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Evaluating hydrologic data products for scientific and management applications related to potential future streamflow conditions in the Upper Mississippi and Illinois Rivers

The hydrology of the Upper Mississippi and Illinois Rivers is a fundamental driver of ecosystem patterns and processes across a large portion of the United States. Quantitative hydrologic data for the main stems of these rivers underlie numerous scientific investigations, statistical models, and decision-making processes for local, State, and Federal agencies involved in the Upper Mississippi River Restoration program. Although historical hydrologic data exist, data representing potential future conditions of the Upper Mississippi and Illinois Rivers lack the resolution necessary to anticipate biotic and abiotic responses to altered hydrology and to determine resilient management actions. A source of future hydrologic scenarios is the readily available LOCA–VIC–mizuRoute hydrologic data products (named for the chain of models the data are produced from—localized constructed analogs, Variable Infiltration Capacity macroscale hydrological model, and the mizuRoute hydrologic routing model—that we shorten further to LVM in this report) that include simulated discharges for historic and future timeframes. The objective of this study is to assess the reliability of the hydrologic data products for their use in Upper Mississippi River Restoration program applications. Key study questions are (1) do the hydrologic data products reproduce characteristics of hydrology necessary to support ecological modeling and restoration decision-making applications within the Upper Mississippi River Restoration program? and (2) are there geographic differences in the reliability of the hydrologic data products? Seven characteristics of river hydrology were selected related to flow magnitude, seasonality, and regime for evaluation. The seven characteristics were calculated using observed and historical simulated hydrologic data at 19 U.S. Geological Survey streamgages throughout the basins of the Upper Mississippi and Illinois Rivers; two streamgages are located on the main stem of the Mississippi River and two streamgages are located on the main stem of the Illinois River. Statistical comparisons between observed and historical simulated characteristics indicated that the hydrologic data products did not reliably represent historical hydrologic conditions in the basin or main stem. The hydrologic data products we evaluated could not reliably capture the overall hydrologic regime or flow magnitudes; the latter is evidenced by substantial underestimates of discharge at most streamgages. Seasonal hydrologic characteristics were captured more reliably than flow magnitude, but overall correspondence was low for most streamgages. A weak latitudinal pattern in seasonal characteristics indicated the hydrologic data products poorly represent streamflow timing in snow-affected regions of the basin. Discrepancies in magnitude, seasonality, and regime indicate the potential for multiple sources of error. Because poor correspondence was present across all 19 streamgages, it was not possible to identify specific drivers of poor performance (that is, drainage area or geography). The modeling chain should be evaluated for biases associated with meteorologic forcing data, as well as hydrologic model formulation and calibration. We conclude that the hydrologic data products we evaluated appear unsuitable for applications tied to habitat and ecosystem restoration and management in the Upper Mississippi and Illinois Rivers. Plans to develop a future hydrology dataset for the Upper Mississippi River Restoration program would benefit from ongoing work to improve global climate model output downscaling methods, to improve hydrologic models, to make use of innovations in machine-learning approaches for projecting hydrology, and other efforts. The framework developed herein to evaluate hydrometeorological outputs generated using global climate models for a specific water resources application is a transferrable approach that could be applied to other data products and river systems.

Illinois, Indiana, Iowa, Minnesota, Missouri, Sout↗

Surface- and ground-water characteristics in the Upper Truckee River and Trout Creek watersheds, South Lake Tahoe, California and Nevada, July-December 1996

The Upper Truckee River and Trout Creek watersheds, South Lake Tahoe, California and Nevada, were studied from July to December 1996 to develop a better understanding of the relation between surface water and ground water. Base flows at 63 streamflow sites were measured in late September 1996 in the Upper Truckee River and Trout Creek watersheds. Most reaches of the main stem of the Upper Truckee River and Trout Creek had gaining or steady flows, with one losing reach in the mid-section of each stream. Twenty-seven of the streamflow sites measured in the Upper Truckee River watershed were on 14 tributaries to the main stem of the Upper Truckee River. Sixteen of the 40 streamflow sites measured in the Upper Truckee River watershed had no measurable flow. Streamflow in Upper Truckee River watershed ranged from 0 to 11.6 cubic feet per second (ft 3 /s). The discharge into Lake Tahoe from the Upper Truckee River was 11.6 ft 3 /s, of which, 40 percent of the flow was from ground-water discharge into the main stem, 40 percent was from tributary inflows, and the remaining 20 percent was the beginning flow. Gains from or losses to ground water along streams ranged from a 1.4 cubic feet per second per mile (ft 3 /s/mi) gain to a 0.5 ft 3 /s/mi loss along the main stem. Fourteen of the streamflow sites measured in the Trout Creek watershed were on eight tributaries to the main stem of Trout Creek. Of the 23 streamflow sites measured in the Trout Creek watershed, only one site had no flow. Flows in the Trout Creek watershed ranged from zero to 23.0 ft 3 /s. Discharge into Lake Tahoe from Trout Creek was 23.0 ft 3 /s, of which, about 5 percent of the flow was from ground-water discharge into the main stem, 75 percent was from tributary inflows, and the remaining 20 percent was the beginning flow. Ground-water seepage rates ranged from a 1.4 ft 3 /s/mi gain to a 0.9 ft3/s/mi loss along the main stem. Specific conductances measured during the seepage run in September 1996 increased in a downstream direction in the main stem of the Upper Truckee River and remained relatively constant in the main stem of Trout Creek. Water temperatures measured during the seepage run also increased in a downstream direction in both watersheds. Depths to ground water measured at 62 wells in the study area were used with the results of the seepage run to produce a water-level map in the Upper Truckee River and Trout Creek watersheds. Ground-water levels ranged from 1.3 to 69.8 feet below land surface. In the upper sections of the watersheds ground-water flow is generally toward the main stems of Upper Truckee River and Trout Creek, whereas in the lower sections, ground-water flow generally parallels the two streams and flows toward Lake Tahoe. The altitude of ground water between Lake Tahoe and Highway 50 was nearly the same as the lake-surface altitude from July to November 1996. This suggests ground-water discharge beneath the Upper Truckee River and Trout Creek drainages directly to Lake Tahoe was minimal and that much of the ground-water discharge was to the channels of the Upper Truckee River and Trout Creek upstream from Highway 50. Hydraulic gradients ranged from near zero to 1,400 feet per mile. Samples were collected at six surface-water-quality and eight ground-water-quality sites from July through mid-December 1996. Specific conductance of the ground-water-quality sites was higher than that of the surface-water-quality sites. Water temperature and pH median values were similar between ground-water-quality and surface-water-quality sites but ground water had greater variation in pH and surface water had greater variation in water temperature. Ground-water nutrient concentrations were generally higher than those in streams except for bioreactive iron.

