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At least 1,441 records · Page 80Linked to original sources

USGS2017

Ecosystem vs. community recovery 25 years after grass invasions and fire in a subtropical woodland

Despite a large body of research documenting invasive plant impacts, few studies have followed individual invaded sites over decades to observe how they change, and none have contrasted how compositional impacts from invasion compare to ecosystem-process impacts over a multi-decadal time-scale. Using direct measurements of plant density and composition and of ecosystems processes, we evaluate how ecosystem structure, above-ground net primary production (ANPP), and above-ground and soil nutrient pools compare over 25 years since fire and C4 grass invasions disrupted seasonally dry Hawaiian woodlands. We compare structure and function between primary woodland that has never burned and is largely native species-dominated, with sites that had been the same woodland type but burned in alien-grass-fuelled fires in the 1970s and 1980s. The sites have not experienced fires since 1987. We report here that woody plant composition and structure continue to be dramatically changed by the initial invasions and fires that occurred 25 years ago and invaders continue to dominate in burned sites. This is reflected in continued low plant carbon pools in burned compared to unburned sites. Yet ANPP and N storage, which were dramatically lower in the initial decade after invasive-grass fuelled fires, have increased and are now indistinguishable from values measured in intact woodlands. Soil carbon pools were resilient to both invasion and fire initially and over time. Above-ground net primary production has recovered because of invasion of burned sites by a non-native N-fixing tree rather than because of recovery of native species. This invasive N-fixing tree is unlikely to return C storage of the invaded sites to those of unburned woodland because of its tissue and growth characteristics and its interactions with invasive grasses. It does not facilitate native species but rather promotes a persistent invasive grass/N-fixer savanna. Synthesis. We conclude that fire, an unusual disturbance in this system, has perpetuated the dominance of these sites by invasive species and that despite the dramatic recovery of above-ground net primary production and N pools, the ecosystem continues to be in a distinctly different state than the pre-fire, pre-Melinis community. Thus, despite the absence of further disturbance (fire), there is no evidence that succession towards the original ecosystem is occurring. The fact that N pools and above-ground net primary production recover because of a new invader (Morella faya), highlights the unpredictability of ecosystem trajectories in the face of altered regional species pools.

Hawaii↗

USGS2012

Future opportunities and challenges in remote sensing of drought

The value of satellite remote sensing for drought monitoring was first realized more than two decades ago with the application of Normalized Difference Index (NDVI) data from the Advanced Very High Resolution Radiometer (AVHRR) for assessing the effect of drought on vegetation. Other indices such as the Vegetation Health Index (VHI) were also developed during this time period, and applied to AVHRR NDVI and brightness temperature data for routine global monitoring of drought conditions. These early efforts demonstrated the unique perspective that global imagers such as AVHRR could provide for operational drought monitoring through their near-daily, global observations of Earth's land surface. However, the advancement of satellite remote sensing of drought was limited by the relatively few spectral bands of operational global sensors such as AVHRR, along with a relatively short period of observational record. Remote sensing advancements are of paramount importance given the increasing demand for tools that can provide accurate, timely, and integrated information on drought conditions to facilitate proactive decision making (NIDIS, 2007). Satellite-based approaches are key to addressing significant gaps in the spatial and temporal coverage of current surface station instrument networks providing key moisture observations (e.g., rainfall, snow, soil moisture, ground water, and ET) over the United States and globally (NIDIS, 2007). Improved monitoring capabilities will be particularly important given increases in spatial extent, intensity, and duration of drought events observed in some regions of the world, as reported in the International Panel on Climate Change (IPCC) report (IPCC, 2007). The risk of drought is anticipated to further increase in some regions in response to climatic changes in the hydrologic cycle related to evaporation, precipitation, air temperature, and snow cover (Burke et al., 2006; IPCC, 2007; USGCRP, 2009). Numerous national, regional, and global efforts such as the Famine and Early Warning System (FEWS), National Integrated Drought Information System (NIDIS), and Group on Earth Observations (GEO), as well as the establishment of regional drought centers (e.g., European Drought Observatory) and geospatial visualization and monitoring systems (e.g, NASA SERVIR) have been undertaken to improve drought monitoring and early warning systems throughout the world. The suite of innovative remote sensing tools that have recently emerged will be looked upon to fill important data and knowledge gaps (NIDIS, 2007; NRC, 2007) to address a wide range of drought-related issues including food security, water scarcity, and human health.

Book chapter↗

USGS1998

Land cover mapping of the National Park Service northwest Alaska management area using Landsat multispectral and thematic mapper satellite data

A land cover map of the National Park Service northwest Alaska management area was produced using digitally processed Landsat data. These and other environmental data were incorporated into a geographic information system to provide baseline information about the nature and extent of resources present in this northwest Alaskan environment. This report details the methodology, depicts vegetation profiles of the surrounding landscape, and describes the different vegetation types mapped. Portions of nine Landsat satellite (multispectral scanner and thematic mapper) scenes were used to produce a land cover map of the Cape Krusenstern National Monument and Noatak National Preserve and to update an existing land cover map of Kobuk Valley National Park Valley National Park. A Bayesian multivariate classifier was applied to the multispectral data sets, followed by the application of ancillary data (elevation, slope, aspect, soils, watersheds, and geology) to enhance the spectral separation of classes into more meaningful vegetation types. The resulting land cover map contains six major land cover categories (forest, shrub, herbaceous, sparse/barren, water, other) and 19 subclasses encompassing 7 million hectares. General narratives of the distribution of the subclasses throughout the project area are given along with vegetation profiles showing common relationships between topographic gradients and vegetation communities.

