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Flow heterogeneity controls dissolution dynamics in topologically complex rocks

Rock dissolution is a common subsurface geochemical reaction affecting pore space properties, crucial for reservoir stimulation, carbon storage, and geothermal energy. Predictive models for dissolution remain limited due to incomplete understanding of the mechanisms involved. We examine the influence of flow, transport, and reaction regimes on mineral dissolution using 29 time-resolved data from 3D rocks. We find that initial pore structure significantly influences the dissolution pattern, with reaction rates up to two orders of magnitude lower than batch conditions, given solute and fluid-solid boundary constraints. Flow unevenness determines the location and rate of dissolution. We propose two models describing expected dissolution patterns and effective reaction rates based on dimensionless metrics for flow, transport, and reaction. Finally, we analyze feedback between evolving flow and pore structure to understand conditions that regulate/reinforce dissolution hotspots. Our findings underscore the major impact of flow arrangement on reaction-front propagation and provide a foundation for controlling dissolution hotspots.

Geophysical Research Letters

Groundwater dependency and hydroclimatic influences on riparian and upland vegetation productivity, Upper San Pedro, Arizona, United States

In arid and semi-arid regions, groundwater sustains vegetation through subsurface water access, yet the responses of groundwater-dependent ecosystems (GDEs) to changing hydroclimate and groundwater availability are relatively understudied. This study investigates seasonal and spatial patterns in vegetation greenness using Landsat Enhanced Vegetation Index (EVI) values across riparian and upland zones in the semi-arid Upper San Pedro (USP) watershed, southern Arizona, which experiences a bimodal precipitation regime. We paired 25 years (2000–2024) of EVI and depth to groundwater (DTG) data from 89 wells and climate metrics (precipitation and vapour pressure deficit) to quantify the sensitivity of vegetation to subsurface moisture as well as atmospheric moisture supply and demand. Vegetation at wells near the USP riparian area showed strong associations between EVI and DTG anomalies during the monsoon season, indicating sustained groundwater use even during this wet period when summer precipitation is abundant. In contrast, upland vegetation that lacked access to groundwater showed minimal sensitivity in EVI to DTG and was generally less responsive to vapour pressure deficit. Interestingly, the riparian GDEs were not decoupled from precipitation and climate variability. These results underscore the importance of groundwater for maintaining riparian productivity and highlight the utility of remote sensing in identifying vegetation-climate-groundwater linkages across heterogeneous dryland landscapes.

Arizona

Transcriptional changes in wild Yukon River Chinook Salmon associated with Ichthyophonus infections

Objective We compared differentially expressed genes in Chinook Salmon Oncorhynchus tshawytscha with three divergent Ichthyophonus statuses (undetected, subclinical infections, or clinical disease; n = 100) to investigate associated transcriptomic responses. Disease associated with the fish parasite Ichthyophonus sp. was first diagnosed in adult Chinook Salmon from the Yukon River in the late 1980s and has subsequently been implicated in premature host mortality. Methods Chinook Salmon tissue sample collections and Ichthyophonus infection data were leveraged from a multi-agency collaboration during summer 2022 at three locations along the main-stem Yukon River that spanned nearly 2,000 km of freshwater migration (lower, middle, and upper river). We sequenced the transcriptome and compared this to infection status based on routine diagnostic procedures. Results Among the 17,569 genes for which messenger RNA was detected, we identified a transcription signature in the skeletal muscle that was associated with Ichthyophonus infections and included 53 differentially expressed genes. The differentially expressed genes and their pathways included those known for involvement in immune functions, energy synthesis, cellular breakdown, and reproduction—all processes that are known to be influenced by senescence during spawning migrations. Conclusions Results demonstrate a clear transcriptional difference between diseased fish (clinical disease group) and those in which Ichthyophonus was undetected, including identifying candidate markers for infection in this population. These results provide a foundation for development of nonlethal biomarkers to evaluate potential Ichthyophonus infections in Chinook Salmon based on gene transcription, protein products, or gene variants (e.g., polymorphisms).

