated models were within generally accepted limits for watershed models, indicating the simulated rates and volumes of runoff and ground-water inflow were reasonable. The total mean annual ground-water inflow to Carson Valley computed using estimates simulated by the watershed models was 38,000 acre-feet, including ground-water inflow from Eagle Valley, recharge from precipitation on eolian sand and gravel deposits, and ground-water recharge from precipitation on the western alluvial fans. The estimate was in close agreement with that obtained from the chloride-balance method, 40,000 acre-feet, but was considerably greater than the estimate obtained from the water-yield method, 22,000 acre-feet. The similar estimates obtained from the watershed models and chloride-balance method, two relatively independent methods, provide more confidence that they represent a reasonably accurate volume of ground-water inflow to Carson Valley. However, the two estimates are not completely independent because they use similar distributions of mean annual precipitation. Annual ground-water recharge of the basin-fill aquifers in Carson Valley ranged from 51,000 to 54,000 acre-feet computed using estimates of ground-water inflow to Carson Valley simulated from the watershed models combined with previous estimates of other ground-water budget components. Estimates of mean annual ground-water discharge range from 44,000 to 47,000 acre-feet. The low range estimate for ground-water recharge, 51,000 acre-feet per year, is most similar to the high range estimate for ground-water discharge, 47,000 acre-feet per year. Thus, an average annual volume of about 50,000 acre-feet is a reasonable estimate for mean annual ground-water recharge to and discharge from the basin-fill aquifers in Carson Valley. The results of watershed models indicate that significant interannual variability in the volumes of ground-water inflow is caused by climate variations. During multi-year drought conditions, the watershed simulations indicate that ground-water recharge could be as much as 80 percent less than the mean annual volume of 50,000 acre-feet.

