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At least 1,477 records · Page 82Linked to original sources

Hydrology and ground-water quality in the mine workings within the Picher Mining District, Northeastern Oklahoma, 2002-03

The Picher mining district of northeastern Ottawa County, Oklahoma, was a major site of mining for lead and zinc ores in the first half of the 20th century. The primary source of lead and zinc were sulfide minerals disseminated in the cherty limestones and dolomites of the Boone Formation of Mississippian age, which comprises the Boone aquifer. Ground water in the aquifer and seeping to surface water in the district has been contaminated by sulfate, iron, lead, zinc, and several other metals. The U.S. Geological Survey, in cooperation with the Oklahoma Department of Environmental Quality, investigated hydrology and ground-water quality in the mine workings in the mining district, as part of the process to aid water managers and planners in designing remediation measures that may restore the environmental quality of the district to pre-mining conditions. Most ground-water levels underlying the mining district had similar altitudes, indicating a large degree of hydraulic connection in the mine workings and overlying aquifer materials. Recharge-age dates derived from concentrations of chlorofluorocarbons and other dissolved gases indicated that water in the Boone aquifer may flow slowly from the northeast and southeast portions of the mining district. However, recharge-age dates may have been affected by the types of sites sampled, with more recent recharge-age dates being associated with mine-shafts, which are more prone to atmospheric interactions and surface runoff than the sampled airshafts. Water levels in streams upstream from the confluence of Tar and Lytle Creeks were several feet higher than those in adjacent portions of the Boone aquifer, perhaps due to low-permeability streambed sediments and indicating the streams may be losing water to the aquifer in this area. From just upstream to downstream from the confluence of Tar and Lytle Creeks, surface-water elevations in these streams were less than those in the surrounding Boone aquifer, indicating that seepage from the aquifer to downstream portions of Tar Creek was much more likely. Water properties and major-ion concentrations indicate that water in the mining area was very hard, with large concentrations of dissolved solids that increased from areas of presumed recharge toward areas with older ground water. Most of the ground-water samples, particularly those from the airshafts, had dissolved-oxygen concentrations less than 1.0 milligram per liter. Small concentrations of dissolved oxygen may have been introduced during the sampling process. The small dissolved-oxygen concentrations were associated with samples containing large iron concentrations that indicates possible anoxic conditions in much of the aquifer. Ground water in the mining district was dominated by calcium, magnesium, and sulfate. Sodium concentrations tended to increase relative to calcium and magnesium concentrations. Ground-water samples collected in 2002-03 had large concentrations of many trace elements. Larger concentrations of metals and sulfate occurred in ground water with smaller pHs and dissolved-oxygen concentrations. Iron was the metal with the largest concentrations in the ground-water samples, occurring at concentrations up to 115,000 micrograms per liter. Cadmium, lead, manganese, zinc, and the other analyzed metals occurred in smaller concentrations in ground water than iron. However, larger cadmium concentrations appeared to be associated with sites that have small iron concentrations and more oxygenated waters. This is noteworthy because the small sulfate and iron concentrations in these waters could lead to conclusions that the waters are less contaminated than waters with large sulfate and iron concentrations. Ground-water quality in the mining district was compared with subsets of samples collected in 1983-85 and in 2002.

Oklahoma↗

Geohydrology of the lower Apalachicola-Chattahoochee-Flint River basin, southwestern Georgia, northwestern Florida, and southeastern Alabama

The lower Apalachicola-Chattahoochee-Flint (ACF) River Basin contains about 4,600 square miles of karstic and fluvial plains and nearly 100,000 cubic miles of predominantly karst limestone connected hydraulically to the principal rivers and lakes in the Coastal Plain of southwestern Georgia, northwestern Florida, and southwestern Alabama. Sediments of late-middle Eocene to Holocene in hydraulic connection with lakes, streams, and land surface comprise the surficial aquifer system, upper semiconfining unit, Upper Floridan aquifer, and lower semiconfining unit and contribute to the exchange of ground water and surface water in the stream-lake-aquifer flow system. Karst processes, hydraulic properties, and stratigraphic relations limit ground-water and surface-water interaction to the following hydrologic units of the stream-lake-aquifer flow system: the surficial aquifer system, upper semiconfining unit, Upper Floridan aquifer, and lower confining unit. Geologic units corresponding to these hydrologic units are, in ascending order: Lisbon Formation; Clinchfield Sand; Ocala, Marianna, Suwannee, and Tampa Limestones; Hawthorn Group; undifferentiated overburden (residuum); and terrace and undifferentiated (surficial) deposits. Similarities in hydraulic properties and direct or indirect interaction with surface water allow grouping sediments within these geologic units into the aforementioned hydrologic units, which transcend time-stratigraphic classifications and define the geohydrologic framework for the lower ACF River Basin. The low water-transmitting properties of the lower confining unit, principally the Lisbon Formation, allow it to act as a nearly impermeable base to the stream-lake-aquifer flow system. Hydraulic connection of the surficial aquifer system with surface water and the Upper Floridan aquifer is direct where sandy deposits overlie the limestone, or indirect where fluvial deposits overlie clayey limestone residuum. The water level in perched zones within the surficial aquifer system fluctuates independently of water-level changes in the underlying aquifer, adjacent streams, or lakes. Where the surficial aquifer system is connected with surface water and the Upper Floridan aquifer, water-table fluctuations parallel those in adjacent streams or the underlying aquifer. More...

Alabama, Florida, Georgia↗

Construction of estimated flow- and load-duration curves for Kentucky using the W ater A vailability T ool for E nvironmental R esources (WATER)

Flow- and load-duration curves were constructed from the model outputs of the U.S. Geological Survey's Water Availability Tool for Environmental Resources (WATER) application for streams in Kentucky. The WATER application was designed to access multiple geospatial datasets to generate more than 60 years of statistically based streamflow data for Kentucky. The WATER application enables a user to graphically select a site on a stream and generate an estimated hydrograph and flow-duration curve for the watershed upstream of that point. The flow-duration curves are constructed by calculating the exceedance probability of the modeled daily streamflows. User-defined water-quality criteria and (or) sampling results can be loaded into the WATER application to construct load-duration curves that are based on the modeled streamflow results. Estimates of flow and streamflow statistics were derived from TOPographically Based Hydrological MODEL (TOPMODEL) simulations in the WATER application. A modified TOPMODEL code, SDP-TOPMODEL (Sinkhole Drainage Process-TOPMODEL) was used to simulate daily mean discharges over the period of record for 5 karst and 5 non-karst watersheds in Kentucky in order to verify the calibrated model. A statistical evaluation of the model's verification simulations show that calibration criteria, established by previous WATER application reports, were met thus insuring the model's ability to provide acceptably accurate estimates of discharge at gaged and ungaged sites throughout Kentucky. Flow-duration curves are constructed in the WATER application by calculating the exceedence probability of the modeled daily flow values. The flow-duration intervals are expressed as a percentage, with zero corresponding to the highest stream discharge in the streamflow record. Load-duration curves are constructed by applying the loading equation (Load = Flow*Water-quality criterion) at each flow interval.

