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Timescales and processes of methane hydrate formation and breakdown, with application to geologic systems

Gas hydrate is an ice-like form of water and low molecular weight gas stable at temperatures of roughly -10ºC to 25ºC and pressures of ~3 to 30 MPa in geologic systems. Natural gas hydrates sequester an estimated one-sixth of Earth’s methane and are found primarily in deepwater marine sediments on continental margins, but also in permafrost areas and under continental ice sheets. When gas hydrate is removed from its stability field, its breakdown has implications for the global carbon cycle, ocean chemistry, marine geohazards, and interactions between the geosphere and the ocean-atmosphere system. Gas hydrate breakdown can also be artificially driven as a component of studies assessing the resource potential of these deposits. Furthermore, geologic processes and perturbations to the ocean-atmosphere system (e.g., warming temperatures) can cause not only dissociation, but also more widespread dissolution of hydrate or even formation of new hydrate in reservoirs. Linkages between gas hydrate and disparate aspects of Earth’s near-surface physical, chemical, and biological systems render an assessment of the rates and processes affecting the persistence of gas hydrate an appropriate Centennial Grand Challenge. This paper reviews the thermodynamic controls on methane hydrate stability and then describes the relative importance of kinetic, mass transfer, and heat transfer processes in the formation and breakdown (dissociation and dissolution) of gas hydrate. Results from numerical modeling, laboratory, and some fields studies are used to summarize the rates of hydrate formation and breakdown, followed by an extensive treatment of hydrate dynamics in marine and cryospheric gas hydrate systems.

Journal of Geophysical Research-Solid Earth↗

Separating sea and slow slip signals on the seafloor

Seafloor pressure measurements hold promise for estimating vertical displacements from transient slow slip events on submarine faults. We assess the accuracy of pressure offset estimates that evolve over days to weeks and the confidence with which they may be attributed to tectonic deformation or to the ocean water column. One common approach to resolve this ambiguity assumes water column pressures vary insignificantly over the study region and are represented by stable reference site pressures. Assessing the validity of this assumption requires independent evidence. Correlations between pressures and colocated temperatures collected during the Hikurangi Ocean Bottom Investigation of Tremor and Slow Slip experiment suggest temperatures might provide a useful independent proxy for water column pressures. We compared offsets estimated using several methods, with temperature and other proxies. The use of a temperature proxy was unsuccessful, because seafloor temperatures did not track the seasonal signal that contributes significantly to seafloor pressure changes over the slow slip event period. Regardless of the estimation method, offsets varied within a few cm around some uncertain reference level. Commonly used statistical measures are shown not to be reliable indicators of offset accuracy since offsets contribute minimally to the total variance. Offsets estimated using identical methods but with seafloor pressures simulated using a regional ocean model were larger than those derived from the data but had a similar pattern. Since the model simulates only water column processes, this suggests a significant fraction of the estimated pressure offsets are due to seasonal water column signal and are not of tectonic origin.

Journal of Geophysical Research- Solid Earth↗

Silicate volcanism on Europa’s seafloor and implications for habitability

Habitable ocean environments on Europa require an influx of reactants to maintain chemical disequilibrium. One possible source of reactants is seafloor volcanism. Modeling has shown that dissipation of tidal energy in Europa's asthenosphere can generate melt, but melt formation cannot be equated with volcanism. Melt must also be transported through Europa's cold lithosphere to erupt at the seafloor. Here, we use two models of dike propagation to show that dikes can only traverse the lithosphere if either the fracture toughness of the lithosphere or the flux into the dike is large (>500 MPa m 1/2 or ∼1 m 2 s −1 , respectively). We conclude that cyclic volcanic episodes might provide reactants to Europa's ocean if magma accumulates at the base of the lithosphere for several thousand years. However, if dikes form too frequently, or are too numerous, the magma flux into each will be insufficient, and volcanism cannot support a habitable ocean environment.

