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Identifying water-quality trends in the Trinity River, Texas, USA, 1969-1992, using sediment cores from Lake Livingston

Chemical analyses were done on cores of bottom sediment from three locations in Lake Livingston, a reservoir on the Trinity River in east Texas to identify trends in water quality in the Trinity River using the chemical record preserved in bottom sediments trapped by the reservoir. Sediment cores spanned the period from 1969, when the reservoir was impounded, to 1992, when the cores were collected. Chemical concentrations in reservoir sediment samples were compared to concentrations for 14 streambed sediment samples from the Trinity River Basin and to reported concentrations for soils in the eastern United States and shale. These comparisons indicate that sediments deposited in Lake Livingston are representative of the environmental setting of Lake Livingston within the Trinity River Basin. Vertical changes in concentrations within sediment cores indicate temporal trends of decreasing concentrations of lead, sodium, barium, and total DDT (DDT plus its metabolites DDD and DDE) in the Trinity River. Possible increasing temporal trends are indicated for chlordane and dieldrin. Each sediment-derived trend is related to trends in water quality in the Trinity River or known changes in environmental factors in its drainage basin or both.

Texas↗

Preliminary results of the first scientific Drilling on Lake Baikal, Buguldeika site, southeastern Siberia

The Baikal Drilling Project (BDP) is a multinational effort to investigate the paleoclimatic history and tectonic evolution of the Baikal sedimentary basin during the Late Neogene. In March 1993 the Baikal drilling system was successfuly deployed from a barge frozen into position over a topographic high, termed the Buguldeika saddle, in the southern basin of Lake Baikal. The BDP-93 scientific team, made up of Russian, American and Japanese scientists, successfully recovered the first long (>100 m) hydraulic piston cores from two holes in 354 m of water. High quality cores of 98 m (Hole 1) and 102 m (Hole 2), representing sedimentation over the last 500,000 years, were collected in 78 mm diameter plastic liners with an average recovery of 72% and 90%, respectively. Magnetic susceptibility logging reveals an excellent hole-to-hole correlation. In this report the scientific team describes the preliminary analytical results from BDP-93 hole 1 cores. Radiocarbon dating by accelerator mass spectrometry provides an accurate chronology for the upper portion of Hole 1. Detailed lithologic characteristics, rock magnetic properties and inorganic element distributions show a significant change to the depositional environment occuring at 50 m subbottom depth, approximately 250,000 BP. This change may be due to uplift and rotation of the horst block in the Buguldeika saddle. The sedimentary section above 50 m is pelitic with varve-like laminae, whereas the section below 50 m contains a high proportion of sand and gravel horizons often organized into turbidite sequences. Accordingly, high resolution seismic records reveal a change in sonic velocity at this depth. It is inferred that sedimentation prior to 250 ka BP was from the west via the Buguldeika river system. After 250 ka BP the Buguldeika saddle reflects an increase in hemipelagic sediments admixed with fine-grained material from the Selenga River drainage basin, east of Lake Baikal. Variations in the spore-pollen assemblage, diatoms, biogenic silica content, rock magnetic properties, clay mineralogy and organic carbon in the upper 50 m of BDP-93-1 reveal a detailed record of climate change over approximately the last 250,000 years. These variables alternate in a pattern characteristic of glacial/interglacial climatic fluctuations. The present age model suggests that the climate signal recorded in Lake Baikal sediments is similar to Late Quaternary signals recorded in Chinese loess sections and in marine sediments.

Siberia↗

Final Laurentide ice-sheet deglaciation and Holocene climate-sea level change

Despite elevated summer insolation forcing during the early Holocene, global ice sheets retained nearly half of their volume from the Last Glacial Maximum, as indicated by deglacial records of global mean sea level (GMSL). Partitioning the GMSL rise among potential sources requires accurate dating of ice-sheet extent to estimate ice-sheet volume. Here, we date the final retreat of the Laurentide Ice Sheet with 10 Be surface exposure ages for the Labrador Dome, the largest of the remnant Laurentide ice domes during the Holocene. We show that the Labrador Dome deposited moraines during North Atlantic cold events at ∼10.3 ka, 9.3 ka and 8.2 ka, suggesting that these regional climate events helped stabilize the retreating Labrador Dome in the early Holocene. After Hudson Bay became seasonally ice free at ∼8.2 ka, the majority of Laurentide ice-sheet melted abruptly within a few centuries. We demonstrate through high-resolution regional climate model simulations that the thermal properties of a seasonally ice-free Hudson Bay would have increased Laurentide ice-sheet ablation and thus contributed to the subsequent rapid Labrador Dome retreat. Finally, our new 10 Be chronology indicates full Laurentide ice-sheet had completely deglaciated by 6.7 ± 0.4 ka, which re quires that Antarctic ice sheets contributed 3.6–6.5 m to GMSL rise since 6.3–7.1 ka.

