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At least 1,477 records · Page 82Linked to original sources

Reconnaissance of the quality of surface water in the upper Virgin River Basin, Utah, Arizona, and Nevada, 1981-82

This report on the quality of surface water in the Virgin River basin from the headwaters near Navajo Lake, Utah, to Littlefield, Ariz., was prepared by the U.S. Geological Survey in cooperation with the Division of Water Rights, Utah Department of Natural Resources. The objectives of the study leading to the report were to obtain information on general chemical characteristics of surface water and to determine effects of the natural environment and water use on these characteristics. The scope of the study did not include an intensive investigation of the effects of man's activities on water quality.

Arizona, Nevada, Utah↗

Definition of regional relationships between dissolved solids and specific conductance, Susquehanna River basin, Pennsylvania and New York

This report presents statistical tests for assessing the accuracy and validity of two regional models of the relationship between dissolved-solids concentration and specific conductance. These models are used to estimate dissolved-solids concentrations based on specific-conductance measurements. The two regional models are compared with station models for 27 stream sites in the Susquehanna River basin. The average standard errors of estimate of two regional models, when used to estimate dissolved-solids concentrations for the 27 stream sites, are 10.7 and 10.6 percent. In comparison, the station models have average standard errors of 9.0 and 9.3 percent, respectively. Results of the statistical tests indicate that in the Susquehanna River basin the regional models can be used to estimate dissolved-solids concentrations from specific-conductance data for sites for which chemical analyses are not available.

New York, Pennsylvania↗

Water resources data for Louisiana, water year 1973

Water resources data for the 1973 water year for West Virginia including records of streamflow or reservoir storage at gaging stations, partial-record stations, and miscellaneous sites, records of water-quality data on the chemical and physical characteristics of surface water, and records of ground-water levels at index wells are given in this report. In Part 1, records are included for 126 gaging stations of which 119 are streamflow discharge stations, 1 is stage only streamflow station, and 6 are reservoir or lake stations; also included are records for 2 low-flow partial-record stations, 39 crest-stage partial-record stations and 7 miscellaneous sites. Locations of gaging stations are shown in Figure 1, and location of partial-record stations are shown in Figure 2. In Part 2, data on the quality of surface water (chemical, temperature, and sediment) were collected from designated sampling sites at predetermined intervals, such as once daily, weekly, monthly, or less frequently, and at some sites data were recorded on punched paper tape at 15-, 30-, or 60-minute intervals. Records are given for 28 sampling stations of which 18 are continuous record stations, and 10 are partial-record stations. Locations of water quality stations are shown in Figure 1. A few pertinent stations (not included above) in bordering States are also included in this report. In Part 3, records are included for 46 observation wells of which 8 are equipped with water-level recorders that give a continuous graph of the fluctuations, 3 are equipped with digital recorders that punch the water level on a tape at hourly intervals, at 35 manual reading are made with a steel tape by observers on the days indicated. Locations of index wells are shown in Figure 2. The records were collected and computed by the Water Resources Division of the U.S. Geological Survey under the direction of Edwin E. Harris, district chief. These data represent that portion of the National Water Data System collected by the U.S. Geological Survey and cooperating State and Federal agencies in West Virginia. Beginning with the 1961 water year, streamflow records and related data have been released by the Geological Survey in annual reports on a State-boundary basis. Water-quality records beginning with the 1964 water year have been similarly released either in separate reports or in conjunction with streamflow records. These reports are for limited distribution and are designed primarily for rapid release of data shortly after the end of the water year. Records of discharge and stage of streams, and contents and stage of lakes and reservoirs are published in a series of U.S. Geological Survey water-supply papers entitled, "Surface Water Supply of the United States." Through September 30, 1960, these water-supply papers were in an annual series and since then are in a 5-year series. Records of chemical quality, water temperatures, and suspended sediment have been published since 1941 in an annual series of water-supply papers entitled, "Quality of Surface Waters of the United States." More information is given under the headings "Publications" on page 21. Records of ground water levels are published in a series of water supply papers entitled, "Ground-water Levels in the United States". Through 1955 these were in an annual series but are now in a 5-year series. More information is given under the heading "Publications" on page 22.

Louisiana↗

Dissolved-mineral inflow to Great Salt Lake and chemical characteristics of the salt lake brine. Part I: Selected hydrologic data

This report presents the data collected for a study of the dissolved-mineral load contributed by surficial sources to Great Salt Lake, Utah. The study was conducted by the U.S. Geological Survey in cooperation with the University of Utah during the period from July 1959 through June 1962, and is part of an overall investigation of the Great Salt Lake basin by the University. Financial support for the study was provided by the U.S. Geological Survey and by the University of Utah Research Fund and Uniform School Fund. Some of the data presented in this report were obtained as part of cooperative programs between the Geological Survey and other agencies.