Geophysical Research Letters↗

Comparative properties of saponitic fault gouge and serpentinite muds cored from mud volcanoes of the Mariana subduction zone

We obtained 12 core samples for physical and chemical characterization from three serpentinite mud volcanoes (Yinazao, Asùt Tesoru, and Fantangisña) located on the forearc of the Mariana subduction system, that were drilled during International Ocean Discovery Program Expedition 366. Two samples from the Fantangisña mud volcano are interpreted to be clay-rich fault gouges derived from the subduction channel. Their bulk compositions are intermediate between the serpentinites and oceanic basalts. The oceanic crustal materials in the gouges have been thoroughly metasomatized and the serpentinites extensively altered to the trioctahedral, Mg-rich smectite clays saponite and corrensite. The only relict phases in clasts of crustal rock are accessory Ti- and P-bearing minerals. The two fault gouge samples have lower frictional strengths ( μ < 0.2) than the serpentinites ( μ = 0.2–0.4), and their measured permeabilities are also somewhat lower. Their physical and compositional properties correspond to saponitic gouges from other faults that juxtapose serpentinite against crustal rocks, in particular gouges from the two creeping traces of the San Andreas Fault recovered in the core from the San Andreas Fault Observatory at Depth. The décollement beneath Fantangisña mud volcano is thus expected to be very weak and likely characterized by stable slip.

Geophysics, Geochemistry, Geosystems↗

Rupture process of the Mw7.0 December 5, 2024 Offshore Cape Mendocino earthquake

The Mw7.0 December 5, 2024 Offshore Cape Mendocino earthquake ruptured a km long portion of the east-west trending Mendocino fault zone (MFZ). In order to clarify the rupture process, we assemble three-component seismograms from regional seismic stations, horizontal coseismic displacement vectors derived from Global Navigation Satellite System (GNSS) time series, and a Sentinel-1 ascending interferogram. These data are interpreted with a model of slip distributed on two vertical fault planes representative of the eastern MFZ and spanning the ~70 km length of the aftershock zone. Assuming right-lateral strike slip, we find that the rupture initiates in the oceanic mantle at 20-30 km depth and proceeds unilaterally updip and toward the east. Early aftershocks locate adjacent to the peak slip areas, tracking the coseismic rupture propagation from oceanic mantle to shallower depth and implying a significant role of static stress transfer in driving aftershocks in an ocean plate environment.

California↗

Magmatic heat and the El Niño cycle

Large submarine lava flows with apparent volumes exceeding 10 km 3 have recently been imaged on the deep ocean floor in various parts of the Pacific by means of GLORIA and SeaMarc side‐looking sonar surveys. Such flows may produce thermal anomalies large enough to perturb the cyclic processes of the ocean and could be a factor in the genesis of El Niño phenomena. We find that known volume rates of mid‐ocean magma production could generate repetitive thermal anomalies as large as 10% of the average El Niño sea surface anomaly at intervals of about 5 years (the mean interval of El Niño events between 1935 and 1984). Likewise, estimated rates of eruption, cooling of lava on the seafloor, and transfer of heat to the near‐surface environment could reasonably produce a thermal anomaly comparable to that associated with El Niño. Larger magmatic events, associated with fluctuations in the total magmatic power and seismicity along the East Pacific Rise, are possible at longer intervals and may explain the extreme size of some El Niño events, such as that of 1982–1983. ©1988. American Geophysical Union. All Rights Reserved.

Eos, Transactions, American Geophysical Union↗

Two major Cenozoic episodes of phosphogenesis recorded in equatorial Pacific seamount deposits

