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How does the onset of offset influence geologic slip rates?

Geologic slip rates are typically based on the displacement accrued by a geomorphic or stratigraphic feature and the age of the offset feature. Because slip rates are commonly calculated by dividing the displacement of a faulted marker by its age, they contain two open time intervals: the elapsed time between the age of an offset feature and the age of the earthquake that displaced the feature, and the time between the present‐day and the most recent earthquake. Here, we explore the influence of including unconstrained open intervals in geologic slip rate calculations. We test the degree to which these open intervals affect geologic slip rates and their uncertainties, and we find that their influence depends primarily on mean earthquake recurrence intervals (RIs). Slip rates on faults with longer RIs, such as the Wasatch fault, can be greatly influenced by an increase of up to 20% when accounting for open intervals. In contrast, slip rates on faults with shorter RIs, such as the San Andreas fault, are only slightly influenced by the assumption that slip rates calculated over open intervals approximate those calculated over closed intervals. Our analyses indicate that faults with moderate slip rates (∼0.2–5 mm/yr) are sensitive to both open interval effects themselves, as well as methods to quantify and account for these effects. We re‐evaluate how slip rates are calculated and defined in displacement–time space using published deformation records. We explore the utility of assigning a probability distribution to the initiation of offset of the oldest faulted feature and the timing of the most recent earthquake (MRE). We find that calculating geologic slip rates without using probability distributions that capture the timing of the MRE and the onset of offset of the oldest faulted feature, especially on slow‐to‐moderate slip rate faults, can lead to systematic underestimation of average geologic slip rates.

Seismological Research Letters

A partially nonergodic ground-motion model for Fourier amplitude spectra for the San Francisco Bay area, California, USA

We develop a partially nonergodic ground-motion model (GMM) for Fourier amplitude spectra for the San Francisco Bay Area, California, USA, using the Bayless and Abrahamson (2019) GMM as a reference ergodic GMM and developing location-dependent adjustments to the predicted median and variance. We compile regional ground-motion data from moment magnitude (𝑀 w ) >3 earthquakes occurring during 2000–2022 for which magnitude information is available in the U.S. Geological Survey Comprehensive Catalog (Guy et al., 2015). The data set predominantly consists of records from 𝑀 w 3.5–4.5 earthquakes but includes three well-recorded 𝑀 w > 5 events. Ground-motion residuals are evaluated using the time-averaged shear-wave velocity in the top 30 m (𝑉 S30 ) from the California-specific map of Thompson et al. (2018) and basin-depth site parameters from the seismic velocity model of Aagaard and Hirakawa (2021). The 𝑉 S30 dependence and basin-depth scaling of the reference ergodic GMM of Bayless and Abrahamson (2019) are evaluated and modified with the updated data set. We compute maps of site adjustments using a varying-coefficient model that considers the spatial correlation structure and uncertainties at each observation location. The spatial covariance model is developed using ground-motion residuals that are standardized by the uncertainty model, which allows for consideration of the aleatory variability in developing the site adjustments. The covariance model is fit considering the means and standard deviations of the site terms at all locations. The use of partially nonergodic median adjustments results in modified variance components of the within-event variability. Due to the low number of large-magnitude earthquakes that control seismic hazard in the data set, we do not modify between-event variance; however, we present adjustments to site-to-site variability for use in partially nonergodic hazard assessments.

California

2024 Surprise Inlet landslides: Insights from a prototype landslide‐triggered tsunami monitoring system in Prince William Sound, Alaska

Alaska's coastal communities face growing landslide hazards owing to glacier retreat and extreme weather intensified by the warming climate, yet hazard monitoring remains challenging. As part of ongoing experimental monitoring in Prince William Sound, we detected three large landslides (0.5–2.3 M m 3 ) at Surprise Inlet on 20 September 2024, within the span of an hour. These events were identified in near real-time through seismic data and later confirmed using satellite imagery, tidal records, and infrasound. The landslides generated a modest tsunami, and a 4 cm wave was recorded by a tide gauge 18 km away, marking the first recorded landslide to reach water since monitoring began in this region in 2021. Here, we examine the detection and interpretation of these landslides using multiple data sources and modeling. We demonstrate the effectiveness of this regional seismic monitoring system and show how complementary instrumentation, where available, can enhance detection capabilities.