California, Nevada↗

Water quality of the Flint River basin, Alabama and Tennessee, 1999-2000

The U.S. Geological Survey monitored eight stream sites in the Flint River Basin during the period January 1999 through May 2000, to characterize patterns in the occurrence of pesticides, fecal-indicator bacteria, and nutrients in relation to season and streamflow conditions and to land-use patterns. This study is part of the National Water-Quality Assessment Program, which was designed to assess water quality as it relates to various land uses. Every water sample collected from the Flint River Basin had detectable levels of at least two pesticides; 64 percent of the samples contained mixtures of at least five pesticides. In general, pesticides detected most frequently and at highest concentrations in streams corresponded to the pesticides with the highest rates of use in the watersheds. Detections of fluometuron, norflurazon, and atrazine were more frequent (by a margin of 15 percent or more) in samples from the Flint River when compared with the frequencies of pesticide detections at 62 agricultural stream sites across the Nation. Detections of fluometuron in the Flint River were more frequent even when compared with a cotton-cultivation subset of the 62 sites. For most pesticides, maximum concentrations did not exceed criteria to protect aquatic life; however, maximum concentrations of atrazine, cyanazine, and malathion exceeded aquaticlife criteria in at least one sample. Concentrations near or exceeding the aquatic-life criteria occurred only during the spring and summer (April-July), and generally occurred during storm flows. Less than 5 percent of the estimated mass of pesticides applied annually to agricultural areas in the Flint River Basin was transported to the stream at the monitoring points on the Flint River near Brownsboro, Alabama, and on Hester Creek near Plevna, Alabama. The pesticides with the highest ratios (greater than 3 percent) of the amount transported instream to the amount applied?atrazine, metolachlor, fluometuron, and norflurazon?are preemergent herbicides applied to the soil before the crops have emerged, which increases the probability of transport in surface runoff. Concentrations of the fecal-bacteria indicator Escherichia coli (E. coli) in the Flint River and Hester Creek exceeded the U.S. Environmental Protection Agency criterion for recreation in almost all storm samples, and in many samples collected up to 6 days following a storm. Concentrations in the Flint River were strongly correlated with sample turbidity, suggesting that turbidity might be useful as a surrogate for estimating E. coli concentrations. Concentrations of the nutrients nitrogen and phosphorus in samples from the Flint River generally exceeded thresholds indicating eutrophic potential, whereas concentrations in samples from Hester Creek were generally below the thresholds. When compared with nutrient data from a set of 24 agricultural basins across the southeastern region of the United States, concentrations in the Flint River and Hester Creek were slightly above the regional median. Base-flow concentrations of certain pesticides, nutrients, and E. coli were compared to land-use information for eight sites in the Flint River Basin. The highest base-flow concentrations of aldicarb sulfoxide, fluometuron, and phosphorus were found in the tributaries with the greatest density of cotton acreage in the watershed. Similarly, high base-flow concentrations of total nitrogen were correlated with a high percentage of cultivated land in the watershed. Lack of information about distribution of stream access by livestock weakened the analysis of correlation between livestock and base-flow concentrations of E. coli and nutrients. Input of dissolved and suspended chemicals from the Flint River during storms influences water quality in the reach of the Tennessee River from which the City of Huntsville, Alabama, withdraws about 40 percent of its drinking water. During the storm of April 2-5, 2000, concentrations of several pesticides were

Water-Resources Investigations Report↗

Water-quality data analysis of the upper Gunnison River watershed, Colorado, 1989-99

Water-quality data from October 1969 to December 1999 for both surface water and ground water in the upper Gunnison River watershed were retrieved and compiled from the U.S. Geological Survey National Water Information System and the U.S. Environmental Protection Agency Storage and Retrieval databases. Analyses focused primarily on a subset of these data from October 1989 to December 1999. The upper Gunnison River watershed is located west of the Continental Divide in the Southern Rocky Mountains physiographic province. Surface-water-quality data were compiled for 482 sites in the upper Gunnison River watershed. Most values of surface-water temperature, dissolved oxygen, and pH were within Colorado Department of Public Health and Environment (CDPHE) in-stream standards. Calcium bicarbonate type water was the most spatially dominant water type in the basin. Nutrients were most commonly sampled along the Slate River and East River near Crested Butte and along the Gunnison River from the confluence of the East and Taylor Rivers to the western edge of the watershed. Median ammonia concentrations were low, with many concentrations less than laboratory reporting levels. All nitrate concentrations met the CDPHE in-stream standard of 10 milligrams per liter. More than 30 percent of stream sites with total phosphorus data (23 of 61 sites) had concentrations greater than the U.S. Environmental Protection Agency (USEPA) recommendation for controlling eutrophication. Ammonia concentrations at a site on the Slate River near Crested Butte had a statistically significant upward trend for the 1995–99 period. The Slate River near Crested Butte site is located immediately downstream from the towns of Crested Butte and Mount Crested Butte and may reflect recent population growth or other land-use changes. However, the rate of change of the trend is small (0.017 milligram per liter per year). Although a multiple comparison test showed nitrate concentrations were statistically different between agriculture and forest sites and between agriculture and urban land-use classified sites, median concentrations were low among all land-use settings. Median concentrations of total phosphorus were greatest in rangeland areas and least in urban areas. No significant differences were identified for median concentrations of total phosphorus in agriculture and forest land-use areas. Median concentrations of arsenic, lead, mercury, selenium, and silver were low or below reporting levels throughout the watershed. Aluminum, cadmium, copper, lead, manganese, and zinc concentrations were elevated near the town of Crested Butte and on Henson Creek upstream from Lake City, which may be explained by upstream areas of historical mining. Samples for six trace elements exceeded standards: cadmium, copper, lead, manganese, silver, and zinc. A downward trend (3 micrograms per liter per year) was identified for the dissolved iron concentration at a site on the Gunnison River at County Road 32 downstream from the city of Gunnison. Streambed-sediment samples from areas affected by historical mining also had elevated concentrations of some trace elements. Chlorophyll- a concentrations in samples from Blue Mesa Reservoir and streams in the Crested Butte and Gunnison areas were typical of unenriched to moderately enriched conditions. Median concentrations of 5-day biochemical oxygen demand concentrations for sites between Crested Butte and Blue Mesa Reservoir were less than 2 milligrams per liter. Occasional high (greater than 200 counts per 100 milliliters) concentrations for fecal coliform were determined at selected sites within the study area. However, median concentrations were less than 100 counts per 100 milliliters except for the Squaw Creek and Cimarron River areas in the western part of the watershed. Ground-water-quality data have been collected by the U.S. Geological Survey from 99 wells. Many wells were completed in aquifers composed of Holocene-age valley fill and alluvium. Most field properties were within the USEPA Secondary Drinking Water Regulations (SDWR) range for treated drinking water, except for 2 (of 40) pH samples. Calcium bicarbonate was the predominant water type in nearly all aquifers except for the aquifers composed of volcanic rock, which had more sodium and sulfate mixed water types. Wells with sulfate concentrations exceeding the SDWR of 250 milligrams per liter were completed in aquifers composed of volcanic rock near Lake City. Dissolution and oxidation of sulfide minerals in these aquifers may explain the elevated sulfate concentrations in ground water at these locations. Nutrient concentrations in ground water were generally low, and median concentrations for ammonia, nitrite, and dissolved phosphorus were below reporting levels. All nitrate concentrations in the samples were below the USEPA drinking-water maximum contaminant level of 10 mg/L. No statistical difference was found in nitrate concentrations among the four land-use classifications (agriculture, forest, rangeland, and urban). Trace elements in ground water were generally below the USEPA SDWR. Three iron samples exceeded the USEPA SDWR of 300 micrograms per liter at two wells located near the city of Gunnison and at a well south of the town of Powderhorn near the Cebolla River. Nine of 39 manganese samples exceeded the USEPA SDWR of 50 micrograms per liter and were collected from aquifers composed of Holocene-age valley fill and alluvium near Gunnison and Crested Butte and in one well near the Cebolla River. Radon gas is a natural radioactive decay product of uranium. All 39 radon samples collected from ground water in the watershed exceeded the proposed USEPA drinking-water maximum contaminant level of 300 picocuries per liter and ranged from 426 to 3,830 picocuries per liter.