Kentucky↗

Importance of hydrologic data for interpreting wetland maps and assessing wetland loss and mitigation

The US Geological Survey collects and disseminates, in written and digital formats, groundwater and surface-water information related to the tidal and nontidal wetlands of the United States. This information includes quantity, quality, and availability of groundwater and surface water; groundwater and surface-water interactions (recharge-discharge); groundwater flow; and the basic surface-water characteristics of streams, rivers, lakes, and wetlands. Water resources information in digital format can be used in geographic information systems (GISs) for many purposes related to wetlands. US Geological Survey wetland-related activities include collection of information important for assessing and mitigating coastal wetland loss and modification, hydrologic data collection and interpretation, GIS activities, identification of national trends in water quality and quantity, and process-oriented wetland research. -Author

Biological Report - US Fish & Wildlife Service↗

Hydrogeologic structure underlying a recharge pond delineated with shear-wave seismic reflection and cone penetrometer data

With the goal of improving the understanding of the subsurface structure beneath the Harkins Slough recharge pond in Pajaro Valley, California, USA, we have undertaken a multimodal approach to develop a robust velocity model to yield an accurate seismic reflection section. Our shear-wave reflection section helps us identify and map an important and previously unknown flow barrier at depth; it also helps us map other relevant structure within the surficial aquifer. Development of an accurate velocity model is essential for depth conversion and interpretation of the reflection section. We incorporate information provided by shear-wave seismic methods along with cone penetrometer testing and seismic cone penetrometer testing measurements. One velocity model is based on reflected and refracted arrivals and provides reliable velocity estimates for the full depth range of interest when anchored on interface depths determined from cone data and borehole drillers' logs. A second velocity model is based on seismic cone penetrometer testing data that provide higher-resolution ID velocity columns with error estimates within the depth range of the cone penetrometer testing. Comparison of the reflection/refraction model with the seismic cone penetrometer testing model also suggests that the mass of the cone truck can influence velocity with the equivalent effect of approximately one metre of extra overburden stress. Together, these velocity models and the depth-converted reflection section result in a better constrained hydrologic model of the subsurface and illustrate the pivotal role that cone data can provide in the reflection processing workflow. ?? 2009 European Association of Geoscientists & Engineers.

Near Surface Geophysics↗

Application of MODFLOW’s farm process to California’s Central Valley

Historically, California’s Central Valley has been one of the most productive agricultural regions in the world. The Central Valley also is rapidly becoming an important area for California’s expanding urban population. During 1980–2007, the population nearly doubled in the Central Valley, increasing the competition for water. Because of the importance of ground water in the Central Valley, the U.S. Geological Survey (USGS) Ground-Water Resources Program is evaluating ground-water conditions in the valley on the basis of historical and anticipated water use. This study updates the USGS Central Valley Regional Aquifer System and Analysis (CVRASA) model that was originally? calibrated to observed conditions for the period 1961-77. The model developed for this study utilizes MODFLOW-2000, and was calibrated to observed conditions for the period 1961-2003. Key updates include characterization of the aquifer system using a detailed textural analysis of more than 8,500 drillers’ logs; use of the MODFLOW subsidence package (SUB) to simulate aquifer-system compaction; and, most importantly, use of the newly developed MODFLOW Farm Process (FMP) for simulating irrigation and other landscape processes. The FMP provides coupled simulation of the ground-water and surface-water components of the hydrologic cycle for irrigated and non-irrigated areas. A dynamic allocation of ground-water recharge and ground-water pumping is simulated on the basis of residual crop-water demand after surface-water deliveries and root uptake from shallow ground water. The FMP links with the Streamflow Routing Package SFR1) to facilitate the simulated conveyance of surface-water deliveries. Ground-water Pumpage through both single-aquifer and multi-node wells, irrigation return flow, and variable irrigation efficiencies also are simulated by the FMP. The simulated deliveries and ground-water pumpage in the updated model reflect climatic differences, differences among defined water-balance regions, and changes in the waterdelivery system, during the 1961–2003 simulation period. The model is designed to accept forecasts from Global Climate Models (GCMs) to simulate the potential effects on surface-water delivery, ground-water pumpage, and ground-water storage in response to climate change. The model provides a detailed transient analysis of changes in ground-water availability in relation to climatic variability, urbanization, and changes in irrigated agriculture.

Conference Paper↗

Estimating Water Storage Capacity of Existing and Potentially Restorable Wetland Depressions in a Subbasin of the Red River of the North

