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Fingerprinting magmatic REE deposit sources with zircon petrochronology

Carbonatites and associated alkaline silicate rocks are of considerable economic interest due to their enrichments in rare earth elements. The petrogenesis and source(s) of these complexes, however, are poorly understood. Models propose either mantle plume-derived carbon-rich melts or a mantle source enriched by subduction-related metasomatism. We use zircon trace elements to fingerprint carbonatite-alkaline complex sources, focusing on the economically significant 1.4 Ga Mountain Pass intrusive suite (MPIS). Autocrystic zircon from MPIS alkaline silicate rocks are enriched in Th and U relative to Nb suggesting a subduction influenced, oxidized source region. Lower Sc/Yb, higher Ti concentrations, and the absence of Eu anomalies in autocrystic zircon suggest derivation from a less hydrous, hotter, and deeper mantle source relative to arc-related 1.8–1.6 Ga inherited zircon. These data are best explained by syn- to post-collisional Mesoproterozoic reactivation of a subduction-metasomatized mantle source. The source and tectonic setting of the MPIS contrasts with Mesoproterozoic Gifford Creek and Bayan Obo carbonatites which exhibit plume-like compositions and are associated with rifts, suggesting different sources and tectonic settings for these economically significant deposits. We demonstrate that zircon petrochronology is a robust method for distinguishing carbonatite sources and can inform more targeted exploration strategies for critical mineral resources.

Conference Paper

Aftershocks in stress shadows are inconsistent with modeled static Coulomb stress changes

Aftershock triggering is commonly attributed to increases in static Coulomb stress. In some areas, termed "stress shadows", a decrease in Coulomb stress is predicted to suppress earthquake occurrence. However, aftershocks are often observed in the modeled stress shadows. We examine several hypotheses that attempt to reconcile these shadow aftershocks with the static Coulomb stress change model: (1) they appear to be in shadows because of inaccuracy in the stress change calculations, (2) they occur on faults of unusual orientation which actually experienced increased Coulomb stress, (3) they occur on faults with different frictional properties, not modeled well by Coulomb stress, and (4) they are secondary aftershocks triggered by prior aftershocks or afterslip. When tested on the 2016 Mw7.0 Kumamoto, Japan, and 2019 Mw7.1 Ridgecrest, California, aftershock sequences, none of these hypotheses can explain the majority of the shadow aftershocks, and taken together these hypotheses can explain only about half of these aftershocks. This implies that Coulomb stress modeling that lacks small-scale fault zone heterogeneity might be inadequate to fully capture the true static stress changes and/or that other physical triggering models are needed, for example transient processes such as delayed triggering by dynamic stress changes from the passing seismic waves.

California

Quantifying groundwater response and uncertainty in beaver-influenced mountainous floodplains using machine learning-based model calibration

Beavers ( Castor canadensis ) alter river corridor hydrology by creating ponds and inundating floodplains, and thereby improving surface water storage. However, the impact of inundation on groundwater, particularly in mountainous alluvial floodplains with permeable gravel/cobble layers overlain by a soil layer, remains uncertain. Numerical modeling across various floodplain structures considers topographic and sediment complexity and multidirectional flow, linking inundation to groundwater response. This study develops a model-data integration workflow to address uncertainty in groundwater response to beaver-induced inundations in a mountainous alluvial floodplain in the Upper Colorado River Basin. Uncertain factors include seasonal hydrologic dynamics, hydraulic conductivities, floodplain structures, and meteorological forcings. We employed an ensemble of groundwater models, based on geophysical and hydrologic data, with machine learning-based calibration using a neural density estimator. This allowed us to quantify the vertical flux from the soil layer to the permeable gravel bed, the down-valley underflow within the gravel bed, and their ratios. Results show a significant increase in the vertical flux relative to down-valley underflow, from 2% during dry pond periods to 20% during wet periods, serving as an analogy for conditions without and with beaver ponds. The study highlights the influence of floodplain structure on groundwater storage, water balance, and water quality impacted by beaver ponds. A thick gravel bed layer, with a large down-valley underflow, minimizes the effect of beaver-induced inundation on water quality. We emphasize the need for field-scale measurements of floodplain structure and improved characterization of evapotranspiration changes to reduce uncertainty in groundwater response.

