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USGS2011

An assessment of stressor extent and biological condition in the North American mid-continent great rivers (USA)

We assessed the North American mid-continent great rivers (Upper Mississippi, Missouri, and Ohio). We estimated the extent of each river in most- (MDC) or least-disturbed condition (LDC) based on multiple biological response indicators: fish and macroinvertebrate, trophic state based on chlorophyll a, macrophyte cover, and exposure of fish-eating wildlife to toxic contaminants in fish tissue (Hg, total chlordane, total DDT, PCBs). We estimated the extent of stressors on each river including nutrients, suspended solids, sediment toxicity, invasive species, and land use (agriculture and impervious surface). All three rivers had a greater percent of their river length in MDC than in LDC based on fish assemblages. The Upper Mississippi River had the greatest percent of river length with eutrophic status. The Ohio River had the greatest percent of river length with fish with tissue contaminant levels toxic to wildlife. Overall, condition indices based on fish assemblages were more sensitive to stress than macroinvertebrate indices. Compared to the streams in its basin, more of the Upper Mississippi and Missouri Rivers were in MDC for nutrients than the Ohio River. Invasive species (Asian carp and Dreissenid mussels) were less widespread and less abundant on the Missouri River than on the other great rivers. The Ohio River had the most urbanized floodplains (greatest percent impervious surface). The Missouri River had the most floodplain agriculture. The effect of large urban areas on river condition was apparent for several indicators. Ecosystem condition based in fish assemblages, trophic state, and fish tissue contamination was related to land use on the floodplain and at the subcatchment scale. This is the first unbiased bioassessment of the mid-continent great rivers in the United States. The indicators, condition thresholds, results, and recommendations from this program are a starting point for improved future great river assessments.

River Systems↗

USGS2021

Forecasting ecological responses for wetland restoration planning in Florida's Everglades

The Everglades wetland was once a river of grass, with water flowing slowly through the sawgrass, southward across the landscape. As developers took hold of south Florida, water was sent away from the heart of the Everglades through canals and levees to protect the former wetland for residential and agricultural development. In the 1990s, planning began to restore the Everglades in what is the largest hydrologic restoration undertaking in the world. With billions of taxpayer dollars at stake, restoration planners benefit from forecasting tools to inform restoration planning. To meet this need, scientists developed predictive ecological models and other decision support tools tailored to this dynamic ecosystem as well as to the needs of restoration planning teams. Predictive modeling has been able to take advantage of well-understood relationships between species of interest and hydrologic dynamics in the Everglades. Recent modeling advances include multi-species approaches that consider interactions among species as well as explicit consideration of trade-offs among species from potential water management actions. Scientists are also starting to look at ecosystem-wide vulnerabilities with explicit consideration of future change such as sea level rise. Modeling tools and approaches continue to be refined to meet decision making needs for Everglades restoration. However, more work is needed to consider additional complexities of this dynamic wetland as well as to consider the broader socio-environmental system.

Florida↗

USGS2013

Adjustment of the San Francisco estuary and watershed to decreasing sediment supply in the 20th century

The general progression of human land use is an initial disturbance (e.g., deforestation, mining, agricultural expansion, overgrazing, and urbanization) that creates a sediment pulse to an estuary followed by dams that reduce sediment supply. We present a conceptual model of the effects of increasing followed by decreasing sediment supply that includes four sequential regimes, which propagate downstream: a stationary natural regime, transient increasing sediment supply, transient decreasing sediment supply, and a stationary altered regime. The model features characteristic lines that separate the four regimes. Previous studies of the San Francisco Estuary and watershed are synthesized in the context of this conceptual model. Hydraulic mining for gold in the watershed increased sediment supply to the estuary in the late 1800s. Adjustment to decreasing sediment supply began in the watershed and upper estuary around 1900 and in the lower estuary in the 1950s. Large freshwater flow in the late 1990s caused a step adjustment throughout the estuary and watershed. It is likely that the estuary and watershed are still capable of adjusting but further adjustment will be as steps that occur only during greater floods than previously experienced during the adjustment period. Humans are actively managing the system to try to prevent greater floods. If this hypothesis of step changes occurring for larger flows is true, then the return interval of step changes will increase or, if humans successfully control floods in perpetuity, there will be no more step changes.

California↗

USGS2025

Greater white-fronted goose habitat use in Louisiana provides water depth management insights

Numerous waterfowl species have altered their geographic distribution in recent decades. The greater white-fronted goose ( Anser albifrons ) has shifted its wintering distribution from coastal marshes in Texas and Louisiana, USA, to interior landscapes, creating challenges for conservation managers. Although the range shift has been primarily attributed to landscape-scale changes in rice production, effects of fine-scale habitat conditions on greater white-fronted goose habitat use are unknown. Thus, information on fine-scale environmental conditions could provide information to managers working to mitigate effects of the shift. We used global positioning system neck collars to monitor 78 greater white-fronted geese in Louisiana each winter during 2016–2019 and visited all used locations to record vegetation height, water depth, and land cover. We modeled greater white-fronted goose habitat use in 4 regions across Louisiana (central, coastal, north, southwest), and evaluated effects of vegetation height, water depth, land cover, and interactions. In our candidate model set, we included a sampling null, which accounted for differences in sampling frequencies among hunt seasons and diel periods. The top model in the central, coastal, and north regions included water depth, whereas the top model in the southwest region included water depth, vegetation height, and land cover. Parameter estimates and confidence intervals indicated that goose habitat use was higher at sites with >5.1 cm of water compared to dry sites or sites with <5.1 cm of water. In the southwest region, goose habitat use was highest in areas identified as other land cover (e.g., corn, cotton, rye, sugarcane) and lowest in open water. Although Louisiana has substantial anthropogenic food resources in the form of rice agriculture and abundant grazing opportunities afforded by mild winters, our results indicate that wet areas provide better habitat to greater white-fronted geese than dry areas. New agricultural flooding regimes in Louisiana could improve habitat quality and potentially mitigate some effects of the winter distribution shift.

