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USGS2018

Topics in coal geochemistry—Short course

This short course was prepared at the request of Servicio Geológico Colombiano (SGC) as a module for staff training. Prior to the short course, the SGC expressed interest in receiving training in (1) geochemistry and quality of coal; (2) geochemistry of trace elements in coal; (3) mercury and halogens in coal; (4) characterization and cycling of atmospheric mercury; (5) mercury, trace elements, and organic constituents in atmospheric fine particulate matter; (6) mercury in coal and the effect of coal quality on mercury emissions from combustion systems; (7) environmental and health effects related to coal use; and (8) related topics in coal combustion processes. A five-session short course was prepared that addressed all but the engineering aspects of coal use. In the sections that follow, topic overviews are given for the material that was presented. Brief descriptions of each slide are given in appendix 1, and the actual short course material, presented as a series of PowerPoint slides, is included in Portable Document Format (PDF) as appendix 2.

Open-File Report↗
USGS2020

Compilation of mercury data and associated risk to human and ecosystem health, Bad River Band of Lake Superior Chippewa, Wisconsin

Mercury is an environmentally ubiquitous neurotoxin, and its methylated form presents health risks to humans and other biota, primarily through dietary intake. Because methylmercury bioaccumulates and biomagnifies in living tissue, concentrations progressively increase at higher trophic positions in ecosystem food webs. Therefore, the greatest health risks are for organisms at the highest trophic positions and for humans who consume organisms such as fish from these high trophic positions. Data on environmental mercury concentrations in various media and biota provide a basis for comparison among sites and regions and for evaluating ecosystem health risks. The U.S. Geological Survey, in cooperation with the Natural Resources Department, Bad River Band of Lake Superior Chippewa, have compiled a dataset from analyses of mercury concentrations in surface water, bed sediment, fish tissue, Rana clamitans (green frog) tissue, Haliaeetus leucocephalus (bald eagle) feathers, Lontra canadensis (North American river otter) hair, Zizania palustris (northern wild rice), and litterfall from samples collected in the Bad River watershed, Wisconsin during 2004–18. These data originated from either the Natural Resources Department or another agency based on samples collected within or near to Bad River Tribal lands before transfer to the U.S. Geological Survey for compilation and analysis at the onset of the project. This report describes the compiled mercury dataset, provides comparisons to similar measurements in the region and elsewhere, and evaluates health risks to humans and to the sampled biota. Except for litterfall, data were not collected on a consistent, regular basis over a sufficient period to evaluate temporal patterns. The reported mercury concentrations are generally similar to those reported elsewhere in the upper Great Lakes region. Reported values are consistent with atmospheric deposition as the principal source and reflect a favorable environment for mercury methylation. Fish mercury concentrations increased at higher food web positions and generally increased with length in most species measured. Sander vitreus (walleye) present the greatest risk to humans among fishes considered here because of their high trophic position and associated elevated mercury concentrations in combination with relatively high walleye consumption rates by the Native American community. Methylmercury concentrations in wild rice are generally low and likely pose little health risk. Despite reports of declining atmospheric mercury deposition across eastern North America during the past decade, a downward trend in litterfall mercury deposition was not evident in samples collected during 2012–18. Limitations in this data compilation and analysis were noted due to missing information such as collection dates and site locations for some samples. Regular monitoring of mercury in litterfall and surface waters along with periodic collection of fish would enable evaluation of temporal change in the mercury cycle that might affect future risk to humans and aquatic ecosystem inhabitants.

Wisconsin↗
USGS2022

Microplastic particles in dust-on-snow, Upper Colorado River Basin, Colorado Rocky Mountains, 2013–16

Atmospheric dust deposited to snow cover (dust-on-snow) diminishes snow-surface albedo (SSA) to result in early onset and accelerated rate of melting, effects that challenge management of downstream water resources. During ongoing investigations to identify the light-energy absorbing dust particles most responsible for diminished SSA in the Upper Colorado River Basin of the Colorado Rocky Mountains, we found microplastic particles, which are defined as those less than 5 millimeters in any dimension. In each of the 38 samples that represented the last remaining dust layer during melt seasons of 2013–16, microplastics were identified by size, shape, and color, and their relative amounts were visually estimated using stereomicroscopy. Considering the remote, high-elevation settings of the sample sites, the microplastic particles must have been deposited from the atmosphere. The possible role of microplastics for diminishing SSA of snow cover in the Upper Colorado River Basin may be linked to the solar-energy absorptive properties of polymers and is the subject of ongoing investigation.