Utah↗

Water resources data for West Virginia, water year 1973

Water resources data for the 1973 water year for West Virginia including records of streamflow or reservoir storage at gaging stations, partial-record stations, and miscellaneous sites, records of water-quality data on the chemical and physical characteristics of surface water, and records of ground-water levels at index wells are given in this report. In Part 1, records are included for 126 gaging stations of which 119 are streamflow discharge stations, 1 is stage only streamflow station, and 6 are reservoir or lake stations; also included are records for 2 low-flow partial-record stations, 39 crest-stage partial-record stations and 7 miscellaneous sites. Locations of gaging stations are shown in Figure 1, and location of partial-record stations are shown in Figure 2. In Part 2, data on the quality of surface water (chemical, temperature, and sediment) were collected from designated sampling sites at predetermined intervals, such as once daily, weekly, monthly, or less frequently, and at some sites data were recorded on punched paper tape at 15-, 30-, or 60-minute intervals. Records are given for 28 sampling stations of which 18 are continuous record stations, and 10 are partial-record stations. Locations of water-quality stations are shown in Figure 1. A few pertinent stations (not included above) in bordering States are also included in this report. In Part 3, records are included for 46 observation wells of which 8 are equipped with water-level recorders that give a continuous graph of the fluctuations, 3 are equipped with digital recorders that punch the water level on a tape at hourly intervals, at 35 manual reading are made with a steel tape by observers on the days indicated. Locations of index wells are shown in Figure 2. The records were collected and computed by the Water Resources Division of the U.S. Geological Survey under the direction of Edwin E. Harris, district chief. These data represent that portion of the National Water Data System collected by the U.S. Geological Survey and cooperating State and Federal agencies in West Virginia. Beginning with the 1961 water year, streamflow records and related data have been released by the Geological Survey in annual reports on a State-boundary basis. Water-quality records beginning with the 1964 water year have been similarly released either in separate reports or in conjunction with streamflow records. These reports are for limited distribution and are designed primarily for rapid release of data shortly after the end of the water year. Records of discharge and stage of streams, and contents and stage of lakes and reservoirs are published in a series of U.S. Geological Survey water-supply papers entitled, "Surface Water Supply of the United States." Through September 30, 1960, these water-supply papers were in an annual series and since then are in a 5-year series. Records of chemical quality, water temperatures, and suspended sediment have been published since 1941 in an annual series of water-supply papers entitled, "Quality of Surface Waters of the United States." More information is given under the headings "Publications" on page 21. Records of ground water levels are published in a series of water supply papers entitled, "Ground-water Levels in the United States". Through 1955 these were in an annual series but are now in a 5-year series. More information is given under the heading "Publications" on page 22.

West Virginia↗

Water resources data for West Virginia, water year 1974

Water resources data for the 1974 water year for West Virginia including records of streamflow or reservoir storage at gaging stations, partial-record stations, and miscellaneous sites, records of water-quality data on the chemical and physical characteristics of surface water, and records of ground-water levels at index wells are given in this report. In Part 1, records are included for 131 gaging stations of which 124 are streamflow discharge stations, 1 is stage only streamflow station, and 6 are reservoir or lake stations; also included are records for 12 low-flow partial-record stations, 38 crest-stage partial-record stations and 13 miscellaneous sites. Locations of gaging stations are shown in Figure 1, and location of partial-record stations are shown in Figure 2. In Part 2, data on the quality of surface water (chemical, temperature, and sediment) were collected from designated sampling sites at predetermined intervals, such as once daily, weekly, monthly, or less frequently, and at some sites data were recorded on punched paper tape at 15-, 30-, or 60-minute intervals. Records are given for 42 sampling stations of which 30 are continuous record stations, and 12 are partial-record stations. Locations of water-quality stations are shown in Figure 1. A few pertinent stations (not included above) in bordering States are also included in this report. In Part 3, records are included for 37 observation wells of which 8 are equipped with water-level recorders that give a continuous graph of the fluctuations, 3 are equipped with digital recorders that punch the water level on a tape at hourly intervals, at 26 manual reading are made with a steel tape by observers on the days indicated. Locations of index wells are shown in Figure 2. The records were collected and computed by the Water Resources Division of the U.S. Geological Survey under the direction of Edwin E. Harris, district chief. These data represent that portion of the National Water Data System collected by the U.S. Geological Survey and cooperating State and Federal agencies in West Virginia. Beginning with the 1961 water year, streamflow records and related data have been released by the Geological Survey in annual reports on a State-boundary basis. Water-quality records beginning with the 1964 water year have been similarly released either in separate reports or in conjunction with streamflow records. These reports are for limited distribution and are designed primarily for rapid release of data shortly after the end of the water year. Records of discharge and stage of streams, and contents and stage of lakes and reservoirs are published in a series of U.S. Geological Survey water-supply papers entitled, "Surface Water Supply of the United States." Through September 30, 1960, these water-supply papers were in an annual series and since then are in a 5-year series. Records of chemical quality, water temperatures, and suspended sediment have been published since 1941 in an annual series of water-supply papers entitled, "Quality of Surface Waters of the United States." More information is given under the headings "Publications" on page 24. Records of ground water levels are published in a series of water supply papers entitled, "Ground-water Levels in the United States". Through 1955 these were in an annual series but are now in a 5-year series. More information is given under the heading "Publications" on page 25.