Colorado↗

Characterization of selenium in the lower Gunnison River basin, Colorado, 1988-2000

Selenium concentrations in certain water bodies in the lower Gunnison River Basin, including the lower Gunnison River and lower Uncompahgre River, have exceeded the Colorado water-quality standard of 5 micrograms per liter for selenium. A task force was formed in 1998 that consists of various government agencies, private irrigation companies, and local residents to address the selenium concerns in the lower Gunnison River Basin. The task force, working with the National Irrigation Water Quality Program, needed more detailed information on selenium loading in the basin to develop viable alternatives for remediating selenium in the lower Gunnison River Basin. In 1999-2000, the U.S. Geological Survey collected selenium data for tributaries of the Gunnison River downstream from the North Fork of the Gunnison and in the North Fork Basin. The largest selenium load in a tributary stream was in the Uncompahgre River, which accounted for about 38 percent of the selenium load in the Gunnison River at Whitewater. The North Fork of the Gunnison River accounted for about 7 percent of the selenium load in the Gunnison River. Two tributaries east of Delta, Sunflower Drain and Bonafide Ditch, consist primarily of irrigation return flows and were other major selenium sources to the Gunnison River. Some tributaries in the lower North Fork Basin had selenium concentrations exceeding 5 micrograms per liter. Except for several streams draining the Uncompahgre Plateau, many tributaries to the Gunnison River downstream from the North Fork had selenium concentrations exceeding 5 micrograms per liter. Except during occasional rain and snowmelt events, selenium loading from nonirrigated desert areas was minimal. Detailed characterization studies were done in 1999-2000 on Cedar Creek and Loutzenhizer Arroyo, which contribute the largest tributary selenium loads to the Uncompahgre River. Selenium concentrations in Cedar Creek downstream from Miguel Road ranged from 12 to 28 micrograms per liter in November 1999. Montrose Arroyo was the largest selenium source to Cedar Creek. On an annual basis, about 20 percent of the selenium load in Cedar Creek originates in the basin upstream from Miguel Road. Selenium concentrations in Loutzenhizer Arroyo ranged from 157 to 347 micrograms per liter in February 2000. A significant increase in selenium concentrations occurred in the stream reach between the Selig Canal and Falcon Road (LZU7). Although selenium concentrations in the west tributary of Loutzenhizer Arroyo were lower than in the main stem, the west tributary contributed about 41 percent of the selenium load. Downstream from the confluence with the west tributary to the mouth, selenium concentrations in the arroyo gradually decreased, and the increase in selenium load in the lower reach was small.

Water-Resources Investigations Report↗

Environmental setting and water-quality issues of the Mobile River Basin, Alabama, Georgia, Mississippi, and Tennessee

The Mobile River Basin is one of over 50 river basins and aquifer systems being investigated as part of the U.S. Geological Survey National Water-Quality Assessment (NAWQA) Program. This basin is the sixth largest river basin in the United States, and fourth largest in terms of streamflow, encompassing parts of Alabama, Georgia, Mississippi, and Tennessee. Almost two-thirds of the 44,000-square-mile basin is located in Alabama. Extensive water resources of the Mobile River Basin are influenced by an array of natural and cultural factors. These factors impart unique and variable qualities to the streams, rivers, and aquifers providing abundant habitat to sustain the diverse aquatic life in the basin. Data from Federal, State, and local agencies provide a description of the environmental setting of the Mobile River Basin. Environmental data include natural factors such as physiography, geology, soils, climate, hydrology, ecoregions, and aquatic ecology, and human factors such as reservoirs, land use and population change, water use, and water-quality issues. Characterization of the environmental setting is useful for understanding the physical, chemical, and biological characteristics of surface and ground water in the Mobile River Basin and the possible implications of that environmental setting for water quality. The Mobile River Basin encompasses parts of five physiographic provinces. Fifty-six percent of the basin lies within the East Gulf section of the Coastal Plain Physiographic Province. The remaining northeastern part of the basin lies, from west to east, within the Cumberland Plateau section of the Appalachian Plateaus Physiographic Province, the Valley and Ridge Physiographic Province, the Piedmont Physiographic Province, and the Blue Ridge Physiographic Province. Based on the 1991 land-use data, about 70 percent of the basin is forested, while agriculture, including livestock (poultry, cattle, and swine), row crops (cotton, corn, soybeans, sorghum, and wheat), and pasture land accounts for about 26 percent of the study unit. Agricultural land use is concentrated along the Black Prairie Belt district of the Coastal Plain. Urban areas account for only 3 percent of the total land use; however, the areal extent of the metropolitan statistical areas (MSA) may indicate more urban influences. The MSAs include urban areas outside of the city boundaries and can include adjacent counties. Seven MSAs are delineated in the Mobile River Basin, including Montgomery, Mobile, Tuscaloosa, Birmingham, Gadsden, Anniston, and Atlanta. The total population for the Mobile River Basin was about 3,673,100 in 1990. State water-quality agencies have identified numerous causes and sources of water-body impairment in the Mobile River Basin. In 1996, organic enrichment, dissolved oxygen depletion, elevated nutrient concentrations, and siltation were the most frequently cited causes of impairment, affecting the greatest number of river miles. Bacteria, acidic pH, and elevated metal concentrations also were identified as causes of impairment. The sources for impairment varied among river basins, were largely a function of land use, and were attributed primarily to municipal and industrial sources, mining, and agricultural activities.