Colorado↗
USGS2024

Quality of groundwater used for domestic supply in the eastern Sacramento Valley and adjacent foothills, California

Summary More than 2 million Californians rely on groundwater from privately owned domestic wells for drinking-water supply. This report summarizes a water-quality survey of domestic and small-system drinking-water supply wells in the eastern Sacramento Valley and adjacent foothills where more than 25,000 residents are estimated to use privately owned domestic wells. Study results show that inorganic and organic constituents in groundwater were present above regulatory (maximum contaminant level, MCL) benchmarks for public drinking-water quality in 8 and 3 percent, respectively, of the aquifer area used for domestic drinking-water supply (herein, “domestic groundwater resources”; fig. 1). The only inorganic constituent detected above regulatory benchmarks was arsenic. The only organic constituent exceeding regulatory benchmarks was the fumigant 1,2,3-trichloropropane (1,2,3-TCP). Three additional organic constituents—the disinfection by-product chloroform, the gasoline oxygenate methyl tert -butyl ether (MTBE), and the solvent tetrachloroethene (PCE)—were detected at low concentrations below one-tenth of regulatory benchmarks in 34, 10, and 10 percent of domestic groundwater resources, respectively. Total dissolved solids (TDS), iron, and manganese exceeded non-regulatory aesthetic guidelines for drinking water in 5, 10, and 26 percent of domestic groundwater resources, respectively. Per- and polyfluoroalkyl substances (PFASs) were detected in 29 percent of domestic groundwater resources,with 5 percent exceeding the recently enacted (April 2024) U.S. Environmental Protection Agency MCLs. Total coliform and enterococci bacteria were detected in 13 and 8 percent of domestic groundwater resources, respectively. Redox sensitive constituents in this study included arsenic, manganese, nitrate, and iron. In the lower elevation portions of the eastern Sacramento Valley study area, reducing conditions in groundwater aquifers promote elevated arsenic, iron, and manganese, and conversely lower concentrations of nitrate. The presence of the volatile organic compound (VOC) 1,2,3-TCP was related to its past history in select agricultural land uses (on orchards or vineyards) in the Sacramento Valley; however, unlike in the San Joaquin Valley where orchards and vineyards are more common, its detection frequency was low (only detected in one well in this study). Chloroform was frequently detected in this study at low levels. Chloroform is a disinfection byproduct commonly found in domestic wells treated by shock chlorination. The solvent PCE is among the most frequently detected VOCs in groundwater, which is primarily related to its long history of use and its persistence in groundwater in oxic conditions. The gasoline oxygenate MTBE was a contaminant introduced to groundwater through atmospheric exchange when it was used as a fuel additive to decrease smog inducing emissions from vehicles. Its occurrence in groundwater at low levels is expected and makes it a potentially useful tracer of relatively recent recharge water being withdrawn from wells. The PFASs are anthropogenic chemicals with hundreds of uses, and they have been incorporated into many different products, processes, and applications worldwide. Like MTBE, the occurrence of PFASs in groundwater may be in part due to atmospheric exchange, but there are several other pathways that contribute PFASs to the environment.

California↗
USGS2025

Insights and strategic opportunities from the USGS 2024 Per- and Polyfluoroalkyl Substances (PFAS) Interagency Workshop