West Virginia↗

Index of current water-resources activities in Ohio, 1985

This report summarizes the U. S. Geological Survey 's Water Resources Division 's program in Ohio in 1985. The work of the Ohio District is carried out through the District office in Columbus and a field office in New Philadelphia. Collection of basic data needed for continuing determination and evaluation of the quantity, quality, and use of Ohio 's water resources is the responsibility of the District 's Hydrologic Surveillance Section. The Hydrologic Investigations Section conducts analytical and interpretive water-resource appraisals describing the occurrence, availability, and the physical, chemical, and biological characteristics of surface and groundwater. In addition to introductory material describing the structure of the Ohio District, information is presented on current projects, sites at which basic surface- and groundwater data are collected , and reports of Ohio 's water resources published by the U.S. Geological Survey and cooperating agencies. (USGS)

Open-File Report↗

Implications for organic maturation studies of evidence of a geologically rapid increase and stabilization of vitrinite reflectance at peak temperature: Cerro Prieto geothermal system, Mexico

A short-term rapid heating and cooling of the rock in well M-94 below 1300 m was caused by a pulse of hot water passing through the edge of the Cerro Prieto, Mexico, geothermal system. Below 1300 m, the peak paleotemperatures were about 225-250 degrees C, but equilibrium well log temperatures indicate a decrease to 150-210 degrees C at present. This hot water pulse sharply increased vitrinite reflectance to levels comparable to those measured in the central part of the system, even though studies of apatite fission-track annealing indicate that the duration of heating was only 10{0}-10{1} yr in M-94, in contrast to 10{3}-10{4} yr in the central part of the system. These data indicate that sedimentary organic matter chemically reacts quickly to temperature increases of about 125 degrees C above ambient, even when the higher temperature existed for only 10{0}-10{1} yr. The quick change of the vitrinite reflectance geothermometer indicates that thermal maturation reactions can stabilize, after a geologically short period of heating, to a level consistent with peak temperature under moderate to high-temperature diagenesis in open, fluid-rich, geothermal systems. Cerro Prieto is one of the most intensively studied and well-known geothermal systems in the world. Thus, data from Cerro Prieto are a benchmark to compare with the predictions of published thermal maturation models such as those formulated by J. Karweil, N. V. Lopatin, and A. K. Burnham and J. J. Sweeney. These thermal maturation models inaccurately predict duration of heating at Cerro Prieto. The kinetic equations used in these models explicitly allow thermal maturation to continue indefinitely at peak temperature, which does not seem to be the case at Cerro Prieto.

Cerro Prieto fault↗

Contaminants of emerging concern in the Great Lakes Basin: A report on sediment, water, and fish tissue chemistry collected in 2010-2012

Despite being detected at low levels in surface waters and sediments across the United States, contaminants of emerging concern (CECs) in the Great Lakes Basin are not well characterized in terms of spatial and temporal occurrence. Additionally, although the detrimental effects of exposure to CECs on fish and wildlife have been documented for many CECs in laboratory studies, we do not adequately understand the implications of the presence of CECs in the environment. Based on limited studies using current environmentally relevant concentrations of chemicals, however, risks to fish and wildlife are evident. As a result, there is an increasing urgency to address data gaps that are vital to resource management decisions. The U.S. Fish and Wildlife Service, in collaboration with the U.S. Geological Survey, is leading a Great Lakes Basin-wide evaluation of CECs (CEC Project) with the objectives to (a) characterize the spatial and temporal distribution of CECs; (b) evaluate risks to fish and wildlife resources; and (c) develop tools to aid resource managers in detecting, averting, or minimizing the ecological consequences to fish and wildlife that are exposed to CECs. This report addresses objective (a) of the CEC Project, summarizing sediment and water chemistry data collected from 2010 to 2012 and fish liver tissue chemistry data collected in 2012; characterizes the sampling locations with respect to potential sources of CECs in the landscape; and provides an initial interpretation of the variation in CEC concentrations relative to the identified sources. Data collected during the first three years of our study, which included 12 sampling locations and analysis of 134 chemicals, indicate that contaminants were more frequently detected in sediment compared to water. Chemicals classified as alkyphenols, flavors/ fragrances, hormones, PAHs, and sterols had higher average detection frequencies in sediment compared to water, while the opposite was observed for pesticides, pharmaceuticals, and plasticizers/flame retardants. The St. Louis River and Maumee River sampling locations had the most CEC detections in water and sediment, relative to other sites, as well as the largest number of maximum detected concentrations across all sites in the Basin. No consistent temporal CEC occurrence patterns were observed at locations sampled multiple times each day. Most appearances and increases in chemical concentrations in sediments occurred at sites immediately downstream from wastewater treatment plants and at sites with predominantly developed land use. The location with the most observed appearances and increases was the St. Louis River. Perfluorinated compounds were commonly detected in fish liver tissues with detections in 100% of both benthic and pelagic species. The occurrence of these chemicals in liver tissue of benthic and pelagic species was generally similar. Abstract

