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At least 145 records · Page 8Linked to original sources

Ground-coupled acoustic airwaves from Mount St. Helens provide constraints on the May 18, 1980 eruption

The May 18, 1980 Mount St. Helens eruption perturbed the atmosphere and generated atmosphere-to-ground coupled airwaves, which were recorded on at least 35 seismometers operated by the Pacific Northwest Seismograph Network (PNSN). From 102 distinct travel time picks we identify coherent airwaves crossing Washington State primarily to the north and east of the volcano. The travel time curves provide evidence for both stratospheric refractions (at 200 to 300 km from the volcano) as well as probable thermospheric refractions (at 100 to 350 km). The very few first-hand reports of audible volcano sounds within about 80 km of the volcano coincide with a general absence of ground-coupled acoustic arrivals registered within about 100 km and are attributed to upward refraction of sound waves. From the coherent refracted airwave arrivals, we identify at least four distinct sources which we infer to originate 10 s, 114 s, ∼ 180 s and 319 s after the onset of an 8:32:11 PDT landslide. The first of these sources is attributed to resultant depressurization and explosion of the cryptodome. Most of the subsequent arrivals also appear to be coincident with a source located at or near the presumed volcanic conduit, but at least one of the later arrivals suggests an epicenter displaced about 9 km to the northwest of the vent. This dislocation is compatible with the direction of the sector collapse and lateral blast. We speculate that this concussion corresponds to a northern explosion event associated with hot cryptodome entering the Toutle River Valley.

Washington↗

Paleomagnetism of some Precambrian basaltic flows and red beds, Eastern Grand Canyon, Arizona

Lava flows and red sandstone beds near the middle of the Upper Precambrian Grand Canyon Series exhibit stable remanent magnetization. The beds are about 1000 m stratigraphically above rocks of the Grand Canyon Series for which paleomagnetic poles have been reported. All specimens were subjected to stepwise thermal (200°–700°C) or alternating field (25–5000 Oe) demagnetization for the determination of characteristic magnetization. The pole for two flows and an intercalated sandstone bed of the Cardenas Lavas of Ford, Breed and Mitchell (upper Unkar Group), is at 174.6W, 0.4N ( N = 10, K = 50, α 95 = 6.9°). The pole for a weathered zone developed across the Cardenas Lavas is at 167.8W, 49.4N ( N = 5, K = 79, α 95 = 8.6°). The pole for directly overlying sandstone of the Nankoweap Formation of Maxson is at 174.4E, 12.5N ( N = 6, K = 105, α 95 = 6.6°). These poles lie on or near, and appear to follow, part of an apparent polar wandering path recently proposed for the Precambrian of North America by Spall. If the fit is not accidental, little or no rotation has occurred between north-central Arizona and parts of the North American continent used to define the proposed path.

Arizona↗

Tectonic significance of precambrian apatite fission-track ages from the midcontinent United States

Apparent apatite fission-track ages from drill core penetrating basement on the flank of the Transcontinental Arch in northwestern Iowa range from 934 ± 86 to 641 ± 90 Ma. These ages, the oldest reported in North America, record at least two thermal events. The 934 Ma age, which is synchronous with K-Ar ages in the Grenville Province and many K-Ar whole-rock and Rb-Sr isochron ages from the Lake Superior region, may document basement cooling caused by regional uplift and erosion of the crust. The remaining fission-track ages are products of a more recent thermal event, relative to the age of the samples, which raised temperatures into the zone of partial annealing. Heating may have occurred between the Middle Ordovician and Middle Cretaceous by burial of the basement with additional sediment. It is estimated that burial raised temperatures in the part of the basement sampled by the core to between 50 and 75°C. These temperature estimates imply paleogeothermal gradients of about 20°C/km, approximately two and one-half times present-day values, and burial of the basement by an additional 2–3 km of sediment.

