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At least 1,477 records · Page 82Linked to original sources

Dryland photoautotrophic soil surface communities endangered by global change

Photoautotrophic surface communities forming biological soil crusts (biocrusts) are crucial for soil stability as well as water, nutrient and trace gas cycling at regional and global scales. Quantitative information on their global coverage and the environmental factors driving their distribution patterns, however, are not readily available. We use observations and environmental modelling to estimate the global distribution of biocrusts and their response to global change using future projected scenarios. We find that biocrusts currently covering approximately 12% of Earth’s terrestrial surface will decrease by about 25–40% within 65 years due to anthropogenically caused climate change and land-use intensification, responding far more drastically than vascular plants. Our results illustrate that current biocrust occurrence is mainly driven by a combination of precipitation, temperature and land management, and future changes are expected to be affected by land-use and climate change in similar proportion. The predicted loss of biocrusts may substantially reduce the microbial contribution to nitrogen cycling and enhance the emissions of soil dust, which affects the functioning of ecosystems as well as human health and should be considered in the modelling, mitigation and management of global change.

Nature Geoscience↗

Interaction of ambient conditions and fecal coliform bacteria in southern Lake Michigan beach waters: Monitoring program implications

Excessive fecal coliform bacteria in public swimming waters can potentially threaten visitor health. Fecal coliform bacteria (1984-1989) and Escherichia coli (1990-1995) density were monitored weekly at the Indiana Dunes National Lakeshore beaches for 12 summers, and park officials closed swimming areas when fecal coliform density exceeded the state water quality criteria (400 CFU fecal coliforms/ 100 ml; 235 CFU E. coli/100 ml water). Due to a 24-hour incubation in the fecal coliform and E. coli assays, beaches were closed the day after collection of high fecal coliform. Our analysis suggests that it is not possible to predict one day's fecal coliform count based on the previous day's results in waters taken from southern Lake Michigan beaches. Dispersal and deposition of bacteria were not uniform among sites or across time apparently due to interactions among environmental variables including rainfall, wind direction, water temperature, and bacteria source. Rainfall combined with northwest winds increased bacteria concentrations. Escherichia coli followed a seasonal trend with similar fluctuations in density among beaches. We suggest that the current beach monitoring protocol is inadequate for predicting fecal coliform density at the time of beach closure, and, subsequently, its use for ensuring visitor safety remains questionable.

Indiana↗

Council Monitoring and Assessment Program (CMAP): User guide for the Gulf Coast Monitoring and Assessment Portal

The Resources and Ecosystems Sustainability, Tourist Opportunities, and Revived Economies of the Gulf Coast States Act (RESTORE Act Final Rule at 31 C.F.R. Part 34) was signed into law on July 6, 2012. The RESTORE Act calls for a regional approach to restoring the long-term health of the valuable natural ecosystem and economy of the Gulf Coast region. The RESTORE Act dedicates 80 percent of civil and administrative penalties paid under the Clean Water Act, after the date of enactment, by the responsible parties in connection with the Deepwater Horizon oil spill to the Gulf Coast Restoration Trust Fund (Trust Fund) for ecosystem restoration, economic recovery, and tourism promotion in the Gulf Coast region. In addition to creating the Trust Fund, the RESTORE Act established the Gulf Coast Ecosystem Restoration Council (RESTORE Council or Council). The Council includes the Governors of the states of Alabama, Florida, Louisiana, Mississippi and Texas, the Secretaries of the U.S. Departments of Agriculture, the Army, Commerce, Homeland Security, and the Interior, and the Administrator of the U.S. Environmental Protection Agency. The Council plays a key role in developing strategies and implementing projects that help ensure the Gulf of Mexico’s natural resources are sustainable and available for future generations. The Council Monitoring and Assessment Program (CMAP) was approved as a Gulf-wide investment by the Council in the 2015 Initial Funded Priorities List and is administered jointly by the National Oceanic and Atmospheric Administration (NOAA) and the U.S. Geological Survey (USGS). Funded activities include the organization of basic, foundational components for a Gulf-wide monitoring network to measure the efficacy of investments in Gulf restoration by the Council. The program, in coordination with the Gulf of Mexico Alliance (GOMA) and through collaboration with the Gulf States, federal and local partners, academia, non-governmental organizations, and business and industry, has leveraged existing resources, capacities, and expertise and built on existing monitoring programs and their data.

