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USGS2023

Reevaluation of 2,3,7,8-tetrachlorodibenzo-p-dioxin equivalency factors for dioxin-like polychlorinated dibenzo-p-dioxins, polychlorinated dibenzofurans, and polychlorinated biphenyls for fishes

An expert meeting was organized by the World Health Organization (WHO) in 1997 to streamline assessments of risk posed by mixtures of dioxin-like chemicals (DLCs) through development of 2,3,7,8-tetrachlorodibenzo- p -dioxin (2,3,7,8-TCDD) equivalency factors (TEFs) for mammals, birds, and fishes. No reevaluation has been performed for fish TEFs. Therefore, the objective of the present study was to reevaluate the TEFs for fishes based on an updated database of relative potencies (RePs) for DLCs. Selection criteria consistent with the WHO meeting resulted in 53 RePs across 14 species of fish ultimately being considered. Of these RePs, 70% were not available at the time of the WHO meeting. These RePs were used to develop updated TEFs for fishes based on a similar decision process as used at the WHO meeting. The updated TEF for 16 DLCs was greater than the WHO TEF, but only four differed by more than an order of magnitude. Measured concentrations of DLCs in four environmental samples were used to compare 2,3,7,8-TCDD equivalents (TEQs) calculated using the WHO TEFs relative to the updated TEFs. The TEQs for none of these environmental samples differed by more than an order of magnitude. Therefore, present knowledge supports that the WHO TEFs are suitable potency estimates for fishes. However, the updated TEFs pull from a larger database with a greater breadth of data and as a result offer greater confidence relative to the WHO TEFs. Risk assessors will have different criteria in the selection of TEFs, and the updated TEFs are not meant to immediately replace the formal WHO TEFs; but those who value a larger database and increased confidence in TEQs could consider using the updated TEFs.

Environmental Toxicology and Chemistry↗

USGS1982

DDT poisoning in a Cooper's hawk collected in 1980

In April 1980, a Cooper's hawk ( Accipiter cooperii ) was found on the ground in Lakewood, Colorado, unable to fly and in convulsion. The bird died shortly thereafter. The hawk was packed in dry ice and shipped air express to the Fish and Wildlife Service, U. S. Department of the Interior, National Wildlife Health Laboratory, Madison, Wisconsin, for necropsy. Following necropsy, the brain, gastrointestinal tract, and remaining carcass except skin, feet, wings, liver, and kidney were packed in dry ice and shipped air express to the Patuxent Wildlife Research Center, Laurel, Maryland, for chemical residue analysis. Because the bird's behavior before death suggested some form of poisoning, the kidney was assayed for thallium, the liver for lead, and the gastrointestinal tract for strychnine, sodium fluoroacetate, and arsenic. When these assays proved negative, the bird was analyzed for organochlorine pesticides. Necropsy findings and pesticide residue analyses are reported here.

Colorado↗

USGS2002

Effects of highway-deicer application on ground-water quality in a part of the Calumet Aquifer, northwestern Indiana

