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New light on a dark subject: On the use of fluorescence data to deduce redox states of natural organic matter (NOM)

This paper reports the use of excitation-emission matrix fluorescence spectroscopy (EEMS), parallel factor statistical analysis (PARAFAC), and oxidation-reduction experiments to examine the effect of redox conditions on PARAFAC model results for aqueous samples rich in natural organic matter. Fifty-four aqueous samples from 11 different geographic locations and two plant extracts were analyzed untreated and after chemical treatments or irradiation were used in attempts to change the redox status of the natural organic matter. The EEMS spectra were generated and modeled using a PARAFAC package developed by Cory and McKnight (2005). The PARAFAC model output was examined for consistency with previously reported relations and with changes expected to occur upon experimental oxidation and reduction of aqueous samples. Results indicate the implied fraction of total sample fluorescence attributed to quinone-like moieties was consistent (0.64 to 0.78) and greater than that observed by Cory and McKnight (2005). The fraction of the quinone-like moieties that was reduced (the reducing index, RI) showed relatively little variation (0.46 to 0.71) despite attempts to alter the redox status of the natural organic matter. The RI changed little after reducing samples using zinc metal, oxidizing at high pH with air, or irradiating with a Xenon lamp. Our results, however, are consistent with the correlations between the fluorescence indices (FI) of samples and the ratio of PARAFAC fitting parameters suggested by Cory and McKnight (2005), though we used samples with a much narrower range of FI values.

Aquatic Sciences↗

Methylmercury production in and export from agricultural wetlands in California, USA: the need to account for physical transport processes into and out of the root zone

Concentration and mass balance analyses were used to quantify methylmercury (MeHg) loads from conventional (white) rice, wild rice, and fallowed fields in northern California's Yolo Bypass. These analyses were standardized against chloride to distinguish transport pathways and net ecosystem production (NEP). During summer, chloride loads were both exported with surface water and moved into the root zone at a 2:1 ratio. MeHg and dissolved organic carbon (DOC) behaved similarly with surface water and root zone exports at ~ 3:1 ratio. These trends reversed in winter with DOC, MeHg, and chloride moving from the root zone to surface waters at rates opposite and exceeding summertime root zone fluxes. These trends suggest that summer transpiration advectively moves constituents from surface water into the root zone, and winter diffusion, driven by concentration gradients, subsequently releases those constituents into surface waters. The results challenge a number of paradigms regarding MeHg. Specifically, biogeochemical conditions favoring microbial MeHg production do not necessarily translate to synchronous surface water exports; MeHg may be preserved in the soils allowing for release at a later time; and plants play a role in both biogeochemistry and transport. Our calculations show that NEP of MeHg occurred during both summer irrigation and winter flooding. Wild rice wet harvesting and winter flooding of white rice fields were specific practices that increased MeHg export, both presumably related to increased labile organic carbon and disturbance. Outflow management during these times could reduce MeHg exports. Standardizing MeHg outflow:inflow concentration ratios against natural tracers (e.g. chloride, EC) provides a simple tool to identify NEP periods. Summer MeHg exports averaged 0.2 to 1 μg m − 2 for the different agricultural wetland fields, depending upon flood duration. Average winter MeHg exports were estimated at 0.3 μg m − 2 . These exports are within the range reported for other shallow aquatic systems.

California↗

Urban proximity while breeding is not a predictor of perfluoroalkyl substance contamination in the eggs of brown pelicans