Seamount phosphorites have been recognized since the 1950s, but this is the first study to provide an in depth exploration of the origin and history of these widespread deposits. Representative samples from equatorial Pacific Cretaceous seamounts were analyzed for chemical, mineralogical, and stable isotope compositions. The phosphorites occur in a wide variety of forms, but most commonly carbonate fluorapatite (CFA) replaced middle Eocene and older carbonate sediment in a deep water environment (>1000 m). Element ratios distinguish seamount phosphorites from continental margin, plateau, and insular phosphorites. Uranium and thorium contents are low and total rare earth element (REE) contents are generally high. REE ratios and shale-normalized patterns demonstrate that the REEs and host CFA were derived from seawater. Strontium isotopic compositions compared with inferred Cenozoic seawater curves define two major episodes of Cenozoic phosphatization: Late Eocene/early Oligocene (39–34 Ma) and late Oligocene/early Miocene (27–21 Ma); three minor events are also indicated. The major episodes occurred at times of climate transition, the first from a nonglacial to glacial earth and the second from a predominantly glacial to warm earth. The paleoceanographic conditions that existed at those times initiated and sustained development of phosphorite by accumulation of dissolved phosphorus in the deep sea during relatively stable climatic conditions when oceanic circulation was sluggish. Fluctuations in climate, sealevel, and upwelling that accompanied the climate transitions may have driven cycles of enrichment and depletion of the deep-sea phosphorus reservoir. As temperature gradients in the oceans increased, Antarctic glaciation expanded and oceanic circulation and upwelling intensified. Expansion and intensification of the oxygen minimum zone may have increased the capacity for midwater storage of phosphorus supplied by dynamic upwelling around seamounts; however, the bottom waters never became anoxic during the phosphogenic episodes. Fluctuations in the CCD and lysocline, CO 2 fluxes, and changes in bottom water circulation and temperatures may have bathed the seamount carbonates in more corrosive waters which, coupled with increased supplies of dissolved phosphorus, promoted replacement processes. The late Eocene/early Oligocene phosphogenic episode recorded in seamount deposits is not matched by large phosphorite deposits in the geologic record, whereas the late Oligocene/early Miocene episode and middle Miocene event are matched by large deposits distributed globally. The seamount phosphorites are exposed at the surface of the seamounts and have been for most of the Neogene and Oligocene. The phosphorites do not show signs of etching that would indicate substantial undersaturation of seawater phosphate with respect to CFA. Mass balance calculations indicate that about 5.4–19 × 10 12 g of P 2 O 5 are locked up in equatorial Pacific seamount phosphorites. That amount is equivalent to about 2-7 years of the present annual input from rivers.

Paleoceanography and Paleoclimatology↗

CRUST 5.1: A global crustal model at 5° x 5°

We present a new global model for the Earth's crust based on seismic refraction data published in the period 1948-1995 and a detailed compilation of ice and sediment thickness. An extensive compilation of seismic refraction measurements has been used to determine the crustal structure on continents and their margins. Oceanic crust is modeled with both a standard model for normal oceanic crust, and variants for nonstandard regions, such as oceanic plateaus. Our model (CRUST 5.1) consists of 2592 5° × 5° tiles in which the crust and uppermost mantle are described by eight layers: (1) ice, (2) water, (3) soft sediments, (4) hard sediments, (5) crystalline upper, (6) middle, (7) lower crust, and (8) uppermost mantle. Topography and bathymetry are adopted from a Mandard database (ETOPO-5). Compressional wave velocity in each layer is based on field measurements, and shear wave velocity and density are estimated using recently published empirical V p -V s and V p -density relationships. The crustal model differs from previous models in that (1) the thickness and seismic/density structure of sedimentary basins is accounted for more completely, (2) the velocity structure of unmeasured regions is estimated using statistical averages that are based on a significantly larger database of crustal structure, (3) the compressional wave, shear wave, and density structure have been explicitly specified using newly available constraints from field and laboratory studies. Thus - this global crustal model is based on substantially more data than previous models and differs from them in many important respects. A new map of the thickness of the Earth's crust is presented, and we illustrate the application of this model by using it to provide the crustal correction for surface wave phase velocity maps. Love waves at 40 s are dominantly sensitive to crustal structure, and there is a very close correspondence between observed phase velocities at this period and those predicted by CRUST 5.1. We find that the application of crustal corrections to long-period (167 s) Rayleigh waves significantly increases the variance in the phase velocity maps and strengthens the upper mantle , velocity anomalies beneath stable continental regions. A simple calculation of crustal isostacy indicates significant lateral variations in upper mantle density. The model CRUST 5.1 provides a complete description of the physical properties of the Earth's crust at a scale of 5° × 5° and can be used for a wide range of seismological and nonseismological problems.