The effects of highway-deicer application on ground-water quality were studied at a site in northwestern Indiana using a variety of geochemical indicators. Site characteristics such as high snowfall rates; large quantities of applied deicers; presence of a high-traffic highway; a homogeneous, permeable, and unconfined aquifer; a shallow water table; a known ground-water-flow direction; and minimal potential for other sources of chloride and sodium to complicate source interpretation were used to select a study area where ground water was likely to be affected by deicer application. Forty-three monitoring wells were installed in an unconfined sand aquifer (the Calumet aquifer) near Beverly Shores in northwestern Indiana. Wells were installed along two transects that approximately paralleled groundwater flow in the Calumet aquifer and crossed US–12. US–12 is a highway that receives Indiana’s highest level of maintenance to maintain safe driving conditions. Ground-water quality and water-level data were collected from the monitoring wells, and precipitation and salt-application data were compiled from 1994 through 1997. The water-quality data indicated that chloride was the most easily traced indicator of highway deicers in ground water. Concentration ratios of chloride to iodide and chloride to bromide and Stiff diagrams of major element concentrations indicated that the principal source of chloride and sodium in ground water from the uppermost one-third to one-half of the Calumet aquifer and downgradient from US–12 was from a halite highway-deicer source. Borehole logs of relative electromagnetic conductivity defined a distinct plume of deicer-affected water in the uppermost 8 feet of aquifer at about 9 feet horizontally from the paved roadway edge and a zone of higher conductivity than background in the lower one-third of the aquifer. Chloride and sodium in the deep parts of the aquifer originated from natural sources. Chloride and sodium from highway deicers were present in the aquifer throughout the year. The highest concentrations of chloride and sodium in ground water were determined in samples collected during the spring and summer from wells open to the water table within about 9 feet of the highway. Chloride concentrations in ground water that were attributable to highway deicers also were found in tested wells about 400 feet downgradient from US–12 during the fall and winter and at greater depths than in wells closer to US–12. Chloride concentrations exceeded the U.S. Environmental Protection Agency’s (USEPA) secondary maximum contaminant level of 250 milligrams per liter for drinking water at seven wells downgradient from the highway during late winter, spring, and summer samplings. The chloride standard was exceeded only in water from wells with total depths that are less than about 10 feet below land surface. Sodium concentrations in water periodically exceeded the USEPA drinking-water equivalency level of 20 milligrams per liter in both the uppermost (deicer 2 Effects of Highway-Deicer Application on Ground-Water Quality in a Part of the Calumet Aquifer, Northwestern Indiana affected) and lower one-thirds of the aquifer. Sodium concentrations in ground water downgradient from US–12 and in the upper 5 feet of the aquifer also occasionally exceeded drinking-water standards for sodium (160 milligrams per liter) as set by the State of Florida and a standard for taste (200 milligrams per liter) as set by the World Health Organization. Dispersion was identified by analysis of aquifer-test data, isotopic dating of ground water, and water-quality data to be the process most responsible for reducing concentrations of highway deicers in the aquifer. Chemical analyses of the sand composing the aquifer indicated that cation exchange decreased the mass of deicerrelated sodium in ground water, although the sand has a limited capacity to sustain the process. Automated daily measurements of specific conductance, correlated to chloride concentrations, indicated that some deicer is retained in the aquifer near the highway throughout the entire year and acts as a continuous chloride source for ground water. Peak concentrations of deicerrelated constituents occasionally were detected by the daily, automated measurements of specific conductance that were made between the monthly samplings of ground water. Data analysis indicated that more frequent sampling than monthly intervals would be necessary if maximum chloride concentrations were to be measured. Some deicer may be retained in the aquifer and unsaturated zone between annual salt-application periods. Chloride concentrations at wells 1-DG-WT and 2-DG-WT remained greater than background through much or all of the year. The estimated masses of chloride transported in ground water past 2-DG in 1995 and 1996 were either slightly greater than (1995) or less than (1996) the masses of chloride applied to US–12 during the study.

Indiana↗

USGS2003

Workshop 3.5: Closing the gap between exposure and effects in monitoring studies

A major challenge to contaminant monitoring programs is the selection of an appropriate suite of measurements for assessing exposure and effects. Early monitoring programs relied solely on residue analysis to detect the organochlorine compounds that were in use at that time. A shift to the use of more transient, less persistent chemicals required that a new set of tools be developed to determine if an organism had been exposed. This led to the development of cellular and biochemical assays that could indicate the presence of these types of chemicals in biota and the environment. However, it was recognized that measures of contaminant presence alone were insufficient to assess the health of biota. As a result, considerable research began to be directed toward development of diagnostic tools for measuring chemical effects in fish and wildlife. Today, contaminant monitoring programs follow a paradigm for study design that emphasizes not only the use of measures of exposure, but also measures of effect. Using data from our monitoring and research studies for hormonally active substances, we discuss a variety of metrics of exposure and effects and their application to specific chemicals, and the current information gaps. We conclude that although several bioindicators of exposure and effect have been promoted and used, to date there continues to be a poor association between cause and effect for endocrine active substances. In part, this is due to the limited number of diagnostic tools that are available and to a lack of basic toxicological information concerning toxicokinetics and mechanisms of action of hormonally active chemicals in fish and wildlife species. In the foreseeable future, both tissue and environmental residue data, despite the many limitations, will continue to be an important component of monitoring programs for hormonally active chemicals as we continue to develop and validate more specific bioindicators of exposure and effects.

