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At least 1,549 records · Page 86Linked to original sources
USGS2021

Miocene neritic benthic foraminiferal community dynamics, Calvert Cliffs, Maryland, USA: Species pool, patterns and processes

The presence/absence and abundance of benthic foraminifera in successive discrete beds (Shattuck “zones”) of the Miocene Calvert and Choptank formations, exposed at the Calvert Cliffs, Maryland, USA, allows for investigation of community dynamics over space and time. The stratigraphic distribution of benthic foraminifera is documented and interpreted in the context of sea-level change, sequence stratigraphy, and the previously published distribution of mollusks. Neritic benthic foraminiferal communities of four sea-level cycles over ∼4 million years of the middle Miocene, encompassing the Miocene Climatic Optimum and the succeeding middle Miocene Climate Transition, are dominated by the same abundant species. They differ in the varying abundance of common species that occur throughout most of the studied section and in the different rare species that appear and disappear. Transgressive systems tracts (TSTs) have higher species diversity than highstand systems tracts (HSTs) but much lower density of specimens. In contrast to some previous research, all beds in the studied section are interpreted as being from the inner part of a broad, low gradient shelf and were deposited at water depths of less than ∼50 m. It is suggested that species are recruited from a regional species pool of propagules throughout the duration of TSTs. Recruitment is curtailed during highstands leading to lower diversity in the HSTs.

Maryland↗
USGS2012

Stratigraphic architecture of bedrock reference section, Victoria Crater, Meridiani Planum, Mars

The Mars Exploration Rover Opportunity has investigated bedrock outcrops exposed in several craters at Meridiani Planum, Mars, in an effort to better understand the role of surface processes in its geologic history. Opportunity has recently completed its observations of Victoria crater, which is 750 m in diameter and exposes cliffs up to ~15 m high. The plains surrounding Victoria crater are ~10 m higher in elevation than those surrounding the previously explored Endurance crater, indicating that the Victoria crater exposes a stratigraphically higher section than does the Endurance crater; however, Victoria strata overlap in elevation with the rocks exposed at the Erebus crater. Victoria crater has a well-developed geomorphic pattern of promontories and embayments that define the crater wall and that reveal thick bedsets (3–7m) of large-scale cross-bedding, interpreted as fossil eolian dunes. Opportunity was able to drive into the crater at Duck Bay, located on the western margin of Victoria crater. Data from the Microscopic Imager and Panoramic Camera reveal details about the structures, textures, and depositional and diagenetic events that influenced the Victoria bedrock. A lithostratigraphic subdivision of bedrock units was enabled by the presence of a light-toned band that lines much of the upper rim of the crater. In ascending order, three stratigraphic units are named Lyell, Smith, and Steno; Smith is the light-toned band. In the Reference Section exposed along the ingress path at Duck Bay, Smith is interpreted to represent a zone of diagenetic recrystallization; however, its upper contact also coincides with a primary erosional surface. Elsewhere in the crater the diagenetic band crosscuts the physical stratigraphy. Correlation with strata present at nearby promontory Cape Verde indicates that there is an erosional surface at the base of the cliff face that corresponds to the erosional contact below Steno. The erosional contact at the base of Cape Verde lies at a lower elevation, but within the same plane as the contact below Steno, which indicates that the material above the erosional contact was built on significant depositional paleotopography. The eolian dune forms exposed in Duck Bay and Cape Verde, combined with the geometry of the erosional surface, indicate that these outcrops may be part of a larger-scale draa architecture. This insight is possible only as a result of the larger-scale exposures at Victoria crater, which significantly exceed the more limited exposures at the Erebus, Endurance, and Eagle craters.

