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Occurrence and attempted mitigation of carbon dioxide in a home constructed on reclaimed coal-mine spoil, Pike County, Indiana

In recent years carbon dioxide intrusion has become recognized as a potentially serious health threat where homes are constructed on or near reclaimed surface coal mines. When carbon dioxide invades the living space of a home, it can collect near the floor, displace the oxygen there, and produce an oxygen-deficient environment. In this investigation, several lines of inquiry were pursued to determine the environmental factors that most influence carbon dioxide intrusion at a Pike County, Ind., home where this phenomenon is known to occur. It was found that carbon dioxide intrusion events at the home are most closely tied to rapid drops in barometric pressure and rainfall. Other researchers have shown that windy conditions and periods of cold weather also can contribute to soil-gas intrusion to structures. From this, a conceptual model was developed to illustrate the influence of these four meteorological conditions. Additionally, three mitigation methods-block-wall depressurization, block-wall and sub-slab depressurization, and block-wall and sub-slab pressurization-were applied successively to the study-site home, and environmental data were collected to evaluate the effectiveness of each mitigation method. In each case, it was found that these methods did not ensure a safe environment when meteorological conditions were favorable for carbon dioxide intrusion.

Scientific Investigations Report↗

Monitoring to assess progress toward meeting the Assabet River, Massachusetts, phosphorus total maximum daily load - Aquatic macrophyte biomass and sediment-phosphorus flux

In 2004, the Total Maximum Daily Load (TMDL) for Total Phosphorus in the Assabet River, Massachusetts, was approved by the U.S. Environmental Protection Agency. The goal of the TMDL was to decrease the concentrations of the nutrient phosphorus to mitigate some of the instream ecological effects of eutrophication on the river; these effects were, for the most part, direct consequences of the excessive growth of aquatic macrophytes. The primary instrument effecting lower concentrations of phosphorus was to be strict control of phosphorus releases from four major wastewatertreatment plants in Westborough, Marlborough, Hudson, and Maynard, Massachusetts. The improvements to be achieved from implementing this control were lower concentrations of total and dissolved phosphorus in the river, a 50-percent reduction in aquatic-plant biomass, a 30-percent reduction in episodes of dissolved oxygen supersaturation, no low-flow dissolved oxygen concentrations less than 5.0 milligrams per liter, and a 90-percent reduction in sediment releases of phosphorus to the overlying water. In 2007, the U.S. Geological Survey, in cooperation with the Massachusetts Department of Environmental Protection, initiated studies to evaluate conditions in the Assabet River prior to the upgrading of wastewater-treatment plants to remove more phosphorus from their effluents. The studies, completed in 2008, implemented a visual monitoring plan to evaluate the extent and biomass of the floating macrophyte Lemna minor (commonly known as lesser duckweed) in five impoundments and evaluated the potential for phosphorus flux from sediments in impounded and free-flowing reaches of the river. Hydrologically, the two study years 2007 and 2008 were quite different. In 2007, summer streamflows, although low, were higher than average, and in 2008, the flows were generally higher than in 2007. Visually, the effects of these streamflow differences on the distribution of Lemna were obvious. In 2007, large amounts of floating macrophytes accumulated behind bridge constrictions and dams; in 2008, high flows during the early part of the growing season carried floating macrophytes past bridges and over dams, minimizing accumulations. Samples of Lemna were collected and weighed to provide an estimate of Lemna biomass based on areal coverage during the summer growing seasons at eight sites in the five impoundments. Average estimated biomass during 2007 was approximately twice the 2008 biomass in each of the areas monitored. In 2007, in situ hyperspectral and high-resolution, multispectral data from the IKONOS satellite were obtained to evaluate the feasibility of using remote sensing to monitor the extent of aquatic plant growth in Assabet River impoundments. Three vegetation indices based on light reflectance were used to develop metrics with which the hyperspectral and satellite data were compared. The results of the comparisons confirmed that the high-resolution satellite imagery could differentiate among the common aquatic-plant associations found in the impoundments. The use of satellite imagery could counterbalance emphasis on the subjective judgment of a human observer, and airborne hyperspectral data can provide higher resolution imagery than multispectral satellite data. In 2007 and 2008, the potential for sediment flux of phosphorus was examined in free-flowing reaches of the river and in the two largest impoundments-Hudson and Ben Smith. These studies were undertaken to determine in situ flux rates prior to the implementation of the Assabet River Total Maximum Daily Load (TMDL) for phosphorus and to compare these rates with those used in the development and evaluation of the TMDL. Water samples collected from a chamber placed on the river bottom were analyzed for total phosphorus and orthophosphorus. Ambient dissolved oxygen concentrations and seasonal temperature differences appeared to affect the rates of sequestration and sediment release of phosphorus. When dissolved oxygen concentrations remained relatively high in the chambers and when the temperature was relatively low, the tendency was for phosphorus concentrations to decrease in the chambers, indicating sediment sequestration of phosphorus; when dissolved oxygen concentrations dropped to near zero and temperatures were warmest, phosphorus concentrations increased in the chambers, indicating phosphorus flux from the sediment. The rates of release and sequestration in the in situ studies were generally comparable with the rates determined in laboratory studies of Assabet River sediment cores for State and Federal agencies. Sediment-core and chamber studies produced substantial sediment fluxes to the water column only under extremely low-DO or anaerobic conditions rarely found in the Assabet River impoundments; thus, sediment is not likely to be a major phosphorus source, especially when compared to the wastewater effluent, which sustains higher ambient concentrations. The regulatory agencies now (2011) have substantial laboratory and field data with which to determine the required 90-percent reduction in phosphorus flux after the completion of upgrades to the wastewater-treatment plants that discharge to the Assabet River.