Journal of Geophysical Research B: Solid Earth↗

Seismic structure of the southern Cascadia subduction zone and accretionary prism north of the Mendocino triple junction

Four multichannel-seismic reflection profiles, collected as part of the Mendocino triple junction seismic experiment, image the toe of the southern Cascadia accretionary prism. Today, 250–600 m of sediment is subducting with the Gorda plate, and 1500–3200 m is accreting to the northern California margin. Faults imaged west and east of the deformation front show mixed structural vergence. A north-south trending, 20 km long portion of the central margin is landward vergent for the outer 6–8 km of the toe of the prism. This region of landward vergence exhibits no frontal thrust, is unusually steep and narrow, and is likely caused by a seaward-dipping backstop close to the deformation front. The lack of margin-wide preferred seaward vergence and wedge-taper analysis suggests the prism has low basal shear stress. The three southern lines image wedge-shaped fragments of oceanic crust 1.1–7.3 km in width and 250–700 m thick near the deformation front. These wedges suggest shortening and thickening of the upper oceanic crust. Discontinuities in the seafloor west of the prism provide evidence for mass wasting in the form of slump blocks and debris fans. The southernmost profile extends 75 km west of the prism imaging numerous faults that offset both the Gorda basin oceanic crust and overlying sediments. These high-angle faults, bounding basement highs, are interpreted as strike-slip faults reactivating structures originally formed at the spreading ridge. Northeast or northwest trending strike-slip faults within the basin are consistent with published focal mechanism solutions and are likely caused by north-south Gorda-Pacific plate convergence.

Journal of Geophysical Research B: Solid Earth↗

Carbon sequestration and its role in the global carbon cycle

For carbon sequestration the issues of monitoring, risk assessment, and verification of carbon content and storage efficacy are perhaps the most uncertain. Yet these issues are also the most critical challenges facing the broader context of carbon sequestration as a means for addressing climate change. In response to these challenges, Carbon Sequestration and Its Role in the Global Carbon Cycle presents current perspectives and research that combine five major areas: • The global carbon cycle and verification and assessment of global carbon sources and sinks • Potential capacity and temporal/spatial scales of terrestrial, oceanic, and geologic carbon storage • Assessing risks and benefits associated with terrestrial, oceanic, and geologic carbon storage • Predicting, monitoring, and verifying effectiveness of different forms of carbon storage • Suggested new CO 2 sequestration research and management paradigms for the future. The volume is based on a Chapman Conference and will appeal to the rapidly growing group of scientists and engineers examining methods for deliberate carbon sequestration through storage in plants, soils, the oceans, and geological repositories.

Book↗

Implications of regional gravity for state of stress in the earth's crust and upper mantle

Topography is maintained by stress differences within the earth. Depending on the distribution of the stress we classify the support as either local or regional compensation. In general, the stresses implied in a regional compensation scheme are an order of magnitude larger than those corresponding to local isostasy. Gravity anomalies, a measure of the earth's departure from hydrostatic equilibrium, can be used to distinguish between the two compensation mechanisms and thus to estimate the magnitude of deviatoric stress in the crust and upper mantle. Topography created at an oceanic ridge crest or in a major continental orogenic zone appears to be locally compensated. Such features were formed on weak crust incapable of maintaining stress differences much greater than the stress from the applied load. Oceanic volcanoes formed on an already cooled, thickened lithosphere are regionally supported with elastic stresses. Similarly, the broad topographic rise seaward of subduction zones is elastically supported as the lithosphere is bent near the plate margin. Although the implied stress is to some degree dependent on the rheological model assumed, the gravity anomalies and surface deformation produced by these features demonstrate that the upper 30–40 km of the oceanic lithosphere is capable of regionally supporting stress differences in the 100-MPa range. Given certain conditions of load emplacement, continental crust can also support loads regionally over 100-m.y. time scales, but the effects of erosion only allow an estimate of a lower bound on stress. Data from space probes indicate that the upper layers of other terrestrial planets also support topographic-induced stress differences in excess of 100 MPa.