Alabama, Florida, Georgia, Louisiana, Mississippi,↗

Prioritizing US Geological Survey science on salinization and salinity in candidate and selected priority river basins

The US Geological Survey (USGS) is selecting and prioritizing basins, known as Integrated Water Science basins, for monitoring and intensive study. Previous efforts to aid in this selection process include a scientifically defensible and quantitative assessment of basins facing human-caused water resource challenges (Van Metre et al. in Environmental Monitoring and Assessment , 192(7), 458 2020). In the present work, we explore this ranking process based on water quality considerations, specifically salinity and salinization. We selected top candidate basins to study salinity and salinization issues in 18 hydrologic regions that include 163 candidate basins. Our prioritization is based on quantitative assessment of sources of salinity, drivers of change, and receptors that must respond to those sources and drivers. Source terms represented in the prioritization include geology, depth to brackish groundwater, stream conductivity, chloride in precipitation, urban and agricultural land use, application of road salt as a deicer, and irrigation. Drivers represented in prioritization include changes in chemical weathering as a result of changes in rainwater chemistry. Receptors include measures of water stress, measurements of stream ecological health, and socioeconomic factors. In addition, we present research activities for the USGS on salinity and salinization that can be pursued in these basins including assessment of sources, pathways, and loadings; predicting and understanding changes in sources, peaks, and trends; understanding the components of salinity and mobilization of contaminants; understanding the relationship between salinization and changing ecosystems; and developing knowledge on the causes and distribution of groundwater salinity, brackish water resources, and challenges related to desalination.

Enviornmental Monitoring and Assessment↗

Contaminant Hazard Reviews. [Reports No. 1-28 on CD-ROM.]

This compact disc (CD) contains the first 28 reports in the Contaminant Hazard Reviews (CHR) that were published originally between 1985 and 1994 in the U.S. Department of the Interior Biological Report series. The CD was produced because printed supplies of these reviews--a total of 84,000--became exhausted and demand remained high. Each review was prepared at the request of environmental specialists of the U.S. Fish and Wildlife Service and each contained specific information on mirex, cadmium, carbofuran, toxaphene, selenium, chromium, polychlorinated biphenyls, dioxins, diazinon, mercury, polycyclic aromatic hydrocarbons, arsenic, chlorpyrifos, lead, tin, index issue, pentachlorophenol, atrazine, molybdenum, boron, chlordane, paraquat, cyanide, fenvalerate, diflubenzuron, zinc, famphur, or acrolein. Each report reviewed and synthesized the technical literature on a single contaminant and its effects on terrestrial plants and invertebrates, aquatic plants and animals, avian and mammalian wildlife, and other natural resources. The subtopics include contaminant sources and uses; physical, chemical, and metabolic properties; concentrations in field collections of abiotic materials and living organisms; deficiency effects, where appropriate; lethal and sublethal effects, including effects on survival, growth, reproduction, metabolism, mutagenicity, teratogenicity, and carcinogenicity; proposed criteria for the protection of human health and sensitive natural resources; and recommendations for additional research.

Book↗

Application of an index of biotic integrity for dunal, palustrine wetlands: Emphasis on assessment of nonpoint source landfill effects on the Grand Calumet Lagoons