Great Lakes Basin↗

Spatial and temporal patterns in streamflow, water chemistry, and aquatic macroinvertebrates of selected streams in Fairfax County, Virginia, 2007–18

Urbanization substantially alters the landscape in ways that can impact stream hydrology, water chemistry, and the health of aquatic communities. Stormwater best management practices (BMPs) are the primary tools used to mitigate the effects of urban stressors such as increased runoff, decreased baseflow, and increased nutrient and sediment transport. To date, Fairfax County Virginia’s stormwater management program has made substantial investments into the implementation of both structural and nonstructural BMPs aimed at restoring and protecting watersheds. The U.S. Geological Survey (USGS), in cooperation with Fairfax County, Virginia, established a long-term water-resources monitoring program to evaluate the watershed-scale effects of these investments. Monitoring began at 14 stations in 2007 and was expanded to 20 stations in 2013. This report utilized the first 10 years of data collection to (1) assess water quantity and quality, as well as ecological condition; (2) compute annual nutrient and sediment loads; and (3) evaluate trends in streamflow, water quality, and ecological condition. Efforts are underway to link the biotic and abiotic patterns described herein to watershed management practices as well as factors such as land use change, public works infrastructure, and climate. Hydrologic, chemical, and benthic macroinvertebrate community conditions in the streams monitored were similar to those observed in other studies of urban streams. Multidecadal trends in baseflow indices and runoff ratios at long-term Chesapeake Bay Non-tidal Network streamgages (CB-NTN) indicate a decrease in groundwater recharge and increase in storm runoff as a result of urbanization. Streamflow yields varied spatially with land cover, geology, and soil characteristics, whereas flashiness was positively related to impervious area. Dissolved oxygen typically was lowest in the Coastal Plain and across all Triassic Lowlands streams, and highest in the Piedmont. Dissolved oxygen concentrations generally were above Virginia’s minimum criterion of 4.0 milligrams per liter (mg/L), most violations occurred at Paul Spring Branch in the Coastal Plain during the warmest months of the year owing to increased chemical and biological oxygen demand. Typical pH values of the monitored streams centered on neutrality (pH = 7); however, diurnal fluctuations were most prevalent in the continuous pH data at Flatlick Branch (FLAT; a Triassic Lowlands station), as a result of increased photosynthesis catalyzed by phosphorus-rich geology. Specific conductance (SC) varied spatially owing to geology (highest at Triassic Lowlands stations) and anthropogenic disturbance (watersheds with high impervious land cover). Specific conductance typically was inversely related to streamflow except in winter months following deicing road salt applications, when values increased by several orders of magnitude. A significant increase in SC of about 2 percent per year was observed from the combined trend result of all monitoring stations over the 10-year period. Significant SC increases occurred at nearly all monitoring stations. Increasing trends were observed during winter and nonwinter months, which suggests that salts applied to deice roadways and other impervious surfaces are stored in the environment and released year-round. Suspended-sediment (SS) concentrations in monthly samples did not vary significantly between most stations, but typically were highest in the spring and lowest in the fall as a result of seasonal differences in streamflow and climate. Suspended-sediment yields ranged from 62 to 1,428 tons per square mile (ton/mi 2 ), with a median of 302 ton/mi 2 . Annual loads were greatest during the wettest water years (October 1-September 30; 2008, 2011, and 2014), with the greatest interannual variability occurring at Difficult Run above Fox Lake (DIFF) and South Fork Little Difficult Run (SFLIL). Suspended sediment was primarily composed of silts and clays; however, the proportion of sand in suspended sediment was related positively to streamflow. Cross-correlation analyses suggested the dominant sources of SS were streambank erosion and resuspension of in-channel material at DIFF and FLAT; whereas, upland sources and erosion of upper streambanks were more common at Dead Run (DEAD), Long Branch (LONG), and SFLIL. Median total phosphorus (TP) concentrations ranged from 0.016 to 0.077 mg/L, with a networkwide median of 0.022 mg/L, were highest in the warm season (April-September), and were composed primarily of dissolved phosphorous. Although TP concentrations were relatively low across the network, the highest concentrations were consistently at stations located in the Triassic Lowlands, owing to phosphorous-rich geology, and in the Coastal Plain, owing to the low-phosphorous sorptive capacity of those soils. A significant increase in TP concentration occurred in a few stations, but the combined trend results from all stations demonstrated a significant increase of about 4 percent per year. Networkwide increases were also observed in total dissolved phosphorus, orthophosphate, and total particulate phosphorus. The composition of TP shifted from dissolved to particulate as streamflow increased and for this reason loads primarily were composed of particulate phosphorous. Median annual TP loads were highest at FLAT and DEAD and ranged from 247 to 642 pounds per square mile (lbs/mi 2 ) networkwide. Interannual variability in phosphorous yields was apparent at most stations; the highest loading years were also the wettest years during the study period and coincident with the highest peak annual flows. Total nitrogen (TN) concentrations typically were low throughout the network with exceptions occurring at stations located in watersheds with a high density of septic infrastructure. Elevated TN concentrations also were observed in some watersheds without a high density of septic systems and may be attributable to geologic and soil properties that limit denitrification as well as other unknown anthropogenic inputs. Total nitrogen typically was dominated by nitrate during baseflows; however, the proportion of particulate nitrogen increased during stormflows. Total nitrogen yields were similar across stations, with medians ranging from about 3,600 to 6,300 lbs/mi 2 and were related to annual streamflow volume. Total nitrogen concentrations and flow-normalized concentrations decreased over the 10-year period at 7 stations, with median reductions of about 2.5 percent. Increasing trends were observed at the two stations with the highest median TN concentration (Captain Hickory Run and SFLIL, 3–5 mg/L), both watersheds contain a high density of septic infrastructure. The combined trend results from all stations revealed no trend in TN and a declining trend in nitrate of about 2 percent per year. Overall, benthic community metrics indicated that streams throughout Fairfax County were initially of poor health; however, many metrics show an improving trend (from poor to fair based on the Fairfax County Index of Biological Integrity [IBI]). Significant increasing trends in IBI occurred at the network-scale and at 4 individual stations; additionally, scores improved by at least 1 qualitative category (for example, poor to fair, fair to good) at 11 of the 14 stations between 2009 (the first year all 14 stations were sampled) and 2017. Changes in all metrics suggest that the biodiversity, function, and condition of streams in Fairfax County are improving, but some of these improvements are driven by increased diversity and percent composition of organisms that are tolerant of the urban environment.