Journal of Aquatic Animal Health

Drone-based radiometric surveys provide high-resolution mine waste characterization

Airborne radiometric surveys use passive geophysical techniques to characterize geochemical variations at or near earth’s surface. These methods have been used for a variety of mapping applications, including mineral resource evaluation. However, detailed characterization of smaller geologic targets, including mine waste features, requires flying at lower altitudes and with tighter line spacing than is feasible with traditional aircraft. Here, a small uncrewed aircraft system (sUAS) equipped with a radiometric sensor was used to acquire high-resolution gamma-spectrometry over small mine waste features and a low-grade stockpile in southwestern New Mexico. The sUAS radiometric system mapped local variability within each survey area and revealed ~2–10 m wide zones where radioelements K, Th, and U may be elevated 2–10× the surrounding material. Additionally, the sUAS radiometric data revealed radioelement variability across survey sites, which correlated reasonably well with variability seen in geochemical samples at each survey site, even though samples collected from individual sites showed high local variability. The sUAS data characterized local heterogeneity within mine waste and other small geologic targets at scales of a few meters to tens of meters, which is not possible with traditional crewed aircraft, and with continuity of coverage that is not possible with ground surveys, thus filling a key gap in geophysical survey spatial resolution.

New Mexico

Towards mobile wind measurements using joust configured ultrasonic anemometer for applications in gas flux quantification

Small uncrewed aerial systems (sUASs) can be used to quantify emissions of greenhouse and other gases, providing flexibility in quantifying these emissions from a multitude of sources, including oil and gas infrastructure, volcano plumes, wildfire emissions, and natural sources. However, sUAS-based emission estimates are sensitive to the accuracy of wind speed and direction measurements. In this study, we examined how filtering and correcting sUAS-based wind measurements affects data accuracy by comparing data from a miniature ultrasonic anemometer mounted on a sUAS in a joust configuration to highly accurate wind data taken from a nearby eddy covariance flux tower (aka the Tower). These corrections had a small effect on wind speed error, but reduced wind direction errors from 50° to >120° to 20–30°. A concurrent experiment examining the amount of error due to the sUAS and the Tower not being co-located showed that the impact of this separation was 0.16–0.21 ms − 1 "> ms − 1 , a small influence on wind speed errors. Lower wind speed errors were correlated with lower turbulence intensity and higher relative wind speeds. There were also some loose trends in diminished wind direction errors at higher relative wind speeds. Therefore, to improve the quality of sUAS-based wind measurements, our study suggested that flight planning consider optimizing conditions that can lower turbulence intensity and maximize relative wind speeds as well as include post-flight corrections.

Alaska

The 2025 Puerto Rico and Virgin Islands U.S. National Seismic Hazard Model Update: Ground motion model selection and comparison

We evaluate, select, and describe the ground-motion models (GMMs) used in the 2025 update of the U.S. National Seismic Hazard Model (NSHM) for Puerto Rico and the U.S. Virgin Islands (PRVI). We identify the most appropriate models that align with GMM selection criteria for use in the PRVI region to improve the accuracy of seismic hazard assessments. The update incorporates globally applicable GMMs suited for the active crustal and subduction earthquakes in the region. We include region-specific adjustments to these GMMs derived from local site response analyses derived from ground motion records. The unadjusted and regionally-corrected GMMs are combined to create a robust model for predicting median ground motion. The model integrates epistemic uncertainty through a median ground motion logic tree that accounts for variations in magnitude and distance. This study compares the GMMs selected for the 2025 PRVI NSHM, including both as-provided and regionally adjusted NGA-West2 and NGA-Subduction models, with those used in the 2003 PRVI NSHM. We evaluate how changes in model selection, weighting, aleatory variability, and epistemic uncertainty influence seismic hazard estimates. Trends with distance, magnitude, and spectral period are analyzed to evaluate how the scaling behavior of the newer GMMs differs from that of earlier models. Relative to the GMMs used in the 2003 NSHM for this region, the 2025 models generally predict lower ground motions. Comparisons with additional GMMs indicate that the adjustments applied for PRVI are consistent with regional-specific modifications developed elsewhere globally. The increase in aleatory variability and epistemic uncertainty in the 2025 update results in a notable increase in hazard levels from these wider uncertainty bounds. These changes can result in as much as a 10%–20% variation in probabilistic ground motion at the 2% in 50 years exceedance level for hazard maps computed across the region for representative site classes and periods.

