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Containing arsenic-enriched groundwater tracing lead isotopic compositions of common arsenical pesticides in a coastal Maine watershed

Arsenical pesticides and herbicides were extensively used on apple, blueberry, and potato crops in New England during the first half of the twentieth century. Lead arsenate was the most heavily used arsenical pesticide until it was officially banned. Lead arsenate, calcium arsenate, and sodium arsenate have similar Pb isotope compositions: 208 Pb 207 Pb = 2.3839-2.4722, and 206 Pb 207 Pb = 1.1035-1.2010. Other arsenical pesticides such as copper acetoarsenite (Paris green), methyl arsonic acid and methane arsonic acid, as well as arsanilic acid are widely variable in isotope composition. Although a complete understanding of the effects of historical use of arsenical pesticides is not available, initial studies indicate that arsenic and lead concentrations in stream sediments in New England are higher in agricultural areas that intensely used arsenical pesticides than in other areas. The Pb isotope compositions of pesticides partially overlap values of stream sediments from areas with the most extensive agricultural use. The lingering effects of arsenical pesticide use were tested in a detailed geochemical and isotopic study of soil profiles from a watershed containing arsenic-enriched ground water in coastal Maine. Acid-leach compositions of the soils represent lead adsorbed to mineral surfaces or held in soluble minerals (Fe- and Mn-hydroxides, carbonate, and some micaceous minerals), whereas residue compositions likely reflect bedrock compositions. The soil profiles contain labile Pb (acid-leach) showing a moderate range in 206 Pb 207 Pb (1.1870-1.2069), and 208 Pb 207 Pb (2.4519-2.4876). Isotope values vary as a function of depth: the lowest Pb isotope ratios (e.g., 208 Pb 206 Pb) representing labile lead are in the uppermost soil horizons. Lead contents decrease with depth in the soil profiles. Arsenic contents show no clear trend with depth. A multi-component mixing scheme that included lead from the local parent rock (Penobscot Formation), lead derived from combustion of fossil fuels, and possibly lead from other anthropogenic sources (e.g., pesticides), could account for Pb isotope variations in the soil profiles. In agricultural regions, our preliminary data show that the extensive use of arsenical pesticides and herbicides can be a significant anthropogenic source of arsenic and lead to stream sediments and soils.

Maine↗

Pesticides in ground water: distribution, trends, and governing factors

A comprehensive review of published information on the distribution and behavior of pesticides and their transformation products in ground water indicates that pesticides from every chemical class have been detected in ground waters of the United States. Many of these compounds are commonly present at low concentrations in ground water beneath agricultural land. Little information is available on their occurrence beneath non-agricultural land, although the intensity of their use in such areas (on lawns, golf courses, rights of way, timberlands, etc.) is often comparable to, or greater than agricultural use. Information on pesticides in ground water is not sufficient to provide either a statistically representative view of pesticide occurrence in ground water across the United States, or an indication of long-term trends or changes in the severity or extent of this contamination over the past three decades. This is largely due to wide variations in analytical detection limits, well selection procedures, and other design features among studies conducted in different areas or at different times. Past approaches have not been well suited for distinguishing "point source" from "nonpoint source" pesticide contamination. Among the variety of natural and anthropogenic factors examined, those that appear to be most strongly associated with the intensity of pesticide contamination of ground water are the depth, construction and age of the sampled wells, the amount of recharge (by precipitation or irrigation), and the depth of tillage. Approaches commonly employed for predicting pesticide distributions in the subsurface--including computer simulations, indicator solutes (e.g., nitrate or tritium), and ground-water vulnerability assessments--generally provide unreliable predictions of pesticide occurrence in ground water. Such difficulties may arise largely from a general failure to account for the preferential transport of pesticides in the subsurface. Significant improvements in understanding and predicting the occurrence and fate of pesticides in ground water are likely to depend on: (1) greater coordination of ground-water sampling across the nation to ensure consistency of study design, and thus comparability of results; (2) more extensive analyses for pesticide transformation products during ground-water monitoring studies; (3) substantially enhanced communication among investigators conducting laboratory experiments, small-scale field studies and large-scale monitoring studies; and (4) more routine testing of predictions of pesticide behavior and ground-water vulnerability against actual field observations of pesticide occurrence in ground water

Book↗

Statewide summary for Texas

The Texas coast (Figure 1) consists of complex and diverse ecosystems with a varying precipitation gradient. The northernmost portion of the coast, extending from Sabine Lake to Galveston Bay, is composed of salt, brackish, intermediate, and fresh marshes, with humid flatwoods inland (Moulton and others, 1997). Coastal prairies are found across the entire coast. From Galveston Bay to Corpus Christi Bay, rivers feed into large bays and estuarine ecosystems. Barrier islands and peninsulas exist along the coast from Galveston Bay to the Mexican border. The southernmost portion of the coast is composed of wind-tidal flats and the hypersaline Laguna Madre. The Laguna Madre lacks rivers and has little rainfall and restricted inlet access to the Gulf. Semiarid rangeland and irrigated agricultural land can be found inland. Approximately 6 million people live in Texas’ coastal counties (U.S. Census Bureau, 2010; Texas GLO, 2013). Seventy percent of the state’s industry and commerce occurs within 160.9 km (100 miles) of the coast (Moulton and others, 1997). Texas ports support 1.4 million jobs and generate $6.5 billion in tax revenues (Texas GLO, 2013). Chemical and petroleum production and marine commerce thrive on the Texas coast. Agriculture, grazing, commercial and recreational fishing, and recreation and tourism are strong industries along the coast and in adjacent areas; oil and gas production, agriculture, and tourism are the state’s three largest industries.