Alaska

The petrogenesis of Þingmúli volcano, East Fjords, Iceland

In this work we revisit Þingmúli volcano (Þ = Th), a classic locality known as an example of a complete tholeiitic differentiation. Þingmúli is a ~ 9.5 Ma extinct central volcano located in the East Fjords of Iceland, in which the whole compositional spectrum from basalt to rhyolites have erupted. These volcanic products have been previously considered as petrogenetically related by an ideal fractionation trend, regardless any temporal relationship or volumetric considerations. Here we report new whole-rock geochemistry, mineral chemistry, isotope analyses, estimation of residence times of the different eruptive deposits, and an update of the original petrogenetic model. Our results highlight that an enriched source, likely spinel lherzolites, generated transitional-alkaline basaltic melts after 15–20% of partial melting at depths of 40–45 km. Many of these basaltic melts erupted at various stages of the volcano's history, while others remained longer in the volcanic plumbing system. These evolved by fractional crystallisation into basaltic andesite magmas with a residence time of ~5 years based on the crystal size distribution of the plagioclase population. Isotopic differences between the basalts/basaltic andesites ( 87 Sr/ 86 Sr ~ 0.7034; 143 Nd/ 144 Nd ~ 0.51315) and the erupted rhyolites ( 87 Sr/ 86 Sr ~ 0.7037; 143 Nd/ 144 Nd ~ 0.51304) indicate that the latter are not petrogenetically related to the former. Therefore, instead of a fractional crystallisation mechanism to generate the rhyolites, we propose the partial melting of ignimbrite layers located beneath the volcano. The broad range of trace element concentrations in andesites and dacites and their different isotopic values compared to the basalts strongly suggest that these magmas have been generated by magma mixing between basaltic and rhyolitic melts, similar to modern day Icelandic volcanoes such as Hekla. These results highlight the need to revisit previously studied Icelandic classic localities and reassess their traditionally proposed petrogenetic models.

Þingmúli volcano, East Fjords

Integrating marine historical ecology into management of Alaska’s Pacific cod fishery for climate readiness

The Pacific cod ( Gadus macrocephalus ) fishery was closed in 2020 after a rapid decline in biomass caused by the marine heat waves of 2014–2019. Pacific cod are exceptionally thermally sensitive and management of this fishery is now challenged by increasingly unpredictable climate conditions. Fisheries monitoring is critical for climate readiness, but short-term monitoring data may be inadequate for recognizing and anticipating change under rapid climate changes. We propose an interdisciplinary, marine historical ecology framework that looks to long-term records (local and traditional knowledge, history, archaeology, and paleoclimatology) to capture a long range of ecological variability and provide historical context for management. In order to connect to contemporary fisheries management, this framework must be built on a common vocabulary and an understanding of the key metrics used in fisheries stock assessments. Here, we propose metrics derived from Pacific cod stock assessment and synthesize information relevant to understanding the effects of past warming periods on cod populations across the Gulf of Alaska and Bering Sea. This case study provides a framework for thinking about how to use these historical records in the context of fisheries management under rapidly changing climate conditions.