Earth and Planetary Science Letters↗

Cassini/VIMS hyperspectral observations of the HUYGENS landing site on Titan

Titan is one of the primary scientific objectives of the NASA-ESA-ASI Cassini-Huygens mission. Scattering by haze particles in Titan's atmosphere and numerous methane absorptions dramatically veil Titan's surface in the visible range, though it can be studied more easily in some narrow infrared windows. The Visual and Infrared Mapping Spectrometer (VIMS) instrument onboard the Cassini spacecraft successfully imaged its surface in the atmospheric windows, taking hyperspectral images in the range 0.4-5.2 ??m. On 26 October (TA flyby) and 13 December 2004 (TB flyby), the Cassini-Huygens mission flew over Titan at an altitude lower than 1200 km at closest approach. We report here on the analysis of VIMS images of the Huygens landing site acquired at TA and TB, with a spatial resolution ranging from 16 to14.4 km/pixel. The pure atmospheric backscattering component is corrected by using both an empirical method and a first-order theoretical model. Both approaches provide consistent results. After the removal of scattering, ratio images reveal subtle surface heterogeneities. A particularly contrasted structure appears in ratio images involving the 1.59 and 2.03 ??m images north of the Huygens landing site. Although pure water ice cannot be the only component exposed at Titan's surface, this area is consistent with a local enrichment in exposed water ice and seems to be consistent with DISR/Huygens images and spectra interpretations. The images show also a morphological structure that can be interpreted as a 150 km diameter impact crater with a central peak. ?? 2006 Elsevier Ltd. All rights reserved.

Planetary and Space Science↗

Interannual observations and quantification of summertime H 2 O ice deposition on the Martian CO 2 ice south polar cap

The spectral signature of water ice was observed on Martian south polar cap in 2004 by the Observatoire pour l'Mineralogie, l'Eau les Glaces et l'Activite (OMEGA) ( Bibring et al., 2004). Three years later, the OMEGA instrument was used to discover water ice deposited during southern summer on the polar cap ( Langevin et al., 2007). However, temporal and spatial variations of these water ice signatures have remained unexplored, and the origins of these water deposits remains an important scientific question. To investigate this question, we have used observations from the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) instrument on the Mars Reconnaissance Orbiter (MRO) spacecraft of the southern cap during austral summer over four Martian years to search for variations in the amount of water ice. We report below that for each year we have observed the cap, the magnitude of the H2O ice signature on the southern cap has risen steadily throughout summer, particularly on the west end of the cap. The spatial extent of deposition is in disagreement with the current best simulations of deposition of water ice on the south polar cap (Montmessin et al., 2007). This increase in water ice signatures is most likely caused by deposition of atmospheric H2O ice and a set of unusual conditions makes the quantification of this transport flux using CRISM close to ideal. We calculate a ‘minimum apparent‘ amount of deposition corresponding to a thin H2O ice layer of 0.2 mm (with 70% porosity). This amount of H2O ice deposition is 0.6–6% of the total Martian atmospheric water budget. We compare our ‘minimum apparent’ quantification with previous estimates. This deposition process may also have implications for the formation and stability of the southern CO2 ice cap, and therefore play a significant role in the climate budget of modern day Mars.

Earth and Planetary Science Letters↗

Does calving matter? Evidence for significant submarine melt

During the summer in the northeast Pacific Ocean, the Alaska Coastal Current sweeps water with temperatures in excess of 12 °C past the mouths of glacierized fjords and bays. The extent to which these warm waters affect the mass balance of Alaskan tidewater glaciers is uncertain. Here we report hydrographic measurements made within Icy Bay, Alaska, and calculate rates of submarine melt at Yahtse Glacier, a tidewater glacier terminating in Icy Bay. We find strongly stratified water properties consistent with estuarine circulation and evidence that warm Gulf of Alaska water reaches the head of 40 km-long Icy Bay, largely unaltered. A 10–20 m layer of cold, fresh, glacially-modified water overlies warm, saline water. The saline water is observed to reach up to 10.4 °C within 1.5 km of the terminus of Yahtse Glacier. By quantifying the heat and salt deficit within the glacially-modified water, we place bounds on the rate of submarine melt. The submarine melt rate is estimated at >9 m d −1 , at least half the rate at which ice flows into the terminus region, and can plausibly account for all of the submarine terminus mass loss. Our measurements suggest that summer and fall subaerial calving is a direct response to thermal undercutting of the terminus, further demonstrating the critical role of the ocean in modulating tidewater glacier dynamics.