Using a newly modified index of biotic integrity for assessing biological integrity of fish communities in dunal, palustrine wetlands, we assessed the non-point source influence of an industrial landfill on the Grand Calumet Lagoons. The landfill is primarily an iron and steel manufacturer's slag waste. No sensitive species, hybrids, headwater species, and either few or no simple lithophilic spawning species were collected from any of the sites in the Grand Calumet Lagoons. Species catch-per-unit of effort varied significantly between reaches in the Middle Lagoon and the West Lagoon. The most disturbed areas were adjacent to the industrial landfill and along the southern shore near the outflow from the West Lagoon. Near- and far-field stations possessed similar numbers of species and relative abundance. The near-field stations showed an increase in tolerant species, a higher proportion of omnivores and carnivores, and a lower environmental quality rating of ‘poor-very poor’. The far-field sites were classified as having ‘fair’ biological integrity and showed an increase in relative abundance, proportion of sensitive species, and an increase in simple lithophils. The loss of biological integrity in the West Pond was not accurately predicted using the modified index of biotic integrity, even though it was rated as extremely degraded by the biological diversity indices. Fish communities were negatively impacted by proximity to the landfill.

Indiana↗

Methods for comparing water-quality conditions among National Water-Quality Assessment Study Units, 1992-1995

The National Water-Quality Assessment is based on intensive investigations of stream and ground-water quality in selected major hydrologic basins (study units) of the United States. One objective of the national assessment is to comparatively evaluate water-quality conditions within and among the different study units. Methods were developed to compare the water-quality conditions of 20 study units that were studied during 1992-1995. Two approaches were taken: (1) water-quality conditions for each study unit were ranked in relation to the findings for all study units, and (2) water-quality conditions for each study unit were compared to established criteria for the protection of human health and aquatic life. Separate rankings were developed for several major characteristics of water quality by using selected combinations of measured values for individual constituents or properties. The water-quality characteristics that were evaluated for streams were nutrients and pesticides in water, organochlorine pesticides and polychlorinated biphenyls in bed sediment and tissue, semivolatile organic compounds and trace elements in bed sediment, fish community degradation, and stream habitat degradation. The water-quality characteristics that were evaluated for ground water were nitrate, pesticides, volatile organic compounds, dissolved solids, and radon. The water-quality rankings are relative strictly to the distribution of conditions measured at sampling sites included in developing the method. Sites in the first 20 National Water-Quality Assessment study units include a broad range of environmental settings, but are not a statistically representative sample of the Nation. > To supplement the relative rankings, established water-quality criteria were used to indicate where particular constituents may have adverse effects, and thus merit further investigation. Established water-quality criteria, which provide consistent benchmarks for national comparisons of individual constituents, were selected from a variety of sources and applied to specific constituents in the specific medium (water or sediment) appropriate for each criterion.

Open-File Report↗

Science from genes to landscapes

Wherever flowering plants flourish, pollinating bees, birds, butterflies, bats, and other animals are at work, providing vital and often unnoticed services. Many of these species are in serious decline, a situation if unabated, threatens agricultural production, maintenance of natural plant communities, and other important services. Responding to this urgent challenge, the U.S. Geological Survey (USGS) is part of efforts to provide scientific information to support pollinator conservation, including the implementation of a national pollinator health strategy ( http://www.usgs.gov/ecosystems/wildlife/pollinators/ .) This science is but one example of how the Ecosystems Science Mission Area of the USGS conducts science to support sound management and conservation of our Nation’s biological resources. It does this through research, technical assistance, and education conducted by Cooperative Research Units and Science Centers located in nearly every State. The quality of life and economic strength in America hinges on healthy ecosystems that support living things and natural processes. Ecosystem science better enables society to understand how and why ecosystems change, to predict and forecast future changes, and to guide actions that can prevent damage to, and restore and sustain ecosystems. It is through this knowledge that informed decisions are made about natural resources that can enhance our Nation's economic and environmental well-being.