Identifying sources of exposure to chemical stressors is difficult when both target organisms and stressors are highly mobile. While previous studies have demonstrated that populations of some organisms proximal to urban centers may display increased burdens of human-created chemicals compared to more distal populations, this relationship may not be universal when applied to organisms and stressors capable of transboundary movements. We examined eggs of brown pelicans ( Pelecanus occidentalis ), a nearshore seabird with daily movements ranging from local to 50 km and annual migrations ranging from year-round residency to 1500 km. Thirty-six eggs from three breeding colonies located at increasing distances to a major urban center (Charleston, South Carolina, USA) were analyzed for concentrations of per - and polyfluoroalkyl substances (PFAS). Areas of high use for each colony during the breeding season were also assessed via the tracking of adult pelicans from each colony using GPS-PTT satellite transmitters and overlapped with measures of relative urbanization via land cover data. We report potentially significant ∑PFAS concentrations in the eggs of pelicans (175.4 ± 120.1 ng/g w wt. SD), driven largely by linear perfluorooctane sulfonate (n-PFOS) (48–546 ng/g w wt.). Residues of the precursor compound perfluorooctane sulfonamide (FOSA) were also present in pelican eggs, suggesting continued exposure of local wildlife beyond implemented phaseouts of some PFAS. For most analytes, egg concentrations did not exhibit a significant spatial structure despite some differentiation in high-use areas unlike similar data for another regional apex predator, the bottlenose dolphin ( Tursiops truncatus ). We suggest that the partially migratory nature of brown pelicans during the non-breeding season, combined with daily ranges that may extend to 50 km from local point sources, may have homogenized exposure across individuals. Charleston likely remains a major source for PFAS in the overall region, however, given the high concentrations observed as well as known releases of PFAS in the nearshore environment.

South Carolina↗

Tracking nonpoint source nitrogen pollution in human-impacted watersheds

Nonpoint source nitrogen (N) pollution is a leading contributor to U.S. water quality impairments. We combined watershed N mass balances and stable isotopes to investigate fate and transport of nonpoint N in forest, agricultural, and urbanized watersheds at the Baltimore Long-Term Ecological Research site. Annual N retention was 55%, 68%, and 82% for agricultural, suburban, and forest watersheds, respectively. Analysis of δ 15 N-NO 3 – , and δ 18 O-NO 3 – indicated wastewater was an important nitrate source in urbanized streams during baseflow. Negative correlations between δ 15 N-NO 3 – and δ 18 O-NO 3 – in urban watersheds indicated mixing between atmospheric deposition and wastewater, and N source contributions changed with storm magnitude (atmospheric sources contributed ∼50% at peak storm N loads). Positive correlations between δ 15 N-NO 3 – and δ 18 O-NO 3 – in watersheds suggested denitrification was removing septic system and agriculturally derived N, but N from belowground leaking sewers was less susceptible to denitrification. N transformations were also observed in a storm drain (no natural drainage network) potentially due to organic carbon inputs. Overall, nonpoint sources such as atmospheric deposition, wastewater, and fertilizer showed different susceptibility to watershed N export. There were large changes in nitrate sources as a function of runoff, and anticipating source changes in response to climate and storms will be critical for managing nonpoint N pollution.

Environmental Science & Technology↗

Surface-water/groundwater boundaries affect seasonal PFAS concentrations and PFAA precursor transformations​

Elevated concentrations of per- and polyfluoroalkyl substances (PFAS) in drinking-water supplies are a major concern for human health. It is therefore essential to understand factors that affect PFAS concentrations in surface water and groundwater and the transformation of perfluoroalkyl acid (PFAA) precursors that degrade into terminal compounds. Surface-water/groundwater exchange can occur along the flow path downgradient from PFAS point sources and biogeochemical conditions can change rapidly at these exchange boundaries. Here, we investigate the influence of surface-water/groundwater boundaries on PFAS transport and transformation. To do this, we conducted an extensive field-based analysis of PFAS concentrations in water and sediment from a flow-through lake fed by contaminated groundwater and its downgradient surface-water/groundwater boundary (defined as ≤100 cm below the lake bottom). PFAA precursors comprised 45 ± 4.6% of PFAS (PFAA precursors + 18 targeted PFAA) in the predominantly oxic lake impacted by a former fire-training area and historical wastewater discharges. In shallow porewater downgradient from the lake, this percentage decreased significantly to 25 ± 11%. PFAA precursor concentrations decreased by 85% between the lake and 84–100 cm below the lake bottom. PFAA concentrations increased significantly within the surface-water/groundwater boundary and in downgradient groundwater during the winter months despite lower stable concentrations in the lake water source. These results suggest that natural biogeochemical fluctuations associated with surface-water/groundwater boundaries may lead to PFAA precursor loss and seasonal variations in PFAA concentrations. Results of this work highlight the importance of dynamic biogeochemical conditions along the hydrological flow path from PFAS point sources to potentially affected drinking water supplies.

