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At least 1,531 records · Page 85Linked to original sources
USGS2003

Differences in native soil ecology associated with invasion of the exotic annual chenopod, Halgeton glomeratus

Various biotic and abiotic components of soil ecology differed significantly across an area where Halogeton glomeratus is invading a native winterfat, [ Krascheninnikovia (= Ceratoides ) lanata ] community. Nutrient levels were significantly different among the native, ecotone, and exotic-derived soils. NO 3 , P, K, and Na all increased as the cover of halogeton increased. Only Ca was highest in the winterfat area. A principal components analysis, conducted separately for water-soluble and exchangeable cations, revealed clear separation between halogeton- and winterfat-derived soils. The diversity of soil bacteria was highest in the exotic, intermediate in the ecotone, and lowest in the native community. Although further studies are necessary, our results offer evidence that invasion by halogeton alters soil chemistry and soil ecology, possibly creating conditions that favor halogeton over native plants.

Biology and Fertility of Soils↗
USGS2010

Zircon-scale insights into the history of a Supervolcano, Bishop Tuff, Long Valley, California, with implications for the Ti-in-zircon geothermometer

Zircon has the outstanding capacity to record chronological, thermal, and chemical information, including the storage history of zoned silicic magma reservoirs like the one responsible for the Bishop Tuff of eastern California, USA. Our novel ion microprobe approach reveals that Bishop zircon rims with diverse chemical characteristics surround intermediate domains with broadly similar compositions. The highest Y, REE, U, and Th concentrations tend to accompany the largest excesses in Y + REE3+:P beyond what can be explained by xenotime substitution in zircon. Apparent Ti-in-zircon temperatures of <720??C for zircon rims are distinctly lower than most of the range in eruption temperatures, as estimated from FeTi-oxide equilibria and zircon solubility at quench. While permissive of crystallization of zircon at near-solidus conditions, the low Ti-in-zircon temperatures are probably better explained by sources of inaccuracy in the temperature estimates. After apparently nucleating from different melts, zircons from across the Bishop Tuff compositional spectrum may have evolved to broadly similar chemical and thermal conditions and therefore it is possible that there was no significant thermal gradient in the magma reservoir at some stage in its evolution. There is also no compelling evidence for punctuated heat ?? chemical influxes during the intermediate stages of zircon growth. Judging by the zircon record, the main volume of the erupted magma evolved normally by secular cooling but the latest erupted portion is characterized by a reversal in chemistry that appears to indicate perfusion of the magma reservoir by-or zircon entrainment in-a less evolved melt from the one in which the zircons had previously resided. ?? 2010 Springer-Verlag.

Contributions to Mineralogy and Petrology↗
USGS2019

Unravelling the complexity of magma plumbing at Mount St. Helens: A new trace element partitioning scheme for amphibole

Volcanoes at subduction zones reside above complex magma plumbing systems, where individual magmatic components may originate and interact at a range of pressures. Because whole-rock compositions of subduction zone magmas are the integrated result of processes operating throughout the entire plumbing system, processes such as mixing, homogenisation and magma assembly during shallow storage can overprint the chemical signatures of deeper crustal processes. Whereas melt inclusions provide an effective way to study the uppermost 10–15 km of the plumbing system, challenges remain in understanding magma intrusion, fractionation and hybridisation processes in the middle to lower crust (15–30 km depth), which commonly involves amphibole crystallisation. Here, we present new insights into the mid-crustal plumbing system at Mount St. Helens, USA, using multiple regression methods to calculate trace element partition coefficients for amphibole phenocrysts, and thus infer the trace element compositions of their equilibrium melts. The results indicate vertically distributed crystal fractionation, dominated by amphibole at higher pressures and in intermediate melts, and by plagioclase at lower pressures. Variations in Nb, Zr and REE concentrations at intermediate SiO 2 contents suggest repeated scavenging of partially remelted intrusive material in the mid-crust, and mixing with material from geochemically diverse sources. Amphibole is an effective probe for deep crustal magmatism worldwide, and this approach offers a new tool to explore the structure and chemistry of arc magmas, including those forming plutonic or cumulate materials that offer no other constraints on melt composition.