Texas↗

Results of a modeling workshop concerning preservation and protection of wetlands in North Dakota

In a recently signed letter, the Governor of North Dakota and the Assistant Secretary of the Interior for Fish and Wildlife and Parks charged a joint state-federal study group with examination of two separate questions: 1) mitigation for the Garrison Diversion Project; and 2) planning for long-range protection and preservation of fish and wildlife habitat in North Dakota. The cochair for this study group (the Secretary of the Interior's Field Representative, Denver, Colorado, and the Natural Resources Coordinator for North Dakota) further articulated the charge concerning the second of these two questions to include three steps: 1) development of a general plan for preservation and protection of migratory waterfowl and their associated wetland habitat; 2) a comprehensive analysis of alternative strategies, including opportunities and constraints, for achieving the goals articulated in Step 1; and 3) design of a coordinated state-federal public information program to assist in plan implementation. In order to obtain input from a variety of interests, the joint study group initiated step 2 activities with a five-day workshop in Bismarck, N. D.; December 8-12, 1980. The objectives of the workshop were: 1) to identify alternative strategies for preserving and enhancing waterfowl production habitat in North Dakota; 2) to identify opportunities and constraints associated with those alternatives; and 3) to promote communication and understanding of the implications of those alternatives for all affected parties. To achieve these objectives, the workshop utilized a group of concepts and techniques collectively known as Adaptive Environmental Assessment (AEA). Developed by Dr. C. S. Holling and his co-workers at the University of British Columbia, the AEA process involves planners, managers, scientists, and other interested parties in a structures atmosphere whose focus is the construction and examination of a computerized simulation model of the resource system under consideration. The modeling process is used to promote communication, identify pertinent issues, identify key data gaps and uncertainties, direct research efforts to fill those gaps, and explore the possible consequences of various management alternatives. The workshop, which was facilitated by the AEA Group of the U.S. Fish and Wildlife Service (FWS), was attended by approximately 25 invited participants representing a variety of interests concerned with the wetlands protection issue in North Dakota. During the week workshop participants conceptualized and constructed a computerized simulation model incorporating many of the hydrologic, agricultural, and wildlife aspects of the wetlands issue. During the process of constructing this model and examining its behavior, participants identified several interesting alternative strategies that may prove useful in an overall wetland protection program, along with a variety of constraints associated with each. Perhaps the most interesting of these alternatives revolve around the idea that there may be a variety of cases in which water can be retained on the land, with concommitant benefits both for wildlife and flood control, without detriment to agricultural productivity. Examples of this kind of activity include flooding of previously drained Type I wetlands in summer fallow areas, installation of smaller drains in Type I and III wetlands to reduce the rate at which water runs off in the spring, and use of strategically located gates in drainage channels associated with the state highway system to slow runoff and create wetland habitat. Several other alternatives discussed at the workshop are related to the notion of using available, uncommitted water supplied to enhance or create wetlands. Several cases were cited in which more certain water supplies would be useful in increasing waterfowl production or reducing disease problems, especially in dry years. Water for such purposes might come from a variety of current of proposed water development projects, both large and small scale. Finally, the potential for re-establishment of "unsuccessfully" drained (i.e., not consistently usable for agricultural purposes) wetlands was discussed at some length. There are apparently substantial acreages of such wetlands in North Dakota and a program to acquire and rehabilitate them might be of considerable utility. The workshop was thus successful in accomplishing its first two objectives--identification of alternative strategies, opportunities, and constraints. However, it would be naive to suppose that any of the alternatives discussed offers a complete, simple solution to the wetlands issue in North Dakota. The most important result of the workshop may therefore be that which was accomplished relative to the third objective--promotion of communication and understanding. It was gratifying and encouraging to see the spirit of communication and cooperation that developed by the end of the workshop. The fact that representatives of many of the interests concerned with the wetlands issue participated in an open exchange of ideas and information marks an important step forward. We believe that it is imperative that this cooperative attitude be maintained, and that there are a variety of ways in which this might be accomplished. Perhaps the simplest would be a small-scale pilot project and research effort to determine the effects of wetland maintenance on summer fallow areas. Such a research program would provide not only useful information, but an opportunity for many of the affected interests to begin working toward mutually acceptable solutions to the overall wetlands issue.