Alaska

Framework for mapping liquefaction hazard–Targeted design ground motions

Liquefaction-induced ground failure poses substantial challenges to geotechnical earthquake engineering design. Current approaches for designing against liquefaction hazards, as specified in most seismic provisions, focus on estimating a liquefaction factor of safety ( 𝐹⁢𝑆𝐿 ) and typically characterize earthquake loading using design parameters based on probabilistic or deterministic ground motion levels. Because 𝐹⁢𝑆𝐿 is estimated deterministically, this basis of design neglects considerable uncertainties for estimating liquefaction triggering and its consequences and results in a lack of liquefaction-specific design criteria, particularly as structural design has advanced toward risk-targeted performance objectives. This study presents a framework for developing liquefaction-targeted design criteria based on a minimum acceptable return period of liquefaction, informed by probabilistic liquefaction hazard analysis (PLHA). PLHA quantifies annualized rates of liquefaction by considering contributions from (1) the full ground-motion probability space, and (2) uncertainties in liquefaction triggering using probabilistic models. PLHA is used in this study to characterize the current, effective return periods of 𝐹⁢𝑆𝐿 ( 𝑇𝑅,𝐹⁢𝑆 ) obtained from conventional liquefaction hazard analysis (CLHA) using uniform-hazard ground motions. 𝑇𝑅,𝐹⁢𝑆 is evaluated in a parametric study of nearly 100 sites throughout the conterminous United States. The results indicate large geographic variations in acceptable liquefaction hazard levels, with implied 𝑇𝑅,𝐹⁢𝑆 ranging between approximately 1,000 to 3,000 years. To address these inconsistencies without the computational demands of full PLHA, a framework is proposed for developing a liquefaction-targeted design peak ground acceleration, 𝑃⁢𝐺⁢𝐴𝐿 , for use in liquefaction models that result in consistent liquefaction design levels across all geographic locations. The mapped 𝑃⁢𝐺⁢𝐴𝐿 is shown to be somewhat sensitive to site-specific properties, and adjustment factors are developed and presented. The proposed 𝑃⁢𝐺⁢𝐴𝐿 mapping procedure produces 𝐹⁢𝑆𝐿 estimates that are consistent with those obtained from full PLHA at a target 𝑇𝑅,𝐹⁢𝑆 , providing a promising roadmap to incorporating PLHA concepts into current liquefaction design methods.

Journal of Geotechnical and Geoenvironmental Engin

Subaerially exposed Iceberg Lake sediments: An exceptional record of historical subaqueous earthquake disturbance at the eastern edge of the Alaskan-Aleutian subduction zone

Paleoseismic records are limited in the Yakutat Terrane (eastern edge of the Alaskan-Aleutian subduction zone) due to the extensive ice cover that hinders traditional methods such as trenching of the faults, but lacustrine sediments offer an alternative archive. We investigated lakebed sediments exposed after recent outburst floods (1999 CE) at Iceberg Lake, a glacier-dammed basin whose stratigraphy was revealed after the lake drained and partially eroded. We logged outcrops across the basin and sampled their sediments. Between annually laminated background deposits, we identified sediment gravity flow beds and in-situ soft-sediment deformation structures (convolutions, sand blows, and fractures) interpreted to be earthquake-induced. Our age model links some of the uppermost depositional and deformational events to the 1958, 1964 and 1979 CE earthquakes. These results demonstrate that Iceberg Lake was a sensitive recorder of seismic shaking and its sediments hold strong potential for producing a paleoseismic record for the northern Yakutat Terrane.

Alaska

Assessing natural recharge in Indian Wells Valley, California: A Basin Characterization Model case study

The communities in Indian Wells Valley (IWV), in the northern Mojave Desert in California, rely on groundwater for domestic and agricultural use. Mountain front recharge from the surrounding Sierra Nevada is the main source of natural recharge to the valley. Increased urbanization, agricultural development, and groundwater pumping during recent decades put IWV in a state of critical overdraft. The U.S. Geological Survey Basin Characterization Model, version 8 (BCMv8) was used to evaluate historical and future climate and hydrologic conditions in IWV. The BCMv8 estimated natural recharge in IWV at 10.7 million cubic meters (Mm 3 ) per year for the period from 1981 to 2010. Future patterns of water balance variables using three future climate scenarios, hot-wet, hot-dry, and warm-moderately wet, were calculated for mid-century (2040–69) and end-of-century (2070–99) periods. Results for both wet models projected an increase in recharge in both periods, whereas the hot-dry model projected a decrease in recharge in both periods. All models reported a large increase in seasonal variability in recharge, indicating more future availability and frequent occurrences of drought years. All climate scenarios projected an increase in climatic water deficit in both periods. These increases in irrigation demand and variability of water supply highlight the importance of strategic management planning for the sustainability of water resources in IWV.

