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Thermodynamics of gas and steam-blast eruptions

Eruptions of gas or steam and non-juvenile debris are common in volcanic and hydrothermal areas. From reports of non-juvenile eruptions or eruptive sequences world-wide, at least three types (or end-members) can be identified: (1) those involving rock and liquid water initially at boiling-point temperatures (‘boiling-point eruptions’); (2) those powered by gas (primarily water vapor) at initial temperatures approaching magmatic (‘gas eruptions’); and (3) those caused by rapid mixing of hot rock and ground- or surface water (‘mixing eruptions’). For these eruption types, the mechanical energy released, final temperatures, liquid water contents and maximum theoretical velocities are compared by assuming that the erupting mixtures of rock and fluid thermally equilibrate, then decompress isentropically from initial, near-surface pressure (≤10 MPa) to atmospheric pressure. Maximum mechanical energy release is by far greatest for gas eruptions (≤∼1.3 MJ/kg of fluid-rock mixture)-about one-half that of an equivalent mass of gunpowder and one-fourth that of TNT. It is somewhat less for mixing eruptions (≤∼0.4 MJ/kg), and least for boiling-point eruptions (≤∼0.25 MJ/kg). The final water contents of crupted boiling-point mixtures are usually high, producing wet, sloppy deposits. Final erupted mixtures from gas eruptions are nearly always dry, whereas those from mixing eruptions vary from wet to dry. If all the enthalpy released in the eruptions were converted to kinetic energy, the final velocity ( v max ) of these mixtures could range up to 670 m/s for boiling-point eruptions and 1820 m/s for gas eruptions (highest for high initial pressure and mass fractions of rock ( m r ) near zero). For mixing eruptions, v max ranges up to 1150 m/s. All observed eruption velocities are less than 400 m/s, largely because (1) most solid material is expelled when m r is high, hence v max is low; (2) observations are made of large blocks the velocities of which may be less than the average for the mixture; (3) heat from solid particles is not efficiently transferred to the fluid during the eruptions; and (4) maximum velocities are reduced by choked flow or friction in the conduit.

Bulletin of Volcanology↗

Eruptive activity at Mount St Helens, Washington, USA, 1984-1988: a gas geochemistry perspective

The results from two different types of gas measurement, telemetered in situ monitoring of reducing gases on the dome and airborne measurements of sulfur dioxide emission rates in the plume by correlation spectrometry, suggest that the combination of these two methods is particularly effective in detecting periods of enhanced degassing that intermittently punctuate the normal background leakage of gaseous effluent from Mount St Helens to the atmosphere. Gas events were recorded before lava extrusion for each of the four dome-building episodes at Mount St Helens since mid-1984. For two of the episodes, precursory reducing gas peaks were detected, whereas during three of the episodes, COSPEC measurements recorded precursory degassing of sulfur dioxide. During one episode (October 1986), both reducing gas monitoring and SO2 emission rate measurements simultaneously detected a large gas release several hours before lava extrusion. Had both types of gas measurements been operational during each of the dome-building episodes, it is thought that both would have recorded precursory signals for all four episodes. Evidence from the data presented herein suggests that increased degassing at Mount St Helens becomes detectable when fresh upward-moving magma is between 2 km and a few hundred meters below the base of the dome and between about 60 and 12 hours before the surface extrusion of lava. ?? 1994 Springer-Verlag.

Bulletin of Volcanology↗

Experimental introduction of excess Ar40 into a granitic melt

Samples of a Precambrian granite were melted in sealed capsules to produce a radiogenic Ar 40 atmosphere over the melt. The amount of Ar 40 incorporated in the quenched charge was then determined. Under these experimental conditions the amount of argon dissolved in the quenched melt was appreciable and could be an important source of error in potassiumargon dating.