Massachusetts↗

Chromium isotopes and the fate of hexavalent chromium in the environment

Measurements of chromium (Cr) stable-isotope fractionation in laboratory experiments and natural waters show that lighter isotopes reacted preferentially during Cr(VI) reduction by magnetite and sediments. The 53 Cr/ 52 Cr ratio of the product was 3.4 ± 0.1 per mil less than that of the reactant. 53 Cr/ 52 Cr shifts in water samples indicate the extent of reduction, a critical process that renders toxic Cr(VI) in the environment immobile and less toxic.

Science↗

U.S. Geological Survey (USGS) Western Region Kasatochi Volcano Coastal and Ocean Science

Alaska is noteworthy as a region of frequent seismic and volcanic activity. The region contains 52 historically active volcanoes, 14 of which have had at least one major eruptive event since 1990. Despite the high frequency of volcanic activity in Alaska, comprehensive studies of how ecosystems respond to volcanic eruptions are non-existent. On August 7, 2008, Kasatochi Volcano, in the central Aleutian Islands, erupted catastrophically, covering the island with ash and hot pyroclastic flow material. Kasatochi Island was an annual monitoring site of the U.S. Fish and Wildlife Service, Alaska Maritime National Wildlife Refuge (AMNWR); therefore, features of the terrestrial and nearshore ecosystems of the island were well known. In 2009, the U.S. Geological Survey (USGS), AMNWR, and University of Alaska Fairbanks began long-term studies to better understand the effects of the eruption and the role of volcanism in structuring ecosystems in the Aleutian Islands, a volcano-dominated region with high natural resource values.

Fact Sheet↗

Factors affecting the toxicity of methylmercury injected into eggs

We developed a standardized protocol for comparing the sensitivities of the embryos of different bird species to methylmercury when methylmercury was injected into their eggs. During the course of developing this protocol, we investigated the effects of various factors on the toxicity of the injected methylmercury. Most of our experiments were done with chicken ( Gallus domesticus ), mallard ( Anas platyrhynchos ), and ring-necked pheasant ( Phasianus colchicus ) eggs, all of which were purchased in large numbers from game farms. A smaller amount of work was done with double-crested cormorant ( Phalacrocorax auritus ) eggs collected from the wild. Several solvents were tested, and corn oil at a rate of 1 μl/g egg contents was selected for the final standardized protocol because it had minimal toxicity to embryos and because methylmercury dissolved in corn oil yielded a dose–response curve in a range of egg concentrations that was similar to the range that causes reproductive impairment when the mother deposits methylmercury into her own eggs. The embryonic stage at which eggs were injected with corn oil altered mercury toxicity; at early stages, the corn oil itself was toxic. Therefore, in the final protocol we standardized the time of injection to occur when each species reached the morphologic equivalent of a 3-day-old chicken embryo. Although solvents can be injected directly into the albumen of an egg, high embryo mortality can occur in the solvent controls because of the formation of air bubbles in the albumen. Our final protocol used corn oil injections into the air cell, which are easier and safer than albumen injections. Most of the methylmercury, when dissolved in corn oil, injected into the air cell passes through the inner shell membrane and into the egg albumen. Most commercial incubators incubate eggs in trays with the air cell end of the egg pointing upward, but we discovered that mercury-induced mortality was too great when eggs were held in this orientation. In addition, some species of bird eggs require incubation on their sides with the eggs being rolled 180° for them to develop normally. Therefore, we adopted a procedure of incubating the eggs of all species on their sides and rolling them 180° every hour. Little has been published about the conditions of temperature, humidity, and the movements to which eggs of wild birds need to be subjected for them to hatch optimally under artificial incubation. Not unexpectedly, hatching success in an artificial incubator is generally less than what natural incubation by the parents can achieve. However, the survival of control embryos of most wild bird species was good (generally ≥ 80%) up to within 1 or 2 days of hatching when we incubated the eggs at 37.5°C (or 37.6°C for gallinaceous species) at a relative humidity that resulted in an approximate 15% to 16% loss in egg weight by the end of incubation and by incubating the eggs on their sides and rolling them 180°/h. To improve statistical comparisons, we used survival through 90% of incubation as our measurement to compare survival of controls with survival of eggs injected with graded concentrations of mercury.