Puerto Rico, Virgin Islands

Road salt collection and redistribution at an urban rain garden on sandy soil, Gary, Indiana

Rain gardens installed as green infrastructure to divert storm runoff from entering combined sewers also collect dissolved constituents and particulates. An urban rain garden in northwestern Indiana, USA, was continuously monitored from November 2019 to May 2021 to evaluate the fate of dissolved constituents entering the rain garden in runoff. Physical and chemical properties of soils in the rain garden were also monitored, along with underlying groundwater. Linear regression models relating specific conductance to chloride concentration indicated that the 0.0371-ha (3998 square feet) rain garden collected approximately 1490 kg (3285 pounds) of road salt from the surrounding 0.2228 ha (24,500 square feet) of impervious surfaces. Soils and groundwater were seasonally affected by road salt application but carryover from year to year was not indicated. Rain garden soil permeability (5.20 × 10 −5 to 9.72 × 10 −5 m/s) remained unchanged during the study period and soil organic carbon generally increased under native vegetation. The results suggest that a rain garden built on sandy soil can divert substantial quantities of runoff and dissolved constituents from combined sewers; however, chloride is transported to sub-infrastructure groundwater that eventually discharges to adjacent waterways with concentrations lower than those observed in runoff.

Indiana

Preconditioned Conjugate-Gradient 2 (PCG2), a computer program for solving ground-water flow equations

This report documents PCG2: a numerical code to be used with the U.S. Geological Survey modular three-dimensional, finite-difference, ground-water flow model. PCG2 uses the preconditioned conjugate-gradient method to solve the equations produced by the model for hydraulic head. Linear or nonlinear flow conditions may be simulated. PCG2 includes two reconditioning options: modified incomplete Cholesky preconditioning, which is efficient on scalar computers; and polynomial preconditioning, which requires less computer storage and, with modifications that depend on the computer used, is most efficient on vector computers. Convergence of the solver is determined using both head-change and residual criteria. Nonlinear problems are solved using Picard iterations. This documentation provides a description of the preconditioned conjugate gradient method and the two preconditioners, detailed instructions for linking PCG2 to the modular model, sample data inputs, a brief description of PCG2, and a FORTRAN listing.

Water-Resources Investigations Report

Groundwater-Surface water interactions research: Past trends and future directions

Interactions between groundwater and surface water sustain groundwater-dependent ecosystems and regulate river temperature and biogeochemical cycles, amongst many other processes. These interactions occur in freshwater environments including rivers, springs, lakes, and wetlands, and in coastal environments via tidal pumping, submarine groundwater discharge, and seawater intrusion. Here, we explore groundwater-surface water interactions research using bibliometric analyses of titles, abstracts, and keywords from 20,275 journal papers published between 1970 and 2023 extracted from Scopus. Analyses show that research into groundwater-surface water interactions is highly multi-disciplinary, with growing contributions from the social and biological sciences. The number of groundwater-surface water interactions papers is rapidly increasing with over 1200 papers published per year since 2020. Drawing on our data-driven approach and expert knowledge, we synthesise current research trends and identify critical future research directions. Despite the thousands of papers on groundwater-surface water interactions, important processes are still difficult to quantify or predict at meaningful spatial scales to inform water-resources management. We see benefits in future groundwater-surface water interactions research focusing on: (1) using new technologies including internet-of-things-based sensors, uncrewed vehicles, and remote-sensing approaches for data collection to inform groundwater-surface water interactions at large scales, (2) seeking approaches to upscale site-specific findings to better inform management, and (3) continuing the movement towards multi-disciplinary investigations to better inform the understanding of groundwater-surface water interactions and processes that will enable better management outcomes.