Scientific Investigations Report↗

Ground deformation and gravity for volcano monitoring

Introduction When magma accumulates or migrates, it can cause pressurization and related ground deformation. Characterization of surface deformation provides important constraints on the potential for future volcanic activity, especially in combination with seismic activity, gas emissions, and other indicators. A wide variety of techniques and instrument types have been applied to the study of ground deformation at volcanoes (sidebar, p. 2; Dzurisin, 2000, 2003, 2007). Geodetic instruments include continuously recording Global Navigation Satellite System (GNSS; of which the United States’ Global Positioning System is one example) stations (fig. D1), borehole tiltmeters, and interferometric synthetic aperture radar (InSAR) measurements (from satellites, occupied and unoccupied aircraft systems, and ground-based sensors). Additional geodetic measurements like continuous- and survey-mode gravity (fig. D2) can contribute substantially to interpreting these data. Borehole strainmeters (see chapter K , this volume, by Hurwitz and Lowenstern, 2024) also have outstanding utility for monitoring deformation, although because of cost and permitting challenges, we do not include them as part of standard volcano monitoring networks for U.S. volcanoes. Still other techniques like light detection and ranging (lidar), structure from motion, and optical satellite data can be used to derive gross topographic changes, which can be used to map volcanic deposits, infer eruption rates, and gain insights into the source processes associated with eruptive activity (see chapter G , this volume, on tracking surface changes caused by volcanic activity; Orr and others, 2024). Experience has shown that no single geodetic monitoring technique is adequate to detect and track the entire range of ground-motion patterns that occur at volcanoes, primarily because of the temporal and spatial diversity of volcano deformation (fig. D3). Similarly, the magnitude of surface deformation varies widely. Geodetic monitoring strategies should therefore include multiple techniques and instrument types to cover a wide range of spatial and temporal scales. In identifying recommendations for geodetic instrumentation for volcano monitoring networks, we attempted to maximize the diversity of instrument types to measure the full range of deformation signals and minimize their expense and number; thus, we do not include several well-known deformation-monitoring techniques in our recommendations. Extensometers, for example, measure strains over distances of a few meters and have an excellent record of success in detecting changes in preeruptive localized ground motion across existing cracks, including at Mount St. Helens, Washington (Iwatsubo and others, 1992), and Piton de la Fournaise, Réunion Island (Peltier and others, 2006). Despite being relatively inexpensive, extensometers are best used primarily when localized ground displacements (for example, ground cracks) need to be tracked, and are not necessary at all volcanoes. In considering volcano deformation monitoring strategies, two complicating factors are deserving of special attention. First, not all deformation is driven by subsurface magmatic activity—for example, at many large stratovolcanoes (for example, Mount Rainier), flank collapses and landslides are significant geologic hazards (Reid and others, 2001) that may occur even in the absence of magmatic activity. Monitoring the stability of volcanoes is thus another critical application of geodetic monitoring networks to inform hazard assessment. One of the most famous examples of edifice instability is the large flank collapse that initiated the May 18, 1980, eruption of Mount St. Helens. Deformation monitoring had detected a bulge on the north flank of the mountain in April 1980 that was expanding by several meters per day (Lipman and others, 1981). Given that flank collapses can happen at any time during a period of volcanic unrest (or even outside a period of unrest), the capability to assess edifice stability is critical. Second, although volcanoes are commonly treated as idealized structures that erupt from single points, like centralvent stratovolcanoes, many are characterized by long rift zones from which eruptions may originate, and distributed volcanic fields are characterized by broadly spaced vents. For example, linear dikes are common at Kīlauea, Mauna Loa, and between Mount Shasta and Medicine Lake in California. At Kīlauea, one of these linear dikes emerged more than 40 kilometers (km) away from the summit of the volcano during the lower East Rift Zone eruption in 2018. Other volcanic fields, like Lassen volcanic center, California, or the San Francisco Volcanic Field, Arizona, have many small vents spread over a wide area. Although the instrumentation guidelines presented in this chapter remain phrased for central-vent volcanoes, they should be modified as needed in the context of the eruptive characteristics of each individual volcanic system. Spatial analysis of geodetic network coverage could help to ensure adequate instrumentation in areas where volcanism can occur over a broad area as opposed to a central vent. As an example, consider the adjacent volcanoes Mount Shasta and Medicine Lake. If station locations are chosen based only on the distance from the centers of the volcanoes, then any geodetic anomalies between the two volcanoes—an area of potential volcanism as indicated by the presence of volcanic features—may remain undetected by ground-based instrumentation. The spatial analysis is accomplished via a grid of pressure point sources (Mogi, 1958) evenly distributed across the map area, at a depth of 5 km in this example (fig. D4). Each source is inflated until predicted deformations exceed the GNSS white noise uncertainty estimates at one site (Langbein, 2017; Murray and Svarc, 2017). This volume of detectable magma provides a measure of the quality of the coverage (fig. D4). The results indicate that, as of 2022, there is a large area between Mount Shasta and Medicine Lake volcano with existing mapped dikes in which a substantial amount of magma could intrude without being detected geodetically. Applying this style of analysis to individual volcanic systems can provide a guide for designing network geometry given the expected locations of future eruptions.

Scientific Investigations Report↗

The marine record of the Russell Fiord outburst flood, Alaska, U.S.A

The advance of Hubbard Glacier, near Yakutat, Alaska, U.S.A., in spring 1986 blocked the entrance to Russell Fiord with an ice-and-sediment dam, behind which a lake formed. The water level in Russell Lake rose to 25.5 m a.s.l. The dam catastrophically failed in October 1986, releasing 5.4 km 3 of water into Disenchantment Bay. High-resolution seismic-reflection profiles show a 7.5 km long channel system cut into and buried by glacimarine sediment, represented by continuous, parallel reflections. The chaotic seismic facies filling the channel is interpreted to be debris flow deposits. A gravity core from channel-overbank deposits contained sandy diamicton with mud clasts. Above the channel a 1-2 m thick sediment drape extends across the bay. Laminated mud, fining-upward sand beds and diamicton were recovered from this unit. The sediment-drape deposits were produced by suspension settling from turbid plumes and non-channelized turbidity currents generated by the outburst flood.

Alaska↗

Paragenesis and chemistry of multistage tourmaline formation in the sullivan Pb-Zn-Ag deposit, British Columbia

