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Hydrogeology of aquifers within the Fairport-Lyons channel system and adjacent areas in Wayne, Ontario, and Seneca Counties, New York

A hydrogeologic investigation was undertaken by the U.S. Geological Survey, in cooperation with the New York State Department of Environmental Conservation, within the areas shown in the Macedon, Palmyra, Newark, and Lyons 7.5-minute quadrangle maps that include parts of Wayne, Ontario, and Seneca Counties in New York. The most productive zone of aquifers within the study area is associated with the Fairport-Lyons glacial-stream channel (hereinafter referred to as the “Fairport-Lyons channel”) in southern Wayne County and adjacent areas. The Fairport-Lyons channel is a west-east-oriented bedrock channel that once served as the outlet for glacial Lake Dawson, which occupied the Genesee Valley near Rochester during the Pleistocene. The Fairport-Lyons channel and intersecting subsidiary channels are hereinafter referred to as the “Fairport-Lyons channel system.” Glacial meltwater eroded this shallow channel network into the underlying bedrock, and the channels subsequently filled with interlayered glaciofluvial sand and gravel and fine-grained lacustrine deposits. These sand and gravel deposits provide the only large supplies of groundwater in Wayne County under unconfined and confined conditions and serve a population of over 20,000 through a combination of domestic and municipal water supply wells. The largest reported well yield, 1,200 gallons per minute, is from an industrial supply well near Newark, N.Y. Much of the sand and gravel within the Fairport-Lyons channel system is generally thinly saturated; however, in three areas—near Macedon, Newark, and Lyons, N.Y.—the saturated thickness of the aquifer is sufficient to support groundwater yields adequate for municipal and industrial use, in part because of induced infiltration from the Erie Canal.

New York↗

Instream investigations in the Beaver Creek Watershed in West Tennessee, 1991-95

The U.S. Geological Survey (USGS), in cooperation with the Tennessee Department of Agriculture, began a long-term scientific investigation in 1989 to evaluate the effect of agricultural activities on water quality and the effectiveness of agricultural best management practices in the Beaver Creek watershed, West Tennessee. In 1993 as a part of this study, the USGS, in cooperation with the Natural Resources Conservation Service, Shelby County Soil Conservation District, and the Tennessee Soybean Promotion Board, began an evaluation of the physical, chemical, biological and hydrological factors that affect water quality in streams and wetlands, and instream resource-management systems to treat agricultural nonpoint-source runoff and improve water quality. The purpose of this report is to present the results of three studies of stream and wetland investigations and a study on the transport of aldicarb from an agricultural field in the Beaver Creek watershed. A natural bottomland hardwood wetland and an artificially constructed wetland were evaluated as instream resource-management systems. These two studies showed that wetlands are an effective way to improve the quality of agricultural nonpoint-source runoff. The wetlands reduced concentrations and loads of suspended sediments, nutrients, and pesticides in the streams. A third paper documents the influence of riparian vegetation on the biological structure and water quality of a small stream draining an agricultural field. A comparison of the upper reach lined with herbaceous plants and the lower reach with mature woody vegetation showed a more stable biological community structure and Water- quality characteristics in the woody reach than in the herbaceous reach. The water-quality characteristics monitored were pH, temperature, dissolved oxygen, and specific conductance. The herbaceous reach had a greater diversity and abundance of organisms during spring and early summer, but the abundance dropped by approximately 85 percent during late summer. A fourth study describes the transport of aldicarb and its metabolites--aldicarb sulfoxide and aldicarb sulfone-in runoff at a small stream draining a cotton field. During 1991 to 1995, aldicarb and its metabolites were detected in runoff events. The highest concentrations occurred when aldicarb was applied to the field just hours before a rain storm. Aldicarb was not detectable in runoff a few weeks after application. The metabolites of aldicarb were detectable for 76 days after application. These studies demonstrate streambank vegetation and wetlands have a significant influence on stream water quality. The importance of weather conditions to herbicide application and runoff also is evident. This information can be used by resource managers to sustain and improve our Nation's streams for future generations.

