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An orbital comparison of a late mantling unit on Aeolis Mons with other erosion-resistant strata explored by MSL in Gale crater, Mars

Previous investigations along Curiosity 's traverse in Gale crater have explored the relationship between orbital and in situ observations. This work aims to better understand the geologic environment of units only observable from orbit and compare them to the properties of units examined by Curiosity . Here, we map an erosion-resistant dark-toned mantling unit that overlies the modern topography of Aeolis Mons (informally known as Mt. Sharp) and compare this unit to two other previously mapped dark-toned resistant units, the marker band and the mound skirting unit (MSU), that have been inferred to represent different geologic environments (lacustrine and aeolian, respectively). Visible to short wave infrared spectra from the Compact Reconnaissance Imaging Spectrometer for Mars and visual images from the High Resolution Imaging Science Experiment and Context Cameras aboard the Mars Reconnaissance Orbiter are used for this comparison. Spectral data suggest a mafic composition with minor alteration, although the composition varies more with location around Mt. Sharp rather than between units. Morphologically, the mantling unit has strong similarities to the marker band based on their consistent low-albedo, erosion-resistance, and smooth appearance, contrasting with the highly variable surface texture of the MSU. We hypothesize that all three units had a similar sediment source but experienced aqueous alteration at different times: early ubiquitous cementation in a surface aqueous environment in the mantling unit and marker band versus patchy late diagenesis in the MSU. If true, these results suggest that water activity continued within the Gale crater long after the erosion of Mt. Sharp.

JGR Planets

40Ar/39Ar geochronology supporting mineral resources research at USGS Denver

The 40 Ar/ 39 Ar geochronology method is used to date potassium-bearing rocks and minerals, based on the decay of 40 K to 40 Ar, which provides important temporal constraints for geological events. The USGS Denver Argon Geochronology Laboratory dates samples from a variety of projects, mainly in the USGS Mineral Resource Program and the National Cooperative Geologic Mapping Program, facilitating in-depth research into the timing of geological events and processes. Recent applications of this method include geochronological studies in the Yellow Pine district, revealing mineralization ages that range from 51 to 70 Ma, and investigations into the Bear Lodge alkaline complex, providing insights into the timing of REE carbonatite formation. Additionally, studies at Alunite Ridge highlight the method's potential for understanding concealed mineral deposits. Ongoing projects continue to leverage 40 Ar/ 39 Ar data to enhance understanding of geologic frameworks and mineral resources, underpinning its importance in modern geochronology and mineral resource assessment.

Conference Paper

Waning greenhouse gas emissions from U.S. Federal lease coal production by the mid-21st century

This study presents estimates of future years (2024–2051) United States Federal lease coal production and the resulting greenhouse gas (GHG) emissions from the combustion, transport, and mining of that fuel. Results from the coal production estimate indicate a decline in production from Federal leases; with known production of 240 million short tons (mtn) in 2023 and a projected decline to 34.0 mtn by 2051, which represents a reduction to 14.2% of the 2023 value. In parallel with this projection, total GHG emissions are estimated to decrease from 402.2 million metric tons of carbon dioxide equivalent (MMT CO 2 eq.) in 2024 to 55.0 MMT CO 2 eq. in 2051, a decline to 13.7% of 2024 emissions estimates. The reductions in coal production and emissions are mainly the result of planned coal combustion power plant closures, with major projected closures in 2037 and 2048. However, GHG emissions estimates for future years can be uncertain as they rely heavily on coal production estimates from operators' public business plans and other publicly available resources. Forward looking plans of this type are subject to significant changes if economic and political factors deviate from current information. Results suggest that average GHG emissions over the time series breakout to 95% end point combustion, 3.7% transportation combustion emissions, and 1.3% fugitive emissions, although there is uncertainty associated with these figures. Uncertainty stemming from production projections, sector distributions, and emissions factors on the future emissions estimates increases with time, ranging from −28% to +48% within the 2024–2051 timeframe.