Detailed petrographic study, scanning electron microscope imaging, and electron microprobe analyses of tourmalines from the Sullivan Pb-Zn-Ag massive sulfide deposit (British Columbia, Canada) document multiple paragenetic stages and large compositional variations. The tourmalines mainly belong to two common solid-solution series: dravite-schorl and dravite-uvite. Ca- and Fe-rich feruvite and alkali-deficient tourmalines are present locally. Products of tourmaline-forming stages include (from oldest to youngest): (1) rare Fe-rich dravite-schorl within black tourmalinite clasts in footwall fragmental rocks; (2) widespread Mg-rich, very fine grained, felted dravite in the footwall (the main type of tourmaline in the footwall tourmalinite pipe); (3) recrystallized, Fe-rich dravite-schorl (locally Ca-Fe feruvite) in the tourmalinite pipe, which preferentially occurs near postore gabbroic intrusions; (4) Mg-rich dravite or uvite associated with chlorite-pyrrhotite and chlorite-albite-pyrite-altered rocks in the shallow footwall and hanging wall; (5) discrete Mg-rich tourmaline grains associated with chlorite and discordant Mg-rich tourmaline rims which occur on disseminated Fe-rich schorl in the bedded Pb-Zn-Ag ores. The timing of rare Fe-rich schorl in the bedded ores is uncertain, but it most likely occurred during or between stages 2 and 3. The different paragenetic stages and their respective tourmaline compositions are interpreted in terms of a multistage evolution involving contributions from: (1) variable mixtures of synsedimentary, Fe-rich hydrothermal fluids and entrained seawater; (2) postore, Fe-rich, gabbro-related hydrothermal fluids; and (3) postore metamorphic reactions. Early synsedimentary, Fe-rich hydrothermal fluids which contained little or no entrained seawater formed Fe-rich black tourmalinite clasts locally in the footwall. The major type of tourmaline in the footwall tourmalinite pipe is Mg rich, recording seawater entrainment under high water/rock conditions, rather than control by the chemical composition of the original host sediments. Rare Fe-rich schorl within the bedded Pb-Zn-Ag ores is believed to have formed on the sea floor by reaction of an Fe-rich brine pool with detrital aluminous sediments. Postore emplacement of gabbro sills and local dikes in the footwall produced Fe-rich hydrothermal fluids, which were responsible for formation of minor Fe-rich dravite-schorl which overprinted earlier dravite. Postore, but synsedimentary, hydrothermal alteration involving entrained seawater was responsible for deposition of dravite and uvite in the hanging wall and for dravite in the brown tourmalinites of the shallow footwall. Mg-rich dravite-uvite associated with chlorite and in discordant rims on schorl in the bedded ores formed by sulfide-silicate reactions during greenschist facies regional metamorphism.

Economic Geology↗

Sediment storage and transport in Pancho Rico Valley during and after the Pleistocene-Holocene transition, Coast Ranges of central California (Monterey County)

Factors influencing sediment transport and storage within the 156??6 km 2 drainage basin of Pancho Rico Creek (PRC), and sediment transport from the PRC drainage basin to its c. 11000 km 2 mainstem drainage (Salinas River) are investigated. Numeric age estimates are determined by optically stimulated luminescence (OSL) dating on quartz grains from three sediment samples collected from a 'quaternary terrace a (Qta)' PRC terrace/PRC-tributary fan sequence, which consists dominantly of debris flow deposits overlying fluvial sediments. OSL dating results, morphometric analyses of topography, and field results indicate that the stormy climate of the Pleistocene-Holocene transition caused intense debris-flow erosion of PRC- tributary valleys. However, during that time, the PRC channel was backfilled by Qta sediment, which indicates that there was insufficient discharge in PRC to transport the sediment load produced by tributary-valley denudation. Locally, Salinas Valley alluvial stratigraphy lacks any record of hillslope erosion occurring during the Pleistocene-Holocene transition, in that the alluvial fan formed where PRC enters the Salinas Valley lacks lobes correlative to Qta. This indicates that sediment stripped from PRC tributaries was mostly trapped in Pancho Rico Valley despite the relatively moist climate of the Pleistocene-Holocene transition. Incision into Qta did not occur until PRC enlarged its drainage basin by c. 50% through capture of the upper part of San Lorenzo Creek, which occurred some time after the Pleistocene-Holocene transition. During the relatively dry Holocene, PRC incision through Qta and into bedrock, as well as delivery of sediment to the San Ardo Fan, were facilitated by the discharge increase associated with stream-capture. The influence of multiple mechanisms on sediment storage and transport in the Pancho Rico Valley-Salinas Valley system exemplifies the complexity that (in some instances) must be recognized in order to correctly interpret terrestrial sedimentary sequences in tectonically active areas. ?? 2009 John Wiley & Sons, Ltd.