Alaska↗

A Next Generation Lunar Orbiter mission

The Moon is the scientific foundation for our knowledge of the early evolution and impact history of the terrestrial planets. Over the last decades the lunar science community has made significant progress in addressing key lunar science and exploration goals, while defining many new high-priority scientific questions regarding the formation and evolution of the Moon. On a broad scale, the last Planetary Decadal Survey defined three scientific objectives to guide studies of the inner planets and Moon. These objectives address the origins and diversity of terrestrial planets, the evolution of life on terrestrial planets, and climate processes on Earth-like planets [1]. Many of these objectives carry forward into exploration goals of a renewed lunar human exploration program, and urgently addressing these objectives will enable the rapid development of exploration plans. A large (Flagship or New Frontiers class) Next Generation Lunar Orbiter (NGLO) mission would address the last Planetary Decadal Survey objective of understanding the origin and diversity of terrestrial planets by studying the geochemistry and geology of the Moon at an unparalleled resolution compared to other lunar mission datasets. Also, NGLO would address the objective of studying the evolution of life on terrestrial planets by furthering knowledge about the composition and distribution of volatile elements on the lunar surface and better characterizing the past and present-day impact rates in the inner Solar System in order to better understand the original delivery of water to Earth. Key exploration goals, including identifying the nature and distribution of lunar volatiles (i.e., water, ice), mapping and characterizing potentially valuable lunar resources, and establishing a human presence on the Moon, also would be addressed by NGLO.

Bulletin of the AAS↗

Isotopic composition of lead in oceanic basalt and its implication to mantle evolution

New data are given in this report for (1) Pb isotopic compositions and U, Th, and Pb concentrations of basalts from the island of Hawaii; (2) redetermined Pb isotopic compositions of some abyssal tholeiites; and (3) U, Th, and Pb concentrations of altered and fresh abyssal basalts, and basalt genesis and mantle evolution are discussed. The Th/U ratios of abyssal and Japanese tholeiites are distinctly lower than those of tholeiites and alkali basalts from other areas. It is thought that these low values reflect a part of the mantle depleted in large ionic lithophile elements. Thus a mantle evolution model is presented, in which Th/U ratios of the depleted zone in the mantle have decreased to ∼2, and U/Pb ratios have increased, showing an apparent ∼1.5-b.y. isochron trend in the 207 Pb/ 204 Pb vs. 206 Pb/ 204 Pb plot. The Pb isotopic compositions of basalts from the island of Hawaii are distinct for each of the five volcanoes, and within each volcano, Pb's of tholeiites and alkali basalts are similar. An interaction between partially melted material (hot plume?) of the asthenosphere and the lithosphere is suggested to explain the trend in the Pb isotopic compositions of Hawaiian basalts.

Earth and Planetary Science Letters↗

Mineralogy and stable isotope geochemistry of hydrothermally altered oceanic rocks

Mineralogical and isotopic variations observed in altered glassy and crystalline rocksfrom the East Pacific Rise and the Mid-Atlantic Ridge provide information about the temperatures of alteration and seawater/rock ratios for various hydrothermal regimes within the oceanic crust. A systematic increase in alteration temperature is evident for the glassy rocksin the sequence: (1) nontronite and celadonite vesicle fillings (35°C), (2) saponite-rich pillow breccias ( 130–170°C), (3) calcite-rich greenstone breccias and epidote-rich greenstone (200–350°C). Theseresults include the highest temperatures thus far reported for saponite formation. The “seawater-dominated” hydrothermal alteration process that formed the saponite-rich pillow breccias is characterized by high water/rock ratios (>0:1), low to moderate temperatures, a seawater origin of most of the carbon in vein calcites (δ 13 C≈0) and the predominance of Fe-rich saponite and calcite as secondary phases. Greenstones (chlorite-quartz-epidote) and greenstone breccias (chlorite-quartz-albite-calcite) are altered in a “rock-dominated” system with lower water/rock ratios (50:1 to < 1:1), higher temperatures, and vein calcites with carbon that is principally of magmatic origin (δ 13 C≈−4). The crystalline rocks (diabase, gabbro, and metagabbro) are affected to varying degrees by pervasive high-temperature seawater interactions that commence soon after solidification, producing varying proportions of fine-grained secondary minerals including talc, smectite, chlorite, vermiculite, actinolite, and sodicplagioclase. Hydrothermal solutions, derived from alteration of the crystalline rocks, are of the appropriate temperature and isotopic composition to alter the overlying glassy rocks to the observed mineralogies as well as being the source of metal-rich deposits associated with the oceanic spreading centers.