Massachusetts↗

Geophysical and hydrologic analysis of an earthen dam site in southern Westchester County, New York

Ninety percent of the drinking water for New York City passes through the Hillview Reservoir facility in the City of Yonkers, Westchester County, New York. In the past, several seeps located downslope from the reservoir have flowed out from the side of the steepest slope at the southern end of the earthen embankment. One seep that has been flowing continuously was discovered during an inspection of the embankment in 1999. Efforts were made in 2001 to locate the potential sources of the continuous flowing seep. In 2005, the U.S. Geological Survey, in cooperation with the New York City Department of Environmental Protection, began a cooperative study to investigate the relevant hydrogeologic framework to characterize the local groundwater-flow system and to determine possible sources of the seeps. The two agencies used hydrologic and surface geophysical techniques to assess the earthen embankment of the Hillview Reservoir. Between April 1, 2005 and March 1, 2008, water levels were measured manually each month at 46 wells surrounding the reservoir, and flow was measured monthly at three of the five seeps on the embankment. Water levels were measured hourly in the East Basin of the reservoir, at 24 of 46 wells, and discharge was measured hourly at two of the five seeps. Slug tests were performed at 16 wells to determine the hydraulic conductivity of the geologic material surrounding the screened zone. Estimated hydraulic conductivities for 25 wells on the southern embankment ranged from 0.0063 to 1.2 feet per day and averaged 0.17 foot per day. The two-dimensional resistivity surveys indicate a subsurface mound of electrically conductive material (low-resistivity zone) beneath the terrace area (top of dam) surrounding the reservoir with a distinct elevation increase closer to the crest. Two-dimensional shear wave velocity surveys indicate a similar structure of the high shear wave velocity materials (high-velocity zone), increasing in elevation toward the crest and decreasing toward the reservoir and toward the northern part of the study area. Water-quality samples collected from 12 wells, downtake chamber 1 of the reservoir, and two seeps detected the presence of arsenic, toluene, and two trihalomethanes. Water-quality samples collected at the two seeps detected fluoride, indicating a connection with reservoir water. Shallow wells on the southern embankment exhibited the largest seasonal water-level fluctuations ranging between 6 feet and 12 feet. The embankment is constructed from reworked low-permeability glacial deposits at the site. Water-level responses in observation wells within the embankment indicate that there is a shallow (approximately the upper 45 feet of the embankment) and a deep water-bearing unit within the embankment with a large downward vertical gradient between the shallow and deep water-bearing units. Precipitation strongly affected water levels in shallow wells, whereas the basin appears to be the main control on water levels in the deep wells. Seeps on the embankment slope appear to be caused by above-average precipitation that increases water levels in the shallow water-bearing unit, but does not easily recharge the deep water-bearing unit. Based on the data that have been analyzed, source water to the seeps appears to be primarily groundwater and, to a lesser extent, water from the East Basin of the reservoir.

New York↗

Flood-inundation maps for the Schoharie Creek at Prattsville, New York, 2014

Digital flood-inundation maps for a 2.6-mile reach of the Schoharie Creek at Prattsville, New York, were created by the U.S. Geological Survey (USGS) in cooperation with the New York State Department of Environmental Conservation. The flood-inundation maps, which can be accessed through the USGS Flood Inundation Mapping Science Web site at http://water.usgs.gov/osw/flood_inundation/ , depict estimates of the areal extent and depth of flooding corresponding to selected water levels (stages) at the USGS streamgage at Schoharie Creek at Prattsville (station number 01350000). Near-real-time stages at this streamgage may be obtained online from the USGS National Water Information System ( http://waterdata.usgs.gov/ ) or the National Weather Service Advanced Hydrologic Prediction Service ( http://water.weather.gov/ahps/ ), which also forecasts flood hydrographs at this site. National Weather Service-forecasted peak-stage information may be used in conjunction with the maps developed in this study to show predicted areas and depths of flood inundation. Flood profiles were computed for the stream reach by means of a one-dimensional step-backwater model. The model was calibrated by using the stage-discharge relation (rating 82.0) at the Schoharie Creek at Prattsville streamgage (station 01350000) and high-water marks from the flood of August 28, 2011. The hydraulic model was then used to compute 17 water-surface profiles for flood stages at 1-foot intervals referenced to the streamgage datum and ranging from bankfull to greater than the highest recorded water level at the streamgage. The simulated water-surface profiles were then combined with a geographic information system digital elevation model, derived from light detection and ranging (lidar) data having a 0.61-foot vertical root-mean squared error and 6.6-foot horizontal resolution, in order to delineate the area flooded at each water level. These flood-inundation maps, along with near-real-time stage data from USGS streamgages and forecasted stage data from the National Weather Service, can provide emergency management personnel and residents with information that is critical for flood response activities such as evacuations and road closures as well as for postflood recovery efforts.