Earth Surface Processes and Landforms↗

Hydrogeology and water quality of a surficial aquifer underlying an urban area, Manchester, Connecticut

The quality of water along flowpaths in a surficial aquifer system in Manchester, Connecticut, was studied during 1993-95 as part of the National Water Quality Assessment program. The flowpath study examined the relations among hydrogeology, land-use patterns, and the presence of contaminants in a surficial aquifer in an urban area, and evaluated ground water as a source of contamination to surface water. A two-dimensional, finite-difference groundwater- flow model was used to estimate travel distance, which ranged from about 50 to 11,000 feet, from the source areas to the sampled observation wells. Land use, land cover, and population density were determined in the source areas delineated by the ground-water-flow simulation. Source areas to the wells contained either high- or medium-density residential areas, and population density ranged from 629 to 8,895 people per square mile. Concentrations of selected inorganic constituents, including sodium, chloride, and nitrite plus nitrate nitrogen, were higher in the flowpath study wells than in wells in undeveloped areas with similar aquifer materials. One or more of 9 volatile organic compounds were detected at 12 of 14 wells. The three most commonly detected volatile organic compounds were chloroform, methyl-tert-butyl ether, and trichloroethene. Trichloroethene was detected at concentrations greater than the maximum contaminant level for drinking water (5 micrograms per liter) in samples from one well. Four pesticides, including dichloro diphenyl dichloroethylene, dieldrin, dichloroprop, and simazine were detected at low concentrations. Concentrations of sodium and chloride were higher in samples collected from wells screened in the top of the saturated zone than in samples collected from deeper zones. Volatile organic compounds and elevated concentrations of nitrite plus nitrate as nitrogen were detected at depths of as much as 60 feet below the water table, indicating that the effects of human activities on the ground-water quality extends to the bottom of the surficial aquifer. The age of ground water, as determined by tritium and 3helium concentrations, was 0.9 to 22.6 years. pH, alkalinity, and calcium were higher and concentrations of dissolved oxygen were lower in ground-water samples with ages of 10 years or more than in samples younger than 10 years. In addition, concentrations of sodium, chloride, and nitrite plus nitrate nitrogen were low in ground-water samples with ages of 10 years or more, indicating that concentrations of these compounds may be increasing with time or that the recharge areas to these wells may have had less intensive urban land use. Methyl-tert-butyl ether was detected only in wells with ground water ages of less than 11 years, which is consistent with the date of introduction of this compound as a gasoline additive in Connecticut. Analysis of additional samples collected for analysis of stable nitrogen isotopes indicated that the most likely source of elevated concentrations of nitrate nitrogen was lawn and garden fertilizers, but other sources, including wastewater effluents, soil organic nitrogen, and atmospheric deposition, may contribute to the total. Population density was positively correlated (at the 97 percent confidence level) to concentrations of nitrite plus nitrate as nitrogen. Water quality in the Hockanum River aquifer has been degraded by human activities, and, after discharge to surface water, affects the water quality in the Hockanum River. On an annual basis, ground-water discharge from the study area to the river (as measured at a downstream continuous-record gaging station) contributes about 5 percent of the annual load of nitrite plus nitrate nitrogen, but, during low flow, contributes 11 percent of the nitrite plus nitrate nitrogen, 32 percent of the calcium, and 16 percent of the chloride to the river.

Connecticut↗

Duration of hydrothermal alteration and mineralization of the Don Manuel porphyry copper system, central Chile

The Don Manuel porphyry copper system, located in the Miocene–Pliocene metallogenic belt of central Chile, contains spatially zoned alteration styles common to other porphyry copper deposits including extensive potassic alteration, propylitic alteration, localized sericite-chlorite alteration and argillic alteration but lacks pervasive hydrolytic alteration typical of some deposits. It is one of the youngest porphyry copper deposits in the Andes. Timing of mineralization and the hydrothermal system at Don Manuel are consistent with emplacement of the associated intrusions (ca. 4 and 3.6 Ma). Two molybdenite samples yielded consistent ages of 3.412 ± 0.037 and 3.425 ± 0.037 Ma. 40 Ar/ 39 Ar ages on hydrothermal biotites (3.57 ± 0.02, 3.51 ± 0.02, 3.41 ± 0.01, and 3.37 ± 0.01 Ma) are associated with potassic alteration. These ages are younger than the youngest intrusion by ~300 k.y. recording the cooling of the system below 350 °C. Such a time gap can be explained by fluxing of hot magmatic fluids from deeper magmatic sources.

central Chile↗