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The National Field Manual for the Collection of Water-Quality Data (National Field Manual) describes protocols (requirements and recommendations) and provides guidelines for U.S. Geological Survey (USGS) personnel who collect data used to assess the quality of the Nation's surface-water and ground-water resources. This chapter of the manual addresses topics related to personal safety to be used in the collection of water-quality data, including: policies and general regulations on field safety; transportation of people and equipment; implementation of surface-water and ground-water activities; procedures for handling chemicals; and information on potentially hazardous environmental conditions, animals, and plants. Each chapter of the National Field Manual is published separately and revised periodically. Newly published and revised chapters will be announced on the USGS Home Page on the World Wide Web under 'New Publications of the U.S. Geological Survey.' The URL for this page is http://pubs.usgs.gov/publications/ index.html.
Problems of ground-water contamination from leaking surface impoundments are common in surficial aquifers, and are a subject of increasing concern and attention. A potentially widespread contamination problem involves organic chemicals used in wood-preserving processes. Creosote is the most extensively used industrial preservative in the United States today, with more than 400 wood-preserving plants in the United States collectively using 4.5x10 9 kg (kilograms) of creosote per year (von Rumker and others, 1975). It is estimated that creosote contains more than 200 major individual compounds with differing molecular weights, polarities, and functionalities, along with dispersed solids and products of polymerization (Novotny and others, 1981). Analyses of creosote consist of approximately 85 percent by weight polynuclear aromatic hydrocarbons, 12 percent phenolic compounds, and 3 percent heterocyclic compounds containing nitrogen, sulfur, and oxygen. Because of the widespread distribution of creosote in the environment, an abandoned wood-treatment plant in Pensacola, Fla., was selected by the U.S. Geological Survey Office of Hazardous Waste Hydrology as one of three national research demonstration areas in order to increase our understanding of hydrologic processes affecting the distributions of contaminants in ground water. The site was selected because of its long, uninterrupted history (1902 81) of discharging wastewaters to unlined surface impoundments, availability of a preliminary data base (Troutman and others, 1984), and the high probability of useful technology transfer from an investigation of the fate of organic compounds associated with wood-preserving wastewaters in the subsurface environment.
This report describes the effects of urbanization on physical, chemical, and biological characteristics of stream ecosystems in 28 watersheds along a gradient of urbanization in the Willamette River basin and surrounding area, Oregon and Washington, from 2003 through 2005. The study that generated the report is one of several urban-effects studies completed nationally by the U.S. Geological Survey National Water-Quality Assessment Program. Watersheds were selected to minimize natural variability caused by factors such as geology, elevation, and climate, and to maximize coverage of different stages of urban development among watersheds. Because land use or population density alone often are not a complete measure of urbanization, a combination of land use, land cover, infrastructure, and socioeconomic variables were integrated into a multimetric urban intensity index (UII) to represent the degree of urban development in each watershed. Physical characteristics studied include stream hydrology, stream temperature, and habitat; chemical characteristics studied include sulfate, chloride, nutrients, pesticides, dissolved and particulate organic and inorganic carbon, and suspended sediment; and biological characteristics studied include algal, macroinvertebrate, and fish assemblages. Semipermeable membrane devices, passive samplers that concentrate trace levels of hydrophobic organic contaminants such as polycyclic aromatic hydrocarbons and polychlorinated biphenyls, also were used. The objectives of the study were to (1) examine physical, chemical, and biological responses along the gradient of urbanization and (2) determine the major physical, chemical, and landscape variables affecting the structure of aquatic communities. Common effects documented in the literature of urbanization on instream physical, chemical, and biological characteristics, such as increased contaminants, increased streamflow flashiness, increased concentrations of chemicals, and changes in aquatic community structure toward a more tolerant community associated with organically enriched conditions, generally were observed in this study. The strongest correlations to the UII and to many of the algal, macroinvertebrate, and fish assemblage metrics and community ordination involved water-chemistry metrics including the total pesticide concentration, toxic equivalents (extract assay from semipermeable membrane devices), and dissolved oxygen. Hydrologic variability metrics, such as flashiness, that normally are considered to be one of the main processes of urban disturbance had a strong association to the algal and fish assemblages in this study; however, the hydrologic variables for macroinvertebrates were secondary to the water-chemistry metrics mentioned above. Generally, the high urban intensity sites had high abundances of eutrophic and lower dissolved oxygen-indicating diatoms, high abundances of noninsects and tolerant insects, and high abundances of nonnative fish species. On the other hand, the low urban intensity sites had higher abundances of pollution sensitive diatoms, larger numbers of the sensitive macroinvertebrate EPT taxa (Ephemeroptera, Plecoptera and Trichoptera Orders), and fish assemblages with higher abundances of sensitive salmonids. The percent salmonid and macroinvertebrate EPT richness metrics plotted against the UII indicated a possible threshold response at about 25 on the UII, which is equivalent to an impervious surface value of about 5 percent. However, due to the added agricultural land use at sites within the 25 to 60 UII range, this possible threshold probably is not solely due to urbanization, but a combination of urban and agricultural land use. The effects of agricultural and urban land use could not be distinguished from each other, yet combined they provide a good assessment of overall watershed disturbance.
