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The linear relation observed in a log Ca ++ versus log Br - plot for subsurface Cl - waters is attributed to ultrafiltration by shale of sea water and fresh water that have passed through sedimentary rocks since their formation. Reactions between these solutions and sedimentary minerals, particularly dolomitization, must have contributed additional Ca ++ to solution.
Reversing the ongoing degradation of the planet's ecosystems requires timely and detailed monitoring of ecosystem change and uses. Yet, the System of National Accounts (SNA), first developed in response to the economic crisis of the 1930s and used by statistical offices worldwide to record economic activity (for example, production, consumption, and asset accumulation), does not make explicit either inputs from the environment to the economy or the cost of environmental degradation ( 1 , 2 ). Experimental Ecosystem Accounting (EEA), part of the System of Environmental-Economic Accounting (SEEA), has been developed to monitor and report on ecosystem change and use, using the same accounting approach, concepts, and classifications as the SNA ( 3 ). The EEA is part of the statistical community's response to move SNA measurement “beyond gross domestic product (GDP).” With the first generation of ecosystem accounts now published in 24 countries, and with a push to finalize a United Nations (UN) statistical standard for ecosystem accounting by 2021, we highlight key advances, challenges, and opportunities.
Soils receive inputs of human pathogenic and indicator bacteria through land application of animal manures or sewage sludge, and inputs by wildlife. Soil is an extremely heterogeneous substrate and contains meso- and macrofauna that may be reservoirs for bacteria of human health concern. The ability to detect and quantify bacteria of human health concern is important in risk assessments and in evaluating the efficacy of agricultural soil management practices that are protective of crop quality and protective of adjacent water resources. The present chapter describes the distribution of selected Gram-positive and Gram-negative bacteria in soils. Methods for detecting and quantifying soilborne bacteria including extraction, enrichment using immunomagnetic capture, culturing, molecular detection and deep sequencing of metagenomic DNA to detect pathogens are overviewed. Methods for strain phenotypic and genotypic characterization are presented, as well as how comparison with clinical isolates can inform the potential for human health risk.
Significant concentrations of oxalate (dissolved plus particulate) were present in sediments taken from a diversity of aquatic environments, ranging from 0.1 to 0.7 mmol/liter of sediment. These included pelagic and littoral sediments from two freshwater lakes (Searsville Lake, Calif., and Lake Tahoe, Calif.), a hypersaline, meromictic, alkaline lake (Big Soda Lake, Nev.), and a South San Francisco Bay mud flat and salt marsh. The oxalate concentration of several plant species which are potential detrital inputs to these aquatic sediments ranged from 0.1 to 5.0% (wt/wt). In experiments with litter bags, the oxalate content of Myriophyllum sp. samples buried in freshwater littoral sediments decreased to 7% of the original value in 175 days. This suggests that plant detritus is a potential source of the oxalate within these sediments. [ 14 C]oxalic acid was anaerobically degraded to 14 CO 2 in all sediment types tested, with higher rates evident in littoral sediments than in the pelagic sediments of the lakes studied. The turnover time of the added [ 14 C]oxalate was less than 1 day in Searsville Lake littoral sediments. The total sediment oxalate concentration did not vary significantly between littoral and pelagic sediments and therefore did not appear to be controlling the rate of oxalate degradation. However, depth profiles of [ 14 C]oxalate mineralization and dissolved oxalate concentration were closely correlated in freshwater littoral sediments; both were greatest in the surface sediments (0 to 5 cm) and decreased with depth. The dissolved oxalate concentration (9.1 μmol/liter of sediment) was only 3% of the total extractable oxalate (277 μmol/liter of sediment) at the sediment surface. These results suggest that anaerobic oxalate degradation is a widespread phenomenon in aquatic sediments and may be limited by the dissolved oxalate concentration within these sediments.