Open-File Report↗

USGS2023

Simulating groundwater flow in the Mississippi Alluvial Plain with a focus on the Mississippi Delta

The Mississippi Alluvial Plain has become one of the most important agricultural regions in the United States but relies heavily on groundwater for irrigation. On average, more than 12 billion gallons are withdrawn daily from the Mississippi River Valley alluvial aquifer. Declining groundwater levels, especially in the Delta region of northwest Mississippi and the Cache and Grand Prairie regions of eastern Arkansas, have led to concerns about future sustainability. The U.S. Geological Survey Mississippi Alluvial Plain Project is focused on quantifying the groundwater system in the alluvial plain and the response of groundwater resources to future development. A key objective of the project is to provide updated groundwater flow models supported by extensive data collection and analyses. MODFLOW 6, PEST++, and several open-source python packages were used to develop a simplified, faster running version of the Mississippi Embayment Regional Aquifer Study model that can provide boundary conditions for local inset models, including the Mississippi Delta model described in this report. An automated workflow was used for model construction, history matching, and development of baseline future climate scenarios. The models incorporate information from a Soil-Water-Balance code simulation of the terrestrial water balance, metering-based estimates of water use from thousands of wells, measured and estimated streamflow and stages, and the largest airborne electromagnetic survey flown to date in the United States. Baseline scenarios for the Mississippi Delta under potential future climates were constructed using recharge, surface runoff and irrigation pumping forcings from a future version of the Soil-Water-Balance model, driven by downscaled temperature and precipitation output from 10 general circulation model simulations, including high and moderate carbon emissions pathways. Results indicate a complex water balance that varies in time and space in terms of the terrestrial recharge, stream leakage, and regional groundwater flow components, which are affected by seasonal forcings, human activity, and alluvial geomorphology. The general circulation model outputs indicate a continued rise in average temperatures but no clear precipitation trend. Increased crop water demand is anticipated from the higher temperatures, resulting in increased irrigation withdrawals to sustain current levels of irrigated agriculture. Simulated drawdowns in groundwater levels at the mid-21st century vary greatly. Under moderate or wet climate scenarios, and in parts of the aquifer that are well connected to surface water, little to no additional drawdown is anticipated. Under dry or warm scenarios, drawdowns of as much as 10 meters or more are possible in parts of the aquifer that are relatively disconnected from surface water. Under dry or warm scenarios, the portion of the Delta with greater than 60 feet of saturated thickness could be reduced from near 100 percent currently (2018) to 80–90 percent by mid-century. Future simulations with the model could include alternative management scenarios to identify options for improving groundwater sustainability. The automated model construction workflows are designed to facilitate regular updating, making this a “living” framework that the Mississippi Department of Environmental Quality and other stakeholders can use for adaptive management going forward.

Arkansas, Louisiana, Mississippi↗

USGS2021

In-situ monitoring of infiltration-induced instability of I-70 embankment west of the Eisenhower-Johnson Memorial Tunnels, phase III

A new methodology that uses recent advances in unsaturated soil mechanics and hydrology was developed and tested. The approach consists of using soil suction and moisture content field information in the prediction of the likelihood of landslide movement. The testing ground was an active landslide on I-70 west of the Eisenhower/Johnson Memorial Tunnels. A joint effort between Colorado School of Mines, CDOT, and USGS performed detailed site characterization, set up and calibrated a hydro-mechanical model of the site based on seven years of field data, and performed a stability analysis of the slope. Results indicate that consecutive years of high or low infiltration have a compounding effect so that the slope stability is influenced by the preceding years. Additionally, a new drainage system is proposed based on analysis of the current horizontal drains.

Colorado↗

USGS2024

Suspended sediment and trace element transport in the Big River downstream from the Old Lead Belt in southeastern Missouri, 2018–21