Introduction In 2021, the U.S. Geological Survey (USGS) published Circular 1490 titled, “Integrated Science for the Study of Perfluoroalkyl and Polyfluoroalkyl Substances (PFAS) in the Environment: A Strategic Science Vision for the U.S. Geological Survey” (Tokranov and others, 2021). Circular 1490 was created to be a resource for USGS scientists prioritizing and planning research related to per- and polyfluoroalkyl substances (PFAS) and to be a guide for developing partnerships with other scientists, State and Federal agencies, and stakeholders engaged in PFAS research and management and mitigation of the environmental and human-health effects of PFAS. This USGS PFAS Strategic Science Vision document was intended to be the foundation for a “living strategic vision,” periodically providing updates on the state of USGS PFAS research, emerging PFAS data gaps and needs, and progress on interagency and stakeholder PFAS partnerships and priorities. To meet this objective, the USGS planned to host an Interagency and Stakeholder PFAS Workshop every 2–3 years. During September 10–12, 2024, the USGS hosted the first Interagency and Stakeholder PFAS Workshop in Reston, Virginia. The Workshop brought together experts from other Federal agencies (U.S. Environmental Protection Agency, National Institute of Environmental Health Sciences, Food and Drug Administration, Department of Defense [Air Force, Army]), State agencies (Washington Fish and Wildlife, Virginia Department of Transportation), and academia (Harvard University, University of Maryland) to address key challenges relating to the measurement and modeling of PFAS and the implications for environmental health. Participants engaged in in-depth discussions centered around six pivotal topics related to PFAS: (1) sampling protocols, methods and interpretation; (2) environmental sources, source apportionment, and occurrence; (3) environmental fate and transport; (4) human and wildlife exposure routes and risk; (5) bioconcentration, bioaccumulation, and biomagnification; and (6) ecotoxicology and effects. Each topic had three breakout sessions. A recurrent theme of workshop discussions was how data on a nationwide scale for PFAS occurrence in various environmental matrices, including air, water, food crops, biota, soil, and streambed sediment could help to advance scientific understanding. Participants noted significant geospatial data gaps, particularly in the midwestern and southern United States and the Pacific Northwest. PFAS data collection tends to be more robust along the eastern seaboard and in California. Participants stressed how enhancing the integration of large and small datasets across various agencies could help to support national scale understanding of PFAS. To address these gaps, attendees suggested leveraging datasets from Federal entities like the USGS and the U.S. Department of Defense, State agencies, and municipal utility services to develop predictive contaminant detection and transport models. Improved coordination between water quality programs and USGS research could help to facilitate access to valuable data, leading to comprehensive databases that inform PFAS point (wastewater treatment plants and landfills) and nonpoint (runoff from land, atmospheric deposition, food packaging) sources, environmental transport mechanisms, environmental detection and concentrations, potential exposure routes, and health effects on different biota, including humans. A specific request was made to develop a map demarking the depth of modern (1953 or later) groundwater, which is susceptible to surface-derived anthropogenic (that is, human-made) contamination, based on tritium-age dating. Emphasis was placed on incorporation of hydrology, groundwater flow paths, groundwater–surface water interactions, and landscape factors in predictive statistical models as a step to improve contaminant source identification and tracking. Molecular fingerprinting approaches garnered attention as techniques to link specific PFAS mixtures detected in a sample to environmental sources and levels in biota (Dávila-Santiago and others, 2022). Integrating data from abiotic (that is, water, soil, and air) and biotic (that is, living organisms) systems identified as a research opportunity. For example, understanding the composition of soils and sediments, which include a mixture of mineral, plant, and animal components, could advance understanding of exposure pathways. The discussions highlighted opportunities to explore and understand the potential redistribution and biotic exposures of PFAS from biosolid and wastewater treatment plant effluent land application practices, in addition to atmospheric releases and discharges from landfill and wastewater treatment plants. Participants identified research gaps surrounding how these sources may contribute to contamination and may affect surrounding ecosystems, including a better definition of anthropogenic background concentrations. Moving forward, the collection of co-occurrence data was noted as a means to improve understanding of complex mixtures and to leverage companion modeling efforts focused on areas with high and low contamination levels to identify areas of concern and unaffected resources. Participants emphasized how centralized USGS databases and the establishment of sample-metadata archives can help to ensure that samples are preserved and accessible for future research. In conclusion, the workshop participants identified opportunities to bridge data gaps and improve measurement techniques, modeling frameworks, databases, and communication, to enhance the understanding of PFAS and their effects on environmental and human health. Upon completion of the workshop, participants indicated an interest in developing strategic data collection, modeling, and analytical approaches to address these challenges.

Open-File Report↗
USGS1972

Emergency ground-water supplies in the Seattle-Tacoma urban complex and adjacent areas, Washington

Urban areas that are supplied from surface-water sources are especially vulnerable to major disruption of their water supplies. Such disruption could result from natural disasters such as earthquakes, floods, or landslides or from such other causes as dam failures fallout of radioactive material or other toxic substance from the atmosphere or other toxic substances from the atmosphere or direct introduction (either accidental or deliberate) of any substance that would render the water unfit for use. Prolonged disruption of public water supplies not only causes personal hardships but also endangers health and safety unless suitable alternative emergency supplies can be provided. The degree of hardship and danger generally increases in direct relation to the population density. Ground water because it occurs beneath protective soil and rock materials is less subject to sudden major contamination than are surface-water bodies. For this reason and also because of its widespread availability in the Puget Sound region ground water is especially desireable as a sources of emergency supplies for drinking or other uses requiring water of good quality. In much of the area existing wells would be suitable as safe sources of emergency supplies.