Book chapter↗
USGS2012

Thermal maturation history of Arctic Alaska and the southern Canada Basin

The emerging global focus on the oil and gas potential of the Arctic underscores the importance of understanding petroleum systems with limited data. Geohistory modeling of Arctic Alaska (including the Chukchi shelf) and the southern Canada basin indicates that regional patterns of thermal maturity and timing of petroleum generation reflect geologic processes associated with rift-opening of the Canada basin and collision orogenesis along the Brooks Range–Herald arch from Jurassic through Tertiary time. The base of the Cretaceous–Tertiary Brookian sequence provides a regional reference horizon because most oil generation occurred as the result of Brookian burial. In Arctic Alaska, basal Brookian strata on the Beaufort rift shoulder grade from immature in the west to overmature in the east. From the crest of the rift shoulder, thermal maturity of basal Brookian strata increases southward into the oil window on the north flank of the Colville foreland basin and into the gas window in the foredeep. A .200-mile-wide area of immature to mature strata in the Chukchi Sea narrows eastward as the Brooks Range converges with the rift shoulder in the eastern North Slope. These patterns reflect generally low Jurassic to Tertiary sediment accommodation on the rift shoulder, large Cretaceous sediment accommodation in the Colville foredeep, and northward impingement of the Brooks Range onto the eastern part of the rift shoulder during the Tertiary. Fewer geologic data in the Canada basin increases the uncertainty of modeling. Projection of stratigraphy from the rift shoulder, reconstruction of regional sediment dispersal patterns, and consideration of source rocks in Arctic Alaska and Canada indicate the potential for four source rocks in the Cretaceous and Paleogene. Model results indicate that all four source rocks are mature or overmature across much of the southern Canada basin. The highest thermal maturity occurs in depocenters immediately north of the rift shoulder and on the eastern margin of the study area, which is the distal Mackenzie delta. The lowest thermal maturity occurs at the northern limit of modeling, more than 200 miles north of the rift shoulder and on the western margin of the study area, adjacent to the Chukchi borderland. A potential source rock in the Lower Cretaceous likely matured during the Early Cretaceous in a western depocenter related to sediment by-pass of the Chukchi shelf, but maturation of all source rocks elsewhere occurred during the Paleogene when large volumes of sediment were shed from the Brooks Range and through the Mackenzie delta.

Alaska↗
USGS2010

Alexandria's Eastern Harbor, Egypt: Pollen, microscopic charcoal, and the transition from natural to human-modified basin

Pollen and microscopic charcoal examined in Holocene sediment core samples record major environmental modifications affecting Alexandria's Eastern Harbor through time. We assess whether such changes on Egypt's coastal margin were influenced primarily by natural, or natural plus human, or primarily human factors. We focus on (1) the times when pollen assemblages and microscopic charcoal content changed in the core, (2) how they changed, and (3) why this occurred. The analysis takes into account the core's stratigraphy, regional climate variability, human history, and local archaeological record. Four pollenmicroscopic charcoal zones are identified. The earliest change occurred at ca. 6000 YBP, during Egypt's earlier Predynastic (Neolithic) period, coinciding with a lithologic break from sand to muddy sand. Pollen during this time indicates a transition to a much drier climate rather than effects of human activity. The second change in pollen occurred 3600-2900 YBP, during a period of continued aridity with no lithologic variation in this core interval. Pollen (cereal taxa, agricultural weeds, grape) and a sharp increase in microscopic charcoal indicate that human activity became prevalent at least 700 y before Alexander the Great's arrival in this region, and these results highlight the transition from a largely natural climatecontrolled environment to one influenced by both climate and anthropogenic activity. The third shift up-core in pollen assemblages is dated at ca. 2300 YBP, at the boundary between a sand and mud unit. It coincides with construction by the Ptolemies of the Heptastadion between Alexandria and Pharos Island. From this time onward, harbor sediment in the nearly enclosed catchment basin indicates a near-continuous record of dominant proximal human activity. ?? 2010 Coastal Education and Research Foundation.