Lead Belt, an area of major lead mining from the 1860s until 1972 where more than 8.5 million tons of lead were mined. After active mining ceased, the effects of mining activities persisted in the Big River system because of large mine waste pile erosion, and floodplain sediment and streambank contamination along several tributaries and the main stem of the Big River. Lead-contaminated streambed and floodplain sediments extend more than 90 miles from the Old Lead Belt to the confluence of the Big River with the Meramec River. The waste piles and mine-waste contaminated streambed and floodplain sediments have been sources of high concentrations of several trace elements, primarily cadmium, lead, and zinc. The U.S. Environmental Protection Agency Region 7 has made several efforts to prevent further erosion of contaminated sediments into the Big River including the capping of major mine waste piles, reclaiming sediment deposits along the floodplains, and monitoring soil conditions of croplands and residential properties. A cooperative effort began in 2011 between the U.S. Geological Survey and the U.S. Environmental Protection Agency Region 7 to characterize suspended sediment quantity and quality in the Big River downstream from the Old Lead Belt as reclamation activities in the drainage basin progressed. The study was completed in two phases, and each phase included continuous stage, turbidity, and water temperature monitoring at the Big River below Bonne Terre, Missouri, streamgage and sampling station. Periodic suspended sediment samples also were collected manually (discrete samples) during base flow and selected stormflow events. Continuous streamflow, turbidity, and discrete suspended sediment data were used to develop regression models to compute daily suspended sediment concentrations and loads. During both phases, the discrete stormflow event samples were also evaluated to determine particle size distribution and concentrations of select trace elements. Phase one was completed from October 2011 through September 2013, and phase two, which is the primary focus of this report, was completed from October 2018 through September 2021. Phase two also included time-integrated suspended sediment samples collected using passive samplers. Discrete samples (collected during stormflow events) and passive samples were analyzed for concentrations of barium, cadmium, lead, and zinc in two sediment size fractions (when possible) to estimate trace element loads. Suspended sediment concentrations and loads and select trace element concentration results computed during phase one were compared to those computed during phase two to identify trends in the Big River Basin during the full study period. The concentrations of cadmium, lead, and zinc in nearly all discrete stormflow event suspended sediment samples and passive suspended sediment samples exceeded the threshold effect concentrations and the probable effect concentrations, which are two sediment quality guidelines. Most samples also exceeded the toxic effect threshold, the level at which sediment is considered to be heavily contaminated and problematic for sediment-dwelling organisms. Bulk cadmium concentrations (median of 7.90 milligrams per kilogram [mg/kg]) exceeded the toxic effect threshold (3.0 mg/kg) in 17 discrete stormflow event samples, and bulk lead concentrations (median of 1,070 mg/kg) exceeded the toxic effect threshold (170 mg/kg) in all 18 discrete stormflow event samples. Bulk zinc concentrations (median of 500 mg/kg) exceeded the toxic effect threshold (540 mg/kg) in eight discrete stormflow event samples. Bulk concentrations of these trace elements in passive suspended sediment samples were slightly greater, with concentrations of cadmium (median of 14.0 mg/kg) and lead (median of 1,860 mg/kg) exceeding the toxic effect threshold in all 18 samples. Bulk concentrations of zinc (median of 733 mg/kg) exceeded the toxic effect threshold in 15 passive samples. Compared to phase one (water years 2012–13), phase two (water years 2019–21) concentrations of lead and cadmium in the fine fraction of discrete suspended sediment samples collected at Big River below Bonne Terre were statistically similar; concentrations of barium and zinc were statistically smaller in samples collected during phase two (water years 2018–21). Sediment quality data from passive samples and daily mean suspended sediment loads from the regression model were used to calculate annual oads of barium, cadmium, lead, and zinc at the Bonne Terre streamgage. Water year 2019 had the largest loads of barium, cadmium, lead, and zinc (58.6, 1.43, 194, and 76.5 tons, respectively). The total loads of barium, cadmium, lead, and zinc for phase two (water years 2019–21) were 149, 4.00, 520, and 213 tons, respectively. Less than 5 percent of the total lead load calculated for the study period was transported when daily mean streamflow was less than 455 cubic feet per second, which is the approximate flow at which the passive samplers were inundated and began sampling. This highlights that most of the lead load is transported during stormflow events and the effectiveness of using passive samplers for ongoing monitoring of the Big River. Annual suspended sediment loads at the Bonne Terre streamgage computed using the regression model were 113,000 tons in water year 2019, 83,400 tons in water year 2020, and 96,500 tons in water year 2021. The event-based suspended sediment loads for the eight sampled stormflow events ranged from 45.3 to 32,500 tons. Although only a portion of all stormflow events during phase two were sampled, the loads accounted for during these eight stormflow events represented approximately 30.9 percent of the total suspended sediment load calculated for the study period, confirming that a large part of suspended sediments continue to be transported in the Big River during stormflow events. Event-based loads of barium, cadmium, lead, and zinc were greatest during the stormflow events sampled in January 2020 (event 4) and March 2021 (event 8). Event-based loads calculated for event 4 for barium, cadmium, lead, and zinc were 17.1, 0.206, 27.2, and 14.5 tons, respectively. During event 8, an estimated 15.6 tons of barium, 0.239 tons of cadmium, 34.0 tons of lead, and 13.6 tons of zinc were transported in suspended sediments. The continued high concentrations of lead in suspended sediments in the Big River, despite reclamation activities, is likely because of the continual transport from streambed and stream banks of lead-enriched sediment, which remain in the system from historical mining activities.

Missouri↗

USGS2020

Making ‘chemical cocktails’ – Evolution of urban geochemical processes across the periodic table of elements