Colorado

Disparate groundwater responses to wildfire

Post-wildfire investigations of groundwater response reveal a range of outcomes, varying from substantial increases to notable decreases in recharge and baseflow, with some studies indicating negligible or short-lived effects. This review assesses these varied responses within five critical categories: climate, vegetation, hydrogeology, fire characteristics, and the cryosphere, examining both short-term (within 2 years) and intermediate (2–10 years post-fire) effects. Despite considerable variability, some consistent patterns emerge. For instance, in hydroclimatic settings where water input and evaporative demand cycles are out of sync, post-wildfire groundwater responses tend to be positive (i.e., increased flux or storage), whereas under low fire severity conditions or in vegetation types that quickly recover, groundwater responses tend to be negative (i.e., decreased flux or storage). We synthesize relevant findings into a compendium of testable hypotheses aimed at explaining the spatiotemporal variability in observed post-wildfire groundwater responses. A recurring theme is the critical influence of the pre-wildfire groundwater regime on expected response and recovery. We identify opportunities for specific improvements in post-wildfire monitoring and modeling that would further advance capabilities to predict groundwater response. A key area for further research is understanding how wildfire effects on snow dynamics and other cryospheric processes translate to changes in groundwater.

WIREs Water

Beyond optimality: Dryland ecosystems infrequently use water efficiently for carbon gain

Optimality theory assumes plants maximize carbon gain per unit water lost and is often implemented to scale leaf-level carbon gain and water use to regional and global scales. Optimality theory is often mathematically represented by assuming plant water-use efficiency (WUE) scales with VPD k , where k = ½ represents expected optimal behavior. It is unclear, however, if this relationship holds in arid and semi-arid ecosystems that are strongly impacted by soil and atmospheric moisture status. We used data from seven flux tower sites along an aridity gradient in New Mexico to answer: how does the relationship between WUE and VPD compare to expectations based on optimality theory? To address this question, we integrated the Dynamic Evapotranspiration Partitioning Approach for Rapid Timescales with a stochastic antecedent model to estimate ecosystem-level WUE (GPP/T) and the net sensitivity of WUE to VPD, or k Dynamic , which we compare to the theoretical optimal sensitivity of k = ½. Our results show that optimality theory is not always appropriate, and k Dynamic often deviates from ½, especially at some of the more arid sites or during periods of low soil moisture. At less arid, higher elevation sites, k Dynamic is most consistent with optimality theory at moderate VPD levels, but not at high VPD. In general, the sensitivity of WUE to VPD is highly variable such that k Dynamic exhibits notable daily and seasonal variability, suggesting highly dynamic stomatal behavior. These results emphasize that representing plant water-use strategies as dynamic in time and space is critical to improving large-scale estimates of plant water use.

New Mexico

Uncertainty and spatial correlation in station measurements for mb magnitude estimation

The body‐wave magnitude (⁠⁠) is a long‐standing network‐averaged, amplitude‐based magnitude used to estimate the magnitude of seismic sources from teleseismic observations. The U.S. Geological Survey National Earthquake Information Center (NEIC) relies on in its global real‐time earthquake monitoring mission. Although waveform modeling‐based moment magnitudes are the modern standard to characterize earthquake size, is important because (1) in many cases, waveform modeling is not possible (e.g., low signal‐to‐noise events), (2) is applicable over a broad range of magnitudes, ∼M 4–7, and (3) there is a many decades‐long history of estimating magnitudes. We use the NEIC Preliminary Determination of Epicenters earthquake catalog to investigate the uncertainty in NEIC station measurements. We show that measurements are spatially correlated, which can bias event ⁠, and we describe an empirical relation between this spatial correlation and station‐to‐station distance. We further describe an approach to mitigate bias from the spatial correlation. Accounting for the spatial covariance of observations can change the event from −0.15 to 0.07 units (10th to 90th percentile) for smaller events (⁠⁠). These smaller events have the largest standard deviations ranging from 0.05 to 0.15 units (10th to 90th percentile).