Pure and Applied Chemistry↗

USGS2009

A review of plague persistence with special emphasis on fleas

Sylvatic plague is highly prevalent during infrequent epizootics that ravage the landscape of western North America. During these periods, plague dissemination is very efficient. Epizootics end when rodent and flea populations are decimated and vectored transmission declines. A second phase (enzootic plague) ensues when plague is difficult to detect from fleas, hosts or the environment, and presents less of a threat to public health. Recently, researchers have hypothesized that the bacterium (Yersinia pestis) responsible for plague maintains a continuous state of high virulence and thus only changes in transmission efficiency explain the shift between alternating enzootic and epizootic phases. However, if virulent transmission becomes too inefficient, strong selection might favor an alternate survival strategy. Another plausible non-exclusive hypothesis, best supported from Asian field studies, is that Y. pestis persists (locally) at foci by maintaining a more benign relationship within adapted rodents during the long expanses of time between outbreaks. From this vantage, it can revert to the epizootic (transmission efficient) form. Similarly, in the United States (US), enzootic plague persistence has been proposed to develop sequestered within New World rodent carriers. However, the absence of clear support for rodent carriers in North America has encouraged a broader search for alternative explanations. A telluric plague existence has been proposed. However, the availability of flea life stages and their hosts could critically supplement environmental plague sources, or fleas might directly represent a lowlevel plague reservoir. Here, we note a potentially pivotal role for fleas. These epizootic plague vectors should be closely studied with newer more exacting methods to determine their potential to serve as participants in or accomplices to a plague persistence reservoir.

Journal of Vector Borne Diseases↗

USGS1999

Characterization and inhibition of nitrite uptake in shortnose sturgeon fingerlings

Efforts are underway to culture the endangered shortnose sturgeon Acipenser brevirostrum for possible reintroduction. As part of a larger project to develop culture techniques for this species, the uptake of nitrite was evaluated in fingerlings (16.5 ± 4.85 g; mean ± SD). Plasma nitrite concentrations increased significantly with exposure time (0–5 d) and dose (0–4 mg nitrite-N/L). Shortnose sturgeon fingerlings were able to concentrate nitrite in their plasma to more than 63 times the environmental concentration. Chloride, as either sodium chloride or calcium chloride, partially inhibited nitrite uptake. However, calcium chloride was a better inhibitor. After previous exposure (2 d at 2.13 ± 0.080 mg nitrite-N/L) plasma nitrite-N decreased from 165.5 to 36.7 mg/L during a 3-d simultaneous exposure to 2.13 ± 0.080 mg nitrite-N/L and treatment with 40 mg chloride/L as calcium chloride. The addition of calcium chloride to the water appeared to be an effective means of preventing nitrite uptake and treating nitrite toxicity in hatchery-reared shortnose sturgeon fingerlings.

Journal of Aquatic Animal Health↗

USGS2014

Base of principal aquifer for parts of the North Platte, South Platte, and Twin Platte Natural Resources Districts, western Nebraska

Water resources in the North and South Platte River valleys of Nebraska, including the valley of Lodgepole Creek, are critical to the social and economic health of the area, and for the recovery of threatened and endangered species in the Platte River Basin. Groundwater and surface water are heavily used resources, and uses are regulated in the study area. Irrigation is the dominant water use and, in most instances, is supplied by both groundwater and surface-water sources. The U.S. Geological Survey and its partners have collaborated to use airborne geophysical surveys for areas of the North and South Platte River valleys including the valley of Lodgepole Creek in western Nebraska. The objective of the surveys was to map the aquifers and underlying bedrock topography of selected areas to help improve the understanding of groundwater–surface-water relations to guide water-management decisions. This project was a cooperative study involving the North Platte Natural Resources District, the South Platte Natural Resources District, the Twin Platte Natural Resources District, the Conservation and Survey Division of the University of Nebraska-Lincoln, and the Nebraska Environmental Trust. This report presents the interpreted base-of-aquifer surface for part of the area consisting of the North Platte Natural Resources District, the South Platte Natural Resources District, and the Twin Platte Natural Resources District. The interpretations presented herein build on work done by previous researchers from 2008 to 2009 by incorporating additional airborne electromagnetic survey data collected in 2010 and additional test holes from separate, related studies. To make the airborne electromagnetic data useful, numerical inversion was used to convert the measured data into a depth-dependent subsurface resistivity model. An interpretation of the elevation and configuration of the base of aquifer was completed in a geographic information system that provided x, y, and z coordinates. The process of interpretation involved manually picking locations (base-of-aquifer elevations) on the displayed airborne electromagnetic-derived resistivity profile by the project geophysicist, hydrologist, and geologist. These locations, or picks, of the base-of-aquifer elevation (typically the top of the Brule Formation of the White River Group) were then stored in a georeferenced database. The pick was made by comparing the inverted airborne electromagnetic-derived resistivity profile to the lithologic descriptions and borehole geophysical logs from nearby test holes. The database of interpretive picks of the base-of-aquifer elevation was used to create primary input for interpolating the new base-of-aquifer contours. The automatically generated contours were manually adjusted based on the interpreted location of paleovalleys eroded into the base-of-aquifer surface and associated bedrock highs, many of which were unmapped before this study. When contours are overlain by the water-table surface, the saturated thickness of the aquifer can be computed, which allows an estimate of total water in storage. The contours of the base-of-aquifer surface presented in this report may be used as the lower boundary layer in existing and future groundwater-flow models. The integration of geophysical data into the contouring process facilitated a more continuous and spatially comprehensive view of the hydrogeologic framework.