Bacterial oxidation of 14 CH 2 Br 2 and 14 CH 3 Br was measured in freshwater, estuarine, seawater, and hypersaline-alkaline samples. In general, bacteria from the various sites oxidized similar amounts of 14 CH 2 Br 2 and comparatively less 14 CH 3 Br. Bacterial oxidation of 14 CH 3 Br was rapid in freshwater samples compared to bacterial oxidation of 14 CH 3 Br in more saline waters. Freshwater was also the only site in which methyl fluoride-sensitive bacteria (e.g., methanotrophs or nitrifiers) governed brominated methane oxidation. Half-life calculations indicated that bacterial oxidation of CH 2 Br 2 was potentially significant in all of the waters tested. In contrast, only in freshwater was bacterial oxidation of CH 3 Br as fast as chemical removal. The values calculated for more saline sites suggested that bacterial oxidation of CH 3 Br was relatively slow compared to chemical and physical loss mechanisms. However, enrichment cultures demonstrated that bacteria in seawater can rapidly oxidize brominated methanes. Two distinct cultures of nonmethanotrophic methylotrophs were recovered; one of these cultures was able to utilize CH 2 Br 2 as a sole carbon source, and the other was able to utilize CH 3 Br as a sole carbon source.
A bacterium experimentally pathogenic for muskrats ( Ondatra zibethica ), white mice, mountain voles ( Microtus montanus ), and deer mice ( Peromyscus maniculatus ) was isolated from the tissues of a sick muskrat captured on the Bear River Migratory Bird Refuge (Brigham City, Utah) and from four surface water samples collected within 15 miles of that point. In culture, the cells are chiefly coccoid, but in the tissues of muskrats and voles they resemble the bizarre forms of Yersinia pestis , except for their smaller size. The characteristics of the organism are described and the name Yersinia philomiragia sp. n. is proposed.
Data bearing on interpretations of the Paleozoic and Mesozoic paleogeography of southwestern North America are important for testing the hypothesis that the Paleozoic miogeocline in this region has been tectonically truncated, and if so, for ascertaining the time of the event and the possible role of the Mojave-Sonora megashear. Here, we present an analysis of existing and new data permitting reconstruction of the Paleozoic continental margin of southwestern North America. Significant new and recent information incorporated into this reconstruction includes (1) spatial distribution of Middle to Upper Devonian continental-margin facies belts, (2) positions of other paleogeographically significant sedimentary boundaries on the Paleozoic continental shelf, (3) distribution of Upper Permian through Upper Triassic plutonic rocks, and (4) evidence that the southern Sierra Nevada and western Mojave Desert are underlain by continental crust. After restoring the geology of western Nevada and California along known and inferred strike-slip faults, we find that the Devonian facies belts and pre-Pennsylvanian sedimentary boundaries define an arcuate, generally south-trending continental margin that appears to be truncated on the southwest. A Pennsylvanian basin, a Permian coral belt, and a belt of Upper Permian to Upper Triassic plutons stretching from Sonora, Mexico, into westernmost central Nevada, cut across the older facies belts, suggesting that truncation of the continental margin occurred in the Pennsylvanian. We postulate that the main truncating structure was a left-lateral transform fault zone that extended from the Mojave-Sonora megashear in northwestern Mexico to the Foothills Suture in California. The Caborca block of northwestern Mexico, where Devonian facies belts and pre-Pennsylvanian sedimentary boundaries like those in California have been identified, is interpreted to represent a missing fragment of the continental margin that underwent ???400 km of left-lateral displacement along this fault zone. If this model is correct, the Mojave-Sonora megashear played a direct role in the Pennsylvanian truncation of the continental margin, and any younger displacement on this fault has been relatively small. ?? 2005 Geological Society of America.
The hydration rate of rhyolitic glass has been determined at temperatures ranging from 5° C to 100° C. The relationship between the depth of hydration, x, and time, t is x 2 = kt; k varies from 0.4 μ 2 /10 3 years at 5° C to 10 4 μ 2 /10 3 years at 100° C; k is independent of the water pressure from a few hundredths of a centimeter to 1 atm. water pressure. The activation energy of hydration is about 20 kcal/mole. The determined hydration rates are consistent with the observation that perlite commonly forms by the hydration of shattered rhyolitic glass, either during the late cooling of a deposit or after the deposit has cooled to a surficial temperature.