The Seismic Record

SlideDetect: Spatio-temporal landslide detection using a three-dimensional convolutional neural network

Landslides pose a serious and ongoing threat to both human lives and infrastructure worldwide; therefore, it is of interest to predict where and when landslides are likely to occur. Advances in machine learning techniques have spurred numerous studies aimed at estimating relative landslide propensity, but are limited to spatial (as opposed to temporal) prediction due to the sparsity of landslide timing data. We address this data gap by training SlideDetect, a 3-dimensional convolutional neural network (3D CNN), to identify landslides based on their spatial and temporal occurrence within multitemporal image stacks. We use an inventory of landsides triggered by the 2018 Hokkaido earthquake and two years of monthly composite optical imagery spanning this event. The model can identify not only landslide location but also landslide date with an area under the precision-recall curve (PR-AUC) of 0.84. We further present a new standard for presenting PR curve results that explicitly compares model performance at different confidence thresholds, allowing for clearer model evaluation and comparison. Our new approach to constraining landslide timing paired with this more consistent and objective method for evaluating model performance shows considerable promise, and with further application and testing, SlideDetect could enhance the data availability and tools needed to advance landslide hazard and risk assessments.

JGR Machine Learning and Computation

Roadway runoff induced acute mortality in juvenile coho salmon during spring storm events

Extensive mortalities of adult coho salmon ( Oncorhynchus kisutch ), often called “Urban Runoff Mortality Syndrome” (URMS), have been documented during the fall in creeks where water quality has been degraded by roadway runoff. The primary cause of mortality is 6PPD-quinone (6PPDQ; N -(1,3-dimethylbutyl)- N ′-phenyl- p -phenylenediamine quinone)–an ozone transformation product that forms on all vehicle tires. Laboratory studies have shown that juvenile coho salmon are highly sensitive to 6PPDQ exposure. Unlike adults, juveniles reside in impacted watersheds year-round, including during the spring when 6PPDQ concentrations can frequently exceed lethal thresholds during storms. To assess the potential incidence of URMS in springtime rearing habitats for juvenile coho salmon, we conducted a paired water quality and toxicology study at Miller Creek, a runoff-impacted watershed in Normandy Park, WA, USA. Using a small field facility, three naïve groups of juvenile coho salmon ( N = 720) were exposed to either creek water or groundwater ( N = 120 per treatment per storm), across three spring storms while comparing water quality and mortality end points. In creek water during exposures, peak 6PPDQ concentrations reached 73–110 ng/L, exceeding reported median lethal concentrations (LC 50 ) for coho salmon. Over each 24–73 h storm exposure period, ∼80% of Miller Creek-exposed juvenile salmon died. No mortality occurred among control fish exposed to groundwater. These results indicate previously unidentified mortality risks for juvenile life stages of coho salmon during spring storms, suggesting substantial and year-round water quality impediments to coho salmon health and recovery across roadway runoff-impacted spawning, rearing, and migratory habitats.

Washington

Integrating detrital magnetite geochemistry and (U-Th)/He chronometry as a sediment provenance tool in geologic and metallogenic terranes