Washington↗
USGS1975

Environmental tritium in the Edwards Aquifer, central Texas 1963-71

Tritium concentrations of samples from 50 wells and springs in the Edwards aquifer in the San Antonio area of Texas have been analysed. Tritium now in the aquifer is partly natural cosmic ray produced tritium, but most is tritium produced by atmospheric thermonuclear tests in the 1950's and early 1960's. The tritium levels in atmospheric precipitation and streams recharging the Edwards are presented for comparison with the ground-water data. In general, tritium distribution within the Edwards confirms the accepted pattern of water flow within the aquifer. Concentrations of greater than 20 tritium units occur in the recharge areas, while less than 1 tritium unit is present along the aquifer's southern and southeastern boundary.

Texas↗
USGS1976

Physical constraints on sounds generated by very small earthquakes

Vertical vibrations of the ground surface due to elastic waves from an earthquake will generate acoustic pressure waves in the overlying atmosphere. Sufficiently intense vibrations of the ground at frequencies greater than about 20 HZ can produce pressure waves that are within the audible range of many animals, including humans. People in the epicentral region of moderate to large earthquakes, for instance, commonly relate hearing sounds accompanying individual earthquakes (here we exclude sounds associated with mechanical resonances in structures such as houses). Descriptions of these sounds range from the report of distant guns to the rumble of thunder or the rushing of a wind (Davison, 1938; Lanchow Seismological Brigade, Appendix II). In many instances, the sounds are described as starting several seconds before the earthquake is felt. Experimental and theoretical verification that such earthquake sounds are generated by high-frequency ground motion from local earthquakes is based on simultaneous acoustic and seismic recordings recently obtained during a swarm of earthquakes in the Imperial Valley, California (Hill and others, 1976). These results show that for local earthquakes in the magnitude range 2 to-3, audible sounds are generated by the first arriving compressional (P) wave while perceptible shaking begins with the larger but slower shear (S) wave, explaining the reports that "earthquake sounds" are frequently heard several seconds before the earthquake is felt. A commonly proposed explanation for alleged anomalous animal behavior hours to days prior to large earthquakes suggests that animals with acute, high-frequency hearing respond to weak '''ultrasonic" sounds generated by small earthquakes occurring in the epicentral region of the impending event. Such earthquakes are presumably too small to be either felt or heard by humans in the region and too small to be routinely recognized as earthquakes on seismograms recorded on a local seismograph network. Evidence that such "popping and cracking" may occur in the region of an impending earthquake comes from laboratory experiments in which the rate of microfracturing in a rock sample subjected to large stress differences increases dramatically before catastrophic failure of the sample (Scholz, 1968; Stesky, 1975). In this paper we investigate the following question: What are the constraints on earthquake size (fault dimension and displacement) and hypocentral distance (distance from the earthquake focus to a point on the Earth's surface) such that animals noted for their acute hearing might react to the sound generated by the event while the same event would go undetected by humans (either by feeling, hearing, or routine identification on a local seismograph network)? Factors to be considered include: 1) the nature of the displacement spectral amplitudes of elastic waves radiated from an earthquake, 2) the effects of attenuation on the spectral components of elastic (seismic) waves over propagation paths from the focus to the Earth's surface, 3) the appropriate scaling of spectral amplitudes from moderate to very small earthquakes, 4) the coupling of elastic waves in the Earth to acoustic waves in the atmosphere, and 5) the threshold-of-hearing characteristics for various animals, including man. In considering these factors, we will find that, except for extremely small, shallow "earthquakes" (fracture dimension on the order of 10 cm and focal depths on the order of 10 m), acoustic emissions from premonitory fracturing ought to be equally audible to both people and animals in the immediate area of the fracturing.

Open-File Report↗
USGS1978

Discrimination of hydrothermally altered rocks along the Battle Mountain-Eureka, Nevada, mineral belt using Landsat images