Executive Summary Concern over flooding along rivers in the Prairie Pothole Region has stimulated interest in developing spatially distributed hydrologic models to simulate the effects of wetland water storage on peak river flows. Such models require spatial data on the storage volume and interception area of existing and restorable wetlands in the watershed of interest. In most cases, information on these model inputs is lacking because resolution of existing topographic maps is inadequate to estimate volume and areas of existing and restorable wetlands. Consequently, most studies have relied on wetland area to volume or interception area relationships to estimate wetland basin storage characteristics by using available surface area data obtained as a product from remotely sensed data (e.g., National Wetlands Inventory). Though application of areal input data to estimate volume and interception areas is widely used, a drawback is that there is little information available to provide guidance regarding the application, limitations, and biases associated with such approaches. Another limitation of previous modeling efforts is that water stored by wetlands within a watershed is treated as a simple lump storage component that is filled prior to routing overflow to a pour point or gaging station. This approach does not account for dynamic wetland processes that influence water stored in prairie wetlands. Further, most models have not considered the influence of human-induced hydrologic changes, such as land use, that greatly influence quantity of surface water inputs and, ultimately, the rate that a wetland basin fills and spills. The goals of this study were to (1) develop and improve methodologies for estimating and spatially depicting wetland storage volumes and interceptions areas and (2) develop models and approaches for estimating/simulating the water storage capacity of potentially restorable and existing wetlands under various restoration, land use, and climatic scenarios. To address these goals, we developed models and approaches to spatially represent storage volumes and interception areas of existing and potentially restorable wetlands in the upper Mustinka subbasin within Grant County, Minn. We then developed and applied a model to simulate wetland water storage increases that would result from restoring 25 and 50 percent of the farmed and drained wetlands in the upper Mustinka subbasin. The model simulations were performed during the growing season (May-October) for relatively wet (1993; 0.79 m of precipitation) and dry (1987; 0.40 m of precipitation) years. Results from the simulations indicated that the 25 percent restoration scenario would increase water storage by 21-24 percent and that a 50 percent scenario would increase storage by 34-38 percent. Additionally, we estimated that wetlands in the subbasin have potential to store 11.57-20.98 percent of the total precipitation that fell over the entire subbasin area (52,758 ha). Our simulation results indicated that there is considerable potential to enhance water storage in the subbasin; however, evaluation and calibration of the model is necessary before simulation results can be applied to management and planning decisions. In this report we present guidance for the development and application of models (e.g., surface area-volume predictive models, hydrology simulation model) to simulate wetland water storage to provide a basis from which to understand and predict the effects of natural or human-induced hydrologic alterations. In developing these approaches, we tried to use simple and widely available input data to simulate wetland hydrology and predict wetland water storage for a specific precipitation event or a series of events. Further, the hydrology simulation model accounted for land use and soil type, which influence surface water inputs to wetlands. Although information presented in this report is specific to the Mustinka subbasin, the approaches

Open-File Report↗

An integrated approach to conjunctive-use analysis with the one-water hydrologic flow model, MODFLOW-OWHM

The MODFLOW-2005 (MF) family of hydrologic simulators has diverged into multiple versions designed for specific needs, thus limiting their use to their respective designs. The One-Water Hydrologic Flow Model (MF-OWHM v1.0) is an integrated hydrologic flow model that is an enhanced fusion of multiple MF versions. While maintaining compatibility with existing MF versions, MF-OWHM includes: linkages for coupled heads, flows, and deformation; facilitation of self-updating models, additional observation and parameter options for higher-order calibrations; and redesigned code for faster simulations. This first release of MF-OWHM incorporates MODFLOW-2005 and the Farm Process (MF-FMP2), with new features (FMP3), combined with Local Grid Refinement (MF-LGR), Streamflow Routing (SFR), Surfacewater Routing Process (SWR), Seawater Intrusion (SWI), Riparian Evapotranspiration (RIP-ET), the Newton Formulation (MF-NWT), and more. MF-OWHM represents a complete integrated hydrologic model that fully links the movement and use of groundwater, surface water, and imported water for consumption by agriculture and natural vegetation on the landscape, and for potable and other uses. By retaining and keeping track of the water during simulation of the hydrosphere, MF-OWHM accounts for “all of the water everywhere and all of the time.” This provides the foundation needed to address integrated hydrologic problems such as evaluation of conjunctive-use alternatives and sustainability analysis, including potential adaptation and mitigation strategies, and best management practices.

Conference Paper↗

Hydrologic investigations of prairie potholes in North Dakota, 1959-68

A prairie pothole is a depression in the prau1e, capable of storing water, that is the result of glacial processes. Years ago, there were many hundreds of thousands of prairie potholes in the North-Central United States, but large numbers of them have been drained for agricultural use. This report is limited to studies of prairie potholes in the eastern part of the glaciated northern Great Plains region in North Dakota-a rolling upland area covered with glacial drift, called the Coteau du Missouri. Potholes are wetlands that are the primary breeding area of migratory waterfowl in the United States. If production of waterfowl is to continue, suitable wetlands must be maintained, and even new wetlands created to offset those destroyed for agricultural use. The initial stage of the Garrison Diversion Unit calls for a normal annual diversion from Garrison Reservoir of 60,000 acre-feet of water for this purpose. Many prairie potholes contain large amounts of emergent aquatic vegetatjon known as hydrophytes. Determining the loss of water by transpiration from emergent hydrophytes was one of the major objectives of the present study of the hydrology of prairie potholes. Other hydrologic factors were studied later, but the first part of the study was devoted almost exclusively to the determination of evaporation and transpiration losses at groups of potholes in Ward, Stutsman, and Dickey Counties. The mass-transfer method was used, and by determining the variation in the mass-transfer coefficient throughout a season, the losses by evaporation and transpiration were determined separately. Separate determinations were accomplished by relating the emergent height and the moisture content of the hydrophytes to the rate of transpiration, as determined by the mass-transfer coefficient. Seasonal evaporation from the study potholes clear of vegetation was found to very nearly equal the generalized evaporation values published by the U.S. Weather Bureau. The effect of hydrophytes in potholes was twofold: their presence reduced evaporation from the water surfaces; and, at the height of the growing season, their transpiration rate, added to the reduced evaporation rate, frequently was greater than the evaporation rate from potholes clear of vegetation. Net seepage outflow from potholes was generally very small-less than 0.01 foot per day per unit of water surface. This rate of seepage was not insignificant, however, because it often amounted to more than one-fourth of the total seasonal .loss of water from a pothole. The source of water supplying the evapotranspiration losses was primarily precipitation on the water surface of a pothole pond. Augmenting this supply was basin inflowoverland flow, flow in channels, and seepage inflow. Of these, overland flow was estimated to have been the largest by far; direct observations were not possible. Basin inflow was very erratic; it depended on combinations of events, such as antecedent soil moisture and rainfall intensity, or depth of snow at time of melting and concurrent rainfall. The occurrences of these combinations were such that, for a given season (October-March or April-September), the total basin inflow generally showed little relation to total precipitation. The greatest inflows were associated with late snowmelt flowing over frozen ground. Following the evapotranspiration study, the effects of ground-water movement were investigated. All the study potholes were located in areas of glacial till in order to reduce the effect of seepage in the mass-transfer computations. Accordingly, ground-water movement was not a major factor in the water budget of the study potholes; however, it could be, in potholes located in areas of outwash sands and gravels, and in potholes in glacial till with only temporary ponds. Also, the direction of ground-water movement has a controlling effect on the water quality of a pothole pond. Where there is no seepage outflow or overflow, there is no mechanism for the removal of dissolved solids brought to the pond by basin inflow. Such potholes are saline-some even more so than sea water. Conversely, potholes that receive no seepage inflow generally contain fresh water and are usually not permanent. All conditions between these two extremes were found. The permanence of water in a pothole (the extent to which the water body is permanent) and its quality were found to have a direct and significant relation to the species of vegetation that grows under those conditions. In fact, the species of vegetation are excellent indicators of water quality and permanence, and the report contains a table listing the common species used as indicators and the conditions that they indicate. Many other facets of the hydrology of prairie potholes were investigated to ensure that no major factor was ignored, and the investigation results are described briefly.

