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Stratigraphy and correlation of the glacial deposits on the Montana Plains

Till units representing at least three pre-Illinoian continental glaciations, at least one Illinoian glaciation, and a late Wisconsin glaciation have been identified on the Montana Plains. Early Wisconsin or middle Wisconsin till units have not been identified. The southernmost limit of late Wisconsin glaciation is in Montana, more than 170 km south of the Lethbridge moraine in Alberta, Canada (Figs 1 and 2). An interpretation that the Lethbridge moraine is the limit of late Wisconsin glaciation (Stalker, 1977, 1980, 1983b; Stalker and Harrison, 1977; Rutter, 1980, 1981; Jackson, 1983) is incompatible with stratigraphic and morphologic evidence from Montana.

Montana, North Dakota↗

Spatial and temporal patterns of late Quaternary eolian deposition, eastern Colorado, USA

Eolian sediment covers about 60% of Colorado east of the Rocky Mountains; about 30% of the sediment is sand and 70% is loess. Initially, flood plains were the principal sources of eolian sediment, but during the Holocene, dunes formed from older eolian sand and alluvium on uplands. Since latest Pleistocene time, dominant dune-forming winds have been northwesterly in the northern part of the region and southwesterly in the southern part. At present, sand sheets and dunes, mainly parabolic types, are stable and covered with vegetation. In dunes, sand is commonly 20–30 m thick but elsewhere averages < 10 m. Three sand units are recognized on the basis of bedforms, topographic expression, and soil development. Preliminary age limits for the three units, based on 26 numerical ages, are 22.5–9 ka, 8−1 ka, and l.0−0. 15 ka. The middle unit is the product of multiple episodes of eolian activity that are not yet accurately dated. Loess is widespread but thin (generally < 2.4 m). Three units — middle Pleistocene, late Pleistocene. and Holocene — are recognized on the basis of differences in soil-profile development and stratigraphic position; late Pleistocene loess is by far the most common loess.

Colorado↗

The need for accuracy in modelling: An example

The need for accurate information in modelling depends on the objectives of the effort. but trustworthy data are essential for a model intended for use in the management of natural resources. This point is illustrated by referring to a recently published model of canvasback ducks. We demonstrate that several key assumptions are not supported by biological evidence, and that inferences drawn from the model could be dangerously misleading if they were used to guide the management of canvasback ducks.

Ecological Modelling↗

Inheritance patterns of enzymes and serum proteins of mallard-black duck hybrids

From 1974 to 1976, a breeding program was used to produce hybrids of black ducks and mallards for the evaluation of inheritance patterns of serum proteins and serum, liver and muscle enzymes. In addition to the crosses designed to produce hybrids, a series of matings in 1975 and 1976 were designed to evaluate inheritance patterns of a hybrid with either a black duck or mallard. At the F1 level, hybrids were easily distinguished using serum proteins. However, once a hybrid was crossed back to either a mallard or black duck, only 12?23% of the progeny were distinguishable from black ducks or mallards using serum proteins and 23?39% using esterases. Muscle, serum and liver enzymes were similar between the two species.

Biochemical Systematics and Ecology↗

Aerial infrared surveys of Reykjanes and Torfajökull thermal areas, Iceland, with a section on cost of exploration surveys

In 1966 and 1968 aerial infrared surveys were conducted over 10 of 13 high-temperature thermal areas in Iceland. The surveys were made with an airborne scanner system, utilizing radiation in the 4.5–5.5 μm wavelength band. Supplementary ground geological studies were made in the Reykjanes and Torfajökull thermal areas to interpret features depicted on the infrared imagery and to relate zones of high heat flux to tectonic structure. In the Reykjanes area in southwestern Iceland a shallow ground temperature map was prepared for temperatures at a depth of 0.5 meters; comparison of this map with the infrared imagery reveals some striking similarities. It appears that aerial infrared surveys outline the surface thermal patterns of high-temperature areas and aid in relating these patterns to possible geological structures controlling the upflow of hot water. Amplitude-slicing techniques applied to the magnetically taped airborne scanner data permit an estimate to be made of the natural heat output on the basis of size of area and specific radiance. In addition to their value in preliminary studies of high-temperature areas, infrared surveys conducted at regular intervals over thermal area under exploitation can provide valuable data on changes that occur in surface manifestations with time. e.