Journal of Coastal Research↗
USGS2009

Sediment characterization and dynamics in Lake Pontchartrain, Louisiana

Lake Pontchartrain in southeastern Louisiana is the largest of several shallow estuaries that together cover over 15,000 km 2 . Wetlands, forests, and large urban areas surround the lake. Primary transport mechanisms of sediments to Lake Pontchartrain include urban runoff, major diversions of the Mississippi River, discharge from streams along the north and west shores, and tidal circulation. Sediments deposited in Lake Pontchartrain are subjected to resuspension and mixing by natural and human activities. Bioturbation and water turbulence throughout the lake are the major mixing agents, and mechanical shell dredging has reworked much of the lake bottom over the last century. Sediment characterization through direct sampling and geophysical surveys indicates that these processes continually rework the top meter of sediment. The lake receives discharge from roadways and industrial and agricultural sources. Contaminants from these sources accumulate in the lake sediments and are an important contributor to the degradation of the estuary. Decline in populations of various benthic organisms, such as shrimp and clams, has been documented in the lake. To characterize the health of this important estuary, the U.S. Geological Survey (USGS) conducted a comprehensive evaluation of the geology, geomorphology, coastal processes, and environmental condition of the Pontchartrain Basin from 1994 to 1997. This report presents an assessment of sediment distribution and quality using a multidisciplinary approach to characterize the influence of various physical and chemical parameters: nearsurface stratigraphy, major trace metal concentrations (Cu, Pb, Zn, and Ni), and short-lived radionuclides ( 210 Pb, 7 Be, and 137 Cs). The results are compared with water-circulation patterns to determine high-resolution sedimentation patterns in the lake. The data show a significant increase in trace metals in the top 1 m of lake sediments. Above this horizon, pollen analysis indicates a correlation with land clearing in the area, a proxy for increasing human development of the surrounding landscape and an increase in surface run-off. The data also show that the top meter of sediment undergoes frequent resuspension during high-energy circulation events and via circulation gyres in the lake. This regular turnover does not allow stratification of recently deposited sediments, restricting the sequestration of contaminated material that enters the lake.

Louisiana↗
USGS2009

Review of the geologic history of the Pontchartrain Basin, northern Gulf of Mexico

The Pontchartrain Basin extends over 44,000 km² from northern Mississippi to the Gulf of Mexico and includes one of the largest and most important estuarine systems in the United States. The basin supports a variety of environments, from woodlands in the north to wetlands in the south, and a growing socioeconomic infrastructure that has led to rapid development of the southern half of the basin over the past two centuries. To properly administer this infrastructure, managers need to understand the complex geologic framework of the basin and how it will respond to continued sea-level rise, variable rates and magnitudes of land subsidence, and human alteration of the landscape. This article summarizes the body of work that describes the regional evolution and stratigraphic architecture of the Pontchartrain Basin. The northern two-thirds of the basin is underlain by a stratigraphy of undifferentiated sands and clays deposited throughout the Plio-Pleistocene by glacially influenced rivers. These deposits were weathered and incised by rivers during sea-level low stands, forming a series of terraces that increase with age from south to north. The southern third of the basin is composed of estuaries formed during the Holocene, while shoreline processes created a series of sandy barriers that restricted communication to the Gulf of Mexico. The Mississippi River completed the geologic development of the basin by building a sequence of subdelta lobes along this southern margin over the past 5000 years, further sealing it from the open Gulf of Mexico. Presently, the modern Mississippi River bypasses the estuarine environment and only contributes sediments during flood events when the river overtops the levee system. Sea-level rise, subsidence within the Holocene delta-plain deposits, and movement along numerous fault systems are the active natural processes that continue to affect basin geomorphology.

Louisiana, Mississippi↗
USGS2013

Geologic controls on regional and local erosion rates of three northern Gulf of Mexico barrier-island systems

The stratigraphy of sections of three barrier island systems in the northeastern Gulf of Mexico (Apalachicola, Mississippi, and Chandeleur) have been mapped using geophysical and coring techniques to assess the influence of geologic variations in barrier lithosomes and adjoining inner shelf deposits on long-term rates of shoreline change at regional and local scales. Regional scale was addressed by comparing average geologic characteristics of the three areas with mean shoreline-change rates for each area. Regionally, differences in sand volume contained within the part of the barrier lithosome above sea level, sand volume on the inner shelf, and to a lesser extent, sediment grain size correlate with shoreline change rates. Larger sand volumes and coarser grain sizes are found where erosion rates are lower. Local scale was addressed by comparing alongshore variations in barrier island and inner shelf geology with alongshore variations in shoreline change. Locally, long-term shoreline change rates are highest directly shoreward of paleovalleys exposed on the inner shelf. While geology is not the sole explanation for observed differences in shoreline change along these three coastal regions, it is a significant contributor to change variability.