Louisiana↗

USGS2010

Nitrous oxide emission from denitrification in stream and river networks

Nitrous oxide (N 2 O) is a potent greenhouse gas that contributes to climate change and stratospheric ozone destruction. Anthropogenic nitrogen (N) loading to river networks is a potentially important source of N 2 O via microbial denitrification that converts N to N 2 O and dinitrogen (N 2 ). The fraction of denitrified N that escapes as N 2 O rather than N 2 (i.e., the N 2 O yield) is an important determinant of how much N 2 O is produced by river networks, but little is known about the N 2 O yield in flowing waters. Here, we present the results of whole-stream 15 N-tracer additions conducted in 72 headwater streams draining multiple land-use types across the United States. We found that stream denitrification produces N 2 O at rates that increase with stream water nitrate (NO 3 − ) concentrations, but that <1% of denitrified N is converted to N 2 O. Unlike some previous studies, we found no relationship between the N 2 O yield and stream water NO 3 − . We suggest that increased stream NO 3 − loading stimulates denitrification and concomitant N 2 O production, but does not increase the N 2 O yield. In our study, most streams were sources of N 2 O to the atmosphere and the highest emission rates were observed in streams draining urban basins. Using a global river network model, we estimate that microbial N transformations (e.g., denitrification and nitrification) convert at least 0.68 Tg·y −1 of anthropogenic N inputs to N 2 O in river networks, equivalent to 10% of the global anthropogenic N 2 O emission rate. This estimate of stream and river N 2 O emissions is three times greater than estimated by the Intergovernmental Panel on Climate Change. Humans have more than doubled the availability of fixed nitrogen (N) in the biosphere, particularly through the production of N fertilizers and the cultivation of N-fixing crops ( 1 ). Increasing N availability is producing unintended environmental consequences including enhanced emissions of nitrous oxide (N 2 O), a potent greenhouse gas ( 2 ) and an important cause of stratospheric ozone destruction ( 3 ). The Intergovernmental Panel on Climate Change (IPCC) estimates that the microbial conversion of agriculturally derived N to N 2 O in soils and aquatic ecosystems is the largest source of anthropogenic N 2 O to the atmosphere ( 2 ). The production of N 2 O in agricultural soils has been the focus of intense investigation (i.e., >1,000 published studies) and is a relatively well constrained component of the N 2 O budget ( 4 ). However, emissions of anthropogenic N 2 O from streams, rivers, and estuaries have received much less attention and remain a major source of uncertainty in the global anthropogenic N 2 O budget. Microbial denitrification is a large source of N 2 O emissions in terrestrial and aquatic ecosystems. Most microbial denitrification is a form of anaerobic respiration in which nitrate (NO 3 − , the dominant form of inorganic N) is converted to dinitrogen (N 2 ) and N 2 O gases ( 5 ). The proportion of denitrified NO 3 − that is converted to N 2 O rather than N 2 (hereafter referred to as the N 2 O yield and expressed as the mole ratio) partially controls how much N 2 O is produced via denitrification ( 6 ), but few studies provide information on the N 2 O yield in streams and rivers because of the difficulty of measuring N 2 and N 2 O production in these systems. Here we report rates of N 2 and N 2 O production via denitrification measured using whole-stream 15 NO 3 − -tracer experiments in 72 headwater streams draining different land-use types across the United States. This project, known as the second Lotic Intersite Nitrogen eXperiment (LINX II), provides unique whole-system measurements of the N 2 O yield in streams. Although N 2 O emission rates have been reported for streams and rivers ( 7 , 8 ), the N 2 O yield has been studied mostly in lentic freshwater and marine ecosystems, where it generally ranges between 0.1 and 1.0%, although yields as high as 6% have been observed ( 9 ). These N 2 O yields are low compared with observations in soils (0–100%) ( 10 ), which may be a result of the relatively lower oxygen (O 2 ) availability in the sediments of lakes and estuaries. However, dissolved O 2 in headwater streams is commonly near atmospheric equilibrium and benthic algal biofilms can produce O 2 at the sediment–water interface, resulting in strong redox gradients more akin to those in partially wetted soils. Thus, streams may have variable and often high N 2 O yields, similar to those in soils ( 11 ). The N 2 O yield in headwater streams is of particular interest because much of the NO 3 − input to rivers is derived from groundwater upwelling into headwater streams. Furthermore, headwater streams compose the majority of stream length within a drainage network and have high ratios of bioreactive benthic surface area to water volume ( 12 ).

Proceedings of the National Academy of Sciences of↗

USGS2008

Simulation of Ground-Water Flow and Effects of Ground-Water Irrigation on Base Flow in the Elkhorn and Loup River Basins, Nebraska