Landsat Multispectral Scanner (MSS) images of the northwestern part of the Battle Mountain-Eureki, Nevada mineral belt were evaluated for distinguishing hydrothermally altered rocks associated with porphyry copper and disseminated gold deposits. Detection of altered rocks from Landsat is based on the distinctive spectral reflectance of limonite present at coatings on weathered surfaces Some altered rocks are visible as bleached areas in individual MSS bands; however, they cannot be consistently distinguished from unaltered rocks with high albedo nor from bright areas resulting .from topographic slope. Black-and-white ratio images were generated to subdue .topographic effects, and three ratio images were composited in color to portray spectral radiance differences, forming an image known as a color-ratio composite (CRC). The optimum CRC image for this area has MSS 4/5 as blue, MSS 4/6 as yellow, and MSS 6/7 as magenta, and differs in two respects from most CRC images of arid areas. First, as a result of the increased vegetation cover in the study area, MSS 5/6 was replaced by MSS 4/6 as the yellow layer. Second, 70 mm positive transparencies were replaced by large format images (64 cm), thereby improving the internal registration of the CRC image and the effective spatial resolution. The pattern of limonitic rocks depicted in the CRC closely agrees with the mapped pattern of the alteration zones at the Copper Canyon and Copper Basin porphyry copper deposits. Certain west-facing topographic slopes in the altered areas are depicted as unaltered in the CRC, apparently due to atmospheric scattering, and illustrate the need for atmospheric correction. The disseminated gold deposits at Gold Acres and Tenabo are poorly represented in the CRC because of the general absence of limonite on these deposits. The presence of unaltered limonitic sedimentary and volcanic rocks is the largest obstacle to discriminating altered areas within the mineral belt. Reflectance spectra, made in situ and in the laboratory indicate differences between altered and unaltered rocks in the Spectra region between 1.1 ?m and 2.5 ?m. Such differences may be detectable by a remote scanner with a longer wavelength range than current Landsat MSS (0.6 ?m-1.1 ?m).

Open-File Report↗
USGS1983

Streamflow and water-quality data for lake and wetland inflows and outflows in the Twin Cities metropolitan area, Minnesota, 1981-82

A study of runoff to selected lakes was done in the Twin Cities metropolitan area from July 1981 to December 1982. The purpose of the study was to determine differences in nutrient-loading characteristics for lakes with and without wetlands and settling ponds. The study also quantified nutrient loading to lakes on a storm, seasonal, and annual basis, complementing an inlake water-quality study of these lakes done by the Metropolitan Council. Discharge and water-quality data were collected periodically during 1981 and continuously during 1982 at 22 sites located in seven lake watersheds Bryant Lake, Lake Elmo, Fish Lake, Lake George, Lake Riley, Spring Lake, and Square Lake. Basin characteristics and land use were determined for each watershed. Recording instruments provided continuous discharge records at 14 sites and continuous rainfall records at six sites. Automatic water-quality samplers were used at lake inlets. The automatic samplers collected samples at 1- to 2-hour intervals during storms. Lake-outlet samples were collected manually on a weekly basis during flow. Samples were analyzed for suspended solids and nutrients. Atmospheric-input data were collected at eight sites from September 23 to November 1, 1982. Discharge and water-quality data were used to calculate storm, seasonal, and annual loads of total suspended solids, volatile suspended solids, total phosphorus, dissolved phosphorus, nitrite-plus-nitrate nitrogen, ammonia nitrogen, and ammonia-plus-organic nitrogen. All data collected during the study are documented in tables and graphs that contain (1) watershed characteristics and land use; (2) storm concentrations; (3) storm, seasonal, and annual loads; (4) storm hydrographs; (5) atmospheric-input concentrations and loads; (6) storm, seasonal, and annual precipitation totals; and (7) results of quality-assurance tests.

Minnesota↗
USGS1985

Data collected by the U.S. Geological Survey during a study of urban runoff in Bellevue, Washington, 1979-82

From October 1979 through January 1982 the U.S. Geological Survey conducted an urban-runoff study in Bellevue, Washington. The study, done in cooperation with the City of Bellevue, was part of the U.S. Environmental Protection Agency 's National Urban Runoff program. The objectives of the study were to (1) establish a consistent and accessible data base for typical urban watersheds; (2) determine the magnitude and frequency of storm-runoff loads of water-quality constituents from three catchments in the city; (3) develop methods for estimating storm and annual loads of water-quality constituents from unsampled catchments in the study area; and (4) test the effectiveness of storm-water-quality management alternatives, such as street sweeping and detention storage, for the attenuation of constituent loads carried in storm runoff. This report presents data collected during the study period. Data include rainfall and runoff amounts, physical characteristics of the catchments, the chemical quality of storm runoff and in wet- and dry-atmospheric deposition, constituent loads in storm runoff and in wet- and dry-atmospheric deposition, and storm characteristics data, such as rainfall and runoff volumes. (USGS)

Open-File Report↗
USGS1988

Hydrologic data for the Salt Bayou estuary near Sabine Pass, Texas, October 1984 to March 1986