Water-Resources Investigations Report↗

Relation of periphyton and benthic invertebrate communities to environmental factors and land use at selected sites in part of the upper Mississippi River basin, 1996-98

The Upper Mississippi River Basin is one of the hydrologic systems selected for study by the National Water-Quality Assessment (NAWQA) Program of the U.S. Geological Survey. NAWQA utilizes a multi-disciplinary approach to explain factors that affect water quality. Part of the NAWQA design addresses the relation of land use and environmental factors to periphyton and benthic invertebrate communities in streams. This report focuses on a 122,000 square kilometer area of the Mississippi River Basin, including the Twin Cities metropolitan area (TCMA). The northeastern part of the study area is forested, the southwestern part is agricultural, and the central part is transitional between forest and agriculture. Sampling sites were selected based on a process that identified small streams in predominantly forested, agricultural, and urban settings, and large river sites on the Mississippi River and major tributaries. Periphyton and benthic invertebrate communities were evaluated at each site. Compared to the forested site, periphyton density and biovolume in small streams generally increased as nutrient concentrations associated with urban and agricultural land use increased. Periphyton communities varied within agricultural and urban streams, indicating that physical and chemical factors other than land use also affect periphyton communities. Benthic invertebrate communities also are affected by land use and associated stream habitat. There were few intolerant taxa (Ephemeroptera and Plecoptera) in urban streams, potentially due to high streamflow variability and contaminants from runoff. Ephemeroptera taxa richness was greatest in the agricultural streams. The most abundant Ephemeroptera taxa were those tolerant to high concentrations of suspended sediment. Richness of Plecoptera and Trichoptera taxa were greatest in the forested stream. Biological communities in the St. Croix and Minnesota River generally reflected relatively homogeneous land uses. Biological communities in the Mississippi River reflected changes in water quality and physical habitat as the Minnesota and St. Croix Rivers join the Mississippi River. Periphyton density and biovolume, and the relative abundance of blue-green algae density increased in the Mississippi River at the confluence compared to the Minnesota and St. Croix Rivers. Relative abundance of benthic invertebrate taxa richness and diversity generally decreased downstream in the large rivers as urban and agricultural land use become more prevalent. Impoundments and dredging of the Mississippi River in and downstream from the TCMA exacerbate effects of increasing river size to produce a more lake-like system.

Iowa, Minnesota, North Dakota, South Dakota, Wisco↗

Occurrence and distribution of nutrients, suspended sediment, and pesticides in the Mobile River Basin, Alabama, Georgia, Mississippi, and Tennessee, 1999-2001

The Mobile River Basin is one of more than 50 river basins and aquifer systems being investigated as part of the U.S. Geological Survey's National Water- Quality Assessment (NAWQA) Program. This basin is the sixth largest river basin in the United States and the fourth largest in terms of streamflow. The Mobile River Basin encompasses parts of Alabama, Georgia, Mississippi, and Tennessee, and almost two-thirds of the 44,0000-square-mile basin is located in Alabama. The extensive water resources of the Mobile River Basin are influenced by an array of natural and cultural factors, which impart unique and variable qualities to the streams, rivers, and aquifers and provide abundant habitat to sustain the diverse aquatic life in the basin. From January 1999 to December 2001, a study was conducted of the occurrence and distribution of nutrients, suspended sediment, and pesticides in surface water of the Mobile River Basin. Nine sampling sites were selected on the basis of land use. The nine sites included two streams draining agricultural areas, two urban streams, and five large rivers with mixed land use. Surface-water samples were collected from one to four times each month to characterize the spatial and temporal variation in nutrient and pesticide concentrations. Nutrient and suspended-sediment concentrations were highest in watersheds dominated by urban or agricultural land uses. Forty-two percent of the total phosphorus concentrations at all nine sites exceeded the U.S. Environmental Protection Agency's recommended maximum concentration of 0.1 milligram per liter. Flow-weighted mean concentrations at the Mobile River Basin sites generally were in the lower to middle percentile ranges compared with data from other NAWQA studies across the Nation. However, flow-weighted mean concentrations of ammonia, total nitrogen, orthophosphate, and total phosphorus at Bogue Chitto Creek, an agricultural watershed, ranked in the upper 20th percentile of agricultural sites sampled across the Nation as part of the NAWQA Program. Nutrient loads in the Tombigbee River were nearly twice as high compared with nutrient loads in the Alabama River. Nutrient yields were highest in Bogue Chitto Creek, Cahaba Valley Creek, and Threemile Branch because of agricultural and urban land uses in these watersheds. Of the 104 pesticides and degradation products analyzed in the stream samples, 69 were detected in one or more samples. Of the 69 detected pesticides, 51 were herbicides, 15 were insecticides, and 3 were fungicides. A relatively small number of heavily used herbicides accounted for most of the detections, including atrazine and its metabolites (deethylatrazine, 2-hydroxyatrazine, deisopropylatrazine, and deethyldeisopropylatrazine), simazine, metolachlor, tebuthiuron, prometon, diuron, and 2,4-D. Diazinon, chlorpyrifos, and carbaryl were the most frequently detected insecticides; metalaxyl was the most frequently detected fungicide in the Mobile River Basin. Concentrations of pesticides detected in surface water of the Mobile River Basin were among the highest concentrations recorded nationally by the NAWQA Program during 1991 to 2001. The three highest concentrations of atrazine detected at sites across the country were recorded at Bogue Chitto Creek; the highest concentrations of 2,4-D, imazaquin, and malathion recorded nationally were detected at Threemile Branch. Aquatic-life criteria were exceeded by concentrations of five herbicides (2,4-D, atrazine, cyanazine, diuron, and metolachlor), six insecticides (carbaryl, chlorpyrifos, diazinon, dieldrin, malathion, and p,p'-DDE), and one fungicide (chlorothalonil). Drinking-water standards were exceeded by concentrations of four herbicides (2,4-D, atrazine, cyanazine, and simazine), three insecticides (alpha- HCH, diazinon, and dieldrin), and one fungicide (chlorothalonil). The types and concentrations of pesticides found in surface water are linked to land use and to the types of pesti

Alabama, Georgia, Mississippi, Tennessee↗

Methods for estimating monthly mean concentrations of selected water-quality constituents for stream sites in the Red River of the North basin, North Dakota and Minnesota