Contributions to Mineralogy and Petrology↗

The plinian eruptions of 1912 at Novarupta, Katmai National Park, Alaska

The three-day eruption at Novarupta in 1912 consisted of three discrete episodes. Episode I began with plinian dispersal of rhyolitic fallout (Layer A) and contemporaneous emplacement of rhyolitic ignimbrites and associated proximal veneers. The plinian column was sustained throughout most of the interval of ash flow generation, in spite of progressive increases in the proportions of dacitic and andesitic ejecta at the expense of rhyolite. Accordingly, plinian Layer B, which fell in unbroken continuity with purely rhyolitic Layer A, is zoned from >99% to ???15% rhyolite and accumulated synchronously with emplacement of the correspondingly zoned ash flow sequence in Mageik Creek and the Valley of Ten Thousand Smokes (VTTS). Only the andesiterichest flow units that cap the flow sequence lack a widespread fallout equivalent, indicating that ignimbrite emplacement barely outlasted the plinian phase. On near-vent ridges, the passing ash flows left proximal ignimbrite veneers that share the compositional zonation of their valley-filling equivalents but exhibit evidence for turbulent deposition and recurrent scour. Episode II began after a break of a few hours and was dominated by plinian dispersal of dacitic Layers C and D, punctuated by minor proximal intraplinian flows and surges. After another break, dacitic Layers F and G resulted from a third plinian episode (III); intercalated with these proximally are thin intraplinian ignimbrites and several andesite-rich fall/flow layers. Both CD and FG were ejected from an inner vent <400 m wide (nested within that of Episode I), into which the rhyolitic lava dome (Novarupta) was still later extruded. Two finer-grained ash layers settled from composite regional dust clouds: Layer E, which accumulated during the D-F hiatus, includes a contribution from small contemporaneous ash flows; and Layer H settled after the main eruption was over. Both are distinct layers in and near the VTTS, but distally they merge with CD and FG, respectively; they are largely dacitic but include rhyolitic shards that erupted during Episode I and were kept aloft by atmospheric turbulence. Published models yield column heights of 23-26 km for A, 22-25 km for CD, and 17-23 km for FG; and peak mass eruption rates of 0.7-1x108, 0.6-2x108, and 0.2-0.4x108 kg s-1, respectively. Fallout volumes, adjusted to reflect calculated redistribution of rhyolitic glass shards, are 8.8 km3, 4.8 km3, and 3.4 km3 for Episodes I, II, and III. Microprobe analyses of glass show that as much as 0.4 km3 of rhyolitic glass shards from eruptive Episode I fell with CDE and 1.1 km3 with FGH. Most of the rhyolitic ash in the dacitic fallout layers fell far downwind (SE of the vent); near the rhyolite-dominated ignimbrite, however, nearly all of Layers E and H are dacitic, showing that the downwind rhyolitic ash is of 'co-plinian' rather than co-ignimbrite origin. ?? 1992 Springer-Verlag.

Bulletin of Volcanology↗

Tholeiitic basalt magmatism of Kilauea and Mauna Loa volcanoes of Hawaii

The primitive magmas of Kilauca and Mauna Loa are generated by partial melting of mantle peridotite at depths of −60 km or more. Results of high-pressure melting experiments indicate that the primitive melt must contain at least 20% MgO in order to have olivine as a liquidus mineral. The least fractionated lavas of both volcanoes have olivine (Fa 13 ) on the liquidus at 1 atmosphere, suggesting that the only substance lost from the primitive melt, during a rather rapid ascent to the surface, is olivine. This relation allows the primitive composition to be computed by adding olivine to the composition of an erupted lava until total MgO is at least 20 percent. Although roughly similar, historic lavas of the two volcanoes show a consistent difference in composition. The primitive melt of Mauna Loa contains 20% more dissolved orthopyroxene, a high-temperature melting phase in the mantle, and is deficient in elements such as potassium, uranium, and niobium, which presumably occur in minor low-melting phases. Mauna Loa appears to be the older volcano, deriving its magma at higher temperature and greater depth from a more depleted source rock.

Hawaii↗

Ostracode δ18O and δ13C evidence of Holocene environmental changes in the sediments of two Minnesota lakes