Archives of Environmental Contamination and Toxico↗

Sources of terrestrially-derived organic carbon in lower Mississippi River and Louisiana shelf sediments: Implications for differential sedimentation and transport at the coastal margin

In this study, we examined the temporal and spatial variability of terrestrial organic carbon sources in lower Mississippi River and Louisiana shelf sediments (during 11 cruises over a 22-month period) to further understand the sorting dynamics and selective transport of vascular plant materials within the primary dispersal system of the river. Bulk ??13C values in lower river sediments ranged from -21.90??? to -24.64??? (mean=-23.20??1.09???), these values were generally more depleted than those found in shelf sediments (-22.5??? to -21.2???). The ??8 (??8 = sum of vanillyl, syringyl and cinnamyl phenols produced from the oxidation of 100 mg of organic carbon) values in the lower river ranged from 0.71 to 3.74 (mean = 1.78??0.23). While there was no significant relationship between ??8 and river discharge (p>0.05), the highest value occurred during peak discharge in April 1999-which corresponded to the highest observed C/N value of 17.41. The ??8 values on the shelf ranged from 0.68 to 1.36 (mean = 0.54??0.30) and were significantly lower (p <0.05) than the average value for lower river sediments. The range of S/V (syringyl/vanillyl) and C/V (cinnamyl/vanillyl) ratios on the shelf, 0.11 to 0.95 and 0.01 to 0.08, respectively, were similar to that found in the lower river. These low C/V ratios are indicative a mixture of woody and non-woody carbon sources. Recent work by Goni et al. [Nature 389 (1997) 275; Geochim. Cosmochim. Acta 62 (1998) 3055], which did not include sampling transects within the primary dispersal system of the Mississippi River, showed a non-woody vascular plant signature on the Louisiana shelf. This suggests that riverine-derived woody tissues preferentially settle out of the water column, in the lower river and inner shelf, prior to the selective dispersal of C3 versus C4 non-woody materials in other regions the shelf and slope. This works further demonstrates the importance of differential settlement of particles, sampling location within the dispersal system, and river discharge, when examining biogeochemical cycles in river-dominated margins. ?? 2002 Elsevier Science B.V. All rights reserved.

Marine Chemistry↗

Temporal variations in Global Seismic Stations ambient noise power levels

Recent concerns about time-dependent response changes in broadband seismometers have motivated the need for methods to monitor sensor health at Global Seismographic Network (GSN) stations. We present two new methods for monitoring temporal changes in data quality and instrument response transfer functions that are independent of Earth seismic velocity and attenuation models by comparing power levels against different baseline values. Our methods can resolve changes in both horizontal and vertical components in a broad range of periods (∼0.05 to 1,000 seconds) in near real time. In this report, we compare our methods with existing techniques and demonstrate how to resolve instrument response changes in long-period data (>100 seconds) as well as in the microseism bands (5 to 20 seconds). High quality broadband data recorded by the GSN are fundamental to characterizing a wide range of Earth science issues including: the size and rupture of large earthquakes ( e.g. , Tsai et al. 2005 ); imaging the interior of the Earth ( e.g. , Van der Hilst et al. 1997 ); tracking global climate variation ( Aster et al. 2008 ); and monitoring calving glaciers (Ekström et al. 2003 , 2006a ). Recent studies based on theoretical Earth models ( Ekström et al. 2006b ; Davis and Berger 2007 ) suggest that broadband seismometer gain levels can vary with time. This has also been confirmed, for the STS-1 sensor, experimentally ( Yuki and Ishihara 2002 ). It therefore has become necessary to systematically check for temporal changes in amplitude at GSN stations. Many of these changes are frequency-dependent in nature and not a priori predictable ( Ekström et al. 2006b ). Robust methods that can be applied to a large number of stations in a broad range of frequency bands are necessary.