Quaternary Science Reviews↗

Sedimentation Survey of Lago Guerrero, Puerto Rico, May 2001

Lago Guerrero, a small reservoir owned by the Puerto Rico Electric Power Authority, is part of the Isabela Hydroelectric System and is located in Aguadilla, in northwestern Puerto Rico. The reservoir had a storage capacity of about 127,376 cubic meters in May 2001 and a maximum depth of about 5.8 meters. Records on dam construction and original topography and storage capacity were not available; therefore, sedimentation rates could not be determined. However, Lago Guerrero resumably was constructed during the 1930?s because it receives water from lago Guajataca, which was constructed in 1928. The May 2001 bathymetric survey of Lago Guerrero established baseline data that are essential to calculate sedimentation rates, sediment yields, storage loss, and sediment deposition sites within the reservoir.

Water-Resources Investigations Report↗

National Gas Hydrate Program Expedition 01 offshore India; gas hydrate systems as revealed by hydrocarbon gas geochemistry

The National Gas Hydrate Program Expedition 01 (NGHP-01) targeted gas hydrate accumulations offshore of the Indian Peninsula and along the Andaman convergent margin. The primary objectives of coring were to understand the geologic and geochemical controls on the accumulation of methane hydrate and their linkages to underlying petroleum systems. Four areas were investigated: 1) the Kerala-Konkan Basin in the eastern Arabian Sea, 2) the Mahanadi and 3) Krishna-Godavari Basins in the western Bay of Bengal, and 4) the Andaman forearc Basin in the Andaman Sea. Upward flux of methane at three of the four of the sites cored during NGHP-01 is apparent from the presence of seafloor mounds, seismic evidence for upward gas migration, shallow sub-seafloor geochemical evidence of methane oxidation, and near-seafloor gas composition that resembles gas from depth. The Kerala-Konkan Basin well contained only CO 2 with no detectable hydrocarbons suggesting there is no gas hydrate system here. Gas and gas hydrate from the Krishna-Godavari Basin is mainly microbial methane with δ 13 C values ranging from −58.9 to −78.9‰, with small contributions from microbial ethane (−52.1‰) and CO 2 . Gas from the Mahanadi Basin was mainly methane with lower concentrations of C 2 -C 5 hydrocarbons (C 1 /C 2 ratios typically >1000) and CO 2 . Carbon isotopic compositions that ranged from −70.7 to −86.6‰ for methane and −62.9 to −63.7‰ for ethane are consistent with a microbial gas source; however deeper cores contained higher molecular weight hydrocarbon gases suggesting a small contribution from a thermogenic gas source. Gas composition in the Andaman Basin was mainly methane with lower concentrations of ethane to isopentane and CO 2, C 1 /C 2 ratios were mainly >1000 although deeper samples were <1000. Carbon isotopic compositions range from −65.2 to −80.7‰ for methane, −53.1 to −55.2‰ for ethane is consistent with mainly microbial gas sources, although one value recorded of −35.4‰ for propane suggests a thermogenic source. Gas hydrate accumulations in the Krishna-Godavari and Mahanadi Basins are the result of a microbially sourced gas hydrate system. The system is enhanced by the migration of microbial gas from surrounding areas through pathways including high-porosity delta sands, shale diapirism, faulting and folding of sediment due to the local processes associated with rapid sediment deposition, sediment overpressure, and the recycling of methane from a rapidly upward moving gas hydrate stability zone. The gas hydrate system in the Andaman Basin is less well constrained due to lack of exploration and occurs in a forearc basin. Each of these hydrate-bearing systems overlies and is likely supported by the presence and possible migration of gas from deeper gas-prone petroleum systems currently generating thermogenic hydrocarbons at much greater depths.