Stable oxygen and carbon isotope geochemistry of ostracode valves, abundance and assemblages of ostracode species, and sedimentological parameters from cores taken in Williams and Shingobee Lakes in north-central Minnesota show changes in climatic and hydrologic history during the Holocene. Isotopic records are consistent with the following scenario: Before 9800 yr B.P. the two lakes were connected. Increasing evaporation through the jack/red pine period (9800-7700 yr B.P.) led to lower lake levels, leaving small separated basins. The prairie period (7700-4000 yr B.P.) reflects high aridity, and lake levels reached low stands shortly before 6500 yr B.P. Low lake levels are associated with groundwater discharge between 6500 and 6000 yr B.P. The hardwood period (4000-3200 yr B.P.) corresponds to long cold winters and warm to cool summers with lower evaporation rates and slower sedimentation. During the white pine period (<3200 yr B.P.) evaporation increased and/or precipitation shifted to the summer months. These changes can be related to shifting atmospheric circulation patterns. Zonal flow was probably dominant during the early Holocene until the end of the prairie period ( c. 4000 yr B.P.). During the hardwood period a combination of zonal and meridional flow patterns caused long and cold winters and wetter summers. During the white pine period wintners were shorter and the meridional flow pattern more significant. Today meridional flow dominates the circulation pattern.

Minnesota↗

Radiocarbon ages of pre-bomb clams and the hard-water effect in Lakes Michigan and Huron

Five radiocarbon ages, all determined by accelerator mass spectrometry, have been obtained for two pre-bomb bivalves from Lake Michigan and one from Lake Huron. After correcting those ages for the fractionation of 14 C in calcite and for the radioactively inert CO 2 in the atmosphere, we find residual ages, caused by the hard water effect, of about 250 years for Lake Michigan and 440 years for Lake Huron.

Lake Huron, Lake Michigan↗

Carbon, oxygen and hydrogen isotope abundances inStylites reflect its unique physiology

Natural abundances of oxygen-18, carbon-14, carbon-13 and deuterium were measured in Stylites andicola , a terrestrial vascular plant lacking stomates, and two terrestrial plant species having stomates that grew nearby. No substantial differences in oxygen-18 and carbon-13 abundances were observed among the three species. The deuterium concentration in Stylites was much higher than in the other species, confirming a previous report of CAM in Stylites. Stylites was depleted in carbon-14 relative to the present day atmosphere, consistent with the proposal that it fixes CO 2 derived from decomposing peat.

Oecologia↗

Time-dependence of sea-ice concentration and multiyear ice fraction in the Arctic Basin

The time variation of the sea-ice concentration and multiyear ice fraction within the pack ice in the Arctic Basin is examined, using microwave images of sea ice recently acquired by the Nimbus-5 spacecraft and the NASA CV-990 airborne laboratory. The images used for these studies were constructed from data acquired from the Electrically Scanned Microwave Radiometer (ESMR) which records radiation from earth and its atmosphere at a wavelength of 1.55 cm. Data are analyzed for four seasons during 1973-1975 to illustrate some basic differences in the properties of the sea ice during those times. Spacecraft data are compared with corresponding NASA CV-990 airborne laboratory data obtained over wide areas in the Arctic Basin during the Main Arctic Ice Dynamics Joint Experiment (1975) to illustrate the applicability of passive-microwave remote sensing for monitoring the time dependence of sea-ice concentration (divergence). These observations indicate significant variations in the sea-ice concentration in the spring, late fall and early winter. In addition, deep in the interior of the Arctic polar sea-ice pack, heretofore unobserved large areas, several hundred kilometers in extent, of sea-ice concentrations as low as 50% are indicated. ?? 1978 D. Reidel Publishing Company.

Boundary-Layer Meteorology↗

Detailed record of SO2 emissions from Pu'u `O`o between episodes 33 and 34 of the 1983-86 ERZ eruption, Kilauea, Hawaii