Irrigated agriculture is vital to the livelihood of communities in the Elkhorn and Loup River Basins in Nebraska, and ground water is used to irrigate most of the cropland. Concerns about the sustainability of ground-water and surface-water resources have prompted State and regional agencies to evaluate the cumulative effects of ground-water irrigation in this area. To facilitate understanding of the effects of ground-water irrigation, a numerical computer model was developed to simulate ground-water flow and assess the effects of ground-water irrigation (including ground-water withdrawals, hereinafter referred to as pumpage, and enhanced recharge) on stream base flow. The study area covers approximately 30,800 square miles, and includes the Elkhorn River Basin upstream from Norfolk, Nebraska, and the Loup River Basin upstream from Columbus, Nebraska. The water-table aquifer consists of Quaternary-age sands and gravels and Tertiary-age silts, sands, and gravels. The simulation was constructed using one layer with 2-mile by 2-mile cell size. Simulations were constructed to represent the ground-water system before 1940 and from 1940 through 2005, and to simulate hypothetical conditions from 2006 through 2045 or 2055. The first simulation represents steady-state conditions of the system before anthropogenic effects, and then simulates the effects of early surface-water development activities and recharge of water leaking from canals during 1895 to 1940. The first simulation ends at 1940 because before that time, very little pumpage for irrigation occurred, but after that time it became increasingly commonplace. The pre-1940 simulation was calibrated against measured water levels and estimated long-term base flow, and the 1940 through 2005 simulation was calibrated against measured water-level changes and estimated long-term base flow. The calibrated 1940 through 2005 simulation was used as the basis for analyzing hypothetical scenarios to evaluate the effects of ground-water irrigation on stream base flow for 1940 through 2005 and for 2006 through 2045. Simulated base flows were compared for scenarios that alternately did or did not include a representation of the effects of ground-water irrigation. The difference between simulated base flows for the two scenarios represents the predicted effects of ground-water irrigation on base flow. Comparison of base flows between simulations with ground-water irrigation and no ground-water irrigation indicated that ground-water irrigation has cumulatively reduced streamflows from 1940 through 2005 by 888,000 acre-feet in the Elkhorn River Basin and by 2,273,000 acre-feet in the Loup River Basin. Generally, predicted cumulative effects of ground-water irrigation on base flow were 5 to 10 times larger from 2006 through 2045 than from 1940 through 2005, and were 7,678,000 acre-feet for the Elkhorn River Basin and 14,784,000 acre-feet for the Loup River Basin. The calibrated simulation also was used to estimate base-flow depletion as a percentage of pumping volumes for a 50-year future time period, because base-flow depletion percentages are used to guide the placement of management boundaries in Nebraska. Mapped results of the base-flow depletion analysis conducted for most of the interior of the study area indicated that pumpage of one additional theoretical well simulated for a future 50-year period generally would result in more than 80 percent depletion when it was located close to the stream, except in areas where depletion was partly offset by reduced ground-water discharge to evapotranspiration in wetland areas. In many areas, depletion for the 50-year future period composed greater than 10 percent of the pumped water volume for theoretical wells placed less than 7 or 8 miles from the stream, though considerable variations existed because of the heterogeneity of the natural system represented in the simulation. For a few streams, predicted future simulated base flows dec

Scientific Investigations Report↗

USGS2019

Simulating land cover change impacts on groundwater recharge under selected climate projections, Maui, Hawaiʻi

This project developed an integrated land cover/hydrological modeling framework using remote sensing and geographic information systems (GIS) data, stakeholder input, climate information and projections, and empirical data to estimate future groundwater recharge on the Island of Maui, Hawaiʻi, USA. End-of-century mean annual groundwater recharge was estimated under four future land cover scenarios: Future 1 (conservation-focused), Future 2 (status-quo), Future 3 (development-focused), and Future 4 (balanced conservation and development), and two downscaled climate projections: a coupled model intercomparison project (CMIP) phase 5 (CMIP5) representative concentration pathway (RCP) 8.5 “dry climate” future and a CMIP3 A1B “wet climate” future. Results were compared to recharge estimated using the 2017 baseline land cover to understand how changing land management and climate could influence groundwater recharge. Estimated recharge increased island-wide under all future land cover and climate combinations and was dominated by specific land cover transitions. For the dry future climate, recharge for land cover Futures 1 to 4 increased by 12%, 0.7%, 0.01%, and 11% relative to 2017 land cover conditions, respectively. Corresponding increases under the wet future climate were 10%, 0.9%, 0.6%, and 9.3%. Conversion from fallow/grassland to diversified agriculture increased irrigation, and therefore recharge. Above the cloud zone (610 m), conversion from grassland to native or alien forest led to increased fog interception, which increased recharge. The greatest changes to recharge occurred in Futures 1 and 4 in areas where irrigation increased, and where forest expanded within the cloud zone. Furthermore, new future urban expansion is currently slated for coastal areas that are already water-stressed and had low recharge projections. This study demonstrated that a spatially-explicit scenario planning process and modeling framework can communicate the possible consequences and tradeoffs of land cover change under a changing climate, and the outputs from this study serve as relevant tools for landscape-level management and interventions.

Hawaii↗

USGS2001

Hydrogeology, model description, and flow analysis of the Mississippi River alluvial aquifer in northwestern Mississippi

The Mississippi River alluvial aquifer underlies a 7,000-square-mile area of the Mississippi River alluvial plain in northwestern Mississippi, an area locally known as the Delta. The alluvial aquifer is the most heavily pumped aquifer in Mississippi, and wells yielding more than 2,000 gallons per minute are common. About 98 percent of the pumpage from the alluvial aquifer is for agriculture. The sand and gravel that form the alluvial aquifer averages about 110 feet in thickness. The aquifer is confined over most of the Delta, and the upper confining unit averages about 25 feet in thickness. The average depth to water in the alluvial aquifer during fall 1999 was about 25 feet. The alluvial aquifer receives lateral recharge at the western boundary from the Mississippi River and at the eastern boundary from aquifers that directly underlie the Bluff Hills. The alluvial aquifer receives water vertically from precipitation, internal streams and lakes, and locally from the Cockfield and Sparta aquifers where they directly underlie the alluvial aquifer. The alluvial aquifer also discharges water to the underlying aquifers, and during extended periods with no surface runoff, to the Mississippi River and to the internal streams and lakes. The magnitude of recharge from the Mississippi River, precipitation, and internal lakes and streams can vary greatly depending upon hydrologic and climatic conditions. The U.S. Geological Survey modular threedimensional finite-difference ground-water flow model, MODFLOW, was used to simulate the Mississippi River alluvial aquifer flow system in northwestern Mississippi. The model uses one layer with a rectangular-grid and 1-mile square cells to represent the alluvial aquifer. The model was calibrated and verified by using spring and fall water-level measurements from January 1988 through December 1996. The values of selected model calibration-derived parameters for the alluvial aquifer are hydraulic conductivity, 425 feet per day; specific yield, 0.32; and storage coefficient, 0.016. The model showed that the aquifer lost water from storage at an average rate of 404 cubic feet per second during the 9-year simulation period. During this period, the average pumpage rate was 1,270 million gallons per day (1,980 cubic feet per second). Simulated areal recharge from precipitation averaged 2.6 inches per year (1,360 cubic feet per second). Vertical recharge from the internal streams and lakes and lateral recharge from aquifers underlying the Bluff Hills averaged 113 and 108 cubic feet per second, respectively. Model results indicated that net recharge from the Mississippi River and from aquifers directly underlying the alluvial aquifer was small.