Journal of Hydrology

Updating regional‐scale geospatial liquefaction models with locally available geotechnical data

We present a method to update the geospatial liquefaction model used by the U.S. Geological Survey’s near‐real‐time ground failure product with subsurface geotechnical data. The geospatial model estimates liquefaction probability from peak ground velocity (via ShakeMap) and geospatial susceptibility proxies. In many regions, additional information relevant to constraining liquefaction likelihood is also available, including surface geology maps and subsurface geotechnical measurements. There is currently no mechanism to use these data in the ground failure product liquefaction model, even though these data could provide more precise constraints on spatial variations in the lithologic character of the soil (surface geology) and direct measurements of the subsurface mechanical properties that affect liquefaction occurrence and severity (geotechnical measurements). In this study, we develop a method to integrate these data with the geospatial model and assess how these data can improve regional‐scale predictions. We develop a Bayesian updating framework and apply it to the 1989 magnitude 6.9 Loma Prieta, California, earthquake, for which mapped observations are available to evaluate performance. We constrain the Bayesian framework with 373 Northern California cone penetration tests and liquefaction susceptibility classes based on the mapped surface geology. This Bayesian model incorporates geotechnical information into the geospatial model and more accurately predicts liquefaction occurrences than the geospatial model, while sacrificing less accuracy in terms of predicting the absence of liquefaction than the geotechnical model. In future applications, this approach could be adapted to update other geospatial models using locally available subsurface data.

California

USGS addresses needs for lithium calibration and quality control materials for pLIBS analysis

Lithium (Li) is a globally important commodity used for energy storage, national defense, human health, and advanced technologies. Lithium resource development requires identifying deposits with elevated concentrations and optimal mineralogy, typically associated with select clays and pegmatites. Lithium is a light, highly reactive alkali metal with low atomic mass that is difficult to detect and quantify using conventional portable geochemical techniques such as X-ray fluorescence (XRF). However, portable laser-induced breakdown spectroscopy (pLIBS) is a powerful analytical technique for lithium exploration due to its ability to analyze solids quickly with minimal preparation. The expanded utility of pLIBS is hampered by the lack of matrix-matched calibration and quality control (QC) materials. The United States Geological Survey (USGS) has developed in-house lithium calibration and QC materials for lithium in clay and pegmatite matrices to address this limitation. We present the workflow and implementation of a custom-built matrix specific calibration on a SciAps Z-300 pLIBS, using proprietary Profile Builder software. The implementation of the custom calibration and quality control standards enables us to collect semiquantitative results directly from the pLIBS while in the field. Ultimately, this calibration has improved confidence in sample selection and collection in the field, providing more efficient site characterization.

Conference Paper

Simulating present and future groundwater/surface-water interactions and stream temperatures in Beaver Creek, Kenai Peninsula, Alaska

In many places, coldwater ecosystems are facing increasing pressure from anthropogenic warming. This study examined stream temperatures and the water balance in the Beaver Creek watershed on the Kenai Peninsula in south-central Alaska—an area that is experiencing rapid warming. Low-gradient streams near the Kenai coast provide important spawning and rearing habitat for salmon but may be especially vulnerable to rising temperatures, because of long residence times, inflows from abundant riparian wetlands, and reliance on groundwater discharge that may also warm, or decrease in volume with rising evapotranspiration. In recent decades, observed maximum 7-day temperatures have consistently exceeded statistical (regression-based) projections. Here we simulate total streamflows and temperatures with a physics-based model that links the Soil Water Balance, MODFLOW 6 and SNTEMP simulation codes on a 7-day timestep. The model is based on existing data and groundwater levels, instream flows, and stream temperatures collected during 2019–23. Future climate scenarios were developed for 2023–50 from downscaled climate projections. Results indicate that groundwater discharge is about 64 percent of the total streamflow during the months of May through September. Total streamflow and groundwater discharge are expected to remain similar to current conditions through 2050. Stream temperatures are expected to rise; by midcentury, near the Beaver Creek mouth the model predicts 34 to 63 additional days per year with average weekly temperatures above 13 degrees Celsius, 14 to 81 additional days with average weekly temperatures above 15 degrees Celsius, and routine exceedances of 20 degrees Celsius during the warmest periods. Projected stream temperatures vary spatially. Areas of high groundwater inflows in the lower main stem and some tributaries may be most resilient to warming air temperatures during dry conditions. During storm events, groundwater-dominated tributaries may have the coolest stream temperatures.