Two generations of chert have been observed in the Mississippian Leadville Limestone of west-central Colorado: (1) an early chert inferred to have precipitated from hypersaline marine waters of high pH after those waters seeped into carbonate muds prior to final burial and lithification of the carbonate; and (2) a late chert that appears to have precipitated from ground waters as amorphous silica after initial lithification but prior to or during karst erosion of the formation in Late Mississippian (?) and Early Pennsylvanian time. A third type of microcrystalline quartz, hydrothermal jasperoid, is associated with ore deposits of Laramide age in the Leadville, but it is not discussed here. Conditions in west-central Colorado at the time that the early cherts formed in the Leadville were probably similar to those associated with the formation of early diagenetic chert in modern sediments, and the early chert in the Leadville is believed to have formed in a manner similar to the modern early cherts. The silica of the late chert appears to have come from Paleozoic sandstones below the Leadville. It was carried by slightly acid artesian waters into the formation, probably in concentrations of less than 60 ppm SiO 2 Super-saturation of amorphous silica occurred within the Leadville and probably was obtained by evaporative concentration at the water-air interface during dry seasons. Dissolution of the limestone by the slightly acid waters may account for the removal of the calcite that is replaced by chert.
Mineralogically, serpentinites consist predominantly of lizardite, clinochrysotile, and antigorite. Recent work has shown that these minerals are not polymorphs. Chrysotile is the only mineral recognized as a synthetic product in experimental studies of the system MgO-SiO 2 -H 2 O. Antigorite seems to be stable at higher temperatures than lizardite or chrysotile. The density of individual serpentine species is dependent on their morphology; the low-density serpentinites (<2.55g/cc) consist predominantly of clino-chrysotile. Seismic velocities and magnetic susceptibilities of serpentinites are related to the degree of serpentinization. The transition of massive serpentinites from ductile to brittle behavior in laboratory experiments at high confining pressures and temperatures above 300°C has been related to dehydration which may provide a mechanism for developing deep-focus earthquakes along Benioff zones. Serpentinite is formed by direct hydration of ultramafic protolith in the crust. The most common ultramafic protoliths are harzburgite, dunite, and Iherzolite. The assemblage generally developed from these is lizardite + chrysotile + brucite + magnetite. In areas of high-grade metamorphism, antigorite is the predominant serpentine mineral. The common, large, alpine-type serpentinized ultramafic masses contain brucite and have MgO/SiO 2 ratios similar to those of their protolith, resulting in volume increase during serpentinization. Metamorphic serpentinites and some highly sheared alpine-type serpentinites have lower MgO/SiO 2 ratios than their protolith, lack brucite, and appear t o have been formed by volume-for-volume replacement with concomitant loss of magnesium or addition of silica. Many large, young masses of peridotite appear to be slabs of oceanic mantle over-thrust onto continental edges. Subsequent sedimentation, serpentinization, and tectonism have greatly modified these original slabs so that their recognition in older orogenic zones is equivocal. The concept of the tectonic evolution of ultramafic rocks from oceanic crust-mantle slabs invading continental margins and being incrementally serpentinized and moved by later tectonic events provides a working hypothesis that allows a better explanation of the many peculiar and varied occurrences of serpentinite. The evidence does not support Hess' suggestion that the third layer of the oceanic crust consists of partly serpentinized mantle peridotite.