North Dakota↗

Global change and water resources in the next 100 years

We are in the midst of a continental-scale, multi-year experiment in the United States, in which we have not defined our testable hypotheses or set the duration and scope of the experiment, which poses major water-resources challenges for the 21st century. What are we doing? We are expanding population at three times the national growth rate in our most water-scarce region, the southwestern United States, where water stress is already great and modeling predicts decreased streamflow by the middle of this century. We are expanding irrigated agriculture from the west into the east, particularly to the southeastern states, where increased competition for ground and surface water has urban, agricultural, and environmental interests at odds, and increasingly, in court. We are expanding our consumption of pharmaceutical and personal care products to historic high levels and disposing them in surface and groundwater, through sewage treatment plants and individual septic systems. These substances are now detectable at very low concentrations and we have documented significant effects on aquatic species, particularly on fish reproduction function. We don’t yet know what effects on human health may emerge, nor do we know if we need to make large investments in water treatment systems, which were not designed to remove these substances. These are a few examples of our national-scale experiment. In addition to these water resources challenges, over which we have some control, climate change models indicate that precipitation and streamflow patterns will change in coming decades, with western mid-latitude North America generally drier. We have already documented trends in more rain and less snow in western mountains. This has large implications for water supply and storage, and groundwater recharge. We have documented earlier snowmelt peak spring runoff in northeastern and northwestern States, and western montane regions. Peak runoff is now about two weeks earlier than it was in the first half of the 20th century. Decreased summer runoff affects water supply for agriculture, domestic water supply, cooling needs for thermoelectric power generation, and ecosystem needs. In addition to the reduced volume of streamflow during warm summer months, less water results in elevated stream temperature, which also has significant effects on cooling of power generating facilities and on aquatic ecosystem needs. We are now required to include fish and other aquatic species in negotiation over how much water to leave in the river, rather than, as in the past, how much water we could remove from a river. Additionally, we must pay attention to the quality of that water, including its temperature. This is driven in the US by the Endangered Species Act and the Clean Water Act. Furthermore, we must now better understand and manage the whole hydrograph and the influence of hydrologic variability on aquatic ecosystems. Man has trimmed the tails off the probability distribution of flows. We need to understand how to put the tails back on but can’t do that without improved understanding of aquatic ecosystems. Sea level rise presents challenges for fresh water extraction from coastal aquifers as they are compromised by increased saline intrusion. A related problem faces users of ‘run-of-the-river’ water-supply intakes that are threatened by a salt front that migrates further upstream because of higher sea level. We face significant challenges with water infrastructure. The U.S. has among the highest quality drinking water in the world piped to our homes. However, our water and sewage treatment plants and water and sewer pipelines have not had adequate maintenance or investment for decades. The US Environmental Protection Agency estimates that there are up to 3.5M illnesses per year from recreational contact with sewage from sanitary sewage overflows. Infrastructure investment needs have been put at 5 trillion nationally. Global change and water resources c

Conference Paper↗

Use of Argon, Corona, and Landsat imagery to assess 30 years of land resource changes in west-central Senegal

Over the past 35 years, an agricultural area of west-central Senegal has experienced rapid population growth, fast expansion of agricultural lands, a decline in rainfall, and degradation of vegetative and soil resources. Although such changes have not escaped the attention of Senegal's people, its government, and the scientific community the ability to monitor and quantify land resource trends of recent decades has been difficult. Recently available high-resolution satellite photographs from the American Argon and Corona Programs provide coverage of Senegal back to 1963. The photographs make it possible to study and map land resources at the beginning of the Space Age. In this study, we characterize the changes that have occurred in the region from the early 1960s to the mid-1 990s. Early Argon and Corona photographs are used to reconstruct the historical land use and land cover; comparisons are made with assessments from recent Landsat images. Field studies and aerial surveys provide additional insight. The forces of change, driven primarily by population growth and unsustainable agricultural practices, are examined

Photogrammetric Engineering and Remote Sensing↗

Pesticides detected in surface waters and fish of the Red River of the North drainage basin

The Red River of the North drainage basin (herein referred to as Red River Basin) within the United States is a study unit under the U.S. Geological Survey (USGS) National Water-Quality Assessment (NAWQA) program. The overall goals of this program, initiated to better define the status and trends of the Nation’s water quality, are to address regional and national water-quality issues in a nationally consistent manner. Pesticide contamination of surface water and fish is one focus of this program. The Red River Basin is about 90,600 square kilometers (km2 ) in area and is composed of rolling prairie with a high density of prairie-pothole wetlands to the west; a very flat glacial lake bed with drainage ditches and meandering streams in the center (Red River Valley Lake Plain); morainal hills with a mosaic of agriculture, lakes, and forest in the southeast; and a flat lake-washed till plain with extensive peatlands in the northeast (fig. 1). Stoner and others (1993) have given a more complete description of the environmental setting of the Red River Basin. Agriculture is a major component of the region’s economy, and is greatest in the Red River Valley Lake Plain. Principal crops are wheat, barley, oats, sunflowers, corn, soybeans, dry beans, potatoes, sugarbeets, alfalfa hay, and other hay. Herbicide, insecticide, and fungicide use depends on crop type and environmental stresses such as crop disease, drought, and periodic insect-pest infestation. This paper focuses on the occurrence, movement, and fate of agricultural pesticides that are applied to crops, but improper disposal, and use of pesticides for household pests, lawn care, golf courses, and home gardening can also result in contamination of the aquatic environment. Furthermore, atmospheric transport is known to transport pesticides to regions far from their source (Kurtz, 1990). Pesticide data have been collected in the Red River Basin by various Federal, State, and local agencies. Tornes and Brigham (1994) recently summarized many of these historical data. This paper summarizes selected data collected as part of the NAWQA program during 1992-93, and briefly compares these data to historical data and to pesticide usage.