New York↗

Characterization of Big Chino subbasin hydrogeology near Paulden, Arizona, using controlled source audio-frequency magnetotelluric surveys

The Big Chino subbasin is located in central-northwest Arizona in the transition zone between the Colorado Plateau and the Basin and Range Province. The controlled source audio-frequency magnetotelluric (CSAMT) geophysical method, a low-impact, non-intrusive, electrical resistance sounding technique, was used to evaluate the subsurface hydrogeology of the southern third of the Big Chino subbasin. The Big Chino subbasin is a northwest-trending, late Tertiary graben bordered by the Big Chino Fault along its northeast flank where there is as much as 1,100 meters of displacement. The main water-bearing stratigraphic unit of the basin is Tertiary alluvial-fill sediment. The Devonian Martin Formation provides water to wells near Drake and the Mississippian Redwall Limestone provides water to wells east of the basin and in the Paulden area. The purpose of the CSAMT surveys was to improve the conceptual model of the aquifer by constraining the basin geometry and identifying stratigraphic units and their subsurface extents. CSAMT methods were used to map the subsurface along 100 kilometers (62 miles) of survey lines across the southern third of the subbasin. Of 21 survey lines, 14 were west of the town of Paulden and another 7 were east of Paulden. Data were cleaned and prepared for entry into Zonge SCS2D software and then inverted to provide a two-dimensional resistivity profile for each survey line. Final inversion models representing the best fit to measured data were compared to driller’s logs or borehole data where present. Data from the CSAMT lines west and north of Paulden are consistent with thicker alluvial basin deposits that range from 100 meters thick to a few hundred meters thick. Data from the CSAMT lines east of Paulden are consistent with thinner alluvial and basalt deposits overlying Paleozoic Martin Formation and Redwall Limestone, Tapeats Sandstone, and Precambrian granite and schist.

Arizona↗

Benthic vertical hydraulic gradients in Upper Klamath Lake, Oregon, 2017

Groundwater piezometers and lake stilling wells were deployed as paired sets at 10 locations in Upper Klamath Lake in south-central Oregon from May to October 2017 to measure hydraulic heads in and beneath the lake. Continuous water-level data from piezometers and stilling wells were then used to calculate the vertical hydraulic gradient (VHG) across the sediment-water interface to determine the direction and relative magnitude of the movement of water between the lake and underlying sediments. Over the study period, heads in lake-bed sediments closely tracked lake levels, both decreasing from spring into autumn. Instantaneous VHG was highly dynamic at all sites and exhibited high-frequency (less than 1 day to less than 1 hour) variations in magnitude and direction. Instantaneous and weekly mean VHG values often exceeded, but were commonly within, the range of measurement uncertainty (VHG less than +0.009 foot per foot [ft/ft] and greater than -0.009 ft/ft). 63 percent of instantaneous VHG values and 66 percent of weekly mean VHG values were within this range. Study period mean VHG was within measurement uncertainty at seven of the nine sites that had continuous water-level data, but two littoral sites (LC03 and LS01) had positive (upward) values greater than measurement uncertainty and are likely locations of vertical groundwater seepage. Data collected in this study provide new information about the hydraulic conditions at the sediment-water interface in UKL and demonstrate that sediment-groundwater exchange in UKL is spatially and temporally heterogeneous.

Oregon↗

Groundwater age and susceptibility of south Atlantic and Gulf Coast principal aquifers of the contiguous United States

Groundwater susceptibility to contamination was investigated by using environmental tracer-based groundwater age metrics in the south Atlantic and Gulf Coast principal aquifer systems of the Southeastern Coastal Plain, Mississippi embayment–Texas coastal uplands, and the Coastal Lowlands. Samples of dissolved gas, tritium, sulfur hexafluoride, tritiogenic helium, and carbon-14 were collected from 231 public supply wells in the 3 principal aquifer systems. Dissolved gas models were used to characterize recharge conditions and they identified recharge mechanisms that ranged from rapid, but short-lived, water table rises (possibly associated with large scale flooding), to slower diffuse recharge not associated with large water table fluctuations. Dissolved gas and geochemical correction models were used to calculate and (or) correct tracer concentrations before input to lumped parameter models of groundwater age. Lumped parameter models that were fit to tracer concentrations indicated groundwater was relatively old across the aquifer systems, with an estimated mean age of about 30,000 years. Estimates of groundwater age were related to hydrogeology, with increasing groundwater ages associated with greater depth, confinement, and distance from the recharge zone. Young groundwater with mean ages less than 2,000 years generally was in unconfined parts of the aquifer system, except for local areas of heavy groundwater extraction from unconfined aquifer units where estimated mean ages were up to 15,000 years. Lumped parameter model optimized age distributions describe the relative contribution of differing flow paths to the mean age, and a composite distribution of all samples from the three aquifer systems indicated that about 15 percent of the total sampled water had an age of less than 100 years. Various metrics of susceptibility, to land surface and geogenic contamination sources, derived from the age distributions, indicated geogenic sources as the primary threat to groundwater quality in the aquifer systems. Values of the susceptibility index (unitless) and fraction of recharge since 2,000 and 15,000 years before present are provided for assessment of individual well susceptibility. The data and interpretation methods presented here provide an additional means of investigating the susceptibility and sustainability of groundwater resources of the Southeastern Coastal Plain, Mississippi embayment–Texas coastal uplands, and the Coastal Lowlands aquifer systems.

