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At least 1,531 records · Page 85Linked to original sources
USGS1983

Hafnium isotope results from mid-ocean ridges and Kerguelen

176Hf/177Hf ratios are presented for oceanic volcanics representing both extremes of the range of mantle HfNdSr isotopic variation. Hf from critical mid-ocean ridgebasalts shows that 176Hf/177Hf does indeed have a greater variability than 143Nd/144Nd and 87Sr/86Sr in the depleted mantle. This extra variation is essentially of a random nature, and can perhaps be understood in terms of known Rb/SrSm/NdLu/Hf fractionation relationships. At the other extreme of mantle isotopic composition, 176Hf/177Hf ratios for igneous rocks from the Indian Ocean island of Kerguelen show a closely similar variation to published 143Nd/144Nd ratios for the same samples. Comparison of HfNdSr c relationships for Tristan da Cunha, Kerguelen and Samoa reveals divergences in the mantle array for ocean island magma sources, and perhaps suggests that these irregularities are largely the result of an extra component of 87Sr/86Sr variation. ?? 1983.

LITHOS↗
USGS1981

Lower Eocene alluvial paleosols (Willwood Formation, Northwest Wyoming, U.S.A.) and their significance for paleoecology, paleoclimatology, and basin analysis

The lower Eocene Willwood Formation of northwest Wyoming is a 700 m thick accumulation of alluvial floodplain and channel mudstones and sandstones, nearly all of which show paleopedogenic modifications. Pedogenesis of Willwood sandstones is indicated by taproot and vertebrate and invertebrate bioturbation, early local cementation by calcium carbonate, and thin illuviation cutans on clastic grains. Pedogenesis in Willwood mudstones is indicated by plant bioturbation, insect and other invertebrate burrow casts and lebensspuren; free iron, aluminum, and manganese mobilization, including hydromorphic gleying; sesquioxide and calcareous glaebule formation in lower parts of the solum; presence of clay-rich and organic carbon-rich zones; and well differentiated epipedons and albic and spodic horizons. Probable A horizons are also locally well developed. Occurrence of variegated paleosol units in thick floodplain mudstone deposits and their association with thin, lenticular, and unconnected fluvial sandstones in the Willwood Formation of the central and southeast Bighorn Basin suggest that these soils formed during times of rapid sediment accumulation. The tabular geometry and lateral persistence of soil units as well as the absence of catenization indicate that Willwood floodplains were broad and essentially featureless. All Willwood paleosols were developed on alluvial parent materials and are complex in that B horizons of younger paleosols were commonly superimposed upon and mask properties of suspected A and B horizons of the next older paleosols. The soils appear to be wet varieties of the Spodosol and Entisol groups (aquods and ferrods, and aquents, respectively), though thick, superposed and less mottled red, purple, and yellow paleosols resemble some ultisols. Most Willwood paleosols resemble warm temperate to subtropical alluvial soils that form today under alternating wet and dry conditions and (or) fluctuating water tables. The up-section decrease in frequency of gley mottles, increase in numerical proportion and thickness of red versus orange coloration, and increase in abundance of calcrete glaebules indicate better drained soils and probably drier climate in late Willwood time. This drying is believed to be related to creation of rain shadows and spacing of rainfall (but not necessarily decrease in absolute rainfall) due to progressive tectonic structural elevation of the mountainous margins of the Bighorn Basin.

Wyoming↗
USGS1992

Effect of membrane filtration artifacts on dissolved trace element concentrations

Among environment scientists, the current and almost universally accepted definition of dissolved constituents is an operational one-only those materials which pass through a 0.45-μm membrane filter are considered to be dissolved. Detailed laboratory and field studies on Fe and Al indicate that a number of factors associated with filtration, other than just pore size, can substantially alter “dissolved” trace element concentrations; these include: filter type, filter diameter, filtration method, volume of sample processed, suspended sediment concentration, suspended sediment grain-size distribution, concentration of colloids and colloidally-associated trace elements and concentration of organic matter. As such, reported filtered-water concentrations employing the same pore size filter may not be equal. Filtration artifacts may lead to the production of chemical data that indicate seasonal or annual “dissolved” chemical trends which do not reflect actual environmental conditions. Further, the development of worldwide averages for various dissolved chemical constituents, the quantification of geochemical cycles, and the determination of short- or long-term environmental chemical trends may be subject to substantial errors, due to filtration artifacts, when data from the same or multiple sources are combined. Finally, filtration effects could have a substantial impact on various regulatory requirements.