Urbanization contributes to the formation of novel elemental combinations and signatures in terrestrial and aquatic watersheds, also known as ‘chemical cocktails.’ The composition of chemical cocktails evolves across space and time due to: (1) elevated concentrations from anthropogenic sources, (2) accelerated weathering and corrosion of the built environment, (3) increased drainage density and intensification of urban water conveyance systems, and (4) enhanced rates of geochemical transformations due to changes in temperature, ionic strength, pH, and redox potentials. Characterizing chemical cocktails and underlying geochemical processes is necessary for: (1) tracking pollution sources using complex chemical mixtures instead of individual elements or compounds; (2) developing new strategies for co-managing groups of contaminants; (3) identifying proxies for predicting transport of chemical mixtures using continuous sensor data; and (4) determining whether interactive effects of chemical cocktails produce ecosystem-scale impacts greater than the sum of individual chemical stressors. First, we discuss some unique urban geochemical processes which form chemical cocktails, such as urban soil formation, human-accelerated weathering, urban acidification-alkalinization, and Freshwater Salinization Syndrome. Second, we review and synthesize global patterns in concentrations of major ions, carbon and nutrients, and trace elements in urban streams across different world regions and make comparisons with reference conditions. In addition to our global analysis, we highlight examples from watersheds in the Baltimore-Washington DC area, USA, which show increased transport of major ions, trace metals, and nutrients across streams draining a well-defined land-use gradient. Urbanization increased the concentrations of multiple major and trace elements in streams draining human-dominated watersheds compared to reference conditions. Chemical cocktails of major and trace elements were formed over diurnal cycles coinciding with changes in streamflow, dissolved oxygen, pH, and other variables measured by high-frequency sensors. Some chemical cocktails of major and trace elements were also significantly related to specific conductance (p < 0.05), which can be measured by sensors. Concentrations of major and trace elements increased, peaked, or decreased longitudinally along streams as watershed urbanization increased, which is consistent with distinct shifts in chemical mixtures upstream and downstream of other major cities in the world. Our global analysis of urban streams shows that concentrations of multiple elements along the periodic table significantly increase when compared with reference conditions. Furthermore, similar biogeochemical patterns and processes can be grouped among distinct mixtures of elements of major ions, dissolved organic matter, nutrients, and trace elements as chemical cocktails. Chemical cocktails form in urban waters over diurnal cycles, decades, and throughout drainage basins. We conclude our global review and synthesis by proposing strategies for monitoring and managing chemical cocktails using source control, ecosystem restoration, and green infrastructure. We discuss future research directions applying the watershed chemical cocktail approach to diagnose and manage environmental problems. Ultimately, a chemical cocktail approach targeting sources, transport, and transformations of different and distinct elemental combinations is beneficial to more holistically monitor and manage the emerging impacts of chemical mixtures in the world's fresh waters.

Applied Geochemistry↗

USGS2010

Theoretical analysis of the transient pressure response from a constant flow rate hydraulic conductivity test

Incorporating a flow pump into a conventional triaxial laboratory system allows fluid to be supplied to or withdrawn from the base of a sediment sample at small and constant rates. An initial transient record of hydraulic head versus time is observed which eventually stabilizes to a constant steady state gradient across the sample; values of hydraulic conductivity can subsequently be determined from Darcy's law. In this paper, analytical methods are presented for determining values of specific storage and hydraulic conductivity from the initial transient phase of such a constant flow rate test. These methods are based on a diffusion equation involving pore pressure and are analogous to those used to describe the soil consolidation process and also to interpret aquifer properties from pumping tests. Examination of the effective stress distributions within the test specimen induced during this type of measurement shows that values of specific storage corresponding to both compression and rebound conditions can be deduced and differentiated simply by reversing the direction of fluid flow. Applicability and limitations of the methods are illustrated with analyses of recently reported flow pump test measurements conducted on a silty-clay specimen.

Water Resources Research↗

USGS2004

Evaluation of multidimensional transport through a field-scale compacted soil liner

A field-scale compacted soil liner was constructed at the University of Illinois at Urbana-Champaign by the U.S. Environmental Protection Agency (USEPA) and Illinois State Geological Survey in 1988 to investigate chemical transport rates through low permeability compacted clay liners (CCLs). Four tracers (bromide and three benzoic acid tracers) were each added to one of four large ring infiltrometers (LRIs) while tritium was added to the pond water (excluding the infiltrometers). Results from the long-term transport of Br - "> Br - from the localized source zone of LRI are presented in this paper. Core samples were taken radially outward from the center of the Br - "> Br - LRI and concentration depth profiles were obtained. Transport properties were evaluated using an axially symmetric transport model. Results indicate that (1) transport was diffusion controlled; (2) transport due to advection was negligible and well within the regulatory limits of k sat ⩽ 1 × 10 - 7 cm / s ; "> k sat ⩽ 1 × 10 − 7 cm / s; (3) diffusion rates in the horizontal and vertical directions were the same; and (4) small positioning errors due to compression during soil sampling did not affect the best fit advection and diffusion values. The best-fit diffusion coefficient for bromide was equal to the molecular diffusion coefficient multiplied by a tortuosity factor of 0.27, which is within 8% of the tortuosity factor (0.25) found in a related study where tritium transport through the same liner was evaluated. This suggests that the governing mechanisms for the transport of tritium and bromide through the CCL were similar. These results are significant because they address transport through a composite liner from a localized source zone which occurs when defects or punctures in the geomembrane of a composite system are present.