Fact Sheet↗

Nitrate in the Columbia Aquifer, central Delmarva Peninsula, Maryland

A study of nitrate in water from 604 wells tapping the Columbia aquifer on the Delmarva Peninsula in eastern Maryland describes the factors that affect nitrate variability. Samples were collected from 196 randomly selected wells and analyzed for nitrogen species. Many were also analyzed for major ions. In addition, results of 313 nitrate analyses were randomly selected from county health department files. About 95 analyses of water samples collected from 1945 to 1978 were also evaluated. The frequency distribution of the nitrate analyses is bimodal, with 25 percent of the sample ranging from 0 to about 0.42 milligrams per liter (mg/L) nitrate as nitrogen (N), and the median is about 0.1 mg/L; the rest ranges from 0.42 to 58 mg/L, and the median is about 5.9 mg/L. The overall median nitrate concentration is about 3.5 mg/L as N. Over half of the samples had nitrate concentrations of 3 mg/L as N or higher, indicating that the water in the aquifer has been affected by human activity. Nitrate-nitrogen concentrations exceeded the water-quality standard of 10 mg/L in 15 percent of the samples established by the U.S. Environmental Protection Agency. The major factors affecting nitrate concentration are the presence of a nitrogen source, hydrogeological conditions, and the soil drainage. Sites with poorly drained soils may have a lower nitrate concentration either because the soils block the entrance of nitrate into the aquifer or because the aquifer under a poorly drained soil is associated with a chemical environment that promotes denitrification. (USGS)

Water-Resources Investigations Report↗

Predicted potential for aquatic exposure effects of per- and polyfluorinated alkyl substances (PFAS) in Pennsylvania’s statewide network of streams

Per- and polyfluoroalkyl substances (PFAS) are contaminants that can lead to adverse health effects in aquatic organisms, including reproductive toxicity and developmental abnormalities. To assess the ecological health risk of PFAS in Pennsylvania stream surface water, we conducted a comprehensive analysis that included both measured and predicted estimates. The potential combined exposure effects of 14 individual PFAS to aquatic biota were estimated using the sum of exposure-activity ratios ( Σ EARs) in 280 streams. Additionally, machine learning techniques were utilized to predict potential PFAS exposure effects in unmonitored stream reaches, considering factors such as land use, climate, and geology. Leveraging a tailored convolutional neural network (CNN), a validation accuracy of 78% was achieved, directly outperforming traditional methods that were also used, such as logistic regression and gradient boosting (accuracies of ~65%). Feature importance analysis highlighted key variables that contributed to the CNN’s predictive power. The most influential features highlighted the complex interplay of anthropogenic and environmental factors contributing to PFAS contamination in surface waters. Industrial and urban land cover, rainfall intensity, underlying geology, agricultural factors, and their interactions emerged as key determinants. These findings may help to inform biotic sampling strategies, water quality monitoring efforts, and policy decisions aimed to mitigate the ecological impacts of PFAS in surface waters.

Pennsylvania↗

Adverse outcome pathway and risks of anticoagulant rodenticides to predatory wildlife

Despite a long history of successful use, routine application of some anticoagulant rodenticides (ARs) may be at a crossroad due to new regulatory guidelines intended to mitigate risk. An adverse outcome pathway for ARs was developed to identify information gaps and end points to assess the effectiveness of regulations. This framework describes chemical properties of ARs, established macromolecular interactions by inhibition of vitamin K epoxide reductase, cellular responses including altered clotting factor processing and coagulopathy, organ level effects such as hemorrhage, organism responses with linkages to reduced fitness and mortality, and potential consequences to predator populations. Risk assessments have led to restrictions affecting use of some second-generation ARs (SGARs) in North America. While the European regulatory community highlighted significant or unacceptable risk of ARs to nontarget wildlife, use of SGARs in most EU member states remains authorized due to public health concerns and the absence of safe alternatives. For purposes of conservation and restoration of island habitats, SGARs remain a mainstay for eradication of invasive species. There are significant data gaps related to exposure pathways, comparative species sensitivity, consequences of sublethal effects, potential hazards of greater AR residues in genetically resistant prey, effects of low-level exposure to multiple rodenticides, and quantitative data on the magnitude of nontarget wildlife mortality.