The Salt Bayou estuary, located in extreme southeast Texas near Sabine Pass, has been altered by construction of the Gulf Intracoastal Waterway. The waterway has interrupted the historical saltwater-freshwater exchange in this important estuary. This alteration may have had a detrimental effect on fish production because of increased salinity, and on waterfowl production because of lower water levels. There have been proposals to develop water control structures in the major channels that would enable some regulation of the saltwater in order to restore the estuary to its approximate historic state. A cooperative effort was initiated by the Louisiana Cooperative Fish and Wildlife Research Unit, the U.S. Fish and Wildlife Service, the Texas Parks and Wildlife Department, and the U.S. Geological Survey to identify the fish species and their transport mechanisms. The U.S. Geological Survey's part of this effort was to describe the present hydrology of Salt Bayou. The purpose of this report is to present the hydrologic data that were collected during October 1984 through March 1986. The initial data-collection network consisted of stage gages at Keith Lake Pass, the mouth of Salt Bayou, Ten Mile Cut, the Intracoastal Waterway, and Star Lake. A stage gage at the Alligator Bayou pumping plant became available later in the study. After 6 months of data were collected, the Ten Mile Cut gage was moved to Wildcow Bayou. The gages at Keith Lake Pass, the mouth of Salt Bayou, Ten Mile Cut, and Wildcow Bayou were equipped with water-velocity recording equipment. The Keith Lake Pass gage also had temperature and specific-conductance recording equipment. Six 24-hour flow investigations were performed to calibrate the velocity recording equipment and to determine the flow at ungaged sites. Before and after these investigations, specific conductance was measured at 43 sites within the estuary. Precipitation data were obtained from National Oceanic and Atmospheric Administration stations at Port Arthur, Anahuac, and Sea Rim State Park and were used to estimate the contribution of freshwater from rainfall. Evaporation data were obtained from Beaumont Research Station and were used to make estimates of water consumption from evapotranspiration. Wind speed and direction were obtained from the National Oceanic and Atmospheric Administration weather station at Sea Rim State Park.

Open-File Report↗
USGS1993

Earthquake locations determined by the Southern Alaska seismograph network for October 1971 through May 1989

This report describes the instrumentation and evolution of the U.S. Geological Survey’s regional seismograph network in southern Alaska, provides phase and hypocenter data for seismic events from October 1971 through May 1989, reviews the location methods used, and discusses the completeness of the catalog and the accuracy of the computed hypocenters. Included are arrival time data for explosions detonated under the Trans-Alaska Crustal Transect (TACT) in 1984 and 1985. The U.S. Geological Survey (USGS) operated a regional network of seismographs in southern Alaska from 1971 to the mid 1990s. The principal purpose of this network was to record seismic data to be used to precisely locate earthquakes in the seismic zones of southern Alaska, delineate seismically active faults, assess seismic risks, document potential premonitory earthquake phenomena, investigate current tectonic deformation, and study the structure and physical properties of the crust and upper mantle. A task fundamental to all of these goals was the routine cataloging of parameters for earthquakes located within and adjacent to the seismograph network. The initial network of 10 stations, 7 around Cook Inlet and 3 near Valdez, was installed in 1971. In subsequent summers additions or modifications to the network were made. By the fall of 1973, 26 stations extended from western Cook Inlet to eastern Prince William Sound, and 4 stations were located to the east between Cordova and Yakutat. A year later 20 additional stations were installed. Thirteen of these were placed along the eastern Gulf of Alaska with support from the National Oceanic and Atmospheric Administration (NOAA) under the Outer Continental Shelf Environmental Assessment Program to investigate the seismicity of the outer continental shelf, a region of interest for oil exploration. Since then the region covered by the network remained relatively fixed while efforts were made to make the stations more reliable through improved electronic instrumentation and strengthened antenna systems. The majority of the stations installed since 1980 were operated only temporarily (from one to several years) for special studies in various areas within the network. Due to reduced funding, the network was trimmed substantially in the summer of 1985 with the closure of 15 stations, 13 of which were located in and around the Yakataga seismic gap. To further reduce costs, two telephone circuits were dropped and multiple radio relays were installed in their place. This economy reduced the reliability of these telemetry links. In addition, data collection from the areas around Cordova and Yakutat was compromised by the necessity of relying on triggered event recording using PC-based systems (Rogers, 1993) that were not fully developed and which proved to be less reliable than anticipated. The principal means of recording throughout the time period of this catalog was 20-channel oscillographs on 16-mm film (Teledyne Geotech Develocorder, Model RF400 and 4000D). Initially one Develocorder was operated at the USGS Alaskan headquarters in Anchorage, but in 1972 recording was shifted to the National Oceanic and Atmospheric Administration (NOAA) Palmer Observatory (currently the West Coast and Alaska Tsunami Warning Center). The Develocorders were turned off at the end of May 1989, and after that time recording was done in digital format at the Geophysical Institute of the University of Alaska in Fairbanks (GIUA). Thus, this catalog covers the entire period of film recording.