Journal of Geotechnical and Geoenvironmental Engin↗

USGS2016

Mapping rice-fallow cropland areas for short-season grain legumes intensification in South Asia using MODIS 250 m time-series data

The goal of this study was to map rainfed and irrigated rice-fallow cropland areas across South Asia, using MODIS 250 m time-series data and identify where the farming system may be intensified by the inclusion of a short-season crop during the fallow period. Rice-fallow cropland areas are those areas where rice is grown during the kharif growing season (June–October), followed by a fallow during the rabi season (November–February). These cropland areas are not suitable for growing rabi -season rice due to their high water needs, but are suitable for a short -season (≤3 months), low water-consuming grain legumes such as chickpea ( Cicer arietinum L.), black gram, green gram, and lentils. Intensification (double-cropping) in this manner can improve smallholder farmer’s incomes and soil health via rich nitrogen-fixation legume crops as well as address food security challenges of ballooning populations without having to expand croplands. Several grain legumes, primarily chickpea, are increasingly grown across Asia as a source of income for smallholder farmers and at the same time providing rich and cheap source of protein that can improve the nutritional quality of diets in the region. The suitability of rainfed and irrigated rice-fallow croplands for grain legume cultivation across South Asia were defined by these identifiers: (a) rice crop is grown during the primary ( kharif ) crop growing season or during the north-west monsoon season (June–October); (b) same croplands are left fallow during the second ( rabi ) season or during the south-east monsoon season (November–February); and (c) ability to support low water-consuming, short-growing season (≤3 months) grain legumes (chickpea, black gram, green gram, and lentils) during rabi season. Existing irrigated or rainfed crops such as rice or wheat that were grown during kharif were not considered suitable for growing during the rabi season, because the moisture/water demand of these crops is too high. The study established cropland classes based on the every 16-day 250 m normalized difference vegetation index (NDVI) time series for one year (June 2010–May 2011) of Moderate Resolution Imaging Spectroradiometer (MODIS) data, using spectral matching techniques (SMTs), and extensive field knowledge. Map accuracy was evaluated based on independent ground survey data as well as compared with available sub-national level statistics. The producers’ and users’ accuracies of the cropland fallow classes were between 75% and 82%. The overall accuracy and the kappa coefficient estimated for rice classes were 82% and 0.79, respectively. The analysis estimated approximately 22.3 Mha of suitable rice-fallow areas in South Asia, with 88.3% in India, 0.5% in Pakistan, 1.1% in Sri Lanka, 8.7% in Bangladesh, 1.4% in Nepal, and 0.02% in Bhutan. Decision-makers can target these areas for sustainable intensification of short-duration grain legumes.

International Journal of Digital Earth↗

USGS2016

Perchlorate and selected metals in water and soil within Mount Rushmore National Memorial, South Dakota, 2011–15

Mount Rushmore National Memorial is located in the east-central part of the Black Hills area of South Dakota and is challenged to provide drinking water to about 3 million annual visitors and year-round park personnel. An environmental concern to water resources within Mount Rushmore National Memorial has been the annual aerial fireworks display at the memorial for the Independence Day holiday during 1998–2009. A major concern of park management is the contamination of groundwater and surface water by perchlorate, which is used as an oxidizing agent in firework displays. A study by the U.S. Geological Survey, in cooperation with the National Park Service, was completed to characterize the occurrence of perchlorate and selected metals (constituents commonly associated with fireworks) in groundwater and surface water within and adjacent to Mount Rushmore National Memorial during 2011–15. Concentrations of perchlorate and metals in 106 water samples (collected from 6 groundwater sites and 14 surface-water sites) and 11 soil samples (collected from 11 soil sites) are reported. Within the Mount Rushmore National Memorial boundary, perchlorate concentrations were greatest in the Lafferty Gulch drainage basin, ranging from less than 0.20 to 38 micrograms per liter (μg/L) in groundwater samples and from 2.2 to 54 μg/L in surface-water samples. Sites within the Starling Gulch drainage basin also had some evidence of perchlorate contamination, with concentrations ranging from 0.61 to 19 μg/L. All groundwater and surface-water samples within the unnamed tributary to Grizzly Bear Creek drainage basin and reference sites outside the park boundary had concentrations less than 0.20 μg/L. Perchlorate concentrations in samples collected at the 200-foot-deep production well (Well 1) ranged from 17 to 38 μg/L with a median of 23 μg/L, whereas perchlorate concentrations in samples from the 500-foot-deep production well (Well 2) ranged from 2.1 to 17 μg/L, with a median of 6.1 μg/L. Perchlorate concentrations in samples of the treated groundwater were similar to the concentrations from Well 1, which was the predominant source of the water supply at Mount Rushmore National Memorial during the study period (2011–15). Springflow upstream from the production wells in the West Fork Lafferty Gulch drainage had the greatest perchlorate concentrations, ranging from 21 to 54 μg/L. The groundwater site within Lafferty Gulch drainage basin but downstream from the park boundary also had a perchlorate concentration less than 0.20 μg/L in the one sample collected at the site. Water samples collected at reference sites generally had concentrations of metals within the same range of those sites within the Mount Rushmore National Memorial boundary, presenting little evidence of metal contamination due to anthropogenic factors within the park boundary. Soil samples were collected near most water sampling sites and within the Hall of Records Canyon where fireworks were launched. Perchlorate concentrations in soil were greatest in the West Fork Lafferty Gulch drainage and Hall of Records Canyon, which are topographically higher than the two groundwater wells. The perchlorate concentrations in groundwater and surface water within Lafferty Gulch drainage basin during 2011–15 were greater than the U.S. Environmental Protection Agency’s Interim Drinking Water Health Advisory benchmark of 15 μg/L. The perchlorate concentrations in the Mount Rushmore water supply relative to this benchmark are of concern; however, this health advisory is based on the assumption that consumers are using the supply as their primary water source and currently is not a regulated standard. The groundwater system at West Fork Lafferty Gulch is highly susceptible to contamination by way of recharge and is isolated from downstream movement by an intrusive body acting as a dam, which may explain why a contamination problem is not likely to disappear or disperse, as could happen in larger aquifer systems. The observed deposition of firework debris within Lafferty Gulch drainage basin coupled with the lack of alternative perchlorate sources indicates that past firework displays are the most probable source of perchlorate contamination.