Water-Resources Investigations Report↗

Hydrogeology and water quality of the Galena-Platteville aquifer at the Parson's Casket Hardware Superfund site, Belvidere, Illinois, 1991-92

The purpose of this letter is to describe the results of the final phase (phase 3) of the U.S. Geological Survey's (USGS) ground-water investigation at the Parson's Casket Hardware site, Belvidere, Ill. (figs. 1 and 2), for the U.S. Environmental Protection Agency (USEPA). Included in this letter are brief descriptions of (1) study methods employed in the phase 3 investigation that have not been previously described in earlier reports, and (2) results of the phase 3 investigation as they relate to the results of the previous phases of the investigation. The data from the phase 3 investigation that are presented and described herein were collected during November 1991-January 1992. The Galena-Platteville aquifer is the uppermost bedrock aquifer beneath the site. The Glenwood Formation of Ordovician age, a potential confining unit, separates the Galena-Platteville aquifer from the underlying St. Peter Sandstone aquifer (fig. 3). The St. Peter Sandstone aquifer is an important source of ground water to Belvidere and other cities in the region. The phase 3 investigation was done (1) to determine the lithology of the Glenwood Formation; (2) to determine the vertical distribution of horizontal hydraulic conductivity (K) and concentrations of volatile organic compounds (VOC's) in the upper 150 ft (feet) of the Galena-Platteville aquifer at an existing monitoring location, borehole G127GP (figs. 2 and 3) ; and (3) to confirm the presence or absence of VOC's in the St. Peter Sandstone aquifer at a new monitoring location, well G127SP (figs. 2 and 3). Additional components of the site investigation described in this letter include determination of vertical hydraulic gradients between the Galena-Platteville and St. Peter Sandstone aquifers and in situ measurement of selected water-quality characteristics (pH, temperature, specific conductance, Eh, and dissolved oxygen) in borehole G127GP. The results of the first and second phases of the USGS investigation at the Parson's Casket Hardware site are presented in two previous USGS Open-File Reports prepared for the USEPA (Mills, 1993a, 1993b) . These reports describe the hydrogeology of the study site, principally the Galena-Platteville aquifer, and the distribution of VOC concentrations in the Galena-Platteville aquifer. (The stratigraphic nomenclature used in this report is that of the Illinois State Geological Survey (Willman and others, 1975, p. 47-87) and does not necessarily follow the usage of the USGS. The aquifer nomenclature is that generally used by the Illinois State Geological Survey and the U.S. Environmental Protection Agency.) The previous two reports also describe most of the study methods employed in the phase 3 investigation.

Open-File Report↗

Environmental setting and water-quality issues of the Mobile River Basin, Alabama, Georgia, Mississippi, and Tennessee

The Mobile River Basin is one of over 50 river basins and aquifer systems being investigated as part of the U.S. Geological Survey National Water-Quality Assessment (NAWQA) Program. This basin is the sixth largest river basin in the United States, and fourth largest in terms of streamflow, encompassing parts of Alabama, Georgia, Mississippi, and Tennessee. Almost two-thirds of the 44,000-square-mile basin is located in Alabama. Extensive water resources of the Mobile River Basin are influenced by an array of natural and cultural factors. These factors impart unique and variable qualities to the streams, rivers, and aquifers providing abundant habitat to sustain the diverse aquatic life in the basin. Data from Federal, State, and local agencies provide a description of the environmental setting of the Mobile River Basin. Environmental data include natural factors such as physiography, geology, soils, climate, hydrology, ecoregions, and aquatic ecology, and human factors such as reservoirs, land use and population change, water use, and water-quality issues. Characterization of the environmental setting is useful for understanding the physical, chemical, and biological characteristics of surface and ground water in the Mobile River Basin and the possible implications of that environmental setting for water quality. The Mobile River Basin encompasses parts of five physiographic provinces. Fifty-six percent of the basin lies within the East Gulf section of the Coastal Plain Physiographic Province. The remaining northeastern part of the basin lies, from west to east, within the Cumberland Plateau section of the Appalachian Plateaus Physiographic Province, the Valley and Ridge Physiographic Province, the Piedmont Physiographic Province, and the Blue Ridge Physiographic Province. Based on the 1991 land-use data, about 70 percent of the basin is forested, while agriculture, including livestock (poultry, cattle, and swine), row crops (cotton, corn, soybeans, sorghum, and wheat), and pasture land accounts for about 26 percent of the study unit. Agricultural land use is concentrated along the Black Prairie Belt district of the Coastal Plain. Urban areas account for only 3 percent of the total land use; however, the areal extent of the metropolitan statistical areas (MSA) may indicate more urban influences. The MSAs include urban areas outside of the city boundaries and can include adjacent counties. Seven MSAs are delineated in the Mobile River Basin, including Montgomery, Mobile, Tuscaloosa, Birmingham, Gadsden, Anniston, and Atlanta. The total population for the Mobile River Basin was about 3,673,100 in 1990. State water-quality agencies have identified numerous causes and sources of water-body impairment in the Mobile River Basin. In 1996, organic enrichment, dissolved oxygen depletion, elevated nutrient concentrations, and siltation were the most frequently cited causes of impairment, affecting the greatest number of river miles. Bacteria, acidic pH, and elevated metal concentrations also were identified as causes of impairment. The sources for impairment varied among river basins, were largely a function of land use, and were attributed primarily to municipal and industrial sources, mining, and agricultural activities.