Future development of the Garrison Diversion Unit may divert water from the Missouri River into the Sheyenne River and the Red River of the North for municipal and industrial use. The U.S. Bureau of Reclamation's Canals, Rivers, and Reservoirs Salinity Accounting Procedures model can be used to predict the effect various operating plans could have on water quality in the Sheyenne River and the Red River of the North. The model uses, as Input, monthly means of streamflow and selected water-quality constituents for a 54-year period at 28 nodes on the Sheyenne River and the Red River of the North. This report provides methods for estimating monthly mean concentrations of selected water-quality constituents that can be used for input to and calibration of the salinity model. Mater-quality data for 32 gaging stations can be used to define selected water-quality characteristics at the 28 model nodes. Materquality data were retrieved from the U.S. Geological Survey's National Mater Data Storage and Retrieval System data base and statistical summaries were prepared. The frequency of water-quality data collection at the gaging stations is inadequate to define monthly mean concentrations of the individual water-quality constituents for all months for the 54-year period; therefore, methods for estimating monthly mean concentrations were developed. Relations between selected water-quality constituents [dissolved solids, hardness (as CaCO 3 ), sodium, sulfate, and chloride] and streamflow were developed as the primary method to estimate monthly mean concentrations. Relations between specific conductance and streamflow and relations between selected water-quality constituents [dissolved solids, hardness (as CaCO 3 ), sodium, sulfate, and chloride] and specific conductance were developed so that a cascaded-regression relation could be developed as a second method of estimating monthly mean concentrations and, thus, utilize a large specific-conductance data base. Information about the quantity and the quality of ground water discharging to the Sheyenne River is needed for model input for reaches of the river where ground water accounts for a substantial part of streamflow during periods of low flow. Ground-water discharge was identified for two reaches of the Sheyenne River. Ground-water discharge to the Sheyenne River in the vicinity of Warwick, N.Dak., was about 14.8 cubic feet per second and the estimated dissolved-solids concentration was about 441 milligrams per liter during October 15 and 16, 1986. Ground-water discharge to the Sheyenne River in a reach between Lisbon and Kindred, N.Dak., ranged from an average of 25.3 cubic feet per second during September 13 to November 19, 1963, to about 45.0 cubic feet per second during October 21 and 22, 1986. Dissolved-solids concentration was estimated at about 442 milligrams per liter during October 21 and 22, 1986.

Water-Resources Investigations Report↗

Hydrologic and chemical interaction of the Arkansas River and the Equus Beds aquifer between Hutchinson and Wichita, south-central Kansas

Large chloride concentrations in Arkansas River water have the potential to degrade water quality in the adjacent Equus beds aquifer between Hutchinson and Wichita, Kansas. The aquifer is an important source of water for municipal, industrial, agricultural, and domestic uses. A three-dimensional, finite-difference, ground-water flow-model program (MODFLOW) was used with data from past studies and data collected during 1988-91 to simulate aquifer and stream conditions during the late 1930's, during 1940-89, and during 1990-2019. Results of ground-water flow-model simulations indicated that declining water levels in the Equus beds aquifer since the 1940's have caused base flow in the Arkansas and Little Arkansas Rivers to decrease. In 1940, the Arkansas and Little Arkansas Rivers had simulated net base-flow gains within the model area of about 21 and about 67 ft 3 /s (cubic feet per second), respectively. By the end of 1989, the Arkansas River had a simulated net base-flow loss of about 52 ft 3 /s, and the Little Arkansas River had a net base-flow gain of about 27 ft 3 /s. Simulations for 1990-2019 showed that the water-level changes in a selected model cell located in the central part of the Wichita well field could range from -0.2 to -78 feet. Waterlevel changes in a selected model cell located near the Arkansas River could range from +1.3 to -1.2 feet. In model simulations where only pumpage varied, net base-flow loss from the Arkansas River to the aquifer ranged from about 59 ft 3 /s (no increase in pumpage since 1989) to 117 ft 3 /s (a 3-percent per year increase in pumpage since 1989) by 2019. Assuming a chloride concentration of 630 milligrams per liter, the median concentration in Arkansas River water collected during 1988-91, the quantity of chloride discharged from the Arkansas River to the aquifer was estimated to have increased from about 21 tons per day in 1940 to about 100 tons per day in 1989. By 2019, chloride discharge was indicated to range from about 110 tons per day (associated with no increase in pumpage since 1989) to 200 tons per day (associated with a 3-percent per year increase in pumpage since 1989). A particle-tracking program (MODPATH), which used the results from the flow model, was used to simulate the distribution in the aquifer of chloride from the river during the same time periods. Particle-tracking simulations show that, during 1940-89, the simulated distribution of particles representing chloride from the Arkansas River expanded from relatively narrow bands near the river to a wider distribution within the aquifer and the Wichita well field. Particle-tracking simulations indicate that chloride discharge from the Arkansas River may have reached the edge of the Wichita well field as early as 1963.

Kansas↗

Determination of traveltimes in the lower San Joaquin River basin, California, from dye-tracer studies during 1994-1995

Dye-tracer studies were done in the lower San Joaquin River Basin in February 1994, June 1994, and February 1995. Dye releases were made in the Merced River (February 1994), Salt Slough (June 1994), Tuolumne River (February 1995), and Dry Creek (February 1995). The traveltimes determined in the studies aided the interpretation of pesticide data collected during storm sampling and guided sample collection during a Lagrangian pesticide study. All three studies used rhodamine WT 20-percent dye solution, which was released as a slug in midstream. The mean traveltime determined in the dye studies were compared to estimates based on regression equations of mean stream velocity as a function of streamflow. Dye recovery, the ratio of the calculated dye load at downstream sites to the initial amount of dye released, was determined for the 1994 studies and a dye-dosage formula was evaluated for all studies. In the February 1994 study, mean traveltime from the Merced River at River Road to the San Joaquin River near Vernalis (46.8 river miles) was 38.5 hours, and to the Delta-Mendota Canal at Tracy pumps (84.3 river miles) was 90.4 hours. In the June 1994 study, mean traveltime from Salt Slough at Highway 165 to Vernalis (64.0 river miles) was 80.1 hours. In the February 1995 study, the mean traveltime from the Tuolumne River at Roberts Ferry to Vernalis (51.5 river miles) was 35.8 hours. For the 1994 studies, the regression equations provided suitable estimates of travel-time, with ratios of estimated traveltime to mean dye traveltime of 0.94 to 1.08. However, for the 1995 dye studies, the equations considerably underestimated traveltime, with ratios of 0.49 to 0.73.In the February 1994 study, 70 percent of the dye released was recovered at Vernalis and 35percent was recovered at the Delta-Mendota Canal at Tracy pumps. In the June 1994 study, recovery was 61 percent at Patterson, 43 percent just upstream of the Tuolumne River confluence, and 37 percent at Vernalis. The dye-dosage formula overestimated the dye required for a given downstream concentration for the 1994 studies by ratios of 1.07 to 2.12. The ratios for the February 1995 studies were 0.67 to 0.95 for the Tuolumne River and 1.21 for Dry Creek. In all studies, the estimates improved with length of dye study.