South Dakota↗

USGS1999

Quantity and quality of seepage from two earthen basins used to store livestock waste in southern Minnesota during the first year of operation, 1997-98

Numerous earthen basins have been constructed in Minnesota for storage of livestock waste. Typically, these basins are excavated pits with partially above-grade, earth-walled embankments and compacted clay liners. Some have drain tile installed around them to prevent shallow ground and soil water to discharge into the basins. Environmental concerns associated with the waste include contamination of ground water by nitrogen compounds and pathogens. The U.S. Geological Survey, in cooperation with the MFC A (Minnesota Pollution Control Agency), studied the quantity and quality of seepage from two earthen basins used to store livestock waste in southern Minnesota during the first year of operation. One basin (site A), located at a small dairy farm, holds a manuresilage mixture, milkhouse wastewater, and local runoff; the other basin (site B), located at a large hog farm, holds a manure-water mixture from a nearby gestation barn. Monitoring systems were installed below compacted clay liners in portions of the sidewalls and bottoms of the basins to determine the quantity and quality of the seepage. Total seepage flow from the site A basin ranged from about 900 to 2,400 gal/d (gallons per day) except during April 1998 when the flow increased to about 4,200 gal/d. Seepage flow in areal units, which closely correlated with flow in gal/d, generally ranged from about 0.07 to 0.18 in./d (inches per day), which exceeded the recommended maximum design rate of 0.018 in./d established by the MPCA. Seepage flow commonly was greater through the sidewalls than through the bottom. Seepage from the site A basin (based on 11 samples each from the bottom and sidewall) had chloride concentrations of 220-350 mg/L (milligrams per liter); ammonium-N (nitrogen) concentrations of 2.40 mg/L or less (except for one concentration of 18.4 mg/L); nitrate-N concentrations of 5.24 mg/L or less; and organic-N concentrations of 6.97 mg/L or less. Ground water would be enriched in chloride and diluted in inorganic-N from mixing with basin seepage. Fecal Coliform bacteria, although abundant in the basin wastewater, were present in very small amounts in the seepage. Total seepage flow from the site B basin generally ranged from 400 to 2,200 gal/d except during 1-month and 3-month periods when the flow ranged from about 3,800 to 6,200 gal/d. Seepage flow in areal units generally ranged from about 0.025 to 0.15 in./d, and, as at the site A basin, exceeded the MPCA recommended maximum design rate of 0.018 in./d. Seepage flow in areal units generally correlated with the flow in gal/d except through the sidewalls when the basin was unfilled. Except during the first three months of the study, seepage flow was greater through the sidewalls than through the bottom. Seepage from the site B basin (based on 10 samples each from the bottom and sidewall) had chloride concentrations of 11 to 100 mg/L; ammonium-N concentrations of 2.58 mg/L or less; nitrate-N concentrations of 25.7 mg/L or less (except for one concentration of 146 mg/L); and organic-N concentrations of 0.92 mg/L or less. Nitrate-N concentrations in the seepage exceeded the U.S. Environmental Protection Agency (1996). MCL (maximum contaminant level) of 10 mg/L in 17 of 22 samples. Background ground-water quality, however, indicated that nitrate-N concentrations were greater than the MCL prior to operation of the basin. Fecal Coliform bacteria, as at the site A basin, were abundant in the basin wastewater, but not in the seepage.

Minnesota↗

USGS1999

Characterizing hydrology and the importance of ground-water discharge in natural and constructed wetlands

Although considered the most important component for the establishment and persistence of wetlands, hydrology has been hard to characterize and linkages between hydrology and other environmental conditions are often poorly understood. In this work, methods for characterizing a wetland’s hydrology from hydrographs were developed, and the importance of ground water to the physical and geochemical conditions in the root zone was investigated. Detailed sampling of nearly continuous hydrographs showed that sites with greater ground-water discharge had higher water tables and more stable hydrographs. Subsampling of the continuous hydrograph failed to characterize the sites correctly, even though the wetland complex is located in a strong regional ground-water-discharge area. By comparing soil-moisture-potential measurements to the water-table hydrograph at one site, we noted that the amount of root-zone saturation was not necessarily driven by the water-table hydrograph but can be a result of other soil parameters (i.e., soil texture and associated capillary fringe). Ground-water discharge was not a significant determinant of maximum or average temperatures in the root zone. High ground-water discharge was associated with earliest date of thaw and shortest period of time that the root zone was frozen, however. Finally, the direction and magnitude of shallow ground-water flow was found to affect the migration and importance of a geochemical species. Areas of higher ground-water discharge had less downward penetration of CO 2 generated in the root zone. In contrast, biotically derived CO 2 was able to penetrate the deeper ground-water system in areas of ground-water recharge. Although ground-water flows are difficult to characterize, understanding these components is critical to the success of wetland restoration and creation efforts.