Journal of Geophysical Research Solid Earth↗

Lead and strontium isotopes and related trace elements as genetic tracers in the Upper Cenozoic rhyolite-basalt association of the Yellowstone Plateau volcanic field

Supported by various field geologic and petrologic data, the contents of Pb, U, Th, Rb, and Sr and the isotopic compositions of Pb and Sr for upper Cenozoic volcanic rocks of the Yellowstone Plateau volcanic field are consistent with the hypothesis of derivation of the basaltic and rhyolitic magmas by partial melting of distinct source regions in the upper mantle and lower crust, respectively. All the basalt samples analyzed but one have systematically lower values of 207 Pb/ 204 Pb and 87 Sr/ 86 Sr than the rhyolites. The values of 206 Pb/ 204 Pb are smaller, and 87 Sr/ 86 Sr are mostly larger than known values in oceanic basalts. In all but one case, the values of 207 Pb/ 204 Pb are higher than expected from an extrapolation of known values in oceanic basalts to less radiogenic values of 206 Pb/ 204 Pb. Because there are no xenoliths, phenocrysts are only moderate to sparse in abundance, REE patterns are low and flat at the radiogenic end of lead isotopic compositions, several values of Rb/Sr are low, and 80% of the basalt samples form a well-developed secondary isochron separate from the rhyolites, we favor an interpretation for basalt genesis wherein isotopic signatures of most mafic magmas were attained in a continental ‘keel’ of mantlelike character about 2.6 b.y. old or somewhat older attached to the crust, and these signatures were unaltered by magma passage through the crust. At the very least, the current data continue to cast serious doubt as to the inevitability of crustal contamination for basaltic magma intruding the continental environment and postulate that much can be learned about the mantle under continents through the study of continental basalts. One basalt unit with an unusually low value of 207 Pb/ 204 Pb and an 87 Ar/ 86 Ar less than 0.704 may represent subcontinental ‘keel’-derived magma that rose unaltered to the surface. Our data also are not consistent with formation of this rhyolite-basalt association primarily by such processes as crystal fractionation, separation of immiscible silicate liquids from a common parental magma, or fractional melting of a homogeneous source. Rather as a conceptual model, we envision large mafic intrusions to have been injected into the lower crust resulting in rhyolite generation through partial anatexis of the adjacent wall rocks which probably had a 206 Pb/ 204 Pb < 17 and 87 Sr/ 86 Sr > 0.709; a model that has much in common with that proposed by Holmes (1931). All the other hypotheses listed have the necessary added complication that either the basalt or the rhyolite or both become contaminated after the two magma types separated, have problems accounting for the lack of igneous rocks of intermediate compositions or production of such large volumes of rhyolitic material (∼5000 km 3 ), and fail to explain why rhyolitic magma is not a more common occurrence in the ocean basin. We appeal to bouyancy of rhyolites to generate a barrier for basalt magma migration and account for the great preponderance of rhyolite relative to basalt at the surface. Furthermore, the complex isotopic picture in the rhyolites indicates that many of these magmas interacted with the upper crustal geologic units that they traversed. The interactions involved diverse processes, probably including reacton with hydrothermal fluids or hydrothermally altered rocks at high levels as well as by contamination with Phanerozoic sedimentary and Precambrian crystalline rocks at deeper levels. At the very least, we feel our study adds a cautionary note to the currently increasingly popular hypothesis that differentiation of basalt or gabbro magmas to rhyolite or granite (as distinct from tonalite or dacite) is a common occurrence and is therefore an important continential building process. Models for formation of rhyolite and granite predominantly by reworking of crust (anatexis) must still be considered. The primitive Archean mantle of the region was characterized by higher Rb/Sr, U/Pb, and Th/U values than are typical of modern suboceanic mantle. The mantle residuum within the continental subcrustal lithosperic ‘keel’ that resulted from the Archean crustal differentiation event probably was depleted in Rb/Sr and U/Pb, and the crust was correspondingly enriched in these ratios. The crust probably was further differentiated by an Archean high-grade metamorphism, during or after the primary event, into a granulitic lower crust depleted in U/Pb and Rb/Sr and a lower-grade upper crust enriched in these ratios.