A tripod-mounted correlation spectrometer was used to measure SO2 emissions from Pu`u `O`o vent, mid-ERZ, Kilauea, Hawaii between Episodes 33 and 34 (June 13 to July 6, 1985). In 24 repose days, 906 measurements were collected, averaging 38 determinations/day. Measurements reflect 13% of the total 576 hours of the repose and 42% of the bright daylight hours. The average SO2 emission for the 24-day repose interval is 167??83 t/d, a total of 4000 tonnes emitted for the entire repose. The large standard deviation reflects the "puffing" character of the plume. The overall rate of SO2 degassing gently decreased with a zero-intercept of 44-58 days and was interrupted by two positive peaks. The data are consistent with the gas emanating from a cylindrical conduit of 50 meter diameter and a length of 1700 meters which degasses about 50% of its SO2 during 24 days. This is in support of the Pu'u `O`o model of Greenland et al. (1987). 36 hours before the onset of Episode 34 (July 5-6, 1985), elevated SO2 emissions were detected while the magma column was extremely active ultimately spilling over during dome fountaining. A "mid-repose" anomaly of SO2 emission (June 21-22, 1985) occurs two days before a sudden increase in the rate of summit inflation (on June 24, 1985), suggesting magma was simultaneously being injected in both the ERZ and summit reservoir until July 24 when it was channelled only to the summit reservoir. This implies degassing magma is sensitive to perturbations within the rift zone conduit system and may at times reflect these disturbances. Periods of 7-45 min are detected in the daily SO2 emissions, which possibly reflect timing of convective overturn in the cylindrical magma body. If the 33-34 repose interval is considered representative of other repose periods, the ERZ reposes of Jan 1983-Jan 1986 ERZ activity, contributed 1.6 ?? 105 tonnes of SO2 to the atmosphere. Including summit fuming from non-eruptive fumaroles (2.7 ?? 105 tonnes SO2); 28% of the total SO2 budget from Kilauea between Jan 1983 to Jan 1986 was contributed by quiescent degassing, and the remainder was released during explosive fountaining episodes. ?? 1988 Springer-Verlag.

Bulletin of Volcanology↗

National Pesticide Monitoring Program: Residues of organochlorine chemicals in freshwater fish, 1980–81

The U.S. Fish and Wildlife Service analyzed residues of organochlorine chemicals in 315 composite samples of whole fish collected in 1980–81 from 107 stations nationwide as part of the National Pesticide Monitoring Program (NPMP). The mean concentrations of total DDT and all p,p ′-ho-mologs except p,p ′-DDT showed significant but small declines relative to mean concentrations before 1978–79. The mean concentration of p,p ′-DDT did not change. The most persistent DDT homolog ( p,p ′-DDE) continued to constitute about 70% of total DDT residues, as it did in 1974–79. DDT contamination attributable to former DDT manufacturing facilities remained evident at sites in Alabama and Arkansas, and high concentrations at one site in Hawaii suggested that input to the environment was continuing. Conversely, the data do not support the contention of others that DDT was still being used in the Southwest. Residues of polychlorinated biphenyls (PCBs) remained widespread, but a significant downward trend in total PCBs was evident, especially in areas that the NPMP has previously shown to be the most heavily contaminated. Mean concentrations of dieldrin had not changed since 1978–79, and levels remained highest in Hawaii and in the Great Lakes. Toxaphene concentrations plateaued after a period of steady increase through the 1970's, but the incidence of toxaphene continued to increase; residues were present at 88% of the stations sampled in 1980–81, including one in Alaska (most likely as a consequence of atmospheric transport). Mean chlordane concentrations were slightly lower than in 1978–79, and residues were detected at fewer stations in 1980–81 than in 1978–79. Residues of other organochlorines [ e.g. , mirex, pentachloroanisole (PCA), benzene hexachloride (BHC) isomers, endrin, heptachlor, hexachlorobenzene (HCB), Dacthal ® (DCPA) 2 , and methoxychlor] were either found at relatively few (<25%) of the stations sampled in 1980–81 or were characterized by relatively low concentrations.

Archives of Environmental Contamination and Toxico↗

Mercury cycling in the Allequash Creek watershed, northern Wisconsin

Although there have been recent significant gains in our understanding of mercury (Hg) cycling in aquatic environments, few studies have addressed Hg cycling on a watershed scale in particular, attention to Hg species transfer between watershed components (upland soils, groundwater, wetlands, streams, and lakes) has been lacking. This study describes spatial and temporal distributions of total Hg and MeHg among watershed components of the Allequash Creek watershed (northern Wisconsin, USA). Substantial increases in total Hg and MeHg were observed as groundwater discharged through peat to form springs that flow into the stream, or rivulets that drain across the surface of the wetland. This increase was concomitant with increases in DOC. During fall, when the Allequash Creek wetland released a substantial amount of DOC to the stream, a 23 fold increase in total Hg concentrations was observed along the entire length of the stream. Methylmercury, however, did not show a similar response. Substantial variability was observed in total Hg (0.9 to 6.3) and MeHg (<0.02 to 0.33) concentrations during synoptic surveys of the entire creek. For the Allequash Creek watershed, the contributing groundwater basin is about 50% larger than the topographic drainage basin. Total Hg concentrations in groundwater, the area of the groundwater basin, and annual stream flow data give a watershed-yield rate of 12 mg/km2/d, which equates to a retention rate of 96%. The calculated MeHg yield rate for the wetland area is 0.6 to 1.5 mg/km2/d, a value that is 3-6 fold greater than the atmospheric deposition rate.