Seismological Research Letters↗

Science for the stewardship of the groundwater resources of Cape Cod, Massachusetts

Groundwater is the sole source of drinking water and a major source of freshwater for domestic, industrial, and agricultural uses on Cape Cod, Massachusetts. Groundwater discharged from aquifers also supports freshwater pond and stream ecosystems and coastal wetlands. Six hydraulically distinct groundwater-flow systems (lenses) have been delineated on Cape Cod. Of the approximately 450 million gallons per day of water that enters these lenses as recharge from precipitation, about 69 percent discharges directly to the coast, about 24 percent discharges to streams, and almost 7 percent is withdrawn by public-supply wells. In most areas, groundwater in the sand and gravel aquifers is shallow and susceptible to contamination from anthropogenic sources and saltwater intrusion. Continued land development and population growth on Cape Cod have created concerns that potable water will become less available and that the quantity and quality of water flowing to natural discharge areas such as ponds, streams, and coastal waters will continue to decline. The U.S. Geological Survey (USGS) has been investigating groundwater and surface-water resources on Cape Cod for more than 50 years. Recent studies highlighted in this fact sheet have focused on the sources of water to public-supply wells, ponds, streams, and coastal areas; the transport and discharge of nitrogen derived from domestic and municipal disposal of wastewater; and the effects of climate change on groundwater and surface-water resources. Other USGS activities include long-term monitoring of groundwater and pond levels and field research on groundwater contamination at the USGS Cape Cod Toxic Substances Hydrology Research Site ( http://ma.water.usgs.gov/MMRCape/ ) near the Joint Base Cape Cod (JBCC), formerly the Massachusetts Military Reservation.

Massachusetts↗

Groundwater quality of aquifers overlying the Oxnard Oil Field, Ventura County, California

Groundwater samples collected from irrigation, monitoring, and municipal supply wells near the Oxnard Oil Field were analyzed for chemical and isotopic tracers to evaluate if thermogenic gas or water from hydrocarbon-bearing formations have mixed with surrounding groundwater. New and historical data show no evidence of water from hydrocarbon-bearing formations in groundwater overlying the field. However, thermogenic gas mixed with microbial methane was detected in 5 wells at concentrations ranging from 0.011–9.1 mg/L. The presence of these gases at concentrations <10 mg/L do not indicate degraded water quality posing a known health risk. Analysis of carbon isotopes (δ 13 C-CH 4 ) and hydrogen isotopes (δ 2 H-CH 4 ) of methane and ratios of methane to heavier hydrocarbon gases were used to differentiate sources of methane between a) microbial, b) thermogenic or c) mixed sources. Results indicate that microbial-sourced methane is widespread in the study area, and concentrations overlap with those from thermogenic sources. The highest concentrations of thermogenic gas were observed in proximity to relatively high density of oil wells, large injection volumes of water disposal and cyclic steam, shallow oil development, and hydrocarbon shows in sediments overlying the producing oil reservoirs. Depths of water wells containing thermogenic gas were within approximately 200 m of the top of the Vaca Tar Sand production zone (approximately 600 m below land surface). Due to the limited sampling density, the source and pathways of thermogenic gas detected in groundwater could not be conclusively determined. Thermogenic gas detected in the absence of co-occurring water from hydrocarbon-bearing formations may result from natural gas migration over geologic time from the Vaca Tar Sand or deeper formations, hydrocarbon shows in sediments overlying producing zones, and/or gas leaking from oil-field infrastructure. Denser sampling of groundwater, potential end-members, and pressure monitoring could help better distinguish pathways of thermogenic gases.