Contributions to Mineralogy and Petrology↗
USGS2003

Nitrogen limitation of growth and nutrient dynamics in a disturbed mangrove forest, Indian River Lagoon, Florida

The objectives of this study were to determine effects of nutrient enrichment on plant growth, nutrient dynamics, and photosynthesis in a disturbed mangrove forest in an abandoned mosquito impoundment in Florida. Impounding altered the hydrology and soil chemistry of the site. In 1997, we established a factorial experiment along a tree-height gradient with three zones, i.e., fringe, transition, dwarf, and three fertilizer treatment levels, i.e., nitrogen (N), phosphorus (P), control, in Mosquito Impoundment 23 on the eastern side of Indian River. Transects traversed the forest perpendicular to the shoreline, from a Rhizophora mangle -dominated fringe through an Avicennia germinans stand of intermediate height, and into a scrub or dwarf stand of A. germinans in the hinterland. Growth rates increased significantly in response to N fertilization. Our growth data indicated that this site is N-limited along the tree-height gradient. After 2 years of N addition, dwarf trees resembled vigorously growing saplings. Addition of N also affected internal dynamics of N and P and caused increases in rates of photosynthesis. These findings contrast with results for a R. mangle -dominated forest in Belize where the fringe is N-limited, but the dwarf zone is P-limited and the transition zone is co-limited by N and P. This study demonstrated that patterns of nutrient limitation in mangrove ecosystems are complex, that not all processes respond similarly to the same nutrient, and that similar habitats are not limited by the same nutrient when different mangrove forests are compared.

Florida↗
USGS2013

Decomposition and nitrogen dynamics of 15 N-labeled leaf, root, and twig litter in temperate coniferous forests

Litter nutrient dynamics contribute significantly to biogeochemical cycling in forest ecosystems. We examined how site environment and initial substrate quality influence decomposition and nitrogen (N) dynamics of multiple litter types. A 2.5-year decomposition study was installed in the Oregon Coast Range and West Cascades using 15 N-labeled litter from Acer macrophyllum, Picea sitchensis, and Pseudotsuga menziesii. Mass loss for leaf litter was similar between the two sites, while root and twig litter exhibited greater mass loss in the Coast Range. Mass loss was greatest from leaves and roots, and species differences in mass loss were more prominent in the Coast Range. All litter types and species mineralized N early in the decomposition process; only A. macrophyllum leaves exhibited a net N immobilization phase. There were no site differences with respect to litter N dynamics despite differences in site N availability, and litter N mineralization patterns were species-specific. For multiple litter × species combinations, the difference between gross and net N mineralization was significant, and gross mineralization was 7–20 % greater than net mineralization. The mineralization results suggest that initial litter chemistry may be an important driver of litter N dynamics. Our study demonstrates that greater amounts of N are cycling through these systems than may be quantified by only measuring net mineralization and challenges current leaf-based biogeochemical theory regarding patterns of N immobilization and mineralization.

Oecologia↗
USGS2013

Litter quality versus soil microbial community controls over decomposition: a quantitative analysis

The possible effects of soil microbial community structure on organic matter decomposition rates have been widely acknowledged, but are poorly understood. Understanding these relationships is complicated by the fact that microbial community structure and function are likely to both affect and be affected by organic matter quality and chemistry, thus it is difficult to draw mechanistic conclusions from field studies. We conducted a reciprocal soil inoculum × litter transplant laboratory incubation experiment using samples collected from a set of sites that have similar climate and plant species composition but vary significantly in bacterial community structure and litter quality. The results showed that litter quality explained the majority of variation in decomposition rates under controlled laboratory conditions: over the course of the 162-day incubation, litter quality explained nearly two-thirds (64 %) of variation in decomposition rates, and a smaller proportion (25 %) was explained by variation in the inoculum type. In addition, the relative importance of inoculum type on soil respiration increased over the course of the experiment, and was significantly higher in microcosms with lower litter quality relative to those with higher quality litter. We also used molecular phylogenetics to examine the relationships between bacterial community composition and soil respiration in samples through time. Pyrosequencing revealed that bacterial community composition explained 32 % of the variation in respiration rates. However, equal portions (i.e., 16 %) of the variation in bacterial community composition were explained by inoculum type and litter quality, reflecting the importance of both the meta-community and the environment in bacterial assembly. Taken together, these results indicate that the effects of changing microbial community composition on decomposition are likely to be smaller than the potential effects of climate change and/or litter quality changes in response to increasing atmospheric CO 2 concentrations or atmospheric nutrient deposition.