Alaska↗
USGS1995

Data on selected herbicides and two triazine metabolites in precipitation of the Midwestern and Northeastern United States, 1990-91

Weekly precipitation (rain and snow) samples were collected from 81 National Atmospheric Deposition Program/National Trends Network sites in the Midwestern and Northeastern United States for the analysis of herbicides. In addition, five high- elevation background sites along the Rocky Mountains and in Alaska were sampled to provide data on herbicides in precipitation at sites far from the study area. The study began in March 1990 and continued through September 1991. The precipitation samples were shipped to the Central Analytical Laboratory operated by the Illinois State Water Survey for analyses of inorganic compounds. Subsamples of the precipitation were shipped to the U.S. Geological Survey laboratory in Lawrence, Kansas, for the analysis of 11 herbicides and 2 triazines metabolites. This report provides descriptions of the study area, sample-collection methods, laboratory methods, and quality assurance. The report also includes a compilation of herbicide concentration data from both enzyme-linked immunosorbent assay and gas chromatography/mass spectrometry methods. Laboratory analyses consisted of 6,230 samples that were analyzed by enzyme-linked immunosorbent assay using alachlor and atrazine microtiter plates and 2,341 samples that were confirmed by gas chromatography/mass spectrometry analysis. Graphical and statistical comparisons of the two analytical methods are given in this report. Data from this study have been useful in determining the spatial and temporal distribution of herbicide concentrations and deposition in precipitation of over a 26-State area of the Midwestern and Northeastern United States. The data also provide evidence of long-range atmospheric transport of herbicides and triazine metabolites.

Open-File Report↗
USGS1997

Hydrologic and water-quality data, Guanella Pass area, Colorado, water year 1995

Water quality of streams and lakes in the Guanella Pass area could be affected by the proposed reconstruction of the existing road through the area. During water year 1995 (October 1, 1994, to September 30, 1995), data were collected that provide reconnaissance information about thehydrology, water quality, sediment transport, biology, and bulk atmospheric-deposition in the Guanella Pass study area. Data were collected at 5 stream monitoring stations, 23 synoptic-stream sites, 11 road-runoff sites, 8 ground-water sites, 4 lake/reservoir sites, 2 snow-precipitation sites, 11 biological sampling sites, and 12 bulk atmospheric- deposition sites.

Open-File Report↗
USGS1998

Surficial geology of Shaver Hollow, Shenandoah National Park

At the request of Shenandoah National Park and the Department of Environmental Sciences at the University of Virginia, the US Geological Survey has completed an examination and map of the surficial deposits in Shaver Hollow. The work was carried out as part of the US Geological Survey - National Park Service cooperative agreement implemented in 1994. Shaver Hollow is a small, well defined drainage basin on the west slope of the Blue Ridge about 6.5 miles south of Thornton Gap and can be reached by trail from mile 37.9 on the Skyline Drive. The hollow is drained by the North Fork of Dry Run, and the watershed within the Shenandoah National park is only 2 square miles in area. The area has been the site of extensive investigations by faculty and students at the University of Virginia and by NPS scientists and investigators studying the interaction of atmosphere chemistry, water composition, and the biota of the hollow (Furman and others, written communication, 1997). Modeling of the chemistry of Dry Run surface water, based on atmospheric, biologic, and geologic data, has been attempted with limited success. Better understanding of the surficial deposits and the interaction of streams and springs with near surface materials is needed before more sophisticated models can be devised. Although the bedrock lithology was mapped at a small scale (1:62,000-scale; Gathright, 1976) no examination of the surficial deposits of the hollow was made. The description of deposits contained herein is based on field observations carried out in September - November, 1996. Also included with this report is a 1/12,000-scale map of the surficial geology of Shaver Hollow (figure 1).