Alabama, Georgia, Mississippi, Tennessee↗

Hydrogeology, ground-water quality, and source of ground water causing water-quality changes in the Davis well field at Memphis, Tennessee

An investigation was conducted by the U.S. Geological Survey from 1992 to 1994 to collect and interpret hydrogeologic and water-quality data to determine the source of ground water causing water-quality changes in water from wells screened in the Memphis aquifer in the Davis well field at Memphis, Tennessee. Water-quality changes in aquifers used for water supply are of concern because these changes can indicate a potential for contamination of the aquifers by downward leakage from near-surface sources. The water-quality changes at the Davis well field were detected by Memphis Light, Gas and Water Division, which has periodically sampled and analyzed water from many of the 14 production wells since the well field began operation in 1971. Memphis Light, Gas and Water Division analyzed the water samples primarily for hardness, alkalinity, chloride, ulfate, and iron. Results of the e analy es and results of more recent (1992) analyse of water samples by the U.S. Geological Survey indicate that the quality of water from eight of the production wells has changed since the well field began operation. For example, from 1972 to 1991, hardness of water from one well has increased from 90 to 292 milligrams per liter (224 percent). The confining unit, which separates the fluvial deposits aquifer from the Memphis aquifer in the area of the well field, is relatively thick and contains many clay layers. However, a test hole drilled for one of five shallow wells installed in the alluvial aquifer in the Mississippi Alluvial Plain just west of the well field indicated that the confining unit separating the alluvial aquifer from the Memphis aquifer locally is absent. Differences in hydrauLic head between the alluvial and fluvial deposits aquifers and the Memphis aquifer favor downward leakage of ground water. Thus, the absence of the confining unit beneath the Mississippi Alluvial Plain just west of the well field provides a direct pathway for water in the alluvial aquifer to enter the Memphis aquifer. Comparison of selected water-quality properties and major inorganic and trace element constituent concentrations in samples from the alluvial, fluvial deposits, and Memphis aquifers indicates that the source of ground water causing waterquality changes at the Davis well field is the alluvial aquifer west of the well field . The presence of tritium and chlorofluorocarbons in water from wells screened in the Memphis aquifer in the western part of the well field indicates that relatively young (post-1940) water from the alluvial aquifer has entered the Memphis aquifer. NETPATH geochemical model code was used to mix waters from the alluvial aquifer with water from the Memphis aquifer using chloride as a conservative tracer. The resulting models indicated that a mixture containing 3 percent alluvial aquifer water mixed with 97 percent unaffected Memphis aquifer water would produce the chloride concentration measured in water from the Memphis aquifer well most affected by water-quality changes. NETPATH also was used to calculate mixing percentages of alluvial and Memphis aquifer Abstract waters based on changes in the concentrations of selected dissolved major inorganic and trace element constituents that define the dominant reactions that occur during mixing. These models indicated that a mixture containing 18 percent alluvial aquifer water and 82 percent unaffected Memphis aquifer water would produce the major constituent and trace element concentrations measured in water from the Memphis aquifer well most affected by water-quality changes. However, these model simulations predicted higher dissolved methane concentrations than were measured in water samples from the Memphis aquifer wells.

Tennessee↗

Statewide analysis of the drainage-area ratio method for 34 streamflow percentile ranges in Texas