North Dakota↗

Hydrological connectivity for riverine fish: measurement challenges and research opportunities

In this review, we first summarize how hydrologic connectivity has been studied for riverine fish capable of moving long distances, and then identify research opportunities that have clear conservation significance. Migratory species, such as anadromous salmonids, are good model organisms for understanding ecological connectivity in rivers because the spatial scale over which movements occur among freshwater habitats is large enough to be easily observed with available techniques; they are often economically or culturally valuable with habitats that can be easily fragmented by human activities; and they integrate landscape conditions from multiple surrounding catchment(s) with in‐river conditions. Studies have focussed on three themes: (i) relatively stable connections (connections controlled by processes that act over broad spatio‐temporal scales >1000 km 2 and >100 years); (ii) dynamic connections (connections controlled by processes acting over fine to moderate spatio‐temporal scales ∼1–1000 km 2 and <1–100 years); and (iii) anthropogenic influences on hydrologic connectivity, including actions that disrupt or enhance natural connections experienced by fish. We outline eight challenges to understanding the role of connectivity in riverine fish ecology, organized under three foci: (i) addressing the constraints of river structure; (ii) embracing temporal complexity in hydrologic connectivity; and (iii) managing connectivity for riverine fishes. Challenges include the spatial structure of stream networks, the force and direction of flow, scale‐dependence of connectivity, shifting boundaries, complexity of behaviour and life histories and quantifying anthropogenic influence on connectivity and aligning management goals. As we discuss each challenge, we summarize relevant approaches in the literature and provide additional suggestions for improving research and management of connectivity for riverine fishes. Specifically, we suggest that rapid advances are possible in the following arenas: (i) incorporating network structure and river discharge into analyses; (ii) increasing explicit consideration of temporal complexity and fish behaviour in the scope of analyses; and (iii) parsing degrees of human and natural influences on connectivity and defining acceptable alterations. Multiscale analyses are most likely to identify dominant patterns of connections and disconnections, and the appropriate scale at which to focus conservation activities.

Freshwater Biology↗

Watershed-scale response to climate change through the twenty-first century for selected basins across the United States

The hydrologic response of different climate-change emission scenarios for the twenty-first century were evaluated in 14 basins from different hydroclimatic regions across the United States using the Precipitation-Runoff Modeling System (PRMS), a process-based, distributed-parameter watershed model. This study involves four major steps: 1) setup and calibration of the PRMS model in 14 basins across the United States by local U.S. Geological Survey personnel; 2) statistical downscaling of the World Climate Research Programme’s Coupled Model Intercomparison Project phase 3 climate-change emission scenarios to create PRMS input files that reflect these emission scenarios; 3) run PRMS for the climate-change emission scenarios for the 14 basins; and 4) evaluation of the PRMS output. This paper presents an overview of this project, details of the methodology, results from the 14 basin simulations, and interpretation of these results. A key finding is that the hydrological response of the different geographical regions of the United States to potential climate change may be very different, depending on the dominant physical processes of that particular region. Also considered is the tremendous amount of uncertainty present in the climate emission scenarios and how this uncertainty propagates through the hydrologic simulations. This paper concludes with a discussion of the lessons learned and potential for future work.

Earth Interactions↗

Climate change and the eco-hydrology of fire: Will area burned increase in a warming western USA?

Wildfire area is predicted to increase with global warming. Empirical statistical models and process-based simulations agree almost universally. The key relationship for this unanimity, observed at multiple spatial and temporal scales, is between drought and fire. Predictive models often focus on ecosystems in which this relationship appears to be particularly strong, such as mesic and arid forests and shrublands with substantial biomass such as chaparral. We examine the drought–fire relationship, specifically the correlations between water-balance deficit and annual area burned, across the full gradient of deficit in the western USA, from temperate rainforest to desert. In the middle of this gradient, conditional on vegetation (fuels), correlations are strong, but outside this range the equivalence hotter and drier equals more fire either breaks down or is contingent on other factors such as previous-year climate. This suggests that the regional drought–fire dynamic will not be stationary in future climate, nor will other more complex contingencies associated with the variation in fire extent. Predictions of future wildfire area therefore need to consider not only vegetation changes, as some dynamic vegetation models now do, but also potential changes in the drought–fire dynamic that will ensue in a warming climate.

Western United States↗

Methylmercury cycling, bioaccumulation, and export from agricultural and non-agricultural wetlands in the Yolo Bypass