Magnetite is ubiquitous in porphyry Cu systems and in sediment sourcing both barren and mineralized regions, with potential as an indicator mineral in concealed and coarsely-mapped terranes. We develop and test a workflow for integrated geochemistry and (U–Th)/He (He) dating for inferring detrital magnetite (DMt) provenance in these settings. The ca. 70 Ma Taurus porphyry Cu–Mo(–Au) district in eastern interior Alaska serves as a test case. DMt from streams draining porphyry-related mineralization was characterized by geochemistry and mineral inclusion and microstructure observations, complemented by similar data for potential porphyry and host rock sources. Principal component analysis and clustering of DMt geochemical data resolve multiple populations in our samples geochemically and texturally compatible with derivation from metamorphic, porphyry-related hydrothermal, and igneous sources. Hydrothermal magnetite comprises ∼16–50% of DMt nearest porphyry mineralization but diminishes to ∼4% ∼15 km downstream. Subsampled grains within populations yield ∼160–110 Ma, ∼70 Ma, ∼55 Ma, and ∼20 Ma magnetite He date modes. Combined with provenance, He dates capture Early Cretaceous regional exhumation of metamorphic host rock and Late Cretaceous porphyry Cu mineralization. DMt grains showing partial hematite replacement yield ca. 55–20 Ma dates regardless of source, overlapping regional warm/wet climatic intervals. We interpret Cenozoic dates to reflect exhumation to near-surface oxidizing conditions and(or) supergene weathering. Magnetite is thus a promising target phase for (1) tracking the spatiotemporal distribution of porphyry systems, and (2) linking the formation and exhumation of these systems to a regional geologic history, both in Alaska and globally.

Alaska, Yukon

Joint pilot fish habitat framework

This story map will take you through the process of exploring and testing methods necessary for a higher resolution, seamless fish habitat assessment across both inland and estuarine waters through the lens of our joint pilot assessment Fish habitat assessments attempt to relate past, current, or future landscape conditions to the state of fish species occurrence, distribution, abundance, or community and habitat condition in streams, rivers, or estuaries. Previous fish habitat assessments, such as the National Fish Habitat Assessment, conducted separate and disconnected assessments for inland waters and estuaries. In this project, National Oceanic and Atmospheric Administration ( NOAA ) and U.S. Geological Survey ( USGS ) researchers created a seamless spatial framework to allow assessments that integrate influences on fish habitat from headwaters to the estuary. This effort began when the Chesapeake Bay Program Fish Habitat Action Team expressed interest in a Baywide fish habitat assessment spanning tidal salt, tidal fresh, warm non-tidal, and cold non-tidal waters. However, the complexity of the myriad of implementation details to consider when developing such an assessment necessitated the need for a tributary-specific pilot assessment. To conduct this pilot assessment, a NOAA/USGS joint partnership was formed with cooperation and support from the Chesapeake Bay Agreement and Chesapeake Bay Fish Habitat Action Team (FHAT).

Maryland

Road salt collection and redistribution at an urban rain garden on sandy soil, Gary, Indiana

Rain gardens installed as green infrastructure to divert storm runoff from entering combined sewers also collect dissolved constituents and particulates. An urban rain garden in northwestern Indiana, USA, was continuously monitored from November 2019 to May 2021 to evaluate the fate of dissolved constituents entering the rain garden in runoff. Physical and chemical properties of soils in the rain garden were also monitored, along with underlying groundwater. Linear regression models relating specific conductance to chloride concentration indicated that the 0.0371-ha (3998 square feet) rain garden collected approximately 1490 kg (3285 pounds) of road salt from the surrounding 0.2228 ha (24,500 square feet) of impervious surfaces. Soils and groundwater were seasonally affected by road salt application but carryover from year to year was not indicated. Rain garden soil permeability (5.20 × 10 −5 to 9.72 × 10 −5 m/s) remained unchanged during the study period and soil organic carbon generally increased under native vegetation. The results suggest that a rain garden built on sandy soil can divert substantial quantities of runoff and dissolved constituents from combined sewers; however, chloride is transported to sub-infrastructure groundwater that eventually discharges to adjacent waterways with concentrations lower than those observed in runoff.

Indiana

Groundwater response to managed aquifer recharge at the Southeast Houghton Artificial Recharge Project in Tucson, Arizona