Water-Resources Investigations Report↗

Water-quality conditions of the lower Boise River, Ada and Canyon Counties, Idaho, May 1994 through February 1997

Agricultural land and water use, wastewater treatment facility discharges, land development, road construction, urban runoff, confined-animal feeding operations, reservoir operations, and river channelization affect the water quality and biotic integrity of the lower Boise River between Lucky Peak Dam and the river's mouth at Parma, Idaho. During May 1994 through February 1997, 4 sites on the Boise River, 12 tributary/drain sites, and 3 wastewater treatment facilities were sampled at various intervals during the irrigation (high-flow) and post-irrigation (low-flow) seasons to determine sources, concentrations, and relative loads of nutrients and suspended sediment. Discharge entering the Boise River from the 12 tributary/drain sites and 3 wastewater treatment facilities was measured to determine the nutrient loads being contributed from each source. Total nitrogen, total phosphorus, and suspended sediment concentrations and loads tended to increase in a downstream direction along the Boise River. Among the 15 sources of discharge to the Boise River, 3 southside tributary/drains and the West Boise wastewater treatment facility contributed the largest loads of total nitrogen; the median daily load was more than 2,000 pounds per day. The West Boise wastewater treatment facility contributed the largest median daily load of total phosphorus (810 pounds per day); Dixie Drain contributed the largest median daily load of suspended sediment (26.4 tons per day). Nitrogen-to-phosphorus ratios at the four Boise River sites indicated that phosphorus could be limiting algal growth at the Diversion Dam site, whereas nitrogen could be limiting algal growth at the Glenwood and Middleton sites during some parts of the year. Algal growth in the Boise River near Parma did not appear to be nutrient limited. Because of the complexity of the plumbing system in the lower Boise River (numerous diversions and inflow points), accurate comparisons between discharge and nutrient loads entering the river at measured sites during high-flow sampling periods were difficult. During low-flow sampling periods, southside tributary/drains contributed most of the discharge and total nitrogen load, and wastewater treatment facilities contributed most of the total phosphorus load to the Boise River. During the 50-day period July 18 through September 5, 1996, the Idaho State standard for maximum daily average temperature for coldwater biota was exceeded by 34 percent at Middleton, 48 percent at Caldwell, and 80 percent near Parma. Violations of State standards for primary and secondary contact recreation were observed at all tributary/ drains and in the Boise River near Parma. Median instantaneous concentrations of fecal coliform bacteria exceeded State standards for primary contact recreation at five tributary/drains and exceeded standards for secondary contact recreation at one tributary/drain (Dixie Drain).

Idaho↗

Ground-water resources of the Middle Loup division of the lower Platte River basin, Nebraska, with a section on Chemical quality of the ground water

The Middle Loup division of the lower Platte River basin is an area of 650 square miles which includes the Middle Loup River valley from the confluence of the Middle and North Loup Rivers in Howard County, Nebr., to the site of the diversion dam that the U. S. Bureau of Reclamation proposes to construct in Blaine County near Milburn, Nebr. It also includes land in Howard and Sherman Counties designated by the Bureau of Reclamation as the Farwell unit. Irrigable land in this division is present on both sides of the Middle Loup River and along its tributaries. Most of the Middle Loup River valley is already irrigated by the Middle Loup Public Power and Irrigation District, which is strictly an irrigation enterprise. The uplands are not irrigated. Loess, dune sand, gravel, silt, and clay of Pleistocene or Recent age are exposed in the report area. These unconsolidated sediments rest on bedrock consisting of alternating layers of shale, mudstone, sandstone, and limestone, which are essentially fiat lying or slightly warped. The Ogallala formation, of Tertiary (Pliocene) age, immediately underlies the Pleistocene sediments and rests on the Pierre shale of Cretaceous age. Belts of alluvium occupy the Middle Loup River valley and the valleys of the principal streams in the area. The soils, dune sand, and terrace deposits are the most recent deposits. The Ogallala formation is water bearing and is the source of supply for some domestic and livestock wells. The saturated part of the sand and gravel formations of Pleistocene age, which yields water freely to wells, is the most important aquifer in the Middle Loup division. The water generally is under water-table conditions. The yields of properly constructed wells range from a few gallons per minute (gpm) to as much as 1,800 gpm. Some wells tap water in both the sand and gravel of Pleistocene age and in the underlying Ogallala formation. No wells are known to penetrate into formations older than the Ogallala. Fluctuations of the water table indicate changes in the amount of ground water stored in the water-bearing formations. The principal factors controlling the rise of the water table are the amount of precipitation within the area, the quantity of water coming into the area as underflow from the west and northwest, seepage from the Middle Loup River at times when the water surface in the river is higher than the adjoining water table, and the infiltration of irrigation water not utilized by vegetation or lost by runoff or evaporation. The principal factors controlling the decline of the water table are the discharge as effluent seepage into the Middle Loup River and its tributaries, the amount of water pumped from wells, evapotranspiration losses, and the amount of water leaving the area as underflow. Periodic water-level measurements were made in a total of 241 observation wells during the period 1948-50. Hydrographs of three observation wells having a longer period of record (1934-50) indicate that the water table rose slightly from 1934 until 1950 and that it remained nearly constant during the 1950 water year. The configuration of the water table in the Middle Loup division shows that, except north and northwest of Sargent, the Middle Loup River is an effluent, or gaining, stream throughout its entire length in this area. Thus any rise or fall in the ground-water level will increase or decrease the discharge of the river. The river recharges the ground- water reservoir only during periods when it is at flood stage. The depth to the water table from the land surface is governed largely by irregularities in topography. The depth to water is less than 10 feet near the river and increases to as much as 60 feet near the valley margins and the bordering intermediate slopes. In the Far- well unit the depth to water is more than 100 feet and in some parts more than 150 feet. Ground water pumped from wells is the source of supply for the principal municipalities in th