Nebraska↗

USGS2020

Spatial and temporal variations in SO2 and PM2.5 levels around Kīlauea volcano, Hawai'i during 2007–2018

Among the hazards posed by volcanoes are the emissions of gases and particles that can affect air quality and damage agriculture and infrastructure. A recent intense episode of volcanic degassing associated with severe impacts on air quality accompanied the 2018 lower East Rift Zone (LERZ) eruption of Kīlauea volcano, Hawai'i. This resulted in a major increase in gas emission rates with respect to usual emission values for this volcano, along with a shift in the source of the dominant plume to a populated area on the lower flank of the volcano. This led to reduced air quality in downwind communities. We analyse open-access data from the permanent air quality monitoring networks operated by the Hawai'i Department of Health (HDOH) and National Park Service (NPS), and report on measurements of atmospheric sulfur dioxide (SO 2 ) between 2007 and 2018 and PM 2.5 (aerosol particulate matter with diameter <2.5 μm) between 2010 and 2018. Additional air quality data were collected through a community-operated network of low-cost PM 2.5 sensors during the 2018 LERZ eruption. From 2007 to 2018 the two most significant escalations in Kīlauea's volcanic emissions were: the summit eruption that began in 2008 (Kīlauea emissions averaged 5–6 kt/day SO 2 from 2008 until summit activity decreased in May 2018) and the LERZ eruption in 2018 when SO 2 emission rates reached a monthly average of 200 kt/day during June. In this paper we focus on characterizing the airborne pollutants arising from the 2018 LERZ eruption and the spatial distribution and severity of volcanic air pollution events across the Island of Hawai'i. The LERZ eruption caused the most frequent and severe exceedances of the Environmental Protection Agency (EPA) PM 2.5 air quality threshold (35 μg/m 3 as a daily average) in Hawai'i in the period 2010–2018. In Kona, for example, the maximum 24-h-mean mass concentration of PM 2.5 was recorded as 59 μg/m 3 on the twenty-ninth of May 2018, which was one of eight recorded exceedances of the EPA air quality threshold during the 2018 LERZ eruption, where there had been no exceedances in the previous 8 years as measured by the HDOH and NPS networks. SO 2 air pollution during the LERZ eruption was most severe in communities in the south and west of the island, as measured by selected HDOH and NPS stations in this study, with a maximum 24-h-mean mass concentration of 728 μg/m 3 recorded in Ocean View (100 km west of the LERZ emission source) in May 2018. Data from the low-cost sensor network correlated well with data from the HDOH PM 2.5 instruments, confirming that these low-cost sensors provide a robust means to augment reference-grade instrument networks.

Hawaii↗

USGS2022

Acetylenotrophic and diazotrophic Bradyrhizobium sp. strain I71 from TCE-contaminated soils

Abstract Acetylene (C 2 H 2 ) is a molecule rarely found in nature, with very few known natural sources, but acetylenotrophic microorganisms can use acetylene as their primary carbon and energy source. As of 2018 there were 15 known strains of aerobic and anaerobic acetylenotrophs; however, we hypothesize there may yet be unrecognized diversity of acetylenotrophs in nature. This study expands the known diversity of acetylenotrophs by isolating the aerobic acetylenotroph, Bradyrhizobium sp. strain I71, from trichloroethylene (TCE)-contaminated soils. Strain I71 is a member of the class Alphaproteobacteria and exhibits acetylenotrophic and diazotrophic activities, the only two enzymatic reactions known to transform acetylene. This unique capability in the isolated strain may increase the genus’ economic impact beyond agriculture as acetylenotrophy is closely linked to bioremediation of chlorinated contaminants. Computational analyses indicate that the Bradyrhizobium sp. strain I71 genome contains 522 unique genes compared to close relatives. Moreover, applying a novel hidden Markov model of known acetylene hydratase (AH) enzymes identified a putative AH enzyme. Protein annotation with I-TASSER software predicted the AH from the microbe Syntrophotalea acetylenica as the closest structural and functional analog. Furthermore, the putative AH was flanked by horizontal gene transfer (HGT) elements, like that of AH in anaerobic acetylenotrophs, suggesting an unknown source of acetylene or acetylenic substrate in the environment that is selecting for the presence of AH. Importance The isolation of Bradyrhizobium strain I71 expands the distribution of acetylene-consuming microbes to include a group of economically important microorganisms. Members of Bradyrhizobium are well studied for their abilities to improve plant health and increase crop yields by providing bioavailable nitrogen. Additionally, acetylene-consuming microbes have been shown to work in tandem with other microbes to degrade soil contaminants. Based on genome, cultivation, and protein prediction analysis, the ability to consume acetylene is likely not widespread within the genus Bradyrhizobium . These findings suggest that the suite of phenotypic capabilities of strain I71 may be unique and make it a good candidate for further study in several research avenues.