Marine and Petroleum Geology↗

A chemostratigraphic method to determine the end of impact-related sedimentation at marine-target impact craters (Chesapeake Bay, Lockne, Tvären)

To better understand the impact cratering process and its environmental consequences at the local to global scale, it is important to know when in the geological record of an impact crater the impact-related processes cease. In many instances, this occurs with the end of early crater modification, leaving an obvious sedimentological boundary between impactites and secular sediments. However, in marine-target craters the transition from early crater collapse (i.e., water resurge) to postimpact sedimentation can appear gradual. With the a priori assumption that the reworked target materials of the resurge deposits have a different chemical composition to the secular sediments we use chemostratigraphy (&delta; 13 C carb , %C org , major elements) of sediments from the Chesapeake Bay, Lockne, and Tv&auml;ren craters, to define this boundary. We show that the end of impact-related sedimentation in these cases is fairly rapid, and does not necessarily coincide with a visual boundary (e.g., grain size shift). Therefore, in some cases, the boundary is more precisely determined by chemostratigraphy, especially carbonate carbon isotope variations, rather than by visual inspection. It is also shown how chemostratigraphy can confirm the age of marine-target craters that were previously determined by biostratigraphy; by comparing postimpact carbon isotope trends with established regional trends.

Chesapeake Bay, Lockne crater, Tvären crater↗

Geomorphology, denudation rates, and stream channel profiles reveal patterns of mountain building adjacent to the San Andreas fault in northern California, USA

Relative horizontal motion along strike-slip faults can build mountains when motion is oblique to the trend of the strike-slip boundary. The resulting contraction and uplift pose off-fault seismic hazards, which are often difficult to detect because of the poor vertical resolution of satellite geodesy and difficulty of locating offset datable landforms in active mountain ranges. Sparse geomorphic markers, topographic analyses, and measurement of denudation allow us to map spatiotemporal patterns of uplift along the northern San Andreas fault. Between Jenner and Mendocino, California, emergent marine terraces found southwest of the San Andreas fault record late Pleistocene uplift rates between 0.20 and 0.45 mm yr –1 along much of the coast. However, on the northeast side of the San Andreas fault, a zone of rapid uplift (0.6–1.0 mm yr –1 ) exists adjacent to the San Andreas fault, but rates decay northeastward as the coast becomes more distant from the San Andreas fault. A newly dated 4.5 Ma shallow-marine deposit located at ∼500 m above sea level (masl) adjacent to the San Andreas fault is warped down to just 150 masl 15 km northeast of the San Andreas fault, and it is exposed at just 60–110 masl to the west of the fault. Landscape denudation rates calculated from abundance of cosmogenic radionuclides in fluvial sediment northeast of, and adjacent to, the San Andreas fault are 0.16–0.29 mm yr –1 , but they are only 0.03–0.07 mm yr –1 west of the fault. Basin-average channel steepness and the denudation rates can be used to infer the erosive properties of the underlying bedrock. Calibrated erosion rates can then be estimated across the entire landscape using the spatial distribution of channel steepness with these erosive properties. The lower-elevation areas of this landscape that show high channel steepness (and hence calibrated erosion rate) are distinct from higher-elevation areas with systematically lower channel steepness and denudation rates. These two areas do not appear to be coincident with lithologic contacts. Assuming that changes in rock uplift rates are manifest in channel steepness values as an upstream-propagating kinematic wave that separates high and low channel steepness values, the distance that this transition has migrated vertically provides an estimate of the timing of rock uplift rate increase. This analysis suggests that rock uplift rates along the coast changed from 0.3 to 0.75 mm yr –1 between 450 and 350 ka. This zone of recent, relatively rapid crustal deformation along the plate boundary may be a result of the impingement of relatively strong crust underlying the Gualala block into the thinner, weaker oceanic crust left at the western margin of the North American plate by the westward migration of the subduction zone prior to establishment of the current transform plate boundary. The warped Pliocene marine deposits and the presence of a topographic ridge support the patterns indicated by the channel steepness analyses, and further indicate that the zone of rapid uplift may herald elevated off-fault seismic hazard if this uplift is created by periodic stick-slip motion on contractional structures.

California↗

The San Francisco Estuary, USA as a reference section for an Anthropocene series

A San Francisco Estuary core was analysed at high resolution to assess its component stratigraphic signatures of the Anthropocene in the form of non-native species, Hg, spheroidal carbonaceous particles, δ 13 C org , δ 15 N, radiogenic materials, and heavy metals. Time series analysis of the core using Ti data provides a chronology to depth 167 cm into the 1960s. Below this, to depth 230 cm, the lowermost part of the core may extend to the 1950s or potentially a little earlier. The earliest anthropogenic marker recorded in the core is the excursion in Hg (beginning at 190 cm) which may denote the early 1960s and is the closest stratigraphic marker in the core to the proposed mid-20th century timing for the onset of the Anthropocene. Biostratigraphical signatures of non-native species arriving in the 1970s–1980s are widespread key markers and are significant tools for the correlation of Anthropocene deposits across the estuary. The absence of signals that indicate pre-1950s deposits precludes the use of the core to mark the Holocene–Anthropocene boundary. However, the core provides an important reference section to demonstrate the palaeontological distinctiveness of Anthropocene series deposits.