Alabama, Colorado, Montana, North Dakota, Utah, Wy

Natural source zone depletion of crude oil in the subsurface: Processes controlling mass losses of individual compounds

At many petroleum hydrocarbon spill sites, residual spilled product forms a long-term source of groundwater contamination. The phrase source zone natural depletion is used to refer to the mass loss rates. Overall mass lost under environmental conditions was analyzed using conservative biomarker concentrations for a 1979 oil spill in northern Minnesota, USA. After 40–41 years, an average of 50% of the mass was lost with values ranging from 22% to 57% depending on location. It is also important to understand the composition changes in the source. To understand controls on the losses of individual compounds, concentrations of volatile hydrocarbons in oil samples were compared with aqueous solubilities, and pore-space oil saturations. The results of the comparison show that losses of the oil compounds were controlled by pore-space oil saturations, solubility, and susceptibility to degradation under methanogenic conditions. Compounds that degrade under methanogenic conditions, including toluene, o -xylene, and n -alkanes are more depleted compared to benzene, ethylbenzene, and m - and p -xylene for which losses are dominated by dissolution. These rates and compound-specific behaviors form a foundation for improved modeling approaches and risk analyses.

Minnesota

Framework for assessing intranational risk of critical mineral sectors: Case study of India

Recent geopolitical actions regarding the supply of critical minerals have highlighted both the threats posed by countries dominating a critical mineral supply chain, and the potential mitigations served by alternative supplier countries. However, no systematic quantification exists for the intranational factors that determine such threats or mitigations. This study outlines a methodological framework for quantifying the intranational risk profile of critical mineral sectors and compares them with the sector's international potential for leverage. The four intranational factors of concentration, synchronization, private sector involvement, and regulatory obstacles were analyzed across multiple scales in order to determine an intranational risk score that quantifies the resilience or fragility of the critical mineral sector in question. Network analysis was also separately conducted to identify the most important entities operating across all critical mineral sectors. Finally, this study assessed the critical mineral sector's global share of reserves and production to determine an international risk score that quantifies the country's critical mineral sector's leverage potential. A case study of India showed that two critical mineral sectors with high leverage potential, chromite and barite, were respectively intranationally resilient and fragile. Of the remaining sectors with minimal leverage, five sectors such as aluminum were intranationally resilient and may serve as viable mitigation options for future critical mineral supply. Three sectors such as titanium were intranationally fragile, but recent regulatory developments may both decrease intranational risk and increase international risk, potentially making them major critical mineral sectors in the future.

Resources Policy

Evidence for a biological origin of uranium-rich carbon masses within the Ediacaran Salt Range Formation of Pakistan

Thucholites are unique organic structures found in igneous and sedimentary rocks composed of a U-C-rich interior enclosed by an organic outer shell. Their formation and occurrence have perplexed scientists for over 100 years. Typically, thucholites are sparse in sedimentary rocks but where found in abundance, they may be the result of rapid paleoecological disruptions, e.g., volcanic ashfall. Here, we evaluated thucholites from the Ediacaran Salt Range Formation of the Indus Basin in Pakistan using field emission scanning electron microscopy (FESEM) and nanoscale secondary ion mass spectroscopy (NanoSIMS) to propose a two-stage mechanism for thucholite development. NanoSIMS results suggest organic matter in thucholite cores formed by biological fractionation (represented by the presence of lighter 13 C/ 12 C and 34 S/ 32 S) while the outer organic mantle formed via radiolysis-induced polymerization. FESEM elemental analysis confirms compositional differences between the two thucholite components (core and mantle), further implying their contrasting origins. Dimensional comparison of thucholite cores and their U-bearing mineral morphologies to ancient and modern U-biomineralized microbes suggests that the thucholite cores formed from metal-biological interactions. The presence of volcanogenic biotite, alkali feldspar, and clay spherules (interpreted as devitrified volcanic glass) with thucholite suggests that the thucholite cores in the Salt Range Formation are biological responses to rapid paleoenvironmental change from volcanic eruption which preserved the fossilized morphologies of Proterozoic microorganisms.