Water Supply Paper↗

Quality of surface waters in the lower Columbia River Basin

This report, made during 1959-60, provides reconnaissance data on the quality of waters in the lower Columbia River basin ; information on present and future water problems in the basin; and data that can be employed both in water-use studies and in planning future industrial, municipal, and agricultural expansion within this area. The lower Columbia River basin consists of approximately 46,000 square miles downstream from the confluence of the Snake and Columbia Rivers The region can be divided into three geographic areas. The first is the heavily forested, sparsely populated mountain regions in which quality of water in general is related to geologic and climatological factors. The second is a semiarid plateau east of the Cascade Mountains; there differences in geology and precipitation, together with more intensive use of available water for irrigation, bring about marked differences in water quality. The third is the Willamette-Puget trough area in which are concentrated most of the industry and population and in which water quality is influenced by sewage and industrial waste disposal. The majority of the streams in the lower Columbia River basin are calcium magnesium bicarbonate waters. In general, the rivers rising in the. Coast Range and on the west slope of the Cascade Range contain less than 100 parts per million of dissolved solids, and hardness of the water is less than 50 parts per million. Headwater reaches of the streams on the east slope of the Cascade Range are similar to those on the west slope; but, downstream, irrigation return flows cause the dissolved-solids content and hardness to increase. Most of the waters, however, remain calcium magnesium bicarbonate in type. The highest observed dissolved-solids concentrations and also some changes in chemical composition occur in the streams draining the more arid parts of the area. In these parts, irrigation is chiefly responsible for increasing the dissolved-solids concentration and altering the chemical composition of the streams. The maximum dissolved-solids concentration and hardness of water observed in major irrigation areas were 507 and 262 parts per million, respectively, for the. Walla Walla River near Touchet, Wash. In terms of the U.S. Salinity Laboratory Staff classification (1954, p. 80), water in most streams in the basin has low salinity and sodium hazards and is suitable for irrigation. A salt-balance problem does exist in the Hermiston-Stanfield, Oreg., area of the Umatilla River basin, and because of poor drainage, improper irrigation practices could cause salt-balance problems in the Willamette River Valley, Oreg., in which irrigation is rapidly increasing. Pollution by sewage disposal has reached undesirable levels in the Walla Walla River, in the Willamette River from Eugene to Portland, Oreg., and in the Columbia River from Portland to Puget Island. In the lower reaches of the Willamette River, the pollution load from sewage and industrial-waste disposal at times depletes the dissolved oxygen in the water to concentrations below what is considered necessary for aquatic life. Water in most of the tributaries to the lower Columbia River is of excellent quality and after some treatment could be used for industrial and municipal supplies. The principal treatment required would be disinfection and turbidity removal.

Water Supply Paper↗

Organic carbon and nitrogen concentrations and annual organic carbon load of six selected rivers of the United States

The organic carbon load during 1969-70 of each of the six rivers in this study is substantial. The 3.4-billion-kilogram (3.7-million-ton) and 47-million-kilogram (52-thousandton) annual organic carbon loads of the Mississippi River and the Brazos River (Tex.), respectively, were approximately equally distributed between dissolved and suspended phases, whereas the 725-million-kilogram (79.8-million-ton) organic load of the Missouri River was primarily in the suspended phase. The major portion of the 6.4-million-kilogram (7.3 thousand-ton) and the 19-million-kilogram (21-thousand-ton) organic carbon loads of the Sopchoppy River (Fla.) and the Neuse River (N.C.), respectively, was in the dissolved phase. DOC (dissolved organic carbon) concentrations in most rivers were usually less than 8 milligrams per litre. SOC (suspended organic carbon) concentrations fluctuated markedly with discharge, ranging between 1 and 14 percent, by weight, in sediment of most rivers. DOC concentrations were found to be independent of discharge, whereas SOC and SIC (suspended inorganic carbon) concentrations were positively correlated with discharge. Seasonal fluctuations in DOC and SOC were exhibited by the Missouri, Neuse, Ohio, and Brazos Rivers, but both SOC and DOC concentrations were relatively constant throughout the year in the Mississippi and Sopchoppy Rivers. The carbon-nitrogen ratio in the sediment phase of all river waters averaged less than 8 1 as compared with 12:1 or greater for most soils. This high nitrogen content shows a nitrogen enrichment of the stream sediment over that in adjacent soils, which suggests that different decomposition and humification processes are operating in streams than in the soils. The abundance of organic material in the dissolved and suspended phase of all river waters in this study indicate a large capacity factor for various types of organic reactivity within all streams and the quantitative importance of organic constituents in relation to the water quality of rivers and streams.

Water Supply Paper↗

Analysis of water quality of the Mahoning River in Ohio

The Mahoning River drains the densely populated and industrialized Warren-Youngstown area in northeastern Ohio. Significant chemical constituents and physical properties generally regarded as important in establishing water-quality standards for the Mahoning River are evaluated on the basis of hydrologic conditions and water use. Most of the interpretations and the appraisal of water-quality conditions are based on data collected from January 1963 to December 1965. Generally, streamflow during this period was lower than during a selected long-term reference period ; however, extremely low flows that occurred in the reference period did not occur in the 3-year study period. Water temperatures of the Mahoning River at Pricetown and Leavittsburg were not affected by thermal loading. Water temperatures at those stations ranged from the freezing point to 78?F during the 1963-65 period. Downstream from Leavittsburg, the use of large quantities of water for industrial cooling caused critical thermal loading during periods of low streamflow. Maximum water temperatures were 108?F and 104?F at Struthers and Lowellville, respectively. Water temperatures of the Mahoning River were lower during high water discharges and increased with higher steel-production indices. Flow augmentation and modifications in industrial processes have improved the water-temperature conditions in recent years. A combination of oxygen-consuming materials and warmed water from industrial and municipal wastes discharged into the lower reaches of the Mahoning River frequently depleted the dissolved-oxygen content. At Lowellville, the river water had a dissolved-oxygen content of 5 ppm (parts per million) or less for 67 percent of the time and 3 ppm or less for 16 percent of the time during the study period. The percentage of saturation of dissolved oxygen followed a similar trend. Both the dissolved-oxygen concentration and the percentage of saturation were noticeably lower downstream from Leavittsburg during the warm months when water temperatures were high and streamflow was low. The dissolved-oxygen content in the Mahoning River at Leavittsburg and Pricetown was almost always at acceptable levels. The calculated dissolved-solids concentration of the Mahoning River ranged from 150 to 450 ppm at Leavittsburg and from 200 ppm to 650 ppm at Lowellville. Industrial use of the water caused an increase in the dissolved-solids concentration at Lowellville. During one steel-mill shutdown the average dissolved-solids concentration decreased from about 360 to about 280 ppm. Chloride concentrations in the Mahoning River ranged from 42 ppm at Pricetown to 108 ppm at Struthers. The chloride load at 50-percent flow duration was 9 and 69 tons per day at Pricetown and Lowellville, respectively. The chloride content of the Mahoning River was well within acceptable levels. Sulfate from wastes disposal and acid mine drainage made up the largest quantity of dissolved-solids load in the Mahoning River. The sulfate load at 50-percent flow duration increased from 38 tons per day at Pricetown to 300 tons per day at Lowellville. At Pricetown the sulfate load ranged from about 2 to 588 tons per day, while at Lowellville, downstream from the industrialized area, the range was from 106 to 2,420 tons per day. Comparison of sulfate loads during periods of steel production with periods of steel-mill shutdown indicated that during low flow about half the sulfate load at Lowellville was derived from steel-mill wastes when the production index was 100. The alkalinity load of the Mahoning River at 50-percent flow duration increased from Pricetown (23 tons per day) to Lowellville (41 tons per day). During steel production the alkalinity of the water showed a marked decrease from Leavittsburg downstream to Lowellville. However, during steel-mill shutdowns the chemical composition of the river at Youngstown and Lowellville was similar to that at Leavittsburg. Acid mine drainag