Journal of Geophysical Research Solid Earth↗

Lu-Hf and Sm-Nd evolution in lunar mare basalts

Lu-Hf and Sm-Nd data for mare basalts combined with Rb-Sr and total REE data taken from the literature suggest that the mare basalts were derived by small (≤10%) degrees of partial melting of cumulate sources, but that the magma ocean from which these sources formed was light REE and Hf-enriched. Calculated source compositions range from lherzolite to olivine websterite. Nonmodal melting of small amounts of ilmenite (≤3%) in the sources seems to be required by the Lu/Hf data. A comparison of the Hf and Nd isotopic characteristics between the mare basalts and terrestrial oceanic basalts reveals that the εHf/εNd ratios in low-Ti mare basalts are much higher than in terrestrial oceanic basalts. The results are qualitatively consistent with the hypothesis that terrestrial basalt sources are partial melt residues whereas mare basalt sources are cumulates. Alternatively, the results may imply that the terrestrial mantle has evolved in two (or more) stages of evolution, and that the net effect was depletion of the mantle during the first ∼1–3 b.y. followed by enrichment during the last 1–2 b.y.; or simply that there is a difference in Lu-Hf crystal-liquid partitioning (relative to Sm-Nd between the lunar and terrestrial mantles.

Journal of Geophysical Research Solid Earth↗

Geologic implications of topographic, gravity, and aeromagnetic data in the northern Yukon-Koyukuk province and its borderlands, Alaska

The northern Yukon-Koyukuk province is characterized by low elevation and high Bouguer gravity and aeromagnetic anomalies in contrast to the adjacent Brooks Range and Ruby geanticline. Using newly compiled digital topographic, gravity, and aeromagnetic maps, I have divided the province into three geophysical domains. The Koyukuk domain, which is nearly equivalent to the Koyukuk lithotectonic terrane, is a horseshoe-shaped area, open to the south, of low topography, high gravity, and high-amplitude magnetic anomalies caused by an intraoceanic magmatic arc. The Angayucham and Kanuti domains are geophysical subdivisions of the Angayucham lithotectonic terrane that occur along the northern and southeastern margins of the Yukon-Koyukuk province, where oceanic rocks have been thrust over continental rocks of the Brooks Range and Ruby geanticline. Basalt of the Angayucham domain causes strong gravity highs and weak magnetic highs. The Kanuti domain is distinguished from the Angayucham domain by intense magnetic highs caused by cumulus mafic and ultramafic plutonic rocks, abundant ultramafic mantle tectonites, and magnetic syenite and monzonite. Long-wavelength, low-intensity magnetic highs and undulating gravity anomalies indicate an undulating basement surface of varied lithology beneath the Kobuk-Koyukuk and Lower Yukon basins. Modeling of gravity and magnetic anomalies shows that oceanic rocks of the Angayucham and Kanuti domains dip inward beneath the Kobuk-Koyukuk basin. The modeling supports, but does not prove, the hypothesis that the crust of the Kobuk-Koyukuk basin is 32–35 km thick, consisting of a tectonically thickened section of Cretaceous volcanic and sedimentary rocks and older oceanic crust. Plutons of the Brooks Range and the southern Ruby geanticline are nonmagnetic, ilmenite series, S-type granites that cause magnetic lows. Plutons of the northern Ruby geanticline are variable in their magnetic properties and cause both highs and lows. Plutons of both the eastern and western Yukon-Koyukuk province are variable in their magnetic expression but commonly cause magnetic lows in contrast to andesite.