California↗

Geology and ground-water resources of the islands of Lanai and Kahoolawe, Hawaii

Lanai lies 59 miles southeast of Honolulu, Oahu, has an area of 141 square miles, and is 3,370 feet high. (See fig. 1 and pl. 1.) Lanai City is the only town of importance. The island produces pineapples and cattle. The surface above about 1,200 feet is generally covered with lateritic soil, which reaches a maximum depth of about 50 feet. Below this level the island is partly devoid of vegetation and is strewn with boulders, the result of having been once submerged by the ocean to this depth. Traces of various emerged and submerged shore lines are described, the highest fossiliferous marine deposits being 1,070 feet above sea level. Lanai is an eroded extinct basaltic volcano built during one period of activity. No secondary eruptions occurred as on most of the other islands. It has three rift zones and a summit caldera. The summit plateau has resulted from collapse along the northwest rift zone. Elsewhere there is much evidence of faulting. About 100 faults and 275 dikes were recorded, but they are so close together in places that it was not possible to show them all on the map. The climate is semitropical, the mean annual temperature of Lanai City, altitude 1,620 feet, being 68&deg; F. Because Lanai lies to the lee of Maui Island it is dry. The mean annual rainfall ranges from 38 inches on the summit to less than 10 inches on the coast. The windward (northeast) side is carved by streams into deep canyons. Maunalei Gulch has the only perennial stream, and it does not reach the sea. Ground water, the lifeblood of Lanai is scarce. Lanai City obtains some of its water supply by a tunnel from gravel in Maumalei Gulch. This water apparently rises from the dike complex in this gulch. The rest of the supply comes from a recently constructed shaft tapping the dike complex not far downstream. The total quantity of high-level ground water discharged by springs and tunnels ranges from about 600,000 gallons a day in wet weather to about 250,000 gallons a day in dry weather. The basal water, although potable, is fairly high in salt. Several sites are recommended for developing and conserving ground water. Kahoolawe Island is 11 miles long, 6 miles wide, 1,491 feet high, covers 45 square miles, and lies 94 miles southeast of Honolulu and 6 3 / 4 miles southwest of Maui. It is a shield-shaped extinct volcano composed chiefly of thin flows of primitive basalt poured in rapid succession from three rift zones and a vent at their intersection. At one stage the volcano was indented with a caldera about 3 miles across which was later completely filled. A graben led southwestward from it. The rocks are divided into Late Tertiary (?) or early Pleistocene(?) pre-caldera basalts, caldera-filling basalts and basaltic andesites, post-caldera basalts and andesites, and Recent post erosional basalts. A few thin vitric tuff beds and cinder cones were found. Marine erosion has cut cliffs as high as 800 feet along the east and south shores and exposed a cross section of the caldera. Only shallow ephemeral gulches exist. The entire summit has been eroded to a hard-pan surface by the wind as a result of the vegetation being destroyed by livestock. The island is semi-arid and well water is needed for stook: "The stook is now supplied entirely from storage of rain and flood waters. During droughts water is hauled by boat from the island of Maui. All the wells dug so far yield water that is too brackish for stock except at the fairly inaccessible south side of Kanapou Bay. The resistivity survey indicates a water table 1.5 feet or less above sea level for 2.25 miles inland. A few sites for wells are recommended in the dike complex where small supplies of water suitable for stock might be found. Petrographic studies by Gordon A. Macdonald indicate that the pre-caldera and caldera-filling lavas are largely normal olivine basalt of the type which forms the bulk of all Hawaiian volcanoes thus far investigated. It represents the undifferentiated magma of the Hawaiian petrographic province. Toward the close of the caldera-filling epoch the vent became less active, and magmatic differentiation produced basaltic andesites, which are interbedded with normal basalts. The post-caldera lavas are largely basaltic andesites and andesites. The much younger lavas, erupted after a period of extensive erosion, are olivine basalts similar in composition to the pre-caldera flows. The mineralogy of the Kahoolawe rocks is described in detail.