Earth and Planetary Science Letters↗

Early Pliocene (Zanclean) sea surface temperature for PlioMIP3

Paleoclimate researchers have been comparing Pliocene environmental data to paleoclimate model results since the 1980s. The Pliocene Model Intercomparison Project (PlioMIP) began in 2008 with a focus on the Late Pliocene. Here we assess the availability and utility of sea surface temperature (SST) data for verification of Pliocene Model Intercomparison Project (PlioMIP3) Early Pliocene (Zanclean) experiments. We analyze published data in terms of quantity and spatial distribution. Only SST estimates derived using alkenone paleo thermometry are reported, and all estimates are based upon the same temperature calibration. Sea surface temperature data are selected from within three distinct time intervals: The early Zanclean 5.3 Ma – 4.2 Ma time slab, and two time slices within the early Zanclean, chosen by PlioMIP3 at 4.870 Ma and 4.474 Ma. Results show the early Zanclean time slab contains 2055 individual estimates. Approximately ∼ 80% of these estimates come from Sites 609, 642, 846, 847, 882, 907, and 1146. There are 17 sites with a total of 42 estimates within the 4.474 Ma ±10 kyr time slice, and 15 sites with a total of 47 data points within the 4.870 Ma ±10 kyr interval. The sparse spatial and temporal distribution of Zanclean data, relative to the data available for the mid Piacenzian, makes point-by-point data model comparison suspect. We suggest interpreting model output against lower resolution long term trends in proxy data, and comparison of models through temperature gradients, may be the most useful application of currently available data. Integrating Zanclean age coastal plain sequences within data model comparison schemes, for increased understanding of regional climate impacts, also holds great potential.

Global and Planetary Change↗

The demise of an icehouse: Calibrating the end of the LPIA

Earth has experienced three complete icehouse-greenhouse turnovers in the Phanerozoic, with the Late Paleozoic Ice Age (LPIA) recognized as the last and most extreme icehouse. The nature, scale and dynamics of the LPIA are characterized by periods of intense glaciation, which are often interrupted by short-lived (1–2 Myrs) intervals associated with ice-free or distal from ice conditions. In this study, we focus on constraining the icehouse-greenhouse turnover across southcentral Gondwana (SCG) reporting new high-resolution U Pb zircon CA-ID-TIMS ages from immediate postglacial facies in the Kalahari and Karoo basins. We integrate these ages with published U Pb zircon CA-ID-TIMS ages ( n = 20) to build a stratigraphic framework for SCG, to investigate the duration and nature of the demise of the LPIA. We confirm the stepwise deglaciation of Gondwana over a ca. 20 Myr period, with deglaciation occurring first in the Paraná Basin at ca. 300 Ma and in the Karoo Basin by 282 Ma. Low-latitude marine carbonates deposited contemporaneously with the final demise of ice is characterized by a major shift towards isotopically depleted δ 13 C and δ 18 O values. We interpret the perturbations in stable isotopes records to be driven by either mantle outgassing or the release of methane and the addition of glacial melt water to the paleo-ocean during warming. The presented stratigraphic framework is built in intracratonic basins, far from any syn - tectonic affects, suggesting a largely climatic driver behind deglaciation events.

Global and Planetary Change↗

Alkali elemental and potassium isotopic compositions of Semarkona chondrules

We report measurements of K isotope ratios in 28 Semarkona chondrules with a wide range of petrologic types and bulk compositions as well as the compositions of CPX-mesostasis pairs in 17 type I Semarkona chondrules, including two chondrules with radial alkali zonation and 19 type II chondrules. Despite the wide range in K/Al ratios, no systematic variations in K isotopic compositions were found. Semarkona chondrules do not record a simple history of Rayleigh-type loss of K. Experimentally determined evaporation rates suggest that considerable alkali evaporation would have occurred during chondrule formation. Nevertheless, based on Na CPX-mesostasis distribution coefficients, the alkali contents of the cores of most chondrules in Semarkona were probably established at the time of final crystallization. However, Na CPX-mesostasis distribution coefficients also show that alkali zonation in type I Semarkona chondrules was produced by entry of alkalis after solidification, probably during parent body alteration. This alkali metasomatism may have gone to completion in some chondrules. Our preferred explanation for the lack of systematic isotopic enrichments, even in alkali depleted type I chondrule cores, is that they exchanged with the ambient gas as they cooled.

Meteoritics and Planetary Science↗

Two Holocene paleofire records from Peten, Guatemala: Implications for natural fire regime and prehispanic Maya land use