Journal of Coastal Research↗
USGS2012

Genesis of the Touissit-Bou Beker Mississippi Valley-type district (Morocco-Algeria) and its relation to the Africa-Europe collision

The Mississippi Valley-type deposits of the Touissit-Bou Beker district are hosted by a 25 m thick sequence of diagenetically and hydrothermally dolomitized carbonate platform rocks of Aalenian-Bajocian age. The sulfide mineralization consists principally of galena and sphalerite and occurs as open-space fillings of voids and moderate to massive replacement of the medium- to coarse-grained host dolostone. Five types of dolomite have been distinguished, two of which (D 1 and D 2 ) are of replacement origin, whereas HD 1 , HD 2 , HD 3 occurring as open-space filling are of hydrothermal affiliation. Main ore controls include stratigraphy and lithology, carbonate dissolution, paleogeography, faults or faulted rocks, and availability of organic matter. Fluid inclusion data, along with Na-Cl-Br leachate, indicate that the ore-forming fluids correspond to evolved NaCl-CaCl 2 -KCl-MgCl 2 basin-derived hot (100° ± 20°C) saline brines (>20 wt % NaCl equiv) that acquired their high salinities and Ca/Na ratios through evaporation of seawater, and subsequent dolomitization and fluid-rock interactions. Stable isotope data for replacement and hydrothermal dolomites are tightly clustered and overlapping, with δ 18 O and δ 13 C values from 20.5 to 21.2 and 0.2 to 0.7‰, respectively. Similarly, sulfides yield δ 34 S values between 11.2 and 1.9‰, whereas those corresponding to the nearby Triassic gypsum cluster yield around 14‰. Altogether, these isotopic compositions are consistent with a basinal-type fluid with reduced sulfur very likely being derived through thermochemical reduction of dissolved sulfate, resulting in metal precipitation, and carbon of mainly marine Aalenian-Bajocian carbonate origin with a minor biogenic component. 87 Sr/ 86 Sr values of replacement dolostone are similar to those of ore-related hydrothermal dolomites, ranging from 0.70746 to 0.70833 and from 0.70769 to 0.70828, respectively, and are different from those of the Visean rhyodacite (0.71849–0.72167). Lead isotope ratios ( 206 Pb/ 204 Pb = 18.319–18.390; 207 Pb/ 204 Pb = 15.620–15.680; 208 Pb/ 204 Pb = 38.452–38.650) of sulfides are consistent with Pb being derived from the Visean rhyodacite and associated volcaniclastic rocks. The intimate link between faults and mineralization suggests the strong possibility of brine flow along both ENE-trending regional-scale faults and NW-SW-trending local-scale faults. The data suggest that MVT mineralization was emplaced during the late Neogene-Quaternary (i.e., ca. 15–0 Ma), possibly as a result of subsurface gravity-driven fluid flow in response to the collision between the African and Eurasian plates.

Touissit-bou Beker District↗
USGS1937

Role of physical chemistry in stratigraphic problems

Stratigraphy is concerned mainly with the genesis and interpretation of stratified rocks, which include some of wide extent and of great scientific as well as economic interest that are largely of chemical rather than of detrital origin. Chemical agencies have been recognized to some extent in genetic studies of these rocks, but little work has been done approaching in maturity the type of study now given to the genesis of igneous rocks and of ores, in which physical chemistry plays so important a part.A plea is presented to geologists with training in physical chemistry to interest themselves in stratigraphic problems that involve the use of this science. Examples cited are the phosphate beds and bedded cherts of the Phosphoria formation in Idaho and adjacent States and the potash-bearing Salado halite of the Permian basin in New Mexico and Texas. The interplay of ions in the solutions from which these formations were derived must have been controlled by such conditions as temperature, pressure, degree of concentration, and the like. Possibly laboratory study would enable us to reproduce these conditions and results and thus better interpret the geologic history of the times when these formations were built.