Minnesota, North Dakota, South Dakota↗

Nutrient pollution of coastal rivers, bays, and seas

Over the past 40 years, antipollution laws have greatly reduced discharges of toxic substances into our coastal waters. This effort, however, has focused largely on point-source pollution of industrial and municipal effluent. No comparable effort has been made to restrict the input of nitrogen (N) from municipal effluent, nor to control the flows of N and phosphorus (P) that enter waterways from dispersed or nonpoint sources such as agricultural and urban runoff or as airborne pollutants. As a result, inputs of nonpoint pollutants, particularly N, have increased dramatically. Nonpoint pollution from N and P now represents the largest pollution problem facing the vital coastal waters of the United States. Nutrient pollution is the common thread that links an array of problems along the nation’s coastline, including eutrophication, harmful algal blooms, ”dead zones,” fish kills, some shellfish poisonings, loss of seagrass and kelp beds, some coral reef destruction, and even some marine mammal and seabird deaths. More than 60 percent of our coastal rivers and bays in every coastal state of the continental United States are moderately to severely degraded by nutrient pollution. This degradation is particularly severe in the mid Atlantic states, in the southeast, and in the Gulf of Mexico. A recent report from the National Research Council entitled “Clean Coastal Waters: Understanding and Reduc- ing the Effects of Nutrient Pollution” concludes that: Nutrient over-enrichment of coastal ecosystems generally triggers ecological changes that decrease the biologi- cal diversity of bays and estuaries. While moderate N enrichment of some coastal waters may increase fish production, over-enrichment generally degrades the marine food web that supports commercially valuable fish. The marked increase in nutrient pollution of coastal waters has been accompanied by an increase in harmful algal blooms, and in at least some cases, pollution has triggered these blooms. High nutrient levels and the changes they cause in water quality and the makeup of the algal community are detrimental to the health of coral reefs and the diversity of animal life supported by seagrass and kelp communi- ties. Research during the past decade confirms that N is the chief culprit in eutrophication and other impacts of nutrient over-enrichment in temperate coastal waters, while P is most problematic in eutrophication of freshwa- ter lakes. Human conversion of atmospheric N into biologically useable forms, principally synthetic inorganic fertilizers, now matches the natural rate of biological N fixation from all the land surfaces of the earth. Both agriculture and the burning of fossil fuels contribute significantly to nonpoint flows of N to coastal waters, either as direct runoff or airborne pollutants. N from animal wastes that leaks directly to surface waters or is volatilized to the atmosphere as ammonia may be the largest single source of N that moves from agricultural operations into coastal waters. The National Research Council report recommended that, as a minimum goal, the nation should work to reverse nutrient should be taken to assure that the 40 percent of coastal areas now ranked as healthy do not develop symptoms of nutrient pollution in 10 percent of its degraded coastal systems by 2010 and 25 percent of them by 2020. Also, action should be taken to assure that the 40 percent of coastal areas now ranked as healthy do not develop symptoms of nutrient pollution. Meeting these goals will require an array of strategies and approaches tailored to specific regions and coastal ecosystems. There is an urgent need for development and testing of techniques that can reliably pinpoint the sources of N pollutants to an estuary. For some coastal systems, N removal during treatment of human sewage may be sufficient to reverse nutrient pollution. For most coastal systems, however, the solutions will be more complex and may involve controls on N compounds emitted during fossil fuel combustion as well as incentives to reduce over-fertilization of agricul- tural fields and nutrient pollution from animal wastes in livestock feedlot operations.

Alabama, California, Connecticut, Delaware, Florid↗

Surface waters of Kansas, 1895-1919

Kansas is preeminently an agricultural state. According to the United States census of 1910, the area in farms was 43,384,799 acres, or 67,789 square miles, 83 per cent of the total area of the state —82,158 square miles. The products of these farms rank high in value among those of farms in other states, as shown by comparative statistics compiled by the United States Department of Agriculture, Bureau of Crop Estimates. For the period from 1913 to 1917 Kansas ranked ninth of the states of the United States in the value of all crops raised, exclusive of livestock; in 1919 Kansas ranked fifth. In livestock Kansas ranked sixth in 1918 and eighth in 1919. Climatic conditions have largely dominated agricultural development in Kansas. Early ventures in dry farming in western Kansas, encouraged by a succession of rainy seasons, resulted in disheartening disasters, due to the dry seasons that followed. Throughout that region the farmers have gradually utilized the surface and underground waters for irrigation to provide against this deficiency of rainfall. The floods that have occurred in the valleys of eastern" Kansas at frequent intervals during the past twenty years have been the subject of much investigation by state and Federal organizations. In 1844 and 1903 exceptionally disastrous floods occurred in the Kansas (Kaw) valley. Floods that were of lesser magnitude, but that caused widespread loss and injury to property, have occurred in other years, the most recent being the flood of 1915. Much of the cultivated land in these valleys lies along fertile river bottoms that are annually liable to overflow, and the control of the flood waters on these rivers and their tributaries is therefore one of the problems arising from unfavorable climate that demand early solution. In view of the increasing demand for water for domestic service and fire protection, the need of determining whether the supply is adequate for rapidly growing centers of population throughout the state has recently been impressed very strongly upon a great many communities. The dependability of available sources of water supply during seasons of drought is fully as important as investigations of flood problems. Practical solutions of the many local and statewide water problems, such as flood protection, flood prevention, domestic water supply, drainage, irrigation, and water power, depend largely on a thorough knowledge of certain physical data relating to water resources. Hydrologic conditions differ widely in the different drainage basins, so that long-time investigations of stream-flow phenomena in each basin, as well as long-time investigations of meteorologic conditions over the state, are essential in the formulation of comprehensive plans to meet specific water problems. The collection of long-time records of stream-flow in Kansas which is published in this volume has been prepared for the use of those who are concerned with the different phases of the utilization of water in the state.