Mississippi↗

USGS2016

Effects of aquifer storage and recovery activities on water quality in the Little Arkansas River and Equus Beds Aquifer, south-central Kansas, 2011–14

The Equus Beds aquifer in south-central Kansas is aprimary water source for the city of Wichita. The Equus Beds aquifer storage and recovery (ASR) project was developed to help the city of Wichita meet increasing current (2016) and future water demands. The Equus Beds ASR project pumps water out of the Little Arkansas River during above-base flow conditions, treats it using drinking-water quality standards as a guideline, and recharges it into the Equus Beds aquifer for later use. Phase II of the Equus Beds ASR project currently (2016) includes a river intake facility and a surface-water treatment facility with a 30 million gallon per day capacity. Water diverted from the Little Arkansas River is delivered to an adjacent presedimentation basin for solids removal. Subsequently, waste from the surface-water treatment facility and the presedimentation basin is returned to the Little Arkansas River through a residuals return line. The U.S. Geological Survey, in cooperation with the city of Wichita, developed and implemented a hydrobiological monitoring program as part of the ASR project to characterize and quantify the effects of aquifer storage and recovery activities on the Little Arkansas River and Equus Beds aquifer water quality. Data were collected from 2 surface-water sites (one upstream and one downstream from the residuals return line), 1 residuals return line site, and 2 groundwater well sites (each having a shallow and deep part): the Little Arkansas River upstream from the ASR facility near Sedgwick, Kansas (upstream surface-water site 375350097262800), about 0.03 mile (mi) upstream from the residuals return line site; the Little Arkansas River near Sedgwick, Kans. (downstream surface-water site 07144100), about 1.68 mi downstream from the residuals return line site; discharge from the Little Arkansas River ASR facility near Sedgwick, Kansas (residuals return line site 375348097262800); 25S 01 W 07BCCC01 SMW–S11 near CW36 (MW–7 shallow groundwater well site 375327097285401); 25S01 W 07BCCC02 DMW–S10 near CW36 (MW–7 deep groundwater well site 375327097285402); 25S 01W 07BCCA01 SMW–S13 near CW36 (MW–8 shallow groundwater well site 375332097284801); and 25S 01W 07BCCA02 DMW–S14 near CW36 (MW–8 deep groundwater well site 375332097284802). The U.S. Geological Survey, in cooperation with the city of Wichita, assessed the effects of the ASR Phase II facility residuals return line discharges on stream quality of the Little Arkansas River by measuring continuous physicochemical properties and collecting discrete water-quality and sediment samples for about 2 years pre- (January 2011 through April 2013) and post-ASR (May 2013 through December 2014) Phase II facility operation upstream and downstream from the ASR Phase II facility. Additionally, habitat variables were quantified and macroinvertebrate and fish communities were sampled upstream and downstream from the ASR Phase II facility during the study period. To assess the effects of aquifer recharge on Equus Beds groundwater quality, continuous physicochemical properties were measured and discrete water-quality samples were collected before and during the onset of Phase II aquifer recharge in two (shallow and deep) groundwater wells. Little Arkansas River streamflow was about 10 times larger after the facility began operating because of greater rainfall. Residuals return line release volumes were a very minimal proportion (0.06 percent) of downstream streamflow volume during the months the ASR facility was operating. Upstream and downstream continuously measured water temperature and dissolved oxygen median differences were smaller post-ASR than pre-ASR. Turbidity generally was smaller at the downstream site throughout the study period and decreased at both sites after the ASR Phase II facility began discharging despite a median residuals return line turbidity that was about an order of magnitude larger than the median turbidity at the downstream site. Upstream and downstream continuously measured turbidity median differences were larger post-ASR than pre-ASR. Median post-ASR continuously measured nitrite plus nitrate and continuously computed total suspended solids and suspended-sediment concentrations were smaller than pre-ASR likely because of higher streamflows and dilution; whereas, median continuously computed dissolved and total organic carbon concentrations were larger likely because of higher streamflows and runoff conditions. None of the discretely measured water-quality constituents (dissolved and suspended solids, primary ions, suspended sediment, nutrients, carbon, trace elements, viral and bacterial indicators, and pesticides) in surface water were significantly different between the upstream and downstream sites after the ASR Phase II facility began discharging; however, pre-ASR calcium, sodium, hardness, manganese, and arsenate concentrations were significantly larger at the upstream site, which indicates that some water-quality conditions at the upstream and downstream sites were more similar post-ASR. Most of the primary constituents that make up dissolved solids decreased at both sites after the ASR Phase II facility began operation. Discretely collected total suspended solids concentrations were similar between the upstream and downstream sites before the facility began operating but were about 27 percent smaller at the downstream site after the facility began operating, despite the total suspended solids concentrations in the residuals return line being 15 times larger than the downstream site. Overall habitat scores were indicative of suboptimal conditions upstream and downstream from the ASR Phase II facility throughout the study period. Substrate fouling and sediment deposition mean scores indicated marginal conditions at the upstream and downstream sites during the study period, demonstrating that sediment deposition was evident pre- and post-ASR and no substantial changes in these habitat characteristics were noted after the ASR Phase II facility began discharging. Macroinvertebrate community composition (evaluated using functional feeding, behavioral, and tolerance metrics) generally was similar between sites during the study period. Fewer macroinvertebrate metrics were significant between the upstream and downstream sites post-ASR (6) than pre-ASR (14), which suggests that macroinvertebate communities were more similar after the ASR facility began discharging. Upstream-downstream comparisons in macroinvertebrate aquatic-life-support metrics had no significant differences for the post-ASR time period and neither site was fully supporting for any of the Kansas Department of Health and Environment aquatic-life-support metrics (Macroinvertebrate Biotic Index; Kansas Biotic Index with tolerances for nutrients and oxygen-demanding substances; Ephemeroptera, Plecoptera, and Trichoptera [EPT] richness; and percentage of EPT species). Overall, using macroinvertebrate aquatic life-support criteria from the Kansas Department of Health and Environment, upstream and downstream sites were classified as partially supporting before and after the onset of ASR facility operations. Fish community trophic status and tolerance groups generally were similar among sites during the study period. Fish community Little Arkansas River Basin Index of Biotic Integrity scores at the upstream and downstream sites were indicative of fair-to-good conditions before the facility began operating and decreased to fair conditions after the facility began operating. Groundwater physicochemical changes concurrent with the beginning of recharge operations at the Sedgwick basin were more pronounced in shallow groundwater. No constituent concentrations in the pre-recharge period in comparison to the post-recharge period increased to concentrations exceeding drinking water regulations; however, nitrate decreased significantly from a pre-recharge exceedance of the U.S. Environmental Protection Agency maximum contaminant level to a post recharge nonexceedance. Shallow groundwater chemical concentrations or rates of detection increased after artificial recharge began for the ions potassium, chloride, and fluoride; phosphorus and organic carbon species; trace elements barium, manganese, nickel, arsenate, arsenic, and boron; agricultural pesticides atrazine, metolachlor, metribuzin, and simazine; organic disinfection byproducts bromodichloromethane and trichloromethane; and gross beta levels. Additionally, water temperature, and pH were larger after recharge began; and total solids and slime-forming bacteria concentrations and densities were smaller. Total solids, nitrate, and selenium significantly decreased; and potassium, chloride, nickel, arsenic, fluoride, phosphorus and carbon species, and gross beta levels significantly increased in shallow groundwater after artificial recharge. Results of biological activity reaction tests indicated that water quality microbiology was different before and after artificial recharge began; at times, these differences may lead to changes in dominant bacterial populations that, in turn, may lead to formation and expansion in populations that may cause bioplugging and other unwanted effects. Calcite, iron (II) hydroxide, hydroxyapatite, and similar minerals, had shifts in saturation indices that generally were from undersaturation toward equilibrium and, in some cases, toward oversaturation. These shifts toward neutral saturation indices might suggest reduced weathering of the minerals present in the Equus Beds aquifer. Chemical weathering in the shallow parts of the aquifer may be accelerated because of the increased water temperatures and the system is more vulnerable to clogged pores and mineral dissolution as the equilibrium state is affected by recharge and withdrawal. When oversaturation is indicated for iron minerals, plugging of aquifer materials may happen.