Economic Geology↗
USGS1982

Massive sulfide deposits of the Southern Appalachians central Virginia volcanic-plutonic belt as a host for massive sulfide deposits

Strata-bound massive sulfide deposits of the central Virginia Piedmont occur in a volcanic- plutonic belt composed of Lower Cambrian(?) metamorphosed volcanic rocks and locally of pre-Upper Ordovician, low potassium granitoid rocks. The belt, interpreted as an ancient island arc, begins about 50 km south of Washington, D. C, and extends some 175 km south- westward. The volcanic rocks within the belt are located along the flanks of the Quantico- Columbia synclinorium and the Arvonia syncline. The Chopawamsic Formation, a western facies of the belt, consists of volcanic rocks that have the geochemical features (rare earth and immobile elements) of a tholeiitic island-arc suite; it also contains calc-alkaline components. Tholeiitic amphibolites of the Ta River Metamorphic Suite on the eastern side of the belt form an oceanward facies of the island arc, coeval with the Chopawamsic. This distribution suggests an underlying westward-dipping Cambrian(?) subduction zone. Contrasts in stratigraphy, geochemistry, and magnetic and gravity features indicate that the central Virginia volcanic- plutonic belt is not related to the Carolina slate belt as has been proposed in the past. Known sulfide bodies in the Chopawamsic and its coeval units total about 13.5 million tons. The Mineral district on the northwest flank of the Quantico-Columbia synclinorium has the largest deposits and contains about 10 million tons. Sulfide bodies in the belt consist largely of pyrite with minor sphalerite and chalcopyrite; Zn and Pb are important in a few of the smaller deposits. There are local concentrations of sphalerite and other base metal minerals within the major pyritic deposits (Zn = 1-12.5%; Cu - 1-2%; Pb as much as 5%). The dom- inantly sphaleritic deposits are found in and northward for about 15 km from the Mineral district. Sulfide mineralization is found in all types of volcanic rock, but the large sulfide bodies on the northwest flank of the Quantico-Columbia synclinorium are in felsite. Am- phibolite, containing local beds of iron-formation, is abundant on the southeast flank of the Arvonia syncline; however, most sulfide mineralization there took place in felsitic to intermediate layers. Mineralization, attributed to submarine volcanic exhalation, took place during formation of the island arc.

Economic Geology↗
USGS1996

Clay alteration and gold deposition in the genesis and blue star deposits, Eureka County, Nevada

The Genesis and Blue Star sedimentary rock-hosted gold deposits occur within the 40-mile-long Carlin trend and are located in Eureka County, Nevada. The deposits are hosted within the Devonian calcareous Popovieh Formation, the siliciclastic Rodeo Creek unit and the siliciclastic Vinini Formation. The host rocks have undergone contact metamorphism, decalcification, silicification, argillization, and supergene oxidation.Detailed characterization of the alteration patterns, mineralogy, modes of occurrence, and associated geochemistry of clay minerals resulted in the following classifications: least altered rocks, found distal to the orebody, consisting of both metamorphosed and unmetamorphosed host rock that has not been completely decalcified; and altered rocks, found proximal to the orebody that have been decalcified. Altered rocks are classified further into the following groups based on clay mineral content: silicic, 1 to 10 percent clay; silicic-argillic, 10 to 35 percent clay; and argillic, 35 to 80 percent clay. Clay species identified are 1M illite, 2M 1 illite, kaolinite, halloysite, and dioctahedral smectite. An early hydrothermal event resulted in the precipitation of euhedral kaolinite and at least one generation of silica. This event occurred contemporaneously with decalcification which increased rock permeability and porosity. A second clay alteration event resulted in the precipitation of hydrothermal 1M illite which replaced hydrothermal kaolinite and is associated with gold deposition. Silver and silica deposition is also associated with this phase of hydrothermal alteration. Hydrothermal alteration was followed by supergene alteration which resulted in the formation of supergene kaolinite, halloysite, and smectite as well as the oxidation of iron-bearing minerals. Supergene clays are concentrated along faults, dike margins, and within rocks containing carbonate. Gold mineralization is not associated with supergene clay minerals within the Genesis and Blue Star deposits. Rocks classified as silicic-argillic in the Popovich Formation represent the most significant gold host. Silicic-argillic rocks commonly exhibit bedding-parallel alteration zones. This pattern of alteration indicates that stratigraphy as well as northwest-trending structures played a significant role in the migration of gold-bearing fluids. Based on K-Ar age determinations of hydrothermal 1M illite associated with gold, the main event of mineralization in the Genesis and Blue Star deposits occurred between 93 and 100 Ma, during mid-Cretaceous time.