Water, Air, & Soil Pollution↗

The non-participation of organic sulphur in acid mine drainage generation

Acid mine drainage is commonly associated with land disturbances that encounter and expose iron sulphides to oxidising atmospheric conditions. The attendant acidic conditions solubilise a host of trace metals. Within this flow regime the potential exists to contaminate surface drinking water supplies with a variety of trace materials. Accordingly, in evaluating the applications for mines located in the headwaters of water sheds, the pre-mining prediction of the occurrence of acid mine drainage is of paramount importance. There is general agreement among investigators that coal organic sulphur is a nonparticipant in acid mine drainage generation; however, there is no scientific documentation to support this consensus. Using simulated weathering, kinetic, mass balance, petrographic analysis and a peroxide oxidation procedure, coal organic sulphur is shown to be a nonparticipant in acid mine drainage generation. Calculations for assessing the acid-generating potential of a sedimentary rock should not include organic sulphur content.

Environmental Geochemistry and Health↗

Mercury accumulation in Devils Lake, North Dakota effects of environmental variation in closed-basin lakes on mercury chronologies

Sediment cores were collected from lakes in the Devils Lake Basin in North Dakota to determine if mercury (Hg) accumulation chronologies from sediment-core data are good indicators of variations in Hg accumulation rates in saline lakes. Sediment cores from Creel Bay and Main Bay, Devils Lake were selected for detailed analysis and interpretation. The maximum Hg concentration in the Creel Bay core was 0.15 micrograms per gram at 8 to 9 centimeters. The maximum Hg concentration in the Main Bay core was 0.07 micrograms per gram at 5 to 7 centimeters. The general decreases in Hg concentrations with depth are attributed to historic variations in atmospheric Hg deposition rate. Hg stratigraphies combined with 210Pb and 137Cs dating analyses yield Hg chronologies that indicate a general increase in Hg accumulation rates in Devils Lake since the middle of the 19th century. Mean modern Hg accumulation rates in Creel Bay were 4.9 nanograms per square centimeter per year, and rates in Main Bay were 1.8 nanograms per square centimeter per year. Mean preindustrial Hg accumulation rates in Creel Bay were 1.2 nanograms per square centimeter per year, and rates in Main Bay were 1.6 nanograms per square centimeter per year. Relatively low Hg concentrations in recent sediments in the Devils Lake Basin, along with similarities in Hg accumulation rates between lakes in the Devils Lake Basin and other lakes in the northern interior of North America, indicate that local sources of Hg are not important sources of Hg. Results of the study indicate that accurate Hg chronologies are discernible in sediment cores collected from saline lakes. However, spatial and temporal variations in lake level and water chemistry common to saline lakes make interpretation of radioisotopic and geochemical chronologies difficult. Hg geochemistry in Devils Lake, and presumably in other saline lakes, is dynamic. The results of this study indicate that the absolute amount of sediment transported to Devils Lake, along with the associated Hg and total organic carbon, and the distribution of sedimentation patterns in Devils Lake may be affected by changing lake levels.

Water, Air, & Soil Pollution↗

Hydrogeologic controls of surface-water chemistry in the Adirondack region of New York State

Relationships between surface-water discharge, water chemistry, and watershed geology were investigated to evaluate factors affecting the sensitivity of drainage waters in the Adirondack region of New York to acidification by atmospheric deposition. Instantaneous discharge per unit area was derived from relationships between flow and staff-gage readings at 10 drainage basins throughout the region. The average chemical composition of the waters was assessed from monthly samples collected from July 1982 through July 1984. The ratio of flow at the 50-percent exceedence level to the flow at the 95-percent exceedence level of flow duration was negatively correlated with mean values of alkalinity or acid-neutralizing capacity (ANC), sum of basic cations (SBC), and dissolved silica, for basins containing predominantly aluminosilicate minerals and little or no carbonate-bearing minerals. Low ratios are indicative of systems in which flow is predominately derived from surface- and ground-water storage, whereas high ratios are characteristic of watersheds with variable flow that is largely derived from surface runoff. In an evaluation of two representative surface-water sites, concentrations of ANC, SBC, and dissolved silica, derived primarily from soil mineral weathering reactions. decreased with increasing flow. Furthermore, the ANC was highest at low flow when the percentage of streamflow derived from ground water was maximum. As flow increased, the ANC decreased because the contribution of dilute surface runoff and lateral flow through the shallow acidic soil horizons to total flow increased. Basins having relatively high ground-water contributions to total flow, in general, have large deposits of thick till or stratified drift. A major factor controlling the sensitivity of these streams and lakes to acidification is the relative contribution of ground water to total discharge. ?? 1987 Martinus Nijhoff/Dr W. Junk Publishers.