California

An early Holocene wet period in the southwestern United States

Multiple generations of spring-fed streams traversed ∼800 km 2 of the Las Vegas Valley in southern Nevada between ca. 10.9 ka and 8.5 ka, depositing an extensive tufa network. The scale of this network and diversity of tufa morphologies is novel in North America and offers an opportunity to obtain quantitative paleoclimate data for the region during the early Holocene. We determined isotopic compositions and estimated past temperatures using clumped isotope data from early Holocene tufa on the valley floor (698 m) as well as tufa forming today at higher elevation in the nearby Spring Mountains at Cold Creek Spring (1856 m). Modern and fossil tufa yielded comparably low δ 18 O values, implying that source waters for both were derived from high-elevation winter precipitation. Clumped isotope temperatures of modern tufa average 15.8 ± 2.5 °C, aligning with mean summer temperatures of the emergent spring water, and indicate equilibrium conditions of tufa formation. The early Holocene tufa yielded similar clumped isotope temperatures, averaging 15.2 ± 3.9 °C, meaning it precipitated at temperatures that occur at much higher elevations today. The Las Vegas tufa record, combined with nearby and temporally correlative paleospring and lacustrine records, suggest that cool/wet conditions prevailed throughout the Mojave Desert during the early Holocene. These records also demonstrate that spring ecosystems responded to millennial-scale hydroclimate variations that supersede climate change driven solely by insolation. The previously unrecognized pattern of ecosystem response to hydroclimate documented here may assist in understanding climate drivers for the early Holocene and provide critical information for the fate of groundwater-dependent ecosystems in the southwestern United States.

Nevada

Evaluation of submersible pressure transducers for streamflow monitoring in small streams

Compact streamgages requiring minimal infrastructure and equipped with submersible pressure transducers (PTs) are increasingly used to monitor small streams, yet disparate implementations obscure their accuracy under real-world conditions. This study isolated instrumentation-derived uncertainty in stage monitoring by co-locating various combinations of commercial vented and unvented PTs with seven U.S. Geological Survey (USGS) reference streamgages on small streams. Multi-year PT stage records from compact streamgages, collected and corrected following USGS protocols, were compared to concurrent reference observations. Vented PTs demonstrated an average measurement uncertainty of ±0.005 m and mean absolute percent error (MAPE) of ±0.2%. Unvented PTs exhibited higher uncertainty, averaging ±0.009 m and ±0.4% MAPE. Although both sensor types had stage errors up to ±0.3 m, 95% of vented PT and unvented PT observations were within 0.01 and 0.02 m of reference stage, respectively. Analysis of additional unvented PTs revealed stage errors of up to ±1.2% when using barometric sensors within 15 km of the in-water sensor. Propagation of stage error to discharge using reference rating models resulted in cumulative discharge MAPEs of ±4.5% for vented and ±5.5% for unvented PTs. These findings highlight PTs as practical alternatives to reference instrumentation when deployed with standardized procedures, potentially expanding access to reliable streamflow data.

conterminous United States

Integration of rupture directivity models for the US National Seismic Hazard Model