Two major wall-rock sequences, the Paleozoic metasedimentary rocks and the Mesozoic metavolcanic rocks, in the eastern Sierra Nevada, California, are separated by an angular unconformity rather than by a fault as has been proposed by other investigators. The unconformity is parallel to formation contacts in the younger metavolcanic rocks and crosscuts formation contacts in the older metasedimentary rocks. Locally, basal conglomerate with pebbles derived from the older metasedimentary rocks occurs just above the unconformity. The older metasedimentary rocks consist mostly of former marl, chert, and mudstone; they contain three generations of superposed structures. The younger metavolcanic rocks consist mostly of former andesite flows, tuff, and graywacke; these contain only the younger two generations of superposed structures. The sinuous trace of the unconformity is primarily the result of superposed deformations of regional scale which occur in most roof pendants of the eastern Sierra Nevada.
Stratal patterns of the Middle Ordovician Hagan K-bentonite complex and associated rocks show that the Black River–Trenton unconformity in the North American midcontinent formed through the complex interplay of eustasy, sediment accumulation rates, siliciclastic influx, bathymetry, seawater chemistry, and perhaps local tectonic uplift. The unconformity is diachronous and is an amalgamated surface that resulted from local late Turinian lowstand exposure followed by regional early Chatfieldian transgressive drowning and sediment starvation. The duration of the unconformity is greatest in southern Wisconsin, northern Illinois, and northern Indiana, where the Deicke and Millbrig K-bentonite Beds converge at the unconformity. On the basis of published isotopic ages for the Deicke and Millbrig beds, it is possible that in these regions erosion and nondeposition spanned a period of as much as 3.2 m.y.
To reconcile differences between the assessments of crustal composition in the southern Basin and Range province on the basis of seismic refraction and reflection data and lower-crustal xenoliths, we measured velocities of xenoliths from the Cima volcanic field in southern California. Lower-crustal samples studied included gabbro, microgabbro, and pyroxenite. We find that the mafic xenolith velocities are compatible with regional in situ measurements from seismic refraction studies, provided that a mixture of gabbro and pyroxenite is present in the lower crust. Supporting this model are observations that many of the lower-crustal xenoliths from the Cima volcanic field are composites of these rock types, with igneous contacts. Vertical incidence synthetic seismograms show that a gabbroic lower crust with occasional pyroxenite layering can produce a reflective lower crust that is similar in texture to that shown by seismic reflection data recorded nearby.
Preferential flow paths are expected in many groundwater systems and must be located because they can greatly affect contaminant transport. The fundamental characteristics of radiogenic isotope ratios in chemically evolving waters make them highly effective as preferential flow path indicators. These ratios tend to be more easily interpreted than solute-concentration data because their response to water-rock interaction is less complex. We demonstrate this approach with groundwater 87 Sr/ 86 Sr ratios in the Snake River Plain aquifer within and near the Idaho National Engineering and Environmental Laboratory. These data reveal slow-flow zones as lower 87 Sr/ 86 Sr areas created by prolonged interaction with the host basalts and a relatively fast flowing zone as a high 87 Sr/ 86 Sr area.
The eastern central Front Range of the Rocky Mountains in Colorado has long been a region of geologic interest because of Laramide-age hydrothermal polymetallic vein-related ores. The region is characterized by a well-exposed array of geologic structures associated with ductile and brittle deformation, which record crustal strain over 1.7 billion years of continental growth and evolution. The mineralized areas lie along a broad linear zone termed the Colorado Mineral Belt. This lineament has commonly been interpreted as following a fundamental boundary, such as a suture zone, in the North American Proterozoic crust that acted as a persistent zone of weakness localizing the emplacement of magmas and associated hydrothermal fluid flow. However, the details on the controls of the location, orientation, kinematics, density, permeability, and relative strength of various geological structures and their specific relationships to mineral deposit formation are not related to Proterozoic ancestry in a simple manner. The objectives of this field trip are to show key localities typical of the various types of structures present, show recently compiled and new data, offer alternative conceptual models, and foster dialogue. Topics to be discussed include: (1) structural history of the eastern Front Range; (2) characteristics, kinematics, orientations, and age of ductile and brittle structures and how they may or may not relate to one another and mineral deposit permeability; and (3) characteristics, localization, and evolution of the metal and non–metal-bearing hydrothermal systems in the eastern Colorado Mineral Belt.