Journal of Geophysical Research Solid Earth↗

The nature of the crust in the Yukon-Koyukuk province as inferred from the chemical and isotopic composition of five Late Cretaceous to Early Tertiary volcanic fields in western Alaska

Late Cretaceous and early Tertiary volcanic and plutonic rocks in western Alaska comprise a vast magmatic province extending from the Alaska Range north to the Arctic Circle, south to Bristol Bay, and west to the Bering Sea Shelf. The chemical and isotopic composition of five of these Late Cretaceous to early Tertiary volcanic fields in the north central part of this province were studied to determine if Paleozoic or older continental crust underlies the Yukon-Koyukuk province. Three of the fields, the Blackburn Hills, Yukon River, and Kanuti, occur within the Yukon-Koyukuk province and two, the Sischu and Nowitna, overlie bordering Precambrian and Paleozoic metamorphic terranes to the southeast. High initial 87 Sr/ 86 Sr of 0.7075–0.7079 and moderate initial 143 Nd/ 144 Nd of 0.51244–0.51247 of rhyolite, dacite, and high-silica andesite of the Sischu volcanic field indicate that the magmas have interacted with the underlying Paleozoic or older continental crust. The relatively limited variation of isotopic (initial 87 Sr/ 86 Sr = 0.7044–0.7051; initial 143 Nd/ 144 Nd = 0.51256–0.51257) and elemental compositions of andesites from the Nowitna field can be accounted for by assimilation of small amounts of Paleozoic or older continental crust during crystal fractionation of andesite parent magmas at crustal levels. The Blackburn Hills field, which consists of medium-K basalt, andesite, and rhyolite intruded by a small granitic pluton, has a large range in initial 87 Sr/ 86 Sr and initial 143 Nd/ 144 Nd that plot in the field for 60 Ma mantle, from near mid-ocean ridge basalts to near “bulk-earth” compositions (initial 87 Sr/ 86 Sr = 0.7033–0.7052; initial 143 Nd/ 144 Nd = 0.51253–0.51290). Andesites and basalts from the Blackburn Hills are divided into two group on the basis of rare earth element (REE) and isotopic composition. Isotopic variation in the more primitive group 1 is best explained by assimilation of the lower crust of the Jurassic to Early Cretaceous Koyukuk terrane by mantle-derived basalts during crystal fractionation, though part of the isotopic variation may be due to metasomatism of an oceanic island basalt type mantle source by fluids derived from subducted sediments. Group 2 andesites from the Blackburn Hills have lower heavy REE abundances and more enriched isotopic compositions. These group 2 andesites and dacites from the Kanuti field, which have ( 87 Sr/ 86 Sr) i = 0.7043–0.7048 and ( 143 Nd/ 144 Nd) i = 0.51248–0.51267, appear to have formed by partial melting of the lower crust of the Koyukuk terrane. The Yukon River field consists of basalt, andesite, dacite, and rhyolite having ( 87 Sr/ 86 Sr) i = 0.7037–0.7051 and ( 143 Nd/ 144 Nd) i = 0.51266–0.51280; its isotopic composition does not require the presence of Paleozoic or older continental crust under the volcanic field and may have formed by interaction between mantle-derived melts and the oceanic Angayucham/Tozitna or island arc Koyukuk terrane. Most of the intrusive rocks and rhyolite domes from the Blackburn Hills volcanic field have ( 87 Sr/ 86 Sr) i = 0.7038–0.7041 and dacites from the Kanuti volcanic field have ( 87 Sr/ 86 Sr) i = 0.7043–0.7048. Thus little or no old continental crust was involved in the genesis of the Late Cretaceous and early Tertiary rocks and therefore probably does not extend beneath this part of the Yukon-Koyukuk province. However, the ultimate source of the small volumes of enriched shoshonitic andesite ( 87 Sr/ 86 Sr = 0.7075, 143 Nd/ 144 Nd = 0.5125) erupted at 118 Ma in the Yukon-Koyukuk province may be continental lithosphere, which may have been thrust under this part of the Yukon-Koyukuk province during arc-continent collision in the Early Cretaceous.