This 18-month field study addresses the seasonal and spatial patterns and processes controlling methylmercury (MeHg) production, bioaccumulation, and export from natural and agricultural wetlands of the Yolo Bypass Wildlife Area (YBWA). The data were collected in conjuntion with a Proposition 40 grant from the State Water Resources Control Board in support of the development of Best Management Practices (BMP's) for reducing MeHg loading from agricultural lands in the wetland-dominated Yolo Bypass to the Sacramento-San Joaquin River Delta. The four managemenr-based questions addressed in this study were: 1. Is there a different among agricultural and managfed wetland types in terms of Me Hg dynamic (production, degradation, bioaccumulation, or export)? 2. Does water residence time influence MeHg dynamics? 3. Does the application of sulfate-based fertilizer impact MeHg production rates? 4. Does the presence (or absence) of vegetation influence MeHg production rates? Measurements of MeHg concentrations in sediment, water, and biota (plants, invertebrates, and fish) were made to assess management-level patterns in five wetland types, which included three type of shallowly-flooded agricultural wetlands (white rice, wild rice, and fallow) and two types of managed wetlands (permanently and seasonally flooded). To strengthen our understanding of the processes underlying the seasonal and spatial patterns of MeHg cycling, additional exploratory factors were measured including ancillary sediment and water quality parameters, stable isotope fractionation (oxygen, sulfur, carbon, and nitrogen), photodemethylation rates, and daily-integrated hydrologic budgets. Samples and field data were collected from May 2007 to July 2008, and nearly all sample analyses were completed by September 2008 as per the Quality Assurance Program Plan (QAPP) requirements. Although wetland type was a major factor that drove the study design, within-field hydrology also proved to be an important factor controlling aqueous MeHg and total mercury (THg) concentrations and export. Overall, agricultural wetlands exhibited higher MeHg concentrations in overlying water, sediment, and biota than did managed seasonal and permanent wetlands. This appears to be partly due to higher rates of sediment in microbial production of MeHg on agricultural wetlands during the fall through spring period. Both sulfate- and iron-reducing bacteria have been implicated in the MeHg production process, and both were demonstrably active in all wetlands studied; however, sulfate-reducing bacteria were not stimulated by the addition of sulfate-based fertilizer to agricultural wetlands, suggesting that easily-degraded (labile) organic matter, rather than sulfate, was limiting their activity in these field types. The data suggest that agriculturally-managed soils promoted MeHg production through 1) enhanced microbial activity via higher temperatures and larger pools of labile carbon, and 2) enhanced pools of microbially available inorganic divalent mercury (Hg(II)) resulting from a decrease in reduced-sulfur, solid-phase minerals under oxic or only mildly reducing conditions. MeHg mass balances were assessed by comparing filed-specific MeHg loads for inlets vs. outlet flows. The overall mass balance for MeHg in surface water during the summer irrigation period (June - September 2007) indicated little to no net MeHg export from the six agricultural wetlands taken as a whole. Of the six agricultural wetlands, there was net overall MeHg export from two fields (one fallow and one white rice) during August, and from four of the six fields (one fallow, one white rice, and two wild rice) during September) Over the entire summer irrigation period, two of the fields (one fallow and one wild rive) showed net MeHg export, and the other four fields showed wither net import or no significant change. Rates of measured photomethylation and exchange between sediment and water pools suggest that both processes may be responsible for the lack of MeHg export. Despite significant differences during winter months between fields in surface water concentrations of MeHg, MeHg loads were not calculated in mid-winter because flood waters had overtopped field boundaries and field fidelity could not be established. During the summer 2007 irrigation season, surface water out-flows from agricultural wetlands were 9%-36% of inlet flows, and evaporation rates explained most of this water loss, with infiltration likely accounting for the remainder. Unfiltered aqueous MeHg concentrations increased from <1 ng L -1 in source waters to up to 10 ng L -1 in agricultural wetland drains during the summer irrigation period. Increases in solute concentration caused by evapoconcentration were estimated by determining concentration factors (outflow/inflow) for chloride (a conservative dissolved constituent) and by measuring oxygen isotope ratios ( 18 O/ 16 O, expressed as δ 18 O) in water. Increases in MeHg concentration from inflows-to-outflows exceeded those caused by evapoconcentration on several fields during the summer irrigation season. This was especially true when initial surface water MeHg concentrations were low, as seen in the southern block of fields receiving irrigation water directly from the Toe Drain. The northern block of fields received irrigation water from Greens Lake, which included Toe Drain water plus recirculated drain water from other agricultural fields within the Yolo Bypass and west of the Yolo Bypass; as such, the northern fields showed a smaller percentage increase in MeHg concentration because initial MeHg concentrations in surface water inflows were greater than in inputs to the southern fields. Mercury concentrations in fish were greater in agricultural wetlands white rice and wild rice) than in the two permanently flooded wetlands. Additionally, Hg concentrations in biota showed a general increase from inlets to outlets withing agricultural wetlands, but not within permanent wetlands. This was particular evident in white rice fields where caged western mosquitofish at the outlets had Hg concentrations that were more than 4 times higher than in caged fish held at the inlets. Similar spatial patterns in Hg bioaccumulation in agricultural and permanent wetlands were seen for wild populations of western mosquitofish and Mississippi silversides. In contrast to fish, invertebrates, such as water-boatman (Corixidae) and back swimmers (Notonectidae), had greater Hg concentrations in permanent wetlands than in tempoarirly flooded agricultural wetlands, Fish THg concentrations were weakly correlated with water MeHg,a and not correlated with sediment MeHg. In contrast, invertebrate MeHg concentrations were more strongly correlated with sediment MeHg than with water MeHg concentrations. These results illustrate the complexity of MeHg bioaccumulation through food webs and indicate the importance of simultaneously using multiple biosentinels when monitoring MeHg production and bioaccumulation. Despite high sediment production rates and water concentrations in agricultural wetlands, MeHg export was physically limited by hydrologic export for all wetlands studied. We suggest that load reduction is maximized by limiting water throughout, but that on-site biota exposure is maximized by this loner water residence time. While field-specific hydrologic loads could not be fully quantified during flood conditions in February 2008, we suggest that the primary period of MeHg export from Yolo Bypass Wildlife Area is during those winter flooding periods when overall microbial activity and MeHg production in agricultural soils is fueled by the decomposition of rice straw, and when hydrologic flowthrough is maximal. Local stakeholders participated in two workshops related to this study, demonstrating an interest in understanding factors controlling MeHg production, export, and bioaccumulation. The results of this field study show that permanently flooded, naturally vegetated wetlands are unlikely to a large source of MeHg production within the YBWA, in contrast with agriculturally-managed wetlands. MeHg loading to Toe Drain waters of the Yolo Bypass may be reduced by lowering rated of hydrologic export from agricultural wetlands during the growing season and especially during rice harvest, However, under these water-holding conditions, biota living within agricultural wetlands may thus be exposed to higher MeHg concentrations in surface water, As observed in this study, rapid bioacculumaltion over a 2-month period led to MeHg concentrations in invertebrates and fish more than 6 and 11 times higher, respectively, than proposed TMDL target values to protect wildlife (0.03 ppm ww). The results of this field study, together with the information from YBWA stakeholders, provide a more definitive understanding of how MeHg cycling and bioaccumulation respond to habitat differences and specific management practices. These results directly address 4 core components of CBDA's Mercury Strategy for the Bay-Delta Ecosystem (Wiener et al., 2003a): a) Quantification and evaluation of THg and MeHg sources, b) Quantification of effects of ecosystem restoration on MeHg exposure, c) Assessment of ecological risk, and d) Identification and testing of potential management approaches for reducing MeHg contamination. In addition, the quantitative results reported here assess the effect of current land use practices in the Yolo Bypass MeHg production, bioaccumulation and export, and provide process-based advice towards achieving current goals of the RWQCB-CVR's Sacramento -- San Joaquin Delta Estuary TMDL for Methyl & Total Mercury (Wood et al., 2010b). Further work is necessary to evaluate biotic exposure in the Yolo Bypass Wildlife Area at higher trophic levels (e.g. birds), to quantify winter hydrologic flux of MeHg to the larger Delta ecosystem, and to evaluate rice straw management options to limit labile carbon supplies to surface sediment during winter months. In summary, agricultural management of rice fields -- specifically the periodic flooding and production of easily degraded organic matter -- promotes the production of MeHg beyond rates seen in naturally vegetated wetlands, whether seasonally or permanently flooded., The exported load from MeHg from these agricultural wetlands may be controlled by limiting hydrologic export from fields to enhance on-site MeHg removal processes, but the tradeoff is that this impoundement increases Me Hg exposure to resident organisms.