Several rupture directivity models (DMs) have been developed in recent years to describe the near-source spatial variations in ground motion amplitudes related to propagation of rupture along the fault. We recently organized an effort towards incorporating these directivity effects into the USGS National Seismic Hazard Model (NSHM), by first evaluating the community's work and potential methods to implement directivity adjustments into probabilistic seismic hazard analysis (PSHA). Guided by this evaluation and comparison among the considered DMs, we selected an approach that can be readily implemented into the USGS hazard software, that provides an azimuthally varying adjustment to the median ground motion and its aleatory variability. This method allows assessment of the impact on hazard levels and provides a platform to test the DM amplification predictions using a generalized coordinate system, necessary for consistent calculation of source-to-site distance terms for complex ruptures. We give examples of the directivity-related impact on hazard, progressing from a simple, hypothetical rupture, to more complex fault systems, composed of multiple rupture segments and sources. The directivity adjustments were constrained to strike-slip faulting, where DMs have good agreement. We find that rupture directivity adjustments using a simple median and aleatory adjustment approach can impact hazard both from a site perspective and on a regional scale, increasing shaking off the end of the fault trace up to 30--40\% and potentially reducing it for sites along strike. Statewide hazard maps of California show that the change in shaking along major faults can be a factor to consider for assessing long-period (>ls) near-source effects within the USGS NSHM going forward, reaching up to 10--20\%. Finally, we suggest consideration of minimum parameter ranges and baseline requirements as future DMs are developed to minimize single approach adaptations, to enable more consistent application within both ground motion and hazard studies.

Earthquake Spectra

Assessment of extreme subsurface hydrologic conditions captured during atmospheric river storms in the San Francisco Bay area (California, USA) with applications to shallow landslide early warning

An increase in soil pore water pressure is the typical trigger for the majority of landslides caused by rainfall. Atmospheric river storms, common to the west coast of North America during the winter season, can deliver landslide triggering rainfall resulting in severe impacts to coastal communities. Using a network of hydrologic monitoring stations situated within landslide-prone terrain in the San Francisco Bay area of California (USA), we assess the meteorologic conditions and resulting hydrologic and landslide response resulting from eight consecutive storm events that caused thousands of shallow landslides during the winter of 2022–2023. We find disparate hydrological responses and resultant degrees of observed landsliding ranging from < 1 landslide/km2 to 18 landslides/km2 at the monitoring sites that reflect the interplay and differences between rainfall delivery, subsurface hydrological characteristics, and geotechnical properties at each site. Antecedent soil moisture from both early season rainfall and the first storm in the sequence played a critical role in setting up some hillslopes for failure. Subsequent storms then generated elevated pore water pressures for several hours with associated landsliding. However, we find that the occurrence of widespread landsliding required not only sufficient pore water pressure magnitude in susceptible hillslopes, but also full and prolonged effective soil saturation throughout hillslope profiles. Landslides may still occur at lower values and durations of effective saturation but are likely to be less extensive regionally. We present these findings within the context of research directions and improvements to landslide early warning systems first suggested by researchers 40 years ago.

California

Evaluating harvest liberalization strategies on population dynamics of southern latitude temperate-breeding Canada geese

The recovery of the Canada goose ( Branta canadensis ) is one of North America's greatest conservation success stories. Today, continental abundance of temperate-breeding Canada geese (those breeding in southern Canada and lower 48 states in the United States) greatly exceeds historical levels. As a result of increased abundance, human–goose conflicts have also increased, ranging from private and agricultural property damage to human health concerns. Managers have primarily attempted to lower Canada goose populations using hunter harvest via liberalized hunting regulations (increased bag limits and total hunting days). To evaluate the effectiveness of harvest strategies for temperate-breeding Canada geese, managers need a better understanding of how liberalized hunting regulations affect population dynamics. We estimated survival and harvest probabilities, abundance, and recovery distribution of temperate-breeding Canada geese banded in Arkansas, USA, during 2005–2020. We found that adult harvest probabilities declined overall during the study and adult survival probabilities increased. Annual abundances of juvenile geese (≤1 year old) declined during the study, whereas there was no detectable trend in abundance of the adult population over time. Most Canada geese breeding in Arkansas were shot in Arkansas, indicating potential for population dynamics to be influenced largely by state-specific harvest regulations. However, our results suggest that harvest liberalization as a management tool may have limited capacity to further influence population dynamics of Canada geese. Declines in productivity and recruitment likely had a greater influence on the similar observed declines in juvenile and adult abundances, respectively, during our study. More research is needed to better understand the ecological mechanism affecting the population dynamics of Canada geese in both urban and rural environments.