Although fire was arguably the primary tool used by the Maya to alter the landscape and extract resources, little attention has been paid to biomass burning in paleoenvironmental reconstructions from the Maya lowlands. Here we report two new well-dated, high-resolution records of biomass burning based on analysis of macroscopic fossil charcoal recovered from lacustrine sediment cores. The records extend from the early Holocene, through the full arc of Maya prehistory, the Colonial, and post-Colonial periods (~ 9000 cal yr BP to the present). (Hereafter BP) The study sites, Lago Paixban and Lago Puerto Arturo, are located in northern Peten, Guatemala. Results provide the first quantitative analysis from the region demonstrating that frequent fires have occurred in the closed canopy forests since at least the early Holocene (~ 9000 BP), prior to occupation by sedentary agriculturalists. Following the arrival of agriculture around 4600 BP, the system transitioned from climate controlled to anthropogenic control. During the Maya period, changes in fire regime are muted and do not appear to be driven by changes in climate conditions. Low charcoal influx and fire frequency in the Earliest Preclassic period suggest that land use strategies may have included intensive agriculture much earlier than previously thought. Preliminary results showing concentrations of soot/black-carbon during the middle and late Preclassic periods are lower than modern background values, providing intriguing implications regarding the efficiency of Maya fuel consumption.

Peten↗

Fe-Ni metal and sulfide minerals in CM chondrites: An indicator for thermal history

CM chondrites were subjected to aqueous alteration and, in some cases, to secondary metamorphic heating. The effects of these processes vary widely, and have mainly been documented in silicate phases. Herein, we report the characteristic features of Fe‐Ni metal and sulfide phases in 13 CM and 2 CM‐related chondrites to explore the thermal history of these chondrites. The texture and compositional distribution of the metal in CM are different from those in unequilibrated ordinary and CO chondrites, but most have similarities to those in highly primitive chondrites, such as CH, CR, and Acfer 094. We classified the CM samples into three categories based on metal composition and sulfide texture. Fe‐Ni metal in category A is kamacite to martensite. Category B is characterized by pyrrhotite grains always containing blebs or lamellae of pentlandite. Opaque mineral assemblages of category C are typically kamacite, Ni‐Co‐rich metal, and pyrrhotite. These categories are closely related to the degree of secondary heating and are not related to degree of the aqueous alteration. The characteristic features of the opaque minerals can be explained by secondary heating processes after aqueous alteration. Category A CM chondrites are unheated, whereas those in category B experienced small degrees of secondary heating. CMs in category C were subjected to the most severe secondary heating process. Thus, opaque minerals can provide constraints on the thermal history for CM chondrites.

Meteoritics and Planetary Science↗

Geologic map of the Galaxias quadrangle (MTM 35217) of Mars

The Galaxias region (MTM 35217) is one of a series of 1:500,000-scale science study areas on Mars sponsored by NASA's Planetary Geology and Geophysics Program. Situated near the northern limit of lava flows associated with Elysium Mons, this region includes a mixture of volcanic and nonvolcanic terrains. The region is also of interest for the fluvial systems that originate along the distal margins of the Elysium lava flows. Resolution of Viking Orbiter images used to prepare the base map ranges from 40 to 160 m/pixel. High-resolution frames (40 to 80 m/pixel) are found in the southeastern part of the map area and along the north edge of the quadrangle, but over half the quadrangle is included in medium-resolution frames (150 m/pixel). Two 8 m/pixel, very high resolution scenes are available (see fig. 1). Interpretation is complicated by variable resolution and sun angles that vary from east to west illumination on different images. Mapping methods and principles are adapted from those developed for lunar photogeologic mapping by Shoemaker and Hackman (1962), refined by Wilhelms (1972), and successfully applied by many workers to a variety of planetary surfaces. Mapping units are distinguished by topography and texture and are ranked by relative age on the basis of superposition and transection relations. Material units are assigned to time-stratigraphic systems defined by Scott and Carr (1978) and Tanaka (1986). This area is included within earlier maps that used Mariner 9 images at 1:5,000,000 scale (Elston, 1979) and globally at 1:25,000,000 scale (Scott and Carr, 1978). Regional maps based on the much higher resolutions of Viking Orbiter allowed more detailed discrimination of materials by Greeley and Guest (1987) at 1:15,000,000 scale and Tanaka and others (1992) at 1:5,000,000 scale. Some map units on this 1:500,000-scale map correspond to, or are partially equivalent to, units on the larger scale maps of Greeley and Guest (1987) and Tanaka and others (1992). Established terminology is used where feasible, but the scale of this map requires that some new units be introduced and that some previous terminology be redefined. Photogeologic methods are limited; therefore, more than one geologic explanation is given for some material units that do not readily lend themselves to an unequivocal interpretation.