Alaska

Potential for continental scientific drilling to inform fault mechanics and earthquake science

Our understanding of fault mechanics and earthquake processes remains limited, largely due to minimal direct observations near active faults at seismogenic depths. This lack of data restricts our ability to accurately assess and mitigate both natural and human-induced seismic hazards. However, recent advancements in drilling capabilities and downhole sensing technologies offer an opportunity: the ability to observe the physical conditions within a volume near active fault zones. In this contribution, we highlight how scientific drilling can provide access to the near-fault environment, enabling measurements of the stress, temperature, fluid pressure, and rock properties at depths where ruptures initiate, propagate, and arrest. These observations are essential to refine models of earthquake nucleation and dynamic rupture, bridging gaps between laboratory experiments, numerical simulations, and surface observations. These insights can advance fundamental understanding in earthquake science but also support the development of more effective seismic hazard assessments and risk mitigation strategies.

Seismica

Earth Mapping Resources Initiative protocols—Sampling hard-rock mine waste and perpetual mine water sources

Supporting the overarching goal to evaluate critical minerals nationwide, the mine waste characterization effort in the U.S. Geological Survey (USGS) Earth Mapping Resources Initiative has created a series of protocols to standardize sampling carried out under this effort by the participating State geological surveys and their cooperators. The protocols are based on published, reviewed methods that can be deployed in the field. The protocols include (1) collecting and processing composite samples of mine and mill waste, including tailings, waste rock, gangue, heap leach piles, ore stockpiles, slag, or other mineralized and processed materials and (2) collecting and preserving water samples from perpetual or long-term mine water sources. The protocols also specify information to document on field sheets and detail the collection of geospatial data. The analytical methods used by the USGS and USGS contract laboratories are described in this report, including the data delivery pathway for USGS-derived data.

Scientific Investigations Report

The damability function: A probabilistic approach to regional landslide dam susceptibility analysis applied to the Oregon Coast Range, USA

Landslides can dam rivers and require rapid response to mitigate catastrophic outburst floods. Here, we present a workflow to map landslide dam formation susceptibility at a regional scale. We define a probabilistic function that combines river valley width and landslide volume to efficiently determine the likelihood of a landslide dam or “damability”. We combine damability values with landslide susceptibility to estimate landslide dam susceptibility. The valley width measurements are automated using a new elevation threshold-based algorithm. Landslide volume is represented as a statistical distribution from mapped landslides. We validate and apply our approach to the Oregon Coast Range, USA and find that 36 % of river stretches exceed a dam potential threshold; these are in river headwaters and steeper terrain, which in this case correlate with more resistant lithologies. We also estimate volumes of the potential dammed lakes and find that most rivers with high dam susceptibility are less likely to impound large lakes because they have low drainage areas. However, widespread susceptibility, and the potential impacts from exceptionally large landslides, suggest that this hazard should be considered in the Pacific Northwest. The damability function workflow can ingest new data and be applied more broadly to assess future landslide dam hazards.