California↗

Ground-truthing electrical resistivity methods in support of submarine groundwater discharge studies: Examples from Hawaii, Washington, and California

Submarine groundwater discharge (SGD) is an important conduit that links terrestrial and marine environments. SGD conveys both water and water-borne constituents into coastal waters, where these inflows may impact near-shore ecosystem health and sustainability. Multichannel electrical resistivity techniques have proven to be a powerful tool to examine scales and dynamics of SGD and SGD forcings. However, there are uncertainties both in data aquisition and data processing that must be addressed to maximize the effectiveness of this tool in estuarine or marine environments. These issues most often relate to discerning subtle nuances in the flow of electricity through variably saturated media that can also be highly conductive ( i.e., seawater). Three contrasting field sites were examined for this study to assess the effectiveness of electrical resistivity techniques in varying coastal settings by comparing resistivity data to direct salinity and resistivity observations, quantifying changes in lithology and beach geomorphology, and fine-tuning inversion protocols. The three study sites all have substantial (up to 85 cm day &minus;1 ) submarine groundwater discharge rates, but the hydrologic, oceanographic, and geologic characteristics of the sites are all very different. At a site in Pelekane Bay on the Big Island of Hawaii, seasonal flooding introduces very high concentrations of fine to coarse sediment into the bay. Near-shore circulation is limited in Pelekane Bay, so this newly introduced sediment can become deposited in the bay where it accumulates over time. At a site in Hood Canal, a fjord within Puget Sound, Washington, SGD rates can be high because of the large tidal range, abundant recharge, and steep hydrologic gradients. At Younger Lagoon in northern California, the flow of groundwater towards the coast is much more parsimonious, but here marine processes, including recirculated seawater, are important in controlling the flow of material towards the coast. Rigorous ground-truthing at each field site showed that multi-channel electrcial resistivity techniques can reproduce the scales and dynamics of a seepage field when such data are correctly collected, and when the model inversions are tuned to field site characteristics. Such information can provide a unique perspective on the scales and dynamics of exchange processes within a coastal aquifer&mdash;information essential to scientists and resource managers alike.

California, Hawaii, Washington↗

The accuracy of ecological flow metrics derived using a physics-based distributed rainfall-runoff model in the Great Plains, USA

The development of a hydrologic foundation, essential for advancing our understanding of flow-ecology relationships, was developed using the high-resolution physics-based distributed rainfall–runoff model V flo in a semi-arid region. We compared the accuracy and bias associated with flow metrics that were generated using V flo , gauge data, and drainage area ratios at both a daily and monthly time step in the Canadian River basin, USA. First, we calibrated and applied bias correction to the V flo model to simulate streamflow at ungauged catchment locations. Next, flow metrics were calculated using simulated and observed data from stream gauge locations. We found discharge predictions using V flo were more accurate than drainage area ratios. General correspondence between predicted discharge and the gauge data was apparent; however, flow metrics calculated using the V flo output did not accurately represent flow variability. Results from the V flo model showed systematic discharge over-predictions in the upper basin and isolated over-predictions in the lower basin, likely due to hail events and sparse rainfall data across the large catchment. Goodness-of-fit statistics (Nash–Sutcliffe efficiency, root-mean square error, and the coefficient of variation) indicated the drainage area ratio and V flo were more accurate at a monthly rather than daily time step, even after quantile mapping. This finding limits the number of streamflow metrics available to develop ecological models, but more importantly, the coarser resolution may hinder our understanding of ecological processes that occur at a submonthly time step. Our approach provides a framework for selecting flow metrics that best represent hydrologic patterns across a large semi-arid catchment with the necessary accuracy to address the ecological questions of interest.