Salt Range

Technique for estimating depth of floods in Tennessee

Estimates of flood depths are needed for design of roadways across flood plains and for other types of construction along streams. Equations for estimating flood depths in Tennessee were derived using data for 150 gaging stations. The equations are based on drainage basin size and can be used to estimate depths of the 10-year and 100-year floods for four hydrologic areas. A method also was developed for estimating depth of floods having recurrence intervals between 10 and 100 years. Standard errors range from 22 to 30 percent for the 10-year depth equations and from 23 to 30 percent for the 100-year depth equations.

Tennessee

Towards mobile wind measurements using joust configured ultrasonic anemometer for applications in gas flux quantification

Small uncrewed aerial systems (sUASs) can be used to quantify emissions of greenhouse and other gases, providing flexibility in quantifying these emissions from a multitude of sources, including oil and gas infrastructure, volcano plumes, wildfire emissions, and natural sources. However, sUAS-based emission estimates are sensitive to the accuracy of wind speed and direction measurements. In this study, we examined how filtering and correcting sUAS-based wind measurements affects data accuracy by comparing data from a miniature ultrasonic anemometer mounted on a sUAS in a joust configuration to highly accurate wind data taken from a nearby eddy covariance flux tower (aka the Tower). These corrections had a small effect on wind speed error, but reduced wind direction errors from 50° to >120° to 20–30°. A concurrent experiment examining the amount of error due to the sUAS and the Tower not being co-located showed that the impact of this separation was 0.16–0.21 ms − 1 "> ms − 1 , a small influence on wind speed errors. Lower wind speed errors were correlated with lower turbulence intensity and higher relative wind speeds. There were also some loose trends in diminished wind direction errors at higher relative wind speeds. Therefore, to improve the quality of sUAS-based wind measurements, our study suggested that flight planning consider optimizing conditions that can lower turbulence intensity and maximize relative wind speeds as well as include post-flight corrections.

Alaska

Approximate inland extent of saltwater intrusion at the base of the Biscayne aquifer, Miami-Dade County, Florida, 2022

Miami-Dade County is part of a densely populated urban corridor in southeastern Florida. The Biscayne aquifer serves as Miami-Dade County’s primary drinking water source and is characterized by highly permeable karstic limestone and carbonate sand. The aquifer’s coastal location and permeable nature make it susceptible to saltwater intrusion. Monitoring the current inland extent and the rate of movement of the saltwater front in the aquifer can inform management strategies for conserving the long-term sustainability of the county’s water supply. In the 1950s, the U.S. Geological Survey published a map of the inland extent of saltwater intrusion in the Biscayne aquifer and has continued to update this map to monitor changes over time, with the most recent update published in 2018. An updated map has been created showing the approximate inland extent of saltwater intrusion in the Biscayne aquifer in eastern Miami-Dade County in 2022, with the 2018 extent shown for comparison. The inland extent of saltwater intrusion was mapped through the interpretation of borehole electromagnetic induction logs and measurements of chloride and specific conductance in groundwater samples. The location of the saltwater interface at the base of the Biscayne aquifer was represented by the 1,000-milligram-per-liter isochlor. This report describes changes in the location of the saltwater interface from 2018 to 2022. By 2022, the saltwater interface had moved farther inland in both the northern and southern parts of the county, advancing by as much as 0.3 kilometer in the north and up to 0.8 kilometer in the Model Land Area to the south. However, it remained relatively unchanged from its 2018 position in the east-central part of the county.

Florida

Assessment of water chemistry of the Coconino aquifer in northeastern Arizona

The Coconino aquifer was investigated as a potential groundwater resource for the Hopi Tribe and Navajo Nation in northeastern Arizona. Basic groundwater chemistry, including major ions, total dissolved solids, and selected trace metal concentrations, are presented and analyzed to characterize the Coconino aquifer. The geochemical compositions of groundwater are associated with changes in geology and groundwater movement and are compared to drinking-water standards to determine suitable areas for potential groundwater resource development. Dissolved-solids concentrations in much of the Coconino aquifer water were higher than the U.S. Environmental Protection Agency’s secondary drinking-water standard of 500 milligrams per liter (mg/L) due to a buried halite body in the southeastern part of the study area. However, trace metal concentrations were generally low. Groundwater may need to be treated for high dissolved-solids concentrations before it is suitable for use as a resource for the Hopi Tribe and Navajo Nation.