Managed aquifer recharge is a widespread practice for storing water in the subsurface as groundwater. At a managed aquifer recharge facility in southern Arizona, groundwater-level and repeat microgravity data were collected to monitor aquifer response. These data were used to inform parameter identification for an unsaturated-zone flow model used to simulate the recharge process. The facility, the Southeast Houghton Artificial Recharge Project (SHARP), consists of 3 surface basins (about 27,600 square meters [6.8 acres] total surface area) where recycled water is distributed in recharge cycles lasting several months, with dry periods in between. During the study period, December 2020–December 2022, Tucson Water (the City of Tucson’s water utility) reported 6.56×10 6 cubic meters of water (5,320 acre-feet) recharged. Monitoring included groundwater-level observations at 3 monitoring wells and repeat microgravity measurements at as many as 22 locations (some stations were destroyed between surveys). Six gravity surveys were carried out using absolute- and relative-gravity meters. Large gravity increases, more than 250 microgals, were observed during the first repeat survey, 3.5 months after the start of recharge, but only in the immediate vicinity of the recharge basins. Data show that water moved downward to the water table, and storage changes in the unsaturated zone away from the facility were likely minimal. Gravity decreased at stations more than 1 kilometer from the facility, consistent with regional groundwater-level changes. Groundwater-level increases in wells adjacent to the recharge basins began 2 months after the second repeat gravity survey, and 5.5 months after recharge began. Unsaturated-zone flow modeling was carried out using software that simulates water movement and parameter estimation. Model calibration was carried out by minimizing an objective function calculated from the differences between simulated and observed groundwater levels, and between simulated and observed repeat microgravity data. Including repeat microgravity data in the objective function reduced the uncertainty in estimated parameter values for saturated hydraulic conductivity and saturated water content. Modeling indicated that the unsaturated zone between the recharge basins and the water table does not become saturated even after 685 days of simulated infiltration. This gradual wetting may account for increasing infiltration rates over time, as hydraulic conductivity increases with increasing water content. Unsaturated-zone water content decreased rapidly between recharge cycles. Model-simulated groundwater mounding extended about 1 kilometer from the center of SHARP after the 685-day period following the onset of recharge.

Arizona

Plan to coordinate post-earthquake investigations supported by the National Earthquake Hazards Reduction Program (NEHRP)

Introduction This report presents a plan supported by the National Earthquake Hazards Reduction Program (NEHRP) to coordinate domestic and international post-earthquake investigations (herein called “the Plan”). Post-earthquake scientific and engineering investigations are undertaken to capture critical information to understand the causes and impacts of the event, lessons from which can substantially improve the Nation’s resilience after future earthquakes. NEHRP is the Federal Government’s coordinated nationwide program to reduce risks to life and property from earthquakes. The Plan describes the activation and coordination of the four designated NEHRP Agencies in the Federal Government: Federal Emergency Management Agency, National Institute of Standards and Technology, U.S. National Science Foundation, and U.S. Geological Survey (USGS). The Plan also describes coordination between NEHRP Agencies and other organizations that may participate in pre-event and post-earthquake investigations, including non-NEHRP Federal agencies; State, regional, local, Tribal, and territorial agencies; domestic nongovernmental organizations; academic institutions and affiliated organizations; private companies; foreign governmental agencies and nongovernmental organizations; and international organizations. The Plan delineates the coordination of NEHRP post-earthquake scientific and engineering investigations to document the direct, indirect, and cascading physical and societal impacts from fault rupture and ground shaking hazards and from secondary hazards such as landslides, liquefaction, and tsunamis. In addition, the Plan identifies pre-event activities necessary to ensure that post-earthquake investigations are executed effectively. The USGS is the lead NEHRP Agency for activating and coordinating NEHRP post-earthquake investigations and for implementing this Plan. The USGS also leads coordination of the NEHRP Agencies in completing the pre-event activities identified in the Plan. The Plan has new information and supersedes USGS Circular 1242, “The Plan to Coordinate NEHRP Post-Earthquake Investigations,” which was published in 2003. This second-generation Plan was developed with the assistance of the Applied Technology Council (ATC) of Redwood City, California, under USGS contract 140G0121P0309, ATC-155. A 17-member Project Review Panel provided guidance on plan development, and input was solicited from subject matter experts representing key stakeholder groups and from participants at a public workshop.