Virginia↗

Combined use of groundwater dating, chemical, and isotopic analyses to resolve the history and fate of nitrate contamination in two agricultural watersheds, Atlantic coastal plain, Maryland

The history and fate of groundwater nitrate (NO 3 − ) contamination were compared in 2 small adjacent agricultural watersheds in the Atlantic coastal plain by combined use of chronologic (CCl 2 F 2 , 3 H), chemical (dissolved solids, gases), and isotopic (δ 15 N,δ 13 C, δ 34 S) analyses of recharging groundwaters, discharging groundwaters, and surface waters. The results demonstrate the interactive effects of changing agricultural practices, groundwater residence times, and local geologic features on the transfer of NO 3 − through local flow systems. Recharge dates of groundwaters taken in 1990–1992 from the surficial aquifer in the Chesterville Branch and Morgan Creek watersheds near Locust Grove, Maryland, ranged from pre-1940 to the late 1980’s. When corrected for localized denitrification by use of dissolved gas concentrations, the dated waters provide a 40-year record of the recharge rate of NO 3 − , which increased in both watersheds by a factor of 3–6, most rapidly in the 1970's. The increase in groundwater NO 3 − over time was approximately proportional to the documented increase in regional N fertilizer use, and could be accounted for by oxidation and leaching of about 20–35% of the fertilizer N. Groundwaters discharging upward beneath streams in both watersheds had measured recharge dates from pre-1940 to 1975, while chemical data for second-order reaches of the streams indicated average groundwater residence times in the order of 20+ years. At the time of the study, NO 3 − discharge rates were less than NO 3 − recharge rates for at least two reasons: (1) discharge of relatively old waters with low initial NO 3 − concentrations, and (2) local denitrification. In the Chesterville Branch watershed, groundwaters remained oxic throughout much of the surficial aquifer and discharged relatively unaltered to the stream, which had a relatively high NO 3 − concentration (9–10 mg/L as N). In the Morgan Creek watershed, groundwaters were largely reduced and denitrified before discharging to the stream, which had a relatively low NO 3 − concentration (2–3 mg/L as N). Chemical and isotopic data indicate that quantitative denitrification occurred within buried calcareous glauconitic marine sediments that are present at relatively shallow depths beneath the Morgan Creek watershed. NO 3 − removal by forests, wetlands, and shallow organic-rich soils in near-stream environments was largely avoided by groundwaters that followed relatively deep flow paths before converging and discharging rapidly upward to the streams.