Georgia↗
USGS1992

Selenium and other elements in freshwater fishes from the irrigated San Joaquin valley, California

Arsenic (As), chromium (Cr), mercury (Hg), and selenium (Se) were measured in composite whole-body samples of five fishes — bluegill ( Lepomis macrochirus ), common carp ( Cyprinus carpio ), mosquitofish ( Gambusia affinis ), largemouth bass ( Micropterus salmoides ), and Sacramento blackfish ( Orthodon microlepidotus ) — from the San Joaquin River system to determine if concentrations were elevated from exposure to agricultural subsurface (tile) drainage. Except for Cr, the concentrations of these elements in fishes from one or more sites were elevated; however, only Se approached concentrations that may adversely affect survival, growth, or reproduction in warm water fishes. Moreover, only Se among the four measured elements exhibited a geographic (spatial) pattern that coincided with known inflows of tile drainage to the San Joaquin River and its tributaries. Historical data from the Grassland Water District (Grasslands; a region exposed to concentrated tile drainage) suggested that concentrations of Se in fishes were at maximum during or shortly after 1984 and have been slightly lower since then. The recent decline of Se concentrations in fishes from the Grasslands could be temporary if additional acreages of irrigated lands in this portion of the San Joaquin Valley must be tile-drained to protect agricultural crops from rising groundwater tables

California↗
USGS1980

Reproductive success and nest attentiveness of mallard ducks fed Aroclor 1254

A dietary dosage of 25 ppm Aroclor 1254 fed to nine-month-old mallards Anas platyrhynchos for at least a month before egg-laying had no detrimental effect on reproductive success or nest attentiveness when hens were allowed to incubate their own eggs. The treatment caused no effect on number of hens laying, date of first egg laid or clutch size. Fertility of eggs was greater among Aroclor-treated birds (87·7%) than among controls (73·2%). Aroclor may have stimulated males to come into reproductive condition sooner than controls. Hatching of fertile eggs and survival of ducklings to 3 weeks of age were similar in treated and control groups. The number of times off the nest per day and total time off the nest per day were the same for control and Aroclor-treated hens in days 14–17 of incubation.

Environmental Pollution (Series A)↗
USGS1994

Thermal history of the periphery of the Junggar Basin, Northwestern China

Geochemical analysis of rock core samples show that the basin periphery has experienced low thermal stress; present-day heat flows are in the range of 25–35 mW/m 2 and have not been significantly higher than the worldwide mean of approx. 63 mW/m 2 since the mid-Permian. Present day heat flows were determined from corrected borehole temperatures and rock thermal conductivities. Paleo-heat flows were determined by first-order reaction kinetic modeling of several geochemical paleothermometers (vitrinite reflectance, clay mineral diagenesis and relative proportions of sterane and hopane biological marker diastereomers).

Junggar Basin, northwestern China↗
USGS1990

Thrust-ridge paleodepositional model for the Upper Freeport coal bed and associated clastic facies, Upper Potomac coal field, Appalachian Basin, U.S.A.

A blind-thrust-ridge model is proposed to explain the lack of coarse clastic material in the vast minable Upper Freeport coal bed (UF). This coal bed contains only fine elastic partings and is overlain by regionally extensive, closely spaced channel-belt deposits in the Upper Potomac coal field of the Appalachian basin. A blind-thrust ridge may have formed a sediment trap and prevented c coarse fluvial sediments from entering the swamp during a period (Westphalian D) when the thick Upper Freeport peat accumulated. Anticlinal thrust ridges and associated depressions may have existed uninterrupted for about 40 km parallel to the Appalachian orogen. Sediment shed from the breached anticlinal ridges accumulated in the sediment trap and was carried out of the ends of the trap by streams that occupied the shear zone at the ends of the blind-thrust ridge. The extent, parallel to the orogen, of thick, areally extensive UF is related to the length of the blind-thrust ridge that, in turn, controlled the spacing of the river-derived coarse clastic sediments that entered the main basin from the east. The thrust plane eventually emerged to the surface of the blind-thrust ridge and peat accumulation was terminated when the ridge became eroded and the sediment trapped behind it was released. The peat was buried by abundant coarse clastic sediment, which formed closely spaced channel belts and intervening flood basins. This model has implications for widespread peat deposits (now coal) that developed in tropical regions a few hundred kilometers from the sea in a tectonically active foreland basin.