Arizona

Disturbance is the primary determinant of food chain length when the top predator is constant

Food chain length (FCL) is a primary determinant of food web structure and is hypothesized to be influenced by habitat size, productivity, and disturbance. Understanding the environmental characteristics that determine food chain length can assist in understanding how food webs may be impacted due to changes in habitats and environmental characteristics. This study examines the impact of hydrologic disturbance on stream food webs when the top predator is constant. We analyzed FCL in less disturbed groundwater flashy streams and more disturbed runoff flashy streams using stable isotopes. Despite no difference in species richness or fish density, food chains in more disturbed streams had a lower FCL compared to food chains in more stable streams. Assemblage analysis showed that flow regime and drainage area significantly impacted individual species abundances. The more disturbed runoff flashy streams had higher proportions of primary consumer fish, such as the algivorous Campostoma sp. (Stonerollers), which likely drives the reduced FCL. Drainage area and land cover had non-significant relationships with FCL. Shifting community structure due to hydrologic variability likely leads to differences in diet of Micropterus dolomieu (Smallmouth Bass), and thus a difference in FCL.

Arkansas, Missouri, Oklahoma

A geographic dataset of rocky reefs habitat areas of particular concern for the United States West Coast

The United States National Marine Fisheries Service determines “essential fish habitat (EFH)” for federally managed species in coordination with regional fishery management councils, considers adverse effects to those habitats, and provides information to further habitat conservation and enhancement. Identifying discrete subsets of EFH as “habitat areas of particular concern (HAPC)” can help focus conservation, management, and research efforts. In 2006, the Pacific Fishery Management Council designated rocky reefs along the United States (U.S.) West Coast as HAPCs for groundfishes because of their ecological significance, sensitivity to human impacts, and relative rarity. To better understand where rocky reefs occur, we (1) located rocky reef areas that were not included in the 2006 rocky reef dataset, and (2) incorporated best available data into a refined geographic dataset that enables visualization. Our update shows that rocky reefs are distributed throughout the U.S. West Coast continental margin, are patchier than previously known, and comprise 8% of the extent of all data inputs. This updated dataset will inform resource management decisions in coastal and marine environments.

California, Oregon, Washington

Base-flow sampling to enhance understanding of the groundwater flow component of nitrogen loading in small watersheds draining into Long Island Sound

Excessive nitrogen discharge is a major concern for the Long Island Sound. Programs have been implemented to reduce point sources of nitrogen to the sound, but little is known about the nonpoint sources. This study aims to better understand the current groundwater contributions of nitrogen from nonpoint sources in the Long Island Sound watershed. During the spring and summer of 2022, the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency, collected water-quality samples to analyze nutrients (nitrogen and phosphorus), chloride, and bromide at 45 stations in the Long Island Sound watershed in Connecticut, New York, and Rhode Island. The stations were in small drainage watersheds (5 to 30 square kilometers) in the southern part of the Long Island Sound watershed. During two separate synoptic sampling events, water-quality samples and instantaneous streamflow measurements were collected under base-flow conditions (where the streamflow is dominated by groundwater inputs rather than overland flow or runoff flow). One sampling event was in the nongrowing season (April 24–25, 2022), and the other was in the growing season (June 30–July 1, 2022). To calculate instantaneous nitrogen loads and yields, streamflow was measured at the time of sample collection. Nitrogen concentrations, loads, and yields varied among sampling stations and by season. Total filtered nitrogen concentrations were generally lower in the nongrowing season (from less than 0.14 to 1.9 milligrams per liter) than in the growing season (from less than 0.23 to 3.0 milligrams per liter). Nitrate plus nitrite concentrations showed little variation between the nongrowing and growing seasons. Unfiltered ammonia plus organic nitrogen concentrations were generally lower in the nongrowing season (from less than 0.07 to 0.83 milligram per liter) than in the growing season (from 0.11 to 0.98 milligram per liter). In contrast, total filtered and unfiltered nitrogen loads and yields were higher in the nongrowing season than during the growing season, likely because streamflows were higher during the nongrowing season. Total unfiltered nitrogen yields during the nongrowing season ranged from less than 0.15 to 5.0 kilograms per square kilometer per day. Total unfiltered nitrogen yields during the growing season ranged from less than 0.12 to 2.5 kilograms per square kilometer per day. Total filtered nitrogen yields during the nongrowing season ranged from less than 0.13 to 5.2 kilograms per square kilometer per day. Total filtered nitrogen yields during the growing season ranged from less than 0.06 to 2.5 kilograms per square kilometer per day.