Water Supply Paper↗

Magnitudes, nature, and effects of point and nonpoint discharges in the Chattahoochee River Basin, Atlanta to West Point Dam, Georgia

During the period April 1975 to June 1978, the U.S. Geological Survey conducted a river-quality assessment of the Upper Chattahoochee River basin in Georgia. One objective of the study was to assess the magnitudes, nature, and effects of point and non-point discharges in the Chattahoochee River basin from Atlanta to the West Point Dam. On an average annual basis and during the storm period of March 1215, 1976, non-point-source loads for most constituents analyzed were larger than point-source loads at the Whitesburg station, located on the Chattahoochee River about 40 river miles downstream of Atlanta. Most of the non-point-source constituent loads in the Atlanta-to-Whitesburg reach were from urban areas. Average annual point-source discharges accounted for about 50 percent of the dissolved nitrogen, total nitrogen, and total phosphorus loads, and about 70 percent of the dissolved phosphorus loads at Whitesburg. During weekends, power generation at the upstream Buford Dam hydroelectric facility is minimal. Streamflow at the Atlanta station during dry-weather weekends is estimated to be about 1,200 ft3/s (cubic feet per second). Average daily dissolved-oxygen concentrations of less than 5.0 mg/L (milligrams per liter) occurred often in the river, about 20 river miles downstream from Atlanta during these periods from May to November. During a low-flow period, June 1-2, 1977, five municipal point sources contributed 63 percent of the ultimate biochemical oxygen demand, 97 percent of the ammonium nitrogen, 78 percent of the total nitrogen, and 90 percent of the total phosphorus loads at the Franklin station, at the upstream end of West Point Lake. Average daily concentrations of 13 mg/L of ultimate biochemical oxygen demand and 1.8 mg/L of ammonium nitrogen were observed about 2 river miles downstream from two of the municipal point sources. Carbonaceous and nitrogenous oxygen demands caused dissolved-oxygen concentrations between 4.1 and 5.0 mg/L to occur in a 22-mile reach of the river downstream from Atlanta. Nitrogenous oxygen demands were greater than carbonaceous oxygen demands in the reach from river mile 303 to 271, and carbonaceous demands were greater from river mile 271 to 235. The heat load from the Atkinson-McDonough thermoelectric power-plants caused a decrease in the dissolved-oxygen concentrations of about 0.2 mg/L. During a critical low-flow period, a streamflow at Atlanta of about 1,800 ft3/s, with present (1977) point-source flows of 185 ft3/s containing concentrations of 45 mg/L of ultimate biochemical oxygen demand and 15 mg/L of ammonium nitrogen, results in a computed minimum dissolved-oxygen concentration of 4.7 mg/L in the river downstream from Atlanta. In the year 2000, a streamflow at Atlanta of about 1,800 ft3/s with point-source flows of 373 ft3/s containing concentrations of 45 mg/L of ultimate biochemical oxygen demand and 5.0 mg/L of ammonium nitrogen, will result in a computed minimum dissolved-oxygen concentration of 5.0 mg/L. A streamflow of about 1,050 ft3/s at Atlanta in the year 2000 will result in a dissolved-oxygen concentration of 5.0 mg/L if point-source flows contain concentrations of 15 mg/L of ultimate biochemical oxygen demand and 5.0 mg/L of ammonium nitrogen. Phytoplankton concentrations in West Point Lake, about 70 river miles downstream from Atlanta, could exceed 3 million cells per milliliter during extended low-flow periods in the summer with present point- and non-point-source nitrogen and phosphorus loads. In the year 2000, phytoplankton concentrations in West Point Lake are not likely to exceed 700,000 cells per milliliter during extended low-flow periods in the summer, if phosphorus concentrations do not exceed 1.0 mg/L in point-source discharges.

Georgia↗

Geohydrology and model analysis of stream-aquifer system along the Arkansas River in Kearny and Finney Counties, southwestern Kansas

A study was made, in cooperation with the Division of Water Resources, Kansas State Board of Agriculture, to determine geohydrologic conditions in an area comprising nearly 850,000 acres along the Arkansas River valley in Kearny and Finney Counties, southwestern Kansas. The Arkansas River meanders atop and interacts hydraulically with the area's multilayered, unconsolidated aquifer system. Declines in static water levels in wells in the heavily pumped lower aquifer ranged from 20 to 80 feet during 1974-80. The river is dry in much of the area. A digital computer model was calibrated to simulate the trends of historic water levels. Simulated 1974-80 conditions depicted an average annual recharge to the unconsolidated aquifer system of 66,900 acre-feet from precipitation and 36,200 acre-feet from river and canal seepage and boundary inflow. Simulated average annual discharge consisted of 634,800 acre-feet from pumpage and boundary outflow. Simulated average annual recharge to the unconsolidated aquifer system was 531,700 acre-feet less than average annual discharge, indicating the ground-water resource is currently (1982) being mined in the study area. Simulation also indicated that there would be sufficient saturated thickness in 2005 for irrigation if 1980 hydrologic conditions continued. Seepage losses from the Arkansas River and irrigation canals are a major source of recharge to the unconsolidated aquifer system. Therefore, the amount of flow in the Arkansas River would be important in determining the rate of future water-level declines in the study area. Streamflow seepage losses could be decreased by (1) decreasing the number of wells pumping in the study area in order to reduce downward leakage from the valley aquifer, or (2) increasing streamflow discharge in order to recharge the valley aquifer. The rate and direction of flow between the river and the valley aquifer depend on the hydraulic conductivity of the streambed and the hydraulic gradient between the river stage and the water table. As long as river stage remains high, the water table in the valley aquifer continues to rise. Seepage from the river to the valley aquifer decreases as the altitude difference between the river stage and the valley aquifer decreases, becoming insignificant when the water level in the valley aquifer nearly equals river stage. However, a rise in the water table in the valley aquifer because of recharge from the river will correspond to increased downward leakage to the lower aquifer, impeding recharge to the valley aquifer.

Kansas↗