Journal of Geophysical Research Solid Earth↗

Deuterium in interstitial water from deep-sea cores

As part of the Joint Oceanographic Institutions Deep Earth Sampling project, the interstitial waters of cores from 69 holes were sampled for deuterium analysis. Sixteen of the cores penetrated sediments as old as Eocene, and several sampled Cretaceous sediments, which allowed us to examine changes in the deuterium content of the oceans with time. Deuterium is shown to be a conservative constituent of the pore water. Its abundance in the pore fluids can be changed by diffusion, but the rate is slow, and corrections for this effect have been made. Changes in the abundance of deuterium can be related to changes in the amount of ice stored in continental glaciers, inasmuch as precipitation in the form of snow is highly depleted in deuterium compared with the oceans. Many of the cores show a change in isotopic composition of samples from early to late Miocene that can be ascribed to the buildup of the Antarctic ice sheets. After correcting for the role of diffusion in reducing the isotopic contrast between samples from a single core, we estimate an increase of 10 per mil (‰) δD (corresponding to a° δ 18 O change of about 1.2‰) between the early and late Miocene. A similiar analysis of Pleistocene to Holocene changes indicates a δD rise of 8‰ during the time of maximum continental ice, which corresponds to a δ 18 O increase of about 1.0‰. On the basis of limited data, we find no δD change in the oceans from Cretaceous to Miocene.

Journal of Geophysical Research Solid Earth↗

Earth‐tides shown by fluctuations of water‐levels in wells in New Mexico and Iowa

It is quite generally known that ocean‐tides produce fluctuations of the water‐level in wells of the artesian type located close to the seashore by periodically changing the external load on the aquifer [see 1 of “References” at end of paper]. Fluctuations of ground‐water as a result of earth‐tides, however, are not generally known although they were observed and studied in a flooded coal‐mine in Europe [2] as early as 1879, and later 1905 to 1912 in wells in South Africa [3]. The phenomena of earth‐tides first came to the attention of the writer in March, 1938, when studying fluctuations of the water‐level In an artesian well near Carlsbad, New Mexico, recorded on charts of a water‐stage recorder, which had an approximately semidiurnal period. Because of the distance from the ocean, about 500 miles, and the altitude of the water‐bearing formation, about 2700 feet, it appeared that the fluctuations could not be the result of ocean‐tides. Neither did it appear they could be the result of other natural phenomena such as changing air‐pressure or changes in water‐level of a nearby lake and river. There was no pumpage from the aquifer, so the fluctuations of the water could not be caused by pumping. T. M. Cramer, Resident Manager of the United States Potash Company at Carlsbad, New Mexico, suggested that the fluctuations must be the result of some lunar attraction. Further study of the fluctuation was made by Dr. C. V. Theis, of the United States Geological Survey, and the writer, whereby the effect of changing air‐pressure was eliminated by correcting the water‐levels to an assumed constant atmospheric pressure. In this study it was demonstrated after applying the barometric correction that the remaining fluctuations were fairly regular and progressed with the transit of the Moon. It was also demonstrated that the fluctuations were of the greatest amplitude during the period of new Moon. Further work by W. E. Hale, of the United States Geological Survey, and the writer, has shown that the fluctuations were much more regular and of greater amplitude during the periods of new and full Moon than during the first and third quarters. It was, therefore, concluded that they are related to true earth‐tides. A preliminary note was published in the Transactions of the American Geophysical Union for 1938 [4].

New Mexico↗

Palæomagnetic evidence relevant to a change in the earth's radius

INTEREST in the hypothesis that the Earth's radius has increased during geological history has been renewed in recent years because of several sets of independent observations and interpretations. From studies of the deformation of mountain ranges and the distribution of faults and oceans, Carey 1 proposes an increase in the Earth's area of 45 per cent since the Pal&aelig;ozoic era. Heezen 2 similarly interprets submarine topography as indicating that the oceans may be immense rift valleys formed by a pulling apart of the continents as the Earth expanded. Using a different approach, Egyed 3,4 infers a rate of increase of the Earth's radius of 0.4&ndash;0.8 mm. per year. This calculation is based on a decrease in the total amount of continental area covered by oceans during the past 400 million years, as determined pal&aelig;ographically. Egyed 4 has also pointed out the desirability of using pal&aelig;omagnetic data to test this hypothesis.

Nature↗