Maryland↗

Chemical analyses (raw laboratory data) and locality index maps of the Confederate Gulch area, Broadwater and Meagher Counties, Montana

Analysis of the side looking airborn radar imagery of Massachusetts, Connecticut and Rhode Island indicates that radar shows the topography in great detail. Since bedrock geologic features are frequently expressed in the topography the radar lends itself to geologic interpretation. The radar was studied by comparisons with field mapped geologic data first at a scale of approximately 1:125,000 and then at a scale of 1:500,000. The larger scale comparison revealed that faults, minor faults, joint sets, bedding and foliation attitudes, lithology and lithologic contacts all have a topographic expression interpretable on the imagery. Surficial geologic features were far less visible on the imagery over most of the area studied. The smaller scale comparisons revealed a pervasive, near orthogonal fracture set cutting all types and ages of rock and trending roughly N40?E and N30?W. In certain places the strike of bedding and foliation attitudes and some lithologic Contacts were visible in addition to the fractures. Fracturing in southern New England is apparently far more important than has been previously recognized. This new information, together with the visibility of many bedding and foliation attitudes and lithologic contacts, indicates the importance of radar imagery in improving the geologic interpretation of an area.

Montana↗

Chemical and biological indicators of nutrient enrichment in the Yellowstone River basin, Montana and Wyoming, August 2000: Study design and preliminary results

A water-quality investigation of the Yellowstone River was conducted during low-flow conditions in August 2000, under the U.S. Geological Survey's National Water-Quality Assessment (NAWQA) program. Samples for analysis of water chemistry (nutrients, field measurements, and other constituents) and biological communities (periphyton, phytoplankton, and macroinvertebrates) were collected at 11 sites on the main stem of the Yellowstone River between Corwin Springs and Sidney, Montana, as well as from tributaries including the Clarks Fork of the Yellowstone River, the Bighorn River, and the Tongue River. Preliminary results of the investigation indicate concentrations of total nitrogen varied little throughout the length of the main stem of the Yellowstone River; total phosphorus concentrations increased slightly in the downstream direction. In contrast, periphyton chlorophyll a and ash-free dry mass concentrations, and algal productivity rates, were highest in the middle sections of the Yellowstone River.

Montana, Wyoming↗

Hydrogeologic characterization of the San Antonio Creek Valley watershed, Santa Barbara County, California