California↗

USGS2024

Nitrate exposure from drinking water and dietary sources among Iowa farmers using private wells

Nitrate levels are increasing in water resources across the United States and nitrate ingestion from drinking water has been associated with adverse health risks in epidemiologic studies at levels below the maximum contaminant level (MCL). In contrast, dietary nitrate ingestion has generally been associated with beneficial health effects. Few studies have characterized the contribution of both drinking water and dietary sources to nitrate exposure. The Agricultural Health Study is a prospective cohort of farmers and their spouses in Iowa and North Carolina. In 2018–2019, we assessed nitrate exposure for 47 farmers who used private wells for their drinking water and lived in 8 eastern Iowa counties where groundwater is vulnerable to nitrate contamination. Drinking water and dietary intakes were estimated using the National Cancer Institute Automated Self-Administered 24-Hour Dietary Assessment tool. We measured nitrate in tap water and estimated dietary nitrate from a database of food concentrations. Urinary nitrate was measured in first morning void samples in 2018–19 and in archived samples from 2010 to 2017 (minimum time between samples: 2 years; median: 7 years). We used linear regression to evaluate urinary nitrate concentrations in relation to total nitrate, and drinking water and dietary intakes separately. Overall, dietary nitrate contributed the most to total intake (median: 97 %; interquartile range [IQR]: 57–99 %). Among 15 participants (32 %) whose drinking water nitrate concentrations were at/above the U.S. Environmental Protection Agency MCL (10 mg/L NO 3 -N), median intake from water was 44 % (IQR: 26–72 %). Total nitrate intake was the strongest predictor of urinary nitrate concentrations (R 2 = 0.53). Drinking water explained a similar proportion of the variation in nitrate excretion (R 2 = 0.52) as diet (R 2 = 0.47). Our findings demonstrate the importance of both dietary and drinking water intakes as determinants of nitrate excretion.

Iowa↗

USGS2007

Characterization of Water Quality in Unmonitored Streams in the Mississippi Alluvial Plain, Northwestern Mississippi, May-June 2006

The Mississippi Department of Environmental Quality is required to develop restoration and remediation plans for water bodies not meeting their designated uses, as stated in the U.S. Environmental Protection Agency's Clean Water Act section 303(d). The majority of streams in northwestern Mississippi are on the 303(d) list of water-quality limited waters. Agricultural effects on streams in northwestern Mississippi have reduced the number of unimpaired streams (reference streams) for water-quality comparisons. As part of an effort to develop an index to assess impairment, the U.S. Geological Survey collected water samples from 52 stream sites on the 303(d) list during May-June 2006, and analyzed the samples for nutrients and chlorophyll. The data were analyzed by trophic group as determined by total nitrogen concentrations. Seven constituents (nitrite plus nitrate, total Kjeldhal nitrogen, total phosphorus, orthophosphorus, total organic carbon, chlorophyll a, and pheophytina) and four physical property measurements (specific conductance, pH, turbidity, and dissolved oxygen) were determined to be significantly different (p < 0.05) between trophic groups. Total Kjeldhal nitrogen, turbidity, and dissolved oxygen were used as indicators of stream productivity with which to infer stream health. Streams having high total Kjeldhal nitrogen values and high turbidity values along with low dissolved oxygen concentrations were typically eutrophic abundant in nutrients), whereas streams having low total Kjeldhal nitrogen values and low turbidity values along with high dissolved oxygen concentrations were typically oligotrophic (deficient in nutrients).