Economic Geology↗
USGS2003

A special issue devoted to gold deposits in northern Nevada: Part 2. Carlin-type Deposits

This is the second of two special issues of Economic Geology devoted to gold deposits in northern Nevada. Readers interested in a general overview of these deposits, their economic significance, their context within the tectonic evolution of the region, and synoptic references on each gold deposit type are directed to the preface of the first special issue (John et al., 2003). Volume 98, issue 2, contains five papers that address regional aspects important to the genesis of gold deposits in northern Nevada and five papers that present detailed studies of epithermal deposits and districts. All of the regional papers are pertinent to Carlin-type gold deposits, because they address the age of mineralization (Arehart et al., 2003), origin and evolutionary history of the northwest-striking mineral belts that localize many deposits (Grauch et al., 2003), nature of the middle and lower crust below these mineral belts (Howard, 2003), district- to deposit-scale stream sediment and lithogeochemical anomalies (Theodore et al., 2003), and stratigraphy and structure of a district located along a northeast-striking lineament (Peters et al., 2003). The nine papers in this second special issue focus on an array of problems pertinent to genetic and exploration models for Carlin-type deposits in northern Nevada (Fig. 1). These investigations sort out and characterize the sequence of deformational, igneous, and hydrothermal events in mining districts, constrain the age of mineralization, map paleothermal gradients, identify structures and lithologies that are preferentially mineralized, ascertain processes of ore formation, determine sources of ore fluid components, and define fluid flow paths. A common theme among these papers is inheritance, whereby older features in the mineral belts influence ore formation in subsequent Carlin-type hydrothermal systems. Three types of inheritance are inferred by one or more of these investigations: (1) structural inheritance, where older faults are reactivated during subsequent contractional and/or extensional tectonic events producing permeable fracture systems that focused flow of ore fluids; (2) alteration inheritance, where one or more preore alteration events produced reactive host rocks that are preferentially mineralized; and (3) geochemical inheritance, in which Au and other elements are recycled from older mineralization into younger Carlin-type deposits. Despite the similar age, tectonic setting, alteration types, mineral parageneses, and geochemical signatures of the deposits studied, these papers do not lead to consensus regarding genetic models for Carlin-type deposits. Rather, the separate investigations by different workers, utilizing both similar and unlike approaches, result in markedly different conclusions. Some of this disparity probably is due to real differences in the origin of different districts; however, the opposing conclusions arrived at by investigations on neighboring deposits in a single district are more problematic and most likely are due to difficulties resulting from the superposition of different types and ages of gold mineralization or to substantial variations in the hydrology and proportions of fluid components derived from deep and shallow sources in each deposit. Further work is needed to validate and understand the significance of these differences.

Nevada↗
USGS2007

Ground water stratification and delivery of nitrate to an incised stream under varying flow conditions