Oregon

U.S. Geological Survey geomagnetic variometer data: Capitalizing on seismic infrastructure

The U.S. Geological Survey’s Geomagnetism Program is collaborating with the Earthquake Hazards Program and Global Seismographic Network Program to densify magnetic field observations. This collaboration focuses on the installation of magnetometers, or magnetic variometers, at existing seismic stations. Along with improving the density of space weather observations for hazard monitoring, these data can be used to correct colocated magnetic field induced noise in seismic data. Such corrections are especially useful during time periods of large magnetic storms where the magnetic field‐induced instrument noise can be of similar amplitude to earthquake ground‐motion records.

contiguous United States

Geochemical disequilibrium at the brittle-ductile transition

We investigate the microtextural, microchemical, and isotopic effects of late-stage ductile deformation in quartzite mylonites and kyanite–muscovite–quartz veins from the Raft River shear zone (Utah). Quartz microstructures record pervasive disequilibrium, expressed by unannealed features including undulatory extinction, deformation lamellae, and poorly defined fabrics, typical of waning deformation in shear zones. Microchemical disequilibrium is best preserved in kyanite quartzites, where CL-zoned kyanite records repeated fractures, overgrowth, and mineral precipitation, and in muscovite from muscovite-poor quartzite mylonites that shows minor-element zoning consistent with syn-deformational overgrowth on detrital cores. In contrast, muscovite from muscovite-rich kyanite quartzites exhibits minimal chemical zoning. These microchemical variations correlate with 40 Ar/ 39 Ar age systematics. Chemically zoned muscovite preserves variable single-step ages, including ∼150 Ma ages, reflecting retention of detrital cores. In contrast, syndeformational muscovite consistently yields Miocene ages, indicating recrystallization and new growth below argon closure temperatures that reset inherited isotopic signatures. Similar trends are observed in quartzite mylonites, where increasing quartz recrystallization and stronger crystallographic preferred orientations occur toward deeper structural levels. Together, these observations indicate increasing retrograde deformation and recrystallization with depth in the Raft River shear zone and demonstrate that strain-driven recrystallization exerts a first-order control on muscovite ages. We suggest that apparent thermochronologic gradients in retrograde shear zones may reflect recrystallization gradients rather than temperature gradients. Where cooling limits the thermal driving force for recrystallization, isotopic relics are preserved, and local deformation and fluid availability control re-equilibration. Consequently, isotopic disequilibrium—particularly in the 40 Ar/ 39 Ar system—may be the rule rather than the exception of retrograde tectonic environments.

Idaho, Utah

Parsimonious high-resolution landslide susceptibility modeling at continental scales

Landslide susceptibility maps are fundamental tools for risk reduction, but the coarse resolution of current continental-scale models is insufficient for local application. Complex relations between topographic and environmental attributes characterizing landslide susceptibility at local scales are not transferrable across areas without landslide data. Existing maps with multiple susceptibility classifications under-represent landslide potential in moderate and gently sloping terrain. We leverage an extensive landslide database ( N = 613,724), a high-resolution digital elevation model (10-m), and high-performance computing resources, to develop a new nationwide susceptibility map for the contiguous United States, Hawaii, Alaska, and Puerto Rico. We calculate four alternative linear and nonlinear thresholds of topographic slope and relief using an objective split-sample calibration. We down-sample our results to a 90-m grid to account for uncertainty in the digital elevation model and landslide position, and evaluate these thresholds' ability to differentiate areas of greater susceptibility. The less conservative nonlinear model optimally balances our priorities of capturing observed landslides (99%) while minimizing area covered by susceptible terrain (43%). Independent evaluation with four statewide landslide inventories ( N = 172,367) reinforces our model selection but highlights spatially variable performance. Therefore, we propose a novel approach to susceptibility classification using the concentration of landslide-prone terrain within each down-sampled grid. While landslides are possible within any cells containing susceptible terrain, those with the highest concentration capture the majority of observed landslides. Our new map characterizes landside susceptibility more consistently than prior models; our transparent classification approach also provides flexibility for accommodating different tolerances in risk reduction measures.

AGU Advances