Oecologia↗
USGS2014

Pyroclast textural variation as an indicator of eruption column steadiness in andesitic Plinian eruptions at Mt. Ruapehu

Between 27 and 11 cal. ka BP, a transition is observed in Plinian eruptions at Mt. Ruapehu, indicating evolution from non-collapsing (steady and oscillatory) eruption columns to partially collapsing columns (both wet and dry). To determine the causes of these variations over this eruptive interval, we examined lapilli fall deposits from four eruptions representing the climactic phases of each column type. All eruptions involve andesite to basaltic andesite magmas containing plagioclase, clinopyroxene, orthopyroxene and magnetite phenocrysts. Differences occur in the dominant pumice texture, the degree of bulk chemistry and textural variability, the average microcrystallinity and the composition of groundmass glass. In order to investigate the role of ascent and degassing processes on column stability, vesicle textures were quantified by gas volume pycnometry (porosity), X-ray synchrotron and computed microtomography (μ-CT) imagery from representative clasts from each eruption. These data were linked to groundmass crystallinity and glass geochemistry. Pumice textures were classified into six types (foamy, sheared, fibrous, microvesicular, microsheared and dense) according to the vesicle content, size and shape and microlite content. Bulk porosities vary from 19 to 95 % among all textural types. Melt-referenced vesicle number density ranges between 1.8 × 10 2 and 8.9 × 10 2 mm −3 , except in fibrous textures, where it spans from 0.3 × 10 2 to 53 × 10 2 mm −3 . Vesicle-free magnetite number density varies within an order of magnitude from 0.4 × 10 2 to 4.5 × 10 2 mm −3 in samples with dacitic groundmass glass and between 0.0 and 2.3 × 10 2 mm −3 in samples with rhyolitic groundmass. The data indicate that columns that collapsed to produce pyroclastic flows contained pumice with the greatest variation in bulk composition (which overlaps with but extends to slightly more silicic compositions than other eruptive products); textures indicating heterogeneous bubble nucleation, progressively more complex growth history and shear-localization; and the highest degrees of microlite crystallization, most evolved melt compositions and lowest relative temperatures. These findings suggest that collapsing columns in Ruapehu have been produced when strain localization is prominent, early bubble nucleation occurs and variation in decompression rate across the conduit is greatest. This study shows that examination of pumice from steady phases that precede column collapse may be used to predict subsequent column behaviour.

Mt. Ruapehu↗
USGS2022

The centenary of IAVCEI 1919–2019 and beyond: The people, places, and things of volcano geodesy

Over the first century of the International Association of Volcanology and Chemistry of the Earth’s Interior (IAVCEI), volcano geodesy grew from roots as an accidental and incidental system of measurements to an important method for monitoring volcanic activity and forecasting eruptions. The first practitioners in volcano geodesy were experts in other disciplines, and it was not until the latter half of the twentieth century that specialists in the field emerged—scientists who developed new methods, measured geodetic change at volcanoes, and quantitatively interpreted the results in terms of magmatic processes. Much of the early work in the field was restricted to a few volcanoes and involved techniques that had been adapted from other applications; relatively few methods were developed specifically for use on volcanoes. These volcanoes, however, provided the natural laboratories needed to advance the field. By the start of the twenty-first century, geodetic studies, especially using space-based techniques, contributed to the recognition of deformation and gravity change at hundreds of volcanoes on Earth. In coming years, IAVCEI researchers will focus on comprehensive exploitation of the growing volumes of geodetic data to better model, forecast, and track activity at volcanoes worldwide. Meanwhile, the field needs to become more diverse, better representing people who live in the shadows of volcanoes around the globe.