The drainage-area ratio method commonly is used to estimate streamflow for sites where no streamflow data are available using data from one or more nearby streamflow-gaging stations. The method is intuitive and straightforward to implement and is in widespread use by analysts and managers of surface-water resources. The method equates the ratio of streamflow at two stream locations to the ratio of the respective drainage areas. In practice, unity often is assumed as the exponent on the drainage-area ratio, and unity also is assumed as a multiplicative bias correction. These two assumptions are evaluated in this investigation through statewide analysis of daily mean streamflow in Texas. The investigation was made by the U.S. Geological Survey in cooperation with the Texas Commission on Environmental Quality. More than 7.8 million values of daily mean streamflow for 712 U.S. Geological Survey streamflow-gaging stations in Texas were analyzed. To account for the influence of streamflow probability on the drainage-area ratio method, 34 percentile ranges were considered. The 34 ranges are the 4 quartiles (0-25, 25-50, 50-75, and 75-100 percent), the 5 intervals of the lower tail of the streamflow distribution (0-1, 1-2, 2-3, 3-4, and 4-5 percent), the 20 quintiles of the 4 quartiles (0-5, 5-10, 10-15, 15-20, 20-25, 25-30, 30-35, 35-40, 40-45, 45-50, 50-55, 55-60, 60-65, 65-70, 70-75, 75-80, 80-85, 85-90, 90-95, and 95-100 percent), and the 5 intervals of the upper tail of the streamflow distribution (95-96, 96-97, 97-98, 98-99 and 99-100 percent). For each of the 253,116 (712X711/2) unique pairings of stations and for each of the 34 percentile ranges, the concurrent daily mean streamflow values available for the two stations provided for station-pair application of the drainage-area ratio method. For each station pair, specific statistical summarization (median, mean, and standard deviation) of both the exponent and bias-correction components of the drainage-area ratio method were computed. Statewide statistics (median, mean, and standard deviation) of the station-pair specific statistics subsequently were computed and are tabulated herein. A separate analysis considered conditioning station pairs to those stations within 100 miles of each other and with the absolute value of the logarithm (base-10) of the ratio of the drainage areas greater than or equal to 0.25. Statewide statistics of the conditional station-pair specific statistics were computed and are tabulated. The conditional analysis is preferable because of the anticipation that small separation distances reflect similar hydrologic conditions and the observation of large variation in exponent estimates for similar-sized drainage areas. The conditional analysis determined that the exponent is about 0.89 for streamflow percentiles from 0 to about 50 percent, is about 0.92 for percentiles from about 50 to about 65 percent, and is about 0.93 for percentiles from about 65 to about 85 percent. The exponent decreases rapidly to about 0.70 for percentiles nearing 100 percent. The computation of the bias-correction factor is sensitive to the range analysis interval (range of streamflow percentile); however, evidence suggests that in practice the drainage-area method can be considered unbiased. Finally, for general application, suggested values of the exponent are tabulated for 54 percentiles of daily mean streamflow in Texas; when these values are used, the bias correction is unity.

Scientific Investigations Report↗

Hydrologic data for urban studies in the Dallas, Texas metropolitan area, 1975

Hydrologic investigations of urban watersheds in Texas were begun by the U.S. Geological Survey in 1954. These studies are now in progress in Austin, Dallas, Dallas County, Fort Worth, Houston, and San Antonio. In August 1961, the Geological Survey in cooperation with the city of Dallas began a program of investigations designed to evaluate hydrologic factors affecting floods on several small streams in Dallas. Through cooperative agreements with the city of Dallas and the Dallas County Department of Public Works, the original program has been expanded to include the greater Dallas metropolitan area.

Texas↗

Occurrence and distribution of nutrients, suspended sediment, and pesticides in the Mobile River Basin, Alabama, Georgia, Mississippi, and Tennessee, 1999-2001

The Mobile River Basin is one of more than 50 river basins and aquifer systems being investigated as part of the U.S. Geological Survey's National Water- Quality Assessment (NAWQA) Program. This basin is the sixth largest river basin in the United States and the fourth largest in terms of streamflow. The Mobile River Basin encompasses parts of Alabama, Georgia, Mississippi, and Tennessee, and almost two-thirds of the 44,0000-square-mile basin is located in Alabama. The extensive water resources of the Mobile River Basin are influenced by an array of natural and cultural factors, which impart unique and variable qualities to the streams, rivers, and aquifers and provide abundant habitat to sustain the diverse aquatic life in the basin. From January 1999 to December 2001, a study was conducted of the occurrence and distribution of nutrients, suspended sediment, and pesticides in surface water of the Mobile River Basin. Nine sampling sites were selected on the basis of land use. The nine sites included two streams draining agricultural areas, two urban streams, and five large rivers with mixed land use. Surface-water samples were collected from one to four times each month to characterize the spatial and temporal variation in nutrient and pesticide concentrations. Nutrient and suspended-sediment concentrations were highest in watersheds dominated by urban or agricultural land uses. Forty-two percent of the total phosphorus concentrations at all nine sites exceeded the U.S. Environmental Protection Agency's recommended maximum concentration of 0.1 milligram per liter. Flow-weighted mean concentrations at the Mobile River Basin sites generally were in the lower to middle percentile ranges compared with data from other NAWQA studies across the Nation. However, flow-weighted mean concentrations of ammonia, total nitrogen, orthophosphate, and total phosphorus at Bogue Chitto Creek, an agricultural watershed, ranked in the upper 20th percentile of agricultural sites sampled across the Nation as part of the NAWQA Program. Nutrient loads in the Tombigbee River were nearly twice as high compared with nutrient loads in the Alabama River. Nutrient yields were highest in Bogue Chitto Creek, Cahaba Valley Creek, and Threemile Branch because of agricultural and urban land uses in these watersheds. Of the 104 pesticides and degradation products analyzed in the stream samples, 69 were detected in one or more samples. Of the 69 detected pesticides, 51 were herbicides, 15 were insecticides, and 3 were fungicides. A relatively small number of heavily used herbicides accounted for most of the detections, including atrazine and its metabolites (deethylatrazine, 2-hydroxyatrazine, deisopropylatrazine, and deethyldeisopropylatrazine), simazine, metolachlor, tebuthiuron, prometon, diuron, and 2,4-D. Diazinon, chlorpyrifos, and carbaryl were the most frequently detected insecticides; metalaxyl was the most frequently detected fungicide in the Mobile River Basin. Concentrations of pesticides detected in surface water of the Mobile River Basin were among the highest concentrations recorded nationally by the NAWQA Program during 1991 to 2001. The three highest concentrations of atrazine detected at sites across the country were recorded at Bogue Chitto Creek; the highest concentrations of 2,4-D, imazaquin, and malathion recorded nationally were detected at Threemile Branch. Aquatic-life criteria were exceeded by concentrations of five herbicides (2,4-D, atrazine, cyanazine, diuron, and metolachlor), six insecticides (carbaryl, chlorpyrifos, diazinon, dieldrin, malathion, and p,p'-DDE), and one fungicide (chlorothalonil). Drinking-water standards were exceeded by concentrations of four herbicides (2,4-D, atrazine, cyanazine, and simazine), three insecticides (alpha- HCH, diazinon, and dieldrin), and one fungicide (chlorothalonil). The types and concentrations of pesticides found in surface water are linked to land use and to the types of pesti