International Journal of Coal Geology↗
USGS1990

Organic geochemical studies of the transformation of gymnospermous xylem during peatification and coalification to subbituminous coal

Organic geochemical investigations of peatified and coalified xylem from gymnosperms have provided useful information on the organic transformational processes collectively known as coalification. The combined use of solid-state 13 C nuclear magnetic resonance (NMR) and pyrolysis/gas chromatography/mass spectrometry (py/gc/ms) has allowed us to examine the organic composition of peatified and coalified xylem on both a bulk (average) compositional basis and on a detailed molecular basis. We conclude from our studies that coalification of gymnospermous xylem involves the following processes1. (1) early selective removal of cellulosic materials so that lignin, a primary constituent of xylem, is transformed to macromolecular aromatic components in coal;2. (2) modification of gymnospermous lignin by demethylation to form catechol-like structures, and by condensation reactions to induce a high level of cross-linking at an early stage of coalification; and (3) dehydroxylation during increasing coalification to subbituminous coal, the resultant xylem becomes more phenolic in character as the catechol-like structures decrease.

International Journal of Coal Geology↗
USGS1990

Studies of angiospermous woods in Australian brown coal by nuclear magnetic resonance and analytical pyrolysis: new insight into early coalification

Many Tertiary coals contain abundant fossilized remains of angiosperms, which commonly dominated the ancient peat-swamp environments; modern analogs of such swamps can be found in tropical and subtropical regions of the world. Comparisons of angiospermous wood from Australian brown coal with similar wood buried in modern peat swamps of Indonesia have provided some new insights into coalification reactions. These comparisons were made by using solid-state 13 C nuclear magnetic resonance (NMR) techniques and pyrolsis-gas chromatography-mass spectrometry (py-gc-ms). These two modern techniques are especially suited for detailed structural evaluation of the complex macromolecules in coal. The earliest transformation (peatification) of organic matter in angiospermous wood is the degradation and removal of cellulosic components and the concomitant selective preservation of lignin-derived components. The angiospermous lignin that becomes enriched in wood as a result of cellulose degradation also is modified by coalification reactions; this modification, however, does not involve degradation and removal of the lignin. Rather, the early coalification process transforms the lignin phenols (guiacyl and syringyl) to eventually yield the aromatic structures typically found in brown coal. One such transformation, which is determined from NMR data, involves the cleavage of aryl-ether bonds that link guaiacyl and syringyl units in lignin, and this transformation leads to the formation of free lignin phenols. Another transformation, which is also determined from the NMR data, involves the loss of methoxyl groups, probably via demethylation, to produce catechol-like structures. Coincident with ether-cleavage and demethylation, the aromatic rings derived from lignin phenols become more carbon-substituted and cross linked, as determined by dipolar-dephasing NMR studies. This cross linking is probably responsible for preventing the lignin phenols, which are freed from the lignin macromolecule by ether cleavage, from being removed from the coal by dissolution. Pyrolysis data suggest that the syringyl units are altered more readily than are guaiacyl units, and this difference in resistance leads to an enrichment of the guaiacyl units in fossil angiospermous woods. Many of the coalification reactions noted above occur to some degree in all angiospermous fossil wood examined; however, some significant differences are observed in the degree of coalification of the fossil wood samples from the same burial depth in the brown coal. These differences indicate that the depth and duration of burial are probably not entirely responsible for the variations in degree of coalification. Different rates of degradation in peat may have contributed to the variations in the apparent degree of coalification; some woods may have been altered more rapidly at the peat stage than others. Although preliminary, this systematic study of botanically related wood in peat and coal results in a more detailed differentiation of coalification reactions than have previous investigations. The combined use of solid-state 13 C NMR and py-gc-ms has facilitated this detailed insight into the coalification of angiospermous wood.