Bulletin of Volcanology↗
USGS2025

Utilizing crystal records to determine the underlying architecture and timescales of magmatic processes during the 2022 Mauna Loa eruption

Details of Mauna Loa’s plumbing system and magma storage dynamics are relatively poorly constrained, relative to nearby Kīlauea volcano. Recent studies have begun to address this gap in knowledge using geophysical imaging or olivine-focused petrology. Here, we use the crystal cargo from the 2022 summit and Northeast Rift Zone eruption to advance our understanding of Mauna Loa’s storage regions and pre˗eruptive processes. We identify textural and geochemical populations of olivine, orthopyroxene, clinopyroxene, and plagioclase macrocrysts as well as evolved glomerocrysts consisting of orthopyroxene, clinopyroxene, and plagioclase. Summit versus rift zone trends can be distinguished between specific crystal populations and are used to infer magma transfer pathways. Melt inclusion barometry from three orthopyroxene populations indicate crystallization depths of ~2–3 km which coincide with previous olivine˗hosted fluid inclusion barometry across Mauna Loa’s recent 200˗yr eruptive history. We combine orthopyroxene˗hosted melt inclusion barometry with diffusion chronometry on the same crystals using Fe˗Mg interdiffusion to estimate timescales of mixing and recharge prior to the eruption. Summit orthopyroxene yield timescales of weeks to months, aligning with geophysically recognized pre˗eruptive intrusion events and previously determined olivine timescales. Northeast Rift Zone orthopyroxene crystals have resorbed cores and yield short pre˗eruptive mixing timescales on the order of hours to days. Chemistry and timescales from the orthopyroxene populations suggest some of the 2022 magmas may have bypassed the shallowest portions of the summit reservoir system and were transferred directly into the rift zone syn˗eruptively.

Hawaii↗
USGS1996

Differentiation and magma mixing on Kilauea's east rift zone: A further look at the eruptions of 1955 and 1960. Part II. The 1960 lavas

New and detailed petrographic observations, mineral compositional data, and whole-rock vs glass compositional trends document magma mixing in lavas erupted from Kilauea's lower east rift zone in 1960. Evidence includes the occurrence of heterogeneous phenocryst assemblages, including resorbed and reversely zoned minerals in the lavas inferred to be hybrids. Calculations suggest that this mixing, which is shown to have taken place within magma reservoirs recharged at the end of the 1955 eruption, involved introduction of four different magmas. These magmas originated beneath Kilauea's summit and moved into the rift reservoirs beginning 10 days after the eruption began. We used microprobe analyses of glass to calculate temperatures of liquids erupted in 1955 and 1960. We then used the calculated proportions of stored and recharge components to estimate the temperature of the recharge components, and found those temperatures to be consistent with the temperature of the same magmas as they appeared at Kilauea's summit. Our studies reinforce conclusions reached in previous studies of Kilauea's magmatic plumbing. We infer that magma enters shallow storage beneath Kilauea's summit and also moves laterally into the fluid core of the East rift zone. During this process, if magmas of distinctive chemistry are present, they retain their chemical identity and the amount of cooling is comparable for magma transported either upward or laterally to eruption sites. Intrusions within a few kilometers of the surface cool and crystallize to produce fractionated magma. Magma mixing occurs both within bodies of previously fractionated magma and when new magma intersects a preexisting reservoir. Magma is otherwise prevented from mixing, either by wall-rock septa or by differing thermal and density characteristics of the successive magma batches.

Bulletin of Volcanology↗
USGS1998

Tephra-fall deposits from the 1992 eruption of Crater Peak, Alaska: implications of clast textures for eruptive processes