Environmental Science & Technology↗

Precision mapping of snail habitat provides a powerful indicator of human schistosomiasis transmission

Recently, the World Health Organization recognized that efforts to interrupt schistosomiasis transmission through mass drug administration have been ineffective in some regions; one of their new recommended strategies for global schistosomiasis control emphasizes targeting the freshwater snails that transmit schistosome parasites. We sought to identify robust indicators that would enable precision targeting of these snails. At the site of the world’s largest recorded schistosomiasis epidemic—the Lower Senegal River Basin in Senegal—intensive sampling revealed positive relationships between intermediate host snails (abundance, density, and prevalence) and human urogenital schistosomiasis reinfection (prevalence and intensity in schoolchildren after drug administration). However, we also found that snail distributions were so patchy in space and time that obtaining useful data required effort that exceeds what is feasible in standard monitoring and control campaigns. Instead, we identified several environmental proxies that were more effective than snail variables for predicting human infection: the area covered by suitable snail habitat (i.e., floating, nonemergent vegetation), the percent cover by suitable snail habitat, and size of the water contact area. Unlike snail surveys, which require hundreds of person-hours per site to conduct, habitat coverage and site area can be quickly estimated with drone or satellite imagery. This, in turn, makes possible large-scale, high-resolution estimation of human urogenital schistosomiasis risk to support targeting of both mass drug administration and snail control efforts.

PNAS↗

Scientific Framework for resilience research on the Upper Mississippi River System

The goal of this research framework is to outline research that would continue to improve our understanding of ecological resilience of the Upper Mississippi River System (UMRS) and inform management of the system for health and resilience. We provide a broad overview of recently completed and ongoing work that has been funded as a part of the UMRS Ecological Resilience Assessment and related efforts to provide context for how proposed research questions build upon our current knowledge and may inform restoration planning and design. We describe two primary objectives within this research framework - the first objective is to investigate hypothesized drivers and feedbacks related to specified resilience, and the second is to expand our utility of general resilience indicators through further development and evaluation. The intended audience for this framework is the Upper Mississippi River Restoration Program (UMRR). The UMRR partnership is made up of natural resource agencies from five states (Illinois, Iowa, Minnesota, Missouri and Wisconsin) and five federal agencies (U.S. Army Corps of Engineers, U.S. Environmental Protection Agency, U.S. Fish and Wildlife Service, U.S. Geological Survey, and USDA Natural Resources Conservation Service).

Illinois, Iowa, Minnesota, Missouri, Wisconsin↗

Monitoring wetland water quality related to livestock grazing in amphibian habitats

Land use alteration such as livestock grazing can affect water quality in habitats of at-risk wildlife species. Data from managed wetlands are needed to understand levels of exposure for aquatic life stages and monitor grazing-related changes afield. We quantified spatial and temporal variation in water quality in wetlands occupied by threatened Oregon spotted frog ( Rana pretiosa ) at Klamath Marsh National Wildlife Refuge in Oregon, United States (US). We used analyses for censored data to evaluate the importance of habitat type and grazing history in predicting concentrations of nutrients, turbidity, fecal indicator bacteria (FIB; total coliforms, Escherichia coli ( E. coli ), and enterococci), and estrogenicity, an indicator of estrogenic activity. Nutrients (orthophosphate and ammonia) and enterococci varied over time and space, while E. coli , total coliforms, turbidity, and estrogenicity were more strongly associated with local livestock grazing metrics. Turbidity was correlated with several grazing-related constituents and may be particularly useful for monitoring water quality in landscapes with livestock use. Concentrations of orthophosphate and estrogenicity were elevated at several sites relative to published health benchmarks, and their potential effects on Rana pretiosa warrant further investigation. Our data provided an initial assessment of potential exposure of amphibians to grazing-related constituents in western US wetlands. Increased monitoring of surface water quality and amphibian population status in combination with controlled laboratory toxicity studies could help inform future research and targeted management strategies for wetlands with both grazing and amphibians of conservation concern.