The San Antonio Creek Valley watershed (SACVW) is located in western Santa Barbara County, about 15 miles south of Santa Maria and 55 miles north of Santa Barbara, California. The SACVW is about 135 square miles and encompasses the San Antonio Creek Valley groundwater basin; the SACVW is separated from adjacent groundwater basins by the Casmalia and Solomon Hills to the north, and the Purisima Hills to the south. At the western, downstream part of the valley, uplifted, consolidated rocks cause groundwater to discharge at land surface at Barka Slough. Since the late 1800s, groundwater has been the primary source of water for agricultural, military, municipal, and domestic uses. Groundwater withdrawal by pumping exceeded the amount of water replenishing the aquifer system during water years 1948–2018, causing groundwater-level declines of more than 150 feet in parts of the valley and reducing base flow at Barka Slough. Reliance on groundwater for agricultural water use (primarily for the irrigation and frost protection of vineyards, and fruit and berry crops) continues to strain the sustainability of the groundwater system. Through a cooperative agreement, the Santa Barbara County Water Agency and Vandenberg Space Force Base invited the U.S. Geological Survey to address declines in groundwater levels, develop a better understanding of the hydrogeologic system, and provide tools to help evaluate and manage the effects of future development of the San Antonio Creek Valley groundwater basin within the encompassing San Antonio Creek Valley watershed (SACVW). The objectives of this study were to (1) refine the hydrogeologic framework of the San Antonio Creek Valley watershed, (2) quantify the hydrologic budget of the valley, and (3) develop hydrologic modeling tools to evaluate and aid in managing the groundwater resource. This report focuses on the first and second objectives to construct a hydrogeologic framework and characterize the historical and present-day hydrologic conditions of the SACVW during water years 1948–2018. As part of the second objective, work included quantifying the hydrologic budget and evaluating the hydrogeologic system using a combination of existing data and geologic and hydrologic data collected for this study. The groundwater-flow system in the SACVW consists of five hydrogeologic units. These separate water-bearing units were identified based on hydrogeologic properties, such as sediment grain size, vertical-head differences in multiple-depth, monitoring-well sites, long-term groundwater level responses to pumping and climate, and the chemical character of groundwater and groundwater age in the mostly semi-consolidated to unconsolidated basin-fill sediments. The hydrogeologic units that comprise the different aquifers vary in their lithologic composition. The upper and lower aquifers (upper Paso Robles Formation, and lower Paso Robles Formation and Careaga Sandstone, respectively) are relatively coarse grained and are comprised of sand, gravel, and clay; the middle confining unit (the middle Paso Robles Formation) is relatively fine grained and is comprised of primarily clay, silt, and sand. The Pezzoni-Casmalia and Los Alamos faults, which are inferred to transect the SACVW between the western and eastern areas of the valley floor, do not appear to substantially affect the groundwater system. Present-day recharge to the study area occurs primarily as infiltration from precipitation and streams in the upland areas of the Casmalia Hills and Solomon Hills, and along the main channel of San Antonio Creek. Reported estimates of annual natural recharge during water years 1948–2018 generally ranged from about 5,000 acre-feet to more than about 30,000 acre-feet. Stable and radioactive isotopes show that groundwater from the lower aquifer is old and probably was recharged as infiltration from precipitation and streams in the eastern upland areas of the Solomon Hills; however, the infiltration and recharge from these sources probably does not occur under present-day climatic conditions. Anthropogenic recharge, from sources such as return flow from agricultural irrigation, municipal water systems, and wastewater effluent, was estimated to range from about 600 acre-feet in 1948 to about 6,600 acre-feet in 2018. The average annual amount of groundwater removed from the SACVW by pumping during 1948–2018 was estimated to be about 17,200 acre-feet per year, increasing from about 3,000 acre-feet in 1948 to about 32,600 acre-feet in 2018. Estimates of annual pumpage generally exceeded estimates of annual recharge beginning in the mid-1970s and continuing through 2018. The predominant direction of groundwater flow under historical and present-day conditions was from the eastern uplands in the Solomon Hills to the west along San Antonio Creek to the discharge area in Barka Slough, and from the northern uplands in the Casmalia Hills south to San Antonio Creek. Pumpage since the early 1900s and the subsequent groundwater-level declines have substantially reduced the amount of natural groundwater discharge at Barka Slough. Estimates of base flow to San Antonio Creek at the western, downstream extent of the SACVW have varied over time in response to changes in groundwater pumpage and climate; however, there was an overall decline in base flow during water years 1956–2018, decreasing from an average of about 1,700 acre-feet per year during 1956–69, to about 300 acre-feet per year during 2016–18. The long-term extraction of groundwater correlates with a decrease in groundwater levels by more than about 150 feet since the early 1940s in the eastern part of the basin near Los Alamos, and as much as about 50 feet in the upland areas and in the western part of the basin. At Barka Slough, groundwater levels have declined below land surface in some places, altering native riparian vegetation in and around the slough. Surface-water quality in the SACVW varied depending on location and the time of year the samples were collected and on the amount of annual precipitation Most groundwater in the SACVW was calcium-bicarbonate-type water with total dissolved-solids concentrations of about 500–800 milligrams per liter generally representing water naturally recharged as infiltration from precipitation and streams. Total dissolved-solids concentrations in some wells ranged from 800 to 8,000 milligrams per liter, suggesting mixing of naturally recharged infiltrated water with water associated with oil-bearing geologic formations, agricultural products, or the evaporation of shallow groundwater. Concentrations of total dissolved solids and the chemical constituents chloride, nitrate plus nitrite (as nitrogen), calcium, and magnesium at selected wells generally increased during water years 1980–2018; increasing concentrations of these constituents may be associated with the expansion of agriculture in the watershed over time and the corresponding increase in the use of nitrates and calcium- and magnesium-based fertilizers and soil additives in modern agricultural practices. The predominant direction of groundwater flow during historical and present-day conditions was from the eastern uplands in the Solomon Hills to the west along San Antonio Creek toward Barka Slough, and from the western uplands in the Casmalia Hills south to San Antonio Creek. The age of groundwater in the SACVW was evaluated using radioactive isotopes, and the flow of groundwater within the SACVW was evaluated using radioactive and stable isotopes. Modern groundwater (recharged after 1952) was generally found adjacent to San Antonio Creek and its tributaries in wells with perforated depths that averaged about 270 feet below land surface. Pre-modern groundwater (recharged before 1952) was found in wells that had average perforation depths of about 540 ft below land surface. Pre-modern groundwater identified in wells in the eastern upland area is interpreted to have had long, slow travel times to the western part of the SACVW where it was eventually discharged as base flow at Barka Slough or extracted as groundwater pumpage.