Alabama, Georgia, Mississippi, Tennessee↗

Sources and loads of nutrients in the South Platte River, Colorado and Nebraska, 1994-95

The South Platte River Basin was one of 20 river basins selected in 1991 for investigation as part of the U.S. Geological Survey's National Water- Quality Assessment (NAWQA) Program. Nationwide, nutrients have been identified as one of the primary nationwide water-quality concerns and are of particular interest in the South Platte River Basin where nutrient concentrations are large compared to concentrations in other NAWQA river basins. This report presents estimates of the magnitude of nutrient-source inputs to the South Platte River Basin, describes nutrient concen- trations and loads in the South Platte River during different seasons, and presents comparisons of nutrient inputs to instream nutrient loads. Annual nutrient inputs to the basin were estimated to be 306,000 tons of nitrogen and 41,000 tons of phosphorus. The principal nutrient sources were wastewater-treatment plants, fertilizer and manure applications, and atmospheric deposition. To characterize nutrient concentrations and loads in the South Platte River during different seasons, five nutrient synoptic samplings were conducted during 1994 and 1995. Upstream from Denver, Colorado, during April 1994 and January 1995, total nitrogen concentrations were less than 2 milligrams per liter (mg/L), and total phosphorus concentrations were less than 0.2 mg/L. The water in the river at this point was derived mostly from forested land in the mountains west of Denver. Total nutrient concentrations increased through the Denver metropolitan area, and concentration peaks occurred just downstream from each of Denver's largest wastewater-treatment plants with maximum concentrations of 13.6 mg/L total nitrogen and 2.4 mg/L total phosphorus. Nutrient concen- concentrations generally decreased downstream from Denver. Upstream from Denver during April 1994 and January 1995, total nitrogen loads were less than 1,000 pounds per day (lb/d), and total phosphorus loads were less than 125 lb/d. Total nutrient loads increased through the Denver metropolitan area, and load peaks occurred just downstream from each of Denver's largest wastewater-treatment plants, with a maximum load of 14,000 lb/d total nitrogen and 2,300 lb/d total phosphorus. In April 1994, nutrient loads generally decreased from Henderson, Colorado, to North Platte, Nebraska. In January 1995, however, nutrient loads increased from Henderson to Kersey, Colorado (maximum loads of 31,000 lb/d total nitrogen and 3,000 lb/d total phosphorus), and then decreased from Kersey to North Platte. Seasonal nutrient loads primarily were dependent on streamflow. Total nitrogen loads were largest in June 1994 and January 1995 when streamflows also were largest. During June, streamflow was large, but nitrogen concentrations were small, which indicated that snowmelt runoff diluted the available supply of nitrogen. Total phosphorus loads were largest in June, when streamflow and phosphorus concentrations were large, which indicated an additional source of phosphorus during snowmelt runoff. Streamflow along the South Platte River was smallest in April and August 1994, and nutrient loads also were smallest during these months. The downstream pattern for nutrient loads did not vary much by season. Loads were large at Henderson, decreased between Henderson and Kersey, and usually were largest at Kersey. The magnitude of the decrease in loads between Henderson and Kersey varied between synoptics and was dependent on the amount of water removed by irrigation ditches. Nutrient loads leaving the basin were very small compared to the estimated total nutrient inputs to the basin. Streamflow balances indicated that the South Platte River is a gaining river throughout much of its length; streamflow-balance residuals were as large as 15 cubic feet per second per mile. Nutrient-load balances indicated that increases in river nitrate loads were, in some places, due to nitrification and, elsewhere, were due to the influx of nitrate-enriched ground water to