Kansas↗

USGS2006

User guide for the farm process (FMP1) for the U.S. Geological Survey's modular three-dimensional finite-difference ground-water flow model, MODFLOW-2000

There is a need to estimate dynamically integrated supply-and-demand components of irrigated agriculture as part of the simulation of surface-water and ground-water flow. To meet this need, a computer program called the Farm Process (FMP1) was developed for the U.S. Geological Survey three-dimensional finite-difference modular ground-water flow model, MODFLOW- 2000 (MF2K). The FMP1 allows MF2K users to simulate conjunctive use of surface- and ground water for irrigated agriculture for historical and future simulations, water-rights issues and operational decisions, nondrought and drought scenarios. By dynamically integrating farm delivery requirement, surface- and ground-water delivery, as well as irrigation-return flow, the FMP1 allows for the estimation of supplemental well pumpage. While farm delivery requirement and irrigation return flow are simulated by the FMP1, the surface-water delivery to the farm can be simulated optionally by coupling the FMP1 with the Streamflow Routing Package (SFR1) and the farm well pumping can be simulated optionally by coupling the FMP1 to the Multi-Node Well (MNW) Package. In addition, semi-routed deliveries can be specified that are associated with points of diversion in the SFR1 stream network. Nonrouted surface-water deliveries can be specified independently of any stream network. The FMP1 maintains a dual mass balance of a farm budget and as part of the ground-water budget. Irrigation demand, supply, and return flow are in part subject to head-dependent sources and sinks such as evapotranspiration from ground water and leakage between the conveyance system and the aquifer. Farm well discharge and farm net recharge are source/sink terms in the FMP1, which depend on transpiration uptake from ground water and other head dependent consumptive use components. For heads rising above the bottom of the root zone, the actual transpiration is taken to vary proportionally with the depth of the active root zone, which can be restricted by anoxia or wilting. Depths corresponding to anoxia- or wilting-related pressure heads within the root zone are found using analytical solutions of a vertical pseudo steady-state pressure- head distribution over the depth of the total root zone (Consumptive Use Concept 1). Alternatively, a simpler, conceptual model is available, which defines how consumptive use (CU) components vary with changing head (CU Concept 2). Subtracting the ground water and precipitation transpiration components from the total transpiration yields a transpiratory irrigation requirement for each cell. The total farm delivery requirement (TFDR) then is determined as cumulative transpiratory and evaporative irrigation requirements of all farm cells and increased sufficiently to compensate for inefficient use from irrigation with respect to plant consumption. The TFDR subsequently is satisfied with surface- and ground-water delivery, respectively constrained by allotments, water rights, or maximum capacities. Five economic and noneconomic drought response policies can be applied optionally, if the potential supply of surface water and ground water is insufficient to meet the crop demand: acreage-optimization with or without a water conservation pool, deficit irrigation with or without water-stacking, and zero policy.