Kansas↗

Responses of benthic macroinvertebrates to urbanization in nine metropolitan areas of the conterminous United States

The effects of urbanization on benthic macroinvertebrates were investigated in nine metropolitan areas (Boston, MA; Raleigh, NC; Atlanta, GA; Birmingham, AL; Milwaukee–Green Bay, WI; Denver, CO; Dallas–Fort Worth, TX; Salt Lake City, UT; and Portland, OR) as a part of the U.S. Geological Survey National Water Quality Assessment Program. Several invertebrate metrics showed strong, linear responses to urbanization when forest or shrublands were developed. Responses were difficult to discern in areas where urbanization was occurring on agricultural lands because invertebrate assemblages were already severely degraded. There was no evidence that assemblages showed any initial resistance to urbanization. Ordination scores, EPT taxa richness, and the average tolerance of organisms were the best indicators of changes in assemblage condition at a site. Richness metrics were better indicators than abundance metrics, and qualitative samples were as good as quantitative samples. A common set of landscape variables (population density, housing density, developed landcover, impervious surface, and roads) were strongly correlated with urbanization and invertebrate responses in all non-agricultural areas. The instream environmental variables (hydrology, water chemistry, habitat, and temperature) that were strongly correlated with urbanization and invertebrate responses were influenced by environmental setting (e.g., dominant ecoregion) and varied widely among metropolitan areas. Multilevel hierarchical regression models were developed that predicted invertebrate responses using only two landcover variables—basinscale landcover (percentage of basin area in developed land) and regional-scale landcover (antecedent agricultural land).

Conference Paper↗

Primary factors affecting water quality and quantity in four watersheds in Eastern Puerto Rico

As part of the U.S. Geological Survey (USGS) Water, Energy, and Biogeochemical Budgets (WEBB) program, four small watersheds in eastern Puerto Rico were monitored to identify and evaluate the effects of geology, landcover, atmospheric deposition, and other factors on stream water quality and quantity. Two catchments are located on coarse-grained granitic plutonic rocks, which weather to quartz- and clay-rich, sandy soils, and two are located on fine-grained volcanic rocks and volcaniclastic sediments, which weather to quartz-poor, fine-grained soils. These differing soil materials result in different hydrologic regimes. Soils on the granitic rocks have greater permeability than those developed on the volcaniclastic rocks, allowing more water infiltration and potentially greater landslide erosion rates. For each bedrock type, one catchment was covered with mature rainforest, and the other catchment was affected by agricultural practices typical of eastern Puerto Rico. These practices led to the erosion of much of the original surface soil in the agricultural watersheds, which introduced large quantities of sediment to stream channels. The agricultural watersheds are undergoing natural reforestation, like much of Puerto Rico. Eastern Puerto Rico receives large atmospheric inputs of marine salts, pollutants from the Northern Hemisphere, and Saharan Desert dust. Marine salts contribute over 80 percent of the ionic charge in precipitation, with peak inputs in January. Intense storms, mostly hurricanes, are associated with exceptionally high chloride concentrations in stream waters. Temperate pollution contributes nitrate, ammonia, and sulfate, with maximum inputs during northern cold fronts in January, April, and May. Pollution inputs have increased through time. Desert dust peaks in June and July, during times of maximum dust transport from the Saharan Desert across the Atlantic Ocean.

Puerto Rico↗

Northern Great Plains Network water quality monitoring design for tributaries to the Missouri National Recreational River