California↗

Future of gas hydrate research

Methane hydrates are ice‐like inclusion compounds, in which every volume of hydrate can contain as much as 180 volumes (STP) of gas.The amount of methane in natural gas hydrates is twice the total recoverable fossil fuel reserve. Because of their natural abundance in oceans and permafrost, hydrates have become an exciting national and international research issue. The movement of the gas and oil industry to ever deepening waters where hydrates occur, the compelling size and distribution of hydrate deposits, and strong international interest all support identification of crucial elements in a hydrate research program.

Eos, Earth and Space Science News↗

Leveraging risk communication science across US federal agencies

Many US federal agencies apply principles from risk communication science across a wide variety of hazards. In so doing, they identify key research and practice gaps that, if addressed, could help better serve the nation’s communities and greatly enhance practice, research, and policy development.

Nature Human Behavior↗

Flexible migration and habitat use strategies of an endangered waterbird during hydrological drought

Wildlife species confront threats from climate and land use change, exacerbating the influence of extreme climatic events on populations and biodiversity. Migratory waterbirds are especially vulnerable to hydrological drought via reduced availability of surface water habitats. We assessed how whooping cranes ( Grus americana ) modified habitat use and migration strategies during drought to evaluate their resilience to changing conditions and adaptive capacity. We categorized >8000 night-roost sites used by 146 cranes from 2010 to 2022 and examined relative use during non-drought, moderate drought, and extreme drought conditions. We found cultivated and uncultivated palustrine and lacustrine wetlands were generally used less during droughts than non-drought conditions. Conversely, impounded palustrine and lacustrine systems and rivers served more frequently as drought refugia (i.e., used more during drought than non-drought conditions). Night roosts occurred primarily on private lands (86% overall); public land use decreased with latitude and increased with drought severity, with greatest use (56%) occurring during severe autumn drought in the southern Great Plains. Quantifying use of identified critical habitats in the United States indicated that Cheyenne Bottoms State Waterfowl Management Area and Quivira National Wildlife Refuge were used less during drought, and the Central Platte River and Salt Plains National Wildlife Refuge received similar use during drought compared to non-drought conditions. Our findings provide insights into compensatory use of habitats, where impounded surface water may function in a complementary fashion with natural wetlands. Collectively, these and other types of wetlands distributed across the migration corridor provided a reliable network of habitat available across the Great Plains. A diversity of wetlands available during variable environmental conditions would be useful in supporting continued recovery of whooping cranes and likely have benefits for a wide array of migratory birds.

Conservation Science and Practice↗

Undeveloped and developed phases in the centennial evolution of a barrier-marsh-lagoon system: The case of Long Beach Island, New Jersey

Barrier islands and their associated backbarrier environments protect mainland population centers and infrastructure from storm impacts, support biodiversity, and provide long-term carbon storage, among other ecosystem services. Despite their socio-economic and ecological importance, the response of coupled barrier-marsh-lagoon environments to sea-level rise is poorly understood. Undeveloped barrier-marsh-lagoon systems typically respond to sea-level rise through the process of landward migration, driven by storm overwash and landward mainland marsh expansion. Such response, however, can be affected by human development and engineering activities such as lagoon dredging and shoreline stabilization. To better understand the difference in the response between developed and undeveloped barrier-marsh-lagoon environments to sea-level rise, we perform a local morphologic analysis that describes the evolution of Long Beach Island (LBI), New Jersey, over the last 182 years. We find that between 1840 and 1934 the LBI system experienced landward migration of all five boundaries, including 171 meters of shoreline retreat. Between the 1920s and 1950s, however, there was a significant shift in system behavior that coincided with the onset of groin construction, which was enhanced by beach nourishment and lagoon dredging practices. From 1934 to 2022 the LBI system experienced ~22 meters of shoreline progradation and a rapid decline in marsh platform extent. Additionally, we extend a morphodynamic model to describe the evolution of the system in terms of five geomorphic boundaries: the ocean shoreline and backbarrier-marsh interface, the seaward and landward lagoon-marsh boundaries, and the landward limit of the inland marsh. We couple this numerical modeling effort with the map analysis during the undeveloped phase of LBI evolution, between 1840 and 1934. Despite its simplicity, the modeling framework can describe the average cross-shore evolution of the barrier-marsh-lagoon system during this period without accounting for human landscape modifications, supporting the premise that natural processes were the key drivers of morphological change. Overall, these results suggest that anthropogenic effects have played a major role in the evolution of LBI over the past century by altering overwash fluxes and marsh-lagoon geometry; this is likely the case for other barrier-marsh-lagoon environments around the world.