Wisconsin↗

USGS2004

Geochemistry of shallow ground water in coastal plain environments in the southeastern United States: Implications for aquifer susceptibility

Ground-water chemistry data from coastal plain environments have been examined to determine the geochemical conditions and processes that occur in these areas and assess their implications for aquifer susceptibility. Two distinct geochemical environments were studied to represent a range of conditions: an inner coastal plain setting having more well-drained soils and lower organic carbon (C) content and an outer coastal plain environment that has more poorly drained soils and high organic C content. Higher concentrations of most major ions and dissolved inorganic and organic C in the outer coastal plain setting indicate a greater degree of mineral dissolution and organic matter oxidation. Accordingly, outer coastal plain waters are more reducing than inner coastal plain waters. Low dissolved oxygen (O2) and nitrate (NO 3-) concentrations and high iron (Fe) concentrations indicate that ferric iron (Fe (III)) is an important electron acceptor in this setting, while dissolved O2 is the most common terminal electron acceptor in the inner coastal plain setting. The presence of a wide range of redox conditions in the shallow aquifer system examined here underscores the importance of providing a detailed geochemical characterization of ground water when assessing the intrinsic susceptibility of coastal plain settings. The greater prevalence of aerobic conditions in the inner coastal plain setting makes this region more susceptible to contamination by constituents that are more stable under these conditions and is consistent with the significantly (p<0.05) higher concentrations of NO3- found in this setting. Herbicides and their transformation products were frequently detected (36% of wells sampled), however concentrations were typically low (<0.1 ??g/L). Shallow water table depths often found in coastal plain settings may result in an increased risk of the detection of pesticides (e.g., alachlor) that degrade rapidly in the unsaturated zone.

Applied Geochemistry↗

USGS2002

Impacts of swine manure pits on groundwater quality

Manure deep-pits are commonly used to store manure at confined animal feeding operations. However, previous to this study little information had been collected on the impacts of deep-pits on groundwater quality to provide science-based guidance in formulating regulations and waste management strategies that address risks to human health and the environment. Groundwater quality has been monitored since January 1999 at two hog finishing facilities in Illinois that use deep-pit systems for manure storage. Groundwater samples were collected on a monthly basis and analyzed for inorganic and bacteriological constituent concentrations. The two sites are located in areas with geologic environments representing different vulnerabilities for local groundwater contamination. One site is underlain by more than 6 m of clayey silt, and 7-36 m of shale. Concentrations of chloride, ammonium, phosphate, and potassium indicated that local groundwater quality had not been significantly impacted by pit leakage from this facility. Nitrate concentrations were elevated near the pit, often exceeding the 10 mg N/l drinking water standard. Isotopic nitrate signatures suggested that the nitrate was likely derived from soil organic matter and fertilizer applied to adjacent crop fields. At the other site, sandstone is located 4.6-6.1 m below land surface. Chloride concentrations and ??15N and ??18O values of dissolved nitrate indicated that this facility may have limited and localized impacts on groundwater. Other constituents, including ammonia, potassium, phosphate, and sodium were generally at or less than background concentrations. Trace- and heavy-metal concentrations in groundwater samples collected from both facilities were at concentrations less than drinking water standards. The concentration of inorganic constituents in the groundwater would not likely impact human health. Fecal streptococcus bacteria were detected at least once in groundwater from all monitoring wells at both sites. Fecal streptococcus was more common and at greater concentrations than fecal coliform. The microbiological data suggest that filtration of bacteria by soils may not be as effective as commonly assumed. The presence of fecal bacteria in the shallow groundwater may pose a significant threat to human health if the ground water is used for drinking. Both facilities are less than 4 years old and the short-term impacts of these manure storage facilities on groundwater quality have been limited. Continued monitoring of these facilities will determine if they have a long-term impact on groundwater resources. ?? 2002 Elsevier Science Ltd. All rights reserved.

Environmental Pollution↗

USGS2010

Volcanogenic uranium deposits: Geology, geochemical processes, and criteria for resource assessment