Reykjanes, Torfajokull↗

Response of douglas fir (Pseudotsuga menziesii) to uraniferous groundwater in a small glaciated drainage, Northeastern Washington State

Douglas fir trees and associated soils were sampled from the slopes of a small (∼4 km 2 ) drainage basin in northeastern Washington to investigate the biogeochemical response to locally uraniferous groundwater. Uranium is preferentially incorporated in needles and twigs compared to larger branches or the trunk. The U concentration in needle ash ranges from 0.2 to 5.8μg g −1 (ppm) and shows no correlation with the U concentration in associated soils. Rather, the distribution of anomalously uraniferous douglas fir (> 1.0 μ g g −1 U in needle ash) appears to be controlled by observed or readily inferred pathways of near-surface groundwater movement in the drainage. These pathways include: (1) general downslope movement of subsurface runoff; (2) increased flux of near-surface groundwater near the toe of an alluvial fan; and (3) emergence of uraniferous (100–150 ng ml −1 [ppb] groundwater in the vicinity of a slope spring. The data also indicate the presence of near-surface uraniferous groundwater along a structurally controlled zone that parallels the north-south strike of the valley, and that includes the slope spring. The results suggest that biogeochemical sampling may be used to supplement more direct, but more limited, measurements of groundwater quality and flow regime in areas of near-surface contaminated groundwater.

Journal of Geochemical Exploration↗

Global data collection and the surveillance of active volcanoes

Data relay systems on existing earth-orbiting satellites provide an inexpensive way to collect environmental data from numerous remote sites around the world. This technology could be used effectively for fundamental monitoring of most of the world's active volcanoes. Such global monitoring would focus attention on the most dangerous volcanoes that are likely to significantly impact the geosphere and the biosphere.

Palaeogeography, Palaeoclimatology, Palaeoecology↗

40Ar/39Ar systematics and argon diffusion in amber: Implications for ancient earth atmospheres

Argon isotope data indicate retained argon in bulk amber (matrix gas) is radiogenic [ 40 Ar/ 39 Ar ≃32o] than the much more abundant surface absorbed argon [ 40 Ar/ 39 Ar ≃295.5]. Neutron-induced 39 Ar is retained in amber during heating experiments to 150° -250°C, with no evidence of recoiled 39 Ar found after irradiation. A maximum permissible volume diffusion coefficient of argon in amber (at ambient temperature) D≤1.5 x 10 −17 cm 2 S −1 is calculated from 39 Ar retention. 40 Ar/ 39 Ar age calculations indicate Dominican Republic amber is ≃ 45 Ma and North Dakota amber is ≃ 89 Ma, both at least reasonable ages for the amber based upon stratigraphic and paleontological constraints and upon the small amount of radiogenic 40 Ar. To date, over 300 gas analyses of ambers and resins of Cretaceous to Recent age that are geographically distributed among fifteen noted world locations identify mixtures of gases in different sites within amber (Berner and Landis, 1988). The presence of multiple mixing trends between compositionally distinct end-members gases within the same sample and evidence for retained radiogenic argon within the amber argue persuasivley against rapid exchange by diffusion of amber-contained gases with moder air. Only gas in primary bubbles entrapped between successive flows of tree resin has been interpreted as original “ancient air”, which is an O 2 -rich end-member gas with air-like N 2 /Ar ratios. Gas analyses of these primary bubbles indicate atmospheric O 2 levels in the Late Cretaceous of ≃ 35%, and that atmospheric O 2 dropped by early Tertiary time to near a present atmospheric level of 21% O 2 . A very low argon diffusion coefficient in amber persuasively argues for a gas in primary bubbles trapped in amber being ancient air (possibly modified only by O 2 reaction with amber).