Oregon↗

Effects of aquifer storage and recovery activities on water quality in the Little Arkansas River and Equus Beds Aquifer, south-central Kansas, 2011–14

The Equus Beds aquifer in south-central Kansas is aprimary water source for the city of Wichita. The Equus Beds aquifer storage and recovery (ASR) project was developed to help the city of Wichita meet increasing current (2016) and future water demands. The Equus Beds ASR project pumps water out of the Little Arkansas River during above-base flow conditions, treats it using drinking-water quality standards as a guideline, and recharges it into the Equus Beds aquifer for later use. Phase II of the Equus Beds ASR project currently (2016) includes a river intake facility and a surface-water treatment facility with a 30 million gallon per day capacity. Water diverted from the Little Arkansas River is delivered to an adjacent presedimentation basin for solids removal. Subsequently, waste from the surface-water treatment facility and the presedimentation basin is returned to the Little Arkansas River through a residuals return line. The U.S. Geological Survey, in cooperation with the city of Wichita, developed and implemented a hydrobiological monitoring program as part of the ASR project to characterize and quantify the effects of aquifer storage and recovery activities on the Little Arkansas River and Equus Beds aquifer water quality. Data were collected from 2 surface-water sites (one upstream and one downstream from the residuals return line), 1 residuals return line site, and 2 groundwater well sites (each having a shallow and deep part): the Little Arkansas River upstream from the ASR facility near Sedgwick, Kansas (upstream surface-water site 375350097262800), about 0.03 mile (mi) upstream from the residuals return line site; the Little Arkansas River near Sedgwick, Kans. (downstream surface-water site 07144100), about 1.68 mi downstream from the residuals return line site; discharge from the Little Arkansas River ASR facility near Sedgwick, Kansas (residuals return line site 375348097262800); 25S 01 W 07BCCC01 SMW–S11 near CW36 (MW–7 shallow groundwater well site 375327097285401); 25S01 W 07BCCC02 DMW–S10 near CW36 (MW–7 deep groundwater well site 375327097285402); 25S 01W 07BCCA01 SMW–S13 near CW36 (MW–8 shallow groundwater well site 375332097284801); and 25S 01W 07BCCA02 DMW–S14 near CW36 (MW–8 deep groundwater well site 375332097284802). The U.S. Geological Survey, in cooperation with the city of Wichita, assessed the effects of the ASR Phase II facility residuals return line discharges on stream quality of the Little Arkansas River by measuring continuous physicochemical properties and collecting discrete water-quality and sediment samples for about 2 years pre- (January 2011 through April 2013) and post-ASR (May 2013 through December 2014) Phase II facility operation upstream and downstream from the ASR Phase II facility. Additionally, habitat variables were quantified and macroinvertebrate and fish communities were sampled upstream and downstream from the ASR Phase II facility during the study period. To assess the effects of aquifer recharge on Equus Beds groundwater quality, continuous physicochemical properties were measured and discrete water-quality samples were collected before and during the onset of Phase II aquifer recharge in two (shallow and deep) groundwater wells. Little Arkansas River streamflow was about 10 times larger after the facility began operating because of greater rainfall. Residuals return line release volumes were a very minimal proportion (0.06 percent) of downstream streamflow volume during the months the ASR facility was operating. Upstream and downstream continuously measured water temperature and dissolved oxygen median differences were smaller post-ASR than pre-ASR. Turbidity generally was smaller at the downstream site throughout the study period and decreased at both sites after the ASR Phase II facility began discharging despite a median residuals return line turbidity that was about an order of magnitude larger than the median turbidity at the downstream site. Upstream and downstream continuously measured turbidity median differences were larger post-ASR than pre-ASR. Median post-ASR continuously measured nitrite plus nitrate and continuously computed total suspended solids and suspended-sediment concentrations were smaller than pre-ASR likely because of higher streamflows and dilution; whereas, median continuously computed dissolved and total organic carbon concentrations were larger likely because of higher streamflows and runoff conditions. None of the discretely measured water-quality constituents (dissolved and suspended solids, primary ions, suspended sediment, nutrients, carbon, trace elements, viral and bacterial indicators, and pesticides) in surface water were significantly different between the upstream and downstream sites after the ASR Phase II facility began discharging; however, pre-ASR calcium, sodium, hardness, manganese, and