Scientific Investigations Report↗

Hydrology, water-quality, and watershed characteristics in 15 watersheds in Gwinnett County, Georgia, water years 2002–20

The U.S. Geological Survey, in cooperation with Gwinnett County Department of Water Resources, established the Long-Term Trend Monitoring program in 1996 to monitor and analyze the hydrologic and water-quality conditions in Gwinnett County, Georgia. Gwinnett County is a suburban to urban area northeast of the city of Atlanta in north-central Georgia. The monitoring program currently consists of 15 watersheds ranging in size from 1.3 to about 161 square miles. This report synthesizes watershed characteristics and hydrologic and water-quality monitoring data collected for water years (WYs) 2002–20. The 15 study watersheds were characterized for land-surface elevations, average land-surface slopes, septic densities, sanitary sewer densities, and detention pond areas. Temporal patterns in watershed characteristics were determined for land cover (2001–19), percent imperviousness (2000–20), population density (2000–20), and building density (1950–2022). In 2001, most of the watersheds had at least 45 percent of their land cover composed of developed land cover groups, and by 2019, at least 59 percent of each watershed was developed. Land cover changes occurred most rapidly between 2004 and 2008 at most watersheds. Percent imperviousness in the study watersheds varied substantially and ranged from 14.75 to 55.13 percent in 2019. Precipitation and runoff were quantified at all study watersheds for WYs 2002–20, and the hydrologic cycle was evaluated both annually and seasonally. Several 1-year or longer droughts occurred during this period. Study area precipitation averaged 51.5 inches per year and runoff averaged 22.5 inches per year. Variations in annual runoff were largely determined by annual precipitation but were also dependent upon watershed storage. Runoff varied seasonally because of high evapotranspiration rates in the summer and changes in base flow associated with seasonal changes in watershed storage. Fifty-one percent of runoff in the study area occurred as base flow. Watersheds with higher imperviousness had higher stormflows because of increased surface runoff and lower base flows because of reduced infiltration that recharges watershed storage. Turbidity, water temperature, and specific conductance were continuously measured at each study site. These constituents varied seasonally, diurnally, and with streamflow. A minimum of two base-flow and six stormflow samples were collected per year at each watershed and were analyzed for 21 water-quality constituents (water temperature, laboratory specific conductance, pH, and turbidity, biochemical and chemical oxygen demand, suspended sediments, nutrients, base cations, trace metals, and total dissolved solids). Concentrations of most particulate constituents were approximately one-half or more orders of magnitude higher in stormflow samples than in base-flow samples. Total copper and zinc stormflow concentrations exceeded the national recommended aquatic life criteria for acute conditions to varying degrees. Annual loads and yields were estimated for 12 constituents (which include suspended sediments, nutrients, base cations, trace metals, and total dissolved solids) using a surrogate regression model approach and the Beale load estimator. Loads were typically higher for years with higher runoff. The proportional range of annual loads for total suspended solids, suspended-sediment concentrations, total phosphorus, and total lead, however, were 3.2 to 4.8 times larger than for annual runoff. Higher-than-expected annual sediment loads occurred in the years that also had some of the highest peak flows during the period, indicating that large storms are responsible for much of the sediment transport. Large development projects in proximity to streams also were related to years with high sediment loads. Yields from the Crooked Creek and North Fork Peachtree Creek watersheds were typically among the highest for 8 of the 12 constituents. These watersheds had the two highest amounts of developed medium plus high intensity land cover and the two highest percentages of imperviousness. Moderate to strong correlations were identified between seven of the constituent yields and the percentage of developed medium and high intensity land cover groups. Temporal trends in concentrations and loads were identified for 140 of the 300 possible watershed-time period-constituent combinations. There were substantially more negative than positive temporal trends identified during WYs 2003–10, whereas the number of negative and positive temporal trends were similar during WYs 2010–20. Measures of sediment transport had the most negative temporal trends. A few watersheds had consistent trends across several constituents; however, these trends did not appear to be associated with temporal changes in development or imperviousness. This study provides a thorough assessment of watershed characteristics, hydrology, and water-quality conditions and trends for the 15 study watersheds and can be used to identify possible factors that affect runoff and water quality and determine changes in water-quality conditions. Watershed managers can use these data and analyses to inform management decisions regarding the designated uses of streams, minimization of flooding, protection of aquatic habitats, and optimization of the effectiveness of best management practices.

Georgia↗

Modeling approaches in avian conservation and the role of field biologists

This review grew out of our realization that models play an increasingly important role in conservation but are rarely used in the research of most avian biologists. Modelers are creating models that are more complex and mechanistic and that can incorporate more of the knowledge acquired by field biologists. Such models require field biologists to provide more specific information, larger sample sizes, and sometimes new kinds of data, such as habitat-specific demography and dispersal information. Field biologists need to support model development by testing key model assumptions and validating models. The best conservation decisions will occur where cooperative interaction enables field biologists, modelers, statisticians, and managers to contribute effectively. We begin by discussing the general form of ecological models—heuristic or mechanistic, "scientific" or statistical—and then highlight the structure, strengths, weaknesses, and applications of six types of models commonly used in avian conservation: (1) deterministic single-population matrix models, (2) stochastic population viability analysis (PVA) models for single populations, (3) metapopulation models, (4) spatially explicit models, (5) genetic models, and (6) species distribution models. We end by considering their unique attributes, determining whether the assumptions that underlie the structure are valid, and testing the ability of the model to predict the future correctly.