Felsic volcanic rocks have long been considered a primary source of uranium for many kinds of uranium deposits, but volcanogenic uranium deposits themselves have generally not been important resources. Until the past few years, resource summaries for the United States or the world generally include volcanogenic in the broad category of "other deposits" because they comprised less than 0.5 percent of past production or estimated resources. Exploration in the United States from the 1940s through 1982 discovered hundreds of prospects in volcanic rocks, of which fewer than 20 had some recorded production. Intensive exploration in the late 1970s found some large deposits, but low grades (less than about 0.10 percent U 3 O 8 ) discouraged economic development. A few deposits in the world, drilled in the 1980s and 1990s, are now known to contain large resources (>20,000 tonnes U 3 O 8 ). However, research on ore-forming processes and exploration for volcanogenic deposits has lagged behind other kinds of uranium deposits and has not utilized advances in understanding of geology, geochemistry, and paleohydrology of ore deposits in general and epithermal deposits in particular. This review outlines new ways to explore and assess for volcanogenic deposits, using new concepts of convection, fluid mixing, and high heat flow to mobilize uranium from volcanic source rocks and form deposits that are postulated to be large. Much can also be learned from studies of epithermal metal deposits, such as the important roles of extensional tectonics, bimodal volcanism, and fracture-flow systems related to resurgent calderas. Regional resource assessment is helped by genetic concepts, but hampered by limited information on frontier areas and undiscovered districts. Diagnostic data used to define ore deposit genesis, such as stable isotopic data, are rarely available for frontier areas. A volcanic environment classification, with three classes (proximal, distal, and pre-volcanic structures), permits use of geologic features on 1:500,000 to 1:100,000 scale maps. Geochemical databases for volcanic rocks are postulated to be more effective than databases for stream sediments or surface radioactivity, both of which tend to be inconsistent because of variable leaching of uranium from soils. Based on empirical associations, spatial associations with areas of wet paleoclimate, adjacent oil and gas fields, or evaporite beds are deemed positive. Most difficult to estimate is the location of depositional traps and reduction zones, in part because they are mere points at regional scale. Grade and tonnage data are reviewed and discussed for 32 deposits in the world. Experience of mining engineers and geologists in Asia suggests that tonnages could be higher than presently known in the Western Hemisphere. Geological analysis, and new data from Asia, suggest a typical or median deposit tonnage of about 5,000 tonnes U 3 O 8 , and an optimistic forecast of discoveries in the range of 5,000 to 20,000 tonnes U 3 O 8 . The likely grade of undiscovered deposits could be about 0.15 percent U 3 O 8 , based on both western and eastern examples. Volcanic terrane is under-explored, relative to other kinds of uranium deposits, and is considered a favorable frontier area for new discoveries.

Open-File Report↗

USGS2013

Numerical simulation of groundwater and surface-water interactions in the Big River Management Area, central Rhode Island

The Rhode Island Water Resources Board is considering use of groundwater resources from the Big River Management Area in central Rhode Island because increasing water demands in Rhode Island may exceed the capacity of current sources. Previous water-resources investigations in this glacially derived, valley-fill aquifer system have focused primarily on the effects of potential groundwater-pumping scenarios on streamflow depletion; however, the effects of groundwater withdrawals on wetlands have not been assessed, and such assessments are a requirement of the State’s permitting process to develop a water supply in this area. A need for an assessment of the potential effects of pumping on wetlands in the Big River Management Area led to a cooperative agreement in 2008 between the Rhode Island Water Resources Board, the U.S. Geological Survey, and the University of Rhode Island. This partnership was formed with the goal of developing methods for characterizing wetland vegetation, soil type, and hydrologic conditions, and monitoring and modeling water levels for pre- and post-water-supply development to assess potential effects of groundwater withdrawals on wetlands. This report describes the hydrogeology of the area and the numerical simulations that were used to analyze the interaction between groundwater and surface water in response to simulated groundwater withdrawals. The results of this analysis suggest that, given the hydrogeologic conditions in the Big River Management Area, a standard 5-day aquifer test may not be sufficient to determine the effects of pumping on water levels in nearby wetlands. Model simulations showed water levels beneath Reynolds Swamp declined by about 0.1 foot after 5 days of continuous pumping, but continued to decline by an additional 4 to 6 feet as pumping times were increased from a 5-day simulation period to a simulation period representative of long-term average monthly conditions. This continued decline in water levels with increased pumping time is related to the shift from the primary source of water to the pumped wells being derived from aquifer storage during the early-time (5 days) simulation to being derived more from induced infiltration from the flooded portion of the Big River (southernmost extent of the Flat River Reservoir) during the months of March through October or from captured groundwater discharge to this portion of the Big River when the downstream Flat River Reservoir is drained for weed control during the months of November through February, as was the case for the long-term monthly conditions.

Rhode Island↗

USGS2017

Groundwater discharge to the Mississippi River and groundwater balances for the Interstate 94 Corridor surficial aquifer, Clearwater to Elk River, Minnesota, 2012–14

The Interstate 94 Corridor has been identified as 1 of 16 Minnesota groundwater areas of concern because of its limited available groundwater resources. The U.S. Geological Survey, in cooperation with the Minnesota Department of Natural Resources, completed six seasonal and annual groundwater balances for parts of the Interstate 94 Corridor surficial aquifer to better understand its long-term (next several decades) sustainability. A high-precision Mississippi River groundwater discharge measurement of 5.23 cubic feet per second per mile was completed at low-flow conditions to better inform these groundwater balances. The recharge calculation methods RISE program and Soil-Water-Balance model were used to inform the groundwater balances. For the RISE-derived recharge estimates, the range was from 3.30 to 11.91 inches per year; for the SWB-derived recharge estimates, the range was from 5.23 to 17.06 inches per year. Calculated groundwater discharges ranged from 1.45 to 5.06 cubic feet per second per mile, a ratio of 27.7 to 96.4 percent of the measured groundwater discharge. Ratios of groundwater pumping to total recharge ranged from 8.6 to 97.2 percent, with the longer-term groundwater balances ranging from 12.9 to 19 percent. Overall, this study focused on the surficial aquifer system and its interactions with the Mississippi River. During the study period (October 1, 2012, through November 30, 2014), six synoptic measurements, along with continuous groundwater hydrographs, rainfall records, and a compilation of the pertinent irrigation data, establishes the framework for future groundwater modeling efforts.

Minnesota↗