The National Park Service (NPS) organized more than 270 parks with important natural resources into 32 ecoregional networks to conduct Inventory and Monitoring (I&M) activities for assessment of natural resources within park units. The Missouri National Recreational River (NRR) is among the 13 parks in the NPS Northern Great Plain Network (NGPN). Park managers and NGPN staff identified surface water resources as a high priority vital sign to monitor in park units. The objectives for the Missouri NRR water quality sampling design are to (1) assess the current status and long-term trends of select water quality parameters; and (2) document trends in streamflow at high-priority stream systems. Due to the large size of the Missouri River main stem, the NGPN water quality design for the Missouri NRR focuses on wadeable tributaries within the park unit. To correlate with the NGPN water quality protocols, monitoring of the Missouri NRR consists of measurement of field core parameters including dissolved oxygen, pH, specific conductance, and temperature; and streamflow. The purpose of this document is to discuss factors examined for selection of water quality monitoring on segments of the Missouri River tributaries within the Missouri NRR. Awareness of the complex history of the Missouri NRR aids in the current understanding and direction for designing a monitoring plan. Historical and current monitoring data from agencies and entities were examined to assess potential NGPN monitoring sites. In addition, the U.S. Environmental Protection Agency 303(d) list was examined for the impaired segments on tributaries to the Missouri River main stem. Because major tributaries integrate water quality effects from complex combinations of land use and environmental settings within contributing areas, a 20-mile buffer of the Missouri NRR was used to establish environmental settings that may impact the water quality of tributaries that feed the Missouri River main stem. For selection of monitoring sites, anthropogenic and natural influences to water quality were assessed for Missouri NRR tributaries. Factors that were examined include the size and contributions of tributaries within watersheds to the main stem; population density; and land use such as urban development and agricultural practices including concentrated animal feeding operations. Based on examination of these data in addition to the park’s legislation and management considerations, two sites were selected for monitoring water quality on Missouri NRR tributaries for the ice-free season (mid-May to mid-October) on a rotational basis every third year. Bow Creek at St. James was selected for water quality monitoring based on lack of long-term water quality monitoring, current recreational use, and proximity of the tributary to intense agricultural practices. In addition, land within the Bow Creek watershed is owned by the NPS. The Niobrara River at Verdel was selected for monitoring due to high use for public recreational activities, adjacent agricultural land use, and documented impairments for designated beneficial uses. Both sites will have access to real-time streamgages that will aid in a greater understanding of water quality.

Natural Resource Technical Report↗

Bird use of reforestation sites: Influence of location and vertical structure

In the Lower Mississippi Valley, more than 300,000 acres of agricultural land have been reforested in the last 10 years. Planning decisions on how and where to restore forest are complex and usually reflect landowner objectives. However, initial planning decisions may have a large influence on the value of restored stands for birds and other wildlife. Reforestation of small, isolated tracts will likely result in mature forests where reproductive output of breeding birds does not compensate for adult mortality (sink habitats). This may be due to factors such as lower reproductive success near edges (edge effects), insufficient area of habitat to attract colonizing birds (area effects), or restricted population mixing and mating opportunities because of limited dispersal among tracts (isolation effects). Conversely, reforestation adjacent to existing forest increases contiguous forest area and provides areas buffered from agricultural or urban habitats (interior forest core). Bottomland reforestation has historically focused on planting relatively slow-growing tree species, particularly oaks (Quercus spp.). Thus, restoration sites are often dominated by grasses and forbs for up to a decade after tree planting. Grassland birds are the first birds to colonize reforested sites. However, abundance and productivity of grassland birds is generally poor on sites associated with woody vegetation, such as sites adjacent to mature forest. As woody vegetation develops on reforested sites, birds preferring shrub-scrub habitat displace grassland species (Twedt et al. 2002) (fig. 1). Planting faster-growing trees compresses the time for colonization by shrub-scrub birds and the increased vertical stature of these trees attracts forest birds (Twedt and Portwood 1996). Additionally, planting next to existing mature forests creates transitional edges that reduce the detrimental effects of abrupt forest-agriculture interfaces.

Technical Note↗

Vegetation changes over 12 years in ungrazed and grazed Conservation Reserve Program Grasslands in the central and southern plains