Connecticut, New York, Rhode Island

Origin of the high Pd/Pt ratio of the J-M Reef, Stillwater Complex Montana USA

The J-M Reef of the Stillwater Complex exhibits a high and consistent Pd/Pt ratio (~3.8). This ratio results from the equilibration of an immiscible sulfide liquid with a relatively high Pd/Pt silicate melt rather than an unusually Pd- and Pt-enriched parental melt. Numerical modeling suggests that the original silicate melt contained typical mantle-derived concentrations of Pd and Pt (~10–20 ppb Pd/Pt ~1). The partitioning of Pt and Pd between sulfide liquid and silicate melt alone cannot explain the consistently high Pd/Pt ratio across variable melt-to-sulfide mass ratios (R factors). Instead Pt-depletion caused by the early fractionation of Pt-alloy from S-undersaturated silicate magma likely established the high Pd/Pt signature. High Pd/Pt ratios can form through batch equilibration of sulfide liquid with silicate melt if partition coefficients are extremely high (>10⁶). Alternatively Pd enrichment may result from sulfide upgrading within the resident footwall mush under smaller partition coefficients (10⁴–10⁶) in this model the instantaneous R factors remain low (R ≈ 100–700). This limits the impact of Pt and Pd partitioning on sulfide composition and helps explain the Pd-enriched character of the J-M Reef.

Montana

Ground-water flow in the surficial aquifer system and potential movement of contaminants from selected waste-disposal sites at Cecil Field Naval Air Station, Jacksonville, Florida

As part of the Installation Restoration Program, Cecil Field Naval Air Station, Jacksonville, Florida, is considering remedialaction alternatives to control the possible movement of contaminants from sites that may discharge to the surface. This requires a quantifiable understanding of ground-water flow through the surficial aquifer system and how the system will respond to any future stresses. The geologic units of interest in the study area consist of sediments of Holocene to Miocene age that extend from land surface to the base of the Hawthorn Group. The hydrogeology within the study area was determined from gamma-ray and geologists' logs. Ground-water flow through the surficial aquifer system was simulated with a seven-layer, finite-difference model that extended vertically from the water table to the top of the Upper Floridan aquifer. Results from the calibrated model were based on a long-term recharge rate of 6 inches per year, which fell in the range of 4 to 10 inches per year, estimated using stream hydrograph separation methods. More than 80 percent of ground-water flow circulates within the surficial-sand aquifer, which indicates that most contaminant movement also can be expected to move through the surficial-sand aquifer alone. The surficial-sand aquifer is the uppermost unit of the surficial aquifer system. Particle-tracking results showed that the distances of most flow paths were 1,500 feet or less from a given site to its discharge point. For an assumed effective porosity of 20 percent, typical traveltimes are 40 years or less. At all of the sites investigated, particles released 10 feet below the water table had shorter traveltimes than those released 40 feet below the water table. Traveltimes from contaminated sites to their point of discharge ranged from 2 to 300 years. The contributing areas of the domestic supply wells are not very extensive. The shortest traveltimes for particles to reach the domestic supply wells from their respective contributing areas ranged from 70 to 200 years.