Scientific Investigations Report↗

USGS2023

Effects of noise from oil and gas development on ungulates and small mammals—A science synthesis to inform National Environmental Policy Act analyses

The U.S. Geological Survey is working with Federal land management agencies to develop a series of science syntheses to support environmental effects analyses that agencies conduct to comply with the National Environmental Policy Act (NEPA). This report synthesizes science information about the potential effects of noise from oil and gas development on North American ungulates and small mammals, including rodents and leporids. We conducted a structured search of published scientific literature to find information about noise levels produced during oil and gas development, methods for analyzing sound propagation, the effects of noise on ungulates and small mammals, and measures to reduce noise emissions. We organized the sections of this synthesis to align with standard elements of NEPA analyses. We found that oil and gas development is a common source of human-caused noise on public lands and includes noise sources such as heavy construction and drilling machinery, long-term production machinery, truck traffic, and aircraft. Common techniques for predicting potential noise include field data collection using a sound level meter, inference from previously published data, and sound propagation modeling. A substantial body of research shows that human-caused noise can affect wildlife health and behavior, with variation in sensitivity to noise among species. Studies have shown consistent, detectable effects of noise on ungulates, but the amount of literature on ungulates is very small, and additional research could improve our understanding of differences in effects among species, seasons, and individual indicators of fitness. Several species of small mammals are dependent on audible signals for predator detection and communication, and noise has been shown to affect their vigilance and foraging behavior. However, other studies have documented no effects to rodents in noisy areas, and the effects of noise on small mammals may differ by species and study system. Techniques suggested in the literature for reducing noise emissions include sound barriers, seasonal and daily timing restrictions, traffic control measures, and siting infrastructure to take advantage of natural sound barriers. Public land managers can use this report by incorporating it by reference in NEPA documentation, as supplemental information, or as a general reference for literature about the effects of noise from oil and gas development on ungulates and small mammals.

Scientific Investigations Report↗

USGS2016

Informing Lake Erie agriculture nutrient management via scenario evaluation

Harmful algal blooms (HABs) have been increasing in extent and intensity in the western basin of Lake Erie. The cyanobacteria Microcystis produces toxins that pose serious threats to animal and human health, resulting in beach closures and impaired water supplies, and have even forced a “do not drink” advisory for the City of Toledo water system for several days in the summer of 2014. The main driver of Lake Erie HABs is elevated phosphorus loading from watersheds draining to the western basin, particularly from the Maumee River watershed (Obenour et al. 2014). Through the 2012 Great Lakes Water Quality Agreement (GLWQA), the U.S. and Canadian governments agreed to revise Lake Erie phosphorus loading targets to decrease HAB severity below levels representing a hazard to ecosystem and human health. New targets limit March-July loadings from the Maumee River to 186 metric tonnes of dissolved reactive phosphorus (DRP) and 860 metric tonnes of total phosphorus (TP) – a 40% reduction from 2008 loads (GLWQA 2016). The Great Lakes region must now determine what policy options are most effective and feasible for meeting those targets. While all sources are important, our focus is on agriculture because it overwhelms other sources. In a conservative ballpark estimate we found that 85% of the Maumee River’s load to Lake Erie comes from farm fertilizers and manures, even though this is only 10% of farmland fertilizer applications (Figure 1). Load targets will not be met without reductions from agriculture. Therefore, the overall goal of this study was to identify potential options for agricultural management to reduce phosphorus loads and lessen future HABs in Lake Erie. We applied multiple watershed models to test the ability of a series of land management scenarios, developed in consultation with agricultural and environmental stakeholders, to reach the proposed targets.

Indiana, Michigan, Ohio↗

USGS2004

Integrated investigations of environmental effects of historical mining in the Basin and Boulder Mining Districts, Boulder River watershed, Jefferson County, Montana