Hawaii↗

A 40,000-year woodrat-midden record of vegetational and biogeographical dynamics in north-eastern Utah

Aim A conspicuous climatic and biogeographical transition occurs at 40-45° N in western North America. This pivot point marks a north–south opposition of wet and dry conditions at interannual and decadal time-scales, as well as the northern and southern limits of many dominant western plant species. Palaeoecologists have yet to focus on past climatic and biotic shifts along this transition, in part because it requires comparisons across dissimilar records [i.e. pollen from lacustrine sediments to the north and plant macrofossils from woodrat ( Neotoma ) middens to the south]. To overcome these limitations, we are extending the woodrat-midden record northward into the lowlands of the central Rocky Mountains. Location Woodrat middens were collected from crevices and rock shelters on south-facing slopes of Dutch John Mountain (2000-2200 m, 40°57′ N, 109°25′ W), situated on the eastern flanks of the Uinta Mountains in north-eastern Utah. The site is near the regional limits for Pinus ponderosa, P. edulis, P. contorta, Cercocarpus ledifolius var. intricatus, Abies concolor, Ephedra viridis and other important western species. Methods We analysed pollen and plant macrofossils from the 40,000-year midden sequence. The middens represent brief, depositional episodes (mostly years to decades). Four middens represent the early to full-glacial period (40,000–18,000 cal-yr bp), eight middens are from the late-glacial/early Holocene transition (13,500–9000 cal yr bp), and 33 middens span the mid-to-late Holocene (last 7500 years). Temporal density of our Holocene middens (one every c. 210 years) is comparable with typical Holocene pollen sequences from lake sediments. Results Early to full-glacial assemblages are characterized by low diversity and occurrence of montane conifers ( Picea pungens, Pseudotsuga menziesii, P. flexilis, Juniperus communis ) absent from the site today. Diversity increases in the late-glacial samples with the addition of J. scopulorum, J. horizontalis, C. montanus, C. ledifolius var. intricatus and mesic understory species. The coniferous trees and J. communis declined and J. osteosperma appeared during the late-glacial/Holocene transition. Juniperus osteosperma populations have occupied the site throughout the Holocene. Pinus ponderosa was established by 7500 cal-yr bp, and has occurred at least locally ever since. Montane conifers and J. horizontalis persisted until c. 5500 cal-yr bp. The signature events of the late Holocene were the invasions of P. edulis and Ephedra viridis and establishment of pinyon–juniper woodland in the last 800 years. Main conclusions The Dutch John Mountain midden record adds to an emerging picture in which mid-elevation conifers ( P. flexilis, Pseudotsuga menziesii, Picea pungens, J. scopulorum, J. communis ) dominated vegetation over a wide area of the Colorado Plateau and adjacent Rocky Mountains. Rather than being fragmented, as often assumed in phylogeographical studies, these species had broader and more-connected distributions than they do in the region today. Paradoxically, subalpine conifers ( Picea engelmannii, A. lasiocarpa ) occurred at higher elevations to the south, possibly representing declining precipitation from south to north owing to southward displacement of the polar jet stream. The Dutch John Mountain record displays a series of extinction and invasion events. Most of the extinctions were local in scale; nearly all constituents of fossil midden assemblages occur within a few kilometres of Dutch John Mountain, and some occur at least locally on its slopes. The sole exception is J. horizontalis , which is regionally extinct. In contrast to extinctions, Holocene invasions were regional in scale; J. osteosperma, P. ponderosa, P. edulis and Ephedra viridis immigrated from glacial-age source populations far to the south.

Utah↗

Dating of river terraces along Lefthand Creek, western High Plains, Colorado, reveals punctuated incision

The response of erosional landscapes to Quaternary climate oscillations is recorded in fluvial terraces whose quantitative interpretation requires numerical ages. We investigate gravel-capped strath terraces along the western edge of Colorado's High Plains to constrain the incision history of this shale-dominated landscape. We use ¹⁰Be and ²⁶Al cosmogenic radionuclides (CRNs), optically stimulated luminescence (OSL), and thermally transferred OSL (TT-OSL) to date three strath terraces, all beveled in shale bedrock and then deposited upon by Lefthand Creek, which drains the crystalline core of the Front Range. Our study reveals: (i) a long history (hundreds of thousands of years) of fluvial occupation of the second highest terrace, T2 (Table Mountain), with fluvial abandonment at 92 ± 3 ka; (ii) a brief occupation of a narrow and spatially confined terrace, T3, at 98 ± 7 ka; and (iii) a 10–25 thousand year period of cutting and fluvial occupation of a lower terrace, T4, marked by the deposition of a lower alluvial unit between 59 and 68 ka, followed by deposition of an upper alluvial package at 40 ± 3 ka. In conjunction with other recent CRN studies of strath terraces along the Colorado Front Range (Riihimaki et al., 2006; Dühnforth et al., 2012), our data reveal that long periods of lateral planation and fluvial occupation of strath terraces, sometimes lasting several glacial-interglacial cycles, are punctuated by brief episodes of rapid vertical bedrock incision. These data call into question what a singular terrace age represents, as the strath may be cut at one time (its cutting-age) and the terrace surface may be abandoned at a much later time (its abandonment age), and challenge models of strath terraces that appeal to simple pacing by the glacial-interglacial cycles.