International Journal of Coal Geology↗
USGS1984

Graphite sample preparation for AMS in a high pressure and temperature press

A high pressure-temperature press is used to make target material for accelerator mass spectrometry. Graphite was produced from typical **1**4C samples including oxalic acid and carbonates. Beam strength of **1**2C was generally adequate, but random radioactive contamination by **1**4C made age measurements impractical.

Nuclear Instruments and Methods in Physics Researc↗
USGS1991

Segmentation and the coseismic behavior of Basin and Range normal faults: examples from east-central Idaho and southwestern Montana, U.S.A.

The range-front normal faults of the Lost River and Lemhi Ranges, and the Beaverhead and Tendoy Mountains in east-central Idaho and southwestern Montana have well-preserved fault scarps on Quaternary deposits along much of their lengths. Fault-scarp morphology, the age of deposits displaced by the faults, and the morphology of the range fronts provide a basis for dividing the faults into segments that are typically 20–25 km long. The Lost River, Lemhi and Beaverhead fault zones are 141–151 km long, and each has six segments. The 60-km-long Red Rock fault (the range-front fault of the Tendoy Mountains) has two central segments that have been active in late Quaternary time; these two segments span the central 27 km of the fault. We recognize four characteristics that help to identify segment boundaries: (1) major en échelon offsets or pronounced gaps in the continuity of fault scarps; (2) distinct, persistent, along-strike changes in fault-scarp morphology that indicate different ages of faulting; (3) major salients in the range front; and (4) transverse bedrock ridges where the cumulative throw is low compared to other places along the fault zone. Only features whose size is measured on the scale of kilometers are regarded as significant enough to represent a segment boundary that could inhibit or halt a propagating rupture.

Journal of Structural Geology↗
USGS1995

Stratigraphic and palaeoenvironmental summary of the south-east Georgia embayment: a correlation of exploratory wells

A Continental Offshore Stratigraphic Test (COST) well and six exploratory wells have been drilled in the south-east Georgia embayment. The oldest rocks penetrated are weakly metamorphosed Lower Ordovician quartz arenites and Silurian shales and argillites in the Transco 1005-1 well and Upper Devonian argillites in the COST GE-1 well. These marine strata, which are equivalent to the Tippecanoe sequence in Florida, underlie the post-rift unconformity and represent part of a disjunct fragment of Gondwana that was sutured to the North American craton during the late Palaeozoic Alleghanian orogeny. The Palaeozoic strata are unconformably overlain by interbedded non-marine Jurassic (Bajocian and younger) sandstones and shales and marginal marine Lower Cretaceous sandstones, calcareous shales and carbonates, which contain scattered beds of coal and evaporite. Together, these rocks are stratigraphically equivalent to the onshore Fort Pierce and Cotton Valley(?) Formations and rocks of the Lower Cretaceous Comanchean Provincial Series. The abundance of carbonates and evaporites in this interval, which reflects marine influences within the embayment, increases upwards, eastwards and southwards. The Upper Cretaceous part of the section is composed mainly of neritic calcareous shales and shaley limestones stratigraphically equivalent to the primarily marginal marine facies of the onshore Atkinson, Cape Fear and Middendorf Formations and Black Creek Group, and to limestones and shales of the Lawson Limestone and Peedee Formations. Cenozoic strata are primarily semiconsolidated marine carbonates. Palaeocene to middle Eocene strata are commonly cherty; middle Miocene to Pliocene strata are massive and locally phosphatic and glauconitic; Quaternary sediments are dominated by unconsolidated carbonate sands. The effects of eustatic changes and shifts in the palaeocirculation are recorded in the Upper Cretaceous and Tertiary strata.

Georgia↗
USGS1989

Organochlorine contaminants in eggs of common terns from the Canadian Great Lakes, 1981