This special volume of aquatic geochemistry is dedicated to the memory of Owen Peterson Bricker III (1936–2011) and serves as a tribute to his life and career. Owen had a distinguished and productive research career in both academics at Johns Hopkins University (Fig. 1) and as a public servant with the Maryland Geological Survey, the US Environmental Protection Agency, and the US Geological Survey. He was a pioneer and leader in aqueous geochemistry, who applied a study approach that quantified mineral weathering reactions and equilibrium thermodynamic relations to better understand the chemical evolution of stream water in small watersheds. He will be especially remembered for his efforts to establish rigorous field studies in small catchments around the United States as a means of quantifying the sources of acid-neutralizing capacity that affect the chemical status and biological health of natural waters.
Analytical scanning transmission electron microscopy has been successfully used to characterize the structure and composition of lamellar exsolution products in pyroxenes. At operating voltages of 100 and 200 keV, microanalytical techniques of x-ray energy analysis, convergent-beam electron diffraction, and lattice imaging have been used to chemically and structurally characterize exsolution lamellae only a few unit cells wide. Quantitative X-ray energy analysis using ratios of peak intensities has been adopted for the U.S. Geological Survey AEM in order to study the compositions of exsolved phases and changes in compositional profiles as a function of time and temperature. The quantitative analysis procedure involves 1) removal of instrument-induced background, 2) reduction of contamination, and 3) measurement of correction factors obtained from a wide range of standard compositions. The peak-ratio technique requires that the specimen thickness at the point of analysis be thin enough to make absorption corrections unnecessary (i.e., to satisfy the “thin-foil criteria”). In pyroxenes, the calculated “maximum thicknesses” range from 130 to 1400 nm for the ratios Mg/Si, Fe/Si, and Ca/Si; these “maximum thicknesses” have been contoured in pyroxene composition space as a guide during analysis. Analytical spatial resolutions of 50–100 nm have been achieved in AEM at 200 keV from the composition-profile studies, and analytical reproducibility in AEM from homogeneous pyroxene standards is ± 1.5 mol% endmember.
In many subsurface situations where human health and environmental quality are at risk (e.g., contaminant hydrogeology petroleum extraction, carbon sequestration, etc.),scientists and engineers are being asked by federal agency decision-makers to predict the fate of chemical species under conditions where both reactions and transport are processes of first-order importance. In 2002, a working group (WG) was formed by representatives of the U.S. Geological Survey, Environmental Protection Agency, Department of Energy Nuclear Regulatory Commission, Department of Agriculture, and Army Engineer Research and Development Center to assess the role of reactive transport modeling (RTM) in addressing these situations. Specifically the goals of the WG are to (1) evaluate the state of the art in conceptual model development and parameterization for RTM, as applied to soil,vadose zone, and groundwater systems, and (2) prioritize research directions that would enhance the practical utility of RTM.
This report, designed to make available to field geologists and others informa- tion obtained in recent investigations by the Geological Survey on identification and occurrence of uranium minerals of the Colorado Plateaus, contains descriptions of the physical properties, X-ray data, and in some instances results of chemical and spectrographic analysis of 48 uranium and vanadium minerals. Also included is a list of locations of mines from which the minerals have been identified.
Physical, chemical, and biological data were collected at 46 sites in the Fox and Des Plaines River Basins as part of the upper Illinois River Basin study of the U.S. Geological Survey?s National Water-Quality Assessment Program. The data, collected from 1999 to 2001, will be used to determine the effects of urbanization on streams in the Chicago, Illinois, metropolitan area. To examine the possible effects of urbanization on stream-water quality, the sampling sites were selected to represent a gradient of land use changing from agriculture into urban. Urban land use for the selected sites ranged from less than 1 percent urban to 92 percent urban. Data-collection methods are presented in the text portion of this report. Physical characteristics of the stream that were collected include descriptive and qualitative habitat and geomorphic measures. Water samples were analyzed for nutrients (nitrogen and phosphorus), 11 major ions, 46 wastewater indicators, pH, and specific conductance. Aquatic communities were sampled to identify and quantify populations of selected algae, benthic macroinvertebrates, and fish. There were 72 unique fish species collected at all of the sites. The number of benthic macroinvertebrate taxa collected at all the sites ranged from 15 to 48. The data and the associated data documentation are presented on a CD-ROM included with this report.