Arkansas

ShakeAlert Earthquake Early Warning System performance during the Mw 7.0 offshore Cape Mendocino earthquake

The 5 December 2024 M w 7.0 Offshore Cape Mendocino earthquake was a challenging test of the U.S. West Coast ShakeAlert earthquake early warning system due to its offshore epicenter and limited near‐source station coverage. We analyzed real‐time performance of all components of the ShakeAlert system, including the seismic algorithms (earthquake point‐source integrated code [EPIC] and Finite‐fault rupture Detector [FinDer]), the geodetic algorithm (Geodetic First Approximation of Size and Time–peak ground displacement [GFAST‐PGD]), and network telemetry during the event. EPIC created the first solution for this earthquake 15 s after origin time with an initial magnitude estimate of M 5.6 and location error of 10 km from the Advanced National Seismic System epicenter. An early spurious trigger from station CE.89101 fortuitously maintained location accuracy and, correspondingly, magnitude accuracy. FinDer contributed its first solution at 18 s with a location estimate closer to the seismic network and produced two distinct rupture geometries, leading to minor fluctuations in estimated intensity contours. GFAST‐PGD did not meet alerting thresholds but otherwise performed as expected. Network latencies were <2 s for most stations, supporting the rapid detection of this earthquake by the system. Roughly five million alerts were delivered to cell phone devices in California and Oregon during this event. This was also the first instance of a school district‐wide ShakeAlert‐powered system being activated. Comparisons to recorded seismograms demonstrate that the maximum warning times before potentially damaging shaking (intensity 6+) were in the range of 5–55 s. Although the ShakeAlert system provided accurate solutions and useful alert delivery, this earthquake raised awareness of potential issues within the system, including the need for improved offshore location estimates, a combination of solutions from ShakeAlert servers, and handling of spurious triggers.

California

Comparing subduction ground-motion models to observations for Cascadia

We evaluate Cascadia subduction ground-motion models (GMMs), considered for the 2023 US National Seismic Hazard Model (NSHM) update, by comparing observations to model predictions. The observations comprise regional recordings from intraslab earthquakes, including contributions from 2021 and 2022 events in southern Cascadia and global records from interface earthquakes. Since the 2018 NSHM update, new GMMs for Cascadia have been published by the Next Generation Attenuation (NGA)-Subduction Project that require independent evaluation. In the regional intraslab comparisons, we highlight a characteristic frequency dependence for Cascadia data, with short periods having lower ground motions and longer periods being comparable to other subduction zones. We evaluate differences in northern and southern Cascadia and find that the NGA-Subduction GMMs developed using southern Cascadia data perform better in this region than the model that did not consider these data. We compare ground-motion variability in Cascadia with the NGA-Subduction model predictions and find differences at short periods ( T = 0.1 s) due to the use of global versus regional data in the development of these models. Moreover, the within-event component of aleatory variability from the GMMs overpredicts the standard deviation of Cascadia recordings at very short periods ( T < 0.05 s). Using global interface earthquakes as a proxy to evaluate the Cascadia GMMs, we find long-period overprediction from a simulation-based GMM and some of the empirical GMMs. When comparing recent observations, we find a similar misfit to GMMs and the 2010 and 2022 Ferndale earthquakes. Finally, we observe different basin amplification factors arising in different subsets of the data, which indicate that differences in basin factors between empirical GMMs could arise from the data selection choices by the developers. As part of evaluating the regional basin terms, we apply basin amplification factors from the magnitude 9 Cascadia earthquake simulations to the empirical GMMs for interface earthquakes. The comparisons presented in this study indicate that the NGA-Subduction GMMs for Cascadia perform well relative to observations and older subduction GMMs.