Virginia↗
USGS1999

Loch Vale Watershed Project quality assurance report, 1995-1998

The Loch Vale Watershed (LVWS) project was initiated in 1980 by the National Park Service with funding from the Aquatic Effects Research Program of the National Acid Precipitation Assessment Program. Initial research objectives were to understand the processes that would either mitigate or accelerate the effects of pollution on soil and surface water chemistry, and to build a record in which long-term trends could be identified and examined. It is important for all data collected in Loch Vale to meet the high standards of quality set forth in previous LVWS QA/QC reports and LVWS Methods Manuals. Given the ever-widening usage of data collected in Loch Vale, it is equally important to provide users of that data with a report assuring that all data are sound. Parameters covered in this report are the quality of meteorological measurements, hydrological measurements, surface water chemistry, and similarities in catch efficiency of two raingage types in Loch Vale for the period of 1995-1998. Routine sampling of weather conditions, precipitation chemistry, and stream/lake water chemistry began in 1982. Since then, all samples and data have been analyzed according to widely accepted and published methods. Weather data have been collected, analyzed, and stored by LVWS project personnel. Methods for the handling of meteorological data are well documented (Denning 1988, Edwards 1991, Newkirk 1995,and Allstott 1995). Precipitation chemistry has always been collected according to National Atmospheric Deposition Program protocol (Bigelow 1988), and analyzed at the Central Analytical Laboratory of the Illinois State Water Survey in Champaign, IL. QA/QC procedures of the National Atmospheric Deposition Program are well documented (Aubertin 1990). Protocols for sampling surface waters are also well documented (Newkirk 1995). Analysis of surface water chemistry has been performed using standard EPA protocol at the US Forest Service's Rocky Mt. Station Biogeochemistry Laboratory since 1993.

Open-File Report↗
USGS1986

Observations of the eruptions of July 22 and August 7, 1980, at Mount St. Helens, Washington

The explosive eruptions of July 22 and August 7, 1980, at Mount St. Helens, Wash., both included multiple eruptive pulses. The beginnings of three of the pulses-two on July 22 and one on August 7-were witnessed and photographed. Each of these three began with a fountain of gases and pyroclasts that collapsed around the vent and generated a pyroclastic density flow. Significant vertical-eruption columns developed only after the density flows were generated. This behavior is attributable to either an increase in the gas content of the eruption jet or a decrease in vent radius with time. An increase in the gas content may have occurred as the vent was cleared (by expulsion of a plug of pyroclasts) or as the eruption began to tap deeper, gas-rich magma after first expelling the upper, gas-depleted part of the magma body. An effective decrease of the vent radius with time may have occurred as the eruption originated from progressively deeper levels in the vent. All of these processes-vent clearing; tapping of deeper, gas-rich magma; and effective decrease in vent radius-probably operated to some extent. A 'relief-valve' mechanism is proposed here to account for the occurrence of multiple eruptive pulses. This mechanism requires that the conduit above the magma body be filled with a bed of pyroclasts, and that the vesiculation rate in the magma body be inadequate to sustain continuous eruption. During a repose interval, vesiculation of the magma body would cause gas to flow upward through the bed of pyroclasts. If the rate at which the magma produced gas exceeded the rate at which gas escaped to the atmosphere, the vertical pressure difference across the bed of pyroclastic debris would increase, as would the gas-flow rate. Eventually a gas-flow rate would be achieved that would suddenly diminish the ability of the bed to maintain a pressure difference between the magma body and the atmosphere. The bed of pyroclasts would then be expelled (that is, the relief valve would open) and an eruption would commence. During the eruption, gas would be lost faster than it could be replaced by vesiculation, so the gas-flow rate in the conduit would decrease. Eventually the gas-flow rate would decrease to a value that would be inadequate to expel pyroclasts, so the conduit would again become choked with pyroclasts (that is, the relief valve would close). Another period of repose would commence. The eruption/repose sequence would be repeated until gas-production rates were inadequate to reopen the valve, either because the depth of the pyroclast bed had become too great, the volatile content of the magma had become too low, or the magma had been expended. A timed sequence of photographs of a pyroclastic density flow on August 7 indicates that, in general, the velocity of the flow front was determined by the underlying topography. Observations and details of the velocity/topography relationship suggest that both pyroclastic flows and pyroclastic surges formed. The following mechanism is consistent with the data. During initial fountain collapse and when the flow passed over steep, irregular terrain, a highly inflated suspension of gases and pyroclasts formed. In this suspension, the pyroclasts underwent rapid differential settling according to size and density; a relatively low-concentration, fine-grained upper phase formed over a relatively high-concentration coarse-grained phase. The low-particle-concentration phase (the pyroclastic surge) was subject to lower internal friction than the basal high-concentration phase (the pyroclastic flow), and so accelerated away from it. The surge advanced until it had deposited so much of its solid fraction that its net density became less than that of the ambient air. At this point it rose convectively off the ground, quickly decelerated, and was overtaken by the pyroclastic flow. The behavior of the flow of August 7 suggests that a pyroclastic density flow probably expands through the ingestion of ai

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