The Boulder River watershed is one of many watersheds in the western United States where historical mining has left a legacy of acid mine drainage and elevated concentrations of potentially toxic trace elements. Abandoned mine lands commonly are located on or affect Federal land. Cleaning up these Federal lands will require substantial investment of resources. As part of a cooperative effort with Federal land-management agencies, the U.S. Geological Survey implemented an Abandoned Mine Lands Initiative in 1997. The goal of the initiative was to use the watershed approach to develop a strategy for gathering and communicating the scientific information needed to formulate effective and cost-efficient remediation of affected lands in a watershed. The watershed approach is based on the premise that contaminated sites that have the most profound effect on water and ecosystem quality within an entire watershed should be identified, characterized, and ranked for remediation. The watershed approach provides an effective means to evaluate the overall status of affected resources and helps to focus remediation at sites where the most benefit will be gained in the watershed. Such a large-scale approach can result in the collection of extensive information on the geology and geochemistry of rocks and sediment, the hydrology and water chemistry of streams and ground water, and the diversity and health of aquatic and terrestrial organisms. During the assessment of the Boulder River watershed, we inventoried historical mines, defined geological conditions, assessed fish habitat, collected and chemically analyzed hundreds of water and sediment samples, conducted toxicity tests, analyzed fish tissue and indicators of physiological malfunction, examined invertebrates and biofilm, and defined hydrological regimes. Land- and resource-management agencies are faced with evaluating risks associated with thousands of potentially harmful mine sites, and this level of effort is not always feasible for every affected watershed. The detailed work described in this report can help Federal land-management agencies decide which characterization efforts would be most useful in characterization of other affected watersheds.

Montana↗

USGS2017

Science programs in Kansas

The U.S. Geological Survey (USGS) is a non-regulatory Earth science agency within the Department of the Interior that provides impartial scientific information to describe and understand the health of our ecosystems and environment; minimize loss of life and property from natural disasters; manage water, biological, energy, and mineral resources; and enhance and protect our quality of life. The USGS cooperates with Federal, State, tribal, and local agencies in Kansas to deliver long-term data in real-time and interpretive reports describing what those data mean to the public and resource management agencies. USGS science programs in Kansas provide real-time groundwater monitoring at more than 19 locations; streamflow monitoring at more than 216 locations; water-quality and trends in the Little Arkansas and Kansas Rivers; inflows and outflows of sediment to/from reservoirs and in streams; harmful algal bloom research in the Kansas River, Milford Lake, and Cheney Reservoir; water-quantity and water-quality effects of artificial groundwater recharge for the Equus Beds Aquifer Storage and Recovery project near Wichita, Kansas; compilation of Kansas municipal and irrigation water-use data statewide; the occurrence, effects, and movement of environmental pesticides, antibiotics, algal toxins, and taste-and-odor compounds; and funding to the Kansas Water Resources Research Institute to further research and education through Kansas universities.

Kansas↗

USGS2004

Quality of ground water for selected municipal water supplies in Iowa, 1997–2002 water years

The Iowa ground-water-quality monitoring program has been conducted cooperatively since 1982 by the Iowa Department of Natural Resources, Iowa Geological Survey; the University of Iowa Hygienic Laboratory; and the U.S. Geological Survey. The original objectives of the program were to provide baseline ground-water-quality data throughout the State for the major aquifers and to address any new areas of water-quality concern. Since the program began, the emphasis and objectives of the program have changed several times. As of 1992, greater emphasis has been placed on determining trends in ground-water quality and correlating water quality with possible contributing factors such as location, land use, aquifer, aquifer depth, and precipitation. From 1997 through 2002, a total of 471 samples of untreated water have been collected from 154 municipal wells throughout Iowa. The samples, collected from six different aquifers, consisted of 192 alluvial aquifer samples (36 wells), 79 Pleistocene aquifer samples (16 wells), 52 Cretaceous aquifer samples (35 wells), 48 Carboniferous aquifer samples (30 wells), 54 Silurian-Devonian aquifer samples (19 wells), and 46 Cambrian-Ordovician aquifer samples (18 wells). Some samples had concentrations greater than or equal to the respective Maximum Contaminant Levels for drinking water established by the U.S. Environmental Protection Agency. Of 471 samples analyzed, 19 samples had concentrations greater than or equal to the Maximum Contaminant Level for sulfate; 31 samples had concentrations greater than or equal to the Maximum Contaminant Level for nitrite plus nitrate; 257 samples had concentrations greater than or equal to the Secondary Maximum Contaminant Level for iron; and 249 samples had concentrations greater than or equal to the Secondary Maximum Contaminant Level for manganese. Of the 443 samples analyzed for pesticides, 87 samples had concentrations greater than or equal to the respective minimum reporting levels for the parent compounds, 30 samples had concentrations greater than or equal to the respective minimum reporting levels for pesticide metabolites, and 26 samples had detectable concentrations (censored values) less than the minimum reporting levels. Concentrations of alachlor, atrazine, cyanazine, and metolachlor accounted for about 90 percent of the samples equal to or exceeding the respective minimum reporting levels for pesticides. No samples had pesticide concentrations greater than the respective Maximum Contaminant or Health Advisory Levels. The compact disc included with this report has information about water-quality properties and concentrations of dissolved solids, major ions, nutrients, trace elements, radionuclides, total organic carbon, pesticides, and synthetic organic compounds for water years 1997 through 2002.