Colorado↗

Geology of the Southern Guadalupe Mountains, Texas

This report deals with an area of 425 square miles in the western part of Texas, immediately south of the New Mexico line. The area comprises the south end of the Guadalupe Mountains and the adjacent part of the Delaware Mountains; it includes the highest peaks in the State of Texas. The area is a segment of a large mountain mass that extends 50 miles or more northward and southward. The report describes the geology of the area, that is, the nature of its rocks, tectonics, and surface features, and the evidence that they give as to the evolution of the area through geologic time. Incidental reference is made to the geology of surrounding regions in order to place the area in its environment. The Permian system of the southwestern United States has been until recently one of the intriguing but little known subjects of American stratigraphy. In the latter half of the nineteenth century after the western. United States was settled, the "red bed" sections of the Permian were studied and reported on by many geologists, but up to 1920 the existence of a contemporaneous marine sequence in western Texas and southeastern New Mexico was little appreciated. Since that year the discovery of extensive oil fields and potash beds in this region gave an impetus to the study of the Permian rocks, and furnished the geologist with records of hundreds of drill holes from which to deduce the nature of the strata not exposed at the surface. At the same time geologists have studied the rocks in the outcropping areas, and have compared them with the strata encountered by drilling. Much remains to be done in order to understand the history of Permian time in the region. The physical and chemical conditions that caused. the deposition of .the various and often complexly related deposits need to be better understood. More of the fossils of the rich and interesting marine faunas should be described, and the relations of the fossils to their environments should be determined. Further, a satisfactory scheme of correlation is needed, and also a subdivision into series that will express the contemporaneity of strata in different areas. One useful contribution to the solution of these problems is the detailed study of sequences of rocks exposed at the surface in the different mountain ranges of Texas and New Mexico. This report deals with one such sequence of rocks in western Texas, the one exposed in the southern Guadalupe Mountains (fig. 1). Here, the Permian rocks are magnificently exposed, to a thickness of about 4,000 feet (pl. 1). They are all of marine origin, and belong to the middle part of the system, with the base concealed and the top absent. Overlying and underlying beds, however, are found in nearby areas.

Texas↗

60 Myr records of major elements and Pb-Nd isotopes from hydrogenous ferromanganese crusts: Reconstruction of seawater paleochemistry

We compare the time series of major element geochemical and Pb- and Nd-isotopic composition obtained for seven hydrogenous ferromanganese crusts from the Atlantic, Indian, and Pacific Oceans which cover the last 60 Myr. Average crust growth rates and age-depth relationships were determined directly for the last about 10 Myr using 10Be/9Be profiles. In the absence of other information these were extrapolated to the base of the crusts assuming constant growth rates and constant initial 10Be/9Be ratios due to the lack of additional information. Co contents have also been used previously to estimate growth rates in Co-rich Pacific and Atlantic seamount crusts (Puteanus and Halbach, 1988). A comparison of 10Be/9Be- and Co-based dating of three Co-rich crusts supports the validity of this approach and confirms the earlier chronologies derived from extrapolated 10Be/9Be-based growth rates back to 60 Ma. Our data show that the flux of Co into Co-poor crusts has been considerably lower. The relationship between growth rate and Co content for the Co-poor crusts developed from these data is in good agreement with a previous study of a wider range of marine deposits (Manheim, 1986). The results suggest that the Co content provides detailed information on the growth history of ferromanganese crusts, particularly prior to 10-12 Ma where the 10Be-based method is not applicable. The distributions of Pb and Nd isotopes in the deep oceans over the last 60 Myr are expected to be controlled by two main factors: (a) variations of oceanic mixing patterns and flow paths of water masses with distinct isotopic signatures related to major paleogeographic changes and (b) variability of supply rates or provenance of detrital material delivered to the ocean, linked to climate change (glaciations) or major tectonic uplift. The major element profiles of crusts in this study show neither systematic features which are common to crusts with similar isotope records nor do they generally show coherent relationships to the isotope records within a single crust. Consequently, any interpretation of time series of major element concentrations of a single crust in terms of paleoceanographic variations must be considered with caution. This is because local processes appear to have dominated over more basin-wide paleoceanographic effects. In this study Co is the only element which shows a relationship to Pb and Nd isotopes in Pacific crusts. A possible link to changes of Pacific deep water properties associated with an enhanced northward advection of Antarctic bottom water from about 14 Ma is consistent with the Pb but not with the Nd isotopic results. The self-consistent profiles of the Pb and Nd isotopes suggest that postdepositional diagenetic processes in hydrogenous crusts, including phosphatization events, have been insignificant for particle reactive elements such as Pb, Be, and Nd. Isotope time series of Pb and Nd show no systematic relationships with major element contents of the crusts, which supports their use as tracers of paleo-seawater isotopic composition.