Techniques and Methods↗

USGS2000

Metals transport in the Sacramento River, California, 1996-1997; volume 1: Methods and data

Metals transport in the Sacramento River, northern California, was evaluated on the basis of samples of water, suspended colloids, streambed sediment, and caddisfly larvae that were collected on one to six occasions at 19 sites in the Sacramento River Basin from July 1996 to June 1997. Four of the sampling periods (July, September, and November 1996; and May-June 1997) took place during relatively low-flow conditions and two sampling periods (December 1996 and January 1997) took place during high-flow and flooding conditions; respectively. Tangential-flow ultrafiltration with 10,000 nominal molecular weight limit, or daltons (0.005 micrometer equivalent), pore-size membranes was used to separate metals in streamwater into ultrafiltrate (operationally defined dissolved fraction) and retentate (colloidal fraction) components, respectively. Conventional filtration with capsule filters (0.45 micrometer pore-size) and membrane filters (0.40 micrometer pore-size) and total-recoverable analysis of unfiltered (whole-body) samples were done for comparison at all sites. Because the total-recoverable analysis involves an incomplete digestion of particulate matter, a more reliable measurement of whole-water concentrations is derived from the sum of the dissolved component that is based on the ultrafiltrate plus the suspended component that is based on a total digestion of colloid concentrates from the ultra-filtration retentate. Metals in caddisfly larvae were determined for whole-body samples and cytosol extracts, which are intercellular solutions that provide a more sensitive indication of the metals that have been bioaccumulated. Trace metals in acidic, metal-rich drainage from abandoned and inactive sulfide mines were observed to enter the Sacramento River system (specifically, into both Shasta Lake and Keswick Reservoir) in predominantly dissolved form, as operationally defined using ultrafiltrates. The predominant source of acid mine drainage to Keswick Reservoir is Spring Creek, which drains the Iron Mountain mine area. Copper concentrations in filtered samples from Spring Creek taken during December 1996, January 1997, and May 1997 ranged from 420 to 560 micrograms per liter. Below Keswick Dam, copper concentrations in conventionally filtered samples ranged from 0.5 micrograms per liter during September 1996 to 9.4 micrograms per liter during January 1997; the latter concentration exceeded the applicable water-quality standard. The proportion of trace metals that was dissolved (versus colloidal) in samples collected at Shasta and Keswick dams decreased in the order cadmium zinc > copper > aluminum iron lead mercury. At four sampling sites on the Sacramento River at various distances downstream of Keswick Dam (Bend Bridge, 71 kilometers; Colusa, 256 kilometers; Verona, 360 kilometers; and Freeport, 412 kilometers) concentrations of these seven metals were predominantly colloidal during both high- and low-flow conditions. Because copper compounds are used extensively as algaecides in rice farming, agricultural drainage at the Colusa Basin Drain was sampled in June 1997 during a period shortly after copper applications to newly planted rice fields. Copper concentrations ranged from 1.3 to 3.0 micrograms per liter in filtered samples and from 12 to 13 micrograms per liter in whole-water samples (total recoverable analysis). These results are consistent with earlier work by the U.S. Geological Survey indicating that copper in rice-field drainage likely represents a detectable, but relatively minor source of copper to the Sacramento River. Lead isotope data from suspended colloids and streambed sediments collected during October and November 1996 indicate that lead from acid mine drainage sources became a relatively minor component of the total lead at the site located 71 kilometers downstream of Keswick Dam and beyond. Cadmium, copper, and zinc concentrations in caddisfly larvae were elevated at several sites downstream of Keswick Dam, but concentrations of aluminum, iron, lead, and mercury were relatively low, especially in the cytosol extracts. Cadmium showed the highest degree of bioaccumulation in whole-body and cytosol analyses, relative to an unmineralized control site (Cottonwood Creek). Cadmium bioaccumulation persisted in samples collected as far as 118 kilometers downstream of Keswick Dam, consistent with transport in a form more bioavailable than lead.

California↗

USGS2024

The EnMAP spaceborne imaging spectroscopy mission: Initial scientific results two years after launch

Imaging spectroscopy has been a recognized and established remote sensing technology since the 1980s, mainly using airborne and field-based platforms to identify and quantify key bio- and geo-chemical surface and atmospheric compounds, based on characteristic spectral reflectance features in the visible-near infrared (VNIR) and short-wave infrared (SWIR). Spaceborne missions, a leap in technology, were sparse, starting with the CHRIS/PROBA and EO1/Hyperion missions in the early 2000s, and providing spectroscopy data with limited spectral coverage and/or low data quality in the SWIR. Since 2019, several countries and agencies have successfully launched a number of spaceborne imaging spectroscopy systems into orbit or deployed them on the International Space Station (ISS) such as DESIS, PRISMA, HISUI, GF-5, EnMAP and EMIT. Among these recent missions, the German Environmental Mapping and Analysis Program (EnMAP) stands for its long-term development, sophisticated design with on-board calibration, high data quality requirements, and extensive accompanying science program. EnMAP was launched in April 2022 and, following a successful commissioning phase, started its operational activities in November 2022. The EnMAP mission encompasses global coverage from 80° N to 80° S through on-demand data acquisitions. Data are free and open access with 30 m spatial resolution, a high spectral resolution with a spectral sampling distance of 6.5 nm and 10 nm in the VNIR and SWIR regions respectively, and a high signal-to-noise ratio. In this paper, we aim to present the mission's current status, coverage, science capabilities and performance two years after launch. We show the potential of EnMAP for space-based imaging spectroscopy to operate in various environments, including high and low light levels, dense forests, Antarctic glaciers, and arid agricultural areas. EnMAP enables various applications in fields such as agriculture and forestry, soil compositional, raw materials, and methane mapping, as well as water quality assessment, and snow and ice properties. The results show that EnMAP's performance exceeds the mission requirements, and highlights the significant potential for contribution to scientific exploitation in various geo- and biochemical sciences. EnMAP is also expected to serve as a key tool for the development and testing of data processing algorithms for upcoming global operational missions.