Circular

Smectite-rich horizons in Inceptisols trigger shallow landslides in tropical granitic terranes

Puerto Rico was affected by >70,000 landslides in the wake of 2017 Hurricane Maria, and landslide prevalence was especially high in the Utuado region in the Cordillera Central. Landslide density was highest where soil parent material is granodiorite; landslide slip surfaces tended to be shallow (<60 cm), and often were mobilized rapidly and with long runout distances. This study combines field observations with soil mineralogy (bulk and clay fractions), soil geochemistry (bulk fraction), and soil strength as determined by field cone penetrometer testing (CPT) to test the hypothesis that clay-rich subsoil horizons function as slip planes when water-logged. Soil pits were excavated to depths of ∼200 cm in Ultisols on an undulating plateau and to ∼100 cm in Inceptisols on steep slopes (36-43 o ) that flank the plateau and cone penetrometer tests (CPT) were done within 2 m of the soil pit. Six pits were located adjacent to scarps from previous landslides, enabling analysis of soil profiles downward through extrapolated slip surfaces. Results from X-ray diffraction (XRD), X-ray fluorescence (XRF) and thermogravimetric analysis (TGA) indicate that soils are heterogeneous, often with subsoil horizons enriched in clay minerals and immobile elements (Al, Fe, Ti). Inceptisols on steep slopes often contain smectite-rich horizons at 30–60 cm depth that appear to function as slip surfaces; in other Inceptisols, such horizons are not present and landslide susceptibility is potentially lower. In Ultisols, soil mineralogy is dominated by kaolinite with minor halloysite, and increased kaolinite content at soil depths ≥80 cm at some sites suggests potential slip surfaces enhancing probability of landslides. The origin of clay-rich horizons appears to be (1) fractures in granodiorite that facilitate water flow and leaching, accelerating mineral dissolution during early weathering stages, and (2) smectite-rich buried soils under permeable colluvium likely deposited by a prior mass wasting event. Where clay-rich layers occur beneath more-permeable horizons, rapid infiltration then absorption of water in clay-rich subsoil horizons causes decreased shear strength and increased landslide susceptibility.

Puerto Rico

Compact seismicity bursts have different characteristics from regional seismicity

Earthquakes tend to cluster, developing into sequences driven by stress perturbations and transient fault-zone processes. Depending on the driving process, earthquake sequences show differing behaviors. This variability challenges our ability to observe or distinguish these driving processes in high resolution. Here we systematically identify seismicity bursts throughout southern California using new statistical methods and examine their causes with other independent geophysical observations. Seismicity bursts are defined as statistically significant seismicity rate anomalies. Our approach has the advantage of being data driven, depending on few earthquake occurrence assumptions. We find abundant seismicity bursts across southern California, most frequently occurring along the San Jacinto Fault and in the Salton Sea and Coso geothermal fields. These seismicity bursts are highly compact in space and time, often encompassed by a 5 km radius and have durations less than 10 hr. Many of the seismicity bursts have their largest earthquake near the beginning of the sequence, but the largest earthquake is usually not an obvious mainshock. We utilize a variety of independent geophysical data sets to analyze the characteristics of the seismicity bursts, finding that the seismicity bursts have low b-values, low spectral stress drops, and varied stress ratios compared to regional seismicity. These differences suggest that seismicity bursts are driven by transient processes acting frequently across fault networks.

California

Enhancing mineral systems exploration through geochronology, thermochronology, and isotope analysis: USGS Geochron and USGS Isotope databases

A mineral systems approach to mineral exploration provides a comprehensive framework for understanding ore deposit formation by examining the geodynamic, magmatic, hydrothermal, and sedimentary processes responsible for mineralization, alteration, and remobilization of economic mineral deposits. Temporal and thermal constraints on ore genesis are crucial for refining mineral system models and guiding predictive exploration strategies. Geochronology and thermochronology offer invaluable insights into the timing and thermal evolution of ore-forming processes, whereas isotopic analyses provide critical information on the source and geochemical history of ore-forming fluids. Combining these methodologies have proven highly effective for mineral exploration in regions like Australia, however, their combined application has been limited in the United States. To apply these tools to mineral systems-based exploration, the U.S. Geological Survey (USGS) has developed two products: (1) The USGS Geochron Database, and (2) the USGS Isotope Database. These databases provide centralized repositories of geo/thermochronological dates and data (Geochron Database) and both radiogenic and stable isotope data (Isotope Database) generated by the USGS and partners over the past decades. Integrating these datasets together and with traditional exploration approaches provides the mineral exploration community with powerful tools for determining the temporal and thermal histories of ore systems and identifying metallogenic source provinces.