The 1992 eruption of Crater Peak, Mount Spurr, Alaska, involved three subplinian tephra-producing events of similar volume and duration. The tephra consists of two dense juvenile clast types that are identified by color, one tan and one gray, of similar chemistry, mineral assemblage, and glass composition. In two of the eruptive events, the clast types are strongly stratified with tan clasts dominating the basal two thirds of the deposits and gray clasts the upper one third. Tan clasts have average densities between 1.5 and 1.7 g/cc and vesicularities (phenocryst free) of approximately 42%. Gray clasts have average densities between 2.1 and 2.3 g/cc, and vesicularities of approximately 20%; both contain abundant microlites. Average maximum plagioclase microlite lengths (13-15 ??m) in gray clasts in the upper layer are similar regardless of eruptive event (and therefore the repose time between them) and are larger than average maximum plagioclase microlite lengths (9-11 ???m) in the tan clasts in the lower layer. This suggests that microlite growth is a response to eruptive processes and not to magma reservoir heterogeneity or dynamics. Furthermore, we suggest that the low vesicularities of the clasts are due to syneruptive magmatic degassing resulting in microlitic growth prior to fragmentation and not to quenching of clasts by external groundwater.

Bulletin of Volcanology↗
USGS1999

Kilauea summit overflows: Their ages and distribution in the Puna District, Hawai'i

The tube-fed pahoehoe lava flows covering much of the northeast flank of Kilauea Volcano are named the 'Aila'au flows. Their eruption age, based on published and six new radiocarbon dates, is approximately AD 1445. The flows have distinctive paleomagnetic directions with steep inclinations (40??-50??) and easterly declinations (0??-10??E). The lava was transported ~40 km from the vent to the coast in long, large-diameter lava tubes; the longest tube (Kazumura Cave) reaches from near the summit to within several kilometers of the coast near Kaloli Point. The estimated volume of the 'Aila'au flow field is 5.2 ?? 0.8 km3, and the eruption that formed it probably lasted for approximately 50 years. Summit overflows from Kilauea may have been nearly continuous between approximately AD 1290 and 1470, during which time a series of shields formed at and around the summit. The 'Aila'au shield was either the youngest or the next to youngest in this series of shields. Site-mean paleomagnetic directions for lava flows underlying the 'Aila'au flows form only six groups. These older pahoehoe flows range in age from 2750 to <18,000 BP, and the region was inundated by lava flows only three times in the past 5000 years. The known intervals between eruptive events average ~1600 years and range from ~1250 years to >2200 years. Lava flows from most of these summit eruptions also reached the coast, but none appears as extensive as the 'Aila'au flow field. The chemistry of the melts erupted during each of these summit overflow events is remarkably similar, averaging approximately 6.3 wt.% MgO near the coast and 6.8 wt.% MgO near the summit. The present-day caldera probably formed more recently than the eruption that formed the 'Aila'au flows (estimated termination ca. AD 1470). The earliest explosive eruptions that formed the Keanakako'i Ash, which is stratigraphically above the 'Aila'au flows, cannot be older than this age.

Bulletin of Volcanology↗
USGS2018

Serum proteins in healthy and diseased Florida manatees (Trichechus manatus latirostris)

A major goal of this study was to determine whether serum protein fractions of healthy Florida manatees differ with age, sex, or living environments (wild versus housed). A second goal was to determine which serum protein fractions vary in diseased versus healthy manatees. Serum protein fractions were determined using agarose gel electrophoresis. Healthy adults had slightly higher total serum protein and total globulin concentrations than younger animals. This largely resulted from an increase in gamma globulins with age. Total serum protein, albumin, alpha-1 globulin, beta globulin, and total globulin concentrations were slightly higher in housed manatees compared to wild manatees, but there was no significant difference in the albumin/globulin (A/G) ratio, suggesting a difference in hydration between these groups. No significant differences were attributable to sex or pregnancy. Serum albumin concentrations and A/G ratios were significantly lower for manatees with boat trauma, entanglements, emaciation, or cold stress compared to healthy manatees. Variable increases were seen in alpha-1globulins, alpha-2 globulins, beta globulins, and gamma globulins. These globulin fractions contain positive acute-phase proteins and immunoglobulins, and their increases may reflect acute or chronic active inflammation. Changes in serum protein fractions were not consistent enough to justify the use of serum protein electrophoresis as a routine diagnostic test for manatees. However, serum (or plasma) protein electrophoresis is required when accurate values for albumin and globulins are needed in manatees and in determining which protein fractions may account for a hyperproteinemia or hypoproteinemia reported in a clinical chemistry panel.