arsenate concentrations were significantly larger at the upstream site, which indicates that some water-quality conditions at the upstream and downstream sites were more similar post-ASR. Most of the primary constituents that make up dissolved solids decreased at both sites after the ASR Phase II facility began operation. Discretely collected total suspended solids concentrations were similar between the upstream and downstream sites before the facility began operating but were about 27 percent smaller at the downstream site after the facility began operating, despite the total suspended solids concentrations in the residuals return line being 15 times larger than the downstream site. Overall habitat scores were indicative of suboptimal conditions upstream and downstream from the ASR Phase II facility throughout the study period. Substrate fouling and sediment deposition mean scores indicated marginal conditions at the upstream and downstream sites during the study period, demonstrating that sediment deposition was evident pre- and post-ASR and no substantial changes in these habitat characteristics were noted after the ASR Phase II facility began discharging. Macroinvertebrate community composition (evaluated using functional feeding, behavioral, and tolerance metrics) generally was similar between sites during the study period. Fewer macroinvertebrate metrics were significant between the upstream and downstream sites post-ASR (6) than pre-ASR (14), which suggests that macroinvertebate communities were more similar after the ASR facility began discharging. Upstream-downstream comparisons in macroinvertebrate aquatic-life-support metrics had no significant differences for the post-ASR time period and neither site was fully supporting for any of the Kansas Department of Health and Environment aquatic-life-support metrics (Macroinvertebrate Biotic Index; Kansas Biotic Index with tolerances for nutrients and oxygen-demanding substances; Ephemeroptera, Plecoptera, and Trichoptera [EPT] richness; and percentage of EPT species). Overall, using macroinvertebrate aquatic life-support criteria from the Kansas Department of Health and Environment, upstream and downstream sites were classified as partially supporting before and after the onset of ASR facility operations. Fish community trophic status and tolerance groups generally were similar among sites during the study period. Fish community Little Arkansas River Basin Index of Biotic Integrity scores at the upstream and downstream sites were indicative of fair-to-good conditions before the facility began operating and decreased to fair conditions after the facility began operating. Groundwater physicochemical changes concurrent with the beginning of recharge operations at the Sedgwick basin were more pronounced in shallow groundwater. No constituent concentrations in the pre-recharge period in comparison to the post-recharge period increased to concentrations exceeding drinking water regulations; however, nitrate decreased significantly from a pre-recharge exceedance of the U.S. Environmental Protection Agency maximum contaminant level to a post recharge nonexceedance. Shallow groundwater chemical concentrations or rates of detection increased after artificial recharge began for the ions potassium, chloride, and fluoride; phosphorus and organic carbon species; trace elements barium, manganese, nickel, arsenate, arsenic, and boron; agricultural pesticides atrazine, metolachlor, metribuzin, and simazine; organic disinfection byproducts bromodichloromethane and trichloromethane; and gross beta levels. Additionally, water temperature, and pH were larger after recharge began; and total solids and slime-forming bacteria concentrations and densities were smaller. Total solids, nitrate, and selenium significantly decreased; and potassium, chloride, nickel, arsenic, fluoride, phosphorus and carbon species, and gross beta levels significantly increased in shallow groundwater after artificial recharge. Results of biological activity reaction tests indicated that water quality microbiology was different before and after artificial recharge began; at times, these differences may lead to changes in dominant bacterial populations that, in turn, may lead to formation and expansion in populations that may cause bioplugging and other unwanted effects. Calcite, iron (II) hydroxide, hydroxyapatite, and similar minerals, had shifts in saturation indices that generally were from undersaturation toward equilibrium and, in some cases, toward oversaturation. These shifts toward neutral saturation indices might suggest reduced weathering of the minerals present in the Equus Beds aquifer. Chemical weathering in the shallow parts of the aquifer may be accelerated because of the increased water temperatures and the system is more vulnerable to clogged pores and mineral dissolution as the equilibrium state is affected by recharge and withdrawal. When oversaturation is indicated for iron minerals, plugging of aquifer materials may happen.