New Jersey↗

Report on the 2010 Chilean earthquake and tsunami response

In July 2010, in an effort to reduce future catastrophic natural disaster losses for California, the American Red Cross coordinated and sent a delegation of 20 multidisciplinary experts on earthquake response and recovery to Chile. The primary goal was to understand how the Chilean society and relevant organizations responded to the magnitude 8.8 Maule earthquake that struck the region on February 27, 2010, as well as how an application of these lessons could better prepare California communities, response partners and state emergency partners for a comparable situation. Similarities in building codes, socioeconomic conditions, and broad extent of the strong shaking make the Chilean earthquake a very close analog to the impact of future great earthquakes on California. To withstand and recover from natural and human-caused disasters, it is essential for citizens and communities to work together to anticipate threats, limit effects, and rapidly restore functionality after a crisis. The delegation was hosted by the Chilean Red Cross and received extensive briefings from both national and local Red Cross officials. During nine days in Chile, the delegation also met with officials at the national, regional, and local government levels. Technical briefings were received from the President’s Emergency Committee, emergency managers from ONEMI (comparable to FEMA), structural engineers, a seismologist, hospital administrators, firefighters, and the United Nations team in Chile. Cities visited include Santiago, Talca, Constitución, Concepción, Talcahuano, Tumbes, and Cauquenes. The American Red Cross Multidisciplinary Team consisted of subject matter experts, who carried out special investigations in five Teams on the (1) science and engineering findings, (2) medical services, (3) emergency services, (4) volunteer management, and (5) executive and management issues (see appendix A for a full list of participants and their titles and teams). While developing this delegation, it was clear that a multidisciplinary approach was required to properly analyze the emergency response, technical, and social components of this disaster. A diverse and knowledgeable delegation was necessary to analyze the Chilean response in a way that would be beneficial to preparedness in California, as well as improve mitigation efforts around the United States. By most standards, the Maule earthquake was a catastrophe for Chile. The economic losses totaled $30 billion USD or 17% of the GDP of the country. Twelve million people, or ¾ of the population of the country, were in areas that felt strong shaking. Yet only 521 fatalities have been confirmed, with 56 people still missing and presumed dead in the tsunami. The Science and Technology Team evaluated the impacts of the earthquake on built environment with implications for the United States. The fires following the earthquake were minimal in part because of the shutdown of the national electrical grid early in the shaking. Only five engineer-designed buildings were destroyed during the earthquake; however, over 350,000 housing units were destroyed. Chile has a law that holds building owners liable for the first 10 years of a building’s existence for any losses resulting from inadequate application of the building code during construction. This law was cited by many our team met with as a prime reason for the strong performance of the built environment. Overall, this earthquake demonstrated that strict building codes and standards could greatly reduce losses in even the largest earthquakes. In the immediate response to the earthquake and tsunami, first responders, emergency personnel, and search and rescue teams handled many challenges. Loss of communications was significant; many lives were lost and effective coordination to support life-sustaining efforts was gravely impacted due to a lack of inter- and intra-agency coordination. The Health and Medical Services Team sought to understand the medical disaster response strategies and operations of Chilean agencies, including perceived or actual failures in disaster preparation that impacted the medical disaster response; post-disaster health and medical interventions to save lives and limit suffering; and the lessons learned by public health and medical personnel as a result of their experiences. Despite devastating damage to the health care and civic infrastructure, the health care response to the Chilean earthquake appeared highly successful due to several factors. Like other first responders, the medical community had the ability and resourcefulness to respond without centralized control in the early response phase. The health care community maintained patient care under austere conditions, despite many obstacles that could have prevented such care. National and international resources were rapidly mobilized to support the medical response. The Emergency Services Team sought to collect information on all phases of emergency management (preparedness, mitigation, response, and recovery) and determine what worked well and what could be improved upon. The Chileans reported being surprised that they were not as ready for this event as they thought they were. The use of mass care sheltering was limited, given the scope of the disaster, because of the resiliency of the population. The impacts of the earthquake and the tsunami were quite different, as were the needs of urban and rural dwellers, necessitating different response activities. The Volunteer Services Team examined the challenges faced in mobilizing a large number of volunteers to assist in the aftermath of a disaster of this scale. One of the greatest challenges expressed was difficulty in communication; the need for redundancy in communication mechanisms was cited. The flexibility and ability to work autonomously by the frontline volunteers was a significant factor in effective response. It was also important for volunteer leadership to know the emergency plans. These plans need to be flexible, include alternative options, and be completed in conjunction with local officials and other volunteers. The Executive/Red Cross Management Team took a broad look at the impacts of the earthquake and the implications for California. Some of the most important preparation for the disaster came from relationships formed before the event. The communities with strong connections between different government services generally fared well. The initial response and resilience of individuals and communities was another important component. Communication system failures limited the ability of a central government to assist impacted communities, or to issue tsunami warnings. It also delayed the response since the government did not know (in some case for several days) the impact and needs of local governments. In general, plans for congregate care shelters existed but were little used as most people chose to stay at damaged homes or with relatives. Looting was a surprise to response officials as well as social scientists, but both public and private sector organizations, including NGOs (Non-Governmental Organizations), must consider security for damaged businesses as a priority in California’s multihazard planning. Class and ethnic divisions that become heightened during some cases of actual or perceived injustice may also emerge in natural disasters in California. Several factors contributed overall to the low casualty rate and rapid recovery. A major factor is the strong building code in Chile and its comprehensive enforcement. In particular, Chile has a law that holds building owners accountable for losses in a building they build for 10 years. A second factor was the limited number of fires after the earthquake. In the last few California earthquakes, 60% of the fires were started by electrical problems, so the rarity of fires may have been affected by the shut down of the electricity grid early in the earthquake. Third, in many areas, the local emergency response was very effective. The most effective regions had close coordination between emergency management, fire, and police and were empowered to respond without communication with the capital. The fourth factor was the overall high level of knowledge about earthquakes and tsunamis by much of the population that helped them respond more appropriately after the event.