Ground water processes affecting seasonal variations of surface water nitrate concentrations were investigated in an incised first-order stream in an agricultural watershed with a riparian forest in the coastal plain of Maryland. Aquifer characteristics including sediment stratigraphy, geochemistry, and hydraulic properties were examined in combination with chemical and isotopic analyses of ground water, macropore discharge, and stream water. The ground water flow system exhibits vertical stratification of hydraulic properties and redox conditions, with sub-horizontal boundaries that extend beneath the field and adjacent riparian forest. Below the minimum water table position, ground water age gradients indicate low recharge rates (2-5 cm yr-1) and long residence times (years to decades), whereas the transient ground water wedge between the maximum and minimum water table positions has a relatively short residence time (months to years), partly because of an upward increase in hydraulic conductivity. Oxygen reduction and denitrification in recharging ground waters are coupled with pyrite oxidation near the minimum water table elevation in a mottled weathering zone in Tertiary marine glauconitic sediments. The incised stream had high nitrate concentrations during high flow conditions when much of the ground water was transmitted rapidly across the riparian zone in a shallow oxic aquifer wedge with abundant outflow macropores, and low nitrate concentrations during low flow conditions when the oxic wedge was smaller and stream discharge was dominated by upwelling from the deeper denitrified parts of the aquifer. Results from this and similar studies illustrate the importance of near-stream geomorphology and subsurface geology as controls of riparian zone function and delivery of nitrate to streams in agricultural watersheds.

Maryland↗
USGS2010

Trends and transformation of nutrients and pesticides in a Coastal Plain aquifer system, United States

Four local-scale sites in areas with similar corn (Zea mays L.) and soybean [Glycine max (L.) Merr.] agriculture were studied to determine the effects of different hydrogeologic settings of the Northern Atlantic Coastal Plain (NACP) on the transport of nutrients and pesticides in groundwater. Settings ranged from predominantly well-drained soils overlying thick, sandy surficial aquifers to predominantly poorly drained soils with complex aquifer stratigraphy and high organic matter content. Apparent age of groundwater, dissolved gases, N isotopes, major ions, selected pesticides and degradates, and geochemical environments in groundwater were studied. Agricultural chemicals were the source of most dissolved ions in groundwater. Specific conductance was strongly correlated with reconstructed nitrate (the sum of N in nitrate and N gas) (R 2 = 0.81, p < 0.0001), and is indicative of the relative degree of agricultural effects on groundwater. Trends in nitrate were primarily related to changes in manure and fertilizer use at the well-drained sites where aquifer conditions were consistently oxic. Nitrate was present in young groundwater but completely removed over time through denitrification at the poorly drained sites where there were variations in chemical input and in geochemical environment. Median concentrations of atrazine (6-chloro-N-ethyl-N'-(1- methylethyl)-1,3,5-triazine-2,4-diamine), metolachlor (2-chloro-N-(2-ethyl-6- methylphenyl)-N-(2-methoxy-1-methylethyl)acetamide), and some of their common degradates were higher at well-drained sites than at poorly drained sites, with concentrations of degradates generally higher than those of the parent compounds at all sites. An increase in the percentage of deethylatrazine to total atrazine over time at one well-drained site may be related to changes in manure application. Copyright ?? 2010 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America. All rights reserved.

Journal of Environmental Quality↗
USGS2000

Historical trends in Chesapeake Bay dissolved oxygen based on benthic foraminifera from sediment cores

Environmentally sensitive benthic foraminifera (protists) from Chesapeake Bay were used as bioindicators to estimate the timing and degree of changes in dissolved oxygen (DO) over the past five centuries. Living foraminifers from 19 surface samples and fossil assemblages from 11 sediment cores dated by 210 Pb, 137 Cs, 14 C, and pollen stratigraphy were analyzed from the tidal portions of the Patuxent, Potomac, and Choptank Rivers and the main channel of the Chesapeake Bay. Ammonia parkinsoniana , a facultative anaerobe tolerant of periodic anoxic conditions, comprises an average of 74% of modern Chesapeake foraminiferal assemblages (DO-0.47 and 1.72 ml l −1 ) compared to 0% to 15% of assemblages collected in the 1960s. Paleoecological analyses show that A. parkinsoniana was absent prior to the late 17th century, increased to 10–25% relative frequency between approximately 1670–1720 and 1810–1900, and became the dominant (60–90%) benthic formaniferal species in channel environments beginning in the early 1970s. Since the 1970s, deformed tests of A. parkinsoniana occur in all cores (10–20% of Ammonia ), suggesting unprecedented stressful benthic conditions. These cores indicate that prior to the late 17th century, there was limited oxygen depletion. During the past 200 years, decadal scale variability in oxygen depletion has occurred, as dysoxic (DO=0.1–1.0 ml l −1 ), perhaps short-term anoxic (DO<0.1 ml l −1 ) conditions developed. The most extensive (spatially and temporally) anoxic conditions were reached during the 1970s. Over decadal timescales, DO variability seems to be linked closely to climatological factors influencing river discharge; the unprecedented anoxia since the early 1970s is attributed mainly to high freshwater flow and to an increase in nutrient concentrations from the watershed.