Kansas↗

Biochar modulates the dynamics of legacy nutrients in enhancing soil health and crop productivity

Most major crops in agricultural soils exhibit relatively low nutrient use efficiency for nitrogen (N), phosphorus (P), and potassium (K), often necessitating supplemental nutrient inputs to achieve sustainable yields. Furthermore, the increasing use of biowastes such as compost, manure, and biosolids, which frequently have nutrient ratios that do not match crop requirements, has contributed to excessive nutrient inputs and subsequent accumulation in soils. This situation has been further exacerbated by intensive farming practices involving multiple cropping cycles per season. Overuse of nutrients causes them to accumulate in the soil, creating a legacy nutrient pool. The application of biochar as soil amendment is considered a potential strategy to control legacy nutrients dynamics. The current review inspects the possible value of biochar in modulating legacy nutrient reserves in the soil, thereby increasing the bioavailability of nutrients and improving crop yield. This review discusses the search scope and synthesis approaches for the bibliometric methodological component through rigorous screening process (Preferred Reporting Items for Systematic Reviews and Meta-Analysis (PRISMA)), focusing on journal articles published in last 20 years that specifically address legacy nutrient management. The significance of the economic and environmental effects of legacy nutrients and the insufficient knowledge of how biochar application influences nutrient dynamics in soil highlight the necessity for additional research to address current gaps.

Land↗

Animals as indicators of ecosystem responses to air emissions

With existing and proposed air-quality regulations, ecological disasters resulting from air emissions such as those observed at Copperhill, Tennessee, and Sudbury, Ontario, are unlikely. Current air-quality standards, however, may not protect ecosystems from subacute and chronic exposure to air emissions. The encouragement of the use of coal for energy production and the development of the fossil-fuel industries, including oil shales, tar sands, and coal liquification, point to an increase and spread of fossil-fuel emissions and the potential to influence a number of natural ecosystems. This paper reviews the reported responses of ecosystems to air-borne pollutants and discusses the use of animals as indicators of ecosystem responses to these pollutants. Animal species and populations can act as important indicators of biotic and abiotic responses of aquatic and terrestrial ecosystems. These responses can indicate long-term trends in ecosystem health and productivity, chemical cycling, genetics, and regulation. For short-term trends, fish and wildlife also serve as monitors of changes in community structure, signaling food-web contamination, as well as providing a measure of ecosystem vitality. Information is presented to show not only the importance of animals as indicators of ecosystem responses to air-quality degradation, but also their value as air-pollution indices, that is, as air-quality-related values (AQRV), required in current air-pollution regulation.

Environmental Management↗

A critical time for mercury science to inform global policy

Mercury is a global pollutant released into the biosphere by varied human activities including coal combustion, mining, artisanal gold mining, cement production, and chemical production. Once released to air, land and water, the addition of carbon atoms to mercury by bacteria results in the production of methylmercury, the toxic form that bioaccumulates in aquatic and terrestrial food chains resulting in elevated exposure to humans and wildlife. Global recognition of the mercury contamination problem has resulted in the Minamata Convention on Mercury, which came into force in 2017. The treaty aims to protect human health and the environment from human-generated releases of mercury curtailing its movement and transformations in the biosphere. Coincident with the treaty’s coming into force, the 13th International Conference of Mercury as a Global Pollutant (ICMGP-13) was held in Providence, Rhode Island USA. At ICMGP-13, cutting edge research was summarized and presented to address questions relating to global and regional sources and cycling of mercury, how that mercury is methylated, the effects of mercury exposure on humans and wildlife, and the science needed for successful implementation of the Minamata Convention. Human activities have the potential to enhance mercury methylation by remobilizing previously released mercury, and increasing methylation efficiency. This synthesis concluded that many of the most important factors influencing the fate and effects of mercury and its more toxic form, methylmercury, stem from environmental changes that are much broader in scope than mercury releases alone. Alterations of mercury cycling, methylmercury bioavailability and trophic transfer due to climate and land use changes remain critical uncertainties in effective implementation of the Minamata Convention. In the face of these uncertainties, important policy and management actions are needed over the short-term to support the control of mercury releases to land, water and air. These include adequate monitoring and communication on risk from exposure to various forms of inorganic mercury as well as methylmercury from fish and rice consumption. Successful management of global and local mercury pollution will require integration of mercury research and policy in a changing world.

Environmental Science & Technology↗