Introduction In 2014 and 2015, the U.S. Geological Survey (USGS) sampled water wells in the Los Angeles Basin and southern San Joaquin Valley, California, and oil wells in the San Joaquin Valley for analysis of multiple chemical, isotopic, and groundwater-age tracers. The purpose of this reconnaissance sampling was to evaluate the utility of tracers for assessing the effects of oil and gas production activities on groundwater quality in California. The study was done in cooperation with the California State Water Resources Control Board. Results of the study are intended to help design a regional groundwater-monitoring program to be implemented as part of California Senate Bill 4 (SB 4 statutes of 2013). The regional monitoring program plans to assess the effects of oil and gas production activities on groundwater quality and to provide a regional context for local monitoring of the groundwater-quality effects from well-stimulation treatments, which are techniques used to improve oil and gas production by increasing their rate of flow to the well. California SB 4 mandates that this local monitoring is to be done by oil-well operators in accordance with monitoring criteria established by the State Water Board. This report evaluates the utility of the chemical, isotopic, and groundwater-age tracers for assessing sources of salinity, methane, and petroleum hydrocarbons in groundwater overlying or near several California oil fields. Tracers of dissolved organic carbon in oil-field-formation water are also discussed. Tracer data for samples collected from 51 water wells and 4 oil wells are examined.
From July 1977 to May 1978, water samples were collected from 116 wells north of the Palouse River in Idaho to define water-quality conditions, on a reconnaissance level, in major aquifers. Geologic and hydrologic data were combined with water-quality data to develop an understanding of factors affecting present and future groundwater quality. Samples were analyzed for 16 major chemical constituents, selected metallic trace elements, pH, specific conductance, water temperature, and total- and fecal-coliform bacteria. Locally, concentrations of dissolved solids, nitrite plus nitrate, iron, and cadmium exceeded mandatory or recommended limits established for public water supplies. Hardness exceeding 300 milligrams per liter may restrict groundwater use esthetically or economically. Groundwater quality is adequate and quantity is sufficient to meet population and economic demands as of 1978.
Disposal of chemical-warfare agents, munitions, and industrial chemicals in J-Field, Aberdeen Proving Ground, Maryland, has resulted in ground-water, surface-water, and soil contamination. This report presents data collected by the U.S. Geological Survey from Novembr 1989 through September 1994 as part of a remedial investigation of J-Field in response to the Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA). Hydrogeologic data, soil-gas and soil-quality data, and water-qualtiy data are included.
In July 1997, the Federal Energy Regulatory Commission (FERC) issued a Final Environmental Impact Statement recommending that the 162-year-old Edwards Dam on the Kennebec River in Augusta, Maine, be removed. The impoundment formed by Edwards Dam extends about 15 mi to the city of Waterville, near the confluence of the Sebasticook River with the Kennebec River. The impoundment has a surface area of 1,143 acres, a gross storage of approximately 740 million ft 3 , and a usable storage of about 184 million ft 3 (Stone and Webster, 1995a). According to FERC, removal of the 917-ft-long, 24-ft-high timber crib and concrete structure would restore 15 mi of riverine habitat, improve passage of ocean-migrating fish species native to the Kennebec River, and result in substantial recreational enhancements (Federal Energy Regulatory Commission, 1997). Because the removal of Edwards Dam would change the hydraulic characteristics of the river in the present-day impoundment, the potential transport of erodible, fine-grained sediment currently in the impoundment is a concern. Of particular concern is the erosion and transport of this sediment to areas downstream from the dam, a process that could introduce possible bacterial and chemical contamination and could impede river navigation as a result of sediment deposition. In an effort to build upon available information on the composition of the riverbed, the U.S. Geological Survey (USGS), in cooperation with the Maine State Planning Office, classified riverbed sediment types and mapped their areal extents in the lower (southern) half of the Edwards Dam impoundment. This report describes the methods used to collect and analyze the data used to create a map of sediment types in the Edwards Dam impoundment. The map is included with this report. Data used to map riverbed sediment types were also used to estimate the volume of observed mud and mud-containing sediment in the study area.