Water-Resources Investigations Report↗

Application of borehole geophysics to water-resources investigations

This manual is intended to be a guide for hydrologists using borehole geophysics in ground-water studies. The emphasis is on the application and interpretation of geophysical well logs, and not on the operation of a logger. It describes in detail those logging techniques that have been utilized within the Water Resources Division of the U.S. Geological Survey, and those used in petroleum investigations that have potential application to hydrologic problems. Most of the logs described can be made by commercial logging service companies, and many can be made with small water-well loggers. The general principles of each technique and the rules of log interpretation are the same, regardless of differences in instrumentation. Geophysical well logs can be interpreted to determine the lithology, geometry, resistivity, formation factor, bulk density, porosity, permeability, moisture content, and specific yield of water-bearing rocks, and to define the source, movement, and chemical and physical characteristics of ground water. Numerous examples of logs are used to illustrate applications and interpretation in various ground-water environments. The interrelations between various types of logs are emphasized, and the following aspects are described for each of the important logging techniques: Principles and applications, instrumentation, calibration and standardization, radius of investigation, and extraneous effects.

Techniques of Water-Resources Investigations↗

Some relations between streamflow characteristics and the environment in the Delaware River region

Streamflow characteristics are determined by a large number of factors of the meteorological and terrestrial environments. Because of lack of quantitative data to describe some of the factors and complex interrelations among them, complete analysis of the relations between streamflow and the various environmental factors is impossible. However, certain simplifying assumptions and generalizations made possible a partial analysis for the Delaware River region. For relations involving average runoff or low-flow parameters, average annual precipitation was assumed to be the principal meteorological factor, and geology (a complex of many factors) was assumed to be the principal terrestrial influence, except for that of basin size which was largely eliminated by expression of discharge in terms of unit area. As a first approximation, physiographic units were used as a basis for classifying the geology. Relations between flow parameters and precipitation are fairly well defined for some physiographic units, but not for those in which the geology varies markedly or the areal variation in average precipitation is very small. These relations provide a basis for adjusting the flow parameters to reduce or eliminate the effects of areal variations in precipitation and increase their significance in studies of the effects of terrestrial characteristics. An investigation of the residual effect of basin size (the effect remaining when discharge is expressed in terms of unit area) on relations between flow parameters and average precipitation indicates that such effect is negligible, except for very large differences in area. Parameters that are derived from base-flow recession curves and are related to a common discharge per unit area have inherent advantages as indicators of effects of terrestrial characteristics of basins, because the.y are independent of areal variations in average annual precipitation. Winter base-flow parameters are also practically independent of the effects of evapotranspiration from ground water. However, in many parts of the region these advantages are reduced or nullified by the difficulties of defining base-flow recession curves, particularly winter curves, with sufficient accuracy. In the absence of suitable base-flow recession data and a suitable basis for adjusting parameters, the ratio of the discharge equaled or exceeded 90 percent of the time to the average discharge (Qtt/Qa), or a similar duration parameter, probably is the best indicator of the influence of terrestrial characteristics, although the ratio may vary somewhat with average precipitation. In a part of the region where geologic differences are large and areal variations in average precipitation are small, values of Qm/Qa for each major geologic unit were determined from streamflow records. From these values and the percentage of area represented by each unit, a ratio for each gaging station was computed. Comparison of these computed results with the observed results indicates that nearly all of the variation in the ratio is associated with variation in geology. The investigation indicates that the original assumptions are correct; average precipitation is the principal meteorological influence and geology is the principal terrestrial influence. Together these two factors account for a very large proportion of the variation in average runoff and low-flow characteristics.

Delaware, New Jersey, Pennsylvania↗

Are Piton de la Fournaise (La Réunion) and Kīlauea (Hawai‘i) really “Analog Volcanoes”?