Comparative Clinical Pathology↗
USGS2001

Isotope geochemistry and fluid inclusion study of skarns from Vesuvius

We present new mineral chemistry, fluid inclusion, stable carbon and oxygen, as well as Pb, Sr, and Nd isotope data of Ca-Mg-silicate-rich ejecta (skarns) and associated cognate and xenolithic nodules from the Mt. Somma-Vesuvius volcanic complex, Italy. The typically zoned skarn ejecta consist mainly of diopsidic and hedenbergitic, sometimes "fassaitic" clinopyroxene, Mg-rich and Ti-poor phlogopite, F-bearing vesuvianite, wollastonite, gehlenite, meionite, forsterite, clinohumite, anorthite and Mg-poor calcite with accessory apatite, spinell, magnetite, perovskite, baddeleyite, and various REE-, U-, Th-, Zr- and Ti-rich minerals. Four major types of fluid inclusions were observed in wollastonite, vesuvianite, gehlenite, clinopyroxene and calcite: a) primary silicate melt inclusions (THOM = 1000-1050??C), b) CO2 ?? H2S-rich fluid inclusions (THOM = 20-31.3??C into the vapor phase), c) multiphase aqueous brine inclusions (THOM = 720-820??C) with mainly sylvite and halite daughter minerals, and d) complex chloride-carbonate-sulfate-fluoride-silicate-bearing saline-melt inclusions (THOM = 870-890??C). The last inclusion type shows evidence for immiscibility between several fluids (silicate melt - aqueous chloride-rich liquid - carbonate/sulfate melt?) during heating and cooling below 870??C. There is no evidence for fluid circulation below 700??C and participation of externally derived meteoric fluids in skarn formation. Skarns have considerably variable 206Pb/204Pb (19.047-19.202), 207Pb/204Pb (15.655-15.670), and 208Pb/204Pb (38.915-39.069) and relatively low 143Nd/144Nd (0.51211-0.51244) ratios. The carbon and oxygen isotope compositions of skarn calcites (??13CV-PDB = -5.4 to -1.1???; ??18OV-SMOW = 11.7 to 16.4???) indicate formation from a 18O- and 13C-enriched fluid. The isotope composition of skarns and the presence of silicate melt inclusion-bearing wollastonite nodules suggests assimilation of carbonate wall rocks by the alkaline magma at moderate depths (< 5 km) and consequent exsolution of CO2-rich vapor and complex saline melts from the contaminated magma that reacted with the carbonate rocks to form skarns.

Mineralogy and Petrology↗
USGS2002

A Geochemical Trophic Cascade in Yellowstone's Geothermal Environments

We contrast the geochemistry of the Madison drainage, which has high concentrations of geothermal features, with the Lamar drainage of Yellowstone National Park, USA, and trace the consequences of geochemical differences through abiotic and biotic linkages in the ecosystem. Waters in the geothermal-dominated drainage contained anomalously high levels of fluoride (F) and silica (SiO 2 ). Soils, stream sediments, and surface waters that interact or mix with geothermal waters, in turn, had elevated F and SiO 2 concentrations compared to similar samples from the Lamar drainage. The geochemical differences were reflected in the chemistry of forage plants, with some plants from geothermally influenced areas containing four- to eightfold higher concentrations of F and SiO 2 than similar plants in the Lamar drainage. Geothermal heat reduced snowpack, and we found that elk (Cervus elaphus) concentrated in these refugia as snowpack increased each winter. The consequent high dietary intake of F in animals associated with the geothermal areas was confirmed by the finding that bone samples from elk living in the Madison drainage contained sixfold higher concentrations of F than samples collected from animals wintering in the Lamar drainage. High F exposure resulted in compromised dentition due to fluoride toxicosis, which was undoubtedly exacerbated by the abrasive action of silica. The consequent accelerated and aberrant tooth wear resulted in early onset of senescence, reduced life span, and an abbreviated age structure. We speculate that these altered demographics, combined with spatial heterogeneity of snowpack, will result in increased vulnerability of this large herbivore population to wolf predation and less resiliency to compensate demographically for predation.