The Conservation Reserve Program (CRP) established under the 1985 Food Security Act has the fundamental objectives of jointly providing economic support to segments of the agricultural community and conservation of natural resources (Osborn, 1997; Heard and others, 2000). Although soil loss on highly erodable lands was the principal natural resource conservation issue addressed in the 1985 CRP, improving water quality and wildlife habitat both became important considerations as the program evolved (Farmer and others, 1988). For example, Best and others (1997) found that production of young birds on CRP fields in the Midwest was ≥15 times the production on row-crop fields because of improved habitat. The increasing importance of wildlife habitat is reflected in continuing refinement of the Environmental Benefits Index (EBI) used by the U.S. Department of Agriculture (USDA) to quantify the potential benefits of enrolling lands in CRP (Osborn, 1997; Ribaudo and others, 2001). The refinements reflect input furnished by federal, state, and non-government organizations seeking greater wildlife habitat quality on CRP lands (Roseberry and David, 1994; Hughes and others, 1995; Millenbah and others, 1996; Patterson and Best, 1996; Rodgers, 1999; Allen and others, 2001). Refinement in the EBI has changed the types of grasses planted on newly enrolled land. In early CRP signups (1 through 11), 71% of new grassland acres were planted to introduced grasses and legumes [Conservation Practice (CP) 1] while 29% of the acres were planted to native grasses (CP2) (Osborn and others, 1992). By the 27th signup in July 2004, over 34.8 million acres (14 million ha) were enrolled in the CRP. More than 73% of these lands were planted to various mixtures of introduced (CP1) or native (CP2) grasses for a minimal contract period of 10 years (USDA, 2004). Continuation of grass plantings under the 2002 Farm Bill may result in CRP lands furnishing grass dominated cover for 20 or more consecutive years. The species of grass established in seeded grasslands can have a major influence on the potential quality of wildlife habitat where vegetation is maintained over a multi-year period. Different species of grass may have comparable abilities to alleviate soil erosion but furnish dissimilar qualities of wildlife habitat (fig. 1). For example, smooth brome, an introduced cool-season grass (grass species and scientific names are presented in table 1), is highly valued for its erosion control and forage attributes (Casler and Carlson, 1995). Switchgrass, a native warm-season grass, also is valued for its soil and water conservation qualities (Moser and Vogel, 1995) but provides greater benefits for some species of wildlife (Clubine, 1995). The quality of nesting and winter cover for ring-necked pheasants (Phasianus colchicus) furnished by smooth brome on northeastern Colorado CRP lands is inferior to that provided by the taller, more robust switchgrass (Allen, 1994). Characteristics of the agricultural landscape surrounding individual CRP fields also play a role in the wildlife habitat potential of CRP plantings (Weber and others, 2002; Nusser and others, 2004). of native and seeded grasslands change in response to the presence (and absence) of physical disturbances such as fire, grazing, tillage, and haying (Hobbs and Huenneke, 1992; Millenbah and others, 1996; Allen and others, 2001; Renfrew and Ribic, 2001; Swengel and Swengel, 2001). The perpetuation of diversity in species composition and vegetation structure following disturbance sustains desirable habitat for a variety of grassland-dependent wildlife (Hall and Willig, 1994; Barnes and others, 1995; King and Savidge, 1995; Granfors and others, 1996; Herkert and others, 1996; Kurzejeski, 1996; Patterson and Best, 1996; Klute and others, 1997). Undisturbed grasslands have lower grass and forb species diversity, greater amounts of dead plant material, decreased as well as seasonally delayed productivity, and diminished structural diversity of vegetation (Peet and others, 1975; Rice and Parenti, 1978; Butler and Briske, 1988; Campa and Winterstein, 1992). Recommendations for the timing of disturbance to increase grass and forb species diversity range from 3 to 8 years following establishment of seeded grasslands in the northern Great Plains and Midwest (Duebbert and others, 1981; Higgens, 1987; Millenbah and others, 1996). The management interval, however, is affected by climatic conditions, soils, grass species, and management history of the individual stand. We quantified changes in vegetation structure and species composition across the typical 10-year contract period in undisturbed southern and central Great Plains CRP fields (fig. 2) planted to introduced and native grasses. In addition, we compared changes in vegetation in fields grazed during the emergency release of 1996 by comparing conditions prior to grazing and two and four years post grazing relative to changes in similar fields that were not grazed. Documentation of long-term changes in vegetation structure and composition for fields planted to common grass seed mixtures across a wide range of environmental conditions provides information to improve long-term wildlife habitat potential, guide program administration, and define management practices that yield economic benefits to operators while still meeting wildlife and conservation objectives. Emergency grazing provisions of the CRP are controversial. Although grazing can alter vegetative characteristics and reduce habitat quality in the short-term (Temple and others, 1999), periodic disturbance may be necessary to maintain habitat quality, and more information is needed assessing long-term effects of emergency grazing on vegetative structure and species composition.

Conference Paper↗

Potential concerns with analytical Methods Used for the detection of Batrachochytrium salamandrivorans from archived DNA of amphibian swab samples, Oregon, USA

Taxonomic identification of pollen has historically been accomplished via light microscopy but requires specialized knowledge and reference collections, particularly when identification to lower taxonomic levels is necessary. Recently, next-generation sequencing technology has been used as a cost-effective alternative for identifying bee-collected pollen; however, this novel approach has not been tested on a spatially or temporally robust number of pollen samples. Here, we compare pollen identification results derived from light microscopy and DNA sequencing techniques with samples collected from honey bee colonies embedded within a gradient of intensive agricultural landscapes in the Northern Great Plains throughout the 2010–2011 growing seasons. We demonstrate that at all taxonomic levels, DNA sequencing was able to discern a greater number of taxa, and was particularly useful for the identification of infrequently detected species. Importantly, substantial phenological overlap did occur for commonly detected taxa using either technique, suggesting that DNA sequencing is an appropriate, and enhancing, substitutive technique for accurately capturing the breadth of bee-collected species of pollen present across agricultural landscapes. We also show that honey bees located in high and low intensity agricultural settings forage on dissimilar plants, though with overlap of the most abundantly collected pollen taxa. We highlight practical applications of utilizing sequencing technology, including addressing ecological issues surrounding land use, climate change, importance of taxa relative to abundance, and evaluating the impact of conservation program habitat enhancement efforts.