California↗

Prioritizing US Geological Survey science on salinization and salinity in candidate and selected priority river basins

The US Geological Survey (USGS) is selecting and prioritizing basins, known as Integrated Water Science basins, for monitoring and intensive study. Previous efforts to aid in this selection process include a scientifically defensible and quantitative assessment of basins facing human-caused water resource challenges (Van Metre et al. in Environmental Monitoring and Assessment , 192(7), 458 2020). In the present work, we explore this ranking process based on water quality considerations, specifically salinity and salinization. We selected top candidate basins to study salinity and salinization issues in 18 hydrologic regions that include 163 candidate basins. Our prioritization is based on quantitative assessment of sources of salinity, drivers of change, and receptors that must respond to those sources and drivers. Source terms represented in the prioritization include geology, depth to brackish groundwater, stream conductivity, chloride in precipitation, urban and agricultural land use, application of road salt as a deicer, and irrigation. Drivers represented in prioritization include changes in chemical weathering as a result of changes in rainwater chemistry. Receptors include measures of water stress, measurements of stream ecological health, and socioeconomic factors. In addition, we present research activities for the USGS on salinity and salinization that can be pursued in these basins including assessment of sources, pathways, and loadings; predicting and understanding changes in sources, peaks, and trends; understanding the components of salinity and mobilization of contaminants; understanding the relationship between salinization and changing ecosystems; and developing knowledge on the causes and distribution of groundwater salinity, brackish water resources, and challenges related to desalination.

Enviornmental Monitoring and Assessment↗

Composition of dust deposited to snow cover in the Wasatch Range (Utah, USA): Controls on radiative properties of snow cover and comparison to some dust-source sediments

Dust layers deposited to snow cover of the Wasatch Range (northern Utah) in 2009 and 2010 provide rare samples to determine the relations between their compositions and radiative properties. These studies are required to comprehend and model how such dust-on-snow (DOS) layers affect rates of snow melt through changes in the albedo of snow surfaces. We evaluated several constituents as potential contributors to the absorption of solar radiation indicated by values of absolute reflectance determined from bi-conical reflectance spectroscopy. Ferric oxide minerals and carbonaceous matter appear to be the primary influences on lowering snow-cover albedo. Techniques of reflectance and Mössbauer spectroscopy as well as rock magnetism provide information about the types, amounts, and grain sizes of ferric oxide minerals. Relatively high amounts of ferric oxide, indicated by hard isothermal remanent magnetization (HIRM), are associated with relatively low average reflectance (<0.25) across the visible wavelengths of the electromagnetic spectrum. Mössbauer spectroscopy indicates roughly equal amounts of hematite and goethite, representing about 35% of the total Fe-bearing phases. Nevertheless, goethite (α-FeOOH) is the dominant ferric oxide found by reflectance spectroscopy and thus appears to be the main iron oxide control on absorption of solar radiation. At least some goethite occurs as nano-phase grain coatings less than about 50 nm thick. Relatively high amounts of organic carbon, indicating as much as about 10% organic matter, are also associated with lower reflectance values. The organic matter, although not fully characterized by type, correlates strongly with metals (e.g., Cu, Pb, As, Cd, Mo, Zn) derived from distal urban and industrial settings, probably including mining and smelting sites. This relation suggests anthropogenic sources for at least some of the carbonaceous matter, such as emissions from transportation and industrial activities. The composition of the DOS samples can be compared with sediments in a likely dust-source setting at the Milford Flat Fire (MFF) area about 225 km southwest of Salt Lake City. The MFF area represents geologically and physiographically similar and widespread dust sources west-southwest of the Wasatch Range and heavily populated Wasatch Front. The DOS layers and MFF sediments are similar in some textural, chemical, and magnetic properties, as well as in the common presence of goethite, hematite, magnetite-bearing basalt fragments, quartz, plagioclase, illite, and kaolinite. Textural and some chemical differences among these deposits can be explained by atmospheric sorting as well as by inputs from other settings, such as salt-crusted playas and contaminant sources.

Utah↗

A model for lignin alteration - Part I: A kinetic reaction-network model

A new quantitative model is presented which simulates the maturation of lignin-derived sedimentary organic matter under geologic conditions. In this model, compositionally specific reactants evolve to specific intermediate and mobile products through balanced, nth order processes, by way of a network of sequential and parallel reactions. The chemical kinetic approach is based primarily on published observed structural transformations of naturally matured, lignin-derived, sedimentary organic matter. Assuming that Upper Cretaceous Williams Fork coal in the Piceance Basin is primarily lignin-derived, the model is calibrated for the Multi-Well Experiment(MWX) Site in this basin. This kind of approach may be applied to other selectively preserved chemical components of sedimentary organic matter. ?? 2001 Elsevier Science Ltd. All rights reserved.

Organic Geochemistry↗