Remote Sensing of Environment↗

USGS1994

Ground-water quality and geochemistry in Carson and Eagle Valleys, western Nevada and eastern California

Aquifers in Carson and Eagle Valleys are an important source of water for human consumption and agriculture. Concentrations of major constituents in water from the principal aquifers on the west sides of Carson and Eagle Valleys appear to be a result of natural geochemical reactions with minerals derived primarily from plutonic rocks. In general, water from principal aquifers is acceptable for drinking when compared with current (1993) Nevada State drinking-water maximum contaminant level standards. Water was collected and analyzed for all inorganic constituents for which primary or secondary drinking-water standards have been established. About 3 percent of these sites had con- stituents that exceeded one or more primary or secondary drinking-water standards have been established. About 3 percent of these sites had con- stituents that exceeded one or more primary standards and water at about 10 percent of the sites had at least one constituent that surpassed a secondary standard. Arsenic exceeded the standard in water at less than 1 percent of the principal aquifer sites; nitrate surpassed its standard in water at 3 percent of 93 sites. Water from wells in the principal aquifer with high concentrations of nitrate was in areas where septic systems are used; these concentrations indicate that contamination may be entering the wells. Concentrations of naturally occurring radionuclides in water from the principal aquifers, exceed the proposed Federal standards for some constituents, but were not found t be above current (1993) State standards. The uranium concen- trations exceeded the proposed 20 micrograms per liter Federal standard at 10 percent of the sites. Of the sites analyzed for all of the inorganic constituents with primary standards plus uranium, 15 percent exceed one or more established standards. If the proposed 20 micrograms per liter standard for uranium is applied to the sampled sites, then 23 percent would exceed the standard for uranium or some other constituent with a primary drinking water standard. This represents a 50-percent increase in the frequency of exceedance. Almost all water sampled from the principal aquifers exceeds the 300 picocuries per liter proposed standard for radon. Ground-water sampling sites with the highest radon activities in water are most commonly located in the upland aquifers in the Sierra Nevada and in the principal aquifers beneath the west sides of Carson and Eagle Valleys.

Open-File Report↗

USGS2004

Metabolism of niclosamide in sediment and water systems

A series of experiments analyzed the kinetics and mechanisms of [ 14C]niclosamide degradation. The aerobic aquatic metabolism of [ 14C]niclosamide was studied in nonsterile river water/sediment mixtures. Test systems, maintained under aerobic conditions, were treated with niclosamide and incubated in the dark at 25.0 ?? 1.0 ??C for 30 days. Half-lives of 4.9 and 5.4 days were calculated for the chlorosalicylic acid- and chloronitroaniline-labeled test systems, respectively. From 0 to 21 days after treatment (DAT), the only metabolism product observed in either test system was aminoniclosamide. At the final sampling interval, five peaks were resolved from the chlorosalicylic acid label, and three peaks were resolved from the chloronitroaniline label test substance. By 30 DAT, sediment-bound residues represented ???70% of the observed radioactivity. For the anaerobic aquatic metabolism of [14C]niclosamide, test systems were incubated under anaerobic conditions for 365 days. Half-lives of 0.65 day for the chlorosalicylic acid label and 2.79 days for the chloronitroaniline label were calculated. From 0 to 3 DAT, niclosamide was first transformed into aminoniclosamide. Aminoniclosamide is readily formed, as it was observed in the chlorosalicylic acid label 0 DAT sampling. Several minor metabolites were observed in the water and sediment extracts. None of these metabolites were formed to a significant amount until the parent niclosamide dissipated below the detection limit. Two of the byproducts from these metabolism studies are polar unknowns eluting at 3 and 5 min by HPLC, similar to the unknowns observed in aqueous photolysis studies.

Journal of Agricultural and Food Chemistry↗

USGS1996

Erosional and depositional patterns associated with the 1993 Missouri River floods inferred from SIR-C and TOPSAR radar data

The Missouri River floods of 1993 caused significant and widespread damage to the floodplains between Kansas City and St. Louis. Immediately downstream of levee breaks, flood waters scoured the bottoms. As the floodwaters continued, they spread laterally and deposited massive amounts of sand as crevasse splays on top of agricultural fields. We explore the use of radar interferometry and backscatter data for quantitative estimation of scour and deposition for Jameson Island/Arrow Rock Bottoms and Lisbon Bottoms, two bottoms that were heavily damaged during the floods and subsequently abandoned. Shuttle imaging radar C (SIR-C) L band (24 cm) HH (horizontally transmitted and horizontally received) radar backscatter data acquired in October 1994 were used together with a distorted Born approximation canopy scattering model to determine that the abundance of natural leafy forbs controlled the magnitude of backscatter for former agricultural fields. Forb areal density was found to be inversely correlated with thickness of sand deposited during the floods, presumably because thick sands prevented roots from reaching nutrient rich, moist bottoms soils. Using the inverse relationship, a lower bound for the mass of sand added was found to be 6.3 million metric tons over the 17 km 2 study area. Digital elevation data from topographic synthetic aperture radar (TOPSAR) C band (5.6 cm) interferometric observations acquired in August 1994 were compared to a series of elevation profiles collected on the ground. Vertical errors in TOPSAR were estimated to range from 1 to 2 m, providing enough accuracy to generate an estimate of total mass (4.7 million metric tons) removed during erosion of levees and scour of the bottoms terrains. Net accretion of material to the study areas is consistent with the geologic record of major floods where sediment-laden floodwaters crested over natural levees, initially scoured into the bottoms, and then deposited sands as crevasse splays as the flows spread out and slowed by frictional dissipation. The addition of artificial levees to the Missouri River system has undoubtedly enhanced flood damage, although quantitative estimation of the degree of enhancement will require additional work.