IMAP↗

Seasonal temperature responses to land-use change in the western United States

In the western United States, more than 79 000??km2 has been converted to irrigated agriculture and urban areas. These changes have the potential to alter surface temperature by modifying the energy budget at the land-atmosphere interface. This study reports the seasonally varying temperature responses of four regional climate models (RCMs) - RSM, RegCM3, MM5-CLM3, and DRCM - to conversion of potential natural vegetation to modern land-cover and land-use over a 1-year period. Three of the RCMs supplemented soil moisture, producing large decreases in the August mean (- 1.4 to - 3.1????C) and maximum (- 2.9 to - 6.1????C) 2-m air temperatures where natural vegetation was converted to irrigated agriculture. Conversion to irrigated agriculture also resulted in large increases in relative humidity (9% to 36% absolute change). Modeled changes in the August minimum 2-m air temperature were not as pronounced or consistent across the models. Converting natural vegetation to urban land-cover produced less pronounced temperature effects in all models, with the magnitude of the effect dependent upon the preexisting vegetation type and urban parameterizations. Overall, the RCM results indicate that the temperature impacts of land-use change are most pronounced during the summer months, when surface heating is strongest and differences in surface soil moisture between irrigated land and natural vegetation are largest. ?? 2007 Elsevier B.V. All rights reserved.

Global and Planetary Change↗

Effect of calcium carbonate saturation of seawater on coral calcification

The carbonate chemistry of seawater is usually not considered to be an important factor influencing calcium-carbonate-precipitation by corals because surface seawater is supersaturated with respect to aragonite. Recent reports, however, suggest that it could play a major role in the evolution and biogeography of recent corals. We investigated the calcification rates of five colonies of the zooxanthellate coral Stylophora pistillata in synthetic seawater using the alkalinity anomaly technique. Changes in aragonite saturation from 98% to 585% were obtained by manipulating the calcium concentration. The results show a nonlinear increase in calcification rate as a function of aragonite saturation level. Calcification increases nearly 3-fold when aragonite saturation increases from 98% to 390%, i.e., close to the typical present saturation state of tropical seawater. There is no further increase of calcification at saturation values above this threshold. Preliminary data suggest that another coral species, Acropora sp., displays a similar behaviour. These experimental results suggest: (l) that the rate of calcification does not change significantly within the range of saturation levels corresponding to the last glacial-interglacial cycle, and (2) that it may decrease significantly in the future as a result of the decrease in the saturation level due to anthropogenic release of CO2 into the atmosphere. Experimental studies that control environmental conditions and seawater composition provide unique opportunities to unravel the response of corals to global environmental changes.

Global and Planetary Change↗

Hydrogen isotopes in high 3He/4He submarine basalts: Primordial vs. recycled water and the veil of mantle enrichment

The hydrogen isotope value ( δ D) of water indigenous to the mantle is masked by the early degassing and recycling of surface water through Earth's history. High 3 He/ 4 He ratios in some ocean island basalts, however, provide a clear geochemical signature of deep, primordial mantle that has been isolated within the Earth's interior from melting, degassing, and convective mixing with the upper mantle. Hydrogen isotopes were measured in high 3 He/ 4 He submarine basalt glasses from the Southeast Indian Ridge (SEIR) at the Amsterdam–St. Paul (ASP) Plateau ( δ D = −51 to −90‰, 3 He/ 4 He = 7.6 to 14.1 R A ) and in submarine glasses from Loihi seamount south of the island of Hawaii ( δ D = −70 to −90‰, 3 He/ 4 He = 22.5 to 27.8 R A ). These results highlight two contrasting patterns of δ D for high 3 He/ 4 He lavas: one trend toward high δ D of approximately −50‰, and another converging at δ D = −75‰. These same patterns are evident in a global compilation of previously reported δ D and 3 He/ 4 He results. We suggest that the high δ D values result from water recycled during subduction that is carried into the source region of mantle plumes at the core–mantle boundary where it is mixed with primordial mantle, resulting in high δ D and moderately high 3 He/ 4 He. Conversely, lower δ D values of −75‰, in basalts from Loihi seamount and also trace element depleted mid-ocean ridge basalts, imply a primordial Earth hydrogen isotopic value of −75‰ or lower. δ D values down to −100‰ also occur in the most trace element-depleted mid-ocean ridge basalts, typically in association with 87 Sr/ 86 Sr ratios near 0.703. These lower δ D values may be a result of multi-stage melting history of the upper mantle where minor D/H fractionation could be associated with hydrogen retention in nominally anhydrous residual minerals. Collectively, the predominance of δ D around −75‰ in the majority of mid-ocean ridge basalts and in high 3 He/ 4 He Loihi basalts is consistent with an origin of water on Earth that was dominated by accretion of chondritic material.

Earth and Planetary Science Letters↗