Ornithological Monographs↗

An integrated monitoring approach using multiple reference sites to assess sustainable restoration in coastal Louisiana

Achieving sustainable resource management in coastal Louisiana requires establishing reference conditions that incorporate the goals and objectives of restoration efforts. Since the reference condition is usually considered sustainable, it can be a gauge to assess the present condition of a (degraded) system or to evaluate progress of management actions toward some target system state (the reference or desired conditions). In 2003, the Coastal Wetlands Planning, Protection, and Restoration Act (CWPPRA) Task Force and the Louisiana State Wetlands Authority adopted the “Coastwide Reference Monitoring System -- Wetlands” (CRMS--Wetlands) for Louisiana. This system will provide data from multiple reference sites to explore the properties of a sustained reference condition. CRMS--Wetlands provides links between project-specific and system-wide objectives, criteria for selecting reference sites or conditions, a more robust statistical design, and critical monitoring variables. In addition, a system-wide assessment and monitoring plan (SWAMP) is being developed that incorporates and evaluates existing monitoring efforts (to the extent possible) within a system-wide experimental design. The SWAMP will integrate monitoring of biological, chemical, physical, and climatological variables in four modules: wetlands (CRMS--Wetlands), barrier islands, inshore waters and rivers, and nearshore coastal waters. Data and information collected under SWAMP will contribute to developing a systems-synthesis model for coastal Louisiana. Regional restoration project leaders in coastal Louisiana acknowledge the mutual dependence of monitoring and modeling the coastal landscape. For example, experiments or measurements should not be conducted independently of modeling and vice versa. Assessment should be directed at reducing scientific uncertainty to improve confidence in modeling and monitoring tools and ultimately to assist management actions. An adaptive environmental assessment and management process prescribes modeling, monitoring, and research activities to be conducted from initial stages of restoration planning to optimize the ability to assess and achieve sustainable restoration.

Louisiana↗

India National Gas Hydrate Program Expedition 02 summary of scientific results: Numerical simulation of reservoir response to depressurization

The India National Gas Hydrate Program Expedition 02 (NGHP-02) discovered gas hydrate at high saturation in sand reservoirs at several sites in the deepwater Bay of Bengal. To assess the potential response of those deposits to scientific depressurization experiments, comprehensive geologic models were constructed to enable numerical simulation for two sites. Both sites (NGHP-02-09 and NGHP-02-16) feature thick sequences of thinly-interbedded reservoir and non-reservoir facies at sub-seafloor depths of less than 300 m and sub-sea depths of 2,400 m or more. These settings pose significant challenges to current modeling capabilities. First, the thinly-bedded reservoir architecture complicates the determination of basic reservoir parameters from both log and core data due to measurement resolution issues. Secondly, the fine-scale variation in sediment properties imparts great contrasts in key parameters over very short distances, creating high gradients at multiple scales and varying orientations that necessitate careful design of high-definition simulation grids. Thirdly, the deposits include internal sources of water, as well as a range of complex boundary conditions, including variable permeability within the overlying mud-rich “seals”, that complicate reservoir depressurization. Lastly, because of the unique combination of great water depth and relatively shallow sub-seafloor depth, models designed to maximize the dissociation rate impose large pressure drawdowns on relatively low-strength sediments. This condition renders the proper evaluation and integration of the geomechanical response to hydrate dissociation critical. In this report, we review the history of gas hydrate reservoir simulation, discuss methods for creating geologic input models, and summarize the key findings and implications of the collaborative NGHP-02 numerical simulation effort. Together, the studies confirm the viability of the modeled accumulations for scientific testing and identify key challenges related to the selection of specific test sites and the design of test wells.

Journal of Marine and Petroleum Geology↗

Geologic studies in Alaska by the U.S. Geological Survey, 1997

The eight papers that follow continue the series of U.S. Geological Survey (USGS) reports on investigations in the geologic sciences in Alaska. The series presents new and sometimes preliminary findings that are of interest to earth scientists in academia, government, and industry; to land and resource managers; and to the general public. Reports presented in Geologic Studies in Alaska cover a broad spectrum of topics from all parts of the State (fig. 1), which serves to emphasize the diversity of USGS efforts to meet the Nation's needs for earth-science information in Alaska. The papers in this volume are organized under the topics Resources, Geologic Framework, and Environment and Climate. Such an organization is intended to reflect the scope and objectives of USGS programs currently active in Alaska. Resource papers include one that presents detailed observations from a Mississippian Zn-Pb-Cu-Ag occurrence in the Brooks Range (Werdon). Mineralogic, chemical, and isotopic data provide the basis for a proposed relationship between this vein-breccia deposit and the shale-hosted massive sulfide deposit type, which includes the active Red Dog mine in the western Brooks Range. Also included under the topic of Resources is a paper that presents geochemical and isotopic data from the Greens Creek and Woewodski Island volcanogenic massive sulfide deposits in southeastern Alaska (Newberry and Brew). The depositional environment and sedimentological setting of Tertiary coal beds in the Matanuska and Susitna Valleys is the focus of a third paper under the topic of Resources (Flores and others). Geologic Framework studies provide background information that is the scientific basis for present and future studies of the environment, mineral and energy resources, paleoclimate, and hazards in Alaska. One paper presents the results of sedimentologic and paleontologic comparisons of lower Paleozoic, deep-water-facies rock units in central Alaska (Dumoulin and others). The authors show which of these units are likely to correlate with one another, suggest likely source regions, and provide a structural restoration of units that have been fragmented by large fault motions. A second framework paper provides a map, rock descriptions, and chemical compositions of volcanic rocks in a newly recognized, geologically young volcanic center in the Aleutian volcanic arc (Hildreth and others). A third paper presents an interesting summary of gravity changes that occurred in south-central Alaska during the great earthquake of 1964 and for the following 25 years (Barnes). Gravity changes correlate with land-elevation changes in some cases, but not in others, which means that different processes are responsible for the gravity changes.