The basaltic ocean island volcanoes of Kīlauea (Island of Hawai‘i) and Piton de la Fournaise (La Réunion Island) are remarkable natural laboratories for volcanology. Both are near the active ends of long hotspot chains and host frequent eruptive activity (both effusive and explosive). Investigations of the geophysical, geochemical, and geologic manifestations of volcanism at the two locales provide insights into a variety of processes, from the supply of magma to its eruption at the surface. The oft-stated claim that Kīlauea and Piton de la Fournaise are “analog volcanoes” appears well founded, at least in part. The two volcanoes share similar characteristics with regard to magma plumbing, occurrence of flank instability, structural and compositional evolution, and eruptive activity. Noteworthy differences include the size of the edifices (Kīlauea is about an order-of-magnitude larger in volume), their life spans (Piton de la Fournaise has been active for twice as long), and flank instability mechanisms. These differences are attributable to Hawai‘i's higher magma supply from and faster plate velocity relative to the hotspot compared to Piton de la Fournaise. Understanding these similarities and differences can be used to leverage studies of processes at one volcano by exploiting their occurrence or absence at the other.

Hawaii↗

Effects of calcium and magnesium on strontium distribution coefficients

The effects of calcium and magnesium on the distribution of strontium between a surficial sediment and simulated wastewater solutions were measured as part of an investigation to determine strontium transport properties of surficial sediment at the Idaho National Engineering Laboratory (INEL), Idaho. The investigation was conducted by the U.S. Geological Survey and Idaho State University, in cooperation with the U.S. Department of Energy. Batch experimental techniques were used to determine strontium linear sorption isotherms and distribution coefficients (K(d)'s) using simulated wastewater solutions prepared at pH 8.0??0.1 with variable concentrations of calcium and magnesium. Strontium linear sorption isotherm K(d)'s ranged from 12??1 to 85??3 ml/g, increasing as the concentration of calcium and magnesium decreased. The concentration of sorbed strontium and the percentage of strontium retained by the sediment were correlated to aqueous concentrations of strontium, calcium, and magnesium. The effect of these cation concentrations on strontium sorption was quantified using multivariate least-squares regression techniques. Analysis of data from these experiments indicates that increased concentrations of calcium and magnesium in wastewater discharged to waste disposal ponds at the INEL increases the availability of strontium for transport beneath the ponds by decreasing strontium sorption to the surficial sediment.

Environmental Geology↗

Neutron scattering reveals fractionation of natural gas mixtures in unconventional petroleum reservoir pores: Perspectives on energy resource recovery and storage

In unconventional petroleum reservoirs hydrocarbon fluids are hosted by both mineral and organic matter pores. These pores can have diameters that range from microns to less than a single nanometer and, for unconventional reservoirs, there is evidence that small pores ( <20 nm diameter) may constitute a large proportion of the available space. Understanding subsurface volumes and how fluids behave in them can be helpful for predicting hydrocarbon production and storage in the subsurface. One area with knowledge gaps regarding hydrocarbon behavior in small pores is the possibility for mixtures to fractionate (i.e., unmix) based on pore size or pore type. Mixture fractionation as a function of pore size could impact recovery of hydrocarbons, drive compositional shifts during production, and limit fluid storage within candidate reservoirs. To investigate natural gas fractionation in small geologic pores, we applied total neutron scattering to probe methane-ethane mixtures at reservoir pressures (up to ≈30 MPa) and temperature (60°C) within a sample from the Upper Cretaceous Niobrara Formation. Neutron scattering data reveal only minor fractionation occurs between methane and ethane in 20-nm diameter sample mesopores. Increased fractionation is observed for sample micropores, with up to 72% (±1% at 1-sigma) methane found in 2 nm diameter pores following injection of a 50%-50% methane-ethane mixture. These data provide rarely available direct experimental observations of hydrocarbon mixture behavior under nanoconfinement in a sample from an important unconventional petroleum reservoir. Our results are discussed in the context of evaluating hydrocarbon resources in unconventional reservoir meso- and micropores, reconciling observed gas composition changes during production, and more broadly, understanding subsurface pore volumes within an energy storage framework.

Fuel↗

Direct measurement of methane hydrate composition along the hydrate equilibrium boundary

The composition of methane hydrate, namely n w for CH 4 · n w H 2 O, was directly measured along the hydrate equilibrium boundary under conditions of excess methane gas. Pressure and temperature conditions ranged from 1.9 to 9.7 MPa and 263 to 285 K. Within experimental error, there is no change in hydrate composition with increasing pressure along the equilibrium boundary, but n w may show a slight systematic decrease away from this boundary. A hydrate stoichiometry of n w = 5.81−6.10 H 2 O describes the entire range of measured values, with an average composition of CH 4 ·5.99(±0.07)H 2 O along the equilibrium boundary. These results, consistent with previously measured values, are discussed with respect to the widely ranging values obtained by thermodynamic analysis. The relatively constant composition of methane hydrate over the geologically relevant pressure and temperature range investigated suggests that in situ methane hydrate compositions may be estimated with some confidence.