Biogeochemistry↗

Sustainability in a materials world

Many adverse impacts on the environment can be directly related to the materials dispersed to the environment during processing or use, or after use as refuse and waste. Some materials, such as toxic wastes, are a major concern because they create immediate problems with longer-term effects. Gases released by major manufacturing industries can contribute to long-term regional and global problems such as acid rain or increased carbon dioxide in the atmosphere. The use of other materials, however, appears to be more benign or strictly localized in their impacts. If the current per capita level of material consumption in the United States was achieved worldwide, it would create major stresses on both resource adequacy and the environment. In fact, stresses have been created and will continue from this consumption style (developed countries) even if others don't achieve them.

Natural Resources Research↗

Origin and influence of coal mine drainage on streams of the United States

Degradation of water quality related to oxidation of iron disulfide minerals associated with coal is a naturally occurring process that has been observed since the late seventeenth century, many years before commencement of commercial coal mining in the United States. Disturbing coal strata during mining operations accelerates this natural deterioration of water quality by exposing greater surface areas of reactive minerals to the weathering effects of the atmosphere, hydrosphere, and biosphere. Degraded water quality in the temperate eastern half of the United States is readily detected because of the low mineralization of natural water. Maps are presented showing areas in the eastern United States where concentrations of chemical constituents in water affected by coal mining (pH, dissolved sulfate, total iron, total manganese) exceed background values and indicate effects of coal mining. Areas in the East most affected by mine drainage are in western Pennsylvania, southern Ohio, western Maryland, West Virginia, southern Illinois, western Kentucky, northern Missouri, and southern Iowa. Effects of coal mining on water quality in the more arid western half of the United States are more difficult to detect because of the high degree of mineralization of natural water. Normal background concentrations of constituents are not useful in evaluating effects of coal mine drainage on streams in the more arid West. Three approaches to reduce the effects of coal mining on water quality are: (1) exclusion of oxygenated water from reactive minerals, (2) neutralization of the acid produced, (3) retardation of acid-producing bacteria population in spoil material, by application of detergents that do not produce byproducts requiring disposal. These approaches can be used to help prevent further degradation of water quality in streams by future mining. ?? 1988 Springer-Verlag New York Inc.

Environmental Geology and Water Sciences↗

The effect of nitrogen loading on a brackish estuarine faunal community: A stable isotope approach

Coastal ecosystems worldwide face increased nutrient enrichment from shoreline and watershed development and atmospheric pollution. We investigated the response of the faunal community of a small microtidal estuary dominated by Ruppia maritima (widgeon grass) in Maine, United States, to increased nitrogen loading using an in situ mesocosm enrichment experiment. Community response was characterized by assessing quantitative shifts in macroin-vertebrate community composition and identifying changes in food web structure using stable carbon and nitrogen isotope ratios of producers and consumers. The community was dominated by brackish water invertebrates including midge larvae, oligochaetes, damselfly larvae, amphipods, and ostracods. Experimental nutrient additions resulted in significantly lower densities of herbivorous chironomids and predatory damselflies and greater densities of deposit feeding oligochaetes. Grazing midge larvae (Chironomidae: Dicrotendipes, Cricotopus) consumed epiphytic algae under both natural and enriched conditions. Deposit feeding Chironomus was dependent on allochthonous sources of detritus under natural conditions and exhibited a shift to autochthonous sources of detritus under enriched conditions. Predatory Enallagma primarily consumed grazing chironomids under all but the highest loading conditions. Experimental nutrient loading resulted in an increase in generalist deposit feeders dependent on autochthonous sources of detritus.

Estuaries↗