Alaska↗

Nutrient attenuation in rivers and streams, Puget Sound Basin, Washington

Nutrients such as nitrogen and phosphorus are important for aquatic ecosystem health. Excessive amounts of nutrients, however, can make aquatic ecosystems harmful for biota because enhanced growth and decay cycles of aquatic algae can reduce dissolved oxygen in the water. In Puget Sound marine waters, low dissolved oxygen concentrations are observed in a number of marine nearshore areas, and nutrients have been identified as a major stressor to the local ecosystem. Delivery of nutrients from major rivers in the Puget Sound Basin to the marine environment can be large. Therefore, it is important to identify factors related to how nutrients are retained (attenuated) within streams and rivers in the Puget Sound Basin. Physical, chemical, and biological factors related to nutrient attenuation were identified through a review of related scientific literature. Numerous empirical modeling approaches for estimating nutrient attenuation in streams and rivers also were compiled, and a subset of these models was applied to the Puget Sound Basin. In particular, models based on the physical characteristics of a river reach (RivR-N model) and on the physical and biological features of a river reach (v f model) were used and compared for the 17 major rivers draining to the Puget Sound. Data on the relative amount of instream attenuation (the fraction of nutrient input removed per kilometer of stream reach) showed some common and general themes. Firstly, headwater reaches throughout the Puget Sound Basin tend to be better than the main stems of the major rivers at attenuating nitrate and orthophosphorus (ortho-P). Secondly, rivers are more efficient at attenuating nitrate than ortho-P, probably because of the close relation between phosphorus and suspended sediment, which was not captured fully in the models. Thirdly, when comparing the RivR-N and v f models for nitrate, physical characteristics of the channel may be more effective predictors of relative nitrate attenuation for main stem reaches, whereas biological factors may be more effective predictors in headwater reaches. These results are explained in terms of four primary factors of attenuation: sinuosity, channel slope, specific discharge, and uptake velocity (v f ) of the reach. A simple scoring procedure based on these four factors showed that reaches where attenuation scores were high had higher relative attenuation of nutrients from the RivR-N and v f models. This attenuation "scorecard" can be used to quickly assess the potential for a given reach to attenuate nutrients. Seasonal relative attenuation at three case studies was greater in summer months (July through September) and much lower and almost constant from January through June. An analysis of relative attenuation across a range of nutrient concentrations showed that, at some point, relative instream attenuation is minimized. For nitrate, relative attenuation reached a minimum value greater than 3 milligrams of nitrogen per liter (mg N/L) during low flow and 1 mg N/L during high flow. For orthophosphate, minimum relative attenuation was observed at about 0.1 milligram of phosphorus per liter (mg P/L) for both low- and high-flow conditions. Generally, the temporal dynamics of nutrient attenuation are dependent on the travel time through a given reach, the proportion of flow in contact with the sediment, and the amount of biological activity. Improved understanding of nutrient attenuation in Puget Sound Basin will benefit from the compilation of more detailed data for specific discharge, channel slope, and channel sinuosity in Puget Sound streams and rivers. Additionally, field studies examining upstream-downstream changes in nutrient load and field-based measurements of v f are needed. From a management perspective, preservation and improvement of instream nutrient attenuation should focus on increasing the travel time through a reach and contact time of water sediment (reactive) surfaces and lowering nutrient concentrations (and loads) to avoid saturation of instream attenuation and increase attenuation efficiency. These goals can be reached by maintaining and restoring channel-flood plain connectivity, maintaining and restoring healthy riparian zones along streams, managing point and nonpoint nutrient loads to streams and rivers, and restoring channel features that promote attenuation such as the addition of woody debris and maintaining pool-riffle morphologies. Many of these management approaches are already being undertaken during projects aimed to restore quality salmon habitat. Therefore, there is a dual benefit to these projects that also may lead to enhanced potential for nitrogen and phosphorus attenuation.

Washington↗

Streamflow and water-quality characteristics at selected sites of the St. Johns River in central Florida, 1933 to 2002

To meet water-supply needs in central Florida for 2020, the St. Johns River is being considered as a source of water supply to augment ground water from the Floridan aquifer system. Current (2004) information on streamflow and water-quality characteristics of the St. Johns River in east-central Florida is needed by water resources planners to assess the feasibility of using the river as an alternate source of water supply and to design water treatment facilities. To address this need, streamflow and water quality of the 90-mile-long middle reach of the St. Johns River, Florida, from downstream of Lake Poinsett to near DeLand, were characterized by using retrospective (1991-99) and recently collected data (2000-02). Streamflow characteristics were determined by using data from water years 1933-2000. Water-quality characteristics were described using data from 1991-99 at 15 sites on the St. Johns River and 1 site each near the mouths of the Econlockhatchee and Wekiva Rivers. Data were augmented with biweekly water-quality data and continuous physical properties data at four St. Johns River sites and quarterly data from sites on the Wekiva River, Blackwater Creek, and downstream of Blue Springs from 2000-02. Water-quality constituents described were limited to information on physical properties, major ions and other inorganic constituents, nutrients, organic carbon, suspended solids, and phytoplankton chlorophyll-a. The occurrence of antibiotics, human prescription and nonprescription drugs, pesticides, and a suite of organic constituents, which may indicate domestic or industrial waste, were described at two St. Johns River sites using limited data collected in water years 2002-03. The occurrence of these same constituents in water from a pilot water treatment facility on Lake Monroe also was described using data from one sampling event conducted in March 2003. Dissolved oxygen concentration and water pH values in the St. Johns River were significantly lower during high-flow conditions than during low-flow conditions. Low dissolved oxygen concentrations may have resulted from the input of water from marsh areas or the subsequent decomposition of organic matter transported to the river during high-flow events. Low water pH values during high-flow conditions likely resulted from the increased dissolved organic carbon concentrations in the river. Concentrations of total dissolved solids and other inorganic constituents in the St. Johns River were inversely related with streamflow. Most major ion concentrations, total dissolved solids concentrations, and specific conductance values varied substantially at the Christmas, Sanford, and DeLand sites during low-flow periods in 2000-01 probably reflecting wind and tidal effects. Sulfide concentrations as high as 6 milligrams per liter (mg/L) were measured in the St. Johns River during high-flow periods. Increased sulfide concentrations likely resulted from the decomposition of organic matter or the reduction of sulfate. Bromide concentrations as high as 17 mg/L were measured at the most upstream site on the St. Johns River during 2000-02. Temporal variations in bromide were characterized by sharp peaks in concentration during low-flow periods. Peaks in bromide concentrations tended to coincide with peaks in chloride concentrations because the likely source of both constituents is ground water affected by relict seawater. Median dissolved organic carbon concentrations ranged from 15 to 26 mg/L during 2000-02, and concentrations as high as 42 mg/L were measured. Water color values and dissolved organic carbon concentrations generally were significantly greater during high-flow conditions than during low-flow conditions. Specific ultraviolet light absorbance data indicated the organic carbon during high-flow events was more aromatic in composition and likely originated from terrestrially derived sources compared to organic carbon in the river during other times of the year. D