Oregon↗

Fate and effects of nitrogen and phosphorus in shallow vegetated aquatic ecosystems

Nitrate concentrations have greatly increased in streams and rivers draining agricultural regions of the Midwestern United States, increasing nitrate transport to the Gulf of Mexico has been implicated in the hypoxic conditions that threaten the productivity of marine fisheries. Increases in nitrate concentrations have been attributed to a combination of factors including agricultural expansion, increased nitrogen application rates, increased tile drainage, and loss of riparian Wetlands, These landscape-level changes have resulted in a decreased natural capacity for nitrogen uptake, removal, and cycling back to the atmosphere. Land managers are increasingly interested in using wetland construction and rehabilitation as a management practice to reduce loss of nitrate from the terrestrial systems. Yet, relatively little is known about the limnological factors involved in nitrate removal by Wetland systems. We conducted a series of studies from 1999-2000 to investigate the functional capacity of shallow, macrophyte-dominated pond wetland systems for uptake, assimilation, and retention of nitrogen (N) and phosphorus (P). We evaluated four factors that were hypothesized to influence nutrient uptake and assimilation: 1) nitrate loading rates; 2) nitrogen to phosphorus (N.P) ratios; 3) frequency of dosing/application; and 4) timing of dose initiation. Nutrient assimilation was rapid; store than 90% of added nutrients were removed from the water column in all treatments. Neither variation in N:P ratios (evaluated range, <13:1 to -114.1), frequency of application (weekly or bi-weekly), nor liming of dose initiation relative to macrophyte development (0%, 15-25%, or 75-90% maximum biomass) had significant effects on nutrient assimilation of wetland community dynamics. Maximum loading of nitrate (60 g N/m 2 2.4 g P/m 2 ) applied as six weekly doses stimulated algal communities, but inhibited macrophyte communities. Predicted shifts from a stable state of macrophyte- to phytoplankton-dominance did not occur due to nutrient additions. Macrophytes, phytoplankton, and the sediment surface were all significant factors in the removal of nitrate from the Water column. Overall, these shallow macrophyte-dominated systems provided an efficient means of removing nutrients from the water column. Construction or rehabilitation of shallow, vegetated wetlands may offer promise as land management practices for nutrient removal in agricultural watersheds.

Report↗

Conceptual model for invasive bivalve control on wetland productivity

Tidal wetlands were the historically dominant features of many coastal regions around the world, including the San Francisco Estuary (Callaway et al. 2011; Whipple et al. 2012). These mosaics of varied interconnected habitats (Mitsch and Gosselink 1993) provide a host of ecosystem services, including biodiversity maintenance, fish and wildlife habitat, water quality improvement, flood abatement, and carbon sequestration (Rabenhorst 1995; Costanza et al. 1997; Bottom et al. 2005; Zedler and Kercher 2005; Barbier et al. 2010). They also support human activities and values such as recreation and aesthetic appreciation (Barbier et al. 2010; Milligan and Kraus-Polk 2016). Despite their critical functions, many wetland landscapes have been destroyed or irreparably altered, either incidentally or intentionally, by human activities (Holland et al. 2004; Zedler and Kercher 2005; Callaway et al. 2011; Cloern and Jassby 2012; Whipple et al. 2012; Schile et al. 2014). San Francisco Estuary (SFE) (see Figure 1) tidal wetlands were largely converted to other land uses in the late 1800s and early 1900s, with the extent of loss and new use varying by region. Wetland losses in the North, Central, and South San Francisco bays and Suisun Bay ranged from 70 percent to 93 percent to accommodate agricultural uses, salt production, managed waterfowl habitat, and urban development (Callaway et al. 2011). Landscape transformation within the most inland portion of the SFE, the Sacramento-San Joaquin Delta (Delta), was even more dramatic. Overall, today’s Delta contains 97 percent less freshwater tidal wetland than its historical state and nearly double the open water area (Whipple et al. 2012). The majority of the modern Delta consists of agricultural tracts protected from tidal waters by human-made dikes or levees, which are commonly armored with riprap. The de-watered, rich peat soils of these created islands have supported abundant agricultural production, but have oxidized, compacted, and blown away in the process, causing significant subsidence (Deverel and Leighton 2010). Occasional levee failures turn islands into lakes; a few large shallow lakes remain after accidental levee breaches were not repaired (Whipple et al. 2012).

California↗

Assessment of 2006 and 2007 drought patterns in the vegetation drought response index across Nebraska

The Vegetation Drought Response Index (VegDRI) is a hybrid geospatial drought indicator and monitoring tool that provides timely drought severity information with relatively higher spatial resolution (1-km2) than the traditional drought monitoring maps. The VegDRI model integrates climate-based drought index data, satellite-based vegetation index information, and several biophysical parameters. During the 2008 growing season, VegDRI was produced in near-real time for 22 states in the central and western United States. Coverage will expand across the conterminous United States in 2009. Validating the results of large-area, operational monitoring tools such as VegDRI requires extensive ground truth information across space and time and to date, only a limited number of assessments of this index have been conducted. This study initiates a comprehensive assessment of historical VegDRI for two summer row crops identified using crop and irrigation masks in an effort to better characterize the accuracy and performance of this index for agricultural drought monitoring. The assessment evaluated drought severity information provided by VegDRI for Nebraska in 2006 and 2007, which represented drought and non-drought conditions over much of the state in those years, respectively. Spatial and statistical comparisons of VegDRI and U.S. Department of Agriculture (USDA) National Agricultural Statistics Service (NASS) crop yield data were conducted for both years. For this initial study, comparisons were restricted to Nebraska’s two predominant crops, corn and soybeans. Irrigated and non-irrigated row crops were analyzed separately. Preliminary results showed that non-irrigated corn yields had a stronger relationship to late-season VegDRI than non-irrigated soybeans. Moderate drought impacts in 2006 were also highlighted by this analysis.

Conference Paper↗