North Dakota↗

Provenance studies by fission-track dating of zircon-etching and counting procedures

In sedimentary rocks that have not been heated to high enough temperatures to anneal fission tracks in zircon (greater than ≈ 160°C), fission-track ages of individual detrital zircon grains provide valuable information about the source rocks eroded to form the sediments. The success of such studies depends, however, on the degree to which the ages determined from the detrital suite accurately portray the range of grain ages that are present in the suite. This in turn depends to a large extent on using counting and, in particular, etching procedures that permit proper sampling of grains with a wide range of age and uranium concentrations. Results are reported here of an experimental study of a ‘detrital’ zircon suite manufactured from several zircon populations of known age. This study suggests that multiple etches are required when a complete spectrum of ages in a zircon suite is desired.

International Journal of Radiation Applications an↗

The effect of α-damage on fission-track annealing in zircon

The thermal stability of confined fission-track lengths in four zircon samples having different spontaneous track densities (i.e. different amounts of ??-damage) has been studied by one hour isochronal annealing experiments. The thermal stability of spontaneous track lengths is independent of initial spontaneous track density. The thermal stability of induced track lengths in pre-annealed zircon, however, is significantly higher than that of spontaneous track lengths. The results indicate that the presence of ??-damage lowers the thermal stability of fission-tracks in zircon. ?? 1988.

International Journal of Radiation Applications an↗

Where groundwater seeps: Evaluating modeled groundwater discharge patterns with thermal infrared surveys at the river-network scale

Predicting baseflow dynamics, protecting aquatic habitat, and managing legacy contaminants requires explicit characterization and prediction of groundwater discharge patterns throughout river networks. Using handheld thermal infrared (TIR) cameras, we surveyed 47 km of stream length across the Farmington River watershed (1,570 km 2 ; CT and MA, USA), mapping locations of bank and waterline groundwater discharges based on their thermal signature. Using the observed groundwater discharge locations and predicted groundwater discharge rates from 6 variations of a numerical groundwater-flow model (MODFLOW-NWT), we compared 1) predicted groundwater-discharge rates in areas with and without observed groundwater discharge, 2) spatial patterns of observed and predicted groundwater discharge locations, and 3) density of observed groundwater discharge locations with predicted discharge rates. Five of six models reasonably predicted the spatial patterns of discharge locations along the 5th order mainstem, but fewer models predicted groundwater discharge patterns in smaller streams. Our results highlight 1) the feasibility of using TIR observations to evaluate groundwater models, 2) model parameters that influence discharge prediction accuracy (riverbed sediment and bedrock hydraulic conductivity and river-aquifer connections), and 3) current strengths and future opportunities for improved modeling of groundwater-discharge patterns.

Connecticut, Massachusetts↗

Rates of zinc and trace metal release from dissolving sphalerite at pH 2.0-4.0

High-Fe and low-Fe sphalerite samples were reacted under controlled pH conditions to determine nonoxidative rates of release of Zn and trace metals from the solid-phase. The release (solubilization) of trace metals from dissolving sphalerite to the aqueous phase can be characterized by a kinetic distribution coefficient, (Dtr), which is defined as [(Rtr/X(tr)Sph)/(RZn/X(Zn) Sph)], where R is the trace metal or Zn release rate, and X is the mole fraction of the trace metal or Zn in sphalerite. This coefficient describes the relationship of the sphalerite dissolution rate to the trace metal mole fraction in the solid and its aqueous concentration. The distribution was used to determine some controls on metal release during the dissolution of sphalerite. Departures from the ideal Dtr of 1.0 suggest that some trace metals may be released via different pathways or that other processes (e.g., adsorption, solubility of trace minerals such as galena) affect the observed concentration of metals. Nonoxidative sphalerite dissolution (mediated by H+) is characterized by a "fast" stage in the first 24-30 h, followed by a "slow" stage for the remainder of the reaction. Over the pH range 2.0-4.0, and for similar extent of reaction (reaction time), sphalerite composition, and surface area, the rates of release of Zn, Fe, Cd, Cu, Mn and Pb from sphalerite generally increase with lower pH. Zinc and Fe exhibit the fastest rates of release, Mn and Pb have intermediate rates of release, and Cd and Cu show the slowest rates of release. The largest variations in metal release rates occur at pH 2.0. At pH 3.0 and 4.0, release rates show less variation and appear less dependent on the metal abundance in the solid. For the same extent of reaction (100 h), rates of Zn release range from 1.53 ?? 10-11 to 5.72 ?? 10-10 mol/m2/s; for Fe, the range is from 4.59 ?? 10-13 to 1.99 ?? 10-10 mol/m2/s. Trace metal release rates are generally 1-5 orders of magnitude slower than the Zn or Fe rates. Results indicate that the distributions of Fe and Cd are directly related to the rate of sphalerite dissolution throughout the reaction at pH 3.0 and 4.0 because these two elements substitute readily into sphalerite. These two metals are likely to be more amenable to usage in predictive acid dissolution models because of this behavior. The Pb distribution shows no strong relation to sphalerite dissolution and appears to be controlled by pH-dependent solubility, most likely related to trace amounts of galena. The distribution of Cu is similar to that of Fe but is the most-dependent of all metals on its mole fraction ratio (Zn:Cu) in sphalerite. The Mn distributions suggest an increase in the rate of Mn release relative to sphalerite dissolution occurs in low Mn samples as pH increases. The Mn distribution in high Mn samples is nearly independent of pH and sphalerite dissolution at pH 2.0 but shows a dependence on these two parameters at higher pH (3.0-4.0).