Concentrations, loads, and yields of particle-associated (hydrophobic) contaminants (PACs) in urban runoff in creeks in Austin, Texas, were characterized using an innovative approach: large-volume suspended-sediment sampling. This approach isolates suspended sediment from the water column in quantities sufficient for direct chemical analysis of PACs. During 1999-2004, samples were collected after selected rain events from each of five stream sites and Barton Springs for a study by the U.S. Geological Survey, in cooperation with the City of Austin. Sediment isolated from composited samples was analyzed for major elements, metals, organochlorine compounds, and polycyclic aromatic hydrocarbons (PAHs). In addition, at the Shoal Creek and Boggy Creek sites, individual samples for some events were analyzed to investigate within-event variation in sediment chemistry. Organochlorine compounds detected in suspended sediment included chlordane, dieldrin, DDD, DDE, DDT, and polychlorinated biphenyls (PCBs). Concentrations of PACs varied widely both within and between sites, with higher concentrations at the more urban sites and multiple nondetections at the least-urban sites. Within-site variation for metals and PAHs was smaller than between-site variation, and concentrations and yields of these and the organochlorine compounds correlated positively to the percentage of urban land use in the watershed. Loads of most PACs tested correlated significantly with suspended-sediment loads. Concentrations of most PACs correlated strongly with three measures of urban land use. Variation in suspended-sediment chemistry during runoff events was investigated at the Shoal and Boggy Creek sites. Five of the eight metals analyzed, dieldrin, chlordane, PCBs, and PAHs were detected at the highest concentrations in the first sample collected at the Shoal Creek site, a first-flush effect, but not at the Boggy Creek site. Temporal patterns in concentrations of DDT and its breakdown products varied from one event to the next. In spite of the first-flush effect in concentrations at the Shoal Creek site, most of the contaminant load was transported at peak discharge, when suspended-sediment concentration and load are maximum.
The upper Illinois River Basin (UIRB) is the 10,949 square mile drainage area upstream from Ottawa, Illinois, on the Illinois River. The UIRB is one of 13 studies that began in 1996 as part of the U.S. Geological Survey's National Water-Quality Assessment program. A compilation of environmental data from Federal, State, and local agencies provides a description of the environmental setting of the UIRB. Environmental data include natural factors such as bedrock geology, physiography and surficial geology, soils, vegetation, climate, and ecoregions; and human factors such as land use, urbanization trends, and population change. Characterization of the environmental setting is useful for understanding the physical, chemical, and biological characteristics of surface and ground water in the UIRB and the possible implications of that environmental setting for water quality. Some of the possible implications identified include depletion of dissolved oxygen because of high concentrations of organic matter in wastewater, increased flooding because of suburbanization, elevated arsenic concentrations in ground water because of weathering of shale bedrock, and decreasing ground-water levels because of heavy pumping of water from the bedrock aquifers.
This report on the reconnaissance of surface-water quality in the Weber River basin was prepared by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Division of Water Rights. The purposes of the reconnaissance were: (1) To obtain information on the general inorganic chemical characteristics of the surface water throughout the Weber River basin and, (2) to determine some of the effects of the natural environment and of present water use on these chemical characteristics. The reconnaissance was limited in scope and did not include intensive study of the effects of municipal sewage, irrigation, industry, or mining on water quality. The principal objective was to define the general water-quality characteristics of streams in the basin. A secondary objective was to define specific problem areas or stream reaches.
The Task Group on Global Geochemical Baselines, operating under the auspices of both the International Union of Geological Sciences (IUGS) and the International Association of Geochemistry (IAGC), has the long-term goal of establishing a global geochemical database to document the concentration and distribution of chemical elements in the Earth’s surface or near-surface environment. The database and accompanying element distribution maps represent a geochemical baseline against which future human-induced or natural changes to the chemistry of the land surface may be recognized and quantified. In order to accomplish this long-term goal, the activities of the Task Group include: (1) developing partnerships with countries conducting broad-scale geochemical mapping studies; (2) providing consultation and training in the form of workshops and short courses; (3) organizing periodic international symposia to foster communication among the geochemical mapping community; (4) developing criteria for certifying those projects whose data are acceptable in a global geochemical database; (5) acting as a repository for data collected by those projects meeting the criteria for standardization; (6) preparing complete metadata for the certified projects; and (7) preparing, ultimately, a global geochemical database. This paper summarizes the history and accomplishments of the Task Group since its first predecessor project was established in 1988.
The US Geological Survey, US Department of Agriculture, and US Environmental Protection Agency are conducting research and regional assessments in support of policy alternatives intended to protect water resources from agricultural chemical contamination. The mid-continent was selected because of the intense row crop agriculture and associated herbicide application in this region. An application of a geographic information system is demonstrated for analyzing and comparing the distribution of estimated atrazine use to the detection rate of atrazine in groundwater. Understanding the relations between atrazine use and detection in groundwater is important in policy deliberations to protect water resources. Relational analyses between measures of chemical use and detection rate by natural resource units may provide insight into critical factors controlling the processes that result in groundwater contamination from agricultural chemicals.