New Mexico, Oklahoma, Texas↗

Streams, springs, and volcanic lakes for volcano monitoring

Introduction Volcanic unrest can trigger appreciable change to surface waters such as streams, springs, and volcanic lakes. Magma degassing produces gases and soluble salts that are absorbed into groundwater that feeds streams and lakes. As magma ascends, the amount of heat and degassing will increase, and so will any related geochemical and thermal signal. Subsurface magma movement can cause pressurization that alters hydrostatic head and may induce groundwater discharge. Fluid-pressure changes have been linked to distal volcano-tectonic earthquakes (White and McCausland, 2016; Coulon and others, 2017) and phreatic eruptions (for example, Yamaoka and others, 2016). Clearly, changes in groundwater and surface waters are both indicators of unrest and clues to how and where magma is rising toward the surface. Where possible, it is prudent to incorporate real-time hydrologic data into multiparameter monitoring of restless volcanoes. Hydrologic dynamics can also be tracked by changes in groundwater levels that are commonly measured in shallow boreholes (see of Flinders, A.F., Lowenstern, J.B., Coombs, M.L., and Poland, M.P., eds., Recommended capabilities and instrumentation for volcano monitoring in the United States: U.S. Geological Survey Scientific Investigations Report 2024–5062–K, 5 p., https://doi.org/10.3133/sir20245062k. ">chapter K , this volume, on boreholes; Hurwitz and Lowenstern, 2024). Although inferred to be common, relatively few volcano-hydrology anomalies are well documented, and many are essentially anecdotal (Newhall and others, 2001), reflecting the fact that high-resolution time series remain rare. Extreme examples include the 2008 eruption of Nevado del Huila, Colombia, where relatively minor phreatomagmatic eruptions were accompanied by expulsion of as much as 300 million cubic meters of groundwater from fissures high on the volcano (Worni and others, 2011), generating large lahars. Substantial decreases in flow rate from springs about 8 kilometers from the summit of Mayon Volcano, Philippines, have been noted before most eruptions in the 20th century (Newhall and others, 2001). Stream monitoring at Redoubt Volcano in 2009 allowed Werner and others (2012) to recognize that groundwater was unable to absorb (or scrub) the high flux of volcanic gas and that a high CO 2 /SO 2 precursor signal had been evident for 5 months prior to the eruption. A key to better interpreting hydrologic anomalies—or even identifying them—is therefore obtaining adequate baseline data. Most hydrologic monitoring at U.S. volcanoes has been accomplished by intermittent sampling surveys with annual or less frequent sampling (for example, https://hotspringchem.wr.usgs.gov/index.php ). More frequent sampling, however, generally is needed to establish reliable baselines. A recent hydrologic and hydrothermal monitoring experiment at 25 sites and 10 of the 12 level 4 (very high threat) volcanoes in the U.S. portion of the Cascade Range demonstrated that there is sufficient temporal variability in hydrothermal fluxes, even during quiescent periods, that one-time measurements will commonly have limited interpretive value (Crankshaw and others, 2018). Thus, surveys are best augmented with data from streamgages (for example, Evans and others, 2004; Bergfeld and others, 2008). Streamflow (water discharge) data allow measured temperature and specific conductance to be converted to heat and solute mass fluxes, which could be insightful parameters for detecting anomalous activity (McCleskey and others, 2012). At the Yellowstone Caldera, long-term monitoring of river solutes has allowed calculation of the chloride flux, a proxy for heat discharge (Hurwitz and others, 2007; McCleskey and others, 2016) from the subsurface magma. This is readily accomplished because data from streamgages are continuously recorded and archived by the U.S. Geological Survey (USGS) National Water Information System (NWIS) (USGS, 2024). Similar studies on stratovolcanoes or shield volcanoes would be scientifically useful, and yet are logistically challenging, requiring streamgages on numerous radial drainages complemented by either frequent manual sampling or numerous deployments of equipment to measure water temperature and specific conductance as a proxy for water chemistry. Another challenge is that some volcanic areas, especially shield volcanoes, are characterized by near-surface porous rocks and soils, such that surface streams are rare and replaced by distant, dilute large-volume springs with only a trace of any original volcanically sourced water (Manga, 2001; Hurwitz and others, 2021). Volcanic lakes are worthy of special attention for monitoring efforts, as their temperature and composition can provide evidence of increased flux of volatile-rich fluids from below. Quantifying changes in volatile and heat release from magma can be simpler in lakes than for volcanoes with radial drainages and no major lakes. Moreover, volcanic lakes pose a range of hazards themselves, including phreatomagmatic eruptions, debris flows, flank collapse, tsunamis, and toxic gas release (Mastin and Witter, 2000; Delmelle and others, 2015; Manville, 2015; Rouwet and others, 2015)—hazards that have historically been responsible for substantial loss of life at many volcanoes worldwide (Manville, 2015). Catastrophic CO 2 release at Lake Nyos, Cameroon, in 1986 suffocated about 1,750 people and about 3,500 livestock and was probably triggered by a large landslide into the gas-saturated lake (Kling and others, 1987; Evans and others, 1993). Gas-charged springs in Soda Bay within Clear Lake (California) have caused almost a dozen deaths to bathers in the past hundred years (ABC News, 2000). A 2005 example of lake overturn and abundant gas release was documented at Mount Chiginagak in Alaska (Schaefer and others, 2008) but did not result in any human casualties. Although thermally stratified lakes, which promote trapping of exsolved magmatic gas, tend to develop in tropical regions, the phenomenon can also arise where salinity creates meromixis (a condition in which a lake does not mix completely), as occurs in Mono Lake, California (Jellison and Melack, 1993; Jellison and others, 1998). If magma erupts or flows into a lake, the interaction between hot magma and cold water can be explosive (Mastin and others, 2004; Zimanowski and others, 2015) and substantially expand the area affected by the eruption. Another hazard is the breaching of crater rims by landslides triggered by volcanic and (or) seismic activity. Under some circumstances, substantial volumes of water can be displaced, leading to large floods and lahars. Late Holocene lake flooding from Aniakchak Crater in the Alaska Peninsula (Waythomas, 2022) and from Paulina Lake in Newberry Crater, Oregon (Chitwood and Jensen, 2000), caused by the failure of outlet sills, testify to the substantial hazards at lake-filled calderas. Several volcanic systems in the United States host lakes known to receive heat and gas from underlying magma. These lakes vary widely in area, depth, and chemical composition. Lakes are present at level 4 volcanoes, including Crater Lake and Newberry Volcano in Oregon; Yellowstone Caldera in Wyoming; Long Valley Caldera, Clear Lake volcanic field, Medicine Lake, and Salton Buttes in California; and Aniakchak Crater, Mount Katmai, Fisher Caldera, Mount Okmok, and Kaguyak Crater, among others, in Alaska. A water lake was present in Halemaʻumaʻu, the crater of Kīlauea, Hawai‘i (fig. F1), from October 2019 to December 2020. Level 3 volcanoes with lakes include Mono Lake volcanic field (Calif.), Mount Bachelor (Ore.), Ukinrek Maars and Mount Chiginagak (Alaska), and Soda Lake (Nevada). In addition, there are lakes at many levels 1 and 2 volcanoes. In the United States, there are no strongly acidic lakes that receive abundant input of magmatic gas, such as those found at Mount Ruapehu (New Zealand), Ijen and Kelud (Indonesia), and Poás (Costa Rica). Nevertheless, many contain fluids that provide clues to magmatic processes below. Since publication of a previous report on recommended instrumentation for volcano monitoring (Moran and others, 2008), continuous hydrologic monitoring has become increasingly feasible. However, changes in water pressure, temperature, and chemistry remain, in general, poorly studied phenomena at volcanoes (Sparks, 2003; National Academies of Sciences, Engineering, and Medicine, 2017). Recent efforts by the USGS have included the temporary study of Cascade Range volcanoes, which included frequent (15 minute to hourly) temporal sampling of temperature, depth, and conductivity (Crankshaw and others, 2018; Ingebritsen and Evans, 2019). At Yellowstone Caldera, many streamgages have now added thermistors and specific conductance sensors, allowing estimation of time-dependent chloride flux as a proxy for variations in subsurface heat flux (McCleskey and others, 2012, 2016). Efforts to better understand lakes have also accelerated, with bathymetric mapping and sampling carried out at several locations in the United States. Especially thorough work was done at Yellowstone Lake thanks to the Hydrothermal Dynamics of Yellowstone Lake (HD-YLAKE, https://hdylake.org ) project, funded primarily by the National Science Foundation. In addition to geophysical surveys and recovery of cores and other samples, HD-YLAKE investigations included remotely operated vehicle (ROV) investigations of hydrothermal vents on the lake floor (fig. F2). Data collected by the ROV provided a better understanding of the thermal and chemical influx from lake-bottom hydrothermal systems (Sohn and others, 2017). In this chapter, we focus on detecting changes in the chemistry, temperature, discharge, or water levels of streams, springs, and lakes that can be caused by seismicity, volumetric strains, or increases in gas flux associated with ascending magma. There is unavoidable overlap with other chapters of this report. Samples of water and gas can also be obtained in boreholes ( of Flinders, A.F., Lowenstern, J.B., Coombs, M.L., and Poland, M.P., eds., Recommended capabilities and instrumentation for volcano monitoring in the United States: U.S. Geological Survey Scientific Investigations Report 2024–5062–K, 5 p., https://doi.org/10.3133/sir20245062k. ">chapter K , this volume; Hurwitz and Lowenstern, 2024), both shallow and deep. Gas monitoring ( of Flinders, A.F., Lowenstern, J.B., Coombs, M.L., and Poland, M.P., eds., Recommended capabilities and instrumentation for volcano monitoring in the United States: U.S. Geological Survey Scientific Investigations Report 2024–5062–E, 11 p., https://doi.org/10.3133/sir20245062e.">chapter E , this volume; Lewicki and others, 2024) relies in part on samples from springs and wells, particularly where measurable gas plumes are absent. Water acts as a trigger and lubricant for landslides and sediment-rich floods, and so hydrology has obvious relevance for lahar monitoring, as discussed in of Flinders, A.F., Lowenstern, J.B., Coombs, M.L., and Poland, M.P., eds., Recommended capabilities and instrumentation for volcano monitoring in the United States: U.S. Geological Survey Scientific Investigations Report 2024–5062–H, 6 p., https://doi.org/10.3133/sir20245062h. ">chapter H (this volume; Thelen and others, 2024). Shared situational awareness among scientists engaged in geophysical, gas, and hydrologic monitoring will improve overall understanding of the volcanic hazard.