British Columbia, California, Oregon, Washington

Time varying crustal anisotropy at Whakaari/White Island volcano

Whakaari/White Island has been the most active New Zealand volcano in the 21st century, producing small phreatic and phreatomagmatic eruptions, which are hard to predict. The most recent eruption occurred in 2019, tragically claiming the lives of 22 individuals and causing numerous injuries. We employed shear-wave splitting analyses to investigate variations in anisotropy during quiescence, unrest, and an eruption between 2018 and 2020. We examined spatial and temporal variations in 7972 shear-wave splitting measurements and derived 1402 V p /IV s ratio measurements. Comparing shear-wave splitting parameters from similar earthquake paths across different times indicates that the observed temporal changes are unlikely to result from variations in earthquake paths through media with spatial variability. Instead, these changes may stem from variations in anisotropy over time, likely caused by changes in crack alignment due to stress or varying fluid content.

Whakaari/White Island volcano

Framework for assessing intranational risk of critical mineral sectors: Case study of India

Recent geopolitical actions regarding the supply of critical minerals have highlighted both the threats posed by countries dominating a critical mineral supply chain, and the potential mitigations served by alternative supplier countries. However, no systematic quantification exists for the intranational factors that determine such threats or mitigations. This study outlines a methodological framework for quantifying the intranational risk profile of critical mineral sectors and compares them with the sector's international potential for leverage. The four intranational factors of concentration, synchronization, private sector involvement, and regulatory obstacles were analyzed across multiple scales in order to determine an intranational risk score that quantifies the resilience or fragility of the critical mineral sector in question. Network analysis was also separately conducted to identify the most important entities operating across all critical mineral sectors. Finally, this study assessed the critical mineral sector's global share of reserves and production to determine an international risk score that quantifies the country's critical mineral sector's leverage potential. A case study of India showed that two critical mineral sectors with high leverage potential, chromite and barite, were respectively intranationally resilient and fragile. Of the remaining sectors with minimal leverage, five sectors such as aluminum were intranationally resilient and may serve as viable mitigation options for future critical mineral supply. Three sectors such as titanium were intranationally fragile, but recent regulatory developments may both decrease intranational risk and increase international risk, potentially making them major critical mineral sectors in the future.

Resources Policy

Evidence for a biological origin of uranium-rich carbon masses within the Ediacaran Salt Range Formation of Pakistan

Thucholites are unique organic structures found in igneous and sedimentary rocks composed of a U-C-rich interior enclosed by an organic outer shell. Their formation and occurrence have perplexed scientists for over 100 years. Typically, thucholites are sparse in sedimentary rocks but where found in abundance, they may be the result of rapid paleoecological disruptions, e.g., volcanic ashfall. Here, we evaluated thucholites from the Ediacaran Salt Range Formation of the Indus Basin in Pakistan using field emission scanning electron microscopy (FESEM) and nanoscale secondary ion mass spectroscopy (NanoSIMS) to propose a two-stage mechanism for thucholite development. NanoSIMS results suggest organic matter in thucholite cores formed by biological fractionation (represented by the presence of lighter 13 C/ 12 C and 34 S/ 32 S) while the outer organic mantle formed via radiolysis-induced polymerization. FESEM elemental analysis confirms compositional differences between the two thucholite components (core and mantle), further implying their contrasting origins. Dimensional comparison of thucholite cores and their U-bearing mineral morphologies to ancient and modern U-biomineralized microbes suggests that the thucholite cores formed from metal-biological interactions. The presence of volcanogenic biotite, alkali feldspar, and clay spherules (interpreted as devitrified volcanic glass) with thucholite suggests that the thucholite cores in the Salt Range Formation are biological responses to rapid paleoenvironmental change from volcanic eruption which preserved the fossilized morphologies of Proterozoic microorganisms.

Salt Range