Journal of Physical Chemistry B↗

Remote sensing studies of the Dionysius region of the Moon

The Dionysius region is located near the western edge of Mare Tranquillitatis and is centered on Dionysius crater, which exhibits a well-developed dark ray system. Proposed origins for these dark rays included impact melt deposits and dark primary ejecta. The region also contains extensive deposits of Cayley-type light plains. Clementine multispectral images and a variety of spacecraft photography were utilized to investigate the composition and origin of geologic units in the Dionysius region. The portions of the dark rays for which spectral and chemical data were obtained are composed of mare debris contaminated with minor amounts of highland material. Both five-point spectra and values of the optical maturity (OMAT) parameter indicate that the dark rays are dominated by mare basalts, not glassy impact melts. The high-albedo rays associated with Dionysius exhibit FeO and TiO2 values that are lower than those of the adjacent dark ray surfaces and OMAT values that indicate that bright ray surfaces are not fully mature. The high-albedo rays are bright largely because of the contrast in albedo between ray material containing highlands-rich ejecta and the adjacent mare-rich surfaces. The mafic debris ejected by Dionysius was derived from a dark, iron-rich unit exposed high on the inner wall of the crater. This layer probably represents a mare deposit that was present at the surface of the preimpact target site. With one possible exception, there is no evidence for buried mare basalts associated with Cayley plains in the region.

Journal of Geophysical Research E: Planets↗

Regional-scale liquefaction analyses

Regional-scale liquefaction hazard analyses are necessary for resilience planning and prioritization of seismic upgrades for critical distributed infrastructure such as levees, pipelines, roadways, and electrical transmission facilities. Two approaches are often considered for liquefaction hazard analysis of distributed infrastructure: (1) conventional, site-specific probe or borehole-based analyses, which do not quantify the uncertainty between investigation locations; or (2) surface geology-based analyses, which often neglect localized geotechnical properties and include a great amount of uncertainty. We describe an analytical method to unify the disparate site-specific and deposit-scale approaches using Gaussian processes. We use borehole data to produce spatial fields of random variables for liquefaction triggering analyses, such as groundwater elevation, soil texture classification, penetration resistance, and cyclic resistance ratio that converge to the site-specific uncertainty at sampling locations but also quantify the uncertainty in-between sampling locations. We demonstrate the effectiveness of Gaussian process models for regional-scale liquefaction hazard analyses in two example studies in Washington state and California, US.

Conference Paper↗

The effect of stress changes on time-dependent earthquake probabilities for the central Wasatch Fault Zone, Utah, USA

Static and quasi-static Coulomb stress changes produced by large earthquakes can modify the probability of occurrence of subsequent events on neighboring faults. This approach is based on physical (Coulomb stress changes) and statistical (probability calculations) models, which are influenced by the quality and quantity of data available in the study region. Here, we focus on the Wasatch Fault Zone (WFZ), a well-studied active normal fault system having abundant geologic and paleoseismological data. Paleoseismological trench investigations of the WFZ indicate that at least 24 large, surface-faulting earthquakes have ruptured the fault’s five central, 35–59-km long segments since ~7 ka. Our goal is to determine if the stress changes due to the youngest paleoevents have significantly modified the present-day probability of occurrence of large earthquakes on each of the segments. For each segment, we modeled the cumulative (coseismic + postseismic) Coulomb stress changes (∆CFScum) due to earthquakes younger than the most recent event on the segment in question and applied the resulting values to the time-dependent probability calculations. Results from the Coulomb stress modeling suggest that the Brigham City, Salt Lake City, and Provo segments have accumulated ∆CFScum larger than 10 bars, whereas the Weber segment has experienced a stress decrease of 5 bars, in the scenario of recent rupture of the Great Salt Lake fault to the west. Probability calculations predict high probability of occurrence for the Brigham City and Salt Lake City segments, due to their long elapsed times (>1-2 ka) when compared to the Weber, Provo, and Nephi segments (< 1 ka). The range of calculated coefficients of variation (CV) has a large influence on the final probabilities, mostly in the case of the Brigham City segment. Finally, when the Coulomb stress and the probability models are combined, our results indicate that the ∆CFScum resulting from earthquakes postdating the youngest events on each of the five segments significantly affects the probability calculations for three of the segments: Brigham City, Salt Lake City, and Provo. The probability of occurrence of a large earthquake in the next 50 years on these three segments may therefore be underestimated if a time-independent approach, or a time-dependent approach that does not consider ∆CFS, is adopted.

Utah↗