Florida

Use of digital land-cover data from the Landsat satellite in estimating streamflow characteristics in the Cumberland Plateau of Tennessee

Characteristics of Streamflow at ungaged sites in coal-mining areas of the Cumberland Plateau may be estimated with regression equations that relate streamflow characteristics to the physiographic and climatic characteristics of the corresponding drainage basins. An experiment was performed to compare the accuracy of equations using basin characteristics derived from maps and climatological records (control group equations) with the accuracy of equations using basin characteristics derived from digital processing of Landsat spectral data as well as maps and climatological records (experimental group equations). Results of this experiment show that (with the exception of low flows and four of six annual peak logarithms) drainage area can explain more than 90 percent of the variance in all streamflow characteristics in both groups of equations. Seventeen of 39 experimental group equations that have two basin characteristics each are different from the corresponding control group equations. Five of the 17 differing experimental group equations have no counterpart in the control group because of lack of significance in control group basin characteristics, seven are slightly more accurate, and five are not measurably different in accuracy. When the equations in both groups are arranged into six flow categories, there is no substantial difference in accuracy between equations using basin characteristics derived from maps and climatological records (control group) and equations using basin characteristics derived from Landsat tapes as well as maps and climatological records (experimental group) for this particular study area, the Cumberland Plateau of Tennessee.

Tennessee

On connecting hydro-social parameters to vegetation greenness differences in an evolving groundwater-dependent ecosystem

Understanding groundwater-dependent ecosystems (i.e., areas with a relatively shallow water table that plays a major role in supporting vegetation health) is key to sustaining water resources in the western United States. Groundwater-dependent ecosystems (GDEs) in Colorado have non-pristine temporal and spatial patterns, compared to agro-ecosystems, which make it difficult to quantify how these ecosystems are impacted by changes in water availability. The goal of this study is to examine how key hydrosocial parameters perturb GDE water use in time and in space. The temporal approach tests for the additive impacts of precipitation, surface water discharge, surface water mass balance as a surrogate for surface–groundwater exchange, and groundwater depth on the monthly Landsat normalized difference vegetation index (NDVI). The spatial approach tests for the additive impacts of river confluences, canal augmentation, development, perennial tributary confluences, and farmland modification on temporally integrated NDVI. Model results show a temporal trend (monthly, 1984–2019) is identifiable along segments of the Arkansas River at resolutions finer than 10 km. The temporal impacts of river discharge correlate with riparian water use sooner in time compared to precipitation, but this result is spatially variable and dependent on the covariates tested. Spatially, areal segments of the Arkansas River that have confluences with perennial streams have increased cumulative vegetation density. Quantifying temporal and spatial dependencies between the sources and effects of GDEs could aid in preventing the loss of a vulnerable ecosystem to increased water demand, changing climate, and evolving irrigation methodologies.

Colorado

Characteristics of the fault damage zone From high-resolution seismic imaging along the Palos Verdes Fault, California

The distribution and intensity of fault damage zones provides insight into fault activity and its relationship to fluid flow in the crust. Presently, measures of the in-situ distribution of fault damage remain limited and along-strike studies are rare. This study focuses on an offshore section Palos Verdes Fault damage zone that spans 28 km, near Los Angeles, California. To investigate the previously unresolved shallow (∼400 m below the seafloor) fault damage zone we use densely spaced (∼500 m line separation) newly collected sparker multichannel seismic lines and sub-bottom profiles. The combination of high-resolution acquisition methods and specialized seismic processing workflows provide improved imaging of shallow faulting. We apply a multi-trace similarity technique to identify discontinuities in the seismic data that may be attributed to faults and fractures. This fault detection approach reveals diverse fault damage patterns on adjacent seismic profiles. However, a discernible damage zone pattern emerges by stacking multiple damage detection profiles along strike. We find that peak damage identified in this way corresponds to the active main fault strand, confirmed in this study, and thus the technique may be useful for identifying active fault strands elsewhere. Additionally, we observe that the variable width of the damage zone along strike is controlled by fault obliquity. Furthermore, our observations reveal a correlation between fault damage and seafloor fluid seeps visible in the water column, suggesting that damage plays a role in controlling fluid flow around the fault.

California