Maryland, Virginia↗
USGS1980

Neogene diatoms from Petersburg, Virginia

Sixty-two diatom taxa have been identified from a diatomaceous sandy clay that crops out near the outlet of Wilcox Lake, Petersburg. Virginia. These diatoms are mostly cosmopolitan marine forms, but some species suggest deposition in brackish water that had a freshwater inflow. The regional stratigraphy, as well as the pelecypods and foraminifers, indicates that the beds may have been laid down in a lagoonal or estuarine environment. The diatom assemblage suggests that the deposit is of early Pliocene age, although previous biostratigraphic studies have considered it to be latest Miocene.

Virginia↗
USGS1991

Holocene Treeline Fluctuations in the Northern San Juan Mountains, Colorado, U.S.A., as Indicated by Radiocarbon-Dated Conifer Wood

An early to mid-Holocene warm period with greater than present-day monsoonal circulation is indicated by evidence in the northern San Juan Mountains of southwestern Colorado. Fifty radiocarbon ages of coniferous wood fragments, and several other radiocarbon ages of willow fragments, woody peat, and organic sediment associated with conifer remains, recovered from six sites at or above present-day treeline indicate that during the first half of the Holocene treeline was higher than present. Radiocarbon ages of coniferous wood fragments recovered from the remains of Lake Emma, a former glacial tarn above present-day treeline, indicate that between 9600 and 5400 BP treeline in the northern San Juan Mountains was at least 80 m higher than present. Furthermore, a radiocarbon age of a large spruce fragment with a complacent annual-ring record suggests that at about 8000 BP timberline may have been at least 140 m higher than present. These data suggest that during the early to mid-Holocene average July temperatures were at least 0.5 to 0.9°C higher than present. Radiocarbon ages and stratigraphy from bogs in the study area near present-day treeline suggest that between 5400 and 3500 BP treeline was near its present-day limits. After 3500 BP treeline was generally lower than present although short climatic ameliorations, with accompanying rises in treeline, may have occurred at about 3100 and 2400 BP. Deuterium concentrations previously determined for the cellulose of 18 conifer fragments from the Lake Emma site indicate a 70‰ decrease in deuterium from 9600 BP to present. These data indicate that the early Holocene increase in July solar radiation may have resulted in the intensification of the Arizona monsoon at that time.

Colorado↗
USGS1996

Little Ice Age evidence from a south-central North American ice core, U.S.A.

In the past, ice-core records from mid-latitude glaciers in alpine areas of the continental United States were considered to be poor candidates for paleoclimate records because of the influence of meltwater on isotopic stratigraphy. To evaluate the existence of reliable paleoclimatic records, a 160-m ice core, containing about 250 yr of record was obtained from Upper Fremont Glacier, at an altitude of 4000 m in the Wind River Range of south-central North America. The δ 18 O (SMOW) profile from the core shows a -0.95‰ shift to lighter values in the interval from 101.8 to 150 m below the surface, corresponding to the latter part of the Little Ice Age (LIA). Numerous high-amplitude oscillations in the section of the core from 101.8 to 150 m cannot be explained by site-specific lateral variability and probably reflect increased seasonality or better preservation of annual signals as a result of prolonged cooler temperatures that existed in this alpine setting. An abrupt decrease in these large amplitude oscillations at the 101.8-m depth suggests a sudden termination of this period of lower temperatures which generally coincides with the termination of the LIA. Three common features in the δ18O profiles between Upper Fremont Glacier and the better dated Quelccaya Ice Cap cores indicate a global paleoclimate linkage, further supporting the first documented occurrence of the LIA in an ice-core record from a temperate glacier in south-central North America.

Upper Fremont Glacier, Wind River Range↗