Scientific Investigations Report↗

Evaluation of ground-water contribution to streamflow in coastal Georgia and adjacent parts of Florida and South Carolina

Stream-aquifer relations in the coastal area of Georgia and adjacent parts of Florida and South Carolina were evaluated as part of the Coastal Georgia Sound Science Initiative, the Georgia Environmental Protection Division's strategy to protect the Upper Floridan aquifer from saltwater intrusion. Ground-water discharge to streams was estimated using three methods: hydrograph separation, drought-streamflow measurements, and linear-regression analysis of streamflow duration. Ground-water discharge during the drought years of 1954, 1981, and 2000 was analyzed for minimum ground-water contribution to streamflow. Hydrograph separation was used to estimate baseflow at eight streamflow gaging stations during the 31-year period 1971?2001. Six additional streamflow gaging stations were evaluated using linear-regression analysis of flow duration to determine mean annual baseflow. The study area centers on three major river systems ? the Salkehatchie?Savannah?Ogeechee, Altamaha?Satilla?St Marys, and Suwannee ? that interact with the underlying ground-water system to varying degrees, largely based on the degree of incision of the river into the aquifer and on the topography. Results presented in this report are being used to calibrate a regional ground-water flow model to evaluate ground-water flow and stream-aquifer relations of the Upper Floridan aquifer. Hydrograph separation indicated decreased baseflow to streams during drought periods as water levels declined in the aquifer. Average mean annual baseflow ranged from 39 to 74 percent of mean annual streamflow, with a mean contribution of 58 percent for the period 1971?2001. In a wet year (1997), baseflow composed from 33 to 70 percent of mean annual streamflow. Drought-streamflow analysis estimated baseflow contribution to streamflow ranged from 0 to 24 percent of mean annual streamflow. Linear-regression analysis of streamflow duration estimated the Q35 (flow that is equaled or exceeded 35 percent of the time) as the most reasonable estimate of baseflow. The Q35, when compared to mean annual streamflow, estimated a baseflow contribution ranging from 65 to 102 percent of streamflow. The Q35 estimate tends to overestimate baseflow as evidenced by the baseflow contribution greater than 100 percent. Ground-water contributions to streamflow are greatest during winter when evapotranspiration is low, and least during summer when evapotranspiration is high. Baseflow accounted for a larger percentage of streamflow at gaging stations in the Salkehatchie?Savannah?Ogeechee River Basin than in the other two basins. This difference is due largely to the availability of data, proximity to the Piedmont physiographic province where the major rivers originate and are by supplied ground water, and proximity to the upper Coastal Plain where there is greater topographic relief and interconnection between streams and aquifers.

Florida, Georgia, South Carolina↗

Monitoring channel morphology and bluff erosion at two installations of flow-deflecting vanes, North Fish Creek, Wisconsin, 2000-03

Flow-deflecting vanes were installed in the streambed along two meander bends with eroding bluffs in 2000 and 2001 in the upper main stem of North Fish Creek, a tributary to Lake Superior in Wisconsin. About 45 vanes were arranged in 15 arrays at each site to deflect the flow away from the eroding toe or base of the bluff (outside of a bend) and toward the point bar (inside of a bend). Channel cross-section and bluff-erosion surveys were done and streamflow and stage were measured before, during, and after vane installation to monitor changes in channel morphology and bluff erosion in the context of hydrologic conditions. There were two large floods in the study area in spring 2001 (recurrence interval of approximately 100 years) and in spring 2002 (recurrence intervals of approximately 50 years). Some maintenance and replacement of vanes were needed after the floods. Most of the channel-morphology changes resulted from the large floods, and fewer changes resulted from near-bankfull or at-bankfull flows (one in October 2002 and four in April and May 2003). At the bluff located 16.4 river miles upstream of the creek mouth (site 16.4), the vanes deflected flow and caused the channel to migrate away from the base of the bluff and toward the point bar, allowing sediment to deposit along the bluff base. The 361-foot reach at site 16.4 had a net gain of 6,740 cubic feet of sediment over the entire monitoring period (2000?03). Deposition (10,660 cubic feet) occurred mainly along the base of the bluff in the downstream part of the bend. Erosion occurred at site 16.4 along the streambed, the point bar side of the channel, and along a midchannel bar (1,220, 1,610, and 1,090 cubic feet, respectively). Less channel migration was observed during 2001-03 at another bluff located 12.2 river miles upstream of the creek mouth (site 12.2), which had a net loss of sediment through the 439-foot reach of 2,800 cubic feet over the monitored time period. The main volume of sediment was lost from the bluff toe in the downstream part of the bend (7,100 cubic feet). Monitored channel-morphology changes at site 12.2 were less than at site 16.4, most likely because installation was done after the April 2001 flood, which caused major changes in channel morphology at site 16.4, and because the monitoring period was shorter than at site 16.4. Bluff-erosion data from both sites indicate that mass wasting and block failures from the bluff top occur episodically and will continue to occur for decades or more.