Scientific Investigations Report↗

Hydrodynamics drive pelagic communities and food web structure in a tidal environment

Hydrodynamic processes can lead to the accumulation and/or dispersal of water column constituents, including sediment, phytoplankton, and particulate detritus. Using a combination of field observations and stable isotope tracing tools, we identified how hydrodynamic processes influenced physical habitat, pelagic communities, and food web structure in a freshwater tidal system. The pelagic habitat of a terminal channel differed spatially, likely aligning with differences in hydrodynamics. Three zones that we classified by exchange with downstream habitat had distinct water quality characteristics, supported different densities of zooplankton and nekton, and exhibited disparate support from benthic and pelagic trophic pathways to pelagic consumers. Hydrodynamically driven zones and their emergent characteristics appeared sensitive to hydrology, as elevated runoff was correlated with a shift in hydrodynamic habitat and organismal distributions. The results of our study highlight the relationship between hydrodynamic processes, biological responses, and climate, and suggest that understanding the physical process can improve understanding of pelagic habitats and communities.

California↗

Water-quality observations of the San Antonio segment of the Edwards aquifer, Texas, with an emphasis on processes influencing nutrient and pesticide geochemistry and factors affecting aquifer vulnerability, 2010–16

As questions regarding the influence of increasing urbanization on water quality in the Edwards aquifer are raised, a better understanding of the sources, fate, and transport of compounds of concern in the aquifer—in particular, nutrients and pesticides—is needed to improve water management decision-making capabilities. The U.S. Geological Survey, in cooperation with the San Antonio Water System, performed a study from 2010 to 2016 to better understand how water quality changes under a range of hydrologic conditions and in contrasting land-cover settings (rural and urban) in the Edwards aquifer. The study design included continuous hydrologic monitoring, continuous water-quality monitoring, and discrete sample collection for a detailed characterization of water quality at a network of sites throughout the aquifer system. The sites were selected to encompass a “source-to-sink” (that is, from aquifer recharge to aquifer discharge) approach. Network sites were selected to characterize rainfall, recharging surface water, and groundwater; groundwater sites included wells in the unconfined part of the aquifer (unconfined wells) and in the confined part of the aquifer (confined wells) and a major discharging spring. Storm-related samples—including rainfall samples, stormwater-runoff (surface-water) samples, and groundwater samples—were collected to characterize the aquifer response to recharge. Elevated nitrate concentrations relative to national background values and the widespread detection of pesticides indicate that the Edwards aquifer is vulnerable to contamination and that vulnerability is affected by factors such as land cover, aquifer hydrogeology, and changes in hydrologic conditions. Greater vulnerability of groundwater in urban areas relative to rural areas was evident from results for urban groundwater sites, which generally had higher nitrate concentrations, elevated δ 15 N-nitrate values, a greater diversity of pesticides, and higher pesticide concentrations. The continuum of water quality from unconfined rural groundwater sites (least affected by anthropogenic contamination) to unconfined urban groundwater sites (most affected by anthropogenic contamination) demonstrates enhanced vulnerability of urban versus rural land cover. Differences in contaminant occurrences and concentration among unconfined urban wells indicate that the urban parts of the aquifer are not uniformly vulnerable, but rather are affected by spatial differences in the sources of nutrients and pesticides. In urban areas, the shallow, unconfined groundwater sites showed greater temporal variability in both nutrient and pesticide concentrations, as well as a greater degree of contamination, than did deeper, confined groundwater sites. In comparison to that of the shallow, unconfined groundwater sites, the water quality of the deeper, confined groundwater sites was relatively invariant during this multiyear study. Although aquifer hydrogeology is an important factor related to aquifer vulnerability, land cover likely has a greater influence on pesticide contamination of groundwater. Temporal variability in hydrologic conditions for the Edwards aquifer is apparent in data for surface water as a source of groundwater recharge, water-level altitude in wells, spring discharge, and groundwater quality. This temporal variability affects recharge sources, recharge amounts, groundwater traveltimes, flow routing, water-rock interaction processes, dilution, mixing, and, in turn, water quality. Relations of land cover, aquifer hydrogeology, and changing hydrologic conditions to water quality are complex but provide insight into the vulnerability of Edwards aquifer groundwater—a vital drinking-water resource.

Texas↗