Continental United States

Guidelines for producing integrated 210Pb and 14C age-models

Accurate reconstructions of past environmental changes are crucial in paleoecological research and require reliable chronologies of sedimentary archives. Establishing robust age-models and obtaining the most appropriate proxies for analysis is a complex scientific endeavor, requiring extensive resources and collaboration among specialists, including radiochronologists. Radiometric dating methods, such as 210 Pb and radiocarbon ( 14 C), are frequently employed to establish chronologies in aquatic sedimentary deposits and peat bogs. In this study, we review key aspects of sampling, analysis, and the principles underlying 210 Pb and 14 C age-models, focusing on methods for developing robust joint chronologies for paleoenvironmental research. Drawing largely from the authors' experiences and group discussions during and after a scientific workshop in 2022, we discuss important considerations for site selection, sampling strategies, and radiometric dating to construct integrated 210 Pb and 14 C age-models. Using expert consensus, this group – called Paleostats – aims to provide a set of best practices for other geochronologists with this methods paper. Among our conclusions, we emphasize the importance of accounting for site-specific factors such as prior information on sedimentation rates to establish appropriate sampling and analytical strategies. The use of appropriate coring devices can minimize disturbance to sediments and ensure the core surface remains intact and preserved until sectioning. Where excess 210 Pb is expected, sectioning at intervals of ≤1 cm provides an adequate sampling resolution for 210 Pb dating. Exceptions are possible, allowing for ~2–3 cm sections in areas with confirmed high sedimentation rates (e.g., > 1 cm yr −1 ). Recovering deeper core sections for 14 C dating with sufficient overlap allows for accounting errors in depth estimates made in the field. Special attention is advised during time intervals where validation proxies, such as the human-made radionuclides 137 Cs or post-bomb 14 C, are expected, and to determine the depth of secular equilibrium between 210 Pb and 226 Ra. Radiocarbon analyses are commonly performed by accelerator mass spectrometry, and age models are constructed mainly using Bayesian statistics with Markov Chain Monte Carlo techniques (e.g., Bacon ). A Bayesian approach ( Plum ) is now available for producing 210 Pb age-models, which infers the 210 Pb ex flux, eliminates the need for selecting an equilibrium depth, and allows dating cores with incomplete 210 Pb ex inventory. Plum offers improved chronologies by integrating raw 210 Pb and 14 C data, and these age-models can be enriched with other dating methodologies, such as identifying tephras and other well-recorded historical events. Harmonized reporting would contribute to making radiometric age-models reproducible, which would benefit from an international effort. Using 210 Pb and 14 C to produce integrated age-models may yield better insights into the interplay between natural and recent anthropogenic forcings on ecosystems. This can enhance our understanding of environmental processes and their impacts on climate change, ultimately supporting science-based assessments and decisions.

Earth-Science Reviews

Decadal shifts in groundwater age detected by environmental tracers across California, USA

Groundwater age offers important insight into recharge, storage, and contamination risk. Although models predict age changes can be driven by pumping and climate variability, direct observational evidence remains limited. Here, we analyzed paired environmental tracer suites (tritium, carbon-14, and tritiogenic helium-3) collected a decade apart from 268 wells across California to assess the prevalence of groundwater age transience. Travel-time distribution models and statistical tests indicated age transience at 29% of sites, occurring most often in agricultural regions, such as the San Joaquin Valley and Southern Coast Ranges, where large carbon-14 changes coincided with substantial nitrate and chloride shifts. Sites with tritiogenic helium-3 data showed more frequent age transience, underscoring the value of multi-tracer data sets. These results provide the first regional evidence of widespread groundwater age change and a method for detecting changing water balances with implications for groundwater sustainability and water quality.

California