Wisconsin↗

Status and Trends of Sea Otter Populations in Southeast Alaska, 1969-2003

Aerial surveys of all known sea otter (Enhydra lutris) habitat in Southeast Alaska (SE AK) in 2002-2003 indicated a population size of 8,949 otters [Standard Error (SE) = 899] at an average density of 0.92 otters per square kilometer. These findings on sea otter distribution and abundance were compared to results from several previous surveys. Sea otters have expanded their range beyond the outer coast of SE AK and currently occupy inside waters such as Glacier Bay and Sumner Strait. This range expansion, along with archeological evidence, supports the hypothesis that sea otters are capable of colonizing inside waters in SE AK. Inside Glacier Bay National Park and Preserve, in northern SE AK, sea otter abundance has increased from 5 in 1995 to 1,266 (SE = 196) in 2002, more than doubling on an average annual basis, indicating immigration and reproduction as factors contributing to population growth. In the remainder of northern SE AK, the estimated abundance has declined from 2,295 in 1987 to 1,838 (SE = 307) in 2002. In southern SE AK, the abundance of sea otters increased from 2,167 in 1988 to 5,845 (SE = 821) in 2003. Overall, population growth rates for sea otters in SE AK between 1987 and 2003 are much lower than rates from previous studies and were unexpected given the amount of unoccupied habitat available in SE AK. Divergent population trajectories were evident between the southern (6.6 percent per year) and northern areas of SE AK (2.0 percent per year). These differences suggest variation in reproductive or survival rates between the areas. Harvest levels between 1989 and 2003 may have had a measurable effect on sea otter populations in SE AK. Available data on age and sex specific fecundity and survival rates could be used to develop age- and sex-structured population matrix models to help guide management and conservation of sea otter populations.

Scientific Investigations Report↗

Characterization of Groundwater Quality Based on Regional Geologic Setting in the Piedmont and Blue Ridge Physiographic Provinces, North Carolina

A compilation of groundwater-quality data collected as part of two U.S. Geological Survey studies provides a basis for understanding the ambient geochemistry related to geologic setting in the Piedmont and Blue Ridge Physiographic Provinces (hereafter referred to as Piedmont and Mountains Provinces) of North Carolina. Although the geology is complex, a grouping of the sampled wells into assemblages of geologic units described as 'geozones' provides a basis for comparison across the region. Analyses of these two data sets provide a description of water-quality conditions in bedrock aquifers of the Piedmont and Mountains Provinces of North Carolina. Analyzed data were collected between 1997 and 2008 from a network of 79 wells representing 8 regional geozones distributed throughout the Piedmont and Mountains Provinces. This area has experienced high rates of population growth and an increased demand for water resources. Groundwater was used by about 34 percent of the population in the 65 counties of this region in 2005. An improved understanding of the quality and quantity of available groundwater resources is needed to plan effectively for future growth and development. The use of regional geologic setting to characterize groundwater-quality conditions in the Piedmont and Mountains Provinces is the focus of this investigation. Data evaluation included an examination of selected properties and the ionic composition of groundwater in the geozones. No major differences in overall ionic chemistry of groundwater among the geozones were evident with the data examined. Variability in the cationic and anionic composition of groundwater within a particular geozone appeared to reflect local differences in lithologic setting, hydrologic and geochemical conditions, and(or) land-use effects. The most common exceedances of the drinking-water criteria (in accordance with Federal and State water-quality standards) occurred for radon, pH, manganese, iron, and zinc. Radon had the most exceedances, with groundwater from 61 of the 69 sampled wells having activities higher than the U.S. Environmental Protection Agency's proposed maximum contaminant level of 300 picocuries per liter. Overall, the Milton and the Raleigh and Charlotte geozones had the greatest number, eight each, of water-quality properties or constituents that exceeded applicable drinking-water criteria in at least one well. The Eastern Blue Ridge and Felsic intrusive geozones each had seven properties or constituents that exceeded criteria, and the Carolina slate geozone had six. Based on limited data, initial results of statistical comparison tests identified statistically significant differences in concentrations of some groundwater constituents among the geozones. Statistically significant differences in median values of specific conductance and median concentrations of calcium, potassium, sodium, bicarbonate, chloride, silica, ammonia, aluminum, antimony, cadmium, and uranium were identified between one or more geozone pairs. Overall, the groundwater constituents appear to be influenced most significantly by the Inner Piedmont, Carolina slate, and Felsic intrusive geozones. The study data indicate that grouping and evaluating analytical data on the basis of regional geozone setting can be useful for characterizing water-quality conditions in bedrock aquifers of the Piedmont and Blue Ridge Provinces of North Carolina.

North Carolina↗