Iowa↗

USGS2018

Coastal effects

The Coasts chapter of the Third National Climate Assessment, published in 2014, focused on coastal lifelines at risk, economic disruption, uneven social vulnerability, and vulnerable ecosystems. This Coastal Effects chapter of the Fourth National Climate Assessment updates those themes, with a focus on integrating the socioeconomic and environmental impacts and consequences of a changing climate. Specifically, the chapter builds on the threat of rising sea levels exacerbating tidal and storm surge flooding, the state of coastal ecosystems, and the treatment of social vulnerability by introducing the implications for social equity. U.S. coasts are dynamic environments and economically vibrant places to live and work. As of 2013, coastal shoreline counties were home to 133.2 million people, or 42% of the population. The coasts are economic engines that support jobs in defense, fishing, transportation, and tourism industries; contribute substantially to the U.S. gross domestic product; and serve as hubs of commerce, with seaports connecting the country with global trading partners. Coasts are home to diverse ecosystems such as beaches, intertidal zones, reefs, seagrasses, salt marshes, estuaries, and deltas that support a range of important services including fisheries, recreation, and coastal storm protection. U.S. coasts span three oceans, as well as the Gulf of Mexico, the Great Lakes, and Pacific and Caribbean islands. The social, economic, and environmental systems along the coasts are being affected by climate change. Threats from sea level rise (SLR) are exacerbated by dynamic processes such as high tide and storm surge flooding (Ch. 19: Southeast, KM 2) , erosion (Ch. 26: Alaska, KM 2) , waves and their effects, saltwater intrusion into coastal aquifers and elevated groundwater tables (Ch. 27: Hawaiʻi & Pacific Islands, KM 1; Ch. 3: Water, KM 1) , local rainfall (Ch. 3: Water, KM 1) , river runoff (Ch. 3: Water, KM 1) , increasing water and surface air temperatures (Ch. 9: Oceans, KM 3) , and ocean acidification (see Ch. 2: Climate, KM 3 and Ch. 9: Oceans, KM 1, 2, and 3 for more information on ocean acidification, hypoxia, and ocean warming) . Although storms, floods, and erosion have always been hazards, in combination with rising sea levels they now threaten approximately $1 trillion in national wealth held in coastal real estate and the continued viability of coastal communities that depend on coastal water, land, and other resources for economic health and cultural integrity (Ch. 15: Tribes, KM 1 and 2) .

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USGS2012

Application of empirical predictive modeling using conventional and alternative fecal indicator bacteria in eastern North Carolina waters

Coastal and estuarine waters are the site of intense anthropogenic influence with concomitant use for recreation and seafood harvesting. Therefore, coastal and estuarine water quality has a direct impact on human health. In eastern North Carolina (NC) there are over 240 recreational and 1025 shellfish harvesting water quality monitoring sites that are regularly assessed. Because of the large number of sites, sampling frequency is often only on a weekly basis. This frequency, along with an 18–24 h incubation time for fecal indicator bacteria (FIB) enumeration via culture-based methods, reduces the efficiency of the public notification process. In states like NC where beach monitoring resources are limited but historical data are plentiful, predictive models may offer an improvement for monitoring and notification by providing real-time FIB estimates. In this study, water samples were collected during 12 dry (n = 88) and 13 wet (n = 66) weather events at up to 10 sites. Statistical predictive models for Escherichiacoli (EC), enterococci (ENT), and members of the Bacteroidales group were created and subsequently validated. Our results showed that models for EC and ENT (adjusted R2 were 0.61 and 0.64, respectively) incorporated a range of antecedent rainfall, climate, and environmental variables. The most important variables for EC and ENT models were 5-day antecedent rainfall, dissolved oxygen, and salinity. These models successfully predicted FIB levels over a wide range of conditions with a 3% (EC model) and 9% (ENT model) overall error rate for recreational threshold values and a 0% (EC model) overall error rate for shellfish threshold values. Though modeling of members of the Bacteroidales group had less predictive ability (adjusted R 2 were 0.56 and 0.53 for fecal Bacteroides spp. and human Bacteroides spp., respectively), the modeling approach and testing provided information on Bacteroidales ecology. This is the first example of a set of successful statistical predictive models appropriate for assessment of both recreational and shellfish harvesting water quality in estuarine waters.

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