To determine if contaminant levels in Common Terns had changed over the last decade, we collected and analyzed eggs from four nesting colonies on the three lower Great Lakes during 1981. DDE and PCBs were detected in every egg from the four colonies. Dieldrin, mirex and trans -nonachlor were detected in more than 45% of the eggs. Seven other organochlorine contaminants (DDD, DDT, hexachlorobenzene, oxychlordane, cis -chlordane, cis -nonachlor and toxaphene) were detected in less than 25% of the eggs. Eggs from the Lake Ontario colony were generally the most heavily contaminated. Comparisons of DDE and PCB data with earlier studies of Common Terns indicated that contaminant levels in eggs from the four sampled colonies, or nearby sites, have decreased by up to 80–90% from 1969–1973 to 1981. Interspecies comparisons showed that Common Tern eggs have lower organochlorine residue levels than eggs of Caspian Terns or Herring Gulls. Dietary variation and migratory status are possible explanations for the differences in residue levels among species. Eggshell thickness, log-PCBs, and log-DDE were not significantly intercorrelated. Elevated contaminant levels in the early 1970s might be at least partly responsible for the decline of the Great Lakes Common Tern population over the past decade. Stabilization of population numbers during the early 1980s suggests that organochlorine pollution levels have been reduced to a point where they are no longer an important factor in the population dynamics of this species on the Great Lakes.

Fighting Island, Georgian Bay, Great Lakes, Lake E↗
USGS1990

Small mammal populations at hazardous waste disposal sites near Houston, Texas, USA

Small mammals were trapped, tagged and recaptured in 0?45 ha plots at six hazardous industrial waste disposal sites to determine if populations, body mass and age structures were different from paired control site plots. Low numbers of six species of small mammals were captured on industrial waste sites or control sites. Only populations of hispid cotton rats at industrial waste sites and control sites were large enough for comparisons. Overall population numbers, age structure, and body mass of adult male and female cotton rats were similar at industrial waste sites and control sites. Populations of small mammals (particularly hispid cotton rats) may not suffice as indicators of environments with hazardous industrial waste contamination.

Environmental Pollution↗
USGS1984

Chemical determination of particulate nitrogen in San Francisco Bay. Nitrogen: chlorophyll a rations in plankton

Particulate nitrogen (PN) and chlorophyll a (Chl a ) were measured in the northern reach of San Francisco Bay throughout 1980. The PN values were calculated as the differences between unfiltered and filtered (0&middot;4 &mu;m) samples analyzed using the UV-catalyzed peroxide digestion method. The Chl a values were measured spectrophotometrically, with corrections made for phaeopigments. The plot of all PNChla data was found to be non-linear, and the concentration of suspended particulate matter (SPM) was found to be the best selector for linear subsets of the data. The best-fit slopes of PNChla plots, as determined by linear regression (model II), were interpreted to be the N: Chl a ratios of phytoplankton. The Y -intercepts of the regression lines were considered to represent easily-oxidizable detrital nitrogen (EDN). In clear water ( < 10 mg l &minus;1 SPM), the N: Chl a ratio was 1&middot;07 &mu;g-at N per &mu;g Chl a . It decreased to 0&middot;60 in the 10&ndash;18 mg l &minus;1 range and averaged 0&middot;31 in the remaining four ranges (18&ndash;35, 35&ndash;65, 65&ndash;155, and 155&ndash;470 mg l &minus;1 ). The EDN values were less than 1 &mu;g-at N l &minus;1 in the clear water and increased monotonically to almost 12 &mu;g-at N l &minus;1 in the highest SPM range. The N: Chl a ratios for the four highest SPM ranges agree well with data for phytoplankton in light-limited cultures. In these ranges, phytoplankton-N averaged only 20% of the PN, while EDN averaged 39% and refractory-N 41%.

California↗
USGS1984

Chronology of late Wisconsinan glaciation in middle North America

We propose a chronology of late Wisconsinan glacial fluctuations in middle North America, from Alberta to Wisconsin, based on radiocarbon dates derived solely from wood. Previous chronologies of the southwestern margin of the North American Continental Ice Sheet have depended to a considerable degree on radiocarbon dates from fine-grained organic sediment. This material is commonly contaminated with older carbon, resulting in chronologic confusion. By using only dates from wood, much of the confusion disappears. However, because of the scarcity of wood dates, only four of the sixteen identified fluctuations are accurately dated: an advance into Iowa about 14,000 to 13,500 BP, an advance into South Dakota and Iowa about 12,300 BP, an advance into the Lake Michigan basin about 11,700 BP, and an advance into the Lake Superior basin about 9900 BP. In addition, the beginning of late Wisconsinan glaciation, before 20,000 BP, is fairly well documented. None of the fluctuations in the western part of the region are accurately dated.

middle North America↗