Open-File Report↗

Statistical facilitation in environmental science: Integrating results from complementary statistical analyses can improve ecological interpretations

Professionals working in biological conservation seek to understand, manage, and restore populations of native organisms using many techniques. A common approach for this discipline is using long-term data collections to inform decision making. However, several quantitative issues complicate statistical analysis of monitoring datasets and can reduce the utility of results for conservation decision making. Integrating results from multiple analyses applied to the same dataset (i.e., approaching the same biological problem using different techniques) is one way to address concerns related to field data that violate statistical assumptions. This process allows data analysts, researchers, and managers to assemble insights based on the weight of evidence. Here we tested whether three different statistical techniques [(1) multiple logistic regression on original data, (2) multiple logistic regression on standardized data (i.e., mean of 0 and standard deviation of 1), and (3) random forest analysis] identified a similar hierarchy for selecting natural and anthropogenic habitat regressors. Our examination of how environmental variables affected Plains Minnow ( Hybognathus placitus ), a state-threatened fish, is relevant to other taxa and locations. We gained useful information from redundancies (i.e., agreements across analyses). New directions also emerged by addressing ambiguities (i.e., disagreements among results across analyses). When multiple analyses were integrated into one ecological story, a clearer interpretation emerged. Viewing different statistical tests as facilitators that provide mutual advantages can advance the understanding and application of statistical analyses applied to non-experimental field datasets.

Kansas↗