Applied Geochemistry↗

Efficacy of hydrogen peroxide to control saprolegniasis on channel catfish (Ictalurus punctatus) eggs

The efficacy of hydrogen peroxide to control mortality associated with saprolegniasis in channel catfish ( Ictalurus punctatus ) eggs was evaluated at the Lost Valley State Fish Hatchery (Warsaw, MO). Two efficacy trials were conducted. In Trial 1, channel catfish eggs in their natural gelatinous matrix were treated with hydrogen peroxide at 0, 500, and 750 mg l(-1). Channel catfish eggs in Trial 2 had the gelatinous matrix removed before treatment with hydrogen peroxide at 0 and 500 mg l(-1). Each treatment regimen was tested in triplicate and each egg jar contained similar to 17,400 eggs. Hydrogen peroxide was administered as a 15-min flow-through treatment applied once daily for a total of six applications. Control jars were similarly treated with culture water. Samples of exposure water were collected during each treatment and analyzed to verify actual treatment concentrations. Hydrogen peroxide treatment efficacy was assessed by comparing the percent egg hatch in the treatment group to the untreated control group in each trial. Mean percent hatch in Trial I was 44% (control), 54% (500 mg l(-1)), and 69% (750 mg l(-1)). Hydrogen peroxide treatment at either 500 or 750 mg l(-1) significantly (P<0.01) increased the percent hatch compared to the untreated control group. In Trial 2, hydrogen peroxide treatment at 500 mg l(-1) significantly (P<0.01) increased the percent egg hatch (67%) relative to the untreated controls (57%). Hydrogen peroxide treatment reduced egg mortality and increased the percent hatch of channel catfish eggs regardless of whether eggs were incubated in the gelatinous matrix or without the matrix in comparison to the untreated control.

Missouri↗

Modeling Carbon Dioxide, pH and Un-Ionized Ammonia Relationships in Serial Reuse Systems

In serial reuse systems, excretion of metabolic carbon dioxide has a significant impact on ambient pH, carbon dioxide, and un-ionized ammonia concentrations. This impact depends strongly on alkalinity, water flow rate, feeding rate, and loss of carbon dioxide to the atmosphere. A reduction in pH from metabolic carbon dioxide can significantly reduce the un-ionized ammonia concentration and increase the carbon dioxide concentrations compared to those parameters computed from influent pH. The ability to accurately predict pH in serial reuse systems is critical to their design and effective operation. A trial and error solution to the alkalinity–pH system was used to estimate important water quality parameters in serial reuse systems. Transfer of oxygen and carbon dioxide across the air–water interface, at overflow weirs, and impacts of substrate-attached algae and suspended bacteria were modeled. Gas transfer at the weirs was much greater than transfer across the air–water boundary. This simulation model can rapidly estimate influent and effluent concentrations of dissolved oxygen, carbon dioxide, and un-ionized ammonia as a function of water temperature, elevation, water flow, and weir type. The accuracy of the estimates strongly depends on assumed pollutional loading rates and gas transfer at the weirs. The current simulation model is based on mean daily loading rates; the impacts of daily variation loading rates are discussed. Copies of the source code and executable program are available free of charge.