Wyoming↗
USGS2007

Dissolved organic carbon in Alaskan boreal forest: Sources, chemical characteristics, and biodegradability

The fate of terrestrially-derived dissolved organic carbon (DOC) is important to carbon (C) cycling in both terrestrial and aquatic environments, and recent evidence suggests that climate warming is influencing DOC dynamics in northern ecosystems. To understand what determines the fate of terrestrial DOC, it is essential to quantify the chemical nature and potential biodegradability of this DOC. We examined DOC chemical characteristics and biodegradability collected from soil pore waters and dominant vegetation species in four boreal black spruce forest sites in Alaska spanning a range of hydrologic regimes and permafrost extents (Well Drained, Moderately Well Drained, Poorly Drained, and Thermokarst Wetlands). DOC chemistry was characterized using fractionation, UV-Vis absorbance, and fluorescence measurements. Potential biodegradability was assessed by incubating the samples and measuring CO2 production over 1 month. Soil pore water DOC from all sites was dominated by hydrophobic acids and was highly aromatic, whereas the chemical composition of vegetation leachate DOC varied significantly with species. There was no seasonal variability in soil pore water DOC chemical characteristics or biodegradability; however, DOC collected from the Poorly Drained site was significantly less biodegradable than DOC from the other three sites (6% loss vs. 13-15% loss). The biodegradability of vegetation-derived DOC ranged from 10 to 90% loss, and was strongly correlated with hydrophilic DOC content. Vegetation such as Sphagnum moss and feathermosses yielded DOC that was quickly metabolized and respired. In contrast, the DOC leached from vegetation such as black spruce was moderately recalcitrant. Changes in DOC chemical characteristics that occurred during microbial metabolism of DOC were quantified using fractionation and fluorescence. The chemical characteristics and biodegradability of DOC in soil pore waters were most similar to the moderately recalcitrant vegetation leachates, and to the microbially altered DOC from all vegetation leachates.

Alaska↗
USGS2008

Plant response to nutrient availability across variable bedrock geologies

We investigated the role of rock-derived mineral nutrient availability on the nutrient dynamics of overlying forest communities (Populus tremuloides and Picea engelmanni-Abies lasiocarpa v. arizonica) across three parent materials (andesite, limestone, and sandstone) in the southern Rocky Mountains of Colorado. Broad geochemical differences were observed between bedrock materials; however, bulk soil chemistries were remarkably similar between the three different sites. In contrast, soil nutrient pools were considerably different, particularly for P, Ca, and Mg concentrations. Despite variations in nutrient stocks and nutrient availability in soils, we observed relatively inflexible foliar concentrations and foliar stoichiometries for both deciduous and coniferous species. Foliar nutrient resorption (P and K) in the deciduous species followed patterns of nutrient content across substrate types, with higher resorption corresponding to lower bedrock concentrations. Work presented here indicates a complex plant response to available soil nutrients, wherein plant nutrient use compensates for variations in supply gradients and results in the maintenance of a narrow range in foliar stoichiometry. ?? 2008 Springer Science+Business Media, LLC.

Ecosystems↗
USGS2002

Interactions between groundwater and surface water: The state of the science

The interactions between groundwater and surface water are complex. To understand these interactions in relation to climate, landform, geology, and biotic factors, a sound hydrogeoecological framework is needed. All these aspects are synthesized and exemplified in this overview. In addition, the mechanisms of interactions between groundwater and surface water (GW-SW) as they affect recharge-discharge processes are comprehensively outlined, and the ecological significance and the human impacts of such interactions are emphasized. Surface-water and groundwater ecosystems are viewed as linked components of a hydrologic continuum leading to related sustainability issues. This overview concludes with a discussion of research needs and challenges facting this evolving field. The biogeochemical processes within the upper few centimeters of sediments beneath nearly all surface-water bodies (hyporheic zone) have a profound effect on the chemistry of the water interchange, and here is where most of the recent research has been focusing. However, to advance conceptual and other modeling of GW-SW systems, a broader perspective of such interactions across and between surface-water bodies is needed, including multidimensional analyses, interface hydraulic characterization and spatial variability, site-to-region regionalization approaches, as well as cross-disciplinary collaborations.

Hydrogeology Journal↗