Geochimica et Cosmochimica Acta↗

Vertical tectonics in northern Escanaba Trough as recorded by thick late Quaternary turbidites

Escanaba Trough, the southernmost segment of the Gorda Ridge, is filled by as much as 500 m of late Quaternary turbidite and hemipelagic sediment. Coring at Deep Sea Drilling Project Site 35 and Ocean Drilling Program (ODP) Sites 1037 and 1038 together with 4.5-kHz deep-tow and 3.5-kHz surface-ship seismic reflection profiles enable a distinct pattern of reflections to be mapped throughout Escanaba Trough in the upper part of this sediment fill. The uppermost 80 m of turbidite sediment, which includes at least 11 turbidity current events, were deposited in <7 kyr. Nine of these turbidites are found throughout Escanaba Trough at water depths >3200 m. The turbidity currents were trapped upon entering Escanaba Trough, resulting in all of the sediment in suspension in the flows being deposited. The thickness of the turbidite layers reflects both the flow thickness and the vertical grain concentration within the flow that deposited the layer. Variations in the turbidite thickness with respect to water depth can be used to estimate the degree of relative vertical movement within the floor of Escanaba Trough. In the area of hydrothermal activity near ODP Site 1038, uplift of as much as 140 m has occurred over the past 8 kyr.

California↗

40Ar/39Ar geochronology of magmatic-steam alunite from Alunite Ridge and Deer Trail Mountain, Marysvale Volcanic Field, Utah: Timing and duration of miocene hydrothermal activity associated with concealed intrusions

Porphyry and epithermal deposits are important sources of base and precious metals. Most actively mined deposits have been exhumed such that ore bodies are relatively close to the surface and are therefore locatable and economic to extract. Identifying and characterizing concealed deposits, particularly more deeply buried porphyry deposits, represents a far greater challenge for mineral exploration, and will become progressively more important as near-surface resources are gradually exhausted over time. We report high-precision 40 Ar/ 39 Ar dates for coarsely crystalline alunite that precipitated from magmatic steam in open fractures in Oligocene dacitic volcanic rocks, and a SHRIMP 206 Pb/ 238 U zircon date for one of several rhyolite dikes present at Alunite Ridge and Deer Trail Mountain, Utah. Both the magmatic-steam alunite and rhyolite dikes are related to concealed intrusions. The rhyolite dike yielded an age of 30.72 ± 0.36 Ma, which is older than a commonly cited 27.1 Ma age estimate for the Three Creeks Tuff Member of the Bullion Canyon Volcanics that is cut by the dike. 40 Ar/ 39 Ar data for samples of magmatic-steam alunite and sericite from six mines and prospects provide evidence for at least two periods of episodic hydrothermal activity at ca. 15.7–15.1 Ma and ca. 14.7–13.8 Ma, with the older and younger pulses of activity recorded at the more eastern and western sites, respectively. These two periods of hydrothermal activity are consistent with previous interpretations that Alunite Ridge and Deer Trail Mountain are underlain by two concealed porphyry stocks. 40 Ar/ 39 Ar analyses of individual bands in a sample of massive, centimeter-scale banded vein alunite yield indistinguishable ages with a weighted mean of 13.98 ± 0.12 Ma, consistent with a short-lived (≲250 ka) magmatic event with episodic vapor discharge recurring on short timescales (≲36 ka). 40 Ar/ 39 Ar geochronology of magmatic-steam alunite is a valuable tool to constrain the timing and duration of magmatic hydrothermal activity associated with unexposed intrusions and potentially porphyry deposits, and therefore may be useful in exploration.