Journal of Geophysical Research E: Planets↗

USGS2006

Occurrence of anthropogenic organic compounds in ground water and finished water of community water systems in Eagle and Spanish Springs Valleys, Nevada, 2002-2004

As a part of the U.S. Geological Survey's National Water-Quality Assessment Program, an effort to characterize the quality of major rivers and aquifers used as a source of supply to some of the largest community water systems (CWSs) in the United States has been initiated. These studies, termed Source Water-Quality Assessments (SWQAs), consist of two sampling phases. Phase 1 was designed to determine the frequency of detection and concentrations of about 260 volatile organic compounds (VOCs), pesticides and pesticide degradates, and other anthropogenic organic compounds in source water of 15 CWS wells in each study. Phase 2 monitors concentrations in the source water and also the associated finished water of CWSs for compounds most frequently detected during phase 1. One SWQA was completed in the Nevada Basin and Range area in Nevada. Ten CWS wells in Eagle Valley and five CWS wells in Spanish Springs Valley were sampled. For phase 2, two wells were resampled in Eagle Valley. Samples were collected during 2002-2004 for both phases. Water use in Eagle Valley is primarily for domestic purposes and is supplied through CWSs. Ground-water sources provide about 55 percent of the public-water supply, and surface-water sources supply about 45 percent. Lesser amounts of water are provided by domestic wells. Very little water is used for agriculture or manufacturing. Spanish Springs Valley has water-use characteristics similar to those in Eagle Valley, although there is more agricultural water use in Spanish Springs Valley than in Eagle Valley. Maximum contaminant concentrations were compared to two human-health benchmarks, if available, to describe the water-quality data in a human-health context for these findings. Measured concentrations of regulated contaminants were compared to U.S. Environmental Protection Agency and Nevada Maximum Contaminant Level (MCL) values. Measured concentrations of unregulated contaminants were compared to Health-Based Screening Levels, which are not regulatory standards and are not legally enforceable values. All of the contaminants detected in this study were found at concentrations less than available human-health benchmarks. In the source waters sampled in phase 1, 10 contaminants of the approximately 260 measured were detected in samples collected from Eagle Valley, and 4 contaminants were detected in samples from Spanish Springs Valley. The most frequently detected compounds in the Eagle Valley source water were chloroform (a disinfection by-product), which was detected in samples from four wells, and deethylatrazine (a degradation product of the herbicide atrazine), which was detected in samples from three wells. Each of the four contaminants detected in the Spanish Springs Valley source waters was detected in samples from one well. The detection frequencies of VOCs and pesticides in samples from the SWQA wells were similar to those in samples from both shallow and deep monitoring wells in Carson City, Reno, and Spanish Springs. This indicates that the SWQA sampling is representative of the organic chemical compounds likely to be detected in the aquifers sampled. However, more organic compounds were detected at low frequencies and concentrations in samples from the monitoring wells than in samples from SWQA wells. Three contaminants were detected in one finished-water sample collected from Eagle Valley. Comparison of SWQA results in the Nevada Basin and Range Study Unit to results of an SWQA in the larger urban area of Salt Lake City showed that fewer anthropogenic compounds were detected in Eagle and Spanish Springs Valleys and generally at lower concentrations than in the Salt Lake City study.

Scientific Investigations Report↗

USGS2021

Land use change influences ecosystem function in headwater streams of the Lowland Amazon Basin

Intensive agriculture alters headwater streams, but our understanding of its effects is limited in tropical regions where rates of agricultural expansion and intensification are currently greatest. Riparian forest protections are an important conservation tool, but whether they provide adequate protection of stream function in these areas of rapid tropical agricultural development has not been well studied. To address these gaps, we conducted a study in the lowland Brazilian Amazon, an area undergoing rapid cropland expansion, to assess the effects of land use change on organic matter dynamics (OM), ecosystem metabolism, and nutrient concentrations and uptake (nitrate and phosphate) in 11 first order streams draining forested ( n = 4) or cropland ( n = 7) watersheds with intact riparian forests. We found that streams had similar terrestrial litter inputs, but OM biomass was lower in cropland streams. Gross primary productivity was low and not different between land uses, but ecosystem respiration and net ecosystem production showed greater seasonality in cropland streams. Although we found no difference in stream concentrations of dissolved nutrients, phosphate uptake exceeded nitrate uptake in all streams and was higher in cropland than forested streams. This indicates that streams will be more retentive of phosphorus than nitrogen and that if fertilizer nitrogen reaches streams, it will be exported in stream networks. Overall, we found relatively subtle differences in stream function, indicating that riparian buffers have thus far provided protection against major functional shifts seen in other systems. However, the changes we did observe were linked to watershed scale shifts in hydrology, water temperature, and light availability resulting from watershed deforestation. This has implications for the conservation of tens of thousands of stream kilometers across the expanding Amazon cropland region.

Tanguro Ranch↗

USGS1996

Seepage measurements from Long Lake, Indiana Dunes National Lakeshore

Long Lake, located near Lake Michigan within the dune-complexes of Indiana Dunes National Lakeshore, USA, was formed some time during the Pleistocene and Holocene epochs. A surficial aquifer underlies Long Lake, which is either a source or sink for the later. The hydrologic processes in the lakeshore and surrounding environs have been significantly altered during the agricultural, municipal, and industrial development of the region. Limited data suggest that the organisms of Long Lake have elevated levels of several contaminants. This study attempts to quantify seepage within the lake to assess the potential threat to groundwater quality. Seepage measurements and minipiezometric tests were used to determine seepage within the lake. Seepage measurements and minipiezometric tests suggest that water seeps out of Long Lake, thus recharging the groundwater that flows southwest away from the lake. There is a great deal of variability in the seepage rate, with a mean of 11.5×10 -4 ±11.2×10 -4 m d -1 . The mean seepage rate of 0.3 m yr -1 for Long Lake is greater than the 0.2 m yr -1 recharge rate estimated for the drainage basin area. The Long Lake recharge volume of 2.5 × 10 5 m 3 yr -1 is approximately 22% of the volume of the lake and is significant when compared to the total surface recharge volume of 4.8 × 10 5 m 3 yr -1 to the upper aquifer of the drainage area. There is a potential for contamination of the groundwater system through seepage from the lake from contaminants derived from aerial depositions.

Indiana↗