Aquacultural Engineering↗

Predator avoidance performance of larval fathead minnows (Pimephales promelas) following short-term exposure to estrogen mixtures

Aquatic organisms exposed to endocrine disrupting compounds (EDCs) at early life-stages may have reduced reproductive fitness via disruption of reproductive and non-reproductive behavioral and physiological pathways. Survival to reproductive age relies upon optimal non-reproductive trait expression, such as adequate predator avoidance responses, which may be impacted through EDC exposure. During a predator–prey confrontation, larval fish use an innate C-start escape behavior to rapidly move away from an approaching threat. We tested the hypotheses that (1) larval fathead minnows exposed to estro gens, a primary class of EDCs, singularly or in mixture, suffer a reduced ability to perform an innate C-start behavior when faced with a threat stimulus; (2) additive effects will cause greater reductions in C-start behavior; and (3) effects will differ among developmental stages. In this study, embryos (post-fertilization until hatching) were exposed for 5 days to environmentally relevant concentrations of estrone (E1), 17-estradiol (E2), and 17-ethinylestradiol (EE2) singularly and in mixture. Exposed embryos were allowed to hatch and grow in control well water until 12 days old. Similarly, post-hatch fathead minnows were exposed for 12 days to these compounds. High-speed (1000 frames/s) video recordings of escape behavior were collected and transferred to National Institutes of Health Image for frame-by-frame anal- ysis of latency period, escape velocity, and total escape response (combination of latency period and escape velocity). When tested 12 days post-hatch, only E1 adversely affected C-start performance of larvae exposed as embryos. Conversely, larvae exposed for 12 days post-hatch did not exhibit altered escape responses when exposed to E1, while adverse responses were seen in E2 and the estrogen mixture. Ethinylestradiol exposure did not elicit changes in escape behaviors at either developmental stage. The direct impact of reduced C-start performance on survival, and ultimately, reproductive fitness provides an avenue to assess the ecological relevance of exposure in an assay of relatively short duration.

Aquatic Toxicology↗

Quantifying home range habitat requirements for bobcats (Lynx rufus) in Vermont, USA

We demonstrate how home range and habitat use analysis can inform landscape-scale conservation planning for the bobcat, Lynx rufus , in Vermont USA. From 2005 to 2008, we outfitted fourteen bobcats with GPS collars that collected spatially explicit locations from individuals every 4 h for 3&ndash;4 months. Kernel home range techniques were used to estimate home range size and boundaries, and to quantify the utilization distribution (UD), which is a spatially explicit, topographic mapping of how different areas within the home range are used. We then used GIS methods to quantify both biotic (e.g. habitat types, stream density) and abiotic (e.g. slope) resources within each bobcat&rsquo;s home range. Across bobcats, upper 20th UD percentiles (core areas) had 18% less agriculture, 42% less development, 26% more bobcat habitat (shrub, deciduous, coniferous forest, and wetland cover types), and 33% lower road density than lower UD percentiles (UD valleys). For each bobcat, we used Akaike&rsquo;s Information Criterion (AIC) to evaluate and compare 24 alternative Resource Utilization Functions (hypotheses) that could explain the topology of the individual&rsquo;s UD. A model-averaged population-level Resource Utilization Function suggested positive responses to shrub, deciduous, coniferous forest, and wetland cover types within 1 km of a location, and negative responses to roads and mixed forest cover types within 1 km of a location. Applying this model-averaged function to each pixel in the study area revealed habitat suitability for bobcats across the entire study area, with suitability scores ranging between &minus;1.69 and 1.44, where higher values were assumed to represent higher quality habitat. The southern Champlain Valley, which contained ample wetland and shrub habitat, was a concentrated area of highly suitable habitat, while areas at higher elevation areas were less suitable. Female bobcat home ranges, on average, had an average habitat suitability score of near 0, indicating that home ranges consisted of both beneficial and detrimental habitat types. We discuss the application of habitat suitability mapping and home range requirements for bobcat conservation and landscape scale management.

Vermont↗