Utah↗

A 450-year record of environmental change from Castle Lake, California (USA), inferred from diatoms and organic geochemistry

A 39-cm sediment core from Castle Lake, California (USA) spans the last ~ 450 years and was analyzed for diatoms and organic geochemistry (δ 15 N, δ 13 C, and C:N), with the goal of determining sensitivity to natural climate variation and twentieth century anthropogenic effects. Castle Lake is a subalpine, nitrogen-limited lake with ~ 5 months of annual ice cover. Human impacts include light recreational use, past fish stocking, and experimental use by the Castle Lake Research Station. The base of the core (below 32 cm; pre mid-1700s) represents the period of maximum ice cover. In contrast, the end of the Little Ice Age (mid 1700s–early 1800s) is dominated by cyclotelloids (mostly Discostella stelligera ), indicating significant open-water periods, a condition that persisted into the early 1900s. Cyclotelloids began to decline in the 1960s and were replaced by the Fragilaria tenera grp. (peak in 1970s), succeeded by Asterionella formosa (peak ~ 2010), and accompanied by a reduction in δ 15 N values and a decrease in C:N that may represent increased atmospheric nitrogen deposition. Another anthropogenic signal was discerned in the core and was interpreted to be the result of an ammonium nitrate fertilization experiment of the epilimnion that was conducted in 1980 and 1981. This signal was manifested in the core largely by a negative excursion in δ 15 N, possibly caused by fractionation during denitrification in surface sediment. A phytoplankton monitoring dataset collected by the Castle Lake Research Station from 1967 to 1984 corroborates the timing of increased araphid euplanktonic species in the 1970s, and increases in two benthic diatoms ( Staurosirella pinnata and Tabellaria fenestrata) , entrained in the phytoplankton tows during the experimentation years. Both ice cover and nitrogen addition appear to be strong drivers that affected the lake diatoms, although additional drivers, such as fish stocking and associated cascade effects need further exploration. These data will be helpful for interpreting longer core records from Castle Lake, should the opportunity arise, as well as cores from similar systems in the region.

California↗

Miocene evolution of the Humboldt Current

Diatom records from the East Pisco Basin (EPB) of southern Peru and offshore Ocean Drilling Program (ODP) Hole 682 A reveal stepwise increases in the primary productivity of the Humboldt Current during the middle and late Miocene. Although diatoms are present back through the late middle Eocene, successively enhanced diatom production occurs during the Miocene in four steps. The first step between 14.2 and 13.8 Ma marks the onset of diatom deposition in the Pisco-0 sequence. A second step at ∼12.9 Ma coincides with a major drop in global sea level during which diatom deposition ceased in the EPB but continued in ODP 682 A as well as in Chile, Ecuador, and Colombia. Beginning at 10.4 to 10.0 Ma, a major increase in diatom sedimentation rates in both the EPB and in ODP 682 A signals an abrupt intensification of the Humboldt Current productivity, which may be related to the closure of the Central American Seaway to deeper water circulation. A fourth step coincides with the transgressive deposition of the diatom-rich Pisco-2 sequence at 8.4 Ma and is enhanced by the onset of the global Late Miocene Biogenic Bloom (8.0–4.5 Ma). Between 7 and 6 Ma, common subtropical diatoms in ODP 682 A contrast with high diatom deposition rates in the EPB, suggesting variable El Niño-La Niña conditions. During this time, fossil vegetation evidence from southern Peru supports the presence of seasonal periods of enhanced rainfall typical of El Niño conditions. The Miocene trend of increasing sea mammal diversity in the EPB parallels these steps, further supporting stepwise enhancement of primary productivity in the Humboldt Current during the Miocene.

Humboldt Current↗

Overview of the Opportunity Mars Exploration Rover Mission to Meridiani Planum: Eagle Crater to Purgatory Ripple

The Mars Exploration Rover Opportunity touched down at Meridiani Planum in January 2004 and since then has been conducting observations with the Athena science payload. The rover has traversed more than 5 km, carrying out the first outcrop‐scale investigation of sedimentary rocks on Mars. The rocks of Meridiani Planum are sandstones formed by eolian and aqueous reworking of sand grains that are composed of mixed fine‐grained siliciclastics and sulfates. The siliciclastic fraction was produced by chemical alteration of a precursor basalt. The sulfates are dominantly Mg‐sulfates and also include Ca‐sulfates and jarosite. The stratigraphic section observed to date is dominated by eolian bedforms, with subaqueous current ripples exposed near the top of the section. After deposition, interaction with groundwater produced a range of diagenetic features, notably the hematite‐rich concretions known as “blueberries.” The bedrock at Meridiani is highly friable and has undergone substantial erosion by wind‐transported basaltic sand. This sand, along with concretions and concretion fragments eroded from the rock, makes up a soil cover that thinly and discontinuously buries the bedrock. The soil surface exhibits both ancient and active wind ripples that record past and present wind directions. Loose rocks on the soil surface are rare and include both impact ejecta and meteorites. While Opportunity's results show that liquid water was once present at Meridiani Planum below and occasionally at the surface, the environmental conditions recorded were dominantly arid, acidic, and oxidizing and would have posed some significant challenges to the origin of life.

Journal of Geophysical Research E: Planets↗